CN102757705A - Waterproof coating - Google Patents
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- CN102757705A CN102757705A CN2011101067876A CN201110106787A CN102757705A CN 102757705 A CN102757705 A CN 102757705A CN 2011101067876 A CN2011101067876 A CN 2011101067876A CN 201110106787 A CN201110106787 A CN 201110106787A CN 102757705 A CN102757705 A CN 102757705A
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Abstract
The invention relates to a method for preparing waterproof coating. The method is characterized by comprising the following steps: performing prepolymerization on 0.001 to 3 mass parts of initiator and 30 to 99.999 mass parts of monomer, adding 0 to 70 mass parts of filler and 0 to 10 parts of crosslinking agent before, after or during prepolymerization, adding 0.0001 to 5 parts of polymerization inhibitor after prepolymerization, and storing; during construction, dividing the products after the prepolymerization into two components, adding 0.1 to 6 mass parts of curing agent into one component and adding 0.1 to 6 mass parts of curing accelerator into the other component; and performing mixed construction on the two components by using a coating roller or a spray gun at the temperature of -10 to +45 DEG C. After coating curing, the waterproof coating has excellent bonding strength with a base material and the product has high tensile strength, high breaking elongation, ageing resistance and excellent chemical stability.
Description
Technical field:
The present invention relates to a kind of waterproof paint, particularly HS for building, snappiness, ageing-resistant waterproof coating such as railway, highway, bridge, terrace.
Background technology:
The cracking of buildings and various structures and seepage almost are big common quality defects of current concrete structure; Also be a difficult problem of the continuous exploratory development of people, this material is one HS, snappiness, high adhesive force, shock resistance to be provided, to resist puncture, ageing-resistant, corrosion-resistant, attrition resistant waterproofing protection film for the building ground.Adaptable across concrete slab, steelwork decking, bridge pier, pipeline, industry ground slab, glass fiber reinforced plastics product etc.
Existing water-proof material, such as materials such as urethane, polyureas, it protects light, tint retention is poor, not ageing-resistant, and material is prone to yellowing, so process dark color or yellow product mostly, should not make light color is product; Another shortcoming of material such as urethane, polyureas is that the isocyanic ester that includes of product etc. has hormesis to human body, and will use the isocyanates reagent of severe toxicity in process of production.The present invention is because main raw material(s) adopts acrylic acid or the like and esters of acrylic acid reagent thereof; Given product good fast light, weathering resistance; Difficult decomposition or flavescence under wind and weather, the UV-irradiation out of doors, rotten; Can keep original gloss and color and luster for a long time, extreme natural environment such as high temperature resistant, low temperature.Because do not use TDI, MDI class reagent commonly used in polyureas, the polyurethane coating in the raw material, polymerization product is the asepsis environment-protecting material.Overcome the inherent defect of materials such as above-mentioned urethane, polyureas.
Also have partial monopoly to adopt esters of acrylic acid to do main raw material, but make emulsion applications mostly, construction curing etc. are all inconvenient.And this patent adopts the mass polymerization mode, pollutes for a short time, and heat energy consumption is few, and the polymerization later stage can rely on polymerization exotherm to keep the carrying out of polyreaction, and speed of response is fast.100% solid content, solvent-free, pollution-free, little to environmental influence, be Green Product.
The present invention also has following major advantage in addition:
Because trade sales coating is coated on inner, external wall, ceiling, ground and other positions of buildings, the mega structure thing is carried out heated baking be difficult to realize and danger close that site operation coating all requires drying and forming-film under the normal temperature usually.The spraying equipment of this product application specialty, easy to use, quick construction, and can in bigger TR, use (10～40 ℃), be adapted at most of weather use down in the vast territory of China.
Because starting material are petrochemicals, material source is wide, aboundresources, and price is comparatively cheap.
This product is rich in snappiness, can adapt to building structure vibrations and displacement to a certain degree, can form the sealing ply of one deck homogeneous and waterproof, seamless one, and do not form stress point.
This product has good cohesive strength, all has good adhesive property with timber, metallic substance, ceramic tile, various stone material, cement etc., and can seal loose ground, special-shaped part and the seam of precoating.
This product has good chemical stability, the contamination and the corrosion of chemical such as acid-and base-resisting, salt, grease, washing composition, and resistance toheat is good.
Summary of the invention:
The present invention proposes a kind of waterproof paint, advantage such as that the product of preparation has is ageing-resistant, corrosion-resistant, HS, H.T..
A kind of waterproof paint of the present invention; It is characterized in that: get 0.001～3 part initiator by mass fraction; The monomer of getting 30～99.999 parts carries out prepolymerization, all can add before the prepolymerization, after the prepolymerization or during prepolymerization to add 0.0001～5 part of stopper after 1～70 part of stopping composition, 0.5～10 part of linking agent, the prepolymerization and preserve; During construction above-mentioned prepolymerization after product is divided into two components, adds 0.1～6 part of solidifying agent in the component, another component adds 0.1～6 part curing catalyst; Under-10～+ 45 ℃ of conditions, with brushing cylinder or spray gun with two component mixed constructions.
Initiator can add 0.3～1.5 part, and preferably 0.3～0.8 part, stopping composition can add 5～40 parts, and preferably 25～35 parts, linking agent can add 0.5～5 part, and preferably 2～4 parts,
Said initiator comprises that any one or a few is used with in Diisopropyl azodicarboxylate, ABVN, Lucidol, peroxo-(2-toluyl), hydrogen peroxide, tertbutyl peroxide, isopropyl benzene hydroperoxide, the Lucidol tert-butyl ester, cyclohexanone peroxide, methylethyl ketone peroxide, Potassium Persulphate or the ammonium persulphate.
Said monomer is methylacrylic acid, TEB 3K, Jia Jibingxisuanyizhi, isopropyl methacrylate, NSC 20956, N-Hexyl methacrylate, methylacrylic acid α-ethylhexyl, Jia Jibingxisuanβ-Qiang Yizhi, methylacrylic acid β-hydroxypropyl acrylate.SY-Monomer G; The methylacrylic acid trihydroxymethylpropanyl ester; Methylacrylic acid one condensed ethandiol ester; Vinylformic acid; Methyl acrylate; Ethyl propenoate; Isopropyl acrylate; Bing Xisuandingzhi; NSC 11786; Vinylformic acid α-ethylhexyl; Propenoic acid beta-hydroxy ethyl ester; The propenoic acid beta-hydroxy propyl ester; Glycidyl acrylate; The vinylformic acid trihydroxymethylpropanyl ester; Vinylformic acid one condensed ethandiol ester; The vinylformic acid pentaerythritol triacrylate; Acrylic amide; USAF RH-1; Vinyl cyanide; Vinylbenzene; Vinyl acetate; Maleic acid; Any one or a few is used with in the methylene-succinic acid.Used monomer preferably below monomeric combination:
TEB 3K: 20～50%
Bing Xisuandingzhi: 20～50%
Vinylformic acid: 5～10%
Methacrylic ester butyl ester: 10～30%
Methylacrylic acid α-ethylhexyl: 5～15%
Three vinylformic acid TriMethylolPropane(TMP)s: 0.5～5%
Said stopping composition is that any one or a few is used with in wilkinite, kaolin, polynite, refractory mortar, white titanium pigment, talcum powder, zinc sulfide white, lime carbonate, WHITE CARBON BLACK, carbon black, the graphite.
Said linking agent is that any one or a few is used with in three vinylformic acid TriMethylolPropane(TMP)s, triallylamine, NSC 20948, cyanacrylate, NSC 20948, the Phthalic acid, diallyl ester.
Said stopper is Resorcinol, MEHQ, tert-butyl catechol, toluhydroquinone, 2-Tert. Butyl Hydroquinone, 2; 5-di-tert-butyl hydroquinone, 4-hydroxyl-2; 2; 6,6-tetramethyl piperidine-1-oxyradical, 1, any one or a few is used with in 1-phenylbenzene-2-trinitrophenyl-hydrazine, the methylene blue.
Said solidifying agent is that any one or a few is used with in Lucidol, peroxo-(2-toluyl), the Lucidol tert-butyl ester.
Said curing catalyst is N, accelerine, and N, the N-dimethyl-p-toluidine, N, N-two (hydroxyethyl) para-totuidine, any one or a few is used with in N-methyl-N-2-hydroxyethyl para-totuidine.
After brushing was solidified, product was rich in snappiness, can adapt to building structure vibrations and displacement to a certain degree; Can form the sealing ply of one deck homogeneous and waterproof; Seamless one, and do not form stress point, this product has good cohesive strength; All have good adhesive property with base materials such as timber, metallic substance, ceramic tile, various stone material, cement, and can seal loose ground, special-shaped part and the seam of precoating.This product has good chemical stability, the contamination and the corrosion of chemical such as acid-and base-resisting, salt, grease, washing composition, and resistance toheat is good.Have good tensile strength and elongation at break, have good cohesive strength with concrete floor
Therefore, can be widely used in industries such as railway, highway, bridge, tunnel, dam, terrace as waterproof paint, also can be used for purposes such as terrace, colour cement application separately, use the present invention to be with a wide range of applications.
Embodiment:
Below in conjunction with case study on implementation embodiment of the present invention is described.
Embodiment 1.
Take by weighing the 0.001Kg Lucidol, add vinylformic acid and esters monomer thereof: Bing Xisuandingzhi 20Kg, Hydroxyethyl acrylate 5Kg, vinylformic acid 10Kg, at 65 ℃, prepolymerization is 3 hours under the nitrogen protection; With TEB 3K 10Kg, NSC 20956 10Kg, methylacrylic acid 2Kg joins in the above-mentioned system, at 85 ℃ again; Prepolymerization under the nitrogen protection, range estimation viscosity is when viscosity is felt similar normal temperature glycerine viscosity; Reduce temperature of reaction to 75 ℃, and extract small amount of sample at any time and detect prepolymer viscosity, with the prepolymer viscosity controller between 100～600PaS; Then continue polymerization inadequately like viscosity, suitable up to viscosity.In order to reduce initiator content in the prepolymer, temperature is risen to 100 ℃ fast, be incubated 2 minutes; So that initiator decomposes fast, this moment, reaction was comparatively violent, should use the water coolant cool quickly fast; Add monomers methyl methacrylate 10Kg, vinylformic acid pentaerythritol triacrylate 2Kg, WHITE CARBON BLACK 5Kg, white titanium pigment 5Kg auxiliary temperature-reducing simultaneously, when system temperature is reduced to below 40 ℃, in above-mentioned prepolymer, add the 0.003Kg hydroquinone of polymerization retarder and preserve; During construction above-mentioned product is divided into two parts of A, B; Add the 0.1Kg Lucidol among the A and stir, add 0.1KgN, accelerine among the B.A, two component manual works of B are stirred, and under the room temperature, change with temperature variation set time on the cement glass wall with being applied to.Sample after the curing is through detecting, with the pull strength of glass metope be 4MPa, tensile strength is 7MPa, elongation at break is 238%.
Embodiment 2.
Take by weighing the 3Kg Diisopropyl azodicarboxylate, add monomer: methylene-succinic acid 5Kg, TEB 3K 15Kg, methylacrylic acid one condensed ethandiol ester 5Kg, vinylformic acid α-ethylhexyl 5Kg, propenoic acid beta-hydroxy ethyl ester 2Kg, vinylbenzene 10Kg, prepolymerization is after 5 hours under 65 ℃ of nitrogen protections; In above-mentioned prepolymer, add filler: white titanium pigment 20Kg, kaolin 20Kg, polynite 20Kg, WHITE CARBON BLACK 10Kg, again system is continued down polymerizations about 2 hours at 70 ℃, the polymerization time view volume is a viscosity and deciding; Hierarchy of control viscosity between 300～1000PaS, reach requirement viscosity after, add 3Kg linking agent Phthalic acid, diallyl ester; Naturally cooling is cooled to below 50 ℃; Shredder ground after 1 hour, added 5Kg stopper toluhydroquinone then and preserved, and during construction above-mentioned product was divided into two parts of A, B; Adding the 6Kg Lucidol tert-butyl ester among the A stirs; Add 6Kg N-methyl-N-2-hydroxyethyl para-totuidine among the B, A, two component manual works of B are stirred, under the room temperature; Solidify to ceramic tile with Cylinder coating brush, change with temperature variation set time.Sample after the curing is through detecting, and tensile strength is 6MPa, and elongation at break is 135%.
Embodiment 3.
Take by weighing filler: talcum powder 10Kg, nano-calcium carbonate 20Kg, organo montmorillonite 5Kg, be warming up to 90 ℃ and vacuumized 2 hours, to remove the moisture in the filler, add monomer then: TEB 3K 40Kg; Vinyl cyanide 30Kg, methylacrylic acid 2Kg, acrylic amide 5Kg, this moment, temperature should be reduced to below 50 ℃; Under this lesser temps, add initiator peroxo-(2-toluyl) 0.8Kg, be warming up to 95 ℃ again, quick prepolymerization is 1 hour under the nitrogen protection; System viscosity is reduced to 75 ℃ with temperature of reaction, to avoid the generation of implode after increasing; Low temperature can carry out polymerization with the long time down, and system viscosity is steadily increased, and hierarchy of control viscosity is between 300～1000PaS; After viscosity meets the requirements, be cooled to below 40 ℃ stopped reaction; In prepolymer, add stopper tert-butyl catechol 0.2Kg and preserve, during construction above-mentioned product is divided into two parts of A, B, add 3Kg peroxo-(2-toluyl) among the A; Add 3Kg N among the B, N-dimethyl-p-toluidine and 10Kg linking agent three vinylformic acid TriMethylolPropane(TMP)s spray on the cement concrete ground with pair component spray guns and to solidify.Sample after the curing is through detecting, with the pull strength of concrete floor be 6MPa, tensile strength is 15MPa, elongation at break is 175%.
Claims (9)
1. waterproof paint; It is characterized in that adopting following method to be prepared from: by mass fraction get 0.001～3 part initiator, 30～99.999 parts monomer carries out prepolymerization, all can add 0～70 part of stopping composition, 0～10 part of linking agent during the forward and backward or prepolymerization of prepolymerization; Adding 0.0001～5 part of stopper after the prepolymerization preserves; During construction above-mentioned prepolymerization after product is divided into two components, adds 0.1～6 part of solidifying agent in the component, another component adds 0.1～6 part curing catalyst, prepares this waterproof paint.
2. waterproof paint according to claim 1; Be characterised in that said initiator comprises that any one or a few is used with in Diisopropyl azodicarboxylate, ABVN, Lucidol, peroxo-(2-toluyl), hydrogen peroxide, tertbutyl peroxide, isopropyl benzene hydroperoxide, the Lucidol tert-butyl ester, cyclohexanone peroxide, methylethyl ketone peroxide, Potassium Persulphate or the ammonium persulphate; Reduce to below 50 ℃ in temperature during prepolymerization and add initiator, the quick prepolymerization under nitrogen protection that heats up is after system viscosity increases; Temperature of reaction is reduced to below 80 ℃; To avoid the generation of implode, hierarchy of control viscosity is between 300-1000PaS, after viscosity meets the requirements; Be cooled to below 40 ℃ stopped reaction.
3. waterproof paint according to claim 1 is characterised in that said monomer is that any one or a few is used with in methylacrylic acid, TEB 3K, Jia Jibingxisuanyizhi, isopropyl methacrylate, NSC 20956, Propenoic acid, 2-methyl, isobutyl ester, N-Hexyl methacrylate, methylacrylic acid α-ethylhexyl, Jia Jibingxisuanβ-Qiang Yizhi, methylacrylic acid β-hydroxypropyl acrylate, SY-Monomer G, methylacrylic acid trihydroxymethylpropanyl ester, methylacrylic acid one condensed ethandiol ester, vinylformic acid, methyl acrylate, ethyl propenoate, isopropyl acrylate, Bing Xisuandingzhi, NSC 11786, vinylformic acid α-ethylhexyl, propenoic acid beta-hydroxy ethyl ester, propenoic acid beta-hydroxy propyl ester, glycidyl acrylate, vinylformic acid trihydroxymethylpropanyl ester, vinylformic acid one condensed ethandiol ester, vinylformic acid pentaerythritol triacrylate, acrylic amide, USAF RH-1, vinyl cyanide, vinylbenzene, vinyl acetate between to for plastic, maleic acid or the methylene-succinic acid.
4. waterproof paint according to claim 1 is characterised in that said monomer is following monomeric combination:
TEB 3K: 20～50%
Bing Xisuandingzhi: 20～50%
Vinylformic acid: 5～10%
NSC 20956: 10～30%
Methylacrylic acid α-ethylhexyl: 5～15%
Three vinylformic acid TriMethylolPropane(TMP)s: 0.5～5%
5. waterproof paint according to claim 1 is characterised in that said stopping composition is that any one or a few is used with in wilkinite, kaolin, polynite, refractory mortar, white titanium pigment, talcum powder, zinc sulfide white, lime carbonate, WHITE CARBON BLACK, carbon black or the graphite.
6. waterproof paint according to claim 1 is characterised in that said linking agent is that any one or a few is used with in three vinylformic acid TriMethylolPropane(TMP)s, triallylamine, NSC 20948, cyanacrylate, NSC 20948 or the Phthalic acid, diallyl ester.
7. waterproof paint according to claim 1; Be characterised in that said stopper is Resorcinol, MEHQ, tert-butyl catechol, toluhydroquinone, 2-Tert. Butyl Hydroquinone, 2; 5-di-tert-butyl hydroquinone, 4-hydroxyl-2,2,6; 6-tetramethyl piperidine-1-oxyradical, 1, any one or a few is used with in 1-phenylbenzene-2-trinitrophenyl-hydrazine or the methylene blue.
8. waterproof paint according to claim 1 is characterised in that said solidifying agent is that any one or a few is used with in Lucidol, peroxo-(2-toluyl) or the Lucidol tert-butyl ester.
9. waterproof paint according to claim 1 is characterised in that said curing catalyst is N, accelerine,, N, the N-dimethyl-p-toluidine, N, any one or a few is used with in N-two (hydroxyethyl) para-totuidine or N-methyl-N-2-hydroxyethyl para-totuidine.
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| CN201110106787.6A CN102757705B (en) | 2011-04-27 | 2011-04-27 | Waterproof coating |
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| CN201110106787.6A CN102757705B (en) | 2011-04-27 | 2011-04-27 | Waterproof coating |
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| CN102757705B CN102757705B (en) | 2015-03-25 |
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