CN103773267A - Amyloid cigarette adhesive based on degradable gelatinized starch and etherified gelatinized starch - Google Patents
Amyloid cigarette adhesive based on degradable gelatinized starch and etherified gelatinized starch Download PDFInfo
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- CN103773267A CN103773267A CN201210400081.5A CN201210400081A CN103773267A CN 103773267 A CN103773267 A CN 103773267A CN 201210400081 A CN201210400081 A CN 201210400081A CN 103773267 A CN103773267 A CN 103773267A
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Abstract
The invention relates to a novel amyloid cigarette adhesive based on degradable gelatinized starch and etherified gelatinized starch. The novel amyloid cigarette adhesive based on the non-gelatinized starch is characterized by comprising the following components by weight: 35%-95% of water, 10%-45% of the degradable gelatinized starch, 1%-25% of the etherified gelatinized starch, 0.05%-1% of a preservative, 0.05%-1% of a defoaming agent and 0-5% of a functional assistant. Detections show that the amyloid cigarette adhesive provided by the invention has good viscosity, fluidity and stability, can be stably stored for more than three months at a room temperature, can be used as any adhesive such as lap adhesive, tipping adhesive, filter rod central line adhesive, packaging adhesive and aluminum foil laminated adhesive in cigarette production, and is applicable to any cigarette machine, particularly a cigarette machine with a single-gun speed higher than 7,000 cigarettes/minute and a highly speed cigarette machine with a speed higher than 10,000 cigarettes/minute. The cigarette adhesive provided by the invention can be also applied in situations such as paper bindings, bottle labels and packing boxes which relate to paper bonding.
Description
Technical field
The present invention relates to starchiness sizing agent, be particularly applicable to a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch that production of cigarettes is used.
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Background technology
Sizing agent is one of raw and auxiliary material important in production of cigarettes manufacturing processed, in a lot of production of cigarettes operations, all relates to sizing agent, mainly comprises: overlapping glue, connect mouth glue, filter stick centre-line glue, packing glue and aluminum foil composite glue etc.At present, the domestic main flow cigarette machine list rifle speed of a motor vehicle is about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/minute) substantially, calculate with this cigarette speed, the speed that rolls out of plume is about 500 ms/min of left and right, for example, concerning overlapping glue, be coated in cigarette tissue the time of plume out from it and be less than 0.1 second, time of drying is only less than 0.1 second, otherwise cigarette machine just there will be " race bar " phenomenon and quits work; Therefore, this just requires cigarette glue to have excellent adhesive property, rheological property etc.
Because polyvinyl acetate emulsion class sizing agent possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, thereby cigarette industry is generally used at home and abroad.But be non-natural sizing agent take polyvinyl acetate emulsion as basic sizing agent, at present, people are interested in the sizing agent of natural class, as starchiness sizing agent etc. because the raw material sources of natural class tackiness agent more extensively, more environmental protection.
Abroad since the 80s and 90s in last century developing starch High Speed Cigarette Adhesives, for example United States Patent (USP) 5085228 has proposed the mixture that one comprises cross-linking starch and modified starch (referring in particular to denaturated starch by acid), mixture is carried out obtaining starch cigarette glue after gelatinization, wherein the amylopection content of special requirement ative starch is at least 70%(weight), and this mixture can select to carry out etherificate, esterification and oxidation modification before gelatinization, this starch cigarette glue is applicable to the production of 6000/minute of the speed of a motor vehicle and above cigarette machine.United States Patent (USP) 5155140 has proposed a kind of tackiness agent, mainly contains by the mixture of 100 parts of water, 4-120 part gum arabic, 3-80 part water soluble starch degraded product, carboxymethyl starch, gelling starch and forms.United States Patent (USP) 5329004 has proposed a kind of take at least 90%(weight of amylopection content) ative starch as raw material, obtained a kind of starch cigarette glue by sour sex change (or enzymolysis, oxidation), Phosphation, gelatinization, this starch cigarette glue is applicable to the production of 6000/minute of the speed of a motor vehicle and above cigarette machine.United States Patent (USP) 5490875 has proposed a kind of take at least 70%(weight of amylopection content) ative starch as raw material, prepared respectively white dextrin and hydrolyzed starch (by enzyme and/or acid), then carried out gelatinization, obtained starch adhesive.Chinese patent CN 1095864C has proposed a kind of starch cigarette glue of unmodified starch, 5-60% treated starch, 0-5% rheology modifier, about 0-1% sanitas and 0-1% defoamer composition of the 2-25% of comprising dispersiveness, and this amylan is greater than 7000 cigarette of per minute applicable to production rate and is sometimes greater than the cigarette machine of 10000 cigarette of per minute.Chinese patent CN 100556973C has proposed the starch-based adhesive that a kind of treated starch with one or more (acetylated starch, acetylize two cross-linking starchs, etherification starch, etherificate cross-linking starch) obtains after modification for the second time again; the modification for the second time of treated starch is to carry out in the process of gelatinization plastic; be acylation modification or etherification modifiedly synchronize and carry out with degraded, this amylan is applicable to the cigarette machine that is more than or equal to 7000/minute.But, the a lot of starch cigarette glues that relate in existing patent still exist the problems such as the speed of a motor vehicle low even not mentioned start speed of a motor vehicle while production, viscosity are poor, glue poor stability, and the domestic commercial starchiness cigarette glue product that not yet occurs meeting cigarette industry practical application request at present.Therefore the starchiness cigarette glue that, still needs to meet numerous requirements such as the high speed of a motor vehicle of existing cigarette machine and there is good viscosity, mobility, stability.
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summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide one can meet the normal Production requirement of existing cigarette machine (7000/minute of single rifle speed of a motor vehicle and with first-class), and there is a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch of good viscosity, mobility and stability.
The object of the invention is to be achieved through the following technical solutions:
Novel starch matter cigarette glue of the present invention, is grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Degraded class-pasted starch 10%-45%
Etherificate class-pasted starch 1%-25%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
In the present invention, described degraded class-pasted starch be by the DAMs such as pyrolysis dextrin, enzymolysis starch, denaturated starch by acid, Sumstar 190 any one or multiplely obtain preferential oxidation starch through gelatinization.
Described etherificate class-pasted starch be by the etherificate kind of starch such as hydroxyethylamyle, hydroxypropylated starch, carboxymethyl starch, oxidation-hydroxyethylamyle, oxidation-hydroxypropylated starch, oxidation-carboxymethyl starch any one or multiplely obtain preferably hydroxypropylated starch, carboxymethyl starch, oxidation-hydroxypropylated starch and oxidation-carboxymethyl starch through gelatinization.
Described oxidation-hydroxyethylamyle, oxidation-hydroxypropylated starch, oxidation-carboxymethyl starch refer to and adopt etherification method, method for oxidation and the carboxymethylated etherification method of method for oxidation and hydroxyethylated etherification method, method for oxidation and hydroxypropylation respectively ative starch to be carried out to composite modified product.
" gelatinization " in the present invention claims again " αization ", and its essence is that water molecules enters in starch small grain, and the hydrogen bond rupture between crystallization phases and the starch molecule of unformed phase has destroyed the association state between starch molecule, is dispersed in water and becomes hydrophilic colloidal solution.According to the difference of equipment used, have multiple production method, the present invention can select cooking process, heat roll in the methods such as method, spray method, extruding puffing method, microwave method, pulse jet method any one or multiple.
Treated starch in the present invention is all by ative starch, modification obtains, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch etc.
Sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
Defoamer select in following kind any one or multiple: ester class, mineral oil and the compound defoamers etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
Functional agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; The carbohydrates such as sucrose; Some mineral substance classes such as wilkinite, silicon-dioxide; Some vegetable jelly such as bean gum, gelatine, gelatin class.By selecting suitable functional agent, can play tackify, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, viscosity is about 100cps-20000cps(25 ℃), and it has good viscosity, mobility and stability, can stablize more than three months time of depositing at normal temperatures.
Any one sizing agent that starchiness cigarette glue in the present invention can be used as in production of cigarettes uses, as overlapping glue, connect mouth glue, filter stick centre-line glue, packing glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention also relates to the occasion of paper bonding applicable to other occasion as binding papers, bottle label, packing box etc.
Embodiment
Below in conjunction with embodiment, the present invention is done to further detailed description, but the scope of the invention is not limited to these embodiment.
Embodiment 1
Adopt oxidation-pasted starch of 15%, hydroxypropylation-pasted starch of 1%, 0.5% Sodium Benzoate, 0.5% dimethyl silicone oil, 3% glycerine and 80% water to prepare starchiness cigarette glue, oxidation-pasted starch used is prepared by waxy corn starch, and hydroxypropylation-pasted starch is prepared by wheat starch.The preparation flow of starchiness cigarette glue is: first oxidation-pasted starch and hydroxypropylation-pasted starch are added to the water, then add successively Sodium Benzoate, dimethyl silicone oil and glycerine, be uniformly mixed.
After testing: the product of making has 18% solid content, in the time of 25 ℃, brookfield viscosity is 600cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 2,
Adopt gelatinization thing, 0.5% potassium sorbate, 0.25% dimethyl silicone oil, 0.25% propylene glycol, 5% sucrose and 74% the water of the mixture of the carboxymethylated starch of oxidation-pasted starch of 10%, 5% hydroxypropylated starch and 5% to prepare starchiness cigarette glue, the gelatinization thing of the mixture of oxidation-pasted starch, hydroxypropylated starch and carboxymethyl starch used is to be prepared by wax sorghum starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of oxidation-pasted starch, hydroxypropylated starch and carboxymethyl starch is added to the water, then add successively potassium sorbate, dimethyl silicone oil, propylene glycol and sucrose, be uniformly mixed all and have.
After testing: products obtained therefrom has 24% solid content, in the time of 25 ℃, brookfield viscosity is 16000cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 3
Adopt gelatinization thing, 0.5% Sodium dehydroacetate, 0.5% tennecetin, 1% polypropylene glycerol aether and 48% the water of the mixture of the oxidation-carboxymethyl starch of oxidation-pasted starch of 10%, oxidation-hydroxypropylated starch of 20% and 20% to prepare starchiness cigarette glue, oxidation-pasted starch used is prepared by Waxy Rice Starch, and the gelatinization thing of the mixture of oxidation-hydroxypropylated starch and oxidation-carboxymethyl starch is prepared by yam starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of oxidation-pasted starch, oxidation-hydroxypropylated starch and oxidation-carboxymethyl starch is added to the water, then add successively Sodium dehydroacetate, tennecetin and polypropylene glycerol aether, be uniformly mixed.
After testing: products obtained therefrom has 50% solid content, in the time of 25 ℃, brookfield viscosity is 8900cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 4
Adopt gelatinization thing, 1% calcium propionate, 1% Tween-40,1% glyceryl monostearate, 1% wilkinite and 61% the water of the gelatinization thing, 5% hydroxypropylated starch of the mixture of 10% pyrolysis dextrin and 10% Sumstar 190 and the mixture of oxidation-hydroxypropylated starch of 10% to prepare starchiness cigarette glue, treated starch used prepares by waxy corn starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of gelatinization thing, hydroxypropylated starch and the oxidation-hydroxypropylated starch of the mixture of pyrolysis dextrin and Sumstar 190 is added to the water, then add successively calcium propionate, Tween-40, glyceryl monostearate and wilkinite, be uniformly mixed.
After testing: products obtained therefrom has 35% solid content, in the time of 25 ℃, brookfield viscosity is 2400cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 5
Adopt gelatinization thing, 1% sodium Diacetate, 1% mineral oil, 3% CSL sodium and 69% the water of the gelatinization thing, 6% hydroxypropylated starch of the mixture of the enzymolysis starch of 5% denaturated starch by acid and 5% and the mixture of oxidation-carboxymethyl starch of 10% to prepare starchiness cigarette glue, the gelatinization thing of the mixture of denaturated starch by acid used and enzymolysis starch is prepared by waxy corn starch, and the gelatinization thing of the mixture of hydroxypropylated starch and oxidation-carboxymethyl starch is prepared by tapioca (flour).The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of gelatinization thing, hydroxypropylated starch and the oxidation-carboxymethyl starch of the mixture of denaturated starch by acid and enzymolysis is added to the water, then add successively sodium Diacetate, mineral oil and CSL sodium, be uniformly mixed.
After testing: products obtained therefrom has 29% solid content, in the time of 25 ℃, brookfield viscosity is 5700cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 6
Adopt the gelatinization thing of the mixture of the denaturated starch by acid of 3% pyrolysis dextrin, 5% Sumstar 190 and 3%, carboxymethylation-pasted starch of 8%, 0.5% Sodium.alpha.-hydroxypropionate, 0.5% nisin, 1% Tripolyglycerol monostearates, 3% silicon-dioxide and 76% water are prepared starchiness cigarette glue, the gelatinization thing of the mixture of pyrolysis dextrin, Sumstar 190 and denaturated starch by acid used is prepared by Waxy Rice Starch, and carboxymethylation-pasted starch is prepared by sweet potato starch.The preparation flow of starchiness cigarette glue is: first gelatinization thing, the carboxymethylation-pasted starch of the mixture of pyrolysis dextrin, Sumstar 190 and denaturated starch by acid are added to the water, then add successively Sodium.alpha.-hydroxypropionate, nisin, Tripolyglycerol monostearates and silicon-dioxide, be uniformly mixed.
After testing: products obtained therefrom has 21% solid content, in the time of 25 ℃, brookfield viscosity is 5100cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Claims (8)
1. the novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch, is characterized in that: the one-tenth by following weight ratio is grouped into:
Water 35%-85%
Degraded class-pasted starch 10%-45%
Etherificate class-pasted starch 1%-25%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%.
2. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 1, it is characterized in that: described degraded class-pasted starch be by pyrolysis dextrin, enzymolysis starch, denaturated starch by acid, Sumstar 190 any one or multiplely obtain preferential oxidation starch through gelatinization.
3. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 1, it is characterized in that: described etherificate class-pasted starch be by hydroxyethylamyle, hydroxypropylated starch, carboxymethyl starch, oxidation-hydroxyethylamyle, oxidation-hydroxypropylated starch, oxidation-carboxymethyl starch any one or multiplely obtain preferably hydroxypropylated starch, carboxymethyl starch, oxidation-hydroxypropylated starch and oxidation-carboxymethyl starch through gelatinization.
4. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 3, is characterized in that: described oxidation-hydroxyethylamyle, oxidation-hydroxypropylated starch, oxidation-carboxymethyl starch refer to and adopt etherification method, method for oxidation and the carboxymethylated etherification method of method for oxidation and hydroxyethylated etherification method, method for oxidation and hydroxypropylation respectively ative starch to be carried out to composite modified product.
5. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 1, is characterized in that: sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
6. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 1, is characterized in that: defoamer select in following kind any one or multiple: ester class, mineral oil and the compound defoamers etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
7. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 1, is characterized in that: functional agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; The carbohydrates such as sucrose; Some mineral substance classes such as wilkinite, silicon-dioxide; Some vegetable jelly such as bean gum, gelatine, gelatin class.
8. a kind of novel starch matter cigarette glue based on degraded class-pasted starch and etherificate class-pasted starch according to claim 1, it is characterized in that: the solid content of starchiness cigarette glue is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, and viscosity is about 100cps-20000cps(25 ℃).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210400081.5A CN103773267B (en) | 2012-10-20 | 2012-10-20 | A kind of starchiness cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch |
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| CN201210400081.5A CN103773267B (en) | 2012-10-20 | 2012-10-20 | A kind of starchiness cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch |
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| CN103773267B CN103773267B (en) | 2016-05-04 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106700966A (en) * | 2016-12-14 | 2017-05-24 | 龚亚龙 | Adhesive and preparation method thereof |
| CN108822762A (en) * | 2018-06-20 | 2018-11-16 | 滁州市光威化工有限公司 | A kind of flame-proof starch connects mouth glue and preparation method thereof |
| CN113088218A (en) * | 2021-05-25 | 2021-07-09 | 佛山市南海华昊华丰淀粉有限公司 | Preparation method and application of starch adhesive for environment-friendly paper bags |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN1081703A (en) * | 1992-07-29 | 1994-02-09 | 李有才 | A kind of preparation method of cigarette glue |
-
2012
- 2012-10-20 CN CN201210400081.5A patent/CN103773267B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN1081703A (en) * | 1992-07-29 | 1994-02-09 | 李有才 | A kind of preparation method of cigarette glue |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106700966A (en) * | 2016-12-14 | 2017-05-24 | 龚亚龙 | Adhesive and preparation method thereof |
| CN108822762A (en) * | 2018-06-20 | 2018-11-16 | 滁州市光威化工有限公司 | A kind of flame-proof starch connects mouth glue and preparation method thereof |
| CN113088218A (en) * | 2021-05-25 | 2021-07-09 | 佛山市南海华昊华丰淀粉有限公司 | Preparation method and application of starch adhesive for environment-friendly paper bags |
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| CN103773267B (en) | 2016-05-04 |
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