CN102604558A - Heat-resistant laminated-positioning electronic adhesive tape for solar cell and preparation method thereof - Google Patents

Heat-resistant laminated-positioning electronic adhesive tape for solar cell and preparation method thereof Download PDF

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Publication number
CN102604558A
CN102604558A CN2012100858884A CN201210085888A CN102604558A CN 102604558 A CN102604558 A CN 102604558A CN 2012100858884 A CN2012100858884 A CN 2012100858884A CN 201210085888 A CN201210085888 A CN 201210085888A CN 102604558 A CN102604558 A CN 102604558A
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China
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adhesive tape
weight part
temperature
compression set
solar batteries
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CN2012100858884A
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CN102604558B (en
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黄时将
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WENZHOU NAIDE ADHESIVE CO., LTD.
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SHANGHAI XINGUAN RUBBER MATERIAL CO Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention provides a heat-resistant laminated-positioning electronic adhesive tape for a solar cell and a preparation method thereof; the adhesive tape disclosed by The invention comprises a gluing layer and a matrix layer, wherein an adhesive layer is coated on the face of the matrix layer; the adhesive layer is one of epoxy resin glue, polyamide glue, organic silica gel or acrylic acid resin glue; and the matrix layer is modified polyethylene (PE) including 50-100 parts of PE, 0-50 parts of polyamide (PA), 1-20 parts of uvioresistant auxiliary titanium dioxide, and 0.1-10 parts of flexibilizer (part by weight). According to the invention, the heat-resistant laminated-positioning electronic adhesive tape has good weather resistance, ultraviolet retardance and electric insulativity.

Description

A kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape and preparation method thereof
Technical field
The present invention relates to a kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, particularly adopt modified PE to do base layer and can have good weathering resistance, ultraviolet block and electrical insulating property.
Background technology
Along with Nonrenewable energy resources such as coal, oil signal for help repeatedly, energy problem becomes the bottleneck of restriction international community Economic development day by day, and more and more countries comes into effect " sunlight program ", develops solar energy resources, seeks the new power of Economic development.In order to make solar cell obtain abundant effective application, the laminating technology of assembly plays critical effect, and this just requires battery sheet localized electron adhesive tape wherein will have good weathering resistance, ultraviolet block and electrical insulating property.In the prior art, the adhesive tape kind of various uses is more, is used for solar battery product and makes also having much of field.The adhesive tape of in the solar cell manufacturing, using; Number average requires insulation and tolerance certain temperature simultaneously mostly; It is required higher than normal tape; Consider the generating efficiency of battery, this will have certain Ginkgo Biloba Leaf Extract sexual function by adhesive tape, so the production of adhesive tape is had higher requirement.
Vilaterm (PE) is to be the polymkeric substance that monomer polymerization forms with ethene, is an important kind in the general-purpose plastics.In five big general-purpose plastics of polymer industry, the Vilaterm industrial development has long history, also is one of kind with fastest developing speed.Compare with other interchangeable heat thermoplastic plastic, Vilaterm has the advantages such as chemical proofing that cost is low, density is little, electrical insulating property is good and good, but also there are shortcomings such as high thermal resistance difference and ultraviolet block difference in Vilaterm.Therefore, if the Vilaterm that cost is low is applied in the electronics adhesive tape of used for solar batteries high-temperature-resistant layer compression set position, then require it to have good temperature resistance and uviolresistance.Therefore the present invention has carried out modification to PE, satisfies solar cell to the adhesive tape requirement.
Summary of the invention
One object of the present invention is to provide the used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape of at least one technical problem in a kind of can the solving the problems of the technologies described above.
Another object of the present invention is to provide a kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape that can shielding of ultraviolet and preparation method thereof.
Another purpose of the present invention is to provide a kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape with excellent electric insulating and high thermal resistance and preparation method thereof.
A purpose more of the present invention is to provide a kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape with good temperature resistance and preparation method thereof.
For realizing above-mentioned purpose, technical scheme of the present invention is.
A kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, it is characterized in that: this adhesive tape comprises adhesive layer and base layer, applies the gluing layer on the matrix aspect.
Described used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape is characterized in that: the gluing layer is a kind of in epoxy resin glue, polymeric amide glue, organic silica gel or the acrylic size.
Described used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, it is characterized in that: said gluing layer, its thickness are 2-20um.
Described used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape; It is characterized in that: base layer is modified poly ethylene (PE) film, comprises the polyamide (PA) of 50-100 weight part PE, 0-50 weight part, the Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide of 1-20 weight part, the toughner EVA of 0.1-10 weight part.
Described used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, it is characterized in that: described base layer, its thickness are 20-100um.
Described used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, it is characterized in that: described modified PE, the median size of Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide is 5-500nm.
The preparation method of a kind of aforesaid used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, it is characterized in that: it comprises the steps:
Adopt melt-blending process with the polyamide (PA) of 50-100 weight part PE, 0-50 weight part, the Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide of 1-20 weight part, the toughner EVA blend of 0.1-10 weight part; Thereby obtain the modified PE base layer; With a kind of being coated on the base layer in epoxy resin glue, polymeric amide glue, organic silica gel or the acrylic size, make used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape again through 50-80 ℃ of dry 5-30min.
Described method is characterized in that: the blend step of modified PE base layer comprises:
Under 100-250 ℃ temperature; With the polyamide (PA) mixing of 50-100 weight part PE and 0-50 weight part 10-50 minute; Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide with the 1-20 weight part adds wherein and mixed 5-25 minute then, and the toughner EVA with the 0.1-10 weight part adds wherein and mixed 20-60 minute afterwards.
Described method is characterized in that: the step of coating comprises: with coating machine with a kind of being coated on the base layer in epoxy resin glue, polymeric amide glue or the acrylic size; Use the drier adhesive tape again, temperature is 50-80 ℃, and the time is 5-30min.
Description of drawings
Fig. 1 is the schematic cross sectional views of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape.
Embodiment
Below in conjunction with accompanying drawing and embodiment the present invention is described further.
Embodiment: as shown in Figure 1, a kind of used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape that adopts the present invention to make comprises gluing layer 1 and base layer 2, and gluing layer 1 is attached on the base layer 2.
Said base layer is a modified PE, comprises the polyamide (PA) of 80 weight part PE, 12 weight parts, the Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide of 5 weight parts, the toughner EVA of 3 weight parts.Can adopt known equipment, for example general stirrer, twin screw extruder, single screw extrusion machine, mill, Banbury mixer etc. are carried out this melt blending.
On modified PE matrix aspect, coating gluing layer is high temperature resistant autohension silica gel.Adopt coating machine that high temperature resistant autohension silica gel is coated on the modified PE matrix aspect, thickness is 6um.Under 50-80 ℃, use drier 10min, make used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape.
Below embodiment is further explained.
The PE low price has good resistance to low temperature (minimum use temperature can reach-70~-100 ℃), and chemicalstability is good, and water-absorbent is little, and electrical insulation capability is good.PA has very high physical strength, and softening temperature is high, and heat-resisting, coefficient of friction is low, and electrical insulating property is good, and self-extinguishing is arranged, good weatherability.Through with PE and PA blend, be expected to obtain the intermingling material of good combination property.When just PE and PA blend, can select appropriate compatilizer (or being called solubilizing agent) as required for use.
In an embodiment, the median size of choosing the Ginkgo Biloba Leaf Extract auxiliary agent is 200nm.If the median size of Ginkgo Biloba Leaf Extract auxiliary agent is less than 5nm, then at first raw materials cost is high, and the industriallization possibility diminishes, and secondly is to be unfavorable for Ginkgo Biloba Leaf Extract auxiliary agent and other component blend because of nanoparticle itself takes place to reunite.If the median size of Ginkgo Biloba Leaf Extract auxiliary agent, then is unfavorable for Ginkgo Biloba Leaf Extract auxiliary agent and other components greater than 500nm and mixes have big PM for particulate matter or block to produce easily.
When the content of Ginkgo Biloba Leaf Extract auxiliary agent when being less than 1 weight part, the rapid variation of Ginkgo Biloba Leaf Extract effect.If the content of Ginkgo Biloba Leaf Extract auxiliary agent is more than 20 weight parts, then the Ginkgo Biloba Leaf Extract effect can not increase because content increases, and therefore there is no need to make the content of Ginkgo Biloba Leaf Extract auxiliary agent to surpass 20 weight parts.The weight part of therefore selected Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide remains between 1-20 part.
In an embodiment, when toughner ethylene-vinyl acetate (MAH-g-EVA) contain quantity not sufficient 0.1 weight part, then do not have toughness reinforcing effect; If the content of toughner surpasses 10 weight parts, then the toughness of polypropene composition is strong excessively, does not meet the products production performance demands.In a preferred embodiment, comprise that weight part is the toughner of 1-15.
Because comprise the Ginkgo Biloba Leaf Extract auxiliary agent according to used for solar batteries high-temperature-resistant layer compression set of the present invention position electronics adhesive tape; So in the time will comprising this used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape and be used in the solar cell device; These parts stop back (for example reflection) part ultraviolet ray; This part ultraviolet ray can be used for the opto-electronic conversion of the battery sheet in the solar cell device, thereby has improved photoelectric transformation efficiency.
Like the method for above-mentioned embodiment, employing and the same or analogous structure of this embodiment or the used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape (of summary of the invention) that material obtained are all within protection domain of the present invention.

Claims (9)

1. used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape, it is characterized in that: this adhesive tape comprises adhesive layer and base layer, applies the gluing layer on the matrix aspect.
2. used for solar batteries high-temperature-resistant layer compression set according to claim 1 position electronics adhesive tape is characterized in that: the gluing layer is a kind of in epoxy resin glue, polymeric amide glue, organic silica gel or the acrylic size.
3. used for solar batteries high-temperature-resistant layer compression set according to claim 2 position electronics adhesive tape, it is characterized in that: said gluing layer, its thickness are 2-20um.
4. described used for solar batteries high-temperature-resistant layer compression set according to claim 1 position electronics adhesive tape; It is characterized in that: base layer is the modified poly ethylene film, comprises the polymeric amide of 50-100 weight part PE, 0-50 weight part, the Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide of 1-20 weight part, the toughner EVA of 0.1-10 weight part.
5. used for solar batteries high-temperature-resistant layer compression set according to claim 4 position electronics adhesive tape, it is characterized in that: described base layer, its thickness are 20-100um.
6. used for solar batteries high-temperature-resistant layer compression set according to claim 4 position electronics adhesive tape, it is characterized in that: described modified PE, the median size of Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide is 5-500nm.
7. preparation method like claim 1 or 2 or 3 or 4 or 5 or 6 described used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tapes, it is characterized in that: it comprises the steps:
Adopt melt-blending process with the polyamide (PA) of 50-100 weight part PE, 0-50 weight part, the Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide of 1-20 weight part, the toughner EVA blend of 0.1-10 weight part; Thereby obtain the modified PE base layer; With a kind of being coated on the base layer in epoxy resin glue, polymeric amide glue, organic silica gel or the acrylic size, make used for solar batteries high-temperature-resistant layer compression set position electronics adhesive tape again through 50-80 ℃ of dry 5-30min.
8. method according to claim 7 is characterized in that: the blend step of modified PE base layer comprises:
Under 100-250 ℃ temperature; With the polyamide (PA) mixing of 50-100 weight part PE and 0-50 weight part 10-50 minute; Ginkgo Biloba Leaf Extract auxiliary agent titanium oxide with the 1-20 weight part adds wherein and mixed 5-25 minute then, and the toughner EVA with the 0.1-10 weight part adds wherein and mixed 20-60 minute afterwards.
9. method according to claim 7 is characterized in that: the step of coating comprises: with coating machine with a kind of being coated on the base layer in epoxy resin glue, polymeric amide glue or the acrylic size; Use the drier adhesive tape again, temperature is 50-80 ℃, and the time is 5-30min.
CN201210085888.4A 2012-03-28 2012-03-28 Heat-resistant laminated-positioning electronic adhesive tape for solar cell and preparation method thereof Expired - Fee Related CN102604558B (en)

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CN201210085888.4A CN102604558B (en) 2012-03-28 2012-03-28 Heat-resistant laminated-positioning electronic adhesive tape for solar cell and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014173018A1 (en) * 2013-04-22 2014-10-30 珠海兴业绿色建筑科技有限公司 High-performance insulating hybrid photovoltaic/thermal solar panel core and fabrication method thereof
WO2016086466A1 (en) * 2014-12-04 2016-06-09 友达光电股份有限公司 Solar module and adhesive tape thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6472015B1 (en) * 1996-04-26 2002-10-29 Sentinal Products Corp. Cross-linked polyolefin tape
EP2012364A1 (en) * 2006-04-26 2009-01-07 Hitachi Chemical Company, Ltd. Adhesive tape and solar cell module using the same
CN102051139A (en) * 2010-12-21 2011-05-11 浙江工业大学 Polyethylene anticorrosion adhesive tape and preparation method thereof
CN102373015A (en) * 2010-08-11 2012-03-14 赵志强 Ethylene vinyl acetate (EVA) adhesive tape

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6472015B1 (en) * 1996-04-26 2002-10-29 Sentinal Products Corp. Cross-linked polyolefin tape
EP2012364A1 (en) * 2006-04-26 2009-01-07 Hitachi Chemical Company, Ltd. Adhesive tape and solar cell module using the same
CN102373015A (en) * 2010-08-11 2012-03-14 赵志强 Ethylene vinyl acetate (EVA) adhesive tape
CN102051139A (en) * 2010-12-21 2011-05-11 浙江工业大学 Polyethylene anticorrosion adhesive tape and preparation method thereof

Non-Patent Citations (2)

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Title
李子东等: "《胶黏剂助剂》", 31 January 2011, 化学工业出版社 *
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014173018A1 (en) * 2013-04-22 2014-10-30 珠海兴业绿色建筑科技有限公司 High-performance insulating hybrid photovoltaic/thermal solar panel core and fabrication method thereof
WO2016086466A1 (en) * 2014-12-04 2016-06-09 友达光电股份有限公司 Solar module and adhesive tape thereof

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