CN102205207A - Coal mine methane preheating catalytic oxidation device with multiple reaction chambers - Google Patents

Coal mine methane preheating catalytic oxidation device with multiple reaction chambers Download PDF

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Publication number
CN102205207A
CN102205207A CN2011100891638A CN201110089163A CN102205207A CN 102205207 A CN102205207 A CN 102205207A CN 2011100891638 A CN2011100891638 A CN 2011100891638A CN 201110089163 A CN201110089163 A CN 201110089163A CN 102205207 A CN102205207 A CN 102205207A
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preheater
air inlet
weary wind
waste gas
coal mine
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CN102205207B (en
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刘永启
刘瑞祥
王延遐
郑斌
高振强
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Shandong University of Technology
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Shandong University of Technology
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Abstract

The invention relates to a coal mine methane preheating catalytic oxidation device with multiple reaction chambers and belongs to technical field of ultralow-concentration methane oxidation. The device comprises a coal mine methane supply system, a pre-heater, even reaction chambers, a suction system, an exhaust system, an exhaust heating system and a measuring and controlling system, wherein an electric heater, a temperature-equalizing and flow-equalizing bed and a catalytic oxidation bed are arranged in each reaction chamber. After starting to heat, the coal mine methane is heated after entering into the pre-heater through the coal mine methane supply system; and then the coal mine methane is supplied to each reaction chamber through the suction system; carbon dioxide and water are oxidized in the catalytic oxidation bed of the reaction chamber; after the reacted heat gas is converged by the exhaust system, one part of the heat gas is used for utilizing the heat; and the residual heat gas enters into the pre-heater and transfers the heat to the fresh coal mine methane, and the residual heat gas is lastly discharged into the atmosphere after being cooled. The coal mine methane preheating catalytic oxidation device with multiple reaction chambers has the advantages of compact structure, low power consumption, simpleness in running, high reliability, and the like.

Description

Multi-reaction chamber coal mine methane preheating catalytic oxidizer
Technical field
The present invention relates to a kind of multi-reaction chamber coal mine methane preheating catalytic oxidizer, belong to super low concentration methane oxidation technical field.
Background technology
The main component of coal mine gas is a methane, is a kind of greenhouse gases, and its greenhouse effects are 21 times of carbon dioxide.In recent years, China is more than 150 hundred million Nm by coal mine methane discharging methane every year 3If this ventilation air gas is used, amount to 2,300 ten thousand tons of standard coals approximately, can reduce discharging 200,000,000 tons of equivalent carbon dioxide.Coal mine wind-lack gas concentration is very low, be difficult to utilize conventional burners directly to be burnt, effectively utilizing method at present is to adopt hot counter flow oxidation technology (Thermal Flow Reversal Reactor, be called for short TFRR) and catalysis counter flow oxidation technology (Catalytic Flow Reversal is called for short CFRR).The basic functional principle of these two kinds of counter flow oxidation technology is identical substantially with structure, and the main distinction is that CFRR has used oxidation catalyst, has reduced the needed temperature of gas oxidation.The MEGTEC company of Sweden adopts the methane in the TFRR technical finesse coal mine methane, and reclaims its energy.MEGTEC company has installed 4 cover TFRR in 2004 at Australia's ratio with than opening up company West Cliff colliery, brings into operation at the beginning of 2007, about 20% coal mine methane in West Cliff colliery can be converted into the useful energy, and generating capacity is 5MW; In one tame colliery, Dengfeng City, China Henan 1 cover TFRR was installed in 2007, has been specifically designed to the destruction ventilation air methane.Units such as the Shandong Technology Univ of China, Shengli Oil Field Shengli Power Machinery Group Co., Ltd, the black bavin new forms of energy in Zibo Co., Ltd also independent development successively the hot counter flow oxidation device of coal mine wind-lack gas, and carried out application test research at colliery scene, begun the demonstration operation now.Nineteen ninety-five Canada mineral and energy technology center (CANMET) begin to research and develop coal mine wind-lack gas catalysis countercurrent reaction (CFRR) technology, develop laboratory scale catalytic methane countercurrent reaction chamber now, and on this device, carried out coal mine wind-lack gas catalytic oxidation simulated test.On the whole, the gas in the coal mine methane can be administered and utilize in hot countercurrent reaction chamber and catalysis countercurrent reaction chamber effectively.But, have only hot countercurrent reaction technology successfully to carry out commercial application at present at colliery scene from the practical application angle.But adopt TFRR technical finesse coal mine wind-lack gas also to exist following problem: (1) TFRR takes up an area of relatively large, for example will handle 150m with the TFRR unit of MEGTEC company 3The gas of/s, its plant area area is about (63 * 14.62 * 4.49) m; (2) oxidation bed of TFRR is made of a large amount of ceramic honey combs, and in general problems such as ceramic honey comb can ftracture after long-term use the, fragmentation and obstruction will change one time ceramic honey comb every year, and maintenance cost is too high; (3) drag losses of TFRR is very big, and generally more than 8000KPa, the energy consumption of blower fan is very high; (4) air-flow in the oxidation bed of TFRR need constantly be changed direction, and maintains the middle part of oxidation bed to guarantee high-temperature area, and control degree is automatically had relatively high expectations, and operating technology requires very high.These subject matters have strengthened the difficulty that the TFRR technology is applied.
Summary of the invention
Purpose of the present invention is exactly that defective, a kind of volume of innovation development that will overcome above-mentioned technology existence are little, the coal mine methane preheating catalytic oxidizer with multi-reaction chamber of compact conformation.Its technical scheme is:
A kind of multi-reaction chamber coal mine methane preheating catalytic oxidizer comprises weary wind supply air system, preheater, even number reative cell, air inlet system and exhaust system, bleed heat-obtaining system, measurement and control system, it is characterized in that:
Weary wind supply air system comprises blower fan, the first weary wind transfer pipeline and the second weary wind transfer pipeline, and an end of the first weary wind transfer pipeline is communicated with the mine air-lack outlet, and the other end is communicated with the second weary wind transfer pipeline through blower fan;
Preheater comprises the preheater core, the weary wind inlet of preheater, the weary wind outlet of preheater, the preheater exhaust gas entrance, the preheater waste gas outlet, preheater shell and the 4th insulation layer, wherein the preheater core adopts gas-gas dividing wall type heat exchanger, the weary wind passage two ends of preheater in-core portion are communicated with weary wind inlet of preheater and the weary wind outlet of preheater respectively, the exhaust steam passage two ends of preheater in-core portion are communicated with preheater exhaust gas entrance and preheater waste gas outlet respectively, the weary wind inlet of preheater passes the 4th insulation layer, reaching the preheater shell outside is communicated with the second weary wind transfer pipeline, the 4th insulation layer is passed in the weary wind outlet of preheater, reach the preheater shell outside, be communicated with the inlet end of air inlet system and exhaust system, the preheater waste gas outlet is communicated with ambient atmosphere through waste gas outlet pipe;
The even number reative cell is arranged side by side, arranging the electrical heating starting drive successively along gas flow direction in each reative cell, samming current-sharing bed and catalytic oxidation bed, wherein samming current-sharing bed is piled up by the honeycomb ceramic heat accumulator of macroporosity and is constituted, some circles are arranged on the honeycomb ceramic heat accumulator, square or polygonal hole, filling catalyst in the catalytic oxidation bed, catalyst is that the cordierite honeycomb ceramic with small porosity is a carrier, alundum (Al is second carrier, Pt, Pd is a main active, be prepared from the equally distributed method of high dispersive rate, and samming current-sharing bed and catalytic oxidation bed both sides are equipped with fixed network, and the gas flow direction in two adjacent reative cells is opposite;
Air inlet system and exhaust system comprise the hot blast tube connector, air inlet pipe, a plurality of air intake branches, a plurality of air inlet flared tubes, a plurality of air inlet cloth bellows, a plurality of waste gas plenum chambers, a plurality of collapsible tubes, a plurality of waste gas arms, flue gas leading and waste gas flared tube, the outside that wherein is positioned at two reative cells of outermost end is communicated with air inlet cloth bellows, waste gas plenum chamber and air inlet cloth bellows are disposed between the two adjacent reative cells successively, and be communicated with reative cell respectively, be that each reative cell all is communicated with air inlet cloth bellows and a waste gas plenum chamber, each air inlet cloth bellows is all successively through an air inlet flared tube, air intake branch is communicated with air inlet pipe, each waste gas plenum chamber is all successively through a collapsible tube, a waste gas arm is communicated with flue gas leading, air inlet pipe connects the weary wind outlet of preheater through the hot blast tube connector, and flue gas leading connects the preheater exhaust gas entrance through the waste gas flared tube;
The heat-obtaining system of bleeding comprises the exhaust tube that is provided with control valve, and wherein the inlet end of exhaust tube is communicated with flue gas leading;
Measurement and control system comprises: measurement and control unit; Be arranged on first pressure sensor, concentration sensor and flowmeter on the second weary wind transfer pipeline, be respectively applied for pressure, concentration and the flow of measuring weary wind in the second weary wind transfer pipeline; Be arranged on second pressure sensor and first temperature sensor on the hot blast tube connector, be used to measure the pressure and temperature of weary wind in the hot blast tube connector; Second temperature sensor that is arranged on the honeycomb ceramic heat accumulator inside of measuring the catalytic oxidation bed is used to measure the temperature of catalytic oxidation bed; Be arranged on the three-temperature sensor on the waste gas outlet pipe, be used to measure the temperature of waste gas outlet; Be arranged on the 4th temperature sensor on the exhaust tube, be used to measure the temperature of hot blast of bleeding; The output of first temperature sensor, second temperature sensor, three-temperature sensor, the 4th temperature sensor, first pressure sensor, second pressure sensor, concentration sensor and flowmeter links to each other with measurement and control unit by holding wire, and the control end of control valve links to each other with measurement and control unit by holding wire.
Described multi-reaction chamber coal mine methane preheating catalytic oxidizer, reative cell is surrounded by inner housing, and the outside of inner housing is surrounded by the 3rd insulation layer, and the 3rd insulation layer outside is provided with shell body.
Described multi-reaction chamber coal mine methane preheating catalytic oxidizer, fixed network are used for fixing the honeycomb ceramic heat accumulator of filling in the samming current-sharing bed and the catalyst carrier of the interior filling of catalytic oxidation bed, fixedly connected with the inwall of inner housing around the fixed network.
Described multi-reaction chamber coal mine methane preheating catalytic oxidizer, electrical heating starting drive comprise a plurality of electrical heating wire and stay pipes parallel to each other of being wound with, and the two ends of each stay pipe are all passed inner housing, are inserted on the 3rd insulation layer.
Described multi-reaction chamber coal mine methane preheating catalytic oxidizer, the junction of inner housing and air inlet cloth bellows, waste gas plenum chamber is equipped with sealing gasket.
Described multi-reaction chamber coal mine methane preheating catalytic oxidizer, the outside of hot blast tube connector, air inlet pipe, air inlet flared tube, collapsible tube, flue gas leading and exhaust tube is equipped with the first insulation layer, and the outside of air inlet cloth bellows, waste gas plenum chamber is equipped with the second insulation layer.
Its operation principle is: behind the device heating starting during operate as normal, from the weary wind of the mine air-lack outlet first weary wind transfer pipeline of flowing through successively, blower fan, the weary wind inlet of the second weary wind transfer pipeline and preheater enters preheater, be heated to heat up at preheater and reach methane and can get temperature by catalytic oxidation, again through the weary wind outlet of preheater, the hot blast tube connector enters air inlet pipe, pass through the air inlet flared tube more successively after a plurality of air intake branch shuntings through air inlet pipe, air inlet cloth bellows enter the reative cell of each reative cell, in the catalytic oxidation bed of reative cell, be oxidized to carbon dioxide and water, reacted hot gas is through the waste gas plenum chamber, collapsible tube confluxes in flue gas leading, a part is carried out heat utilization through exhaust tube is removed, remaining gas is through the waste gas flared tube, the preheater exhaust gas entrance enters preheater, with the fresh weary wind of heat transferred, the cooling back is by the preheater waste gas outlet, waste gas outlet pipe enters among the atmosphere.
The present invention compared with prior art, its advantage and beneficial effect are:
1, a plurality of reative cells are combined in employing, and adopt a preheater to concentrate preheating, can reduce the volume and the floor space of whole device greatly; This kind structure realizes modularized design and manufacturing easily simultaneously.
2, the flow resistance of preheater is less, thereby the flow resistance of whole device is less, can reduce the power of blower fan effectively, improves the performance driving economy of device.
3, have only filled honeycomb pottery in samming current-sharing bed and the catalytic oxidation bed, the ceramic honey comb consumption significantly reduces, and then has reduced because of changing the maintenance cost that ceramic honey comb brings.
Description of drawings
Fig. 1 is the section of structure of the embodiment of the invention 1.
Fig. 2 is an A-A profile embodiment illustrated in fig. 1.
Fig. 3 is a B-B profile embodiment illustrated in fig. 1.
Fig. 4 is the C-C profile of Fig. 2.
Fig. 5 is the partial structurtes profile of the embodiment of the invention 2.
Fig. 6 is a D-D profile embodiment illustrated in fig. 5.
:1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24.25. 26. 27. 28. 29. 30.31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45.
The specific embodiment
Below in conjunction with embodiment embodiment of the present invention are further specified.
Embodiment 1
In the embodiment shown in Fig. 1-4 1: the coal mine wind-lack gas preheating catalytic oxidizer with four reative cells 16 includes weary wind supply air system, preheater 8, reative cell 16, air inlet system and exhaust system, bleed heat-obtaining system, measurement and control system.Wherein:
Weary wind supply air system comprises that an end of blower fan 1, the first weary wind transfer pipeline 2 and second weary wind transfer pipeline 7, the first weary wind transfer pipelines 2 is communicated with the mine air-lack outlet, and the other end is communicated with the second weary wind transfer pipeline 7 through blower fan 1;
Preheater 8 comprises preheater core 39, the weary wind inlet 44 of preheater, the weary wind outlet 43 of preheater, preheater exhaust gas entrance 42, preheater waste gas outlet 38, preheater shell 41 and the 4th insulation layer 40, wherein preheater core 39 adopts gas-gas dividing wall type heat exchanger, the weary wind passage two ends of preheater core 39 inside are communicated with weary wind inlet 44 of preheater and the weary wind outlet 43 of preheater respectively, the exhaust steam passage two ends of preheater core 39 inside are communicated with preheater exhaust gas entrance 42 and preheater waste gas outlet 38 respectively, the weary wind inlet 44 of preheater passes the 4th insulation layer 40, reaching preheater shell 41 outsides is communicated with the second weary wind transfer pipeline 7, the 4th insulation layer 40 is passed in the weary wind outlet 43 of preheater, reach preheater shell 41 outsides, be communicated with the inlet end of air inlet system and exhaust system, preheater waste gas outlet 38 is communicated with ambient atmosphere through waste gas outlet pipe 6;
Four reative cells 16 are arranged side by side, and each reative cell 16 surrounds by inner housing 30, and the outside of inner housing 30 is surrounded by the 3rd insulation layer 31, and the 3rd insulation layer 31 outside are provided with shell body 29; Arranging electrical heating starting drive, samming current-sharing bed 17 and catalytic oxidation bed 18 successively along gas flow direction in each reative cell 16, wherein the electrical heating starting drive comprises a plurality of electrical heating wire 32 and stay pipes 33 parallel to each other of being wound with, and the two ends of each stay pipe 33 are all passed inner housing 30, are inserted on the 3rd insulation layer 31; Samming current-sharing bed 17 is piled up by the honeycomb ceramic heat accumulator of macroporosity and is constituted, some circles, square or polygonal hole are arranged on the honeycomb ceramic heat accumulator, filling catalyst in the catalytic oxidation bed 18, catalyst is that the cordierite honeycomb ceramic with small porosity is a carrier, alundum (Al is second carrier, Pt, Pd are main active, be prepared from the equally distributed method of high dispersive rate, and samming current-sharing bed 17 and catalytic oxidation bed 18 both sides are equipped with fixed network 19; Fixed network 19 is used for fixing the honeycomb ceramic heat accumulator of filling in the samming current-sharing bed 17 and the catalyst carrier of catalytic oxidation bed 18 interior fillings, fixedlys connected with the inwall of inner housing 30 around the fixed network 19; Gas flow direction in adjacent two reative cells 16 is opposite;
Air inlet system and exhaust system comprise hot blast tube connector 9, air inlet pipe 26, three air intake branches 22, three air inlet flared tubes 20, three air inlet cloth bellows 25, two waste gas plenum chambers 28, two collapsible tubes 34, two waste gas arms 35, flue gas leading 36 and waste gas flared tubes 12.The outside that wherein is positioned at two reative cells 16 of outermost end is communicated with air inlet cloth bellows 25, waste gas plenum chamber 28 and air inlet cloth bellows 25 are disposed between the two adjacent reative cells 16 successively, also are communicated with reative cell 16 respectively, be that each reative cell 16 all is communicated with air inlet cloth bellows 25 and a waste gas plenum chamber 28, and the junction of the inner housing 30 of each reative cell 16 and air inlet cloth bellows 25, waste gas plenum chamber 28 is equipped with sealing gasket 27; Each air inlet cloth bellows 25 all is communicated with air inlet pipe 26 through an air inlet flared tube 20, air intake branch 22 successively, each waste gas plenum chamber 28 all is communicated with flue gas leading 36 through a collapsible tube 34, a waste gas arm 35 successively, air inlet pipe 26 connects the weary wind outlet 43 of preheater through hot blast tube connector 9, and flue gas leading 36 connects preheater exhaust gas entrance 42 through waste gas flared tube 12; The outside of hot blast tube connector 9, air inlet pipe 26, air inlet flared tube 20, collapsible tube 34, flue gas leading 36 is equipped with the first insulation layer 23, and the outside of air inlet cloth bellows 25, waste gas plenum chamber 28 is equipped with the second insulation layer 24;
The heat-obtaining system of bleeding comprises the exhaust tube 14 that is provided with control valve 13,, wherein the outside of exhaust tube 14 is provided with the first insulation layer 23, and the inlet end of exhaust tube 14 is communicated with flue gas leading 36;
Measurement and control system comprises: measurement and control unit 37; Be arranged on first pressure sensor 5, concentration sensor 4 and flowmeter 3 on the second weary wind transfer pipeline 7, be respectively applied for pressure, concentration and the flow of measuring weary wind in the second weary wind transfer pipeline 7; Be arranged on second pressure sensor 10 and first temperature sensor 11 on the hot blast tube connector 9, be used to measure the pressure and temperature of weary wind in the hot blast tube connector 9; Be arranged on second temperature sensor 21 of the honeycomb ceramic heat accumulator inside of measuring catalytic oxidation bed 18, be used to measure the temperature of catalytic oxidation bed 18; Be arranged on the three-temperature sensor 45 on the waste gas outlet pipe 6, be used to measure the temperature of waste gas outlet; Be arranged on the 4th temperature sensor 15 on the exhaust tube 14, be used to measure the temperature of hot blast of bleeding; The output of first temperature sensor 11, second temperature sensor 21, three-temperature sensor 45, the 4th temperature sensor 15, first pressure sensor 5, second pressure sensor 10, concentration sensor 4 and flowmeter 3 links to each other with measurement and control unit 37 by holding wire, and the control end of control valve 13 links to each other with measurement and control unit 37 by holding wire.
Embodiment 2
In the embodiment shown in Fig. 5-6 2: coal mine wind-lack gas preheating catalytic oxidizer has six reative cells 16, air inlet system and exhaust system are made of hot blast tube connector 9, air inlet pipe 26, four air inlet flared tubes 20, four air inlet cloth bellows 25, three waste gas plenum chambers 28, three collapsible tubes 34, flue gas leading 36, waste gas flared tubes 12, air inlet pipe 26 is provided with four air intake branches 22, flue gas leading 36 is provided with three waste gas arms 35, and remainder is identical with embodiment 1.

Claims (6)

1. a multi-reaction chamber coal mine methane preheating catalytic oxidizer comprises weary wind supply air system, preheater (8), even number reative cell (16), air inlet system and exhaust system, bleed heat-obtaining system and measurement and control system, it is characterized in that:
Weary wind supply air system comprises blower fan (1), the first weary wind transfer pipeline (2) and the second weary wind transfer pipeline (7), and an end of the first weary wind transfer pipeline (2) is communicated with the mine air-lack outlet, and the other end is communicated with the second weary wind transfer pipeline (7) through blower fan (1);
Preheater (8) comprises preheater core (39), the weary wind inlet of preheater (44), the weary wind outlet of preheater (43), preheater exhaust gas entrance (42), preheater waste gas outlet (38), preheater shell (41) and the 4th insulation layer (40), wherein preheater core (39) adopts gas-gas dividing wall type heat exchanger, the inner weary wind passage two ends of preheater core (39) are communicated with weary wind inlet of preheater (44) and the weary wind outlet of preheater (43) respectively, the inner exhaust steam passage two ends of preheater core (39) are communicated with preheater exhaust gas entrance (42) and preheater waste gas outlet (38) respectively, the weary wind inlet of preheater (44) passes the 4th insulation layer (40), reaching preheater shell (41) outside is communicated with the second weary wind transfer pipeline (7), the 4th insulation layer (40) is passed in the weary wind outlet of preheater (43), reach preheater shell (41) outside, be communicated with the inlet end of air inlet system and exhaust system, preheater waste gas outlet (38) is communicated with ambient atmosphere through waste gas outlet pipe (6);
Even number reative cell (16) is arranged side by side, arranging the electrical heating starting drive successively along gas flow direction in each reative cell (16), samming current-sharing bed (17) and catalytic oxidation bed (18), wherein samming current-sharing bed (17) is piled up by the honeycomb ceramic heat accumulator of macroporosity and is constituted, some circles are arranged on the honeycomb ceramic heat accumulator, square or polygonal hole, the interior filling catalyst of catalytic oxidation bed (18), catalyst is that the cordierite honeycomb ceramic with small porosity is a carrier, alundum (Al is second carrier, Pt, Pd is a main active, be prepared from the equally distributed method of high dispersive rate, and samming current-sharing bed (17) and catalytic oxidation bed (18) both sides are equipped with fixed network (19), and the gas flow direction in adjacent two reative cells (16) is opposite;
Air inlet system and exhaust system comprise hot blast tube connector (9), air inlet pipe (26), a plurality of air intake branches (22), a plurality of air inlet flared tubes (20), a plurality of air inlet cloth bellows (25), a plurality of waste gas plenum chambers (28), a plurality of collapsible tubes (34), a plurality of waste gas arms (35), flue gas leading (36) and waste gas flared tube (12), the outside that wherein is positioned at two reative cells (16) of outermost end is communicated with air inlet cloth bellows (25), waste gas plenum chamber (28) and air inlet cloth bellows (25) are disposed between adjacent two reative cells (16) successively, and be communicated with reative cell (16) respectively, be that each reative cell (16) all is communicated with air inlet cloth bellows (25) and a waste gas plenum chamber (28), each air inlet cloth bellows (25) is all successively through an air inlet flared tube (20), air intake branch (22) is communicated with air inlet pipe (26), each waste gas plenum chamber (28) is all successively through a collapsible tube (34), a waste gas arm (35) is communicated with flue gas leading (36), air inlet pipe (26) connects the weary wind outlet of preheater (43) through hot blast tube connector (9), and flue gas leading (36) connects preheater exhaust gas entrance (42) through waste gas flared tube (12);
The heat-obtaining system of bleeding comprises the exhaust tube (14) that is provided with control valve (13), and wherein the inlet end of exhaust tube (14) is communicated with flue gas leading (36);
Measurement and control system comprises: measurement and control unit (37); Be arranged on first pressure sensor (5), concentration sensor (4) and flowmeter (3) on the second weary wind transfer pipeline (7), be respectively applied for pressure, concentration and the flow of measuring weary wind in the second weary wind transfer pipeline (7); Be arranged on second pressure sensor (10) and first temperature sensor (11) on the hot blast tube connector (9), be used to measure the pressure and temperature of weary wind in the hot blast tube connector (9); Second temperature sensor (21) that is arranged on the honeycomb ceramic heat accumulator inside of measuring catalytic oxidation bed (18) is used to measure the temperature of catalytic oxidation bed (18); Be arranged on the three-temperature sensor (45) on the waste gas outlet pipe (6), be used to measure the temperature of waste gas outlet; Be arranged on the 4th temperature sensor (15) on the exhaust tube (14), be used to measure the temperature of hot blast of bleeding; The output of first temperature sensor (11), second temperature sensor (21), three-temperature sensor (45), the 4th temperature sensor (15), first pressure sensor (5), second pressure sensor (10), concentration sensor (4) and flowmeter (3) links to each other with measurement and control unit (37) by holding wire, and the control end of control valve (13) links to each other with measurement and control unit (37) by holding wire.
2. multi-reaction chamber coal mine methane preheating catalytic oxidizer as claimed in claim 1, it is characterized in that: reative cell (16) is surrounded by inner housing (30), the outside of inner housing (30) is surrounded by the 3rd insulation layer (31), and the 3rd insulation layer (31) outside is provided with shell body (29).
3. multi-reaction chamber coal mine methane preheating catalytic oxidizer as claimed in claim 1, it is characterized in that: fixed network (19) is used for fixing the honeycomb ceramic heat accumulator of the interior filling of samming current-sharing bed (17) and the catalyst carrier of the interior filling of catalytic oxidation bed (18), fixedlys connected with the inwall of inner housing (30) around the fixed network (19).
4. multi-reaction chamber coal mine methane preheating catalytic oxidizer as claimed in claim 1, it is characterized in that: the electrical heating starting drive comprises a plurality of electrical heating wire (32) and stay pipes (33) parallel to each other of being wound with, and the two ends of each stay pipe (33) are all passed inner housing (30), are inserted on the 3rd insulation layer (31).
5. multi-reaction chamber coal mine methane preheating catalytic oxidizer as claimed in claim 1 is characterized in that: inner housing (30) is equipped with sealing gasket (27) with the junction of air inlet cloth bellows (25), waste gas plenum chamber (28).
6. multi-reaction chamber coal mine methane preheating catalytic oxidizer as claimed in claim 1, it is characterized in that: the outside of hot blast tube connector (9), air inlet pipe (26), air inlet flared tube (20), collapsible tube (34), flue gas leading (36) and exhaust tube (14) is equipped with the first insulation layer (23), and the outside of air inlet cloth bellows (25), waste gas plenum chamber (28) is equipped with the second insulation layer (24).
CN 201110089163 2011-04-11 2011-04-11 Coal mine methane preheating catalytic oxidation device with multiple reaction chambers Expired - Fee Related CN102205207B (en)

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CN102773046A (en) * 2012-08-05 2012-11-14 山东理工大学 Combustor started regenerative catalytic oxidation device with a plurality of reaction chambers for coal mine ventilation air methane (VAM)
CN102773047A (en) * 2012-08-05 2012-11-14 山东理工大学 Coal mine ventilation preheating catalytic oxidizer with two-stage hot blast recirculation
CN105080337A (en) * 2015-08-10 2015-11-25 中国矿业大学(北京) Cyclone type coal mine ventilation air methane catalysis oxidation reactor
CN108854517A (en) * 2018-05-31 2018-11-23 上海化工研究院有限公司 A kind of Vehicular heating catalytic decomposition type air cleaning unit
CN108905609A (en) * 2018-07-31 2018-11-30 中国华能集团有限公司 Circulation of tail gas explosion-proof type coal mine gas catalytic oxidizing equipment and method
US10537849B2 (en) 2015-03-11 2020-01-21 Johnson Matthey Davy Technologies Limited Process for removing CO2 from crude natural gas
US10828601B2 (en) 2013-10-21 2020-11-10 Johnson Matthey Davy Technologies Limited Process for removing methane from a gas

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CN102773047A (en) * 2012-08-05 2012-11-14 山东理工大学 Coal mine ventilation preheating catalytic oxidizer with two-stage hot blast recirculation
CN102773047B (en) * 2012-08-05 2014-07-30 山东理工大学 Coal mine ventilation preheating catalytic oxidizer with two-stage hot blast recirculation
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