CN103535927A - Rubber thermosensitive mechanical embossing glove and production technology thereof - Google Patents
Rubber thermosensitive mechanical embossing glove and production technology thereof Download PDFInfo
- Publication number
- CN103535927A CN103535927A CN201310536861.7A CN201310536861A CN103535927A CN 103535927 A CN103535927 A CN 103535927A CN 201310536861 A CN201310536861 A CN 201310536861A CN 103535927 A CN103535927 A CN 103535927A
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- Prior art keywords
- temperature
- gloves
- latex
- impregnation
- embossing
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- 238000004049 embossing Methods 0.000 title claims abstract description 42
- 238000005516 engineering process Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 229920001971 elastomer Polymers 0.000 title abstract 5
- 239000004816 latex Substances 0.000 claims abstract description 25
- 229920000126 latex Polymers 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 15
- 238000005406 washing Methods 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 238000005470 impregnation Methods 0.000 claims description 39
- 239000000839 emulsion Substances 0.000 claims description 26
- 238000002360 preparation method Methods 0.000 claims description 22
- 239000003292 glue Substances 0.000 claims description 20
- 239000002562 thickening agent Substances 0.000 claims description 14
- 238000007598 dipping method Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 210000003813 thumb Anatomy 0.000 claims description 7
- NSEQHAPSDIEVCD-UHFFFAOYSA-N N.[Zn+2] Chemical group N.[Zn+2] NSEQHAPSDIEVCD-UHFFFAOYSA-N 0.000 claims description 6
- 239000005018 casein Substances 0.000 claims description 6
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical group NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 6
- 235000021240 caseins Nutrition 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 208000035126 Facies Diseases 0.000 claims description 4
- 241000411545 Punargentus Species 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 210000001161 mammalian embryo Anatomy 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract 2
- 238000004528 spin coating Methods 0.000 abstract 1
- 230000035699 permeability Effects 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
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- Gloves (AREA)
Abstract
The invention relates to a rubber thermosensitive mechanical embossing glove and a production technology thereof. The production technology of the rubber thermosensitive mechanical embossing glove comprises procedures of preparing materials, mixing latex, immersing the latex, thermosensitive mechanical embossing, drying, washing and re-drying. The procedure of preparing materials is covering a glove base on a hand die, increasing the hand die temperature to 70 DEG C, immersing the hand die with the glove base into impregnating latex obtained from the latex mixing procedure for 1 to 2 seconds and performing spin coating for 2 times; the procedure of thermosensitive mechanical embossing is enabling the glove with a downward palm after latex impregnating to enter into a patterned die plate and performing thermosensitive mechanical embossing for 5 seconds; the rubber thermosensitive mechanical embossing glove is obtained after the drying, washing and re-drying procedures. The rubber thermosensitive mechanical embossing glove produced through the production procedure has the advantages of improving holding force and protecting force due to the fact that mechanical embossing is performed on the internal of the palm after latex impregnating, being soft in texture, light and sensitive and good in breathability, enabling a person not easy to get tired after long time wearing and being particularly applicable to operation applications in mechanical industries.
Description
Technical field
The present invention relates to a kind of protective gloves and preparation technology thereof, particularly a kind of latex temperature-sensitive machinery embossing gloves and preparation technology thereof.
Background technology
Reinforcement along with mankind's sense of self-protection, to the safeguard function of safety protection glove, require also more and more higher, application number 201110001374.1, denomination of invention is a kind of manufacture method of gum dipping safety protection gloves, disclose a kind of methyl alcohol that first gloves base dipping is added to calcium nitrate, then flooded latex and make impregnation safety gloves; Application number 200810021536.6, denomination of invention: the patent of invention of antislip gumming gloves and production method thereof, disclose a kind ofly before dipping process, first gloves base is carried out to the production technology that some pearl is processed, make antislip gumming gloves, the protective gloves that applicable garden management is used.But the problems such as said method all exists the inner gripping power of gloves palm and protection is inadequate.
Summary of the invention
The object of this invention is to provide the inner gripping power of a kind of raising palm and protection, in use better prevent latex temperature-sensitive machinery embossing gloves and preparation technology thereof that liquid enters.
For reaching above object, the technical scheme that the present invention takes is: the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves, is characterized in that: comprise the following steps: successively through getting the raw materials ready, impregnation, impregnation, temperature-sensitive machinery embossing, oven dry, washing and baking operation again.
Below the further improvement to technique scheme:
Described procedure for preparation, raw material is natural emulsion, thickener and heat sensitizer.
Described natural emulsion mass concentration is 61%; Described thickener is casein, and consumption is natural emulsion 5 ‰; Described heat sensitizer is zinc ammonium complex ion, and consumption is natural emulsion 2%.
Described impregnation operation, is that gloves embryo is inserted in after fingerprint, and fingerprint temperature is increased to 70 ℃, then immerses in the dipping glue that impregnation operation obtains, and controls the impregnation degree of depth, and the impregnation time is 1-2s, even glue 2 times.
In described impregnation operation, the impregnation degree of depth is for to count 3.5 ± 0.5cm from thumb finger tip.
In described impregnation operation, the impregnation degree of depth is for to count 11 ± 1.5cm from thumb finger tip.
Described temperature-sensitive machinery embossing operation, is that the gloves facies palmaris after impregnation is entered on figuratum template down, carries out temperature-sensitive machinery embossing 5s.
Described impregnation operation, is that natural emulsion, heat sensitizer and thickener are joined in liquid mixing agitator in the ratio in procedure for preparation, controls rotating speed 100 r/min, stirs half an hour, obtains flooding glue.
Described baking operation, puts into baking oven by the gloves after temperature-sensitive machinery embossing, dries for the first time 80 ℃ of temperature, 15 minutes time; Described washing step, enters the gloves after drying for the first time in soaked pond and washes 15min; Described baking operation again, by the gloves after washing, dries temperature 80-100 ℃, time 60-80 minute for the second time.
The prepared product of preparation technology of temperature-sensitive machinery embossing gloves, technical indicator is as follows: adhesive force (peel strength): 40N; Thickness: glue face thickness 2mm; Tearing strength: meet and exceed level Four (>=75N); Wear-resistant power: in >=2000 cycles, reach three grades of levels.
The present invention adopts above technical scheme, compared with prior art has the following advantages:
The gloves that adopt explained hereafter of the present invention to go out, carry out mechanical graining after the inner impregnation of palm, have better improved gripping power and protection; Coating can prevent entering of liquid, and the gloves quality that makes is soft, light and handy sensitive, good permeability, wears for a long time indefatigability, is particularly suitable for machinery industry operation.
The specific embodiment
Except as otherwise noted, the percentage adopting in the present invention is mass percent.
embodiment 1
A preparation technology for latex temperature-sensitive machinery embossing gloves, comprises the following steps:
(1) get the raw materials ready: natural emulsion, thickener, heat sensitizer;
Described natural emulsion is three tree board natural emulsions of Thailand of import, 205Kg/ bucket, and mass concentration is 61%;
Thickener is casein, and consumption is natural emulsion 5 ‰;
Heat sensitizer is zinc ammonium complex ion, and consumption is natural emulsion 2%, the adding of heat sensitizer is conducive to rear operation and carries out temperature-sensitive machinery embossing.
Through lot of experiments, thickener is casein, and consumption is natural emulsion 5 ‰; Heat sensitizer is zinc ammonium complex ion, and consumption is natural emulsion 2% time, and the product quality making is best, therefore preferred this proportioning.
(2) impregnation: natural emulsion, heat sensitizer and thickener are joined in liquid mixing agitator in the ratio of step (1), control rotating speed 100 r/min, stir half an hour, obtain flooding glue.
(3) impregnation: gloves embryo is inserted in after fingerprint; fingerprint temperature is increased to 70 ℃; immerse again the dipping glue 1-2s that step (2) obtains; the impregnation degree of depth is for to count 3.5 ± 0.5cm from thumb finger tip; even glue 2 times; glue is uniformly distributed; avoid occurring glue beans; control the different impregnation degree of depth; the gloves that make are different to the degree of palm protection, and the impregnation degree of depth is darker, larger to the degree of palm protection; the product quality optimum of the impregnation degree of depth for making when thumb finger tip is counted 3.5 ± 0.5cm, therefore preferred this technological parameter.
(4) temperature-sensitive machinery embossing: the gloves facies palmaris after step (3) impregnation is entered on figuratum template down, carry out temperature-sensitive machinery embossing 5s, after the inner impregnation of palm, mechanical graining has better improved gripping power and protection.
(5) dry: the gloves that step (4) pressed to line are put into baking oven, dry for the first time 80 ℃ of temperature, 15 minutes time.
(6) washing: the gloves after step (5) is dried enter in soaked pond washes 15min.
(7) dry again: by the gloves after washing, then dry for the second time, temperature 80-100 ℃, time 60-80 minute, obtains latex temperature-sensitive machinery embossing gloves product.
As follows by the gloves specific targets of producing after technique of the present invention:
Adhesive force (peel strength): 40N;
Thickness: glue face thickness 2mm;
Tearing strength: meet and exceed level Four (>=75N);
Wear-resistant power: in >=2000 cycles, reach three grades of levels;
Anti-aging: ageing resistace reaches 1 grade of product requirement;
Pliability: softness;
Gas permeability: good air permeability.
embodiment 2
A preparation technology for latex temperature-sensitive machinery embossing gloves, comprises the following steps:
(1) get the raw materials ready: natural emulsion, thickener, heat sensitizer;
Described natural emulsion is three tree board natural emulsions of Thailand of import, 205Kg/ bucket, and mass concentration is 61%;
Thickener is casein, and consumption is natural emulsion 5 ‰;
Heat sensitizer is zinc ammonium complex ion, and consumption is natural emulsion 2%, the adding of heat sensitizer is conducive to rear operation and carries out temperature-sensitive machinery embossing.
Through lot of experiments, thickener is casein, and consumption is natural emulsion 5 ‰; Heat sensitizer is zinc ammonium complex ion, and consumption is natural emulsion 2% time, and the product quality making is best, therefore preferred this proportioning.
(2) impregnation: natural emulsion, heat sensitizer and thickener are joined in liquid mixing agitator in the ratio of step (1), control rotating speed 100 r/min, stir half an hour, obtain flooding glue.
(3) impregnation: gloves embryo is inserted in after fingerprint; fingerprint temperature is increased to 70 ℃,, then immerse the dipping glue 1-2s that step (2) obtains; the impregnation degree of depth is for to count 11 ± 1.5cm from thumb finger tip; even glue 2 times, is uniformly distributed glue, avoids occurring glue beans; control the different impregnation degree of depth; the gloves that make are different to the degree of palm protection, and the impregnation degree of depth is darker, larger to the degree of palm protection.
(4) temperature-sensitive machinery embossing: the gloves facies palmaris after step (3) impregnation is entered on figuratum template down, carry out temperature-sensitive machinery embossing 5s.
(5) dry: the gloves that step (4) pressed to line are put into baking oven, dry for the first time 80 ℃ of temperature, 15 minutes time.
(6) washing: the gloves after step (5) is dried enter in soaked pond washes 15min.
(7) dry again: by the gloves after washing, then dry for the second time, temperature 80-100 ℃, time 60-80 minute, obtains latex temperature-sensitive machinery embossing gloves.
As follows by the gloves specific targets of producing after technique of the present invention:
Adhesive force (peel strength): 40N;
Thickness: glue face thickness 2mm;
Tearing strength: meet and exceed level Four (>=75N);
Wear-resistant power: in >=2000 cycles, reach three grades of levels;
Anti-aging: ageing resistace reaches 1 grade of product requirement;
Pliability: softness;
Gas permeability: good air permeability.
The gloves that adopt explained hereafter of the present invention to go out, carry out mechanical graining after the inner impregnation of palm, have better improved gripping power and protection; Coating can prevent entering of liquid, and quality is soft, light and handy sensitive, good permeability, wears for a long time indefatigability, is particularly suitable for machinery industry operation.
Claims (10)
1. a preparation technology for latex temperature-sensitive machinery embossing gloves, is characterized in that: comprise the following steps: successively through getting the raw materials ready, impregnation, impregnation, temperature-sensitive machinery embossing, oven dry, washing and baking operation again.
2. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 1, is characterized in that: described procedure for preparation, raw material is natural emulsion, thickener and heat sensitizer.
3. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 2, is characterized in that: described natural emulsion mass concentration is 61%; Described thickener is casein, and consumption is natural emulsion 5 ‰; Described heat sensitizer is zinc ammonium complex ion, and consumption is natural emulsion 2%.
4. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 1, it is characterized in that: described impregnation operation, that gloves embryo is inserted in after fingerprint, fingerprint temperature is increased to 70 ℃, immerse again in the dipping glue that impregnation operation obtains, control the impregnation degree of depth, the impregnation time is 1-2s, even glue 2 times.
5. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 4, is characterized in that: the described impregnation degree of depth is for to count 3.5 ± 0.5cm from thumb finger tip.
6. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 4, is characterized in that: the described impregnation degree of depth is for to count 11 ± 1.5cm from thumb finger tip.
7. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 1, is characterized in that: described temperature-sensitive machinery embossing operation is that the gloves facies palmaris after impregnation is entered on figuratum template down, carries out temperature-sensitive machinery embossing 5s.
8. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 1, it is characterized in that: described impregnation operation, that natural emulsion, heat sensitizer and thickener are joined in liquid mixing agitator in the ratio in procedure for preparation, control rotating speed 100 r/min, stir half an hour, obtain flooding glue.
9. the preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 1, is characterized in that: described baking operation, the gloves after temperature-sensitive machinery embossing are put into baking oven, and dry for the first time 80 ℃ of temperature, 15 minutes time; Described washing step, enters the gloves after drying for the first time in soaked pond and washes 15min; Described baking operation again, by the gloves after washing, dries temperature 80-100 ℃, time 60-80 minute for the second time.
10. the prepared product of preparation technology of a kind of latex temperature-sensitive machinery embossing gloves according to claim 1, is characterized in that: technical indicator is as follows: adhesive force (peel strength): 40N; Thickness: glue face thickness 2mm; Tearing strength: meet and exceed level Four (>=75N); Wear-resistant power: in >=2000 cycles, reach three grades of levels.
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| CN201310536861.7A CN103535927B (en) | 2013-11-04 | 2013-11-04 | A kind of latex temperature-dependent mechanical embossing gloves and preparation technology thereof |
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| CN201310536861.7A CN103535927B (en) | 2013-11-04 | 2013-11-04 | A kind of latex temperature-dependent mechanical embossing gloves and preparation technology thereof |
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| CN103535927B CN103535927B (en) | 2015-09-09 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104957810A (en) * | 2015-06-29 | 2015-10-07 | 山东星宇手套有限公司 | Environment-friendly latex slip-proof glove and preparation technology thereof |
| CN105495785A (en) * | 2016-01-29 | 2016-04-20 | 山东星宇手套有限公司 | Fifteen-stitch nylon and polyurethane filament moon-pattern butyronitrile foaming glove and preparation process thereof |
| CN105533869A (en) * | 2016-01-29 | 2016-05-04 | 山东星宇手套有限公司 | Fifteen-stitch nylon and spandex filament butyronityile superfine foaming glove and preparation process thereof |
| CN106174816A (en) * | 2016-08-31 | 2016-12-07 | 山东星宇手套有限公司 | A kind of temperature-sensitive embossing partly soaks fingerprint |
| CN106313396A (en) * | 2016-08-31 | 2017-01-11 | 山东星宇手套有限公司 | Thermo-sensitive embossing machine and embossing method |
| CN106313383A (en) * | 2016-08-31 | 2017-01-11 | 山东星宇手套有限公司 | Heating system and method for thermosensitive embossing production line |
| CN106360856A (en) * | 2016-08-31 | 2017-02-01 | 山东星宇手套有限公司 | Thermosensitive embossing setting fingerprint and manufacturing method of glove |
| CN106360855A (en) * | 2016-08-31 | 2017-02-01 | 山东星宇手套有限公司 | Thermo-sensitive embossing flat-plate hand mold |
| CN106496674A (en) * | 2016-11-02 | 2017-03-15 | 山东星宇手套有限公司 | A kind of injecting glue embossing gloves and its preparation technology |
| WO2018072106A1 (en) * | 2016-10-19 | 2018-04-26 | 山东星宇手套有限公司 | Method for preparing natural latex thermosensitive embossed slip-proof gloves |
| CN108299689A (en) * | 2018-04-28 | 2018-07-20 | 山东星宇手套有限公司 | Natural emulsion composite mortar and preparation method thereof, protective gloves and preparation method thereof |
| WO2019192276A1 (en) * | 2018-04-04 | 2019-10-10 | 汇鸿 （南通） 安全用品有限公司 | Ultra thin glove and preparation method therefor |
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| CN104957810A (en) * | 2015-06-29 | 2015-10-07 | 山东星宇手套有限公司 | Environment-friendly latex slip-proof glove and preparation technology thereof |
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| CN105533869A (en) * | 2016-01-29 | 2016-05-04 | 山东星宇手套有限公司 | Fifteen-stitch nylon and spandex filament butyronityile superfine foaming glove and preparation process thereof |
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| CN106174816A (en) * | 2016-08-31 | 2016-12-07 | 山东星宇手套有限公司 | A kind of temperature-sensitive embossing partly soaks fingerprint |
| CN106313396A (en) * | 2016-08-31 | 2017-01-11 | 山东星宇手套有限公司 | Thermo-sensitive embossing machine and embossing method |
| CN106313383A (en) * | 2016-08-31 | 2017-01-11 | 山东星宇手套有限公司 | Heating system and method for thermosensitive embossing production line |
| CN106360856A (en) * | 2016-08-31 | 2017-02-01 | 山东星宇手套有限公司 | Thermosensitive embossing setting fingerprint and manufacturing method of glove |
| CN106360855A (en) * | 2016-08-31 | 2017-02-01 | 山东星宇手套有限公司 | Thermo-sensitive embossing flat-plate hand mold |
| WO2018072106A1 (en) * | 2016-10-19 | 2018-04-26 | 山东星宇手套有限公司 | Method for preparing natural latex thermosensitive embossed slip-proof gloves |
| CN106496674A (en) * | 2016-11-02 | 2017-03-15 | 山东星宇手套有限公司 | A kind of injecting glue embossing gloves and its preparation technology |
| WO2019192276A1 (en) * | 2018-04-04 | 2019-10-10 | 汇鸿 （南通） 安全用品有限公司 | Ultra thin glove and preparation method therefor |
| CN108299689A (en) * | 2018-04-28 | 2018-07-20 | 山东星宇手套有限公司 | Natural emulsion composite mortar and preparation method thereof, protective gloves and preparation method thereof |
| WO2019205206A1 (en) * | 2018-04-28 | 2019-10-31 | 山东星宇手套有限公司 | Natural latex composite slurry and preparation method therefor, and protective gloves and manufacturing method therefor |
| CN111363211A (en) * | 2018-04-28 | 2020-07-03 | 山东星宇手套有限公司 | Natural latex composite slurry and preparation method thereof, and protective gloves and preparation method thereof |
| CN111363211B (en) * | 2018-04-28 | 2022-07-26 | 山东星宇手套有限公司 | Natural latex composite slurry and preparation method thereof, and protective gloves and preparation method thereof |
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