CN102395464A - 具有非弹性区的双轴弹性非织造层压体 - Google Patents

具有非弹性区的双轴弹性非织造层压体 Download PDF

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Publication number
CN102395464A
CN102395464A CN2009801575234A CN200980157523A CN102395464A CN 102395464 A CN102395464 A CN 102395464A CN 2009801575234 A CN2009801575234 A CN 2009801575234A CN 200980157523 A CN200980157523 A CN 200980157523A CN 102395464 A CN102395464 A CN 102395464A
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CN
China
Prior art keywords
fabric
layered product
twin shaft
melt
rubber
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2009801575234A
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English (en)
Inventor
A·D·韦斯特伍德
W·M·费里
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to CN201610973229.2A priority Critical patent/CN106564255A/zh
Publication of CN102395464A publication Critical patent/CN102395464A/zh
Pending legal-status Critical Current

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Abstract

公开了在双轴弹性非织造层压体中赋予约束的方法,和该受约束层压体本身,所述方法包括提供包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的双轴弹性非织造层压体;和使所述至少一个熔纺弹性织物的至少一部分,或优选,仅一部分熔合到所述可延伸织物的至少一个上以产生至少一个非弹性区。令人希望地,所述至少一个熔纺弹性织物和至少一个可延伸织物或膜是双轴弹性的,并由于所述至少一个熔纺弹性体层而称为是“非织造的”。所述熔纺弹性织物可以包含基于聚烯烃的弹性体或弹性体与热塑性材料的共混物。

Description

具有非弹性区的双轴弹性非织造层压体
相关申请的交叉引用
本申请要求于2009年4月21日提交的U.S.S.N.61/171,135,和于2009年2月27日提交的U.S.S.N.61/156,078的优先权,它们都以全文引入作为参考。本申请涉及于2009年9月24同时提交的国际专利申请号------(带有代理案卷号[2008EM066A-PCT])和------(带有代理案卷号[2008EM066B-PCT])和------(带有代理案卷号[2008EM290-PCT],它们都以全文引入作为参考。
技术领域
本公开内容涉及双轴弹性非织造织物的制备和由其制得的层压体的加工方法,更尤其涉及包含基于聚烯烃的弹性体非织造织物并经加工而在该层压体上赋予某种约束(constraint)的双轴弹性层压体。
背景技术
通常,用于卫生吸收剂市场的弹性组分经设计仅具有横向拉伸(″CD″)或仅具有纵向拉伸(″MD″)。仅有CD拉伸的产品通常用于婴儿尿布或训练罩市场,而仅MD拉伸的产品通常是成人失禁市场要求或优选的。这两种不同优选取向的原因与在转化和制造过程期间衣服和织物进料的取向有直接关系。
某种程度的双轴拉伸可能是更复杂的成人失禁衣服要求的。在成人失禁衣服中,为了维持漏泄保护,产品需要在腰、腹部、下背和胯部周围的大面积内舒适地配合高水平的顺应性。为了做到这一点,织物需要能够在使用者的腰周围拉伸以及沿着使用者躯干垂直地提供某种拉伸。
制造同时结合弹性芯与美学上令人愉悦且可延伸的外覆盖物的单一织物的独特方法是熔纺较高分子量弹性体以提供足够弹性和提供与该弹性织物结合的至少一个更软的外覆盖物或″面″层以形成层压体。层状织物结构将是双轴弹性的,这使得将该织物用于各种卫生转化方法(由于退卷所要求的力)和将织物供入可能引起织物的潜在尺寸变化、变窄/颈缩的机器中更具挑战,这使得制造过程更具挑战。在某些制品中仅沿一个方向具有织物弹性且沿其它方向不具弹性是非常优选的。
为了克服双轴弹性织物造成的转化挑战,本发明人已经发现可以使用压延(calendaring)在织物中引入非弹性区。这些压延区的取向以及数目、间隔、尺寸和图案可以用于仅产生CD拉伸,仅产生MD拉伸或这两者的组合,从而导致受控水平的双轴拉伸。
这种方法的另一个优点是它能够在织物中产生″盲区″或较大非弹性区。这些非弹性区的重要性是它允许婴儿尿布中的弹性翼和″耳″或训练罩(或甚至某些成人失禁衣服)中的侧板更牢固地与底板连接,以及为吊钩/尿布紧固体系提供连接点。没有盲区的情况下,存在这样的担心:弹性织物的蠕变和剪切可能靠近底板或吊钩的连接点发生,这可能引起衣服的配合和功能问题,而导致渗漏增加或衣服不能适当地保留在婴儿或成人上。
相关的在先公开包括U.S.6,465,073和U.S.6,717,028。
发明内容
发明概述
本文公开了在双轴弹性非织造层压体中赋予约束的方法,包括提供包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的双轴弹性非织造层压体(也称为″BEL″);和使所述至少一个熔纺弹性织物的至少一部分,或优选,仅一部分熔合到所述可延伸织物的至少一个上以产生至少一个非弹性区。令人希望地,所述至少一个熔纺弹性织物和至少一个可延伸织物或膜是双轴弹性的,并由于所述至少一个熔纺弹性体层而称为是″非织造的″。
本文还公开了包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的受约束双轴弹性非织造层压体,其中所述织物层的至少一个部分在离散区中彼此熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。
熔合步骤可以通过任何适合的手段例如通过压延,粘合剂,声能,微波能或其它电磁能,或本领域中已知的其它方法进行。构成熔纺弹性织物的纤维包含至少一种弹性体,优选基于丙烯的弹性体,更优选具有小于80dg/min的熔体流动速率(230℃/2.16kg)的丙烯-α-烯烃弹性体。可以将任何其它可熔纺材料与所述弹性体共混以形成弹性层,并且大多数任何材料可以与可以通过其它方法例如共成型(coform)方法等结合的弹性层一起包括。可延伸织物或膜可以使用适合于织造或非织造织物的任何材料例如弹性体、热塑性材料、棉(及其它天然材料)或任何这些材料的共混物制备。构成所述受约束双轴弹性非织造层压体的任一层的纤维可以是单组分或双组分纤维,并且可以具有任何合乎需要的横截面几何形态。
本文公开的各种描述性元素和数值范围可以与其它描述性元素和数值范围结合以描述多层层压体、制品和它们的各种制造方法的优选实施方案;此外,可以将元素的任何数值上限与同样元素的任何数值下限结合以描述优选的实施方案。在这方面,短语″在X至Y的范围内″旨在包括在″X″和″Y″值的范围内。
附图简述
图1a是受约束双轴弹性非织造层压体的一个实施方案的图示,该双轴弹性非织造层压体具有呈连续地沿MD方向具有合乎需要宽度的线条形式的非弹性区,该图示是从该层状织物结构上面观察的;
图1b是受约束双轴弹性非织造层压体的一个实施方案的图示,该双轴弹性非织造层压体具有呈连续地沿CD方向具有合乎需要宽度的线条形式的非弹性区,该图示是从上面观察的;
图2a是受约束双轴弹性非织造层压体的一个实施方案的图示,该双轴弹性非织造层压体具有呈连续地平行于MD方向具有合乎需要宽度的断裂或不连续线条形式的非弹性区,该图示是从上面观察的;
图2b是受约束双轴弹性非织造层压体的一个实施方案的图示,该双轴弹性非织造层压体具有呈连续地相对于MD方向有一定角度具有合乎需要宽度的线条形式的非弹性区,该图示是从上面观察的;和
图3是复杂的受约束双轴弹性非织造层压体的图示,该双轴弹性非织造层压体具有变化宽度的非弹性区以致限定最终用途制品的翼片和背片部分,该最终用途制品可以从该图中描述的梯形区至少部分切割,该图示是从上面观察的。
发明详述
介绍
本文描述了已经被加工而在层压体中形成约束的双轴弹性非织造层压体。此外,所述约束呈多层层压体中的″非弹性区″(或″盲区″)的形式,以致帮助其加工而形成最终制品例如尿布或成人失禁衣服。所述非弹性区可以具有这样的尺寸以致其长度从织物的一个边缘到另一个边缘是连续或不连续的,并具有例如,至少1或2或3或5或10mm的宽度。非弹性区可以呈任何形状。″双轴弹性非织造层压体″(″BEL″)是包括与织物或膜(优选可延伸织物或膜)的至少一个其它层结合的至少一个熔纺弹性织物的层状结构,所述层状结构按织物的纵向(″MD″)和横向(″CD″)都是弹性的。BEL形成时是双轴弹性的并且不需要机械或物理加工例如颈缩和压延来赋予双轴弹性,但是根据需要可以使用这些二次处理。本公开内容描述了受约束BEL和制造BEL和受约束BEL的方法。
本文所使用的″非织造织物″(或″织物″)是方位取向或随机取向的纤维的纺织结构(a textile structure)(例如,片材、网幅或絮垫),没有首先制备纱线或涉及机织或针织方法。本文描述的织物包括可以通过机械、化学或热联锁方法(thermally interlocking process)增强的纤维或连续长丝的网络。非织造织物的实例包括熔纺织物(通过熔纺方法制得)、梳理织物(carded fabric)、干法成网织物(例如,梳理织物或气流成网织物)和湿法成网织物。任何这些类型的织物可以通过本领域中已知的手段物理缠绕,然后可以称为″射流喷网法″织物。
本文所使用的″熔纺织物″是指通过这样一种方法制得的织物,其中纤维的网幅由经过一个或多个模头的小孔(直径数量级为0.1-2mm)或喷丝头喷嘴挤出以形成细长丝(数量级为0.1-250μm)的聚合物熔体或溶液形成,然后通过适当手段例如通过高压空气减细该长丝并放下在移动筛、鼓或其它适合的设备上。″熔纺″方法包括,但不限于,纺粘、溶液纺丝、共成型和熔喷。熔纺纤维通常具有小于250μm的平均直径。用于制备熔纺纤维的适合的聚合物的非限制性实例是聚丙烯(例如,均聚物、共聚物、抗冲共聚物)、聚酯(例如,PET)、聚酰胺、聚氨酯(例如,LycraTM)、聚乙烯(例如,LDPE、LLDPE、HDPE、塑性体)、聚碳酸酯和它们的共混物。
本文所使用的″纺粘″是指形成织物的熔纺方法,其中经过喷丝头挤出聚合物熔体或溶液以形成长丝,将该长丝通过合适的手段例如通过静电荷或高速空气减细,然后将这些减细的长丝(在这一阶段变成″纤维″)放下在移动筛上以形成织物。放下的纤维任选地可以穿过加热的压延机或其它一些适合的装置以将纤维压实成内聚性结构。在某些实施方案中,纺粘方法中减细用空气小于大约50℃。由纺粘方法产生的纤维通常具有其中赋予的某种单轴分子取向度。纺粘纤维往往具有,但是不一定具有大于大约7μm的平均直径。
本文所使用的″熔喷″是指形成织物的熔纺方法,其中经过喷丝头挤出聚合物熔体或溶液以形成长丝,通过合适的手段例如通过静电荷或高速空气减细该长丝,然后将这些减细的长丝(在这一阶段变成″纤维″)放下在移动筛上以形成织物。在某些实施方案中,可以有或可以没有独立的骤冷空气源。在某些实施方案中,熔喷方法中减细用空气大于大约50℃。熔喷纤维往往具有,但是不一定具有小于大约7μm的平均直径。
本文所使用的术语″共成型″是指另一种熔纺方法,其中靠近设备安排至少一个熔纺模头,经过该设备在形成织物的同时将其它材料添加到该织物中。此类其它材料可以是例如,纸浆、超吸收颗粒、纤维素或短纤维。共成型方法描述在U.S.4,818,464和U.S.4,100,324中,两篇文献引入供参考。对本公开内容来说,共成型方法认为是熔纺方法的一个特定的实施方案。
本文所使用的″纤维″是其长度远大于其直径或宽度的结构;平均直径的数量级为0.1-350μm,并包括天然和/或合成材料。纤维可以是″单组分″或″双组分″的。双组分纤维包含由单独的熔体/液体加料装置(例如,挤出机),但是经由相同喷丝头挤出的具有不同化学和/或物理性能的两种或更多种聚合物,其中这两种聚合物在相同长丝内,而导致纤维具有由每种不同聚合物构成的不同域。此种双组分纤维的构型可以是,例如,鞘/芯配置,其中一种聚合物被另一种聚合物包围或可以是并列式布置的,如U.S.5,108,820中那样,片段或″派″型的,其中聚合物的不同域呈″派切片″或″天星状(islands in the sea)″形状的交替片段,例如U.S.7,413,803中那样,在此引入供参考。纤维也可以是″单成分″或″双成分″的,这是指它们由单一聚合物或两种或更多种聚合物的共混物构成。
通过本文描述的方法制得的纤维可以称为″熔纺″、″纺粘″或″熔喷″纤维。熔纺纤维可以具有任何合乎需要的平均直径,在某些实施方案中,在0.1或1或4至15或20或40或50或150或250μm的范围内,或以另一种方式表示,小于5.0或3.0或2.0或1.9或1.8或1.6或1.4或1.2或1.0的旦尼尔(g/9000m)。
本文所使用的″原位层压体″(或″ISL″)是指包括至少两个织物层的结构,该织物层通过于2009年2月27日提交的U.S.S.N.61/156,078描述的原位熔纺方法制备,该文献引入供参考。″复合材料″是指包括至少一个ISL和至少一个其它材料层(或″可延伸层″)例如膜、另一个织物或由任何适合的材料制造的另一个ISL的结构。本文所使用的ISL和包括ISL的ISL复合材料在优选的实施方案中是双轴弹性的,因此是BEL的实施方案。ILS复合材料可以例如,如下制备:首先将熔纺织物层依次沉积到移动成型带上,然后在所述第一熔纺织物层的上面沉积另一个熔纺织物层或添加梳理或干法成网织物,然后在那些层的上面添加熔纺织物层,任选地接着是粘附各个层状材料的某种方法,例如通过热点粘结(thermal point bonding)或各层彼此的固有粘附倾向、应用粘合剂、使用声能、水力缠绕(hydroentangling)等。或者,可以单独地形成织物层,在辊中收集,并在单独的一个或多个粘结步骤中结合。ISL和ISL复合材料还可以具有呈许多不同构型的各种数量的层并且可以包括其它材料如膜、粘合剂、纺织材料、吸收材料(例如,纸浆(pulp)、纸张、超吸收颗粒等)和例如,U.S.6,503,853(引入供参考)中公开的其它材料、共成型材料、熔喷和纺粘材料或气流成网材料等。
本文所使用的称为是″弹性″或″弹性体″的材料(例如,纤维、织物、层压体)是在施加拉伸力后可以沿至少一个方向(例如,CD、MD或介于在它们之间)拉伸,但是在释放该拉伸力后恢复到大致其原始尺寸的那些。例如,拉伸的材料可以具有比其松弛的未拉伸长度大至少50%或80%的拉伸长度,并在释放拉伸力后将收缩/恢复到其拉伸长度的至少50%内。术语″可延伸″是指沿施加力方向拉伸或延伸其松弛长度或宽度的至少50%的材料。可延伸织物通常伴随常用制品(例如,尿布等)的弹性体织物或膜层并由可延伸材料(例如,聚氨酯、苯乙烯类嵌段共聚物、乙烯-乙酸乙烯酯、某些聚丙烯共聚物、聚乙烯和它们的共混物)形成,或通过织物(天然或合成织物)的机械扭曲或扭转形成。
本文所使用的″膜″是聚合物(例如,热塑性材料和/或弹性体)材料的平的未经担载的部分,其厚度相对于其宽度和长度非常小并在其整个结构中具有连续或几乎连续的宏观形态,而允许空气按扩散受限的速率或更低速率通过。然而,这种定义不意味着排除以本领域中已知的任何手段(例如,通过在膜中包括在活化(例如,应用热等)时产生孔隙度的添加剂)制得的所谓的″微孔″膜。此类添加剂包括粘土、碳酸钙和在本领域中熟知的并尤其描述在U.S.6,632,212中的其它添加剂,该文献在此引入供参考。本文描述的BEL可以包括一个或多个膜层并且可以包含本文对于织物描述的任何材料。在某些实施方案中,膜不存在于本文描述的BEL中。
弹性体
BEL和受约束BEL包括至少一个熔纺弹性织物层。熔纺弹性层可以通过任何适合的技术形成,但是优选使用本文描述的熔纺方法形成。用来形成弹性织物的弹性体可以包括能够熔体挤出和熔纺的任何适合的弹性体。在一个实施方案中,弹性织物包含选自以下的弹性体:丙烯-α-烯烃弹性体、乙烯-α-烯烃无规和嵌段共聚物(例如,InfuseTM弹性体)、天然橡胶(″NR″)、合成聚异戊二烯(″IR″)、丁基橡胶(异丁烯和异戊二烯的共聚物,″IIR″)、卤化丁基橡胶(氯化丁基橡胶:″CIIR″;溴化丁基橡胶:″BIIR″)、聚丁二烯(″BR″)、苯乙烯-丁二烯橡胶(″SBR″)、丁腈橡胶、氢化丁腈橡胶、氯丁二烯橡胶(″CR″)、聚氯丁二烯、氯丁橡胶、乙烯-丙烯橡胶(″EPM″)、乙烯-丙烯-二烯橡胶(″EPDM″)、表氯醇橡胶(″ECO″)、聚丙烯酸酯类橡胶(polyacrylic rubber)(例如,″ACM″、″ABR″)、硅氧烷橡胶、氟硅氧烷橡胶、含氟弹性体、全氟弹性体、聚醚嵌段酰胺(″PEBA″)、氯磺化聚乙烯(″CSM″)、乙烯-乙酸乙烯酯(″EVA″)、热塑性弹性体(″TPE″)、热塑性硫化橡胶(″TPV″)、热塑性聚氨酯(″TPU″)、热塑性聚烯烃(″TPO″)(无规和嵌段)、聚硫橡胶或这些弹性体中任何两种或更多种的共混物。这些材料(单独地或共混的)可以按将促进熔纺成非织造织物的任何分子量。弹性织物可以包含10或20或30或40至50或70或80或90或95或100%的一种或多种弹性体,按织物的重量计,并在某些实施方案中可以基本上由一种或多种弹性体组成和在另一个实施方案中基本上由一种弹性体组成。弹性层的其余部分可以包含任何热塑性材料、木材或粘胶(viscos)材料或本领域中已知的其它吸收性材料。
在一个优选的实施方案中,弹性层包含10或20或30或40至50或70或80或90或95或100%的基于聚烯烃的弹性体,按织物的重量计。″基于聚烯烃的″是指聚合物弹性体由至少50wt%烯烃衍生的单元构成,其实例包括乙烯和C3-C16α-烯烃,和它们的组合。优选的基于聚烯烃的弹性体是包含至少50wt%乙烯或丙烯或丁烯衍生的单元的那些。在一个特定的实施方案中,弹性层包含基于聚烯烃的弹性体,在一个特定的实施方案中,具有小于80或60或40或24或20dg/min的MFR的丙烯-α-烯烃弹性体。在一个特定的实施方案中,弹性层基本上由丙烯-α-烯烃弹性体组成。
本文所使用的″丙烯-α-烯烃弹性体″是指弹性体的、具有适中结晶度并具有丙烯衍生的单元和一种或多种衍生自乙烯、更高级α-烯烃的单元和/或任选的二烯衍生的单元的无规共聚物。该共聚物的总共聚单体含量在一个实施方案中是5-35wt%。在一些实施方案中,当存在多于一种共聚单体时,特定的共聚单体的量可以小于5wt%,但是总共聚单体含量大于5wt%。所述丙烯-α-烯烃弹性体可以通过许多不同参数描述,并且那些参数可以包括由本文描述的任何合乎需要的上限与任何合乎需要的下限构成的数值范围。
基于聚烯烃的弹性体和丙烯-α-烯烃弹性体可以是无规共聚物(共聚单体衍生的单元沿着聚合物主链无规地分布)或嵌段共聚物(共聚单体衍生的单元沿着长序列存在)或它们的任何变型(具有每种的某些性能)。无规性或″嵌段性″在共聚物中的存在可以通过本领域中已知的13CNMR测定并描述在例如,18J.POLY.SCI.,POLY.LETT.ED.389-394(1980)中。
在某些实施方案中,丙烯-α-烯烃弹性体包含在5或7或9至13或16或18wt%范围内的乙烯或C4-C10α-烯烃衍生的单元(或″共聚单体衍生的单元″),按该弹性体的重量计。所述丙烯-α-烯烃弹性体还可以包含两种不同共聚单体衍生的单元。此外,这些共聚物和三元共聚物可以包含如下所述的二烯衍生的单元。在一个特定的实施方案中,丙烯-α-烯烃弹性体包含丙烯衍生的单元和选自乙烯、1-己烯和1-辛烯的共聚单体单元。并且在一个更特定的实施方案中,共聚单体是乙烯,并因此所述丙烯-α-烯烃弹性体是丙烯-乙烯共聚物。当存在二烯时,所述丙烯-α-烯烃弹性体包含小于5或3wt%二烯衍生的单元,或在其它实施方案中包含0.1或0.5或1至5wt%,按该弹性体的重量计。适合的二烯包括例如:1,4-己二烯、1,6-辛二烯、5-甲基-1,4-己二烯、3,7-二甲基-1,6-辛二烯、双环戊二烯(″DCPD″)、乙叉基降冰片烯(″ENB″)、降冰片二烯、5-乙烯基-2-降冰片烯(″VNB″)和它们的组合。
在某些实施方案中,丙烯-α-烯烃弹性体具有75%或更大,80%或更大,82%或更大,85%或更大或90%或更大的通过13C NMR测量的三个丙烯单元的三单元组立构规整度。在一个实施方案中,三单元组立构规整度在50-99%的范围内,在另一个实施方案中,在60-99%的范围内,在又一个实施方案中,在75-99%的范围内,在又一个实施方案中,在80-99%的范围内,在又一个实施方案中,在60-97%的范围内。三单元组立构规整度是如下测定的:通过13C核磁共振(″NMR″)技术测定本文表示为″m/r″的立构规整度指数。立构规整度指数m/r由H.N.Cheng在17MACROMOLECULES 1950(1984)中限定的那样计算,引入本文供参考。符号″m″或″r″描述邻接丙烯基团对的立体化学,″m″是指内消旋,″r″是指外消旋。1.0的m/r比值一般描述间同立构聚合物,2.0的m/r比值描述无规立构材料。全同立构材料理论上可以具有接近无穷大的比值,并且许多副产物无规立构聚合物具有足够的全同立构含量以导致大于50的比值。丙烯-α-烯烃弹性体的实施方案具有从4或6的下限到8或10或12的上限的立构规整度指数m/r。
在某些实施方案中,丙烯-α-烯烃弹性体具有在0.5或1或5J/g至35或40或50或65或75或80J/g范围内的根据本文描述的差示扫描量热法(″DSC″)程序测定的熔融热(″Hf″)。在某些实施方案中,Hf值小于80或75或60或50或40J/g。在某些实施方案中,丙烯-α-烯烃弹性体具有0.5-40%,在另一个实施方案中,1-30%,在又一个实施方案中,5-25%的百分率结晶度,其中″百分率结晶度″是根据本文描述的DSC程序测定的。聚丙烯的最高阶热能估算为189J/g(即,100%结晶度等于189J/g)。在另一个实施方案中,丙烯-α-烯烃弹性体具有小于40%,在另一个实施方案中,0.25-25%,在又一个实施方案中,0.5-22%,在又一个实施方案中,0.5-20%的结晶度。
在某些实施方案中,丙烯-α-烯烃弹性体具有通过DSC测定的单一峰熔融转变;在某些实施方案中,丙烯-α-烯烃弹性体具有小于90℃的主峰熔融转变,与大于大约110℃的宽的熔融结束转变。峰″熔点″(″Tm″)定义为在样品熔融范围内最大吸热的温度。然而,丙烯-α-烯烃弹性体可以显示与主峰相邻的副熔融峰,和/或熔融结束转变,但是对于本文目的,此种副熔融峰一起看作单一熔点,其中这些峰的最高峰认为是丙烯-α-烯烃弹性体的Tm。丙烯-α-烯烃弹性体在某些实施方案中具有小于105或100或90或80或70℃的峰Tm;在其它实施方案中具有10或15或20或25至65或75或80或95或105℃的峰Tm
DSC测定的程序如下。称出大约0.5克聚合物并在大约140℃-150℃下,使用″DSC模具″和MylarTM衬板压制到大约15-20密耳(大约381-508微米)的厚度。通过悬挂在空气中(没有除去MylarTM衬板)允许该压制垫片冷却到环境温度。在室温下(大约23-25℃)退火该压制垫片大约8天。在此阶段结束时,使用冲模从该压制垫片取出大约15-20mg圆片并放入10微升铝样品盘中。将该样品放入差示扫描量热计(Perkin ElmerPyris 1 Thermal Analysis System)中并冷却到大约-100℃。以大约10℃/min加热样品以达到大约165℃的最终温度。热输出(记录为样品熔融峰下的面积)是熔融热的量度并且可以用焦耳/克(J/g)聚合物表示并且通过Perkin Elmer System自动地计算。在这些条件下,熔融曲线显示两个最大值,在最高温度处的最大值取作在样品的熔融范围内的熔点,相对于聚合物的随温度变化的增加性热容量的基线测量值。
在某些实施方案中,丙烯-α-烯烃弹性体具有0.840-0.920g/cm3,在另一个实施方案中,0.845-0.900g/cm3,在又一个实施方案中,0.850-0.890g/cm3的密度,该值是在室温下根据ASTM D-1505试验方法测得的。
在某些实施方案中,丙烯-α-烯烃弹性体具有小于80或70或50或40或30或24或20dg/min,在其它实施方案在0.1或1或4或6至12或16或20或40或60或80dg/min范围内的熔体流动速率(″MFR″,ASTM D1238,2.16kg,230℃)。
在某些实施方案中,丙烯-α-烯烃弹性体具有在20或40至80或90肖尔A的范围内的肖尔A硬度(ASTM D2240)。在又一个实施方案中,丙烯-α-烯烃弹性体具有大于500%或1000%或2000%;在其它实施方案中,在500%至800或1200或1800或2000或3000%范围内的极限伸长率(ASTM D 412)。
在某些实施方案中,丙烯-α-烯烃弹性体具有在50,000至1,000,000g/mol,在另一个实施方案中,60,000至600,000,在又一个实施方案中,70,000至400,000范围内的重均分子量(″Mw″)值。丙烯-α-烯烃弹性体具有在某些实施方案中,在10,000至500,000g/mol范围内,在又一个实施方案中,在20,000至300,000范围内,在又一个实施方案中,在30,000至200,000范围内的数均分子量(″Mn″)值。所述丙烯-α-烯烃弹性体具有在某些实施方案中,在80,000至3,000,000g/mol范围内,在另一个实施方案中,在100,000至700,000范围内,在又一个实施方案中,在120,000至500,000范围内的z-均分子量(″Mz″)。
在某些实施方案中,通过将丙烯-α-烯烃弹性体减粘裂化达到合乎需要的分子量(因此,合乎需要的MFR)。″减粘裂化丙烯-α-烯烃弹性体″(本领域中还称为受控流变性)是已经用减粘裂化试剂处理以致该试剂使聚合物链分裂的共聚物。减粘裂化试剂的非限制性实例包括过氧化物、羟基胺酯及其它氧化和自由基产生剂。换言之,减粘裂化弹性体可以是减粘裂化试剂和弹性体的反应产物。具体来说,减粘裂化丙烯-α-烯烃弹性体是已经用减粘裂化试剂处理以致其MFR相对于处理之前的MFR值增加,在一个实施方案中,增加至少10%,在另一个实施方案中,增加至少20%的减粘裂化丙烯-α-烯烃弹性体。在某些实施方案中,纤维和织物的制备方法从挤出机及其它设备部件排除任何减粘裂化试剂。丙烯-α-烯烃弹性体在这种情况下称作″反应器等级″弹性体。所谓的″排除″或″排除的″是指减粘裂化试剂例如过氧化物、羟基胺酯、氧气(或空气)及其它氧化和自由基产生剂不有意地添加到挤出机或挤出机下游的成纤设备的任何其它组件中。因此,在这个实施方案中,被吹塑成纤维和织物的弹性体是当引入向成纤设备进料的挤出机中时具有所需MFR的弹性体。
在某些实施方案中,丙烯-α-烯烃弹性体的分子量分布(″MWD″)在1.5或1.8或2.0至3.0或3.5或4.0或5.0的范围内。测定分子量(Mn、Mz和Mw)和MWD的技术如下,并且如Verstate等人在21MACROMOLECULES3360(1988)中所述那样,引入本文供参考。本文描述的条件支配公开的试验条件。在配有Chromatix KMX-6在线光散射光度计的Waters 150凝胶渗透色谱仪上测量分子量和MWD。在135℃、采用1,2,4-三氯苯作为移动相的情况下,利用该系统。使用ShowdexTM(Showa DenkoAmerica,Inc.)聚苯乙烯凝胶柱802、803、804和805。在LiquidChromatography of Polymers and Related Materials III 207(J.Cazes编辑,Marcel Dekker,1981)中讨论了这一技术,将其引入作为参考。对于柱子的铺展来说,采用没有校正的情况;然而,根据通常接受的标准,例如由National Bureau of Standards,Polyethylene(SRM 1484)得到的数据,和阴离子生产的氢化聚异戊二烯(乙烯-丙烯的交替共聚物)证明,对Mw/Mn或Mz/Mw的这种校正小于0.05个单位。根据洗脱时间-分子量关系计算Mw/Mn,然而使用光散射光度计评价Mz/Mw。使用可商购的计算机软件GPC2(可以从LDC/Milton Roy-Riviera Beach,Fla获得的MOLWT2)进行数值分析。
本文描述的丙烯-α-烯烃弹性体可以使用已知用于制备聚丙烯的任何催化剂和/或方法制备。在某些实施方案中,丙烯-α-烯烃弹性体可以包括根据WO 02/36651、U.S.6992158和/或WO 00/01745中的程序制备的共聚物,这些文献都引入供参考。丙烯-α-烯烃弹性体的优选的制备方法参见U.S.2004/0236042和U.S.6,881,800,它们都在此引入作为参考。优选的丙烯-α-烯烃弹性体是可以商品名VistamaxxTM(ExxonMobil Chemical Company,Houston,TX,USA)和Vers ifyTM(TheDow Chemical Company,Midland,Michigan,USA),某些等级的TafmerTMXM或NotioTM(Mitsui Company,Japan)和某些等级的SoftelTM(BasellPolyolefins of the Netherlands)商购的。
虽然纤维和织物组合物的″丙烯-α-烯烃弹性体″组分有时论述为单一聚合物,但是该术语还考虑具有在本文所述范围内的性能的两种或更多种不同丙烯-α-烯烃弹性体的共混物。
BEL的熔纺方法和构造
BEL可以通过引入弹性熔纺织物的任何适合的技术制备。在某些实施方案中,通过熔纺方法,优选熔喷方法形成弹性织物。织物和/或膜的可延伸层可以通过任何适合的技术与弹性织物连接,例如通过在线层压或粘附预形成的织物,或同时或接近同时地熔纺副(secondary)层或面层以致它与弹性织物粘附,或通过前述原位层压(″ISL″)方法。如果通过ISL技术形成,则每个织物和/或膜层当然必须是可熔纺的。然而,甚至在此类层状结构中,复合材料可以由此类ISL和副层构成,该副层可以不是熔纺的例如射流喷网法织物和/或其它纺织织物。
熔纺弹性织物的形成要求通过经由熔纺设备挤出制造纤维,该熔纺设备包括至少一个模头,所述模头能够处理合适的熔体温度和压力以纺丝细纤度(fine denier)纤维。具体来说,所述设备具有至少一个包括多个喷嘴的模头,每一喷管与其自己的挤出机流体连接以允许经过该喷嘴熔纺不同材料。纺丝喷嘴界定窄的孔口,经过该孔口将熔融聚合物熔纺成长丝。每个模头可以具有任意数目的喷嘴。在某些实施方案中,喷嘴密度范围为20或40或50个喷嘴/英寸至120或150或200或300或350个喷嘴/英寸。挤出过程通常伴有纤维的机械或空气动力拉伸。本文描述的BEL可以通过本领域中已知能够熔纺可挤出聚合物的任何技术制造。在一个实施方案中,熔纺BEL是从能够在大于200psi(1.38MPa)或500psi(3.45MPa)或更高的熔体压力和50-350℃的熔体温度下操作的设备熔纺的。
在某些实施方案中,BEL和织物的制备方法从熔喷挤出机及其它设备部件排除任何减粘裂化试剂。所谓的″排除″或″排除的″是指减粘裂化试剂例如过氧化物、羟基胺酯及其它氧化和自由基产生剂不添加到挤出机或挤出机下游的在熔喷设备中的所述设备的任何其它组件中。因此,被纺丝成纤维和织物的弹性体或其它材料是当引入向熔喷设备进料的挤出机中时具有所需MFR的材料。
可以用于至少制备本文描述的弹性织物(和构成织物的纤维)及其它可延伸织物层的适合的熔纺设备的实例公开在U.S.4,380,570、U.S.5,476,616、U.S.2004/0209540中和由R.Zhao在″Melt BlowingPolyoxymethylene Copolymer″in INT′L NONWOVENS J.,19-24中(2005年夏)中,它们中每一篇引入供参考。在一个特定的实施方案中,使用能够熔喷的设备。合乎需要的设备将通常包括至少一个挤出机,并可以包括齿轮泵以维持设备内的熔体压力。挤出机与至少一个模块,或阵列模头(array die)连接,以致熔体可以从挤出机转移至模块。在目前的情况下,设备具有至少一个具有多个喷嘴的模头,每个喷管与其自己的挤出机流体连接以允许不同材料经过该喷嘴熔纺和/或允许以不同通量(throughput)将熔体纺丝。在另一种排列中,可以有多于一个阵列模头,每个模头与挤出机连接和/或能够以不同通量将熔体纺丝。阵列模头包括喷丝头部分并且还与至少一个用于将高压空气输送到模头的喷丝头部分的空气歧管连接。喷丝头包括多个纺丝喷嘴,经过该喷嘴挤出熔体并同时用空气压力减细以形成长丝,或纤维。
在此形成BEL的一个或多个层的熔纺纤维如下形成:经过多个细小、通常圆形的模头毛细管或″纺丝喷嘴″将熔融共聚物作为熔融线或长丝挤出到汇聚或平行(通常热且高速)的气流(一个或多个)(例如空气或氮气)中以减细熔融热塑性材料的长丝并形成纤维。在熔纺过程中,通常通过牵引空气将熔融长丝的直径降低至所需尺寸。此后,通过高速气流载运熔喷纤维并沉积在收集表面上以形成具有随机分配的熔喷纤维的至少一个网幅。熔纺纤维可以是连续或不连续的并且平均直径一般在0.5-350μm的范围内。
更具体地说,在可用于形成弹性熔喷织物的熔纺方法中,将熔融聚合物提供给分布在一对空气板之间的至少一个阵列模头,该空气板形成一个或多个主喷气嘴(air nozzle),一个空气板是顶板。在一个实施方案中,熔喷设备包括具有多个喷丝头喷嘴(或″喷嘴″)的阵列模头,喷嘴密度在20或30或40至200或250或320个喷嘴/英寸的范围内。在一个实施方案中,每个喷嘴具有0.05或0.10或0.20至0.80或1.00或2.00mm范围内的内直径。在一个实施方案中,空气板以凹入式构型安装以致纺丝喷嘴的尖端从主喷气嘴凹回。在另一个实施方案中空气板以齐平构型安装,其中空气板端部与纺丝喷嘴尖端在同一水平面。在还有的其它实施方案中,纺丝喷嘴尖端呈突出或″伸出(stick-out)″构型以致纺丝喷嘴尖端延伸过空气板的端部。此外,可以提供多于一个空气流以便用于纺丝喷嘴。
在一个实施方案中,热空气(″主空气″)经由主喷气嘴提供,该主喷气嘴至少位于模头尖端的每一侧上或围绕着其圆周或围绕着每个喷嘴。热空气加热模头并因此防止当熔融聚合物离开并冷却时模头变得被凝固性聚合物堵塞。热空气还将熔体拉伸或使之变细成纤维。主空气可以平行于正成型的熔融长丝流动,或按至多垂直于正成型的长丝的任何角度流动,优选地,主空气流动在平行(0度)至大约30或40度的角度范围内。在某些实施方案中,熔喷方法中的主空气压力在模头中的恰恰要离开时的位置处通常为2或5至10或15或20或30磅/平方英寸表压(″psig″)。主空气温度在某些实施方案中通常在200或230至300或320或350℃的范围内,并在其它实施方案中用在大于50或80或100或150℃的温度下的空气减细。主空气流量通常为5或10或20至24或30或40标准立方英尺/分钟/英寸模头宽度(″SCFM/英寸″)。
用于制备本文描述的熔纺ISL的聚合物的熔体温度大于形成聚合物(和任何其它添加剂)的熔体时的温度且小于聚合物(和任何其它添加剂)的分解温度,在某些实施方案中,在50或100或150℃至250或280或350℃的范围内。在还有的其它实施方案中,熔体温度是小于150或200或220或230或250或260或270或280℃。在大于200psi(1.38MPa)或500psi(3.45MPa)或750ps i(5.17MPa)或1000psi(6.89MPa)的熔体压力下,或在其它实施方案中在200psi(1.38MPa)或500psi(3.45MPa)或750psi(5.17MPa)至1000psi(6.89MPa)或2000psi(13.78MPa)的范围内的熔体压力下将聚合物形成纤维。因此,熔纺设备必须能够产生和承受此种压力以将例如,低MFR(小于80dg/min)丙烯-α-烯烃弹性体纺丝成熔纺织物和包含至少一种本文所述弹性织物的BEL或ISL。
按照熔融聚合物流动量/英寸模头/单位时间表示,使用本文描述的组合物制造弹性熔喷织物的通量通常在0.1或0.2或0.3至0.5或1.0或1.25或2或3或5克/孔/分钟(ghm)的范围内。因此,对于具有30个喷嘴/英寸的模头,聚合物通量通常是大约0.4至1.2或3.2或4或5lb/英寸/小时(″PIH″)。
因为可以使用此种高温,所以为了使离开纺丝喷嘴的长丝骤冷或凝固,令人希望地从纤维除去大量热。空气或氮气的冷气体可以用于加速熔纺长丝冷却和凝固成纤维。具体来说,沿相对于纤维伸长方向的交叉流动方向(垂直或成一定角度)的冷却(″辅助″)空气流可用来将熔纺长丝骤冷并用来控制由其形成的纤维的直径。此外,附加的、冷却器加压的骤冷空气可以使用并可以导致纤维的更快冷却和凝固。在某些实施方案中,除了主空气之外,或者代替主空气,辅助冷空气流也可用来减细长丝。在0或10℃至20或25或30或40℃的温度下的辅助空气也可以经由模头(一个或多个)提供或在熔纺设备内其它合乎需要的位置提供。或者,水骤冷也可以施用于刚离开纺丝喷嘴的纤维上。
经由控制空气与阵列模头温度、空气压力和聚合物进料速率,可以调节在熔纺工艺期间形成的纤维的直径。构成熔纺弹性织物的最终纤维可以具有在0.1或1或4至15或20或40或50或150或250μm的范围内的平均直径,或在还有的其它实施方案中可以具有小于40或20或15μm的平均直径;或以另一种方式表示,小于5.0或3.0或2.0或1.9或1.8或1.6或1.4或1.2或1.0的旦尼尔(g/9000m)。
在冷却之后或在冷却期间,收集熔纺纤维以形成层状结构或BEL。具体来说,在本领域中已知的任何合乎需要的设备例如位于喷嘴下面或横跨喷嘴的移动筛网、移动带或收集(光滑或图案化/压花)鼓(一个或多个)上收集纤维。为了在纺丝喷嘴下方提供足够空间用于成纤、减细和冷却,在聚合物喷嘴尖端和筛网或收集鼓顶部之间希望形成3英寸至2英尺或更多的距离。在某些实施方案中,各层的纤维不通过二次方法彼此结合。
在任何情况下,熔纺弹性体织物层一旦形成就与一个或多个可延伸层组合和/或结合以形成BEL,该可延伸层包含其它织物、网、共成型织物、纱布(scrim)和/或膜,任何它们由天然材料、合成材料或其共混物制备。在某些实施方案中,该材料可以是可延伸的、弹性或塑性的。可以通过本领域中已知的任何手段将可延伸层与BEL结合,例如通过已知的织物-织物或织物-膜层压技术,在热、空气压力或水压下接触以使织物(或膜)层与熔纺弹性织物的至少一个面缠绕和/或接合。在某些实施方案中,当熔纺弹性织物层以合乎需要的速率移动时,直接地将该熔纺弹性织物层铺放在另一个可延伸和/或弹性织物上。一种这样的方法描述在2008年9月30日提交的美国序列号61/101,341中,引入供参考。制备,缠绕和层压织物的其它方法由Roger Chapman以″NonwovenFabrics,Staple Fibers″和Bruce Barton以″Coated Fabrics″进行了描述,这两篇文献都在KIRK-OTHMER ENCYCLOPEDIA OF CHEMICALTECHNOLOGY(分别John Wiley&Sons 2005和1993)中,引入供参考。
可以用于制备一个或多个可延伸层的材料的非限制性实例是聚丙烯(例如,均聚物、抗冲共聚物、无规或嵌段共聚物)、聚乙烯(例如,LDPE、LLDPE、HDPE)、塑性体(乙烯-α-烯烃无规和嵌段共聚物)、聚氨酯、聚酯例如聚对苯二甲酸乙二醇酯、聚乳酸、聚氯乙烯、聚四氟乙烯、苯乙烯类嵌段共聚物、乙烯-乙酸乙烯酯共聚物、聚酰胺、聚碳酸酯、纤维素材料(例如,棉、RayonTM、LyocellTM、TencilTM)、木材、粘胶、弹性体和这些材料中任何两种或更多种的共混物。更广泛列表描述如下。在任何情况下,与一个或多个弹性层相邻的层中的至少一个必须是织物,以致当熔合到弹性层上时,降低熔合″区″的弹性。或者,如果唯一的相邻层(一个或多个)是膜,则它必须由热塑性材料制成,该热塑性材料当熔合到本文所述弹性层上时降低熔合″区″的弹性。
可延伸层(一个或多个)(有时称为″面″层)可以呈膜、织物或这两种形式。膜可以是流延、吹塑膜,或通过任何其它合适的方法制得。当可延伸层是织物时,该可延伸层可以是熔纺织物、梳理织物、干法成网或湿法成网织物,它们中任何可以是射流喷网法的。干法成网方法包括机械手段,例如如何制备梳理织物,和空气动力学手段,例如气流成网方法。干法成网非织造物可以是用短纤维加工机械例如梳理机和回丝机制成的,所述加工机械设计用来操作干燥状态下的短纤维。还包括在这种类别中的是由呈丝束形式的纤维制造的非织造物和由短纤维和缝合长丝或纱线构成的织物,即缝合的非织造物。通过湿法成网方法制得的织物用与纸浆纤维化例如锤磨机和纸成型相联系的机械设备制成。网幅粘结方法可以描述为化学方法或物理方法。在任何情况下,干法和湿法成网织物可以射流和/或水力缠绕而形成射流喷网法织物,如本领域中已知的那样。化学粘结是指使用水基和溶剂基聚合物将纤维网幅粘结在一起。这些粘结剂可以通过浸透(浸渍)、喷雾、印刷或作为泡沫施加来施加。物理粘结方法包括热力学方法例如压延和热空气粘结,和机械法例如针刺和水力缠绕。熔纺非织造物由一种连续方法制造:通过熔体挤出纺丝纤维,然后通过偏转器直接分散到网幅中或可以用空气流引导。
″梳理″可以包括解缠结、清洁和掺合纤维以制备用于进一步加工成非织造织物的网幅并且是本领域中熟知的。当使用这些方法制备时,织物称作″梳理″织物。目的是取得大量纤维簇绒(tuft)并制备均匀、清洁网幅。梳理方法的实例描述在U.S.4,105,381中,引入本文供参考。该方法主要排列通过机械缠结和纤维-纤维摩擦维持在一起作为网幅的纤维。主要类型梳理是辊梳理。梳理作用是纤维在一系列互相配合的梳理辊上在锯齿线的点之间的梳理或工作。移除短纤维和不相干体,打开纤维簇绒,并近乎平行排列纤维。当表面之一按大于其它表面的速度移动时,发生纤维的梳理或平行化。当所述点沿相同方向排列并且更迅速移动的表面从更缓慢移动的表面移除或转移时,纤维被移除或″剥除″。
设计用来制备非织造网幅的高速梳理机可以配备有一个或多个主机筒、辊或固定顶端、一个或两个落纱机或这些主要部件的不同组合。单机筒梳理机通常用于要求纵向或平行纤维取向的产品。双机筒梳理机(或″串连″梳理机)基本上是通过剥除机(scripper)的部分和进料辊连接在一起的两个单机筒梳理机以从第一工作区输送和进料网幅到第二工作区。两个梳理单元一前一后地连接分布工作区并允许按与较慢单机筒机器相当的网幅质量水平达到更大纤维通量。辊-顶梳理机(roller-top card)可以具有五至七组劳动者和剥除机以混合和梳理机筒上携带的纤维。新成组纤维到梳理区的多次转移行为和再引入提供提高网幅均匀性的加倍作用。固定顶端梳理机(stationary-top card)具有安装在板上的金属布,该板围绕着机筒的上边缘凹入地布置。如此建立的额外的梳理表面提供扩展的纤维排列而具有最小纤维提取。
在某些实施方案中,BEL可以包括一个或多个共成型织物层。形成此种织物的方法描述在例如,U.S.4,818,464和U.S.5,720,832中,两者都引入本文供参考。一般而言,可以形成两种或更多种不同热塑性和/或弹性体材料的织物。例如,本文描述的共成型织物可以包含1或5或10或20或40或50至60或70或80或90或99wt%的热塑性材料如聚丙烯或弹性体例如丙烯-α-烯烃和99或90或80或70或60至50或40或20或10或5或1wt%的其它热塑性材料例如其它聚丙烯、聚乙烯、聚氨酯等,或弹性体例如丙烯-α-烯烃弹性体或苯乙烯类嵌段共聚物。因此,在一个方面中,提供熔融挤出的主要材料(例如,聚丙烯或弹性体)和任选地,一种或多种其它材料(弹性体、吸附、热塑性材料等)引入到惰性气体的至少一个迅速移动料流或射流的剪切层上,所述惰性气体来自围绕高速气体输送喷嘴布置或在所述高速气体输送喷嘴的交替侧或相对侧上布置的两个或更多个挤出开口或开口组。从这些开口挤出的材料可以是相同材料或,也可以是化学和/或物理性能方面彼此不同的材料。命名为第一、第二等热塑性、吸收或弹性体材料,所述材料可以具有相同或不同的化学组成或分子结构并且,当具有相同分子结构时,可以在分子量或导致物理性能差异的其它特性方面不同。在其中使用在某些方面,例如物理性能方面彼此不同的热塑性材料的那些情况下,挤出头或模头将配备有多个室,一个室用于所述热塑性材料中的每一种,例如第一、第二等热塑性材料。即,模头配备有用于第一热塑性材料的第一室和用于第二热塑性材料的第二室等。相对照而言,此种配置,其中单一室配备有为所述单一室和第一和第二热塑性材料挤出出口开口中的每一个之间提供连通的导管或通道,当第一室和第二室分别用于第一和第二热塑性材料时,每个室配备有到仅一个挤出出口开口或开口组的通道。因此,第一热塑性材料室利用第一热塑性材料通道与第一挤出出口开口连通,而第二热塑性材料室经由第二热塑性材料和/或弹性体材料通道与第二热塑性材料挤出开口连通。
构成本文描述的BEL或受约束BEL的两个或更多个各种织物和/或膜层可以仅仅彼此相邻而没有结合,或一个或多个层可以按某种方式结合在一起。本文所使用的″结合″(或″粘结″或″粘附″)是指两个或更多个织物,或多个纤维经由以下彼此固定:1)熔融或非熔融材料能够经由化学相互作用粘附的固有倾向和/或2)熔融或非熔融纤维和/或织物与包含其它材料的纤维缠绕以在织物之间产生连接的能力,其中任何弹性织物层的弹性相对于织物的初始弹性降低至多20%。BEL或受约束BEL的相邻织物和/或膜层的这种粘结或粘附与形成非弹性区的受约束BEL的各层的″熔合″有区别。本文描述的BEL的层可以通过已知的方法彼此粘结,包括热粘结方法例如热压花、点粘结、压延和超声波粘结;机械缠绕方法例如针刺和水力缠结;使用粘合剂例如热熔粘合剂和氨基甲酸酯粘合剂;和挤出层压。粘合剂可用来促进织物和/或膜层的粘结,但是在一个特定的实施方案中,粘合剂不存在于本文描述的织物和/或膜层(不用来粘结织物的纤维)中;在另一个实施方案中,不存在于本文描述的BEL或受约束BEL(不用来粘结相邻的织物层)中。
BEL可以具有部分地由其整体性质限定的许多性能,或构成其中的织物的纤维的那些。在某些实施方案中,构成本文所述可延伸(或″面″)层的纤维具有大于4或6或8或10或12μm的平均直径,在其它实施方案中,具有小于80或50或40或30或20或10或5μm的平均直径。在又一个实施方案中,构成BEL的可延伸织物层的纤维具有5或6或8或10至20或50或80或100或150或200或250或350或1000μm的平均直径。在某些实施方案中,BEL或受约束BEL可以具有5或10或15或20g/m2至25或30或40或50或60或100g/m2的单位重量(basisweight)。
受约束BEL的任何层(不论织物或膜)可以包括一种或多种添加剂。添加剂可以按任何合乎需要的水平存在,其实例包括0.0005或0.01或0.1至3或4或5或10wt%,按纤维或织物或膜的重量计。本文所使用的″添加剂″包括,例如,稳定剂、表面活性剂、抗氧化剂、抗臭氧剂(例如硫脲)、填料、迁移(预防)剂、着色剂、成核剂、抗粘连剂、UV阻滞剂/吸收剂、烃树脂(例如,OpperaTM树脂、PicolyteTM增粘剂、聚异丁烯等)及其它增粘剂、油(例如,石蜡油、矿物油、芳族油、合成油)、滑动添加剂、亲水性添加剂(例如,IrgasurfTM560HL)、疏水性添加剂(例如,蜡)和它们的组合。主和副抗氧化剂包括,例如,位阻酚、位阻胺和磷酸酯。滑爽剂包括,例如,油酸酰胺和芥酸酰胺。填料的实例包括炭黑,粘土、滑石、碳酸钙、云母、二氧化硅、硅酸盐和它们的组合。其它添加剂包括分散剂和催化剂钝化剂例如硬脂酸钙、水滑石和氧化钙,和/或本领域中已知的其它酸中和剂。添加剂可以通过任何手段例如通过在熔纺之前干燥共混添加剂与纯聚合物材料的粒料,或通过获得已经具有添加剂(一个或多种)的织物材料而添加到构成受约束BEL的各个层的材料中。
约束方法和由其制得的受约束BEL
然后让通过任何适合的手段制备的BEL经由使该层状结构经历约束手段而经历熔合步骤以形成受约束BEL。在某些实施方案中,BEL的一个或多个,或全部层不彼此粘附,而是仅仅彼此邻接。在其它实施方案中,BEL的至少两个层,或全部层彼此粘附。″约束手段″是任何设备、物质或方法,它们能够使至少一个熔纺弹性织物的至少一部分熔合到可延伸织物中的至少一个上而产生至少一个非弹性区。″熔合″方法在BEL上产生不再″弹性″的区域,并且可以包括使一个相邻层熔合到弹性层(一个或多个)上,或基本上(至少90%)熔合所有层,直至熔合贯穿BEL的完全厚度(全部层)中的所有层。在某些实施方案中,使所述至少一个熔纺弹性织物的离散区熔合到可延伸织物中的至少一个上产生下述的区:所述区具有的弹性比熔纺弹性织物的初始弹性低至少40%或50%或60%或70%或80%或90%或98%。BEL的熔合产生受约束BEL。
本文描述了在双轴弹性非织造层压体中赋予约束的方法,包括提供包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的双轴弹性非织造层压体;和使所述至少一个熔纺弹性织物的至少一部分熔合到所述可延伸织物的至少一个上以产生至少一个非弹性区。熔合可以通过任何手段实现,例如通过将各层加热而在至少两个层之间形成粘附,或水力缠绕至少两个层,或超声波手段,电子手段,或用于使各层彼此粘附的其它适合的手段。粘合剂可以用于熔合,而是在某些实施方案中,粘合剂的施用不存在于熔合步骤中。粘合剂的实例包括包含低重均分子量(<80,000g/mol)聚烯烃、聚乙酸乙烯酯聚酰胺,烃树脂、天然沥青、苯乙烯类橡胶、聚异戊二烯和它们的共混物的那些粘合剂。
通过熔合步骤产生的″非弹性区″的″非弹性″是指其弹性小于上面对于″弹性″材料所限定的弹性。非弹性区可以呈现适合于所需最终用途的任何″离散″形状或形式,例如尿布或成人失禁衣服。例如,非弹性区可以呈长度是其宽度至少两或三倍的长线或块体的形式。在一些实施方案中,非弹性区界定不规则形状区域,或非线性形状例如圆圈、圆弧或包括此类特征的形状。
在一个特定实施方案中,所述熔合包括压延双轴弹性非织造层压体以使熔纺弹性织物的至少一部分熔融并产生一个或多个弹性织物与至少一个可延伸织物的熔合。在一个特定的实施方案中,所述熔合步骤是利用具有高热分区型式(raised heated zoning patterns)的压延机进行的。在某些实施方案中,所述熔合进一步将压花图案引入层压体中。所述熔合和压花步骤可以利用压延机进行,该压延机具有任选地加热的相互啮合的辊。此外,熔合和压花步骤可以利用在真空差异(a vacuumdifferential)下运转的图案化相互啮合的真空鼓进行,或利用其它适合的手段进行。
在某些实施方案中,进行所述熔合以致弹性的程度沿BEL的CD、BEL的MD或介于它们之间的某个角度和/或它们的组合维持。例如,熔合可以使得BEL仅沿CD方向,或与CD方向成45度,或与CD方向成20度,或在90度至20度或45度的范围内等是弹性的。此外,受约束BEL中的弹性可以使得CD和MD弹性都降低而不是完全除去。在一个特定实施方案中,所述经结合(bound)织物层的至少一个部分在离散区中熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。
在某些实施方案中,所述层压体具有CD宽度和与所述层压体的CD垂直的非弹性区,所述非弹性区具有为所述层压体CD宽度的至少2或5或10或20%的CD宽度。在还有的其它实施方案中,所述层压体具有CD宽度和与所述层压体的MD垂直的非弹性区,所述非弹性区具有为所述层压体的CD宽度的至少2或5或10或20%的MD宽度。
受约束的BEL可以呈现任何适合的形式。它可以具有多于一个弹性熔纺织物层,以及多个可延伸织物和/或膜层。一些层可以通过任何适合的手段例如熔纺、干法成网、梳理、纺织机织或湿法成网手段形成。在一个特定的实施方案中,至少一个弹性层是熔喷织物,在更特定的实施方案中,是包含丙烯-α-烯烃弹性体或基本上由丙烯-α-烯烃弹性体组成的熔喷织物。在一个特定的实施方案中,双轴弹性非织造层压体是上面涉及的ISL。在一个特定的实施方案中,ISL是通过下述方法形成的,该方法包括同时熔纺彼此邻接的两种或更多种聚合物熔体以形成相邻织物,其中彼此邻接的织物层彼此原位缠绕而在织物层之间形成混合纤维的界面区。
用于形成受约束织物的BEL或受约束BEL本身可以包括原位层压体,该原位层压体包括选自以下的结构:TE、TET、Tb1ET、Tb1ETb1、Tb1Eb1Tb1、T0 b1Eb1Tb1、TEC、CEC0、TCET、TTE、TEE、TE0EE0T、E0EE0、E0 b1EE0 b1、CECT、CETT、TTETT、TT0ET0T、TCECT、TE0ET、TEET、TEb1ET、TCE、T0ET、T0ETb1、T0CET、TEE0、Tb1Eb1C、T0 b1Eb1CT、TE0T、TEb1C、T0EC0T、Tb1E、Tb1Eb1、Tb1ET、Tb1EC、Tb1ET、TEb1、TECb1、TEb1T、TEb1C、TECb1T、TTE、TCCE、TTETT、TTECC、TTETT、Tb1TETTb1、TT0E、TT0C、T0ETT、TECC、T0 b1CETb1、TEE0、TCb1EC0、TEE0T、TEE0C、TT0ET0T、TTb1E、TTb1EC、Tb1CEb1T、Tb1ET、T0 b1ET、Tb1EEC、Tb1CET、TEb1、TET0Cb1、TEEb1C、TEb1CT0、TCb1ECb1、TC0ECT、TCb1ECT和它们的变型,其中″T″是包含第一热塑性材料的织物,″T0″是包含具有与″T″不同物理性能(一种或多种)的第一热塑性材料的织物,″C″是包含不同于第一热塑性材料的第二热塑性材料的织物,″C0″是包含具有与″C″不同物理性能(一种或多种)的第二热塑性材料的织物,″E″是包含弹性体的织物,″E0″是包含具有与″E″不同物理性能(一种或多种)的弹性体的织物,和下标″b1″是指包含热塑性材料、弹性体或两者的共混物的织物。上面涉及的″物理″性能是那些例如织物的单位重量、纤维密度、形成织物(一种或多种)的纤维直径、织物(一种或多种)的孔隙尺寸、其空气渗透性、其水压头(hydrohead)、耐磨性、柔软程度(″手感″)及其它此类性能。
BEL或受约束BEL的一个或多个弹性织物层可以由上述弹性体中任一种或多种,或弹性体和热塑性材料或用来制备至少一个可延伸层的其它材料的共混物制成。弹性织物层与至少一个可延伸层结合,更具体地说,两个层直接地与弹性层相邻并夹持弹性层。在某些实施方案中,受约束BEL的所有织物和/或膜层彼此熔合。在某些实施方案中,可延伸织物层(一个或多个)包含选自以下的材料:聚丙烯、聚乙烯、官能化聚烯烃、塑性体(密度通常小于0.90g/cm3的乙烯-α-烯烃无规共聚物)、聚氨酯、聚酯例如聚对苯二甲酸乙二醇酯、聚乳酸、聚氯乙烯、聚四氟乙烯、苯乙烯类嵌段共聚物、乙烯-乙酸乙烯酯共聚物、聚酰胺、聚碳酸酯、纤维素材料、弹性体(如上所述)、聚(乙炔)、聚(噻吩)、聚(苯胺)、聚(芴)、聚(吡咯)、聚(3-烷基噻吩)、聚(亚苯基硫醚)、聚萘、聚(亚苯基亚乙烯基)、聚(偏二氟乙烯)、乙烯-α-烯烃嵌段共聚物、木材、粘胶、棉,和这些材料中任何两种或更多种的共混物。如所提及的那样,弹性熔纺织物层可以包括任何热塑性材料或可以熔纺或以别的方式(例如通过共成型方法等)包括在熔纺弹性织物中的上述材料中的任一种。
在一个特定的实施方案中,BEL或受约束BEL包括两个或更多个面织物层和在它们之间的包含丙烯-α-烯烃弹性体的弹性织物,该面织物层包含任何两种或更多种类型的纤维的共混物,该纤维包括聚丙烯、聚对苯二甲酸乙二醇酯、粘胶、棉。在另一个特定的实施方案中,BEL或受约束BEL包括两个或更多个面织物层和在它们之间的包含丙烯-α-烯烃弹性体的弹性织物,该面织物层包含聚丙烯、聚对苯二甲酸乙二醇酯或这两者的共混物。
熔合步骤产生本文所述的″非弹性区″。在某些实施方案中,所述熔合沿着所述宽度和平行于所述双轴弹性非织造层压体的MD产生至少三个非弹性区从而在层压体中赋予CD弹性,其中所述非弹性区的两个沿着所述层压体的边缘延伸和一个非弹性区沿着所述层压体的中间向下延伸。在其它实施方案中,在网幅任一侧的较大区域经历熔合步骤而产生较大非弹性区域以充当用于吊钩连接的盲区和允许将该组件与吸收性衣服底板(例如,成人失禁衣服或婴儿尿布)粘结的部位。这些区更耐受蠕变和剪切并防止吊钩脱层和防止弹性组件拉离尿布底板。
上述制备的受约束BEL可以呈现包括至少一个熔纺弹性织物和至少一个可延伸织物的任何形式。在一个方面中本文证明的是包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的受约束双轴弹性非织造层压体,其中所述织物层的至少一个部分在离散区中彼此熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD或按介于它们之间的某种取向。受约束BEL的特定实施方案示于图1-3的图示中。
图1a是具有非弹性区04和弹性区06(都与MD平行)的受约束BEL或受约束BEL片段02的俯视图的图示。例如,这种构造将产生沿CD有弹性且沿MD无弹性的层状织物。图1b是具有非弹性区10和弹性区12(都与CD平行)的受约束BEL或受约束BEL片段08的俯视图的图示。例如,这种构造将产生沿MD有弹性且沿CD无弹性的层状织物。此种非弹性区可以呈任何其它形式,例如与CD或MD平行的部分线、与CD和/或MD成一定角度的非弹性区或任何其它合乎需要的形式。
在某些实施方案中,受约束BEL具有CD宽度和至少一个与所述层压体的CD垂直的非弹性区,所述非弹性区(一个或多个)具有在所述层压体的CD宽度的2或3或4或5至10或20或30%内,在另一个实施方案中,大于2或5或10%的CD宽度。同样,在某些实施方案中,受约束BEL具有CD宽度和至少一个与所述层压体的MD垂直的非弹性区,所述非弹性区(一个或多个)具有在所述层压体的CD宽度的2或3或4或5至10或20或30%内的,在另一个实施方案中,大于2或5或10%的MD宽度。可以仅有一个区,或两个或三个或四个或更多区。所述区可以彼此相同或不同,并且可以彼此平行或成一定角度。
例如,图2a所示的是具有平行于MD的非弹性区的断裂平行线16的受约束BEL 14(其余部分是弹性区域18(非粘结区))的俯视图的图示。这种结构可能沿MD方向赋予受约束BEL部分弹性和沿CD方向赋予完全弹性。作为受约束BEL的另一个实例,图2b中所示的是具有相对于MD成一定角度的直线22而产生非弹性区的结构,所述弹性部分24呈延伸的菱形形状。这种结构可能沿MD和CD方向都部分受约束,或许沿MD方向更如此。线或区22的角度可以增加以使该织物沿CD方向更受约束。
受约束BEL,特别是包括原位层压体的那些,可以呈现更复杂的设计以适应特定制品例如尿布和失禁衣服的生产。更复杂的受约束BEL 26的实例示于图3的图示中。受约束BEL 26包括与MD平行的非弹性区28和40。所述区可以具有不同形式或,在这种情况下,不同宽度。非弹性区28的宽度大于区40的宽度,保持弹性区30的可变宽度。此类结构如26可以形成尿布的模板。例如,可以从图3中的虚线所示的任一区32、34、36和38(梯形形状)切割包括吊钩区域(结构26的中间非弹性区28)和背片附着区(26的边缘)的尿布或尿布部分。图1-3中的非弹性区04、10、16和28可以呈任何合乎需要的宽度。在某些实施方案中,宽度在1或2或3至5或10或20或30mm的范围内,且在其它实施方案中大于1或2或3或10或20或50或100mm。
图3示出了仅CD拉伸的织物,例如用于尿布耳和/或翼的织物如何可以看起来具有压延到织物中的盲区。梯形形状是指代表尿布耳/翼并且它如何能从织物卷中冲切以致在耳的任一端具有非弹性区或″盲区″用于与尿布的背片附着以及用于附着吊钩紧固系统,同时仍然在耳或翼的中部维持仅CD拉伸构型。
用于盲区的具体间隔将取决于具体的消费者要求。从织物生产观点,最适宜的方法将是让消费者经由压延方法当织物进入它们的尿布转化器时形成盲区。或者,织物生产者能产生标准的仅CD弹性织物,其根据顾客的要求切割。它能经设计以致压延方法集成到切割方法中以致当织物被切割时产生盲区。这然后将允许依据最终用途、尺寸和设计的范围对弹性织物进行必要的定制。
本文描述的BEL或受约束BEL可以呈现任何数目的层状结构,它们可以包括由原位层压方法或传统的层压方法或产生层状结构的其它手段制造的那些。因此,BEL或受约束BEL可以进一步特征在于将所述至少一个弹性织物层(表示为″E″)与一个或多个可延伸的织物或膜层结合以形成层压体,所述层压体选自由以下构成的结构:ME、MEM、EE、EEE、EEEE、EEM、MMEMM、MMEM、EME、EMME、EEMEE、EMMEE、EMEEE、EEMMEE、EMEME、EEEMEE、SE、SES、SEM、SEES、SEEES、SSESS、SSES、SSEES、SSEEES、EE、EEE、EEEE、DEEEE、MEEEE、SEEEE、EES、ESE、ESSE、EESEE、ESSEE、ESEEE、EESSEE、ESESE、EEESEE、DE、DDE、DED、DEE、DDDDE、EED、EDE、EDDE、EEDEE、EDDEE、EEDDEE、DME、DDMEE、EDMDE、DEMED、DDEMED、DDEMEDD、DDEMMEDD、DEMMED、EDMDMD、EMDME、EDMMDD、EEDMDEE、DDDDME、EEDMMDEE、FE、MEF、FEE、FEF、SEF、DEF、WEF、FEEE、FEEEE、FEEF、FEFEF、FEEM、EFE、EMFE、EEFEE、EFFEE、EMFEE、EEMFEE、EFD、EDFD、EDDFFD、EDFDD、DEF、DFE、DDDFE、FDE、EDDF、EFDEE、FEDDEE、EFDDEE、DMEF、DFMEE、EDFDE、DEFED、DDEFED、DDEFEDD、DDEFFEDD、DEFFED、EFDFD、EFDFE、SFME、SSFME、EFFE、TxE、TxSD、TxSW、TxMTx、TxSMSTx、TxETx、TxTxETxTx、ETxE、WE、WEW、EWE、EA、EAE、AEA、TxEETx、TxSESTx、DTxETxD、WTxETxD、WSESW、DSESD、ETxTxE、ETxETxE、WTxETxW、WWEWW、WEEW、WSESW、WEAAEW、SEAAES、EATx、EAW、SEAWES、DEAED、SWEWS,其中″M″代表熔喷织物层,″S″代表纺粘织物层,″F″代表膜层,″D″代表干法成网(梳理、气流成网)织物层,″Tx″代表织物的纺织类型,″W″代表织造织物,和″A″代表吸收性(纸浆、纸张、超吸收材料等)织物。任何那些层可以由本文对弹性层(一个或多个)和可延伸层(一个或多个)描述的材料或材料共混物制成。
双组分纤维
在某些实施方案中,用来形成受约束BEL中任何一个或全部的纤维是双组分或″共轭″纤维。这些包括是并列式、分节、鞘/芯、天星状结构(″基体原纤维″)和本领域中已知的其它的结构。因此,双组分纤维是具有横截面形态的纤维,该横截面形态在变化的几何结构方面是至少两相的。在某些实施方案中,用来制备纤维的聚合物中至少一种是丙烯-α-烯烃弹性体。共轭纤维的第二、第三等等组分可以由任何适合的材料制成例如聚丙烯、聚乙烯(例如,LDPE、LLDPE、HDPE)、塑性体(例如乙烯-α-烯烃共聚物)、聚氨酯、聚酯例如聚对苯二甲酸乙二醇酯、聚乳酸、聚氯乙烯、聚四氟乙烯、苯乙烯类嵌段共聚物、丙烯-α-烯烃弹性体(例如,VistamaxxTM特种弹性体)、乙烯-α-烯烃弹性体(例如、InfuseTM弹性体)、乙烯-乙酸乙烯酯共聚物、聚酰胺、聚碳酸酯、纤维素材料(例如,棉、RayonTM、LyocellTM、TencilTM)、木材、粘胶和这些材料中任何两种或更多种的共混物。尤其优选的第二(或第三等等)组分是聚乙烯。制备双组分纤维的主要目的是开发任一聚合物本身不存在的能力。通过这一技术,可以制备可以想到的任何横截面形状或几何结构的纤维。并列式纤维一般用作自卷曲纤维。存在用来获得自卷曲纤维的数种体系。它们中之一基于每种组分的不同收缩特性。已有基于组分的不同电子性能制备自卷曲纤维的尝试。一些类型的并列式纤维随着牵引张力移除而自发地卷曲并且其它具有″潜在卷曲″,这在某些环境条件获得时出现。在一些实施方案中,当将纤维沉浸在水中而可以消除可逆卷曲并当干燥纤维时可逆卷曲再出现时,使用″可逆″和″不可逆″卷曲。这种现象基于组分的溶胀特性。当纤维用作热粘结的非织造网幅中的粘结纤维时,利用在纤维两侧上的不同熔点。
鞘-芯双组分纤维是其中组分之一(芯)基本上(至少90%)完全被第二组分(鞘)包围的那些纤维。在某些实施方案中,受约束BEL的一个或多个层的纤维是双组分的。粘附并不总是对于纤维完整性重要。制备鞘-芯纤维的最常用的方法是这样一种技术,其中将两种聚合物液体分开地引导至非常接近于喷丝孔的位置,然后以鞘-芯形式挤出。在同心纤维的情况下,提供″芯″聚合物的孔在纺纱孔出口的中心并且芯聚合物流体的流动条件被控制以维持当纺纱时这两种组分的同心度。偏心纤维制备基于数种方法:偏心布置内部聚合物孔道并控制两种组分聚合物的供应率;接近鞘组分熔体的供给源引入不同元素;临到自喷嘴出来时与同心鞘-芯组分合并引入单组分的料流;和通过让纺丝同心纤维在热边缘上通过而使该纤维变形。由两种聚合物的混合物以所要求的比例纺丝基质原纤维;其中一种聚合物以小液滴形式悬浮在第二熔体中。基质-原纤维制备中的特征为希望在喷丝孔下面立即强制冷却纤维。两种组分的不同的可纺性将几乎禁止该混合物的可纺性,除低浓度混合物(小于20%)之外。双组分纤维用来制备进入如下产品的织物:尿布、女性护理品和成人失禁产品(作为顶片、后片、腿袖带、弹性腰带、转移层);气流成网非织造结构用作湿巾中的吸收性芯;并用于纺丝花边非织造产品如医疗一次性织物,和过滤产品。
此外,在某些实施方案中,受约束BEL层的任何一个或全部可以是包含基于丙烯的纤维的混合纤维织物。混合纤维织物公开在例如,U.S.2008/0038982中,引入本文供参考。可以有一种、两种或更多种与所述基于丙烯的纤维一起的其它类型的纤维,包括由以下物质制造的纤维:聚丙烯、聚乙烯、塑性体、聚氨酯、聚酯例如聚对苯二甲酸乙二醇酯、聚乳酸、聚氯乙烯、聚四氟乙烯、苯乙烯类嵌段共聚物、丙烯-α-烯烃弹性体(例如,VistamaxxTM特种弹性体)或本文所述的其它弹性体,乙烯-乙酸乙烯酯共聚物、聚酰胺、聚碳酸酯、纤维素材料(例如,棉、RayonTM、LyocellTM、TencilTM)、木材、粘胶和这些材料中任何两种或更多种的共混物。
其它纺丝后处理
虽然受约束BEL不需要进一步机械拉伸,但是它们仍然可以经历其它纺丝后、层压后和/或熔合后处理。在不脱离本发明精神和范围的情况下可以进行在本领域中已知的各种其它可能的加工和/或修整步骤,例如切割、化学处理、印刷图形等。例如,受约束BEL可以任选地沿横向(″CD″)和/或纵向(″MD″)机械地拉伸以提高膨松、感觉和延伸性。
中一个特定的实施方案,受约束BEL可以经过沿CD和/或MD方向有槽的两个或更多个辊。此种有槽的卫星/砧型辊配置描述在U.S.2004/0110442和U.S.2006/0151914和U.S.5,914,084中,它们中每一篇引入本文供参考。所述有槽辊可以由钢或其它硬质材料(例如硬橡胶)构成。如果需要的话,可以通过在本领域中已知的任何适合的方法施加热,例如热空气、红外线加热器、加热夹辊或受约束BEL围绕着一个或多个热辊或蒸汽罐部分包裹等。还可以将热施加于有槽辊本身上。还应该理解,其它有槽辊配置是同样适合的,例如彼此紧密相邻布置的两个有槽辊。
除有槽辊之外,其它技术也可以用来沿一个或多个方向机械地拉伸复合材料。例如,可以沿MD和/或CD机械地拉伸非织造网幅的自定中心啮合圆盘描述在U.S.4,223,059、U.S.4,285,100和U.S.4,368,565中,它们中每一篇引入本文供参考。此种方法使用有槽辊,该有槽辊由安装在轴上以允许其连续自定中心的方式的一个直径的圆盘和另一个直径的圆盘组成。在一个优选的实施方案中,圆盘交替地安装在轴上。在另一个实施方案中,两个这样的有槽辊按交错或啮合关系与控制将基材引入此种啮合性有槽辊的辊隙中的速度的装置一起放置,所述速度基本上相同于所述有槽辊的表面速度从而横向地拉伸基材的增长部分。此种方法尤其可用于由较长且当拉伸不倾于撕裂,但是将经历分子取向的纤维制造的织物。
在另一个实例中,可以让复合材料穿过拉伸复合材料的拉幅机。此种拉幅机是在本领域中熟知的并描述在例如,U.S.2004/0121687中,引入本文供参考。虽然通常对于本文描述的BEL或受约束BEL是不必要的,但是这种方法仍然可以依照要求进行。
多层结构例如受约束BEL和/或受约束BEL的各个层的接合或粘结可以进行以致将额外的CD和/或MD取向赋予受约束BEL。可以采取许多途径形成包括弹性膜和/或织物层的多层结构,该弹性膜和/或织物层在一旦层压层粘结在一起时仍保持弹性。一种途径是在将织物层粘结到弹性膜上之前折叠,弄皱,弄绉或聚集织物层。在规定点或线(不连续地跨越膜的表面)处将聚集的织物粘结到膜上。在膜/织物处于松弛状态时,所述织物在膜上保持弄皱或起皱;一旦拉伸弹性膜,织物层变平直到起皱材料基本上平坦,此时弹性体拉伸停止。
赋予CD和/或MD拉伸的另一种途径是拉伸弹性膜/织物,然后在拉伸膜的同时将织物粘结到膜上。同样,在规定点或线处将织物与膜粘结,而不是连续地跨越膜的表面。当允许拉伸膜松弛时,织物在未拉伸弹性膜上弄皱或起皱。虽然通常对于本文描述的BEL或受约束BEL是不必要的,但是这种方法仍然可以依照要求进行。
另一种途径是在将织物粘结到弹性体层上之前″颈缩″织物,如U.S.5,336,545、U.S.5,226,992、U.S.4,981,747和U.S.4,965,122中所述,它们中每一篇引入本文供参考。颈缩是这样一种方法,通过该方法,沿一个方向牵引织物,这使织物中的纤维紧密滑动在一起,并且织物沿垂直于牵引方向的方向的宽度减小。如果颈缩织物与膜或织物的弹性层点粘结,则所得的层状结构将稍微沿垂直于在颈缩过程中牵引织物的方向的方向拉伸,因为颈缩织物的纤维可以当层状结构拉伸时彼此滑离。虽然通常对于本文描述的BEL或受约束BEL是不必要的,但是这种方法仍然可以依照要求进行。
又一种途径是弹性多层结构一旦形成时将该弹性多层结构活化。活化是使弹性层状结构变得易于拉伸的方法。最通常,活化是弹性层状结构的物理处理、改性或变形,所述活化通过机械法进行。例如,弹性层状结构可以通过使用啮合辊逐渐拉伸,如U.S.5,422,172或U.S.2007/0197117中所述,这两篇文献都引入本文供参考,以使该层状结构变得可拉伸和可恢复。最后,弹性膜或织物可以满足它不需要活化并且简单地形成到和/或粘结到可延伸层上而形成弹性层状结构。此种方法还可以用于非弹性层状结构以改进其它性能例如褶皱和软度。
在某些实施方案中,面层是本征非弹性的以致当结合到受约束BEL中时,所述面层是非约束性的且可延伸的,而无需任何机械拉伸。例如当由丙烯-α-烯烃弹性体制造的弹性织物层夹在两个可延伸聚丙烯或聚丙烯/PET射流喷网法织物之间时,情况就是这样。
制品
可以使用本文描述的受约束BEL制备许多有用的吸收或阻隔性产品。有用的制品的非限制性实例包括个人护理品、婴儿尿布、训练罩、吸收底垫、游泳衣、擦拭物、女性卫生产品、绑带、伤口护理品、医生衣服、手术长袍、过滤器、成人失禁产品、手术单、覆盖物、衣服、防护性服装、服装或清洁制品和设备。由于制备这些制品中的任选的压花步骤,任何这些制品可以具有成形和/或图案化的压花以便功能性和/或美学性目的。压花可以包括非弹性区的一部分或全部。
在一个实施方案中,吸收制品是一次性尿布,例如,U.S.2008/0119102中公开的那样,引入供参考。此种尿布一般界定前腰部分、后腰部分和将所述前和后腰部分互联的中部。成人失禁衣服通常将呈现相似的形式,但是具有弹性和无弹性的一些不同区(或″盲区″)。所述前和后腰部分包括尿布的一般部分,它们经构造在使用过程中分别大体上在穿戴者的前和后腹部上延伸。该尿布的中部包括尿布的一般部分,其经构造延伸经过穿戴者腿之间的胯部。因此,中部是其中尿布中通常发生重复液体浪涌的区域。例如,这些结构中的任一个或多个可以包括本文描述的受约束BEL。
尿布包括,但不限于,外覆盖物或背片、透液体侧衬垫或顶片(与所述背片呈面对关系布置)和吸收性芯体或液体保持结构,例如吸收垫,其设置在所述背片和顶片之间。例如,这些结构中的任一个或多个可以包括本文描述的受约束BEL。所述背片限定长度,或纵向,和宽度或横向,它们与尿布的长度和宽度重合。液体保持结构一般具有分别小于背片的长度和宽度的长度和宽度。因此,尿布的边缘部,例如背片的边缘部可以延伸穿过液体保持结构的端边缘。在某些实施方案中,背片向外延伸穿过液体保持结构的端边缘以形成尿布的侧边缘和末端边缘。顶片一般与背片作同等延伸,但是根据需要可以任选地覆盖比背片的面积更大或更小的面积。
为了提供改进的配合和帮助减少身体分泌液从尿布的渗漏,尿布侧边缘和末端边缘可以用适合的弹性构件加以弹性化。例如,尿布可以包括腿弹性物,该腿弹性物经构造可操作地拉紧尿布的侧边缘以提供加以弹性化的腿带,该带子可以围绕着穿戴者的腿紧密地配合以减少渗漏和提供改进的舒适和外观。腰弹性物用来使尿布的末端边缘弹性化以提供加以弹性化的腰带。该腰带弹性物配置用来提供围绕着穿戴者的腰带的弹性、舒适紧密的配合。可以形成本文所述受约束BEL的潜弹性材料,例如丙烯-α-烯烃弹性体适合于用作腿弹性物和腰弹性物。此类材料的示例是包括背片或与背片熔合的片材,以致弹性压缩力被施加于背片上。
众所周知,紧固件,例如钩和环紧固件可以用来将尿布固定在穿戴者上。或者,可以采用其它紧固件,例如按钮、插销、固定杆、粘合带紧固件、粘聚性物、织物和环紧固件等。在所示实施方案中,尿布包括与紧固件连接的一对侧板(翼或耳),表示为钩和环紧固件的钩部分。一般而言,所述侧板与尿布的在腰部分之一中的侧边连接并从那里向外横向地延伸。所述侧板可以使用潜弹性材料加以弹性化或赋予弹性。
尿布还可以包括设置在顶片和液体保持结构之间的浪涌控制层以迅速地接受流体分泌液和将该流体分泌液分布到尿布内的液体保持结构中。尿布还可以包括设置在液体保持结构和背片之间的透气层,也称作间隔物,或间隔层,以隔离背片与液体保持结构而减少衣服在空气渗透性外覆盖物或背片的外表面处的潮湿。这些结构中任一种可以包括本文所述的受约束BEL。
一次性尿布还可以包括一对容积挡板,其配置用来提供对身体分泌液的侧向流动的屏障。该容器挡板可以沿着邻接液体保持结构侧边的尿布的横向相对侧边设置。每个容器挡板通常限定不连接的边缘,其配置用来在至少尿布的中部维持直立、垂直构型以形成相对穿戴者身体的密封。该容器挡板可以沿着液体保持结构的整个长度纵向地延伸或可以仅沿着液体保持结构的长度部分延伸。当容器挡板长度比液体保持结构短时,容器挡板可以选择性地沿着尿布在中部中的侧边布置在任何地方。此种容器挡板是本领域技术人员公知的。
在织物中引入仅MD弹性的能力将大大地简化此类物品如成人失禁衣服的制造过程。许多这样的衣服利用SpandexTM纱线制备用于下背和腹部区域的MD拉伸板,它们通常称为″腹部弹性物″。这些织物可以具有至多64条穿入机器的spandex丝束并且各个丝束在聚丙烯及其它层之间胶合。用仅仅在单一辊中进料弹性织物以消除所有胶合、层压方法和穿入机器的替代这种非常复杂制造步骤的优点将是显著设备简化的,具有更高的生产速度、更高的产率(低废料率)、减少的停机时间以及其它优点。
虽然已经描述了BEL和受约束BEL和如何制备它们的各个方面,但是本文在编号实施方案中描述的是:
1.包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的受约束双轴弹性非织造层压体,其中所述织物层的至少一个部分在离散区中彼此熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。在某些实施方案中,所述熔纺弹性织物包含反应器等级基于聚烯烃的弹性体,或基本上由反应器等级基于聚烯烃的弹性体组成。
2.编号实施方案1的受约束双轴弹性非织造层压体,其中所述经结合织物层的至少一个部分在离散区中熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。
3.编号实施方案1和2的受约束双轴弹性非织造层压体,其中所述层压体具有CD宽度和至少一个与所述层压体的CD垂直的非弹性区,所述非弹性区(一个或多个)具有为所述层压体CD宽度的至少2%的CD宽度。
4.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述层压体具有CD宽度和至少一个与所述层压体的MD垂直的非弹性区,所述非弹性区(一个或多个)具有为所述层压体CD宽度的至少2%的MD宽度。
5.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述双轴弹性非织造层压体是原位层压体。
6.编号实施方案5的受约束双轴弹性非织造层压体,包括选自以下的结构:TE、TET、Tb1ET、Tb1ETb1、Tb1Eb1Tb1、T0 b1Eb1Tb1、TEC、CEC0、TCET、TTE、TEE、TEET、E0EE0、E0 b1EE0 b1、CECT、CETT、TTETT、TT0ET0T、TCECT、TE0ET、TE0EE0T、TEb1ET、TCE、T0ET、T0ETb1、T0CET、TEE0、Tb1Eb1C、T0 b1Eb1CT、TE0T、TEb1C、T0EC0T、Tb1E、Tb1Eb1、Tb1ET、Tb1EC、Tb1ET、TEb1、TECb1、TEb1T、TEb1C、TECb1T、TTE、TCCE、TTETT、TTECC、TTETT、Tb1TETTb1、TT0E、TT0C、T0ETT、TECC、TECC0、T0 b1CETb1、TEE0、TCb1EC0、TEE0T、TEE0C、TT0ET0T、TTb1E、TTb1EC、Tb1CEb1T、Tb1ET、T0 b1ET、Tb1EEC、Tb1CET、TEb1、TET0Cb1、TEEb1C、TEb1CT0、TCb1ECb1、TC0ECT、TCb1ECT和它们的变型,其中″T″是包含第一热塑性材料的织物,″T0″是包含具有与″T″不同物理性能(一种或多种)的第一热塑性材料的织物,″C″是包含不同于第一热塑性材料的第二热塑性材料的织物,″C0″是包含具有与″C″不同物理性能(一种或多种)的第二热塑性材料的织物,″E″是包含弹性体的织物,″E0″是包含具有与″E″不同物理性能(一种或多种)的弹性体的织物,和下标″b1″是指包含热塑性材料、弹性体或两者的共混物的织物。
7.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中粘合剂不存在于所述层之间。
8.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述弹性织物包含选自以下的弹性体:丙烯-α-烯烃弹性体、天然橡胶、合成聚异戊二烯、丁基橡胶、卤化丁基橡胶、聚丁二烯、苯乙烯-丁二烯橡胶、苯乙烯类嵌段共聚物、丁腈橡胶、氢化丁腈橡胶、氯丁二烯橡胶、聚氯丁二烯、氯丁橡胶、乙烯-丙烯橡胶、乙烯-丙烯-二烯橡胶、表氯醇橡胶、聚丙烯酸酯类橡胶、硅氧烷橡胶、氟硅氧烷橡胶、含氟弹性体、全氟弹性体、聚醚嵌段酰胺、氯磺化聚乙烯、乙烯-乙酸乙烯酯、乙烯-α-烯烃无规和嵌段共聚物、热塑性弹性体、热塑性硫化橡胶、热塑性聚氨酯、热塑性烯烃、聚硫橡胶和这些弹性体中任何两种或更多种的共混物。
9.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述熔纺弹性织物包含具有小于80dg/min的MFR的基于聚烯烃的弹性体。优选,所述弹性体是反应器等级弹性体。
10.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述熔纺弹性织物包含具有小于80dg/min的MFR,小于80J/g的Hf和5-35wt%的源自共聚单体的含量的丙烯-α-烯烃弹性体,按所述丙烯-α-烯烃弹性体的重量计。
11.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述可延伸织物层(一个或多个)包含选自以下的材料:聚丙烯、聚乙烯、官能化聚烯烃、塑性体(乙烯-α-烯烃无规共聚物)、聚氨酯、聚酯例如聚对苯二甲酸乙二醇酯、聚乳酸、聚氯乙烯、聚四氟乙烯、苯乙烯类嵌段共聚物、乙烯-乙酸乙烯酯共聚物、聚酰胺、聚碳酸酯、纤维素材料、弹性体、聚(乙炔)、聚(噻吩)、聚(苯胺)、聚(芴)、聚(吡咯)、聚(3-烷基噻吩)、聚(亚苯基硫醚)、聚萘、聚(亚苯基亚乙烯基)、聚(偏二氟乙烯)、乙烯-α-烯烃嵌段共聚物、木材、粘胶、棉,和这些材料中任何两种或更多种的共混物。
12.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,进一步特征在于将所述至少一个弹性织物层(表示为″E″)与一个或多个可延伸的织物或膜层结合以形成层压体,所述层压体选自由以下构成的结构:ME、MEM、EE、EEE、EEEE、EEM、MMEMM、MMEM、EME、EMME、EEMEE、EMMEE、EMEEE、EEMMEE、EMEME、EEEMEE、SE、SES、SEM、SEES、SEEES、SSESS、SSES、SSEES、SSEEES、EE、EEE、EEEE、DEEEE、MEEEE、SEEEE、EES、ESE、ESSE、EESEE、ESSEE、ESEEE、EESSEE、ESESE、EEESEE、DE、DDE、DED、DEE、DDDDE、EED、EDE、EDDE、EEDEE、EDDEE、EEDDEE、DME、DDMEE、EDMDE、DEMED、DDEMED、DDEMEDD、DDEMMEDD、DEMMED、EDMDMD、EMDME、EDMMDD、EEDMDEE、DDDDME、EEDMMDEE、FE、MEF、FEE、FEF、SEF、DEF、WEF、FEEE、FEEEE、FEEF、FEFEF、FEEM、EFE、EMFE、EEFEE、EFFEE、EMFEE、EEMFEE、EFD、EDFD、EDDFFD、EDFDD、DEF、DFE、DDDFE、FDE、EDDF、EFDEE、FEDDEE、EFDDEE、DMEF、DFMEE、EDFDE、DEFED、DDEFED、DDEFEDD、DDEFFEDD、DEFFED、EFDFD、EFDFE、SFME、SSFME、EFFE、TxE、TxSD、TxSW、TxMTx、TxSMSTx、TxETx、TxTxETxTx、ETxE、WE、WEW、EWE、EA、EAE、AEA、TxEETx、TxSESTx、DTxETxD、WTxETxD、WSESW、DSESD、ETxTxE、ETxETxE、WTxETxW、WWEWW、WEEW、WSESW、WEAAEW、SEAAES、EATx、EAW、SEAWES、DEAED、SWEWS,其中″M″代表熔喷织物层,″S″代表纺粘织物层,″F″代表膜层,″D″代表干法成网(梳理、气流成网)织物层,″Tx″代表织物的纺织类型,″W″代表织造织物,和″A″代表吸收性(纸浆、纸张、超吸收材料等)织物。给定结构中的一个或多个″E″层可以是原位层压体。
13.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述双轴弹性非织造层压体包括两个或更多个面织物层,和在其之间的包含丙烯-α-烯烃弹性体的弹性织物,所述面织物层包含任何两种或更多种类型的纤维的共混物,所述纤维包括聚丙烯、聚对苯二甲酸乙二醇酯、粘胶、棉。
14.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,其中所述双轴弹性非织造层压体包括两个或更多个面织物层和在其之间包含丙烯-α-烯烃弹性体的弹性织物,所述面织物层包含聚丙烯、聚对苯二甲酸乙二醇酯或这两种的共混物。
15.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,还包括沿着所述宽度和平行于所述双轴弹性非织造层压体的MD的至少三个非弹性区从而在所述层压体中赋予CD弹性,其中所述非弹性区的两个沿着所述层压体的边缘延伸和一个非弹性区沿着所述层压体的中间向下延伸。
16.前述编号实施方案中任一项的受约束双轴弹性非织造层压体,包括如下至少形成熔纺弹性织物:经过至少一个具有多个喷嘴的模头将单独的或呈与其它聚合物的共混物形式的一种或多种丙烯-α-烯烃弹性体挤出以形成多个连续纤维,所述一种或多种丙烯-α-烯烃弹性体具有小于80dg/min的MFR,至少一个模头在大于500psi(3.45MPa)的熔体压力下操作以形成至少一种弹性织物。
17.吸收或阻隔性产品,其包括前述编号实施方案中任一项的受约束双轴弹性非织造层压体,所述制品选自个人护理品、婴儿尿布、训练罩、吸收底垫、游泳衣、擦拭物、女性卫生产品、绑带、伤口护理品、医生衣服、手术长袍、过滤器、成人失禁产品、手术单、覆盖物、衣服(garment)、防护性服装、服装(clothing apparel)或清洁制品和设备。
18.在前述编号实施方案中任一项的双轴弹性非织造层压体中赋予约束的方法,包括提供包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的双轴弹性非织造层压体;和使所述至少一个熔纺弹性织物的至少一部分熔合到所述可延伸织物的至少一个上以产生至少一个非弹性区。
19.编号实施方案18的方法,其中所述至少一个熔纺弹性织物的离散区到所述可延伸织物的至少一个上的熔合产生一个或多个下述的区:所述区具有的弹性比所述熔纺弹性织物的初始弹性低至少40%。
20.编号实施方案18和19的方法,其中所述熔合步骤是利用具有高热分区型式的压延机进行的。
21.编号实施方案18-20中任一项的方法,其中所述熔合使用超声波装置进行。
22.编号实施方案18-21中任一项的方法,其中所述熔合进一步将压花图案引入层压体中。
23.编号实施方案18-22中任一项的方法,其中所述熔合和压花步骤利用压延机进行,该压延机具有任选地加热的阴阳辊。
24.编号实施方案18-23中任一项的方法,其中所述熔合和压花步骤利用在真空差异下运行的图案化阴阳真空鼓进行。
25.编号实施方案5的方法,其中通过下述方法形成原位层压体:该方法包括同时熔纺彼此邻接的两种或更多种聚合物熔体以形成相邻织物,其中彼此邻接的织物层彼此原位缠绕而在织物层之间形成混合纤维的界面区。
26.编号实施方案18-25中任一项的方法,其中粘合剂的应用不存在于所述熔合步骤中。
27.编号实施方案18-26中任一项的方法,其中不使用粘合剂使任何两个或更多个织物和/或膜层彼此粘附。

Claims (25)

1.在双轴弹性非织造层压体中赋予约束的方法,包括:
提供包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的双轴弹性非织造层压体;和
使所述至少一个熔纺弹性织物的至少一部分熔合到所述可延伸织物的至少一个上以产生至少一个非弹性区。
2.权利要求1的方法,其中所述经结合织物层的至少一个部分在离散区中熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。
3.权利要求1或2的方法,其中所述层压体具有CD宽度和与所述层压体的CD垂直的非弹性区,所述非弹性区具有为所述层压体CD宽度的至少2%的CD宽度。
4.权利要求1或2的方法,其中所述层压体具有CD宽度和与所述层压体的MD垂直的非弹性区,所述非弹性区具有为所述层压体CD宽度的至少2%的MD宽度。
5.前述权利要求中任一项的方法,其中所述熔合包括压延所述双轴弹性非织造层压体以使所述熔纺弹性织物的至少一部分熔融并产生与至少一个可延伸织物的熔合。
6.前述权利要求中任一项的方法,其中所述熔合步骤是利用具有高热分区型式的压延机进行的。
7.前述权利要求中任一项的方法,其中所述熔合进一步将压花图案引入所述层压体中。
8.前述权利要求中任一项的方法,其中所述双轴弹性非织造层压体是原位层压体。
9.前述权利要求中任一项的方法,其中粘合剂的应用不存在于所述熔合步骤中。
10.前述权利要求中任一项的方法,其中所述弹性织物包含选自以下的弹性体:丙烯-α-烯烃弹性体、天然橡胶、合成聚异戊二烯、丁基橡胶、卤化丁基橡胶、聚丁二烯、苯乙烯-丁二烯橡胶、苯乙烯类嵌段共聚物、丁腈橡胶、氢化丁腈橡胶、氯丁二烯橡胶、聚氯丁二烯、氯丁橡胶、乙烯-丙烯橡胶、乙烯-丙烯-二烯橡胶、表氯醇橡胶、聚丙烯酸酯类橡胶、硅氧烷橡胶、氟硅氧烷橡胶、含氟弹性体、全氟弹性体、聚醚嵌段酰胺、氯磺化聚乙烯、乙烯-乙酸乙烯酯、乙烯-α-烯烃无规和嵌段共聚物、热塑性弹性体、热塑性硫化橡胶、热塑性聚氨酯、热塑性烯烃、聚硫橡胶和这些弹性体中任何两种或更多种的共混物。
11.前述权利要求中任一项的方法,其中所述熔纺弹性织物包含具有小于80dg/min的MFR的基于聚烯烃的弹性体。
12.前述权利要求中任一项的方法,其中所述熔合沿着所述宽度和平行于所述双轴弹性非织造层压体的MD产生至少三个非弹性区从而在所述层压体中赋予CD弹性,其中所述非弹性区的两个沿着所述层压体的边缘延伸和一个非弹性区沿着所述层压体的中间向下延伸。
13.前述权利要求中任一项的方法,包括如下至少形成熔纺弹性织物:经过至少一个具有多个喷嘴的模头将单独的或呈与其它聚合物的共混物形式的一种或多种丙烯-α-烯烃弹性体挤出以形成多个连续纤维,所述一种或多种丙烯-α-烯烃弹性体具有小于80dg/min的MFR,至少一个模头在大于500psi(3.45MPa)的熔体压力下操作以形成至少一个弹性织物。
14.吸收或阻隔性产品,其包括通过前述权利要求中任一项的方法制得的受约束双轴弹性非织造层压体,所述制品选自个人护理品、婴儿尿布、训练罩、吸收底垫、游泳衣、擦拭物、女性卫生产品、绑带、伤口护理品、医生衣服、手术长袍、过滤器、成人失禁产品、手术单、覆盖物、衣服、防护性服装、服装或清洁制品和设备。
15.包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的受约束双轴弹性非织造层压体,其中所述织物层的至少一个部分在离散区中彼此熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。
16.权利要求15的受约束双轴弹性非织造层压体,其中所述经结合织物层的至少一个部分在离散区中熔合,所述离散区平行于所述双轴弹性层压体的CD,平行于所述双轴弹性层压体的MD,或按介于它们之间的某种取向。
17.权利要求15或16的受约束双轴弹性非织造层压体,其中所述双轴弹性非织造层压体是原位层压体。
18.权利要求15-17中任一项的受约束双轴弹性非织造层压体,其中粘合剂不存在于所述层之间。
19.权利要求15-18中任一项的受约束双轴弹性非织造层压体,所述弹性织物包含选自以下的弹性体:丙烯-α-烯烃弹性体、天然橡胶、合成聚异戊二烯、丁基橡胶、卤化丁基橡胶、聚丁二烯、苯乙烯-丁二烯橡胶、苯乙烯类嵌段共聚物、丁腈橡胶、氢化丁腈橡胶、氯丁二烯橡胶、聚氯丁二烯、氯丁橡胶、乙烯-丙烯橡胶、乙烯-丙烯-二烯橡胶、表氯醇橡胶、聚丙烯酸酯类橡胶、硅氧烷橡胶、氟硅氧烷橡胶、含氟弹性体、全氟弹性体、聚醚嵌段酰胺、氯磺化聚乙烯、乙烯-乙酸乙烯酯、乙烯-α-烯烃无规和嵌段共聚物、热塑性弹性体、热塑性硫化橡胶、热塑性聚氨酯、热塑性烯烃、聚硫橡胶或这些弹性体中任何两种或更多种的共混物。
20.权利要求15-19中任一项的受约束双轴弹性非织造层压体,其中所述熔纺弹性织物包含具有小于80dg/min的MFR的基于聚烯烃的弹性体。
21.权利要求15-20中任一项的受约束双轴弹性非织造层压体,进一步特征在于将所述至少一个表示为″E″的弹性织物层与一个或多个可延伸的织物或膜层结合以形成层压体,所述层压体选自由以下构成的结构:ME、MEM、EE、EEE、EEEE、EEM、MMEMM、MMEM、EME、EMME、EEMEE、EMMEE、EMEEE、EEMMEE、EMEME、EEEMEE、SE、SES、SEM、SEES、SEEES、SSESS、SSES、SSEES、SSEEES、EE、EEE、EEEE、DEEEE、MEEEE、SEEEE、EES、ESE、ESSE、EESEE、ESSEE、ESEEE、EESSEE、ESESE、EEESEE、DE、DDE、DED、DEE、DDDDE、EED、EDE、EDDE、EEDEE、EDDEE、EEDDEE、DME、DDMEE、EDMDE、DEMED、DDEMED、DDEMEDD、DDEMMEDD、DEMMED、EDMDMD、EMDME、EDMMDD、EEDMDEE、DDDDME、EEDMMDEE、FE、MEF、FEE、FEF、SEF、DEF、WEF、FEEE、FEEEE、FEEF、FEFEF、FEEM、EFE、EMFE、EEFEE、EFFEE、EMFEE、EEMFEE、EFD、EDFD、EDDFFD、EDFDD、DEF、DFE、DDDFE、FDE、EDDF、EFDEE、FEDDEE、EFDDEE、DMEF、DFMEE、EDFDE、DEFED、DDEFED、DDEFEDD、DDEFFEDD、DEFFED、EFDFD、EFDFE、SFME、SSFME、EFFE、TxE、TxSD、TxSW、TxMTx、TxSMSTx、TxETx、TxTxETxTx、ETxE、WE、WEW、EWE、EA、EAE、AEA、TxEETx、TxSESTx、DTxETxD、WTxETxD.WSESW、DSESD、ETxTxE、ETxETxE、WTxETxW、WWEWW、WEEW、WSESW、WEAAEW、SEAAES、EATx、EAW、SEAWES、DEAED、SWEWS,其中″M″代表熔喷织物层,″S″代表纺粘织物层,″F″代表膜层,″D″代表干法成网(梳理、气流成网)织物层,″Tx″代表织物的纺织类型,″W″代表织造织物,和″A″代表吸收性(纸浆、纸张、超吸收材料等)织物。
22.权利要求15-21中任一项的受约束双轴弹性非织造层压体,其中所述双轴弹性非织造层压体包括两个或更多个面织物层,和在其之间的包含丙烯-α-烯烃弹性体的弹性织物,所述面织物层包含任何两种或更多种类型的纤维的共混物,所述纤维包括聚丙烯、聚对苯二甲酸乙二醇酯、粘胶、棉。
23.权利要求15-22中任一项的受约束双轴弹性非织造层压体,还包括沿着所述宽度和平行于所述双轴弹性非织造层压体的MD的至少三个非弹性区从而在层压体中赋予CD弹性,其中所述非弹性区的两个沿着所述层压体的边缘延伸和一个非弹性区沿着所述层压体的中间向下延伸。
24.吸收或阻隔性产品,其包括权利要求15-23中任一项的受约束双轴弹性非织造层压体,所述制品选自个人护理品、婴儿尿布、训练罩、吸收底垫、游泳衣、擦拭物、女性卫生产品、绑带、伤口护理品、医生衣服、手术长袍、过滤器、成人失禁产品、手术单、覆盖物、衣服、防护性服装、服装或清洁制品和设备。
25.在双轴弹性非织造层压体中赋予约束的方法,包括:
提供包括至少一个熔纺弹性织物和至少一个可延伸织物或膜的双轴弹性非织造层压体;和
使所述至少一个熔纺弹性织物的一个或多个离散区熔合到所述可延伸织物的至少一个上以产生下述的区:所述区具有的弹性比所述熔纺弹性织物的初始弹性低至少40%。
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CN107000361B (zh) * 2014-12-19 2019-06-14 金伯利-克拉克环球有限公司 具有经改善的粘结特征的非织造开孔弹性膜
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