CN103059479A - Flame-retardant polyvinyl chloride wire and cable material capable of preventing rat bites - Google Patents
Flame-retardant polyvinyl chloride wire and cable material capable of preventing rat bites Download PDFInfo
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- CN103059479A CN103059479A CN2011103201545A CN201110320154A CN103059479A CN 103059479 A CN103059479 A CN 103059479A CN 2011103201545 A CN2011103201545 A CN 2011103201545A CN 201110320154 A CN201110320154 A CN 201110320154A CN 103059479 A CN103059479 A CN 103059479A
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- polyvinyl chloride
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Abstract
The invention relates to a flame-retardant polyvinyl chloride wire and cable material capable of preventing rat bites, and belongs to the technical field of thermoplastic materials. The flame-retardant polyvinyl chloride wire and cable material capable of preventing the rat bites is composed of the following raw materials of, by weight, 100-125 parts of a polyvinyl chloride resin, 25-43 parts of a plasticizer, 50-70 parts of a mineral filler, 5-10 parts of a metal oxide, 10-20 parts of a fire retardant, 0.5-1 part of a rat repellent, 2-3 parts of a calcium-zinc compound stabilizing agent, 0.8-1.4 parts of an antioxidant and 1-2 parts of a lubricating agent. The flame-retardant polyvinyl chloride wire and cable material capable of preventing the rat bites provided by the invention has the following properties that the tensile strength is higher than equal to 12 MPa, the breakage elongation is larger than or equal to 180%, flame-retardant property can reach UL-94-V-0 (1.6 mm), and the wire can prevent rat bites.
Description
Technical field
The invention belongs to the thermoplastic material technical field, specifically a kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing.
Background technology
Polyvinyl chloride is a kind of good material, is widely used in each row.Such as: shoemaking, packing, daily, electrical equipment, power cord etc.Polyvinyl chloride electrical wire and cable is usually baited by mouse in dark moist environment, causes the fracture of electric wire electric wire, the invention provides a kind of electric wire and cable material that can prevent that mouse stings, and can well avoid this phenomenon.
Summary of the invention
Task of the present invention is to provide a kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing, and it has preferably processibility, preferably intensity and elongation performance.
Task of the present invention is finished like this, a kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing, and its raw material by following parts by weight forms:
100～125 parts of polyvinyl chloride (PVC) RESINS;
25～43 parts in softening agent;
50～70 parts of mineral fillers;
5～10 parts of metal oxides;
10～20 parts of fire retardants;
0.5～1 part of Ratproof agent;
2～3 parts of calcium zinc compound stabilizers;
0.8～1.4 part in oxidation inhibitor;
0.5～1 part of lubricant.
In one embodiment of the invention, described polyvinyl chloride (PVC) RESINS refers to the polyvinyl chloride (PVC) RESINS of chlorination.
In another embodiment of the present invention, described softening agent refers to any one in tritolyl phosphate and the dioctyl sebacate.
In yet another embodiment of the present invention, described mineral filler refers to any one in aluminium hydroxide and the magnesium hydroxide.
In another embodiment of the present invention, described metal oxide refers to any one in antimonous oxide and the molybdic oxide.
In another embodiment of the present invention, described fire retardant refers to any one in TDE and the tetrabromo-bisphenol.
More of the present invention and among embodiment, described Ratproof agent refers to Vanillyl pelargonic amide.
In of the present invention and then embodiment, described calcium zinc compound stabilizer refers to CZ-756E.
At again of the present invention and embodiment, described oxidation inhibitor refers to any one in 2.4 di-tert-butyl-phenyls-tris phosphite, Tyox B, the thio-2 acid 2 stearyl ester.
In more of the present invention and then embodiment, described lubricant refers to any one in stearic acid and the calcium stearate.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing of the present invention has following performance: tensile strength 〉=12MPa, elongation at break 〉=180%, and flame retardant resistance can reach UL-94-V-0 (1.6mm), and electric wire can prevent damaged by rats.
Embodiment
Embodiment 1:
A kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing is comprised of the raw material of following parts by weight:
100 parts of the polyvinyl chloride (PVC) RESINS of chlorination;
26 parts of tritolyl phosphates;
50 parts in aluminium hydroxide;
5.2 parts of antimonous oxides;
11 parts of TDE;
0.6 part of Vanillyl pelargonic amide;
2.1 parts of calcium zinc stabilizers (CZ-756E);
2.4 0.8 part of di-tert-butyl-phenyl-tris phosphite;
1 part of stearic acid.
With the accurate weighing of above-mentioned component, add in the high-speed mixer successively and mix, after mixing, be transferred on the twin screw plasticator and plasticate, again pelletizing behind water cooling bracing after plasticating evenly after then entering centrifugal drier and carrying out drying, is packed at last.
Embodiment 2:
A kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing is comprised of the raw material of following parts by weight:
107 parts of the polyvinyl chloride (PVC) RESINS of chlorination;
31 parts of dioctyl sebacates;
57 parts of magnesium hydroxides;
6.8 parts of molybdic oxides;
14 parts of tetrabromo-bisphenols;
0.8 part of Vanillyl pelargonic amide;
2.5 parts of calcium zinc stabilizers (CZ-756E);
1.0 parts of Tyox Bs;
0.7 part of stearic acid;
2 parts of carbon blacks (tinting material).
With the accurate weighing of above-mentioned component, add in the high-speed mixer successively and mix, after mixing, be transferred on the twin screw plasticator and plasticate, again pelletizing behind water cooling bracing after plasticating evenly, then after entering centrifugal drier and carrying out drying, pack at last, namely obtain the fire-retardant polyvinyl chloride wire cable material of black mouse bite preventing.
Embodiment 3:
A kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing is comprised of the raw material of following parts by weight:
111 parts of the polyvinyl chloride (PVC) RESINS of chlorination;
35 parts of tritolyl phosphates;
63 parts in aluminium hydroxide;
7.9 parts of antimonous oxides;
17 parts of TDE;
0.9 part of Vanillyl pelargonic amide;
2.8 parts of calcium zinc stabilizers (CZ-756E);
1.2 parts of thio-2 acid 2 stearyl esters;
0.8 part of calcium stearate;
2 parts of red iron oxides (tinting material).
With the accurate weighing of above-mentioned component, add in the high-speed mixer successively and mix, after mixing, be transferred on the twin screw plasticator and plasticate, again pelletizing behind water cooling bracing after plasticating evenly, then after entering centrifugal drier and carrying out drying, pack at last, namely obtain the fire-retardant polyvinyl chloride wire cable material of red mouse bite preventing.
Embodiment 4:
A kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing is comprised of the raw material of following parts by weight:
117 parts of chlorinated polyvinyl chloride resins;
41 parts of tritolyl phosphates;
67 parts in aluminium hydroxide;
9.1 parts of antimonous oxides;
19 parts of TDE;
1.0 parts of Vanillyl pelargonic amides;
2.9 parts of calcium zinc stabilizers (CZ-756E);
1.3 parts of thio-2 acid 2 stearyl esters;
0.9 part of calcium stearate;
Blue (tinting material) 3 parts of phthalein cyanogen.
With the accurate weighing of above-mentioned component, add in the high-speed mixer successively and mix, after mixing, be transferred on the twin screw plasticator and plasticate, again pelletizing behind water cooling bracing after plasticating evenly, then after entering centrifugal drier and carrying out drying, pack at last, namely obtain the fire-retardant polyvinyl chloride wire cable material of blue mouse bite preventing.
Embodiment 5:
A kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing is comprised of the raw material of following parts by weight:
124 parts of chlorinated polyvinyl chloride resins;
43 parts of tritolyl phosphates;
70 parts of magnesium hydroxides;
10 parts of molybdic oxides;
16 parts of TDE;
0.7 part of Vanillyl pelargonic amide;
3.0 parts of calcium zinc stabilizers (CZ-756E);
1.4 parts of thio-2 acid 2 stearyl esters;
1.0 parts of stearic acid;
3 parts in phthalein cyanogen green (tinting material).
With the accurate weighing of above-mentioned component, add in the high-speed mixer successively and mix, after mixing, be transferred on the twin screw plasticator and plasticate, again pelletizing behind water cooling bracing after plasticating evenly, then after entering centrifugal drier and carrying out drying, pack at last, namely obtain the fire-retardant polyvinyl chloride wire cable material of green mouse bite preventing.
Through test, the flame-retardant polyvinyl chloride wire cable material of mouse bite preventing of the present invention has following performance characteristic:
Claims (10)
1.
A kind of flame-retardant polyvinyl chloride wire cable material of mouse bite preventing is characterized in that its raw material by following parts by weight forms:
100～125 parts of polyvinyl chloride (PVC) RESINS;
25～43 parts in softening agent;
50～70 parts of mineral fillers;
5～10 parts of metal oxides;
10～20 parts of fire retardants;
0.5～1 part of Ratproof agent;
2～3 parts of calcium zinc compound stabilizers;
0.8～1.4 part in oxidation inhibitor;
0.5～1 part of lubricant.
2.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described polyvinyl chloride (PVC) RESINS refers to the polyvinyl chloride (PVC) RESINS of chlorination.
3.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described softening agent refers to any one in tritolyl phosphate and the dioctyl sebacate.
4.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described mineral filler refers to any one in aluminium hydroxide and the magnesium hydroxide.
5.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described metal oxide refers to any one in antimonous oxide and the molybdic oxide.
6.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described fire retardant refers to any one in TDE and the tetrabromo-bisphenol.
7.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described Ratproof agent refers to Vanillyl pelargonic amide.
8.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described calcium zinc compound stabilizer refers to CZ-756E.
9.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described oxidation inhibitor refers to any one in 2.4 di-tert-butyl-phenyls-tris phosphite, Tyox B, the thio-2 acid 2 stearyl ester.
10.
The flame-retardant polyvinyl chloride wire cable material of a kind of mouse bite preventing according to claim 1 is characterized in that described lubricant refers to any one in stearic acid and the calcium stearate
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103201545A CN103059479A (en) | 2011-10-20 | 2011-10-20 | Flame-retardant polyvinyl chloride wire and cable material capable of preventing rat bites |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103201545A CN103059479A (en) | 2011-10-20 | 2011-10-20 | Flame-retardant polyvinyl chloride wire and cable material capable of preventing rat bites |
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| CN103059479A true CN103059479A (en) | 2013-04-24 |
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| CN2011103201545A Pending CN103059479A (en) | 2011-10-20 | 2011-10-20 | Flame-retardant polyvinyl chloride wire and cable material capable of preventing rat bites |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103772785A (en) * | 2014-01-03 | 2014-05-07 | 山东省塑料研究开发中心 | Polyethylene master batch for preventing ant and rat bite from damaging plastic pipelines and preparation method thereof |
| CN104045933A (en) * | 2014-06-06 | 2014-09-17 | 桐庐雷泰生物科技有限公司 | Rat-proof PVC (polyvinyl chloride) material |
| CN104109305A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Anti-rat-type PVC cable material and preparation method |
| CN112210117A (en) * | 2020-10-10 | 2021-01-12 | 合肥工业大学 | Rat-proof agent with flame-retardant synergistic function and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4892683A (en) * | 1988-05-20 | 1990-01-09 | Gary Chemical Corporation | Flame retardant low smoke poly(vinyl chloride) thermoplastic compositions |
| CN101161712A (en) * | 2007-09-03 | 2008-04-16 | 上海斯瑞聚合体科技有限公司 | Environment-friendly type ant-proof ratproof material for electric wire and cable |
| CN201323089Y (en) * | 2009-01-22 | 2009-10-07 | 安徽天星光纤通信设备有限公司 | Rat and ant proof indoor CAT5E cable |
| CN101633765A (en) * | 2009-05-22 | 2010-01-27 | 上海凯波特种电缆料厂有限公司 | Insulating grade PVC sheath material for ultrahigh pressure cables and preparation method thereof |
| CN102140214A (en) * | 2011-04-27 | 2011-08-03 | 山西永东化工股份有限公司 | Cable material added with super conductive carbon black and manufacturing method thereof |
| CN102190838A (en) * | 2011-04-29 | 2011-09-21 | 太仓市立新电器塑料有限公司 | Polyvinyl chloride (PVC) rat-proof sleeve |
-
2011
- 2011-10-20 CN CN2011103201545A patent/CN103059479A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4892683A (en) * | 1988-05-20 | 1990-01-09 | Gary Chemical Corporation | Flame retardant low smoke poly(vinyl chloride) thermoplastic compositions |
| CN101161712A (en) * | 2007-09-03 | 2008-04-16 | 上海斯瑞聚合体科技有限公司 | Environment-friendly type ant-proof ratproof material for electric wire and cable |
| CN201323089Y (en) * | 2009-01-22 | 2009-10-07 | 安徽天星光纤通信设备有限公司 | Rat and ant proof indoor CAT5E cable |
| CN101633765A (en) * | 2009-05-22 | 2010-01-27 | 上海凯波特种电缆料厂有限公司 | Insulating grade PVC sheath material for ultrahigh pressure cables and preparation method thereof |
| CN102140214A (en) * | 2011-04-27 | 2011-08-03 | 山西永东化工股份有限公司 | Cable material added with super conductive carbon black and manufacturing method thereof |
| CN102190838A (en) * | 2011-04-29 | 2011-09-21 | 太仓市立新电器塑料有限公司 | Polyvinyl chloride (PVC) rat-proof sleeve |
Non-Patent Citations (3)
| Title |
|---|
| 中国大百科全书总编辑委员会: "《中国大百科全书》", 30 September 2002, article "助剂", pages: 361-362 * |
| 化学工业部科学技术情报研究所编辑出版: "《世界精细化工手册》", 31 December 1982, article "助剂", pages: 568 * |
| 许国章主编: "《使用病媒生物防制技术》", 31 August 2010, article "助剂", pages: 29 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103772785A (en) * | 2014-01-03 | 2014-05-07 | 山东省塑料研究开发中心 | Polyethylene master batch for preventing ant and rat bite from damaging plastic pipelines and preparation method thereof |
| CN103772785B (en) * | 2014-01-03 | 2016-06-22 | 山东省塑料研究开发中心 | A kind of preventing from being eaten by ant and mouse plastic conduit polyethylene master batch and preparation method thereof |
| CN104045933A (en) * | 2014-06-06 | 2014-09-17 | 桐庐雷泰生物科技有限公司 | Rat-proof PVC (polyvinyl chloride) material |
| CN104109305A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Anti-rat-type PVC cable material and preparation method |
| CN112210117A (en) * | 2020-10-10 | 2021-01-12 | 合肥工业大学 | Rat-proof agent with flame-retardant synergistic function and preparation method and application thereof |
| CN112210117B (en) * | 2020-10-10 | 2022-02-18 | 合肥工业大学 | Rat-proof agent with flame-retardant synergistic function and preparation method and application thereof |
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Application publication date: 20130424 |