CN104087183A - Aqueous wax emulsion for improving brightness of leather - Google Patents
Aqueous wax emulsion for improving brightness of leather Download PDFInfo
- Publication number
- CN104087183A CN104087183A CN201410311950.6A CN201410311950A CN104087183A CN 104087183 A CN104087183 A CN 104087183A CN 201410311950 A CN201410311950 A CN 201410311950A CN 104087183 A CN104087183 A CN 104087183A
- Authority
- CN
- China
- Prior art keywords
- water
- wax emulsion
- emulsification
- emulsion
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses aqueous wax emulsion for improving the brightness of leather. The aqueous wax emulsion is prepared by using a direct high temperature sealed emulsification method, that is, adding water, a surfactant, an emulsification synergist, oxidized polyethlene wax and other additives into a reaction kettle, sealing, heating and stirring, emulsifying for a while, and subsequently cooking, thereby obtaining the polyethlene wax superfine microemulsion. Due to adoption of the emulsification synergist, the dispersion stability of the wax emulsion is improved.
Description
Technical field
The present invention relates to a kind of preparation method of polymer-wax, particularly a kind of water-based wax emulsion that increases leather polishing degree.
Background technology
Oxidized polyethylene wax emulsion is applied to the fields such as water color ink, water lustering oil, agricultural, leather, shoe polish, forestry, wooden industry, gardens industry, water-borne coatings, water-miscible paint, paper product tamanori, yarn fabric softening agent and water-fast arrangement.Have that particle diameter is tiny, good waterproof performance, hardness of film are high, tack-free, be coating, leather, weaving, the good additive of ink.It can also be for ink, lustering agent, polishing wax, liquid shoe cream, liquid automobile polish, liquid floor wax and liquid leather jacket wet goods field.
CN102030996 relates to a kind of water-soluble OP wax emulsion and preparation method thereof, this OP wax emulsion is formed with wt% and is calculated and comprise following component OP wax 19.5-32 part by OP wax, fatty alcohol-polyoxyethylene ether, aliphatic alcohol polyoxyvinethene phosphate salt, the deionized water of certainweight umber, fatty alcohol-polyoxyethylene ether 2.54-9.25 part, aliphatic alcohol polyoxyvinethene phosphate salt 0.45-1.58 part, deionized water 65-70 part, by reactor heating and melting, select agent-in-oil method technique, add and stir successively.
CN101503517 relates to a kind of preparation method of cationic-nonionic modified oxidated polyethylene wax emulsion, first low-molecular-weight oxidized polyethlene wax is carried out to esterification modification with organic bases, then use sun-nonionic compound emulsifier to carry out emulsification, then carry out the composite cationic-nonionic modified oxidated polyethylene wax emulsion that makes.This product can be applied to the fields such as process hides covering with paint, fruit freshness preserving.Be characterized in the emulsion institute of modified waxes electrically charged be positively charged ion, the wax emulsion-stabilizing of the more single cationic emulsifier emulsification of shelf characteric.
Existing known technology mostly adopts fatty alcohol-polyoxyethylene ether series of surfactants as main emulsifying agent, and wherein oleophilic group is connected with ehter bond with hydrophilic group part, and stability is not high, has influence on the stability that emulsion is used yet.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of water-based wax emulsion that increases leather polishing degree.
Adopt the preparation of direct high-temperature closed emulsion process, be about to water, tensio-active agent, emulsification synergistic agent, oxidized polyethlene wax and other additives add in reactor, start heating and stir after airtight.After emulsification for some time, cooling, i.e. available polyethylene wax super microemulsion.Emulsification synergistic agent can improve the dispersion stabilization of wax emulsion.
The invention provides a kind of water-based wax emulsion that increases leather polishing degree, by following steps, realize:
Mark by weight, by oxidized polyethlene wax 5-40 part, emulsifying agent 1-10 part, perfluoroalkyl trimethyl-glycine 0.1-0.5 part, Dioctadecyl Amine 0.1-0.5 part, defoamer 0.1-0.5 part etc. joins in emulsifying kettle, heated mixt 100-150 ℃, makes all material meltings, and melts is cooled to 80-100 ℃, the isothermal hot water that slowly adds water 30-60 part, high-speed stirring, is incubated 0.5-3 hour simultaneously, cooling rapidly, the cold water of 10-30 part is added to discharging after stirring.
Described emulsifying agent is nonionic emulsifier, is any one in Voranol EP 2001, polyoxyethylene alkyl phenyl ether, polyxyethylated allyl ether, polyoxyethylene shrink Sorbitol Powder fatty acid ester, polyoxyethylene sorbitol fatty acid ester, glycerol fatty acid ester, fatty alcohol-polyoxyethylene ether.Preferred fat polyoxyethylenated alcohol.For commercially available prod, as the product of Tianjin Hong Mei Chemical Co., Ltd. production.
The preferred polysiloxane defoamers of described defoamer, as kinds such as HX-5040, HX-5041, HX-5042, HX-5050, HX-5051, preferably HX-5041, is commercially available prod, as the product of Fanyu, Guangzhou China auxiliary agent company limited production.
Described emulsification synergistic agent perfluoroalkyl trimethyl-glycine is commercially available prod, as the product of Wuhan Sai Woer Chemical Co., Ltd. production.Molecular formula is: C
15h
15f
17n
2o
4s.
Described emulsification synergistic agent Dioctadecyl Amine is commercially available prod, as added the product that many foodstuff additive company limited produces in Suzhou.Molecular formula is: C
37h
77n.
Beneficial effect of the present invention:
Oxidized polyethlene wax superfine emulsion, through perfluoroalkyl trimethyl-glycine and Dioctadecyl Amine synergy emulsification, can significantly obviously be improved the performances such as microemulsion damping, diffusion, film forming, levelling.Improve the stability that emulsion is used.
Embodiment
Following examples are only to further illustrate the present invention, are not restriction the scope of protection of the invention.
The invention provides a kind of water-based wax emulsion that increases leather polishing degree, by following steps, realize:
Embodiment 1
In 500L emulsifying kettle, add oxidized polyethlene wax 20Kg, fatty alcohol-polyoxyethylene ether 4Kg, perfluoroalkyl trimethyl-glycine 0.2Kg, Dioctadecyl Amine 0.3Kg, HX-5041 defoamer 0.2Kg, 120 ℃ of heated mixt, make all material meltings, and melts is cooled to 90 ℃, the isothermal hot water that slowly adds water 50Kg, high-speed stirring, is incubated 1 hour simultaneously, cooling rapidly, the cold water of 20Kg is added to discharging after stirring.Obtain product, be numbered SX-1.
Embodiment 2
In 200L emulsifying kettle, add oxidized polyethlene wax 5Kg, fatty alcohol-polyoxyethylene ether 1Kg, perfluoroalkyl trimethyl-glycine 0.1Kg, Dioctadecyl Amine 0.1Kg, HX-5041 defoamer 0.1Kg, 100 ℃ of heated mixt, make all material meltings, and melts is cooled to 80 ℃, the isothermal hot water that slowly adds water 30Kg, high-speed stirring, is incubated 0.5 hour simultaneously, cooling rapidly, the cold water of 10Kg is added to discharging after stirring.Obtain product, be numbered SX-2.
Embodiment 3
In 500L emulsifying kettle, add oxidized polyethlene wax 40Kg, fatty alcohol-polyoxyethylene ether 10Kg, perfluoroalkyl trimethyl-glycine 0.5Kg, Dioctadecyl Amine 0.5Kg, HX-5041 defoamer 0.5Kg, 150 ℃ of heated mixt, make all material meltings, and melts is cooled to 100 ℃, the isothermal hot water that slowly adds water 60Kg, high-speed stirring, is incubated 3 hours simultaneously, cooling rapidly, the cold water of 30Kg is added to discharging after stirring.Obtain product, be numbered SX-3.
Comparative example 1
Do not add perfluoroalkyl trimethyl-glycine, the other the same as in Example 1.Products obtained therefrom is numbered SX-4.
Comparative example 2
Do not add Dioctadecyl Amine, the other the same as in Example 1.Products obtained therefrom is numbered SX-5.
Comparative example 2
Do not add perfluoroalkyl trimethyl-glycine, Dioctadecyl Amine, the other the same as in Example 1.Products obtained therefrom is numbered SX-6.
Embodiment 4
The water-based wax emulsion that embodiment 1-3 and comparative example 1-3 make, for leather finish technique, detects feel and the gloss of coating.Method is referring to Wei Shilin work " Wei Shilin, tanning technology, China Light Industry Press, 2005 ".
Detection of Stability: get water-based wax emulsion that embodiment 1-3 and comparative example 1-2 make with static after 10 times of volumes of hot water dilution, observe emulsion and change.
| Sample | Feel | Color and luster | Stability |
| SX-1 | Smooth plentiful | Light homogeneous | Not stratified |
| SX-2 | Smooth plentiful | Light homogeneous | Not stratified |
| SX-3 | Smooth plentiful | Light homogeneous | Not stratified |
| SX-4 | Moisture feeling is strong | Light homogeneous | Not stratified |
| SX-5 | Moisture feeling is strong | Light homogeneous | Not stratified |
| SX-6 | Moisture feeling is stronger | Light homogeneous | Layering after 1 week |
Claims (3)
1. a water-based wax emulsion that increases leather polishing degree, is characterized in that comprising the following steps:
Mark by weight, by oxidized polyethlene wax 5-40 part, emulsifying agent 1-10 part, perfluoroalkyl trimethyl-glycine 0.1-0.5 part, Dioctadecyl Amine 0.1-0.5 part, defoamer 0.1-0.5 part etc. joins in emulsifying kettle, heated mixt 100-150 ℃, makes all material meltings, and melts is cooled to 80-100 ℃, the isothermal hot water that slowly adds water 30-60 part, high-speed stirring, is incubated 0.5-3 hour simultaneously, cooling rapidly, the cold water of 10-30 part is added, and after stirring, discharging obtains product.
2. a kind of water-based wax emulsion that increases leather polishing degree according to claim 1, is characterized in that, uses perfluoroalkyl trimethyl-glycine, and Dioctadecyl Amine is as emulsification synergistic agent.
3. a kind of water-based wax emulsion that increases leather polishing degree obtaining according to the described preparation method of one of claim 1-2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410311950.6A CN104087183B (en) | 2014-06-26 | 2014-06-26 | A kind of water-borne wax emulsion increasing leather polishing degree |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410311950.6A CN104087183B (en) | 2014-06-26 | 2014-06-26 | A kind of water-borne wax emulsion increasing leather polishing degree |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104087183A true CN104087183A (en) | 2014-10-08 |
| CN104087183B CN104087183B (en) | 2016-01-20 |
Family
ID=51634950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410311950.6A Active CN104087183B (en) | 2014-06-26 | 2014-06-26 | A kind of water-borne wax emulsion increasing leather polishing degree |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104087183B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838263A (en) * | 2016-04-10 | 2016-08-10 | 张耀忠 | Compound wax emulsion |
| CN106244025A (en) * | 2016-08-02 | 2016-12-21 | 鄢海军 | A kind of wax of preventing coating protection Automobile paint |
| CN106752419A (en) * | 2016-11-28 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing OPE and preparation method thereof |
| CN107325652A (en) * | 2016-11-28 | 2017-11-07 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
| CN111979802A (en) * | 2020-07-24 | 2020-11-24 | 江苏海云花新材料有限公司 | Wax emulsion for yarn dyeing |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265663A (en) * | 1979-09-27 | 1981-05-05 | Petrolite Corporation | Wax formulations |
| US4592934A (en) * | 1984-11-02 | 1986-06-03 | Union Carbide Corporation | Method of preparing and packaging automobile wax |
| US5202041A (en) * | 1990-03-02 | 1993-04-13 | Enichem Synthesis S.P.A. | Ski lubricant comprising paraffinic wax and a hydrocarbon compound containing a perfluoro segment |
| TW442579B (en) * | 1995-03-15 | 2001-06-23 | Nihon Parkerizing | Aqueous chromate treatment composition and process for metal material |
| CN1519226A (en) * | 2003-01-21 | 2004-08-11 | 上海高维科技发展有限公司 | Method for synthetizing betaine of perfluoroalkyl group |
| US7503963B2 (en) * | 2003-12-05 | 2009-03-17 | Ashland Licensing And Intellectual Property Llc | Cleaning and polishing wax composition |
| CN101503516A (en) * | 2009-03-09 | 2009-08-12 | 陕西科技大学 | Preparation of cationic-nonionic oxidated polyethylene wax compositional hand feeling agent |
| CN101503517A (en) * | 2009-03-09 | 2009-08-12 | 陕西科技大学 | Preparation of cationic-nonionic modified oxidated polyethylene wax emulsion |
| CN101772567A (en) * | 2007-08-06 | 2010-07-07 | 纳幕尔杜邦公司 | Fluorinated nonionic surfactants |
| CN102030996A (en) * | 2010-10-27 | 2011-04-27 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-soluble OP wax emulsion and preparation method thereof |
| CN102115639A (en) * | 2011-04-07 | 2011-07-06 | 燕山大学 | Quick polishing shoe cream |
| CN103146204A (en) * | 2013-03-19 | 2013-06-12 | 广西壮族自治区化工研究院 | Emulsion paraffin for producing waterproof fiberboard and preparation method thereof |
| CN103614083A (en) * | 2013-12-03 | 2014-03-05 | 沈阳化工大学 | Automobile cleaning water wax and preparation method thereof |
| CN103773238A (en) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | Wax-containing composition used for water resistance and viscidity increasing of table tennis bats |
-
2014
- 2014-06-26 CN CN201410311950.6A patent/CN104087183B/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265663A (en) * | 1979-09-27 | 1981-05-05 | Petrolite Corporation | Wax formulations |
| US4592934A (en) * | 1984-11-02 | 1986-06-03 | Union Carbide Corporation | Method of preparing and packaging automobile wax |
| US5202041A (en) * | 1990-03-02 | 1993-04-13 | Enichem Synthesis S.P.A. | Ski lubricant comprising paraffinic wax and a hydrocarbon compound containing a perfluoro segment |
| TW442579B (en) * | 1995-03-15 | 2001-06-23 | Nihon Parkerizing | Aqueous chromate treatment composition and process for metal material |
| CN1519226A (en) * | 2003-01-21 | 2004-08-11 | 上海高维科技发展有限公司 | Method for synthetizing betaine of perfluoroalkyl group |
| US7503963B2 (en) * | 2003-12-05 | 2009-03-17 | Ashland Licensing And Intellectual Property Llc | Cleaning and polishing wax composition |
| CN101772567A (en) * | 2007-08-06 | 2010-07-07 | 纳幕尔杜邦公司 | Fluorinated nonionic surfactants |
| CN101503516A (en) * | 2009-03-09 | 2009-08-12 | 陕西科技大学 | Preparation of cationic-nonionic oxidated polyethylene wax compositional hand feeling agent |
| CN101503517A (en) * | 2009-03-09 | 2009-08-12 | 陕西科技大学 | Preparation of cationic-nonionic modified oxidated polyethylene wax emulsion |
| CN102030996A (en) * | 2010-10-27 | 2011-04-27 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-soluble OP wax emulsion and preparation method thereof |
| CN102115639A (en) * | 2011-04-07 | 2011-07-06 | 燕山大学 | Quick polishing shoe cream |
| CN103773238A (en) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | Wax-containing composition used for water resistance and viscidity increasing of table tennis bats |
| CN103146204A (en) * | 2013-03-19 | 2013-06-12 | 广西壮族自治区化工研究院 | Emulsion paraffin for producing waterproof fiberboard and preparation method thereof |
| CN103614083A (en) * | 2013-12-03 | 2014-03-05 | 沈阳化工大学 | Automobile cleaning water wax and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 程宁: "含氟表面活性剂的生产应用现状及研究进展", 《日用化学品科学》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838263A (en) * | 2016-04-10 | 2016-08-10 | 张耀忠 | Compound wax emulsion |
| CN106244025A (en) * | 2016-08-02 | 2016-12-21 | 鄢海军 | A kind of wax of preventing coating protection Automobile paint |
| CN106752419A (en) * | 2016-11-28 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing OPE and preparation method thereof |
| CN107325652A (en) * | 2016-11-28 | 2017-11-07 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
| CN111979802A (en) * | 2020-07-24 | 2020-11-24 | 江苏海云花新材料有限公司 | Wax emulsion for yarn dyeing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104087183B (en) | 2016-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104087183B (en) | A kind of water-borne wax emulsion increasing leather polishing degree | |
| CN105238232B (en) | Aqueous antirust paint and preparation method thereof | |
| CN104278287A (en) | Corrosion-inhibition type water-based metal cleaner | |
| CN104513616B (en) | Leather finish wax is stablized in a kind of environmental protection | |
| CN108373760A (en) | A kind of water-based acrylic acid modified alcoholic acid antirust paint and preparation method thereof | |
| CN103146276B (en) | Leather moditied processing matrix material and preparation method thereof | |
| CN107805437A (en) | It is a kind of to be used to repair aqueous woodware paint of color and preparation method thereof | |
| CN103911033A (en) | Special environment-friendly paint prepared by using raw lacquer as biomass base for furniture and cabinets | |
| CN106634424A (en) | Water-based epoxy anti-corrosion primer | |
| CN102675781B (en) | Condensed polytetrafluoroethylene aqueous dispersion, preparation method and application thereof | |
| CN109852181A (en) | The preparation method of epoxy modified acrylic resin antirust emulsion | |
| CN102703623A (en) | Novel greasing agent for synthetic leather and preparation method for novel greasing agent | |
| CN109021574A (en) | A kind of aqueous dimethylformamide MQ resin emulsion and preparation method thereof | |
| CN104479235A (en) | Wax emulsion for improving wear resistance of water-based ink | |
| CN107903994A (en) | Cold rolled sheet factory leveling precision, preparation method and its application method | |
| CN101838931A (en) | Aqueous environment-friendly leather bottom-closing and wax residue-covering emulsion and preparation process thereof | |
| CN105419975B (en) | A kind of electric power facility surface dust antirust cleaning treatment agent | |
| CN106220778A (en) | The preparation method of acrylic polyurethane enamel water-borne acrylic resin | |
| CN110016264A (en) | A kind of dip-coating water soluble acrylic acid amino-stoving varnish and preparation method thereof | |
| CN105601881A (en) | Preparation method of water-based polyurethane, emulsion and product | |
| CN106978052A (en) | A kind of preparation method of environmental protection paint | |
| CN105086568A (en) | Dispersing and anti-settling agent for powder-free PVC glove coating with high dilution ratio | |
| CN113652283B (en) | Water-based behenic acid amide emulsion and preparation method thereof | |
| CN109722888A (en) | A kind of novel terylene spinning finish | |
| CN106867387B (en) | A kind of environmental protection paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |