CN102965005A - Aromatic-hydrocarbon-free anticorrosion scheme for metal structure - Google Patents
Aromatic-hydrocarbon-free anticorrosion scheme for metal structure Download PDFInfo
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- CN102965005A CN102965005A CN2012105380188A CN201210538018A CN102965005A CN 102965005 A CN102965005 A CN 102965005A CN 2012105380188 A CN2012105380188 A CN 2012105380188A CN 201210538018 A CN201210538018 A CN 201210538018A CN 102965005 A CN102965005 A CN 102965005A
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- coating method
- protective system
- described protective
- coating
- substrate surface
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Abstract
The invention discloses an aromatic-hydrocarbon-free anticorrosion scheme for a metal structure, which comprises the following steps: mixing siloxane, solvent, silicon dioxide particle, rare-earth compound, deionized water, catalyst, carbon fiber, polyimide and other components, aging, filtering the aged mixture, and applying the mixture on a substrate surface by spraying, brushing or impregnation to form a coating on the substrate surface after deposition, thereby implementing surface anticorrosion treatment.
Description
Technical field
The present invention relates to a kind of protective system coating method, relate in particular to a kind of metal structure surface that is applicable to, have the coating method of the environmental protection coating material of excellent gloss and mechanical and physical performance and aromatic free solvent.
Background technology
In modern industry and daily life, corrosion of metal is seen everywhere, and the destruction of the forms such as crevice corrosion, stress corrosion and corrosion fatigue that especially occur in the storage vessel of a fuel oil dangerization product is caused great potential safety hazard for people's lives.
The metal protection method that adopts at present can roughly be divided three classes: a class is to carry out anodic oxidation treatment, namely form the anode oxide film of one deck tens micron thickness in the metallic surface, but because the anode oxidation process power consumption is large, and electrolyte solution is seriously polluted, be difficult to process, use its application to be restricted; Equations of The Second Kind is chemical conversion film, being about to metal parts is immersed in the solution of definite composition, rely at a certain temperature chemical reaction to form one deck chemical conversion film, now most widely used is the oxidation of chromic salt chemistry, but chromic salt is a kind of carcinogenic toxicant, and the world environments protective tissue has proposed restriction and used chromic salt and other to contain chromate compound; The 3rd class is organic coating, namely applies one deck organic coating in the metallic surface, with outward appearance and the physical and chemical performance that improves metal.People begin rare earth element is used in the aseptic technic of metallic surface in recent years.
The rare-earth conversion coatings film technique develops into today, and people have carried out a large amount of improvement to various film-forming process, and the performance of film also is improved.At present the rare-earth conversion coatings technology mainly is immersion treatment, and this technological operation is simple, be easy to safeguard; But its drawback is that the long period of soaking process treatment time is oversize, and formed rete is thinner and relatively poor with the sticking power of base material.Find through long-term exploratory development, add strong oxidizer in the soaking solution, such as H
2O
2, KMnO
4, (NH
4)
2S
2O
8Etc. strong oxide compound, rate of film build is improved greatly, the treatment time shortens dramatically, and the treatment soln temperature is not high yet simultaneously, can at room temperature use.But because the existence of strong oxidizer is so that the less stable for the treatment of process.
The problem that exists in order to solve the rare-earth conversion coatings treatment process, the present invention proposes a kind of improved protective system coating method.This method anticorrosion with low cost, remarkable in economical benefits can be carried out normal temperature and be spread, and coating processes is simple, and solution is environment friendly and pollution-free.
Summary of the invention
The objective of the invention is for the deficiencies in the prior art part, provide a kind of coating method of environment friendly corrosion protection coating, in order to solve the protection against corrosion difficult problem of the surfaces externally and internally applications such as steel, aluminium, especially aluminium alloy, and coating aromatic free solvent, do not contain strong oxidizer, without poisonous pigment, be fit to various constructional methods, application is not subject to seasonal restrictions, and construction technology is simple and convenient, and technical costs is cheap, good environmental protection.
The present invention is achieved by the following technical solutions:
(1) prepare following component (mass parts):
A aminopropyl triethoxysilane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 1-5 of d cerium;
E deionized water 5-25;
F acetic acid 4-6;
G carbon fiber 5-7;
H polyimide 1-3;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment
The present invention relates to a kind of metal construction without the anticorrosion scheme of aromatic hydrocarbons, after being mixed, the various components of protective system carry out maturation process, again the mixture after the slaking is filtered, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Described SiO
2The particle diameter of particle is the 50-100 nanometer.
Described maturation process is to leave standstill at normal temperatures 50-60 hour.
Described base material is steel or aluminium, preferred aluminium alloy.
Heat in the deposition process after spraying, brushing or dipping, Heating temperature is to heat 1 minute to 1 hour under 50 ℃ to the 150 ℃ temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush forms coating at substrate surface.
Protective system coating method disclosed by the invention is simple, convenient, quick, reliable, and raw material is cheap, this method can be simply in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of substrate material, substantially need not to carry out other adjustment on the equipment, is the Eco-power production technique of a kind of height.
The below elaborates with embodiment to the present invention, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) prepare following component (mass parts):
A aminopropyl triethoxysilane 1;
B propyl alcohol 40;
C SiO
2Particle 1;
The oxide compound 1 of d cerium;
E deionized water 5;
F acetic acid 4;
G carbon fiber 5;
H polyimide 1;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment 2
(1) prepare following component (mass parts):
A aminopropyl triethoxysilane 10;
B propyl alcohol 60;
C SiO
2Particle 5;
The oxide compound 5 of d cerium;
E deionized water 25;
F acetic acid 6;
G carbon fiber 7;
H polyimide 3;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment 3
(1) prepare following component (mass parts):
A aminopropyl triethoxysilane 5;
B propyl alcohol 50;
C SiO
2Particle 3;
The oxide compound 3 of d cerium;
E deionized water 15;
F acetic acid 5;
G carbon fiber 6;
H polyimide 2;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Claims (9)
1. a metal construction comprises without the anticorrosion scheme of aromatic hydrocarbons:
(1) prepare following component (mass parts):
A aminopropyl triethoxysilane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 1-5 of d cerium;
E deionized water 5-25;
F acetic acid 4-6;
G carbon fiber 5-7;
H polyimide 1-3;
(2) with carrying out maturation process after the said components mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
2. the coating method of described protective system according to claim 1 is characterized in that described SiO
2The particle diameter of particle is the 50-100 nanometer.
3. the coating method of described protective system according to claim 1 is characterized in that described maturation process is to leave standstill at normal temperatures 50-60 hour.
4. the coating method of described protective system according to claim 1 is characterized in that described base material is steel or aluminium.
5. the coating method of described protective system according to claim 1 is characterized in that described base material is aluminium alloy.
6. the coating method of described protective system according to claim 1 is characterized in that heat, Heating temperature is 50 ℃ to 150 ℃, 1 minute to 1 hour heat-up time in described deposition process.
7. the coating method of described protective system according to claim 1 is characterized in that described coat-thickness is 1 micron to 10 microns.
8. the coating method of described protective system according to claim 7 is characterized in that described coat-thickness is 1 micron to 5 microns.
9. the coating method of described protective system according to claim 1 is characterized in that, adopts spraying in the described step (2) or the method for brushing forms coating at substrate surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105380188A CN102965005A (en) | 2012-12-13 | 2012-12-13 | Aromatic-hydrocarbon-free anticorrosion scheme for metal structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105380188A CN102965005A (en) | 2012-12-13 | 2012-12-13 | Aromatic-hydrocarbon-free anticorrosion scheme for metal structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102965005A true CN102965005A (en) | 2013-03-13 |
Family
ID=47795448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105380188A Pending CN102965005A (en) | 2012-12-13 | 2012-12-13 | Aromatic-hydrocarbon-free anticorrosion scheme for metal structure |
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| CN (1) | CN102965005A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107779082A (en) * | 2017-10-30 | 2018-03-09 | 四川行之智汇知识产权运营有限公司 | A kind of rare earth preservative |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5750197A (en) * | 1997-01-09 | 1998-05-12 | The University Of Cincinnati | Method of preventing corrosion of metals using silanes |
| CN101717930A (en) * | 2009-12-25 | 2010-06-02 | 华烁科技股份有限公司 | Environment-friendly nano water-based silane treatment agent capable of improving anti-corrosion performance of metal surface |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
| US20120204762A1 (en) * | 2009-08-11 | 2012-08-16 | Evonik Degussa Gmbh | Aqueous silane systems for bare corrosion protection and corrosion protection of metals |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for hot forming and process for the production thereof |
-
2012
- 2012-12-13 CN CN2012105380188A patent/CN102965005A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5750197A (en) * | 1997-01-09 | 1998-05-12 | The University Of Cincinnati | Method of preventing corrosion of metals using silanes |
| US20120204762A1 (en) * | 2009-08-11 | 2012-08-16 | Evonik Degussa Gmbh | Aqueous silane systems for bare corrosion protection and corrosion protection of metals |
| CN101717930A (en) * | 2009-12-25 | 2010-06-02 | 华烁科技股份有限公司 | Environment-friendly nano water-based silane treatment agent capable of improving anti-corrosion performance of metal surface |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for hot forming and process for the production thereof |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107779082A (en) * | 2017-10-30 | 2018-03-09 | 四川行之智汇知识产权运营有限公司 | A kind of rare earth preservative |
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Application publication date: 20130313 |