CN102975415B - High-transparency energy-saving door/window base material with high oxidation resistance - Google Patents
High-transparency energy-saving door/window base material with high oxidation resistance Download PDFInfo
- Publication number
- CN102975415B CN102975415B CN201210516685.6A CN201210516685A CN102975415B CN 102975415 B CN102975415 B CN 102975415B CN 201210516685 A CN201210516685 A CN 201210516685A CN 102975415 B CN102975415 B CN 102975415B
- Authority
- CN
- China
- Prior art keywords
- layer
- base material
- window base
- saving door
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a high-transparency energy-saving door/window base material with high oxidation resistance. The high-transparency energy-saving door/window base material comprises a base plate, and is characterized in that the upper surface of the base plate is sequentially provided with a Bi2O3 refracting layer, a CrNx barrier layer, a ZrO anti-oxidation layer, a radiation reduction Ag-coated layer, a (CrNi)NxOy film layer and a SnO2 protective layer from bottom to top. The high-transparency energy-saving door/window base material has the advantages of high light transmittance and high oxidation resistance.
Description
Technical field:
The present invention relates to a kind of saturating energy saving door and window base material of height of high antioxidant.
Background technology:
Existing door and window base material, be especially coated with the transparent doors window base material of functional film layer, its light transmittance is lower, and meanwhile, its non-oxidizability is poor, causes base material cannot long storage time.Therefore be necessary to make improvements existing product, to improve its light transmittance and non-oxidizability.
Summary of the invention:
The object of the present invention is to provide the saturating energy saving door and window base material of a kind of height of high antioxidant, it has higher light transmittance and stronger non-oxidizability.
The saturating energy saving door and window base material of height of high antioxidant, comprises substrate, it is characterized in that: the upper surface of described substrate is from bottom to top provided with a Bi successively
2o
3refracting layer, a CrN
xradiation plating Ag layer, one (CrNi) N fall in barrier layer, a ZrO anti oxidation layer,
xo
yrete and a SnO
2protective layer.
The present invention improves by following scheme:
Bi described above
2o
3the thickness of refracting layer is 15 ~ 25nm, has high refractive index, and its refractive index can reach more than 2.3.
CrN described above
xthe thickness on barrier layer is 0.5 ~ 3nm, prevents from falling radiation plating Ag layer oxidized.
The thickness of ZrO anti oxidation layer described above is 5 ~ 10nm, and have strong decay resistance, non-oxidizability is strong.
The thickness falling radiation plating Ag layer described above is 7 ~ 10nm, greatly can reduce infra-red radiation.
(CrNi) described above N
xo
ythe thickness of rete is 0.5 ~ 5nm, can improve rete wearability, improve light transmittance, improve tempering time high temperature oxidation resistance.
SnO described above
2the thickness of protective layer is 30 ~ 40nm, good corrosion resistance.
Tool of the present invention has the following advantages: the Bi adopting high index of refraction
2o
3refracting layer, can improve light transmittance greatly, and its light transmittance can reach 86%, and CrN
xbarrier layer, ZrO anti oxidation layer and (CrNi) N
xo
ythe cooperation of rete will be fallen radiation plating Ag layer and will be clipped in the middle, and stop that the corrosion of radiation plating Ag layer falls in outer bound pair, improve its non-oxidizability, compared with traditional product, can increase the resting period of about 1 year.
Accompanying drawing illustrates:
Fig. 1 is structure sectional view of the present invention.
Detailed description of the invention:
As shown in Figure 1, a kind of saturating energy saving door and window base material of height of high antioxidant, comprises substrate 1, is from bottom to top located at a Bi of the upper surface of substrate 1 successively
2o
3refracting layer 2, one CrN
xradiation plating Ag layer 5, (CrNi) N falls in barrier layer 3, ZrO anti oxidation layer 4,
xo
yrete 6 and a SnO
2protective layer 7.
Described substrate 1 is glass or other transparent high-strength materials.
Described Bi
2o
3the thickness of refracting layer 2 is 15 ~ 25nm, has high refractive index, and its refractive index can reach more than 2.3.It adopts magnetron sputtering membrane process, with interchange intermediate frequency power supply sputtering Bi target, makes reacting gas (amount of oxygen and power direct proportionality), finally form Bi at substrate surface with argon gas and a small amount of oxygen
2o
3refracting layer 2.
Described CrN
xthe thickness on barrier layer 3 is 0.5 ~ 3nm, prevents from falling radiation plating Ag layer oxidized.It adopts magnetron sputtering membrane process, with dc source sputtering chromium target, makes reacting gas, finally at Bi with nitrogen
2o
3refracting layer surface forms CrN
xbarrier layer.
The thickness of described ZrO anti oxidation layer 4 is 5 ~ 10nm, and have strong decay resistance, non-oxidizability is strong.It adopts magnetron sputtering membrane process, and with dc source sputtering Zr target, employing argon gas, oxygen do reacting gas, and argon oxygen ratio is 1:2, finally at CrN
xbarrier layer surface forms ZrO anti oxidation layer.
The described thickness falling radiation plating Ag layer 5 is 7 ~ 10nm, greatly can reduce infra-red radiation.It adopts magnetron sputtering membrane process, with dc source sputtering silver target, is finally formed on ZrO anti oxidation layer surface and falls radiation plating Ag layer.
Described (CrNi) N
xo
ythe thickness of rete 6 is 0.5 ~ 5nm, and it adopts magnetron sputtering membrane process, with dc source sputtering nickel chromium triangle target, does reacting gas, ooze a small amount of oxygen with nitrogen, is finally falling radiation plating Ag layer surface formation (CrNi) N
xo
yrete, can improve rete wearability, improve light transmittance, improve tempering time high temperature oxidation resistance.
Described SnO
2the thickness of protective layer 7 is 30 ~ 40nm, with interchange intermediate frequency power supply sputtering tin target, makes reacting gas, finally at (CrNi) N with oxygen
xo
yfilm surface forms SnO
2protective layer, good corrosion resistance.
The foregoing is only preferred embodiment of the present invention, be not used for limiting scope of the invention process, all equal changes of doing according to the scope of the claims of the present invention and modification, all fall into the scope that patent of the present invention contains.
Claims (6)
1. the saturating energy saving door and window base material of the height of high antioxidant, comprises substrate, it is characterized in that: the upper surface of described substrate is from bottom to top provided with a Bi successively
2o
3refracting layer, a CrN
xradiation plating Ag layer, one (CrNi) N fall in barrier layer, a ZrO anti oxidation layer,
xo
yrete and a SnO
2protective layer, described Bi
2o
3the thickness of refracting layer is 15 ~ 25nm.
2. the saturating energy saving door and window base material of the height of a kind of high antioxidant according to claim 1, is characterized in that: described CrN
xthe thickness on barrier layer is 0.5 ~ 3nm.
3. the saturating energy saving door and window base material of the height of a kind of high antioxidant according to claim 2, is characterized in that: the thickness of described ZrO anti oxidation layer is 5 ~ 10nm.
4. the saturating energy saving door and window base material of the height of a kind of high antioxidant according to claim 3, is characterized in that: described in radiation plating Ag layer falls and thickness be 7 ~ 10nm.
5. the saturating energy saving door and window base material of the height of a kind of high antioxidant according to claim 4, is characterized in that: described (CrNi) N
xo
ythe thickness of rete is 0.5 ~ 5nm.
6. the saturating energy saving door and window base material of the height of a kind of high antioxidant according to claim 5, is characterized in that: described SnO
2the thickness of protective layer is 30 ~ 40nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210516685.6A CN102975415B (en) | 2012-12-05 | 2012-12-05 | High-transparency energy-saving door/window base material with high oxidation resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210516685.6A CN102975415B (en) | 2012-12-05 | 2012-12-05 | High-transparency energy-saving door/window base material with high oxidation resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102975415A CN102975415A (en) | 2013-03-20 |
| CN102975415B true CN102975415B (en) | 2014-12-31 |
Family
ID=47849902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210516685.6A Active CN102975415B (en) | 2012-12-05 | 2012-12-05 | High-transparency energy-saving door/window base material with high oxidation resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102975415B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108862685A (en) * | 2018-08-10 | 2018-11-23 | 安徽原野滤材有限公司 | A kind of novel nano filter cloth |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101027258A (en) * | 2004-09-27 | 2007-08-29 | 冯·阿德纳设备有限公司 | Layer system that can be annealed and method for producing the same |
| US20070281171A1 (en) * | 2005-05-12 | 2007-12-06 | Afg Industries, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
| CN201817403U (en) * | 2010-09-01 | 2011-05-04 | 林嘉宏 | Low emissivity glass capable of being processed in different places |
| CN102092960A (en) * | 2010-12-17 | 2011-06-15 | 华中科技大学 | Low emissivity glass |
| CN201962204U (en) * | 2011-03-03 | 2011-09-07 | 林嘉宏 | Single-sliver and low-radiation coated glass capable of being machined at different place |
| CN202186945U (en) * | 2011-07-11 | 2012-04-11 | 信义节能玻璃（芜湖）有限公司 | LOW-E film coating glass |
-
2012
- 2012-12-05 CN CN201210516685.6A patent/CN102975415B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101027258A (en) * | 2004-09-27 | 2007-08-29 | 冯·阿德纳设备有限公司 | Layer system that can be annealed and method for producing the same |
| US20070281171A1 (en) * | 2005-05-12 | 2007-12-06 | Afg Industries, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
| CN201817403U (en) * | 2010-09-01 | 2011-05-04 | 林嘉宏 | Low emissivity glass capable of being processed in different places |
| CN102092960A (en) * | 2010-12-17 | 2011-06-15 | 华中科技大学 | Low emissivity glass |
| CN201962204U (en) * | 2011-03-03 | 2011-09-07 | 林嘉宏 | Single-sliver and low-radiation coated glass capable of being machined at different place |
| CN202186945U (en) * | 2011-07-11 | 2012-04-11 | 信义节能玻璃（芜湖）有限公司 | LOW-E film coating glass |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102975415A (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105189388B (en) | Glass sheet with high infrared radiation transmission | |
| TWI616417B (en) | Glass sheet having a high transmission in the infrared | |
| CN103802379B (en) | A kind of radiation coated glass capable of being toughened containing silver alloy | |
| CN102975415B (en) | High-transparency energy-saving door/window base material with high oxidation resistance | |
| CN203293613U (en) | Neutral color low-emissivity coated glass with three-silver composite structure and low U value | |
| CN103895276A (en) | Silver-based low-radiation coated glass | |
| CN101691281A (en) | Low radiation glass taking silica-based material as dielectric layer | |
| CN102950841B (en) | A kind of single silver-layer low-radiation glass of high transmission rate | |
| CN102975416B (en) | Energy-saving door/window base material with high oxidation resistance | |
| CN101691282A (en) | Low radiation glass | |
| CN101255018A (en) | Low-radiation glass | |
| CN203864111U (en) | Novel low-emissivity glass | |
| CN104325734A (en) | Blue three-silver LOW-E glass and preparation method thereof | |
| CN104325736A (en) | Three-silver LOW-E coated glass | |
| CN104290402A (en) | Intermediate reflective three-silver LOW-E glass and preparation method thereof | |
| CN104264119A (en) | Asymmetric-film-series double-silver LOW-E glass and preparation method thereof | |
| CN204160833U (en) | A kind of gold can tempered and low-radiation glass | |
| CN106116174B (en) | A kind of three silver medal low-e glass of high-transparency | |
| CN102503175B (en) | Temperable magnetron sputtering single silver LOW-E glass and preparation method thereof | |
| CN204382744U (en) | A kind of double silver coating glass of high transmission Low emissivity | |
| CN205676363U (en) | A kind of coated glass | |
| CN205687807U (en) | A kind of anti-zoned coated glass | |
| CN106116175B (en) | A kind of fire prevention gold and silver indigo plant low-e glass | |
| CN203391407U (en) | Low-transmittance coated glass for alleviating light pollution | |
| TW201446696A (en) | Glass sheet having a high transmission in the infrared |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171222 Address after: Kohiki village Torch Development Zone, Guangdong city of Zhongshan Province: Pu 528400 No. 3 Patentee after: Zhongshan Xinhua Hui door and window Co., Ltd. Address before: 528400 Zhongshan Torch Development Zone, Guangdong Venture Building No. 229 Patentee before: Zhongshan Chuangke Scientific Research Technology Services Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200430 Address after: 528400 no.2-1, Junda street, Langwang village, Minmin Town, Zhongshan City, Guangdong Province Patentee after: ZHONGSHAN ZHONGJIA NEW MATERIAL Co.,Ltd. Address before: Kohiki village Torch Development Zone, Guangdong city of Zhongshan Province: Pu 528400 No. 3 Patentee before: ZHONGSHAN XINHUAHUI DOORS AND WINDOWS Co.,Ltd. |
|
| TR01 | Transfer of patent right |