CN103552321B - 带图象的层压材料 - Google Patents

带图象的层压材料 Download PDF

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CN103552321B
CN103552321B CN201310388396.7A CN201310388396A CN103552321B CN 103552321 B CN103552321 B CN 103552321B CN 201310388396 A CN201310388396 A CN 201310388396A CN 103552321 B CN103552321 B CN 103552321B
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interlayer
interlayer sheet
image
sheet
glass
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CN103552321A (zh
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M.C.雷诺
A.J.L.安德森
G.M.麦克卢斯基
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Kuraray U.S. limited-liability company
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Priority claimed from AUPQ9830A external-priority patent/AUPQ983000A0/en
Priority claimed from AUPR0567A external-priority patent/AUPR056700A0/en
Priority claimed from AUPR2194A external-priority patent/AUPR219400A0/en
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    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
    • B32B17/10935—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin as a preformed layer, e.g. formed by extrusion
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    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C—CHEMISTRY; METALLURGY
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Abstract

一种制作带图象的层压材料（10）的方法和装置。用基于溶剂的墨、漆或染料系统把一图象（18）印刷在一聚乙烯醇缩丁醛夹层（16）上。该夹层（16）把两片材料（12、14）连接形成该层压制品。

Description

带图象的层压材料
本申请是原案申请日为2001年9月3日、申请号为01818285.2(PCT/AU01/01106)、发明名称为《带图象的层压材料》的发明专利申请的分案申请。
技术领域
本发明涉及带图象的层压材料的制作，可从该材料的一面或两面看到该图象。该材料可用任何合适基质如玻璃、聚碳酸酯、丙烯酸、纤维素醋酸丁酸酯（CAB）或其他热塑树脂制成。该图象可为图案、艺术作品、书写标记或任何其他可见物。
背景技术
层压材料，特别是层压玻璃，作为建筑材料有许多应用。比方说可用它们制作窗户、墙壁、门和屏风。也可用它们制作咖啡桌和其它类小家具。层压材料由于较之普通玻璃片其固有的安全性而用于多种场合。层压材料一般用一聚乙烯醇缩丁醛夹层或一基于聚醚的脂族热塑聚氨酯夹层如由Morton International , Inc.生产的PE399 Krystalflex薄膜等将两张材料片连接而成。该生产过程一般包括两个步骤。在一个步骤中把该夹层置于这两张材料片之间后在通过压辊的同时加热，两压辊挤压这两张材料片而与该软化的夹层接触。另一个步骤是在一高压蒸锅中对如此形成的层压制品进行处理，完成该粘合过程。
在许多应用场合要求在该层压材料上生成某种图象。该图象可起装饰作用，也可以通过部分地或者完全地阻挡通过该层压板观看起到一功能性目的。迄今为止，制作带图象的层压材料的各种方法存在严重的实际问题。在层压材料如玻璃上形成图象的一种方法是用丝网印刷把该图象印刷到该制成的层压材料上。这一工艺很麻烦，所能生成的图象在颜色和细节方面受到限制。例如，多色图象需要分步印刷各种颜色。此外，图象只能形成在单块玻璃片上，这在实际上意味着，无法用通常方式形成图象，以便其后可任意切割玻璃片。
还有用其他方法在层压材料上形成图象的。这些方法是把其上有图象的一层材料引入该层压板中。该方法的缺点是，各张材料片之间的粘合强度直接受到影响。这是因为其上有图象的材料造成粘合面积减小。
在美国专利No.4,968,553所述另一种方法中，用一张印刷有图象的聚氨酯与两张玻璃片层压在一起形成一张带图象的层压制品。该张聚氨酯用基于非溶剂的墨印刷，从而不与尿烷起化学反应。这一工艺的商业应用由于需要使用聚氨酯片而非普通夹层如PVB而受到限制。
巴西专利申请910 4893所述一种方法是直接在PVB夹层上印刷。该申请在层压前使用丙烯酸漆在PVB上形成一图象。但丙烯漆在层压时非常不利于该夹层与相邻玻璃表面之间的粘合。
发明内容
本发明的一个方面是提供一种制作带图象的层压材料的方法，包括如下步骤：使用基于溶剂的墨，油漆或者染料系统在一张夹层片的第一表面上形成一图象、把该片夹层置于两张材料片之间、通过激活该夹层把这两张材料片连接形成该层压制品。
本发明的第二方面是提供一张带图象的层压板，该层压板包括由一夹层连接的两张材料片，该图象由基于溶剂的墨、漆或染料系统形成在该夹层的第一表面上。
本发明的第三方面是提供一种夹层，在该夹层的第一表面上用基于溶剂的墨、漆或染料系统形成一图象。
该连接步骤可包括把另外的一层或多层夹层连接到该带图象夹层上。在本发明一种形式中，另外一夹层连接到该带图象夹层的带图象表面上。在本发明的另一种形式中，另外的夹层可连接到带图象夹层的两个表面上。也可在带图象夹层的两个表面上连接多层夹层。
这些夹层最好作为层压过程的一部分互相连接。
最好是，该夹层由聚乙烯醇缩丁醛制成。该夹层也可由基于聚醚的脂族热塑聚氨酯等制成。
本发明的另一方面提供一种制作带图象的层压材料的方法，包括下列步骤：机械稳定一张夹层片、在该夹层的第一表面上形成一图象、除去该机械稳定、把该夹层置于两张材料片之间、然后通过激活该夹层把这两张材料片连接成该层压制品。
该连接步骤可包括把另外一层或多层夹层连接到该带图象夹层上。在本发明一种形式中，另外一层夹层连接到该带图象夹层的带图象表面上。在本发明的另一种形式中，另外的夹层可连接到带图象夹层的两个表面上。也可在带图象夹层的两个表面上连接多层夹层。
这些夹层最好作为层压过程的一部分互相连接。
在这方面最好是，这些夹层由聚乙烯醇缩丁醛制成。这些夹层也可由基于聚醚的脂族热塑聚氨酯如PE399 Krystalflex®薄膜制成。该图象最好使用基于溶剂的墨、漆或染料系统形成在该夹层上。这些系统可包括颜料和/或其他添加剂。
在本发明一种很优选的形式中，图象使用压电的按需即喷数字印刷方法印刷在该夹层上。这种方法使用基于溶剂的墨、漆或染料系统。
在本发明的一种形式中，用该夹层与一可除去膜片或基质之间的机械连接实现该机械稳定性。该可除去膜片可采用任何合适形式。该可除去膜片可为一张直接粘在该夹层上的衬纸。该可除去膜片也可为一张以任何合适方式粘接在该夹层边缘上的合适片材料。例如可用胶带进行该粘接。可除去的该衬底的合适材料也包括纤维强化乙烯树脂。在某些工艺中该机械稳定也可通过一连接提供给该印刷机的一部件上。
该可除去膜片或基质在图象形成过程中绷紧该夹层，使得夹层在形成图象的工艺期间被处理而不发生变形。适合于形成图象的工艺需要以一致的速率在一系统中移动该夹层，防止印刷时出现“磁头痕迹和遗漏”。此外，适合于在该夹层上形成图象的许多工艺涉及到使用热量。该夹层对热很敏感，在温度为60℃或以上时一般会失去其机械强度的大部分。使用衬底膜片或基质可在使用热量的系统中处理该夹层而不拉长或损坏该夹层。
本领域普通技术人员显然可知，本说明书中使用的术语“基于溶剂的墨、漆或染料系统”指这样一种系统，在该系统中，一合适有机溶剂或多种溶剂中含有着色剂。例如，在使用墨的情况下，一颜料扩散在一有机溶剂或多种溶剂中。这些墨包括所谓的“油基”墨。
用基于溶剂的墨、漆或染料系统在该夹层上形成图象不会影响该夹层与片材之间的粘合过程。其原因是，基于溶剂的墨、漆或染料系统蚀刻入夹层的表面，造成该夹层与相邻片材分离、从而不与相邻片材粘合的区域。这与例如汇集在夹层表面、从而使夹层表面网状化的基于丙烯酸的颜料载体成鲜明对照。这造成夹层的无法与相邻片材粘合的区域，从而无法形成层压制品。
在使用基于溶剂的墨、特别是油基墨的情况下，该有机溶剂被形成用来对颜料牢牢粘接到该夹层上起到重大作用。
在本发明的一种形式中使用另外夹层可提高该层压制品的粘合强度。这些另外的夹层可连接在该带图象夹层的一个表面上。该表面可为其上有图象的表面。
另外的夹层也可连接到带图象夹层的任一表面上或其两个表面上。
另外的夹层可作为层压过程的一部分连接到带图象夹层上。即，这些夹层（包括带图象夹层）一起放置或叠置在两张层压材料之间，从而当层压整个夹层-片材的夹心制品时粘合在一起。
此外，另外的夹层还可保护图象免受光、特别是阳光中的紫外线的照射。这有助于防止图象中的墨褪色、保持图象清晰、提高图象在该层压材料中的寿命。
最好是，在该层压工艺中，使用该夹层之前，使该图象固化在该夹层上。根据环境温度，在某些情况下固化时间达24小时或24小时以上是有利的。这一改进的原因据信是由于溶剂进一步蒸发，从而余下的墨、漆或染料进一步蚀刻入该夹层中。
可在任何合适的夹层上形成该图象。例如，图象可印刷在这样的夹层上，即一旦层压在两张材料片之间就透明的夹层上。也可使用比方说经上色而变得不透明或局部不透明的夹层。可使用适合于层压特殊片材的任何厚度的夹层。多个常用夹层的厚度为0.38mm的倍数。
下面结合附图和例子例示、说明本发明。
附图简要说明
图1为本发明一张层压安全玻璃第一实施例的示意图，为说明起见示出局部切去的各层；
图2为图1所述该张安全玻璃的示意剖面图；
图3为本发明一张层压安全玻璃第二实施例的示意图，为说明起见示出局部切去的各层；
图4为图3所述该张安全玻璃的示意剖面图；
图5为本发明一张层压安全玻璃第三实施例的示意图，为说明起见示出局部切去的各层；
图6为图5所述该张安全玻璃的示意剖面图；
图7为本发明一张层压安全玻璃第四实施例的示意图，为说明起见示出局部切去的各层；
图8为图7所述该张安全玻璃的示意剖面图；
图9为实现本发明方法所使用的第一印刷机的端视示意图；
图10为图9所示印刷机的正视图；
图11为实现本发明方法所使用的第二印刷机的端视示意图；
图12为类似图11的视图，示出如何把夹层传送给该印刷机；
图13为实现本发明方法所使用的第三印刷机的端视示意图；
图14为实现本发明方法所使用的第四印刷机的端视示意图；
图15为图14所示印刷机的端视示意图；
图16为图15的局部放大图；以及
图17为一玻璃层压工艺中的设备和步骤的示意图。
本发明最佳实施方式
以下说明和例子指按照本发明和使用本发明方法使用PVB夹层制作层压安全玻璃制品。本发明同样适用于其他层压材料和使用不同形式的夹层。
图1－8示出按照本发明形成的带图的层压安全玻璃的四个不同实施例。形成图象的过程下面结合图9－16说明，层压过程结合图17说明。
参见图1和2，层压安全玻璃10由其上使用基于溶剂的墨印刷一图象18的一PVB夹层16连接两张玻璃片12、14而成。
图3和4示出本发明一张层压安全玻璃的第二实施例。各附图中相同部件用同一标号表示。在本发明该形式中，其上不印刷图象的另外两层PVB夹层20、22插入在夹层16与对应玻璃片12、14之间。即，夹层16的其上印刷有图象18的表面与和该表面相邻的该张玻璃片12之间有第二张夹层片20。 第三张夹层片22插入在夹层16的与其上有图象18的表面相反的表面与和该相反表面相邻的该张玻璃片14之间。
图5和6示出本发明一张层压玻璃的第三实施例。各附图中相同部件用同一标号表示。在本发明该形式中，另外只有一张其上不印刷图象的PVB夹层插入在夹层16的其上印刷有图象18的表面与相邻玻璃片12之间。
图7和8示出本发明一张层压安全玻璃的第四实施例。各附图中相同部件用同一标号表示。在本发明该形式中，另外一张PVB夹层24使用基于溶剂的墨印刷有图象18。印刷有图象18的夹层16与24相邻，另一张PVB夹层20插入在夹层16的其上印刷有图象18的表面和相邻玻璃片12之间。可用其上印刷有相间距图象18的两层夹层16、24提供当观看层压安全玻璃10时，在整个图象中的更大的深度。
图9－16示出可用来在一PVB夹层上形成图象的一些喷墨印刷机。这些印刷机为市场上有售的宽型喷墨印刷机。本领域普通技术人员显然可知，为了使用这些印刷机在任何基质上印刷一图象，必需以通常方式向该印刷机提供合适图象数据。在大多数情况下，这涉及首先获得或准备一数字化图象。可在一普通计算机上从一存储介质如CD或使用普通扫描技术扫描一原始图象来生成合适数字图象。使用合适计算机程序如Adobe® Photoshop®生成一PostScript文件。可通过合适界面用PostScript文件向该印刷机提供复制该图象所需数据。在某些情况下，在向该印刷机输出复制图象所需数据前可使用辅助软件如Postershop ®RIP (光栅图象处理) 定标和矫正颜色。作为本发明方法的一部分，下面说明四种不同印刷机的特征及其使用。
图9和10简示出一称为MMT（Metro Media Technologies International Inc.）喷漆系统的宽型喷墨印刷机的各部件。该印刷机使用大转鼓32，该大转鼓32用辐条36可转动地支撑在一轴38上。该印刷机的机架34紧靠一装在一滑架42上的印刷头40支撑该转鼓。如图10中箭头46所示，该滑架42响应印刷机控制装置（未示出）而轴向移动印刷头40。印刷头40如所公知地受印刷机电子器件（未示出）驱动。
在该过程中PVB夹层16因贴在转鼓32表面上而获得机械稳定。为此可把夹层16铺在转鼓上后使用虚线44所示普通胶带把该夹层的边缘粘在转鼓32上。我们发现，把PVB夹层如此连接在印刷机30的转鼓32上即可使它获得足够的机械稳定，从而可如所公知地随着转鼓32在印刷头40旁的转动进行精确印刷。
喷墨印刷机30使用基于溶剂的汽车漆，该溶剂为MIBK（甲基·异丁基酮）。
图10、11简示出一Idanit®喷墨印刷机50。该喷墨印刷机50与结合图9和10所述印刷机相似，即一合适轴60支撑一转鼓58。一由一底座54和立柱52构成的机架把两印刷头56置于紧靠转鼓58的位置上。在该例中转鼓58上打有一连串孔（未示出），真空作用在转鼓内部。用真空保持并机械稳定PVB夹层16。如图12所示，夹层16从一供料筒62经引导辊64装到该转鼓上。在大多数情况下，夹层16的前边缘首先用胶带粘在转鼓上，防止夹层与印刷头56接触。一旦一大段夹层16包在转鼓上，由孔（未示出）施加的真空保持夹层，然后如所公知，随着夹层16因转鼓58的转动而移动，印刷头56进行印刷。
印刷机50使用任何合适的基于溶剂的颜料墨。
图13简示出一压电的按需即喷的宽型Vutek5300数字印刷机。该印刷机由VutekInc.制造。
印刷机70运行时，待印刷的材料在一连串滚轮上通过并通过一印刷头90。印刷机70把待印刷材料张紧在滚轮82与84之间而提供一稳定的印刷表面。由于夹层16的特性，它在印刷过程中必需稳定。为此使用一与夹层16一起通过印刷机70的牺牲片材72。该牺牲片材72可为纤维强化的乙烯树脂或纸或在中等张力下不伸长的任何其他材料。在某些情况下，夹层16可用胶带粘在牺牲卷材72上。在其他情况下，夹层16与卷材72同时穿过印刷机即可提供所需机械稳定性。
如该图所示，夹层16由一座落在三个滚轮78中两个滚轮上的供料筒74供应。一牺牲支撑片材72由一也座落在滚轮78中两个滚轮上的类似筒76供应。这可确保两材料以大致相同的速度供应。夹层16和片材72在绕过在其间进行印刷的定位滚轮82和84前绕过张紧滚轮78和80。绕过滚轮84后夹层16、片材72在卷绕到卷取滚轮88前绕过另一滚轮86。印刷机70在滚轮82与84之间张紧片材72而提供稳定的印刷表面。夹层16紧贴片材，而片材72保持张紧，使得夹层16不受很大张力。与任何其他进行精确印刷的基质一样，这可确保夹层16在印刷头90前方通过时不伸长或变形。
印刷机70使用基于溶剂的颜料墨如可从 Inkwear Inc. 购得的墨。
一种称为ULTRAVU-3的合适墨可有如下颜色：
青色 淡青色
洋红 IID 淡洋红HD
黄色 黑色
橘黄色 绿色
这些墨含有80％的乙二醇-丁醚乙酸、20％的环己酮、10％的甲基-2-吡咯烷酮（淡洋红HD）和制造商未公开的其他成分。
为另一种称为Arizona印刷机的类似印刷机生产的墨包括如下成分：
成分名称 百分比
2-buxtoxethyl 乙酸 70%
丙醇, 1（或2）-（2-甲氧亚甲基乙氧基）-乙酸 30%
炭墨 1.0-5.0％
乙烯基氯-乙基乙酸聚合物 1.0-5.0％
丙烯酸共聚物 1.0-5.0％
NJ TS RN 12307-5038P 1.0-5.0％
图14－16简示出一平台式压电的按需即喷的喷墨印刷机如台湾Eastech生产的Mutoh Falcon Jet 6100。该Falcon Jet 6100 基本上为一台标准的Mutoh Falcon Jet6000 ，只是印刷头稍有改动。该改动预热了印刷头中的墨以改变墨的粘度，使得墨合适流动。这一改动对于在该印刷机中使用油基墨是必要的。
如附图所示，平台式印刷机100有一支撑一上台板106的机架101。存储在一供料筒110上的夹层16越过台板106传给卷取辊112。夹层由分别位于印刷头108附近夹层上方和下方的一对夹辊102和104传动。下辊102如通常那样受驱而使夹层16以受控速度向前通过印刷头108。夹层16在夹辊104和102附近的平台106上的定位，机械稳定该夹层以受印刷头的印刷。即，夹层基本不受张力，可与印刷头108精确对齐，从而可以360dpi或720dpi在夹层上印刷高质量图象。Mutoh Falcon Jet 6100印刷机通常被提供有来自一合适计算机的数据。为了驱动该印刷机，该计算机使用如Onyx® Postershop® 的软件把postscript数据转换成光栅图象处理格式供该印刷机使用。Mutoh Falcon Jet 6100使用的墨由Eastech提供，其成分如下：
着色剂 8%
乙醇乙酯 30%
乙酸乙酯 8.5％
甲基乙基酮 7%
N-丁基乙酸 17.5%
Ethycese 乙二醇-甲基 29%
一旦用上述任一技术在夹层上形成图象，就如所公知地用该夹层形成一张层压玻璃。图17简示出该层压过程。
该层压过程包括把玻璃片原料120从一台122上方传到一清洗机124。已印刷有图象的聚乙烯缩醇丁醛夹层通常在约6－7℃的受控湿度的温度中被存储在一存储区126中。玻璃片120传到一保持环境清洁的储藏室128中一台130上。然后把它们传到一传递台132上，在该传递台上，把带图象夹层叠置在第一张玻璃片的表面上。第二张玻璃片叠置到带图象夹层顶面上与第一张玻璃片对齐，形成一玻璃夹层（带图象）的玻璃夹层板。
也可把任何所需另外夹层插入在带图象夹层与各玻璃片之间。例如，可把一夹层叠置在第一玻璃片上，然后是带图象夹层、另一夹层和第二玻璃片。从而形成一玻璃片-夹层-带图象夹层-夹层-玻璃片夹层板。
该夹层板通过一工作温度为约200℃的炉子134后从压力约为10bar的两压辊之间通过，使得夹层软化、与两玻璃片粘接在一起。压辊确保除去该层压物中空气。然后把如此形成的夹层板传送到一工作在135℃温度、11.5bar压力下的高压蒸锅中一般高压蒸约3.5小时。
例1
使用结合图1和2所述单张0.38mm厚PVB夹层制备层压玻璃样本。该张玻璃片厚3mm。用使用结合图9和10（样本A）和图13（样本B）所述印刷机和方法制备的夹层制备样本。使用上述公知层压过程生成玻璃层压制品。所得玻璃层压制品的两种样本均有良好层压强度。夹层上的图象质量优越、很少变形。
例2
用使用结合图14－16所述按需即喷的平台式印刷机印刷的PVB夹层制备层压玻璃样本。使用上述公知层压过程按照结合图3和4所述实施例形成该层压制品（三层夹层，带图象夹层两表面上各有一夹层）。
下述层压图象质量优越、不变形。
按照澳大利亚层压安全玻璃标准AS2208-1996对这些样本进行测试，包括沸腾测试和碎裂测试。分别对夹层上印刷浅色和深色图象的层压玻璃制品进行这些测试。深色图象相当于夹层单位面积上的墨、漆或染料的数量大。结果这些样本都符合该澳大利亚标准。
尽管按照本发明制作的上述某些例子符合安全玻璃或层压玻璃A级应用场合澳大利亚测试标准，但本发明不限于这些应用场合。本发明玻璃也可用于无需符合安全玻璃或A级标准的其他应用场合。
此外如上所述，尽管所述例子涉及使用玻璃片制作层压玻璃，但在本发明范围内本发明可使用其他各种适合于层压的材料如聚碳酸酯、丙烯酸、CAB和其他热塑树脂。
该制作过程中可使用不同材料片获得同样结果。例如，可用一张聚碳酸酯和一张玻璃片形成聚碳酸酯-夹层-玻璃夹层板后粘接成层压制品。
此外，在本发明范围内还可把基于聚醚的脂族热塑聚氨酯之类合适材料用作夹层。例如可用PE399 Krystalflex®薄膜形成夹层。
以上只是说明了本发明某些实施例，可在本发明范围内作出改动。

Claims (21)

1.一种带图象的层压材料制作方法，包括如下步骤：
提供在张力下将会伸长的夹层片，
机械稳定该夹层片，从而使得该夹层片基本不受张力，
在该机械稳定的夹层片的第一表面上形成一图象、除去该机械稳定，
把该夹层片插入在两张材料片之间；以及
通过激活该夹层片把这两张材料片连接在一起；
其中，通过使用基于有机溶剂的颜料墨系统在该夹层片的第一表面上面进行喷墨印刷从而形成图象，
基于有机溶剂的墨蚀刻入该夹层片的表面，造成所述夹层片与相邻片材分离、从而不与该相邻片材粘合的区域，使得在该夹层片上形成图象不会影响该夹层片与片材之间的粘合过程；
该机械稳定防止该夹层片在进行喷墨印刷过程中伸长或变形；
该夹层片为聚乙烯醇缩丁醛或基于聚醚的脂族热塑聚氨酯夹层片；和
这两张材料片的材料是玻璃。
2.按权利要求1所述的方法，其中，机械稳定该夹层片的步骤包括：通过一对定位在喷墨印刷头附近的夹辊使该夹层片通过印刷机的平台。
3.按权利要求1所述的方法，其中，机械稳定该夹层片的步骤是通过在图象形成过程中使用可除去膜片支撑该夹层片而执行的。
4.按权利要求3所述的方法，其中，该夹层片被暂时附加到该膜片上。
5.按权利要求3所述的方法，其中，该膜片选自纤维强化的乙烯树脂和纸。
6.按权利要求1所述的方法，其中，机械稳定该夹层片的步骤是通过将该夹层片可除去地附加到印刷机器的部件上而执行的。
7.按权利要求6所述的方法，其中，所述部件是转鼓。
8.按权利要求1所述的方法，其中，所述图象是通过用压电的按需即喷数字印刷方法而形成的。
9.按权利要求1所述的方法，其中，把这两张材料片连接在一起的步骤进一步包括：把第二夹层片插入在所述第一表面和与所述第一表面相邻的材料片之间。
10.按权利要求9所述的方法，进一步包括：把第三夹层片插入在所述第二夹层片的与所述第一表面相对的表面和与所述相对的表面相邻的材料片之间。
11.按权利要求1所述的方法，进一步包括：在至少两个夹层片的第一表面上形成相应的图象并且把该至少两个夹层片插入在所述材料片之间。
12.按权利要求1所述的方法，其中，所述夹层片是聚乙烯醇缩丁醛片。
13.按权利要求1所述的方法，其中，两张玻璃片是通过加热软化所述夹层片而连接在一起的。
14.按权利要求13所述的方法，其中，所述图象是通过用压电的按需即喷数字印刷方法而形成的。
15.按权利要求1所述的方法，其中，使用包括头的印刷机进行喷墨印刷并且在所述头中预热所述墨。
16.按权利要求1所述的方法，其中，所述带图象的层压材料符合澳大利亚层压安全玻璃标准AS2208-1996的要求。
17.按权利要求1所述的方法，其中，所述基于有机溶剂的颜料墨系统包括甲基·异丁基酮。
18.按权利要求3所述的方法，其中，所述夹层片和所述膜片绕过两个定位滚轮并且在所述两个定位滚轮之间进行喷墨印刷。
19.按权利要求4所述的方法，其中，所述夹层片和所述膜片绕过两个定位滚轮并且在所述两个定位滚轮之间进行喷墨印刷。
20.按权利要求4所述的方法，其中，所述膜片被直接粘在所述夹层片上。
21.按权利要求7所述的方法，其中，所述夹层片采用常规胶带或真空被附接到所述转鼓上。
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DE60124287T3 (de) 2015-03-19
NZ524898A (en) 2005-03-24
CN103552321A (zh) 2014-02-05
EP1322482A4 (en) 2004-06-23
DE60124287T2 (de) 2007-04-05
CA2420870C (en) 2010-06-22
EP1322482B1 (en) 2006-11-02
JP2004506559A (ja) 2004-03-04
US9403346B2 (en) 2016-08-02
AU2001285590B2 (en) 2009-10-15
EP1741552A1 (en) 2007-01-10
DE60124287D1 (de) 2006-12-14
DE20122692U1 (de) 2007-03-01
EP1322482A1 (en) 2003-07-02
JP5138142B2 (ja) 2013-02-06
WO2002018154A1 (en) 2002-03-07
US20040234735A1 (en) 2004-11-25
CN1473114A (zh) 2004-02-04
CA2420870A1 (en) 2002-03-07
EP1322482B2 (en) 2014-11-19

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