CN103694519A - Butadiene-acrylonitrile rubber capacitor sealing ring and preparation method thereof - Google Patents

Butadiene-acrylonitrile rubber capacitor sealing ring and preparation method thereof Download PDF

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Publication number
CN103694519A
CN103694519A CN201310648201.8A CN201310648201A CN103694519A CN 103694519 A CN103694519 A CN 103694519A CN 201310648201 A CN201310648201 A CN 201310648201A CN 103694519 A CN103694519 A CN 103694519A
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parts
butadiene
mixing
carbon black
paracril
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CN103694519B (en
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连秉卫
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TONGLING RIXING ELECTRONICS Co Ltd
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Abstract

The invention discloses a butadiene-acrylonitrile rubber capacitor sealing ring which is prepared from the following raw materials in parts by weight: 80-90 parts of butadiene-acrylonitrile rubber 3304, 1-2 parts of sulphur, 4-6 parts of zinc oxide, 1-1.5 parts of stearic acid, 1-2 parts of antioxygen BHT (butylated hydroxytoluene), 10-15 parts of kieselguhr, 1-2 parts of accelerant M, 1-2 parts of ammonium phosphate, 2-3 parts of resorcinol, 2-3 parts of naphthenic oil, 2.4-3.6 parts of microcrystalline wax, 1.4-1.6 parts of carnauba wax, 22-25 parts of fast extruding furnace black N660, 18-22 parts of high abrasion carbon black, 8-12 parts of aluminum hydroxide, 5-7 parts of zinc oxide, 0.3-0.7 part of accelerant DM (dibenzothiazole disulfide) and 12-15 parts of modified attapulgite. According to the butadiene-acrylonitrile rubber capacitor sealing ring, by adding the modified attapulgite, the process property of a rubber material is improved; by using an environment-friendly compounding agent, the toxic and side effects and the pollution to the environment are reduced. The butadiene-acrylonitrile rubber capacitor sealing ring is extremely good in oil resistance and higher in abrasion resistance, low in production cost and simple in process.

Description

A kind of paracril electrical condenser sealing-ring and preparation method thereof
Technical field
The present invention relates to rubber composite manufacture field, particularly a kind of paracril electrical condenser sealing-ring and preparation method thereof.
Background technology
Electrical condenser is conventionally referred to as electric capacity, is one of a large amount of electronic components that use in electronics, be widely used in circuit every aspects such as straight-through friendship, coupling, bypass, filtering, resonant tank, energy transformation, controls.Electrical condenser is comprised of housing, capacitor core, end cap and connection terminal, steeping medium is housed in capacitor casing, steeping medium is generally vegetables oil or mineral oil, the sealing position of electrical condenser is equipped with gasket or sealing-ring, because the Working environment of electrical condenser varies, some electrical condensers need to be worked under rugged environment, and that electrical condenser gasket needs is high temperature resistant, cold-resistant, acid and alkali-resistance, salt spray resistance etc. have different requirements.
Summary of the invention
The object of this invention is to provide a kind of paracril electrical condenser sealing-ring and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A paracril electrical condenser sealing-ring, is made by the raw material of following weight part: paracril 330480-90, sulphur 1-2, zinc oxide 4-6, stearic acid 1-1.5, antioxidant BHT 1-2, diatomite 10-15, captax 1-2, ammonium phosphate 1-2, Resorcinol 2-3, naphthenic oil 2-3, microcrystalline wax 2.4-3.6, carnauba wax 1.4-1.6, extrude carbon black N66022-25, high abrasion furnace carbon black N330 18-22, aluminium hydroxide 8-12, zinc oxide 5-7, altax 0.3-0.7, attapulgite modified 12-15 soon;
The described attapulgite modified raw material by following weight part is made: attapulgite 20-24, tolylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, clay 12-15, nano titanium oxide 3-4, Zirconium tetrafluoride 1-2, Union carbide A-162 1-2, ferrocene 1-2, Vulcanization accelerator TMTD 1-2, aluminium hydroxide 8-10,2-amino-2-methyl-1-propanol 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into attapulgite, clay mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
Paracril electrical condenser sealing-ring of the present invention, is made by following concrete steps: paracril 3304, sulphur, zinc oxide, stearic acid, antioxidant BHT, diatomite, captax are added in Banbury mixer, be heated to 80-90 ℃, mixing 3-5min; Then be warming up to 110-130 ℃, add again ammonium phosphate, Resorcinol, naphthenic oil, microcrystalline wax, carnauba wax, mixing 6-8min, add again fast extrusion carbon black N660, high abrasion furnace carbon black N330 to continue mixing 4-6min, add the mixing 4-6min of all the other remaining components, obtain rubber mass of the present invention.
Excellent effect of the present invention is: the present invention adds attapulgite modified, has improved the processing performance of sizing material, uses environment-friendly type Synergist S-421 95, reduces its toxic side effect and the pollution to environment; Oil-proofness of the present invention is fabulous, and wear resistance is higher, and thermotolerance is better, and bonding force is strong, and production cost is low, and technique is simple.
Embodiment
Below by specific examples, the present invention is described in detail.
A paracril electrical condenser sealing-ring, by following weight part (kilogram) raw material make: paracril 330480, sulphur 1, zinc oxide 4, stearic acid 1, antioxidant BHT 1, diatomite 10, captax 1, ammonium phosphate 1, Resorcinol 2, naphthenic oil 2, microcrystalline wax 2.4, carnauba wax 1.4, extrude carbon black N66022, high abrasion furnace carbon black N330 18, aluminium hydroxide 8, zinc oxide 5, altax 0.3, attapulgite modified 12 soon;
Described attapulgite modified by following weight part (kilogram) raw material make: attapulgite 20, tolylene diisocyanate 3, tri (propylene glycol) diacrylate 2, clay 12, nano titanium oxide 3, Zirconium tetrafluoride 1, Union carbide A-162 1, ferrocene 1, Vulcanization accelerator TMTD 1, aluminium hydroxide 8,2-amino-2-methyl-1-propanol 2, Fructus Zanthoxyli oil 1; Preparation method puts into attapulgite, clay mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
Paracril electrical condenser sealing-ring of the present invention, is made by following concrete steps: paracril 3304, sulphur, zinc oxide, stearic acid, antioxidant BHT, diatomite, captax are added in Banbury mixer, be heated to 80-90 ℃, mixing 3-5min; Then be warming up to 110-130 ℃, add again ammonium phosphate, Resorcinol, naphthenic oil, microcrystalline wax, carnauba wax, mixing 6-8min, add again fast extrusion carbon black N660, high abrasion furnace carbon black N330 to continue mixing 4-6min, add the mixing 4-6min of all the other remaining components, obtain rubber mass of the present invention.
By anti-corrosive rubber sealing-ring of the present invention and common sizing material physicals, contrast as following table.
Figure BDA0000430043870000031
Use as can be seen from the table rubber seal product of the present invention, comprehensive comparison is good.

Claims (2)

1. a paracril electrical condenser sealing-ring, it is characterized in that, by the raw material of following weight part, made: paracril 3304 80-90, sulphur 1-2, zinc oxide 4-6, stearic acid 1-1.5, antioxidant BHT 1-2, diatomite 10-15, captax 1-2, ammonium phosphate 1-2, Resorcinol 2-3, naphthenic oil 2-3, microcrystalline wax 2.4-3.6, carnauba wax 1.4-1.6, extrude carbon black N660 22-25, high abrasion furnace carbon black N330 18-22, aluminium hydroxide 8-12, zinc oxide 5-7, altax 0.3-0.7, attapulgite modified 12-15 soon;
The described attapulgite modified raw material by following weight part is made: attapulgite 20-24, tolylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, clay 12-15, nano titanium oxide 3-4, Zirconium tetrafluoride 1-2, Union carbide A-162 1-2, ferrocene 1-2, Vulcanization accelerator TMTD 1-2, aluminium hydroxide 8-10,2-amino-2-methyl-1-propyl alcohol 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into attapulgite, clay mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
2. paracril electrical condenser sealing-ring according to claim 1, it is characterized in that, by following concrete steps, made: paracril 3304, sulphur, zinc oxide, stearic acid, antioxidant BHT, diatomite, captax are added in Banbury mixer, be heated to 80-90 ℃, mixing 3-5min; Then be warming up to 110-130 ℃, add again ammonium phosphate, Resorcinol, naphthenic oil, microcrystalline wax, carnauba wax, mixing 6-8min, add again fast extrusion carbon black N660, high abrasion furnace carbon black N330 to continue mixing 4-6min, add the mixing 4-6min of all the other remaining components, obtain rubber mass of the present invention.
CN201310648201.8A 2013-12-04 2013-12-04 A kind of Butadiene-acrylonitrrubber rubber capacitor sealing ring and preparation method thereof Expired - Fee Related CN103694519B (en)

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CN103937054A (en) * 2014-04-12 2014-07-23 安徽江威精密制造有限公司 Capacitor O-shaped rubber sealing pad and preparation method thereof
CN104086876A (en) * 2014-07-01 2014-10-08 安徽江威精密制造有限公司 Special filler for wear-resistant fatigue-resistant capacitor films and preparation method thereof
CN112266511A (en) * 2020-10-30 2021-01-26 安徽中联汽车零部件有限公司 Preparation method of wear-resistant automobile Y-shaped rubber ring

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Publication number Priority date Publication date Assignee Title
CN103937054A (en) * 2014-04-12 2014-07-23 安徽江威精密制造有限公司 Capacitor O-shaped rubber sealing pad and preparation method thereof
CN103937054B (en) * 2014-04-12 2015-12-30 安徽江威精密制造有限公司 A kind of electrical condenser O shape rubber gasket and preparation method thereof
CN104086876A (en) * 2014-07-01 2014-10-08 安徽江威精密制造有限公司 Special filler for wear-resistant fatigue-resistant capacitor films and preparation method thereof
CN104086876B (en) * 2014-07-01 2016-04-20 安徽江威精密制造有限公司 A kind of wear-resisting strain-resistant electrical container film filler special and preparation method thereof
CN112266511A (en) * 2020-10-30 2021-01-26 安徽中联汽车零部件有限公司 Preparation method of wear-resistant automobile Y-shaped rubber ring

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Inventor after: Wang Xin

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