CN103773268B - A kind of novel starch matter cigarette glue containing modified-cellulose - Google Patents
A kind of novel starch matter cigarette glue containing modified-cellulose Download PDFInfo
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- CN103773268B CN103773268B CN201210400083.4A CN201210400083A CN103773268B CN 103773268 B CN103773268 B CN 103773268B CN 201210400083 A CN201210400083 A CN 201210400083A CN 103773268 B CN103773268 B CN 103773268B
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Abstract
A kind of novel starch matter cigarette glue containing modified-cellulose, it is characterized in that: be grouped into by the one-tenth of following weight ratio: water: 350%-85%, pyrolysis dextrin 5%-50%, glucose <i>:</iGreatT.Gr eaT.GT5%-50%, modified-cellulose 0.1%-20%, sanitas 0.05%-1%, defoamer 0.05%-1%, auxiliary agent 0-5%.Starchiness cigarette glue of the present invention has good viscosity, mobility and stability, can stablize at normal temperatures and deposit more than three months time.Can use as any one sizing agent in production of cigarettes, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the cigarette machine of single rifle speed of a motor vehicle more than 7000/minute and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.Also be applicable to other occasion as binding papers, bottle label, packing box etc. relate to paper bonding occasion.
Description
Technical field
The present invention relates to starchiness cigarette glue, particularly a kind of novel starch matter cigarette glue containing modified-cellulose.
Background technology
Sizing agent is one of raw and auxiliary material important in production of cigarettes manufacturing processed, all relates to sizing agent, mainly comprise in a lot of production of cigarettes operation: overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc.At present, the domestic main flow cigarette machine list rifle speed of a motor vehicle is substantially about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/minute), calculate with this cigarette speed, the speed that rolls out of plume is about about 500 ms/min, such as, concerning overlapping glue, from its be coated in cigarette tissue to plume out time be less than 0.1 second, time of drying is only less than 0.1 second, otherwise cigarette machine just there will be " race bar " phenomenon and quits work; Therefore, this just requires that cigarette glue has excellent adhesive property, rheological property etc.
Because polyvinyl acetate emulsion class sizing agent possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, thus at home and abroad cigarette industry is generally used.But the sizing agent based on polyvinyl acetate emulsion is non-natural sizing agent, at present, the sizing agent of people to natural class is interested, as starchiness sizing agent etc. because the raw material sources of natural class tackiness agent more extensively, more environmental protection.
Starch High Speed Cigarette Adhesives is developed abroad from the 80s and 90s in last century, such as United States Patent (USP) 5085228 proposes the mixture that one comprises cross-linking starch and modified starch (referring in particular to denaturated starch by acid), starch cigarette glue is obtained after gelatinization is carried out to mixture, the amylopection content wherein specially requiring ative starch is at least 70%(weight), and this mixture can be selected to carry out etherificate, esterification and oxidation modification before gelatinization, this starch cigarette glue is applicable to the production of the speed of a motor vehicle 6000/minute and above cigarette machine.United States Patent (USP) 5155140 proposes a kind of tackiness agent, mainly contains and is made up of the mixture of 100 parts of water, 4-120 part gum arabic, 3-80 part water soluble starch degraded product, carboxymethyl starch, gelling starch.United States Patent (USP) 5329004 proposes a kind of with amylopection content at least 90%(weight) ative starch for raw material, obtain a kind of starch cigarette glue by Acid denaturation (or enzymolysis, oxidation), Phosphation, gelatinization, this starch cigarette glue is applicable to the production of the speed of a motor vehicle 6000/minute and above cigarette machine.United States Patent (USP) 5490875 proposes a kind of with amylopection content at least 70%(weight) ative starch for raw material, prepared white dextrin and hydrolyzed starch (by enzyme and/or acid) respectively, then carried out gelatinization, obtain starch adhesive.Chinese patent CN1095864C proposes a kind of starch cigarette glue of unmodified starch, 5-60% treated starch, 0-5% rheology modifier, about 0-1% sanitas and the 0-1% defoamer composition comprising 2-25% dispersiveness, and this amylan is applicable to production rate and is greater than per minute 7000 cigarette and the cigarette machine being sometimes greater than per minute 10000 cigarette.Chinese patent CN100556973C proposes a kind of with one or more treated starch (acetylated starch, acetylize two cross-linking starch, etherification starch, Crosslinked and hydroxypropyl starch) the modified starch-based adhesive obtained of process second time again; the second time modification of treated starch carries out in the process of gelatinization plastic; be acylation modification or etherification modifiedly synchronously carry out with degraded, this amylan is applicable to the cigarette machine being more than or equal to 7000/minute.But, the problems such as the speed of a motor vehicle low even not mentioned start speed of a motor vehicle when a lot of starch cigarette glues related in existing patent still also exist production, viscosity are poor, glue poor stability, and domesticly at present not yet there is the commercial starchiness cigarette glue product meeting cigarette industry practical application request.Therefore, still need numerous requirements such as the high speed of a motor vehicle that can meet existing cigarette machine and there is the starchiness cigarette glue of good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, there is provided one can meet the normal Production requirement of existing cigarette machine (single rifle speed of a motor vehicle 7000/minute and with first-class), and there is a kind of novel starch matter cigarette glue containing modified-cellulose of good viscosity, mobility and stability.
The object of the invention is by the following technical programs: a kind of novel starch matter cigarette glue containing modified-cellulose, is grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Pyrolysis dextrin 5%-50%
Glucose 5%-50%
Modified-cellulose 0.1%-20%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Auxiliary agent 0-5%
In the present invention, described pyrolysis dextrin comprises yellow starch gum, Britain glue.
In the present invention, described glucose can use sucrose, malt syrup, maltose alcohol, maltodextrin, fruit glucose syrup, any one or multiple replacement in cyclodextrin.
Modified-cellulose in the present invention comprises methylcellulose gum, Xylo-Mucine, Vltra tears, Natvosol, and modified-cellulose has the effect strengthening cohesive force, regulation and control cigarette glue viscosity.
Pyrolysis dextrin in the present invention all by obtaining ative starch modification, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch etc.
Sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
Defoamer select in following kind any one or multiple: ester class, mineral oil and the composite anti-foaming agent etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
Auxiliary agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; Some mineral substance classes such as wilkinite, silicon-dioxide.By selecting the functional agent be suitable for, thickening can be played, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, viscosity is about 100cps-20000cps(25 DEG C), and it has good viscosity, mobility and stability, can stablize at normal temperatures and deposit more than three months time.
Starchiness cigarette glue in the present invention can use as any one sizing agent in production of cigarettes, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the cigarette machine of single rifle speed of a motor vehicle more than 7000/minute and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention be also applicable to other occasion as binding papers, bottle label, packing box etc. relate to paper bonding occasion.
Embodiment
Below in conjunction with embodiment, further detailed description is done to the present invention, but the scope of the invention is not limited to these embodiments.
Embodiment 1
Adopt 10% Britain glue, 7% glucose, 5% methylcellulose gum, the phenylformic acid of 1%, the dimethyl silicone oil of 1% and 76% water prepare starchiness cigarette glue, wherein Britain glue is prepared by W-Gum.The preparation flow of starchiness cigarette glue is: be first dissolved in water by methylcellulose gum, then adds Britain glue, glucose, phenylformic acid and dimethyl silicone oil successively, is uniformly mixed.
After testing: products obtained therefrom has the solid content of 22%, 25 DEG C time, brookfield viscosity is 1100cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 2
Adopt 15% Britain glue, 5% cyclodextrin, 7% Xylo-Mucine, 3% wilkinite, 1% epoxy soybean oil, 1% glycerine, the potassium sorbate of 1%, the polyoxyethylene polyoxypropylene amidogen ether of 1% and 66% water prepare starchiness cigarette glue.Wherein Britain glue is prepared by tapioca (flour).The preparation flow of starchiness cigarette glue is: be first dissolved in water by Xylo-Mucine, then add Britain glue, cyclodextrin, wilkinite, epoxy soybean oil, glycerine, potassium sorbate and polyoxyethylene polyoxypropylene amidogen ether successively, be uniformly mixed.
After testing: products obtained therefrom has the solid content of 31%, 25 DEG C time, brookfield viscosity is 6900cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 3
Adopt 8% yellow starch gum, 20% maltodextrin, 10% Natvosol, 3% silicon-dioxide, 1% wilkinite, 1% wollastonite powder, the sodium Diacetate of 1%, the fatty acid ester compounded thing of higher alcohols of 1% and 55% water prepare starchiness cigarette glue, wherein yellow starch gum is prepared by Waxy Rice Starch.The preparation flow of starchiness cigarette glue is: be first dissolved in water by Natvosol, then add the fatty acid ester compounded thing of yellow starch gum, maltodextrin, silicon-dioxide, wilkinite, wollastonite powder, sodium Diacetate and higher alcohols successively, be uniformly mixed.
After testing: products obtained therefrom has the solid content of 43%, 25 DEG C time, brookfield viscosity is 10900cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 4
Adopt 9% Britain glue, 10% maltose alcohol, 5% Vltra tears, 4% attapulgite, 0.5% nisin, the tennecetin of 0.5%, the silicone emulsion of 1% and 70% water prepare starchiness cigarette glue, wherein Britain glue is prepared by sweet potato starch.The preparation flow of starchiness cigarette glue is: be first dissolved in water by Vltra tears, then adds Britain glue, maltose alcohol, attapulgite, nisin, tennecetin and silicone emulsion successively, is uniformly mixed.
After testing: products obtained therefrom has the solid content of 27%, 25 DEG C time, brookfield viscosity is 5050cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 5
Adopt 10% Britain glue, 10% sucrose, 15% glucose, 5% methylcellulose gum, the potassium sorbate of 1%, the dimethyl silicone oil of 1% and 58% water prepare starchiness cigarette glue, wherein Britain glue is prepared by tapioca (flour).The preparation flow of starchiness cigarette glue is: be first dissolved in water by methylcellulose gum, then adds Britain glue, sucrose, glucose, potassium sorbate and dimethyl silicone oil successively, is uniformly mixed.
After testing: products obtained therefrom has the solid content of 40%, 25 DEG C time, brookfield viscosity is 13020cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 6
Adopt 6% yellow starch gum, 10% maltodextrin, 3% cyclodextrin, 2% Xylo-Mucine, the Sodium dehydroacetate of 0.5%, the mineral oil of 0.5% and 78% water prepare starchiness cigarette glue, wherein yellow starch gum is prepared by sweet potato starch.The preparation flow of starchiness cigarette glue is: be first dissolved in water by Xylo-Mucine, then adds yellow starch gum, maltodextrin, cyclodextrin, Sodium dehydroacetate and mineral oil successively, is uniformly mixed.
Products obtained therefrom has the solid content of 20%, and 25 DEG C time, brookfield viscosity is 1110cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Claims (8)
1. the novel starch matter cigarette glue containing modified-cellulose, is characterized in that: be grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Pyrolysis dextrin 5%-50%
Glucose 5%-50%
Modified-cellulose 0.1%-20%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Auxiliary agent 0-5%.
2. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, is characterized in that: described pyrolysis dextrin comprises yellow starch gum, Britain glue.
3. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, is characterized in that: described glucose can use any one or multiple replacement in sucrose, malt syrup, maltose alcohol, maltodextrin, really glucose syrup, cyclodextrin.
4. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, is characterized in that: modified-cellulose comprises methylcellulose gum, Xylo-Mucine, Vltra tears, Natvosol.
5. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, is characterized in that: sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin.
6. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, is characterized in that: defoamer select in following kind any one or multiple: propylene glycol, dimethyl silicone oil are polysiloxane-based, polypropylene glycerol aether polyethers, Tweens, Tripolyglycerol monostearates ester class, mineral oil and composite anti-foaming agent.
7. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, is characterized in that: auxiliary agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; Glycerine, sorbitol polyol class; Wilkinite, silicon-dioxide.
8. a kind of novel starch matter cigarette glue containing modified-cellulose according to claim 1, it is characterized in that: the solid content of described starchiness cigarette glue is weight ratio 15%-65%, and pH value is 3-9, viscosity is 100cps-20000cps under 25 DEG C of conditions.
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| CN201210400083.4A CN103773268B (en) | 2012-10-20 | 2012-10-20 | A kind of novel starch matter cigarette glue containing modified-cellulose |
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| CN201210400083.4A CN103773268B (en) | 2012-10-20 | 2012-10-20 | A kind of novel starch matter cigarette glue containing modified-cellulose |
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| CN103773268A CN103773268A (en) | 2014-05-07 |
| CN103773268B true CN103773268B (en) | 2016-03-16 |
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| CN109468135B (en) * | 2018-11-14 | 2021-04-09 | 东北大学秦皇岛分校 | Silica sol modified cellulose-based binder, environment-friendly water storage type sand fixing plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN101676345A (en) * | 2008-09-19 | 2010-03-24 | 张跃龙 | Water-soluble environment-friendly synthetic adhesive |
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2012
- 2012-10-20 CN CN201210400083.4A patent/CN103773268B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN101676345A (en) * | 2008-09-19 | 2010-03-24 | 张跃龙 | Water-soluble environment-friendly synthetic adhesive |
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