CN102412361B - Laminated heat dissipation substrate and electronic assembly structure using same - Google Patents

Laminated heat dissipation substrate and electronic assembly structure using same Download PDF

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Publication number
CN102412361B
CN102412361B CN201110126956.2A CN201110126956A CN102412361B CN 102412361 B CN102412361 B CN 102412361B CN 201110126956 A CN201110126956 A CN 201110126956A CN 102412361 B CN102412361 B CN 102412361B
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layer
bond layer
resin
stacking
substrate
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CN102412361A (en
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李弘荣
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Azotek Co Ltd
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Azotek Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/64Heat extraction or cooling elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/30Technical effects
    • H01L2924/301Electrical effects
    • H01L2924/3011Impedance

Abstract

The invention provides a laminated heat dissipation substrate and an electronic assembly structure using the same. The laminated heat dissipation substrate includes a substrate, a laminated bonding layer, an insulating layer, and a conductive layer. The laminated bonding layer is arranged on the substrate and at least comprises a first bonding layer and a second bonding layer. The first bonding layer is disposed on the substrate. The second bonding layer is disposed on the first bonding layer. The insulating layer is disposed on the laminated bonding layer. The conductive layer is disposed on the insulating layer. The electronic assembly structure comprises the laminated heat dissipation substrate and an electronic assembly. The insulating layer and the conductive layer further enclose an accommodating space on the laminated bonding layer, and the accommodating space exposes the laminated bonding layer. The electronic assembly is arranged in the accommodating space and on the laminated bonding layer and is electrically connected with the conductive layer. The electronic component is preferably a light emitting diode.

Description

Stacking heat-radiating substrate and use the electronics packaging assembly of this stacking heat-radiating substrate
Technical field
The invention relates to a kind of stacking heat-radiating substrate, can use by supplied for electronic assembly. Specifically, the invention relates to a kind of stacking heat-radiating substrate for photodiode.
Background technology
In recent years along with the development of High Power LED (LED) technology, its luminous efficiency is promoted to 160��more than 170lm/W gradually. But, its electro-optical efficiency only about 40��50%. In other words, the electric energy of its input still has exhausted major part to convert heat energy to, if these heat energy can not be directed at external environment fast, chip temperature will be caused to rise, and then affect luminous intensity and life-span. Therefore, the heat management problems of high-capacity LED product is more and more paid attention to.
In LED product, printed circuit board (PCB) is indispensable part, it is provided that electronic package is installed and interconnection prop carrier, is again wherein main raw taking heat-radiating substrate. General industry the most often uses metal substrate as heat-radiating substrate, and as shown in Figure 1A, existing electronics packaging assembly 90 comprises aluminum metal substrate 10, insulation layer 50 and conductive layer 70. Namely the maximum heat radiation bottleneck of this type substrate is the insulation layer 50 between conductive layer 70 and aluminum metal substrate 10. Insulation layer 50 uses epoxy resin as main raw mostly, but because of its heat-conduction coefficient on the low side, it is necessary to add heat conductive filler separately, such as fillers such as aluminum oxide, aluminium nitride and boron nitride, improve the heat-conduction coefficient of this layer, and then reduce the thermal impedance of this substrate. Even so, the heat-conduction coefficient of insulation layer 50 is still far below metallic substance, therefore is still the main bottleneck of heat radiation. On the other hand, as shown in Figure 1B, in different embodiments, may have, between the aluminum metal substrate 10 of existing electronics packaging assembly 90 and insulation layer 50, the demand that copper containing layer 33 is set.But, copper containing layer 33 is not good with the adhesion of aluminum metal substrate 10, easily makes copper containing layer 33 peel off from aluminum metal substrate 10.
Summary of the invention
The main purpose of the present invention, for providing a kind of stacking heat-radiating substrate, has preferably adhesive force of metal layer.
Another object of the present invention, for providing a kind of stacking heat-radiating substrate, has thinner thickness.
Another object of the present invention, for providing a kind of electronics packaging assembly, has preferably heat-sinking capability.
The stacking heat-radiating substrate of the present invention comprises substrate, stacking bond layer, insulation layer and conductive layer. Stacking bond layer is arranged on substrate, at least comprises the first bond layer and the 2nd bond layer. First bond layer is arranged on substrate. 2nd bond layer is arranged on the first bond layer, and the sticking power of the first bond layer and substrate is greater than the sticking power of the 2nd bond layer and substrate. Insulation layer is arranged on stacking bond layer. Conductive layer is arranged on insulation layer.
Substrate comprises aluminum or aluminum alloy or copper or copper alloy. 2nd bond layer is copper or copper alloy. Stacking bond layer comprises the 3rd bond layer further, is arranged between the first bond layer and the 2nd bond layer, and wherein the 3rd bond layer comprises metal, metal alloy or pottery. The sticking power that the sticking power of the 3rd bond layer and the first bond layer and the 2nd bond layer is greater than between the first bond layer and the 2nd bond layer. In the preferred embodiment, the first bond layer contains zinc. The nickel content of the 3rd bond layer is greater than 90%, and phosphorus content is less than 10%. Stacking bond layer comprises protective layer further, and under being arranged at insulation layer, protective layer comprises metal, metal alloy, metal oxide or organic compound. Protective layer can be copper oxide or chromated oxide; or can be nitrogenous, containing oxygen, containing phosphorus or containing the organic compound of sulphur; also can be silicane organic compound, or also can be nickel, cobalt, zinc, chromium, molybdenum, copper, nickelalloy, cobalt-base alloy, zinc alloy, Chrome metal powder, molybdenum alloy, copper alloy or its mixture.
The material of insulation layer is included as polyimide resin, polyamide-imide resin, poly-naphthalic acid resin, epoxy resin, acrylic resin, amido formate system resin, silicone resin, poly-to ring dimethylbenzene system resin, bismaleimides system resin, polyether ketone resin, unsaturated polyester resin, polyamide resin, urethane resin, resol, polyethersulfone resin, polyethylene terephthalate or its mixture. Conductive layer is selected from tin, nickel, silver, copper, gold, palladium, cobalt, chromium, titanium, platinum, tantalum, tungsten and molybdenum.
In different embodiments, stacking heat-radiating substrate can comprise toss about insulation layer and conductive layer of tossing about further. Insulation layer of tossing about is arranged at the another side of substrate relative to stacking bond layer. Conductive layer of tossing about is arranged at the another side of insulation layer opposing substrate of tossing about. Stacking heat-radiating substrate can comprise a plurality of hole further and run through toss about insulation layer and conductive layer of tossing about, and is filled with thermally conductive material in hole. The material of insulation layer of tossing about is included as polyimide resin, epoxy resin, acrylic resin, amido formate system resin, silicone resin, poly-to ring dimethylbenzene system resin, bismaleimides system resin, polyether ketone resin, unsaturated polyester resin, polyamide resin, urethane resin, resol, polyethersulfone resin, polyethylene terephthalate or its mixture. Conductive layer of tossing about is selected from tin, nickel, silver, copper, gold, palladium, cobalt, chromium, titanium, platinum, tantalum, tungsten and molybdenum.
The electronics packaging assembly of the present invention comprises aforementioned stacking heat-radiating substrate and electronic package. Wherein, insulation layer and conductive layer cross accommodating space further on stacking bond layer, and accommodating space exposes stacking bond layer. Electronic package is arranged in accommodating space and on stacking bond layer, and is electrically connected with conductive layer. Electronic package is preferably photodiode.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to the technique means of the present invention can be better understood, and can be implemented according to the content of specification sheets, and in order to above and other objects of the present invention, feature and advantage can be become apparent, below especially exemplified by better embodiment, and coordinate accompanying drawing, it is described in detail as follows.
Accompanying drawing explanation
Figure 1A and 1B is prior-art illustration;
Fig. 2,3A, 3B, 4,5A, 5B and 6A be different embodiments of the invention schematic diagram;
Fig. 6 B is the better embodiment schematic diagram of the present invention; And
Fig. 6 C, 7A and 7B are different embodiments of the invention schematic diagram.
Embodiment
Technique means and effect that predetermined goal of the invention is taked is reached for further setting forth the present invention, below in conjunction with accompanying drawing and better embodiment, the stacking heat-radiating substrate propose foundation the present invention and its embodiment of electronics packaging assembly using this stacking heat-radiating substrate, structure, feature and effect thereof, be described in detail as follows.
Embodiment as shown in Figure 2, the stacking heat-radiating substrate 800 of the present invention comprises substrate 100, stacking bond layer 300, insulation layer 500 and conductive layer 700. Specifically, substrate 100 is preferably and uses metal or alloy to make, and owing to this type of material is with good thermal conductivity, therefore can promote the radiating effect of heat-radiating substrate 800 entirety further. Wherein, because aluminium quality is relatively light, price is lower and has good thermal conductivity, therefore in the preferred embodiment, substrate 100 uses aluminum or aluminum alloy to make.
Stacking bond layer 300 is arranged on substrate 100, at least comprises the first bond layer 310 and the 2nd bond layer 320. First bond layer 310 is arranged on substrate 100, better but do not limit containing zinc. 2nd bond layer 320 is arranged on the first bond layer 310. 2nd bond layer 320 is copper or copper alloy. Wherein, the 2nd bond layer 320 is lower with the sticking power of the substrate 100 using aluminum or aluminum alloy to make, and the first bond layer 310 then has good sticking power with substrate 100.
Stacking bond layer 300 comprises the 3rd bond layer 330 further, is arranged between the first bond layer 310 and the 2nd bond layer 320, and wherein the 3rd bond layer 330 comprises metal, metal alloy or pottery. Metal is selected from tin, nickel, silver, copper, gold, palladium, cobalt, chromium, titanium, platinum, tantalum, tungsten and molybdenum. In the preferred embodiment, the 3rd bond layer 330 is nickelalloy, and nickel content is between 90% to 100%, and phosphorus content is between 0 to 10%. Wherein, the 3rd bond layer 330 and the first bond layer 310 and all there is good sticking power with the 2nd bond layer 320. Furthermore, the 3rd bond layer 330 respectively and the first bond layer 310 and and the 2nd bond layer 320 between sticking power better, be greater than the first bond layer 310 and and the 2nd bond layer 320 between sticking power. Therefore, the 2nd bond layer 320 can be attached on the first bond layer 310 more well by the 3rd bond layer 330.
Comprehensive speech, embodiment as shown in Figure 3A, stacking bond layer 300 is except comprising the first bond layer 310 and the 2nd bond layer 320, can comprise multiple bond layer further is sequentially laminated between the first bond layer 310 and the 2nd bond layer 320, and each adjacent bond layer has good sticking power to each other.By this, even if the bond layer being laminated in the superiors is not good with the sticking power of substrate 100, the bond layer being located in therebetween still can be utilized to be attached to well on substrate 100. Wherein, each bond layer can select identical or different materials, also namely available identical or different material successively stacking go out adjacent bond layer. On the other hand, can by control formation condition such as ratio, temperature, the time etc. in the middle of processing procedure, order uses the different bond layers of identical material to have different physics, chemical property.
Insulation layer 500 is arranged on stacking bond layer 300. Conductive layer 700 is arranged on insulation layer 500. Wherein, the material of insulation layer is included as polyimide resin, polyamide-imide resin, poly-naphthalic acid resin, epoxy resin, acrylic resin, amido formate system resin, silicone resin, poly-to ring dimethylbenzene system resin, bismaleimides system resin, polyether ketone resin, unsaturated polyester resin, polyamide resin, urethane resin, resol, polyethersulfone resin, polyethylene terephthalate or its mixture. Conductive layer is selected from tin, nickel, silver, copper, gold, palladium, cobalt, chromium, titanium, platinum, tantalum, tungsten and molybdenum.
Different embodiments as shown in Figure 3 B, stacking bond layer 300 comprises protective layer 333 further, is arranged between the 2nd bond layer 320 and insulation layer 500. In other words, protective layer 333 is the superiors of multiple bond layers that stacking bond layer 300 comprises. Protective layer 333 comprises metal, metal alloy, metal oxide or organic compound. 2nd bond layer 320 is copper in this embodiment, and protective layer 333 is copper oxide. The insulation layer 500 that protective layer 333 is not only upper and lower with it respectively and the 2nd bond layer 320 have good sticking power, more can have anti-welding protected effect of Denging. But in other different embodiment; 2nd bond layer 320 can be copper alloy, and protective layer 333 can be the mixture of or its alloy of other metal oxide (such as: chromated oxide), organic compound (such as: nitrogenous, containing oxygen, containing phosphorus or containing the organic compound of sulphur or silicane organic compound), one or more metals (such as nickel, cobalt, zinc, chromium, molybdenum, copper) itself. Wherein, protective layer 333 can overlapped way be arranged further, and is above-mentioned arbitrary combination.
As shown in Figure 4, in different embodiments, stacking heat-radiating substrate 800 can comprise toss about insulation layer 550 and conductive layer 770 of tossing about further. Insulation layer 550 of tossing about is arranged at the another side of the relative stacking bond layer 300 of substrate 100. Conductive layer 770 of tossing about is arranged at the another side of insulation layer 550 opposing substrate 100 of tossing about. The material of insulation layer 550 of tossing about is included as polyimide resin, polyamide-imide resin, poly-naphthalic acid resin, epoxy resin, acrylic resin, amido formate system resin, silicone resin, poly-to ring dimethylbenzene system resin, bismaleimides system resin, polyether ketone resin, unsaturated polyester resin, polyamide resin, urethane resin, resol, polyethersulfone resin, polyethylene terephthalate or its mixture. Conductive layer 770 of tossing about is selected from tin, nickel, silver, copper, gold, palladium, cobalt, chromium, titanium, platinum, tantalum, tungsten and molybdenum.
In different embodiments as shown in Figure 4, stacking heat-radiating substrate 800 can comprise a plurality of hole 400 further and run through toss about insulation layer 550 and conductive layer 770 of tossing about. In different embodiments, thermally conductive material (not illustrating) can be filled with in a plurality of hole 400.Wherein, the position of hole 400, quantity, internal diameter or distribution mode etc., can change according to design requirement. The heat-conduction coefficient of thermally conductive material is preferably and is greater than 10W/mK, comprises metal, alloy, pottery, metal or pottery-polymer composite, thermal conductive silicon resin or its mixture. Wherein, metal can be silver, copper, aluminium, nickel or iron, and alloy can be tinsel, tin pb-ag alloy or SAC. Pottery can be aluminum oxide, boron nitride, aluminium nitride, silicon carbide, carbon nanotube or graphite etc. Thermally conductive material is filled in mode its changes in material properties visual of hole 400, such as can be poured into hole 400 when thermal conductive silicon resin heat conduction thing is flow state, or make the plating of metal heat-conducting thing be formed in hole 400, or with mechanical force by solid metal-polymer composite heat conduction thing press-in hole 400. Wherein, heat conduction thing is not limited to fill up hole 400, it is also possible to the mode of coverage hole 400 sidewall is arranged. In different embodiments, in a plurality of hole 400, electronic package (not illustrating) also can be set.
Embodiment as shown in Figure 5A, the electronics packaging assembly 900 of the present invention comprises aforementioned stacking heat-radiating substrate 800 and electronic package 200. Wherein, insulation layer 500 and conductive layer 700 cross accommodating space 600 further on stacking bond layer 300, and accommodating space 600 exposes stacking bond layer 300. In the preferred embodiment, it is the stacking heat-radiating substrate 800 shown in Fig. 2 is removed with physics or chemical mode etching specific region insulation layer 500 and conductive layer 700, to form accommodating space 600. As shown in Figure 5A, electronic package 200 is arranged in accommodating space 600 and on stacking bond layer 300, and is electrically connected with conductive layer 700. Wherein, the mode of connection is preferably and uses wire 222. Electronic package 200 is preferably photodiode, and also namely electronics packaging assembly 900 is preferably for light emitting diode illuminating apparatus. But in different embodiments, electronics packaging assembly 900 can be used for other electronic installation. Specifically, in the electronics packaging assembly 900 of the present invention, between electronic package 200 and substrate 100, there is no insulation layer 500, integral thickness can be made to reduce. On the other hand, the heat produced when electronic package 200 operates can more directly be sent to substrate 100 and dispel the heat, can improving heat radiation efficiency.
Between the 2nd bond layer 320 of different embodiments as shown in Figure 5 B, electronic package 200 and stacking bond layer 300, between the 2nd bond layer 320 and the 3rd bond layer 330, between the 3rd bond layer 330 and the first bond layer 310, between the first bond layer 310 and substrate 100, there is good sticking power respectively. Therefore, even if electronic package 200 sticking power that is direct and substrate 100 is not good, the first bond layer 310 being located in therebetween, the 3rd bond layer 330 and the 2nd bond layer 320 still can be utilized to be attached to well on substrate 100.
In the such as embodiment shown in Fig. 6 A to Fig. 6 C, wherein, protective layer 333 optionally retains (such as Fig. 6 A) in processing procedure or removes (such as Fig. 6 B). In other words, protective layer 333 can retain in processing procedure and be arranged at insulation layer 500 times as shown in Figure 6A simultaneously and be exposed to accommodating space 600, or can remove in processing procedure and only be arranged at insulation layer 500 times as shown in Figure 6B. On the other hand, insulation layer 500 can be arranged with overlapped way further. Such as in the embodiment shown in Fig. 6 C, insulation layer 500 comprises the first insulation layer 510 and the 2nd insulation layer 520. Therefore then effect can be increased by this. Furthermore, as shown in figs. 7 a and 7b, insulation layer 500 and conductive layer 700 also can be arranged in stacking.
The above, it it is only the better embodiment of the present invention, not the present invention is done any restriction in form, although the present invention discloses as above with better embodiment, but and be not used to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, make a little change when the technology contents of above-mentioned announcement can be utilized or it is modified to the equivalent embodiment of equivalent variations, in every case it is do not depart from technical solution of the present invention content, the any simple modification above embodiment done according to the technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.

Claims (13)

1. a stacking heat-radiating substrate, it is characterised in that, comprise:
One substrate;
One stacking bond layer, is arranged on this substrate, at least comprises:
One first bond layer, is arranged on this substrate; And
One the 2nd bond layer, is arranged on this first bond layer, and the sticking power of this first bond layer and this substrate is greater than the sticking power of the 2nd bond layer and this substrate, and the 2nd bond layer is copper or copper alloy;
One insulation layer, being arranged on this stacking bond layer, the material of this insulation layer is polyimide resin, polyamide-imide resin, poly-naphthalic acid resin, epoxy resin, acrylic resin, amido formate system resin, silicone resin, poly-to ring dimethylbenzene system resin, bismaleimides system resin, polyether ketone resin, unsaturated polyester resin, polyamide resin, urethane resin, resol, polyethersulfone resin, polyethylene terephthalate or its mixture; And
One conductive layer, is arranged on this insulation layer;
Wherein, this stacking bond layer comprises a protective layer further; under being arranged at this insulation layer; and between this insulation layer and the 2nd bond layer; this protective layer is copper oxide or chromated oxide; or nitrogenous, containing oxygen, containing phosphorus or containing the organic compound of sulphur, or silicane organic compound, or nickel, cobalt, zinc, chromium, molybdenum, nickelalloy, cobalt-base alloy, zinc alloy, Chrome metal powder, molybdenum alloy or its mixture.
2. stacking heat-radiating substrate as claimed in claim 1, it is characterised in that, this first bond layer contains zinc.
3. stacking heat-radiating substrate as claimed in claim 1, it is characterised in that, this substrate comprises aluminum or aluminum alloy or copper or copper alloy.
4. stacking heat-radiating substrate as claimed in claim 1, it is characterized in that, this stacking bond layer comprises one the 3rd bond layer further, it is arranged between this first bond layer and the 2nd bond layer, the sticking power that the sticking power of the 3rd bond layer and this first bond layer and the 2nd bond layer is greater than between this first bond layer and the 2nd bond layer.
5. stacking heat-radiating substrate as claimed in claim 4, it is characterised in that, the 3rd bond layer comprises metal, metal alloy or pottery.
6. stacking heat-radiating substrate as described in claim 4 or 5, it is characterised in that, the 3rd bond layer is nickelalloy or nickel-phosphorus alloy, and its nickel content is greater than 90%, and phosphorus content is less than 10%.
7. stacking heat-radiating substrate as claimed in claim 1, it is characterised in that, this conductive layer is selected from tin, nickel, silver, copper, gold, palladium, cobalt, chromium, titanium, platinum, tantalum, tungsten and molybdenum.
8. stacking heat-radiating substrate as claimed in claim 1, it is characterised in that, comprise further:
One tosses about insulation layer, is arranged at the another side of this substrate relative to this stacking bond layer;
One tosses about conductive layer, is arranged at the another side of this insulation layer of tossing about relative to this substrate; And
A plurality of hole, this plurality of hole runs through this toss about insulation layer and this conductive layer of tossing about, and is filled with thermally conductive material in this hole.
9. stacking heat-radiating substrate as claimed in claim 8, it is characterized in that, the material of this insulation layer of tossing about is included as polyimide resin, polyamide-imide resin, poly-naphthalic acid resin, epoxy resin, acrylic resin, amido formate system resin, silicone resin, poly-to ring dimethylbenzene system resin, bismaleimides system resin, polyether ketone resin, unsaturated polyester resin, polyamide resin, urethane resin, resol, polyethersulfone resin, polyethylene terephthalate or its mixture.
10. an electronics packaging assembly, it is characterised in that, comprise:
Stacking heat-radiating substrate as claimed in claim 1, wherein this insulation layer and this conductive layer cross an accommodating space further on this stacking bond layer, and this accommodating space exposes this stacking bond layer; And
One electronic package, is arranged in this accommodating space and on this stacking bond layer, and is electrically connected with this conductive layer.
11. electronics packaging assemblies as claimed in claim 10, it is characterized in that, this stacking bond layer comprises one the 3rd bond layer further, it is arranged between this first bond layer and the 2nd bond layer, the sticking power that the sticking power of the 3rd bond layer and this first bond layer and the 2nd bond layer is greater than between this first bond layer and the 2nd bond layer.
12. electronics packaging assemblies as claimed in claim 10, it is characterised in that, this insulation layer arranges with stacking or individual layer mode.
13. electronics packaging assemblies as claimed in claim 10, it is characterised in that, this insulation layer and this conductive layer stacking are arranged.
CN201110126956.2A 2010-09-21 2011-05-17 Laminated heat dissipation substrate and electronic assembly structure using same Active CN102412361B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
TW099131992 2010-09-21
TW99131992 2010-09-21
TW100110313A TWI481085B (en) 2010-09-21 2011-03-25 A laminated heat dissipating plate and an electronic assembly structure using the same
TW100110313 2011-03-25

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CN102412361A CN102412361A (en) 2012-04-11
CN102412361B true CN102412361B (en) 2016-06-08

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