CN103215661A - Electrostatic spinning device and spinning method - Google Patents

Electrostatic spinning device and spinning method Download PDF

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CN103215661A
CN103215661A CN2013101172956A CN201310117295A CN103215661A CN 103215661 A CN103215661 A CN 103215661A CN 2013101172956 A CN2013101172956 A CN 2013101172956A CN 201310117295 A CN201310117295 A CN 201310117295A CN 103215661 A CN103215661 A CN 103215661A
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spinning
electrode
spinning head
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metal silk
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CN103215661B (en
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高小歌
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Abstract

The invention relates to an electrostatic spinning device, which takes a combination mechanism of a spinning head and a solution pool as a core component, and a method of effectively andstably obtaining nano-fibers from polymer solution by utilizing the device. The electrostatic spinning device comprises the spinning head and the solution pool located below the spinning head, wherein the spinning head comprises a supporting mechanism provided with a high-voltage contact, a conductor wire electrode, an insulation connecting rod, a cam mechanism capable of outputting lifting motion to the conductor wire electrode, and a drive motor which are connected in sequence. When the conductor wire electrode of the spinning head is descended and is immersed into the polymer solution through a slit of a cover board of the solution pool to dip the solution, after the conductor wire electrode is ascended to and contacted with the high-voltage contact, the polymer solution attached on the conductor wire electrode is supplied to a high-voltage electrostatic field formed between the spinning head and a counter electrode, so that a good spinning state is obtained.

Description

A kind of electrostatic spinning apparatus and spinning process
Technical field
The present invention relates to the electrostatic spinning technique field, relate in particular to a kind of electrostatic spinning apparatus and spinning process that from polymer solution, obtains nanofiber.
Background technology
Electrostatic spinning technique is applied to prepare the macromolecule monodimension nanometer material, can obtain the superfine fibre of diameter about 10~1000nm.Compare conventional fibre, new features such as high porosity that the remarkable decline of the diameter of nanofiber is brought and high-specific surface area make electrostatic spinning technique be studied widely and use in fields such as filtration, dressing, catalysis, sensing and tissue engineering brackets.
Common single needle head electrospinning device mainly is made of assemblies such as high voltage source, Spinning pumps, spinning head and gatherers.Under the high voltage electric field effect between spinning head and the gatherer, the shape that accumulates in the polymer solution droplets of spinning head mouth can become taper---and " taylor cone ", the impetus of electric field force is at the vertex of a cone.Along with the increase of electric field force, " taylor cone " comes to a point gradually, after cone-apex angle reaches a critical value, the metastable state of drop is destroyed, vertex of a cone solution surface molecule is subjected to enough big electric field force and overcomes surface tension, and polymer solution ejects from the vertex of a cone, forms injection stream.Electric field force stretches thousands of times to millions of times jet, and the diameter of jet is reduced to several microns to tens nanometers thereupon.Along with solvent evaporates, the fiber of gained finally is collected on metallic plate, wrapping head or other gatherers that is connected with ground wire with the form of nonwoven fabric.From applying electrostatic field, to forming nanofiber, the most difficult generation also is that a slowest step is to form " taylor cone ", and this is the rate determining step of spinning process.
In the electrostatic spinning of single needle head, spinning efficiency is very low, and (flow velocity of general spinning solution is 0.1~10mL/h), can't satisfy the requirement of industrial production to production efficiency.The prerequisite that electrostatic spinning technique can obtain industrial applications is to use new electrostatic spinning technique to improve unit interval spinning output.
CN101210352A, CN102776582A etc. disclose spininess head electrospinning process, can improve spinning efficiency effectively than the single needle head.The advantage of spininess head electrostatic spinning technique is that principle is simple, is the simple amplification to single needle head electrostatic spinning technique.But when improving spinning efficiency, also brought much more complicated problems, as: because electric field phase mutual interference between the syringe needle, the spinning Electric Field Distribution is irregular, and the electric field of syringe needle can be seriously undermined near the center, and each syringe needle nanofiber productive rate and fibre diameter difference are very big; Spininess head jet causes collector to obtain the fibre weight skewness because of the interference deflection of contiguous jet surface charge; In addition, syringe needle diameter Xiao Yi stops up, and is not easy cleaning, spininess head system maintenance cost height, and maintenance time is long, influences industrial production.
WO2005/024101A1 discloses a kind of columniform axial symmetry spinning electrode, its part immerses spinning solution, spinning electrode with electrode is formed electrostatic field, by this electrode around its symmetry axis rotation, spinning solution is fed in the electrostatic field continuously, reaches the purpose of continuous spinning.This invention has solved between the little and spininess head of syringe needle spinning amount the interactive problem of electric field mutually well.But, in actual production, unavoidable new problem mainly contains 3: 1, columniform electrode and to need could producing enough electric-field intensity up to the electrical potential difference more than the 80kV between the electrode, this requirement to the insulating Design processing of high voltage source performance requirement, spinning equipment is harsh; 2, columniform electrode needs the trough of the splendid attire q.s solution of an opening, make the part of electrode can immerse solution and the electrode rotation is not interfered, this set can make that solvent volatilizees in a large number, solution concentration changes, and solution concentration has determined pattern, structure, the performance of nanofiber, the steady quality of product during influence is produced continuously; 3, columniform electrode is in rotary course, exposed aerial surface area is very big, and during spinning, the thin electrolyte film that this part electrode surface adheres to, the solution that participate in to form taylor cone only accounts for the seldom part of liquid film, a large amount of solution in electric field, polarize and with sneak into after air contacts in the groove in the solution, we pass through big quantity research and find out, solution contacts and the erosion of polarized and water in air with electrode, can cause the aging of solution.This has reduced raw-material utilization rate widely in actual production, improve production cost.
WO2006/131081 has announced several cylindrical electrodes that have the tip of evagination, has solved first problem that cylindrical electrode is used to a certain extent, and promptly the tip of evagination can reduce the required electrical potential difference of the enough electrostatic fields of generation.But novel electrode does not only solve the easily problem that changes of the solution concentration brought of volatilization of solvent, does not solve the aging problem that is accelerated of solution yet; And electrode processing cost height, clean difficulty.
WO2009/010020 has announced a kind of brand-new spinning electrode, it selects for use the less wire of diameter as spinning electrode, and the invention before having overcome provides the dependence of high potential difference to equipment, has reduced the insulating Design processing request of equipment.It adopts the mode of spraying the polymer base fluid on electrode, can solve the problem that causes base fluid to wear out that cylindrical electrode runs into.Yet, have two aspect problems more outstanding:
On the one hand, raw material utilization ratio existing problems, promptly the solution of Pen Saing can not be used for spinning fully, and this is the certainty of this feed liquid way.
On the other hand, the feed liquid way that WO2009/010020 announced can't make all positions spinning simultaneously of a certain electrode at one time, this be because: enter the process that electric field finishes to spinning from solution, taylor cone to be formed into the beginning spinning be a longest step consuming time in the whole process.And described feed liquid way is with nozzle base fluid to be sprayed onto the other end along an end of wire electrode, also or with lead progressively pulls out from solution along its length.Obviously, which kind of feed liquid way no matter all exists diverse location on the spinning wire electrode that the problem of spinning can not take place simultaneously.
The technical process of this scheme reality is: a certain position has obtained new soln on the electrode; Through a little time interval, produced taylor cone in this position; Then this position just begins spinning, experiences this position spinning instability of a time interval again and need obtain new soln once more.Obviously, the problem of this feed liquid way is that beginning spinning, normally spinning, three processes of end spinning of whole one metal wire electrode can not take place on whole electrode the same time, and the discontinuous and unstable of this technology is very big problem aborning.
Summary of the invention
The object of the present invention is to provide a kind of method that can realize from polymer solution the device of stable, continuous spinning and utilize described device spinning, technology substantive issue such as too high with the operating voltage that solves existing device for spinning and method, that technology is stable inadequately and utilization rate of raw materials is low.
The present invention utilizes the principle of electrostatic spinning, a kind of device that obtains nanofiber from polymer solution is provided, described device is a core component with spinning head and solution pool combined mechanism, spinning head connects the positive pole of high voltage source, to electrode grounding or connect the negative pole of high voltage source, formed the high-voltage electrostatic field at spinning head and between, caused the accompanying polymer solution generation electrostatic spinning of spinning head, and the nanofiber that obtains has been collected on the nanofiber storage component electrode.
For reaching this purpose, the present invention by the following technical solutions:
One of purpose of the present invention is to provide a kind of electrostatic spinning apparatus, and described device comprises spinning head and is positioned at the solution pool of spinning head below; Described spinning head comprises successively the supporting mechanism that has high-voltage contact that connects, conductor metal silk electrode, insulated connecting rod, to the cam mechanism and the drive motors of conductor wire electrode output elevating movement.
Conductor metal silk electrode of the present invention, an end links to each other with the supporting mechanism that has high-voltage contact, and the other end links to each other with an end of insulated connecting rod; The other end of insulated connecting rod then links to each other with cam mechanism; Cam mechanism connects drive motors.
When drive motors output torque, cam mechanism becomes torque into straight reciprocating motion, drive insulated connecting rod and move up and down, and then drive conductor metal silk electrode moves up and down.
The present invention adopt the conductor metal silk as electrode can than diameter greater than the cylindrical electrode of 30mm when the spinning, needed voltage reduces more than the 20kV, has reduced the requirement to apparatus insulated grade, thereby has reduced the manufacturing cost of equipment.
Described conductor metal silk electrode material has certain rigidity for the metal or alloy of conduction, makes conductor metal silk electrode keep straight between supporting mechanism and insulated connecting rod.Preferably, the length of described conductor metal silk electrode is 10~2500mm, more preferably 100~2000mm; Preferably, the diameter of described conductor metal silk electrode is 0.5~20mm, more preferably 0.5~10mm.
Further, described conductor metal silk electrode is single metal wire or is made of many one metal wires wringing.
Supporting mechanism of the present invention plays the effect of supporting and retraining movement locus to conductor metal silk electrode.The inboard top of described supporting mechanism is embedded with the high-voltage contact that links to each other with high voltage source, when conductor metal silk electrode rises to the top of spinning head, contacts with high-voltage contact to make conductor metal silk electrode have high-voltage potential.In the present invention, when conductor metal silk electrode rises to predetermined spinning position, just can touch high-voltage contact and switch on.Like this and since spinning head with the position of electrode is fixed, distance each other keeps constant, as long as fixing input high pressure, spinning head and be constant to the electric-field intensity between the electrode.Constant electric-field intensity will make the nanofiber diameter distribution narrow of production, and this is favourable to product quality.
Solution pool of the present invention top is provided with the cover plate that has slit, and described slit allows conductor metal silk electrode freely to pass through when elevating movement; Preferably, described cover plate is dismantled and assembled form.The solution pool that has the slit cover plate of the present invention has reduced solvent evaporates, delayed the solution concentration variation, and it is aging to have weakened the solution that steam brings, and when improving the soln using rate, has guaranteed the steady quality of spinning.
The material of solution pool of the present invention is nonconducting plastics or Inorganic Non-metallic Materials, is preferably the mixture of a kind of in polymethyl methacrylate, polyamide, polytetrafluoroethylene (PTFE), Kynoar, Merlon, polyethylene terephthalate, polyethylene, polypropylene, polyphenylene oxide, polyether sulfone, polyether-ether-ketone, polyimides, pottery or the glass or at least two kinds.Those skilled in the art can be known no matter adopt which kind of material, all should do not dissolved by the solvent of the polymer solution of its splendid attire.
Spinning head of the present invention and solution pool are formed combined mechanism; Described combined mechanism is by a solution pool and a plurality of spinning head is supporting constitutes, or by spinning head and corresponding one by one supporting the forming of solution pool.
Described spinning head top is provided with receiving element, forms the spinning zone between described receiving element and the spinning head; Described receiving element comprises the nanofiber storage component and is positioned at the one or more to electrode of nanofiber storage component top.
Described high-voltage contact and described the two poles of the earth that electrode are connected high voltage source respectively; Preferably, described high-voltage contact links to each other with the positive pole of high voltage source, and is described to electrode grounding.
Two of purpose of the present invention is to provide a kind of utilization electrostatic spinning apparatus method of carrying out spinning as mentioned above, the conductor metal silk electrode of described spinning head is under the constraint of the drive of insulated connecting rod and supporting mechanism, and the slit that moves downward by the solution pool cover plate is immersed in the polymer solution; The spinning zone that moves upward to setting then the time touches high-voltage contact, under given voltage, forms the high-voltage electrostatic field in the spinning zone, causes the spinning head spinning, repeats said process again after reaching predetermined spinning time.
Dip in the solution pool when getting solution when conductor metal silk electrode drops to, because conductor metal silk electrode has broken away from high-voltage contact, in the time of in immersing solution, described electrode is not charged, has avoided solution because of the aging problem of polarization.The advantage of this process is tangible: prolong the ageing time of solution, thereby reduce the replacing frequency of solution, improve the utilization rate of solution, also guaranteed stable spinning quality simultaneously.
When conductor metal silk electrode descends, can pass through the slit of solution pool cover plate, and be immersed in the polymer solution of institute's splendid attire in the solution pool, make conductor metal silk electrode surface speckle with polymer solution.Move upward when speckling with conductor metal silk electrode, when touching the high-voltage contact on supporting mechanism top,, make conductor metal silk electrode have high-voltage potential because high-voltage contact links to each other with high voltage source.
Described conductor metal silk electrode is done the elevating movement of rule with grouping or integral form; Described rule is the function rule.The described characteristics of motion is controlled according to technological design and requirement.
In spinning process, described receiving element is dynamically to receive, described nanofiber storage component with certain speed by the spinning zone.Described " certain speed " can rule of thumb be selected with actual conditions by those skilled in the art, and the present invention there is no particular restriction, and this term is clearly in this area.
The present invention realizes controlling the different conductor wire electrode by the control drive motors and defers to different elevating movement rules, realize that the different conductor wire electrode replaces spinning, can make even, continuous, stable being deposited on on the nanofiber storage component of certain speed by the spinning zone of nanofiber.
Compare with the prior art scheme, the present invention has following beneficial effect:
Apparatus and method of the present invention have efficiently, stablize, the controlled advantage of spinning state, technology substantive issue such as solved effectively that the spinning efficiency that exists in the prior art is low, operating voltage is too high, technology is unstable, the aging fast and utilization rate of raw materials of spinning solution is low.
Description of drawings
Fig. 1 is the structural representation of electrostatic spinning apparatus of the present invention;
Fig. 2 is the structural representation of spinning head of the present invention and solution pool combined mechanism;
Fig. 3 is that the A of device shown in Figure 1 is to view;
Fig. 4 is the B-B cross sectional view of Fig. 3;
Fig. 5 is the structural representation of the specific embodiment of electrostatic spinning apparatus of the present invention.
Among the figure: the 1-nanofiber; The 2-combined mechanism; The 3-spinning head; 31-conductor metal silk electrode; The 32-high-voltage contact; The 33-supporting mechanism; The 34-insulated connecting rod; The 35-cam mechanism; The 36-drive motors; The 4-solution pool; The 41-cover plate; The 42-slit; 5-is to electrode; The 6-polymer solution; 7-nanofiber storage component.
Below the present invention is described in more detail.But following example only is a simple and easy example of the present invention, does not represent or limit the scope of the present invention, and protection scope of the present invention is as the criterion with claims.
The specific embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
As shown in Figure 1 and Figure 2, a kind of electrostatic spinning apparatus, described device comprise spinning head 3 and the solution pool 4 that is positioned at spinning head 3 belows; Described spinning head 3 comprises successively the supporting mechanism that has high-voltage contact 32 33 that connects, conductor metal silk electrode 31, insulated connecting rod 34, to the cam mechanism 35 and the drive motors 36 of conductor wire electrode 31 output elevating movements.
Described conductor metal silk electrode 31 materials are the metal or alloy of conduction.The length of described conductor metal silk electrode 31 is 10~2500mm, more preferably 100~2000mm.The diameter of described conductor metal silk electrode 31 is 0.5~20mm, more preferably 0.5~10mm.Described conductor metal silk electrode 31 constitutes for single metal wire or by many one metal wires wringing.
Described solution pool 4 tops are provided with the cover plate 41 that has slit 42, and described slit 42 allows conductor metal silk electrode 31 freely to pass through when elevating movement.Described cover plate 41 is dismantled and assembled form.
The material of described solution pool 4 is nonconducting plastics or Inorganic Non-metallic Materials, is preferably the mixture of a kind of in polymethyl methacrylate, polyamide, polytetrafluoroethylene (PTFE), Kynoar, Merlon, polyethylene terephthalate, polyethylene, polypropylene, polyphenylene oxide, polyether sulfone, polyether-ether-ketone, polyimides, pottery or the glass or at least two kinds.
Described spinning head 3 and solution pool 4 are formed combined mechanism 2; Described combined mechanism 2 constitutes by a solution pool 4 and a plurality of spinning head 3 are supporting, or by spinning head 3 and corresponding one by one supporting the forming of solution pool 4.
Described spinning head 3 tops are provided with receiving element, form the spinning zone between described receiving element and the spinning head 3; Described receiving element comprises nanofiber storage component 7 and is positioned at the one or more to electrode 5 of nanofiber storage component 7 tops.
Described high-voltage contact 32 and described the two poles of the earth that electrode 5 are connected high voltage source respectively; Preferably, described high-voltage contact 32 links to each other with the positive pole of high voltage source, and is described to electrode 5 ground connection.
A kind of utilization is the electrostatic spinning apparatus method of carrying out spinning as mentioned above, the conductor metal silk electrode 31 of described spinning head 3 is under the constraint of the drive of insulated connecting rod 34 and supporting mechanism 33, and the slit 42 that moves downward by solution pool 4 cover plates 41 is immersed in the polymer solution 6; The spinning zone that moves upward to setting then the time touches high-voltage contact 32, under given voltage, forms the high-voltage electrostatic field in the spinning zone, causes spinning head 3 spinning, repeats said process again after reaching predetermined spinning time.
Described conductor metal silk electrode 31 is done the elevating movement of rule with grouping or integral form; Described rule is the function rule.
In spinning process, described receiving element is dynamically to receive, described nanofiber storage component 7 with certain speed by the spinning zone.
Fig. 4 very clearly demonstrates the working method of electrostatic spinning apparatus involved in the present invention as an example.In this example, several spinning heads are arranged in parallel, and the orientation of spinning head is vertical with the direction of motion of nanofiber storage component 7.Part spinning head 3 is positioned at the spinning position, have high-voltage potential and electrode 5 is formed 6 spinning of high voltage electric field initiated polymerization thing solution, form nanofiber 1, the spinning head 3 that another part is immersed in the polymer solution 6 of solution pool 4 is then not charged because of the high-voltage contact that breaks away from, and this set solution that brings of can effectively avoiding polarizing is aging.
Electrostatic spinning apparatus shown in Figure 5 comprises 6 spinning heads 301,302,303,304,305,306, corresponding conductor metal silk electrode 311,312,313,314,315,316 is parallel to each other, this group spinning head offside have 6 be arranged in parallel to electrode 51,52,53,54,55,56, and vertical with the direction of motion of nanofiber storage component 7.The high-voltage contact of 6 spinning heads all connects the positive pole of high voltage source, and 6 to the equal ground connection of electrode.Nanofiber storage component 7 is air filtration filter paper, its with the speed of 3/min by the spinning zone, collection nanofiber 1, the preparation efficiency of nanofiber composite filter paper is 3m/min.
Before the equipment work, injection of polymer solution 6 in solution pool 4 at first, liquid level is not higher than cover plate 41 lower edges and gets final product.
Set out-put supply, the electric current of high voltage source.That adopt to determine but 6 drive motors of unshowned control program control, drive conductor metal silk electrode and do the elevating movement of periodic law, it contact with high-voltage contact and begins that rising time of getting back to the top is designated as a spinning cycle again to decline from rising to the top.According to principle of the present invention, conductor metal silk electrode is in the spinning state when being positioned at the top, is in the no power state during decline, in the specific embodiment, the spinning state of setting conductor metal silk electrode and the time of no power state equate, for the spinning cycle half, become the electrode spinning half period.
In the electrode spinning half period, be in the spinning state in the electrifying electrodes on top, the electrode in the bottom immerses in the polymer solution and picks solution.In the specific embodiment of the present invention, setting 3 conductor metal silk electrodes 311,313,315 is one group, other 3 conductor metal silk electrodes 312,314,316 are one group, when work, these two groups of conductor metal silk electrodes are in the different electrode spinning half periods respectively, promptly when conductor metal silk electrode 311,313,315 was in the spinning state, conductor metal silk electrode 312,314,316 was immersed in and picks solution in the polymer solution, and vice versa.Like this, total energy guarantees that 3 wire electrode spinning are at the same time arranged in the whole spinning cycle, has guaranteed that spinning is continuous in the described electrostatic spinning apparatus running.
In the specific embodiment of the present invention, can adopt the conductor metal silk electrode of different length, diameter, material, and by adjusting output voltage, the electric current of high voltage source, and set the concrete electrode spinning half period and reach concrete spinning technique requirement.Table 1 has exemplarily provided the aforementioned parameters according to 6 kinds of specific embodiment of the present invention.
The different parameters of six kinds of specific embodiment of table 1
Figure BDA00003017324700101
Applicant's statement, the present invention illustrates detailed structure feature of the present invention and spinning process by the foregoing description, but the present invention is not limited to above-mentioned detailed structure feature and spinning process, does not mean that promptly the present invention must rely on above-mentioned detailed structure feature and spinning process could be implemented.The person of ordinary skill in the field should understand, any improvement in the present invention to the increase of the equivalence replacement of the selected parts of the present invention and accessory, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.

Claims (10)

1. an electrostatic spinning apparatus is characterized in that, described device comprises spinning head (3) and is positioned at the solution pool (4) of spinning head (3) below; Described spinning head (3) comprises successively the supporting mechanism that has high-voltage contact (32) (33) that connects, conductor metal silk electrode (31), insulated connecting rod (34), to the cam mechanism (35) and the drive motors (36) of conductor wire electrode (31) output elevating movement.
2. device as claimed in claim 1 is characterized in that, described conductor metal silk electrode (31) material is the metal or alloy of conduction; Preferably, the length of described conductor metal silk electrode (31) is 10~2500mm, more preferably 100~2000mm; Preferably, the diameter of described conductor metal silk electrode (31) is 0.5~20mm, more preferably 0.5~10mm;
Preferably, described conductor metal silk electrode (31) constitutes for single metal wire or by many one metal wires wringing.
3. device as claimed in claim 1 or 2 is characterized in that, described solution pool (4) top is provided with the cover plate (41) that has slit (42), and described slit (42) allows conductor metal silk electrode (31) freely to pass through when elevating movement; Preferably, described cover plate (41) is dismantled and assembled form.
4. as the described device of one of claim 1-3, it is characterized in that, the material of described solution pool (4) is nonconducting plastics or Inorganic Non-metallic Materials, is preferably the mixture of a kind of in polymethyl methacrylate, polyamide, polytetrafluoroethylene (PTFE), Kynoar, Merlon, polyethylene terephthalate, polyethylene, polypropylene, polyphenylene oxide, polyether sulfone, polyether-ether-ketone, polyimides, pottery or the glass or at least two kinds.
5. as the described device of one of claim 1-4, it is characterized in that described spinning head (3) and solution pool (4) are formed combined mechanism (2); Described combined mechanism (2) is by a solution pool (4) and the supporting formation of a plurality of spinning head (3), or by spinning head (3) and corresponding one by one supporting the forming of solution pool (4).
6. as the described device of one of claim 1-5, it is characterized in that described spinning head (3) top is provided with receiving element, form the spinning zone between described receiving element and the spinning head (3); Described receiving element comprises nanofiber storage component (7) and is positioned at the one or more to electrode (5) of nanofiber storage component (7) top.
7. device as claimed in claim 6 is characterized in that, described high-voltage contact (32) and described the two poles of the earth that electrode (5) are connected high voltage source respectively; Preferably, described high-voltage contact (32) links to each other with the positive pole of high voltage source, and is described to electrode (5) ground connection.
8. the utilization method of carrying out spinning as electrostatic spinning apparatus as described in one of claim 1-7, it is characterized in that, the conductor metal silk electrode (31) of described spinning head (3) is under the constraint of the drive of insulated connecting rod (34) and supporting mechanism (33), and the slit (42) that moves downward by solution pool (4) cover plate (41) is immersed in the polymer solution (6); The spinning zone that moves upward to setting then the time touches high-voltage contact (32), under given voltage, forms the high-voltage electrostatic field in the spinning zone, causes spinning head (3) spinning, repeats said process again after reaching predetermined spinning time.
9. method as claimed in claim 8 is characterized in that, described conductor metal silk electrode (31) is done the elevating movement of rule with grouping or integral form; Described rule is the function rule.
10. method as claimed in claim 8 or 9 is characterized in that, in spinning process, described receiving element is dynamically to receive, described nanofiber storage component (7) with certain speed by the spinning zone.
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