CN103773268A - Novel amyloid cigarette adhesive containing modified cellulose - Google Patents
Novel amyloid cigarette adhesive containing modified cellulose Download PDFInfo
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- CN103773268A CN103773268A CN201210400083.4A CN201210400083A CN103773268A CN 103773268 A CN103773268 A CN 103773268A CN 201210400083 A CN201210400083 A CN 201210400083A CN 103773268 A CN103773268 A CN 103773268A
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Abstract
The invention relates to a novel amyloid cigarette adhesive containing modified cellulose. The amyloid cigarette adhesive comprises, by weight, 35%-85% of water, 5%-50% of pyrolyzed dextrin, 5%-50% of glucose, 0.1%-20% of modified cellulose, 0.05%-1% of a preservative, 0.05%-1% of a defoaming agent and 0-5% of auxiliary agents. The cigarette adhesive provided by the invention has good viscosity, fluidity and stability, can be stably stored for more than three months at a room temperature, can be used as any adhesive such as lap adhesive, tipping adhesive, filter rod central line adhesive, packaging adhesive and aluminum foil laminated adhesive in cigarette production, and is applicable to any cigarette machine, particularly a cigarette machine with a single-gun speed higher than 7,000 cigarettes/minute and a highly speed cigarette machine with a speed higher than 10,000 cigarettes/minute. The cigarette adhesive provided by the invention can be also applied in situations such as paper bindings, bottle labels and packing boxes which relate to paper bonding.
Description
Technical field
The present invention relates to starchiness cigarette glue, particularly a kind of novel starch matter cigarette glue that contains modified-cellulose.
Background technology
Sizing agent is one of raw and auxiliary material important in production of cigarettes manufacturing processed, in a lot of production of cigarettes operations, all relates to sizing agent, mainly comprises: overlapping glue, connect mouth glue, filter stick centre-line glue, packing glue and aluminum foil composite glue etc.At present, the domestic main flow cigarette machine list rifle speed of a motor vehicle is about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/minute) substantially, calculate with this cigarette speed, the speed that rolls out of plume is about 500 ms/min of left and right, for example, concerning overlapping glue, be coated in cigarette tissue the time of plume out from it and be less than 0.1 second, time of drying is only less than 0.1 second, otherwise cigarette machine just there will be " race bar " phenomenon and quits work; Therefore, this just requires cigarette glue to have excellent adhesive property, rheological property etc.
Because polyvinyl acetate emulsion class sizing agent possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, thereby cigarette industry is generally used at home and abroad.But be non-natural sizing agent take polyvinyl acetate emulsion as basic sizing agent, at present, people are interested in the sizing agent of natural class, as starchiness sizing agent etc. because the raw material sources of natural class tackiness agent more extensively, more environmental protection.
Abroad since the 80s and 90s in last century developing starch High Speed Cigarette Adhesives, for example United States Patent (USP) 5085228 has proposed the mixture that one comprises cross-linking starch and modified starch (referring in particular to denaturated starch by acid), mixture is carried out obtaining starch cigarette glue after gelatinization, wherein the amylopection content of special requirement ative starch is at least 70%(weight), and this mixture can select to carry out etherificate, esterification and oxidation modification before gelatinization, this starch cigarette glue is applicable to the production of 6000/minute of the speed of a motor vehicle and above cigarette machine.United States Patent (USP) 5155140 has proposed a kind of tackiness agent, mainly contains by the mixture of 100 parts of water, 4-120 part gum arabic, 3-80 part water soluble starch degraded product, carboxymethyl starch, gelling starch and forms.United States Patent (USP) 5329004 has proposed a kind of take at least 90%(weight of amylopection content) ative starch as raw material, obtained a kind of starch cigarette glue by sour sex change (or enzymolysis, oxidation), Phosphation, gelatinization, this starch cigarette glue is applicable to the production of 6000/minute of the speed of a motor vehicle and above cigarette machine.United States Patent (USP) 5490875 has proposed a kind of take at least 70%(weight of amylopection content) ative starch as raw material, prepared respectively white dextrin and hydrolyzed starch (by enzyme and/or acid), then carried out gelatinization, obtained starch adhesive.Chinese patent CN 1095864C has proposed a kind of starch cigarette glue of unmodified starch, 5-60% treated starch, 0-5% rheology modifier, about 0-1% sanitas and 0-1% defoamer composition of the 2-25% of comprising dispersiveness, and this amylan is greater than 7000 cigarette of per minute applicable to production rate and is sometimes greater than the cigarette machine of 10000 cigarette of per minute.Chinese patent CN 100556973C has proposed the starch-based adhesive that a kind of treated starch with one or more (acetylated starch, acetylize two cross-linking starchs, etherification starch, etherificate cross-linking starch) obtains after modification for the second time again; the modification for the second time of treated starch is to carry out in the process of gelatinization plastic; be acylation modification or etherification modifiedly synchronize and carry out with degraded, this amylan is applicable to the cigarette machine that is more than or equal to 7000/minute.But, the a lot of starch cigarette glues that relate in existing patent still exist the problems such as the speed of a motor vehicle low even not mentioned start speed of a motor vehicle while production, viscosity are poor, glue poor stability, and the domestic commercial starchiness cigarette glue product that not yet occurs meeting cigarette industry practical application request at present.Therefore the starchiness cigarette glue that, still needs to meet numerous requirements such as the high speed of a motor vehicle of existing cigarette machine and there is good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide one can meet the normal Production requirement of existing cigarette machine (7000/minute of single rifle speed of a motor vehicle and with first-class), and there is a kind of novel starch matter cigarette glue that contains modified-cellulose of good viscosity, mobility and stability.
The object of the invention is by the following technical programs: a kind of novel starch matter cigarette glue that contains modified-cellulose, is grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Pyrolysis dextrin 5%-50%
Glucose
5%-50%
Modified-cellulose 0.1%-20%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Auxiliary agent 0-5%
In the present invention, described pyrolysis dextrin comprises yellow starch gum, Britain glue.
In the present invention, described glucose can be used any one or the multiple replacement in sucrose, malt syrup, maltose alcohol, maltodextrin, fruit glucose syrup, cyclodextrin.
Modified-cellulose in the present invention comprises methylcellulose gum, Xylo-Mucine, Vltra tears, Natvosol, and modified-cellulose has the effect that strengthens cohesive force, regulation and control cigarette glue viscosity.
Pyrolysis dextrin in the present invention is all by ative starch, modification obtains, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch etc.
Sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
Defoamer select in following kind any one or multiple: ester class, mineral oil and the compound defoamers etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
Auxiliary agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; Some mineral substance classes such as wilkinite, silicon-dioxide.By selecting suitable functional agent, can play tackify, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, viscosity is about 100cps-20000cps(25 ℃), and it has good viscosity, mobility and stability, can stablize more than three months time of depositing at normal temperatures.
Any one sizing agent that starchiness cigarette glue in the present invention can be used as in production of cigarettes uses, as overlapping glue, connect mouth glue, filter stick centre-line glue, packing glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention also relates to the occasion of paper bonding applicable to other occasion as binding papers, bottle label, packing box etc.
Embodiment
Below in conjunction with embodiment, the present invention is done to further detailed description, but the scope of the invention is not limited to these embodiment.
Embodiment 1
Adopt 10% Britain glue, 7% glucose, 5% methylcellulose gum, 1% phenylformic acid, 1% dimethyl silicone oil and 76% water to prepare starchiness cigarette glue, wherein Britain glue is prepared by W-Gum.The preparation flow of starchiness cigarette glue is: first methylcellulose gum is dissolved in water, then adds successively Britain glue, glucose, phenylformic acid and dimethyl silicone oil, be uniformly mixed.
After testing: products obtained therefrom has 22% solid content, in the time of 25 ℃, brookfield viscosity is 1100cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 2
Adopt 15% Britain glue, 5% cyclodextrin, 7% Xylo-Mucine, 3% wilkinite, 1% epoxy soybean oil, 1% glycerine, 1% potassium sorbate, 1% polyoxyethylene polyoxypropylene amidogen ether and 66% water to prepare starchiness cigarette glue.Wherein Britain glue is prepared by tapioca (flour).The preparation flow of starchiness cigarette glue is: first Xylo-Mucine is dissolved in water, then add successively Britain glue, cyclodextrin, wilkinite, epoxy soybean oil, glycerine, potassium sorbate and polyoxyethylene polyoxypropylene amidogen ether, be uniformly mixed.
After testing: products obtained therefrom has 31% solid content, in the time of 25 ℃, brookfield viscosity is 6900cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 3
Adopt 8% yellow starch gum, 20% maltodextrin, 10% Natvosol, 3% silicon-dioxide, 1% wilkinite, 1% wollastonite powder, 1% sodium Diacetate, 1% the fatty acid ester compounded thing of higher alcohols and 55% water to prepare starchiness cigarette glue, wherein yellow starch gum is prepared by Waxy Rice Starch.The preparation flow of starchiness cigarette glue is: first Natvosol is dissolved in water, then add successively the fatty acid ester compounded thing of yellow starch gum, maltodextrin, silicon-dioxide, wilkinite, wollastonite powder, sodium Diacetate and higher alcohols, be uniformly mixed.
After testing: products obtained therefrom has 43% solid content, in the time of 25 ℃, brookfield viscosity is 10900cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 4
Adopt 9% Britain glue, 10% maltose alcohol, 5% Vltra tears, 4% attapulgite, 0.5% nisin, 0.5% tennecetin, 1% silicone emulsion and 70% water to prepare starchiness cigarette glue, wherein Britain glue is prepared by sweet potato starch.The preparation flow of starchiness cigarette glue is: first Vltra tears is dissolved in water, then adds successively Britain glue, maltose alcohol, attapulgite, nisin, tennecetin and silicone emulsion, be uniformly mixed.
After testing: products obtained therefrom has 27% solid content, in the time of 25 ℃, brookfield viscosity is 5050cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 5
Adopt 10% Britain glue, 10% sucrose, 15% glucose, 5% methylcellulose gum, 1% potassium sorbate, 1% dimethyl silicone oil and 58% water to prepare starchiness cigarette glue, wherein Britain glue is prepared by tapioca (flour).The preparation flow of starchiness cigarette glue is: first methylcellulose gum is dissolved in water, then adds successively Britain glue, sucrose, glucose, potassium sorbate and dimethyl silicone oil, be uniformly mixed.
After testing: products obtained therefrom has 40% solid content, in the time of 25 ℃, brookfield viscosity is 13020cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 6
Adopt 6% yellow starch gum, 10% maltodextrin, 3% cyclodextrin, 2% Xylo-Mucine, 0.5% Sodium dehydroacetate, 0.5% mineral oil and 78% water to prepare starchiness cigarette glue, wherein yellow starch gum is prepared by sweet potato starch.The preparation flow of starchiness cigarette glue is: first Xylo-Mucine is dissolved in water, then adds successively yellow starch gum, maltodextrin, cyclodextrin, Sodium dehydroacetate and mineral oil, be uniformly mixed.
Products obtained therefrom has 20% solid content, and in the time of 25 ℃, brookfield viscosity is 1110cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Claims (8)
1. a novel starch matter cigarette glue that contains modified-cellulose, is characterized in that: the one-tenth by following weight ratio is grouped into:
Water 35%-85%
Pyrolysis dextrin 5%-50%
Glucose
5%-50%
Modified-cellulose 0.1%-20%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Auxiliary agent 0-5%.
2. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, is characterized in that: described pyrolysis dextrin comprises yellow starch gum, Britain glue.
3. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, is characterized in that: described glucose can be used any one or the multiple replacement in sucrose, malt syrup, maltose alcohol, maltodextrin, fruit glucose syrup, cyclodextrin.
4. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, is characterized in that: modified-cellulose comprises methylcellulose gum, Xylo-Mucine, Vltra tears, Natvosol.
5. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, is characterized in that: sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
6. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, is characterized in that: defoamer select in following kind any one or multiple: ester class, mineral oil and the compound defoamers etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
7. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, is characterized in that: auxiliary agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; Wilkinite, silicon-dioxide etc.
8. a kind of novel starch matter cigarette glue that contains modified-cellulose according to claim 1, it is characterized in that: the solid content of described starchiness cigarette glue is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, and viscosity is about 100cps-20000cps(25 ℃).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210400083.4A CN103773268B (en) | 2012-10-20 | 2012-10-20 | A kind of novel starch matter cigarette glue containing modified-cellulose |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210400083.4A CN103773268B (en) | 2012-10-20 | 2012-10-20 | A kind of novel starch matter cigarette glue containing modified-cellulose |
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| CN103773268A true CN103773268A (en) | 2014-05-07 |
| CN103773268B CN103773268B (en) | 2016-03-16 |
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| CN201210400083.4A Active CN103773268B (en) | 2012-10-20 | 2012-10-20 | A kind of novel starch matter cigarette glue containing modified-cellulose |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109468135A (en) * | 2018-11-14 | 2019-03-15 | 东北大学秦皇岛分校 | A kind of silica sol modified cellulose-based binder, environment protection water storage type fix the sand plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN101676345A (en) * | 2008-09-19 | 2010-03-24 | 张跃龙 | Water-soluble environment-friendly synthetic adhesive |
-
2012
- 2012-10-20 CN CN201210400083.4A patent/CN103773268B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN101676345A (en) * | 2008-09-19 | 2010-03-24 | 张跃龙 | Water-soluble environment-friendly synthetic adhesive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109468135A (en) * | 2018-11-14 | 2019-03-15 | 东北大学秦皇岛分校 | A kind of silica sol modified cellulose-based binder, environment protection water storage type fix the sand plate and preparation method thereof |
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| Publication number | Publication date |
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| CN103773268B (en) | 2016-03-16 |
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