CN103834091B - A kind of take linear low density polyethylene as capacitor metalized film of matrix and preparation method thereof - Google Patents

A kind of take linear low density polyethylene as capacitor metalized film of matrix and preparation method thereof Download PDF

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Publication number
CN103834091B
CN103834091B CN201410075392.8A CN201410075392A CN103834091B CN 103834091 B CN103834091 B CN 103834091B CN 201410075392 A CN201410075392 A CN 201410075392A CN 103834091 B CN103834091 B CN 103834091B
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density polyethylene
low density
linear low
matrix
metalized film
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Expired - Fee Related
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CN201410075392.8A
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CN103834091A (en
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汤广顺
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Guangdong Huilong new materials Co. Ltd.
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Wuhu Edison Automation Equipment Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/002—Details
    • H01G4/005—Electrodes
    • H01G4/008—Selection of materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/002—Details
    • H01G4/005—Electrodes
    • H01G4/015—Special provisions for self-healing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C08L2203/162—Applications used for films sealable films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of take linear low density polyethylene as the capacitor metalized film of matrix, it is characterized in that, be made up of the raw material of following weight part: linear low density polyethylene 200, xylogen 2-3, nano diatomite 1-2, dimethylaminoethyl methacrylate 2-3, ethylene glycol ethyl ether 1-2, ferrocene 1-2, polyvinyl alcohol 1-2, titanate coupling agent TMC-TTS? 1-2, auxiliary agent 5-6; Complete processing of the present invention is simple, and little with its film capacitor contact resistance made, thus makes product performance good; The present invention with the addition of auxiliary agent, enhances barrier and the resistance to air loss of film, has good resistance to pressure and shock-resistance, has the feature that heat seal strength is high, heat sealability is good, long service life simultaneously.

Description

A kind of take linear low density polyethylene as capacitor metalized film of matrix and preparation method thereof
Technical field
The present invention relates to field of capacitor manufacture, particularly a kind of take linear low density polyethylene as capacitor metalized film of matrix and preparation method thereof.
Background technology
Film capacitor works as electrode with tinsel, by itself and poly-ethyl ester, and polypropylene, the plastics film such as polystyrene or polycarbonate, after the overlap of two ends, is wound into the electrical condenser of cylindric structure; In the middle of all plastics film electric capacity, the characteristic of polypropylene (PP) electric capacity and polystyrene (PS) electric capacity is the most remarkable, certainly the price of these two kinds of electrical condensers is also higher, the film quality of electrical condenser directly affects work-ing life and the product performance of electrical condenser, the demand of capacitor film is large, kind is many, the film of single raw material production is adopted to be difficult to adapt to the requirement in market, but often kind of raw material has its weak point, so the film produced is difficult to the demand meeting various situation.
Summary of the invention
The object of this invention is to provide a kind of take linear low density polyethylene as capacitor metalized film of matrix and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
Take linear low density polyethylene as a capacitor metalized film for matrix, be made up of the raw material of following weight part: linear low density polyethylene 200, xylogen 2-3, nano diatomite 1-2, dimethylaminoethyl methacrylate 2-3, ethylene glycol ethyl ether 1-2, ferrocene 1-2, polyvinyl alcohol 1-2, titanate coupling agent TMC-TTS1-2, auxiliary agent 5-6;
Described auxiliary agent is made up of the raw material of following weight part: metallocene linear-low density polyethylene 12-15, calcium zinc stabilizer 2-3, cyanuric acid zinc 1-2,2-ethylhexyl diphenyl phosphate 5-6, linden ashes 1-2, nanometer jade powder 0.3-0.4, phosphorous acid ester 8-10, polyisobutene 2-3, Flos Rosae Rugosae quintessence oil 0.1-0.2; Metallocene linear-low density polyethylene is heated to molten state by preparation method, and then, add nanometer jade powder, linden ashes, stir 10-15 minute, finally add other composition, dispersed with stirring is even, and cooling, granulation, to obtain final product.
Of the present invention take linear low density polyethylene as the capacitor metalized film of matrix, it is characterized in that, is made up of following concrete steps:
(1) by linear low density polyethylene, xylogen, nano diatomite, dimethylaminoethyl methacrylate heating and melting, add auxiliary agent again and all the other remaining components fully stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 DEG C;
(2) sheet melt step (1) made, by slab obtained after sharp cooling roll and air raining chamber cooling and shaping, carries out longitudinal stretching, cross directional stretch, alligatoring face corona treatment successively;
(3) rolling, for the first time ageing treatment, second time ageing treatment;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
Complete processing of the present invention is simple, and little with its film capacitor contact resistance made, thus makes product performance good; The present invention with the addition of auxiliary agent, enhances barrier and the resistance to air loss of film, has good resistance to pressure and shock-resistance, has the feature that heat seal strength is high, heat sealability is good, long service life simultaneously.
Embodiment
Below by specific examples, the present invention is described in detail.
Take linear low density polyethylene as a capacitor metalized film for matrix, be made up of the raw material of following weight part (kilogram): linear low density polyethylene 200, xylogen 2, nano diatomite 1, dimethylaminoethyl methacrylate 2, ethylene glycol ethyl ether 1, ferrocene 1, polyvinyl alcohol 1, titanate coupling agent TMC-TTS1, auxiliary agent 5;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): metallocene linear-low density polyethylene 12, calcium zinc stabilizer 2, cyanuric acid zinc 1,2-ethylhexyl diphenyl phosphate 5, linden ashes 2, nanometer jade powder 0.3, phosphorous acid ester 8, polyisobutene 2, Flos Rosae Rugosae quintessence oil 0.1; Metallocene linear-low density polyethylene is heated to molten state by preparation method, and then, add nanometer jade powder, linden ashes, stir 10-15 minute, finally add other composition, dispersed with stirring is even, and cooling, granulation, to obtain final product.
Of the present invention take linear low density polyethylene as the capacitor metalized film of matrix, it is characterized in that, is made up of following concrete steps:
(1) by linear low density polyethylene, xylogen, nano diatomite, dimethylaminoethyl methacrylate heating and melting, add auxiliary agent again and all the other remaining components fully stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 DEG C;
(2) sheet melt step (1) made, by slab obtained after sharp cooling roll and air raining chamber cooling and shaping, carries out longitudinal stretching, cross directional stretch, alligatoring face corona treatment successively;
(3) rolling, for the first time ageing treatment, second time ageing treatment;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
The technical indicator of the metallized film of the embodiment of the present invention is as follows:
(1) lateral shrinkage≤0.2%, longitudinal contraction rate≤2.5%
(2) transverse tensile strength >=18Mpa, longitudinal tensile strength >=12Mpa;
(3) minimum break-down voltage 600Vv/um.

Claims (1)

1. one kind take linear low density polyethylene as the capacitor metalized film of matrix, it is characterized in that, be made up of the raw material of following weight part: linear low density polyethylene 200, xylogen 2-3, nano diatomite 1-2, dimethylaminoethyl acrylate methyl ammonia ethyl ester 2-3, ethylene glycol ethyl ether 1-2, ferrocene 1-2, polyvinyl alcohol 1-2, titanate coupling agent TMC-TTS1-2, auxiliary agent 5-6;
Described auxiliary agent is made up of the raw material of following weight part: metallocene linear-low density polyethylene 12-15, calcium zinc stabilizer 2-3, cyanuric acid zinc 1-2,2-ethylhexyl diphenyl phosphate 5-6, linden ashes 1-2, nanometer jade powder 0.3-0.4, phosphorous acid ester 8-10, polyisobutene 2-3, Flos Rosae Rugosae quintessence oil 0.1-0.2; Metallocene linear-low density polyethylene is heated to molten state by preparation method, and then, add nanometer jade powder, linden ashes, stir 10-15 minute, finally add other composition, dispersed with stirring is even, cooling, and granulation, to obtain final product;
Described is that the capacitor metalized film of matrix is made up of following concrete steps with linear low density polyethylene:
(1) by linear low density polyethylene, xylogen, nano diatomite, dimethylaminoethyl acrylate methyl ammonia ethyl ester heating and melting, add auxiliary agent again and all the other remaining components fully stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 DEG C;
(2) sheet melt step (1) made, by slab obtained after sharp cooling roll and air raining chamber cooling and shaping, carries out longitudinal stretching, cross directional stretch, alligatoring face corona treatment successively;
(3) rolling, for the first time ageing treatment, second time ageing treatment;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
CN201410075392.8A 2014-03-04 2014-03-04 A kind of take linear low density polyethylene as capacitor metalized film of matrix and preparation method thereof Expired - Fee Related CN103834091B (en)

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CN108623880A (en) * 2018-05-09 2018-10-09 上海昶法新材料有限公司 A kind of production method of lignin/low density polyethylene (LDPE) inflation film

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5308879A (en) * 1992-09-07 1994-05-03 Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha Process for preparing biodegradable resin foam
EP0708148A1 (en) * 1994-10-21 1996-04-24 Ems-Inventa Ag For blown films usable moulding compositions based on degradable aliphatic polyesters
CN1465623A (en) * 2002-06-21 2004-01-07 张惠民 Environment protection type lignin fog-film
CN102380996A (en) * 2011-08-03 2012-03-21 大连方盛塑料有限公司 Food packing plastic substrate film and production process thereof
CN102717571A (en) * 2012-07-02 2012-10-10 河北永新包装有限公司 Microwave heating composite packaging film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5308879A (en) * 1992-09-07 1994-05-03 Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha Process for preparing biodegradable resin foam
EP0708148A1 (en) * 1994-10-21 1996-04-24 Ems-Inventa Ag For blown films usable moulding compositions based on degradable aliphatic polyesters
CN1465623A (en) * 2002-06-21 2004-01-07 张惠民 Environment protection type lignin fog-film
CN102380996A (en) * 2011-08-03 2012-03-21 大连方盛塑料有限公司 Food packing plastic substrate film and production process thereof
CN102717571A (en) * 2012-07-02 2012-10-10 河北永新包装有限公司 Microwave heating composite packaging film and preparation method thereof

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