Tea tree controlled release fertilizer and preparation technology thereof
Technical field
The invention belongs to the vegetable fertilizer field, particularly, the present invention relates to be used for the release and release control fertilizer of tea tree.
Background technology
Tea big country is drunk tea, planted in China, and the tealeaves YO occupies the second in the world.Different according to plantation geographical position and kind, the tea tree tealeaves of can gathering in 1 year 2~4 times, so the supply that need in the process of growth of tea tree, keep continual nutrient supply, especially nitrogenous fertilizer just can make tea yield remain on higher level.
For this reason, someone's tea tree fertilizer that begins one's study at present.For example, Chinese patent 93102872 discloses the special-purpose fertile of tea tree blade face, and it comprises 30~55% urea, 5~20% glucose, 10~25% sylvite, 10~30% zinc salt and microbiotic etc.
More be composite fertilizer at present.For example; Chinese patent 200910016860 discloses the tea tree organic and inorganic compound fertilizer, it comprise 3~15 parts in urea, 10~30 parts in ammonium sulfate, 5~25 parts of diammonium phosphate, 5~15 parts of vitriolate of tartar and with microbial fermentation bacteria fermentation furfural dregs, scarp and differentiation matchmaker 40~70 parts of fermentation fertilizers.
But after using with apply fertilizer, especially after southern rain-belt is used, wherein the solubility inorganic fertilizer can the fast speed dissolving, has reduced the effect that fertilizer is used on the one hand, causes the fertilizer waste, also pollutes peripheral water body in addition.For this reason, there is the people to prepare slowly-releasing (controlled release) fertilizer through the mode that increases coating on the fertilizer surface.For example; Chinese patent 03128868 discloses a kind of tea tree control release composite fertilizer special; It is made up of coated carbamide and phosphorus potassium complex fertilizer; Wherein the ratio of nitrogen, phosphorus, potash fertilizer is 1: 0.2~0.5: 0.2~0.5, and coated carbamide is made up of urea, urease inhibitors, nitrification inhibitor and organic coated material.Wherein organic coated material is ROHM or urethane resin, even Plastic Resins such as urethane are buried underground, also needs to decompose decades.Therefore, in this tea tree control release composite fertilizer special, organic coated material usage is many, then is difficult to effectively discharge inner fertilizer, even causes the white pollution of Plastic Resin; And organic coated material usage is few, and soluble componentss such as the urea of infiltration are many, and then urea etc. is met dissolving rapidly behind the water, makes fertiliser granulates form vesicular or disintegration easily, and actual slowly-releasing (controlled release) ability is very limited.
And for example, Chinese patent 200710115645 discloses a kind of special controlled release fertilizer for tree plant, wherein still continues above thinking and uses thermoplastic resin, still can't solve white pollution and slowly-releasing (controlled release) hyperenergia or weak excessively problem.Especially the potash fertilizer of this patent, phosphate fertilizer and trace element do not have coated parcel, and only are to mix with thermoplastic resin membrane wrapping urea, and therefore slowly-releasing (controlled release) ability to these several constituents does not almost have.
For this reason; The inventor is through long-term and arduous research, picked out rumen-undegraded fat the existing chemical products as vast as the open sea and come Wrapped fertilizer, and the emission levels in the tea tree release and release control fertilizer of formation is moderate; And this material can degrade at occurring in nature, can not form white pollution.The rumen-undegraded fat powder is used to wrap up the feed of animal edible in the prior art; And because it has the fusing point that exceeds envrionment temperature (this is lower than the intravital problem of animal); And nobody uses it in the feed parcel, but the inventor finds in aqueous physical environment, can discharge with moderate speed.More unexpected is, the inventor finds that this material only has under the condition of mineral manure at parcel, and encapsulation rate is not high, therefore needs more material to wrap up, and causes cost to increase; And when parcel contains the fertilizer of yellow humic acid, only need less material just effectively to seal, reduced cost.
Summary of the invention
The technical problem that the present invention will solve is the tea tree fertilizer that provides new, and it can controlled release (that is slowly-releasing) fertilizer.The present invention also provides application and the method for preparation tea tree fertilizer etc. in addition.
Particularly,, the invention provides tea tree fertilizer in first aspect, it comprise outer field integument and fertiliser granulates, it is characterized in that the weight ratio of integument and fertiliser granulates is 0.3~3: 7~12, wherein
Integument is made up of rumen-undegraded fat; With,
Fertiliser granulates comprises nitrogen, phosphorus, potassium, zinc and magnesium.
Preferably in first aspect present invention, the diameter of fertiliser granulates is about 0.3~1.5mm, is preferably 0.4~0.8mm, most preferably is 5mm.
Preferably in first aspect present invention, the weight ratio of integument and fertiliser granulates is 0.5~2: 8~9.5.
Preferably in first aspect present invention, fertiliser granulates comprises urea, diammonium phosphate, Repone K, Zinc vitriol and bitter salt.More preferably wherein, the weight ratio of urea, diammonium phosphate, Repone K, Zinc vitriol and bitter salt is 30~40: 40~60: 8~12: 0.5~1.5: 0.5~1.5.
Preferably in first aspect present invention, fertiliser granulates also comprises yellow humic acid.More preferably wherein, the weight ratio of urea, diammonium phosphate, Repone K, Zinc vitriol, bitter salt and yellow humic acid is 23~33: 30~50: 6~10: 0.5~1.5: 0.5~1.5: 15~25.
Preferably in first aspect present invention, rumen-undegraded fat is hundred HTL316 of Canon.
In second aspect, the invention provides rumen-undegraded fat in preparation tea tree Application in Fertilizer.More preferably wherein, tea tree fertilizer is the tea tree release and release control fertilizer.
Preferably in second aspect present invention, tea tree fertilizer is the tea tree fertilizer of first aspect present invention.
In the third aspect, the invention provides the preparation method of the tea tree fertilizer of first aspect present invention, it comprises:
(1) fusing rumen-undegraded fat; With
(2) rumen-undegraded fat with fusing sprays on the fertiliser granulates surface.
Preferably in third aspect present invention, the diameter of fertiliser granulates is about 0.3~1.5mm, is preferably 0.4~0.8mm, most preferably is 5mm.
The present invention has advantage and effect: elements such as the required nitrogen of growth of tea plant, phosphorus, potassium, zinc and magnesium can be provided, improve the output of tealeaves; Controlled release/slow release fertilizer effectively reduces the turnover rate of fertilizer, improves the utilising efficiency of fertilizer; Controlled release/sustained release rate is moderate and stable, further improves the output of tealeaves; The equal degradable of fertilizer component can not bring white pollution; When using yellow humic acid, not only can increase nutriment in a fertilizer, and can effectively improve encapsulation rate, reduce the consumption of lapping, practice thrift cost.
For the ease of understanding, below will the present invention be described in detail through concrete embodiment.What need particularly point out is that specific examples only is in order to explain, not constitute limitation of the scope of the invention.Obviously those of ordinary skill in the art can explain according to this paper, within the scope of the invention the present invention is made various corrections and change, and these corrections and change are also included in the scope of the present invention.In addition, the present invention has quoted open source literature, and these documents also are in order more clearly to describe the present invention, and their full text content is all included the present invention in and carried out reference, just look like they full text in specification sheets of the present invention repeated description the same excessively.
Embodiment
Following this paper will describe invention through concrete embodiment.As not specializing part, listed method is implemented in the reference that can be quoted according to agronomy that those skilled in the art were familiar with and fertilizer science handbook and this paper.In addition, employed material and facility all can be bought from market among the embodiment.
The parcel of embodiment 1 mineral manure
Get 35 kilograms in urea, 50 kilograms of diammonium phosphate, 10 kilograms in Repone K, 1 kilogram of Zinc vitriol, 1 kilogram of bitter salt; After mixing, add 3 kg of water then, mix the back crushing screening and granulate; Process the particle that diameter is about 0.5mm, be no Wrapped fertilizer.
Getting the HTL316 of 0.5 kilogram of hundred Canon (BergaFat) (can available from Nanning city converge new peak herding ltd) melts in 60 ℃ of baking ovens; With fluidized granulation dressing machine it is all evenly sprayed on the particulate surface of 9.5 kilograms of above-mentioned preparations then and form integument, promptly get mineral manure 1; Other gets the HTL316 of 2 kilogram of hundred Canon (BergaFat) (can available from Nanning city converge new peak herding ltd) and in 60 ℃ of baking ovens, melts; With fluidized granulation dressing machine it is all evenly sprayed on the particulate surface of 8 kilograms of above-mentioned preparations then and form integument, promptly get mineral manure 2.
Embodiment 2 contains the parcel of the fertilizer of yellow humic acid
Get 28 kilograms of ammonium chlorides, 40 kilograms of diammonium phosphate, 8 kilograms in Repone K, 1 kilogram of Zinc vitriol, 1 kilogram of bitter salt; After mixing; Add 20 kilograms of yellow humic acids and 2 kg of water then, mix the back crushing screening and granulate, process the particle that diameter is about 0.5mm.
Getting the HTL316 of 0.5 kilogram of hundred Canon (BergaFat) (can available from Nanning city converge new peak herding ltd) melts in 60 ℃ of baking ovens; With fluidized granulation dressing machine it is all evenly sprayed on the particulate surface of 9.5 kilograms of above-mentioned preparations then and form integument, promptly get the fertilizer that contains yellow humic acid.
The dissulution test of embodiment 3 Wrapped fertilizers
Get mineral manure 1, the mineral manure 2 of embodiment 1 and 2 preparations and contain the fertilizer of yellow humic acid; And get the no Wrapped fertilizer of embodiment 1 preparation and with the fertilizer of urethane resin parcel as contrast; Be immersed in the clear water; Detect fertilizer solubility rate wherein at the different time water sampling, the result is as shown in the table:
No Wrapped fertilizer is all dissolvings at once almost, show to have slow releasing function; With the fertilizer of urethane parcel except the fertiliser granulates that do not have environmental sealing (sealing) in initial dissolving, disengage fertilizer thereafter seldom again, dissolution efficiency is too low; The encapsulation rate of mineral manure 1 is very low, causes a large amount of fertilizer just dissolving at first, but can continue to disengage the fertilizer of sealing thereafter; Mineral manure 2 is higher with the encapsulation rate of the fertilizer that contains yellow humic acid, and the fertilizer that major part is sealed continues to disengage in the back.
Embodiment 4 tea tree fertilization effects
The inventor entrusts Guilin Inst. of Tea Science, Guangxi Prov.; The fertilizer that contains yellow humic acid with embodiment 2 preparations carries out manurial experiment to tea tree; Use once before only sprouting in the spring every year; No Wrapped fertilizer with embodiment 1 preparation is contrast simultaneously, plants after 1 year, and experimental group is higher by 12.8% than the tealeaves mean yield of control group.