CN104691069A - Teflon composite film for protective garment - Google Patents

Teflon composite film for protective garment Download PDF

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Publication number
CN104691069A
CN104691069A CN201510127631.4A CN201510127631A CN104691069A CN 104691069 A CN104691069 A CN 104691069A CN 201510127631 A CN201510127631 A CN 201510127631A CN 104691069 A CN104691069 A CN 104691069A
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China
Prior art keywords
parts
protective garment
composite film
polytetrafluoroethylene film
film
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Granted
Application number
CN201510127631.4A
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Chinese (zh)
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CN104691069B (en
Inventor
徐春华
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Suzhou New District Huashida Engineering Plastic Co Ltd
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Suzhou New District Huashida Engineering Plastic Co Ltd
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Priority to CN201510127631.4A priority Critical patent/CN104691069B/en
Publication of CN104691069A publication Critical patent/CN104691069A/en
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Publication of CN104691069B publication Critical patent/CN104691069B/en
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/02Layered materials

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a teflon composite film for a protective garment. The teflon composite film comprises a teflon film layer and a PU coating. The PU coating comprises a bottom layer and an upper layer. The upper surface and the lower surface of the teflon film layer are coated with the bottom layer and the upper layer respectively. The teflon film layer comprises, by weight, 85-95 parts of polyflon, 5-8 parts of silicone powder, 2-4 parts of polyether ether ketone and 3.5-6.5 parts of lubricant. The PU coating comprises, by weight, 100 parts of PU resin, 10-15 parts of polyethylene wax, 5-10 parts of nanometer titania and 10-18 parts of N,N- nanometer titania. In this way, according to the teflon composite film for the protective garment, elasticity and protective performance of the film product are improved, the multiple functions of high temperature resisting, abrasion resisting, water resisting, moisture permeating, corrosion preventing and the like are achieved, and the teflon composite film is especially suitable for the protective garment used in a workplace where the working environment is severe.

Description

A kind of protective garment polytetrafluoroethylcomposite composite film
Technical field
The present invention relates to polytetrafluoroethylcomposite composite film, particularly relate to a kind of protective garment polytetrafluoroethylcomposite composite film.
Background technology
Polytetrafluoroethylene film has the multiple excellent functions such as windproof, geomantic omen, moisture-inhibiting, but polytetrafluoroethylene film lacks flexibility, wears no resistance, if direct combination is in textile material, can affect the effect of itself and textile material.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of protective garment polytetrafluoroethylcomposite composite film of kind of the present invention, add elasticity and the protective of film article, there is the several functions such as high temperature resistant, wear-resisting, waterproof, moisture-inhibiting, anticorrosion, be particularly suitable for the workplace protection clothes of work under bad environment.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of protective garment polytetrafluoroethylcomposite composite film, comprise polytetrafluoroethylene film layer and PU coating, described PU coating comprises bottom and upper strata, described bottom and upper strata are coated in the upper and lower surface of polytetrafluoroethylene film layer respectively, and described polytetrafluoroethylene film layer is made up of the raw material of following weight portion: polyflon 85-95 part, silicone powder 5-8 part, polyethers ether copper 2-4 part, lubricant 3.5-6.5 part; Described PU coating is made up of the raw material of following weight portion: PU resin 100 parts, Tissuemat E 10-15 part, nano titanium oxide 5-10 part, DMF 10 – 18 parts.
In the present invention's preferred embodiments, described polytetrafluoroethylene film layer is made up of the raw material of following weight portion: polyflon 90-95 part, silicone powder 6-8 part, polyethers ether copper 3-4 part, lubricant 4.5-6.5 part.
In the present invention's preferred embodiments, described lubricant is kerosene.
The preparation method of protective garment polytetrafluoroethylcomposite composite film, comprise the following steps:
(1) polytetrafluoroethylene film preparation, take 90 parts of polyflons, 7 parts of silicone divide, 3 parts of polyethers ether copper are poured in mixer to stir and made blended stock, then circular bar is extruded into after being mixed with 6.5 parts of kerosene by compound, then microscler strip is squeezed into along its length, again by strip axial tension at 115-125 DEG C, remove kerosene simultaneously, form stretched film;
(2) shape, by stretched film thermal finalization 5-7S at temperature is 265-295 DEG C, namely form polytetrafluoroethylene film;
(3) 100 parts of PU resins, 12 parts of Tissuemat Es, 10 parts of nano titanium oxides are added N, in dinethylformamide, stir the solution making 45%, then add diluent dilution and make polyurethane coating solution, scraper is used to be coated in above polytetrafluoroethylene film by polyurethane solutions, then be the baking 5-7min of 80-90 DEG C in temperature, take out; Then according to same method, polyurethane solutions being coated in polytetrafluoroethylene film bottom surface, is the baking 5-7min of 80-90 DEG C in temperature, takes out; And then put into the drying oven baking 8-10min that temperature is 145-155 DEG C.
The invention has the beneficial effects as follows: a kind of protective garment polytetrafluoroethylcomposite composite film of the present invention, add elasticity and the protective of film article, there is the several functions such as high temperature resistant, wear-resisting, waterproof, moisture-inhibiting, anticorrosion, be particularly suitable for the workplace protection clothes of work under bad environment.
Detailed description of the invention
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of protective garment polytetrafluoroethylcomposite composite film, comprise polytetrafluoroethylene film layer and PU coating, described PU coating comprises bottom and upper strata, described bottom and upper strata are coated in the upper and lower surface of polytetrafluoroethylene film layer respectively, and described polytetrafluoroethylene film layer is made up of the raw material of following weight portion: polyflon 85-95 part, silicone powder 5-8 part, polyethers ether copper 2-4 part, lubricant 3.5-6.5 part; Described PU coating is made up of the raw material of following weight portion: PU resin 100 parts, Tissuemat E 10-15 part, nano titanium oxide 5-10 part, DMF 10 – 18 parts.
Further, described polytetrafluoroethylene film layer is made up of the raw material of following weight portion: polyflon 90-95 part, silicone powder 6-8 part, polyethers ether copper 3-4 part, lubricant 4.5-6.5 part.
Further, described lubricant is kerosene.
The preparation method of protective garment polytetrafluoroethylcomposite composite film, comprise the following steps:
(1) polytetrafluoroethylene film preparation, take 90 parts of polyflons, 7 parts of silicone divide, 3 parts of polyethers ether copper are poured in mixer to stir and made blended stock, then circular bar is extruded into after being mixed with 6.5 parts of kerosene by compound, then microscler strip is squeezed into along its length, again by strip axial tension at 115-125 DEG C, remove kerosene simultaneously, form stretched film;
(2) shape, by stretched film thermal finalization 5-7S at temperature is 265-295 DEG C, namely form polytetrafluoroethylene film;
(3) 100 parts of PU resins, 12 parts of Tissuemat Es, 10 parts of nano titanium oxides are added N, in dinethylformamide, stir the solution making 45%, then add diluent dilution and make polyurethane coating solution, scraper is used to be coated in above polytetrafluoroethylene film by polyurethane solutions, then be the baking 5-7min of 80-90 DEG C in temperature, take out; Then according to same method, polyurethane solutions being coated in polytetrafluoroethylene film bottom surface, is the baking 5-7min of 80-90 DEG C in temperature, takes out; And then put into the drying oven baking 8-10min that temperature is 145-155 DEG C.
The invention has the beneficial effects as follows: a kind of protective garment polytetrafluoroethylcomposite composite film of the present invention, add elasticity and the protective of film article, there is the several functions such as high temperature resistant, wear-resisting, waterproof, moisture-inhibiting, anticorrosion, be particularly suitable for the workplace protection clothes of work under bad environment.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (4)

1. a protective garment polytetrafluoroethylcomposite composite film, it is characterized in that, comprise polytetrafluoroethylene film layer and PU coating, described PU coating comprises bottom and upper strata, described bottom and upper strata are coated in the upper and lower surface of polytetrafluoroethylene film layer respectively, and described polytetrafluoroethylene film layer is made up of the raw material of following weight portion: polyflon 85-95 part, silicone powder 5-8 part, polyethers ether copper 2-4 part, lubricant 3.5-6.5 part; Described PU coating is made up of the raw material of following weight portion: PU resin 100 parts, Tissuemat E 10-15 part, nano titanium oxide 5-10 part, DMF 10 – 18 parts.
2. protective garment polytetrafluoroethylcomposite composite film according to claim 1, it is characterized in that, described polytetrafluoroethylene film layer is made up of the raw material of following weight portion: polyflon 90-95 part, silicone powder 6-8 part, polyethers ether copper 3-4 part, lubricant 4.5-6.5 part.
3. protective garment polytetrafluoroethylcomposite composite film according to claim 1, is characterized in that, described lubricant is kerosene.
4. the preparation method of protective garment polytetrafluoroethylcomposite composite film according to claim 1, is characterized in that, comprise the following steps:
(1) polytetrafluoroethylene film preparation, take 90 parts of polyflons, 7 parts of silicone divide, 3 parts of polyethers ether copper are poured in mixer to stir and made blended stock, then circular bar is extruded into after being mixed with 6.5 parts of kerosene by compound, then microscler strip is squeezed into along its length, again by strip axial tension at 115-125 DEG C, remove kerosene simultaneously, form stretched film;
(2) shape, by stretched film thermal finalization 5-7S at temperature is 265-295 DEG C, namely form polytetrafluoroethylene film;
(3) 100 parts of PU resins, 12 parts of Tissuemat Es, 10 parts of nano titanium oxides are added N, in dinethylformamide, stir the solution making 45%, then add diluent dilution and make polyurethane coating solution, scraper is used to be coated in above polytetrafluoroethylene film by polyurethane solutions, then be the baking 5-7min of 80-90 DEG C in temperature, take out; Then according to same method, polyurethane solutions being coated in polytetrafluoroethylene film bottom surface, is the baking 5-7min of 80-90 DEG C in temperature, takes out; And then put into the drying oven baking 8-10min that temperature is 145-155 DEG C.
CN201510127631.4A 2015-03-24 2015-03-24 A kind of protective garment polytetrafluoroethylcomposite composite film Active CN104691069B (en)

Priority Applications (1)

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CN201510127631.4A CN104691069B (en) 2015-03-24 2015-03-24 A kind of protective garment polytetrafluoroethylcomposite composite film

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Application Number Priority Date Filing Date Title
CN201510127631.4A CN104691069B (en) 2015-03-24 2015-03-24 A kind of protective garment polytetrafluoroethylcomposite composite film

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CN104691069B CN104691069B (en) 2016-09-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105413979A (en) * 2015-10-28 2016-03-23 沈阳名华模塑科技有限公司 Method for producing colored bumpers
CN108948611A (en) * 2018-08-15 2018-12-07 宁波登越新材料科技有限公司 A method of eliminating polytetrafluoroethylmicroporous microporous membrane layering
CN113524838A (en) * 2021-07-08 2021-10-22 无锡市劲甲新材料科技有限公司 Reusable breathable moisture-permeable antistatic medical protective fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030010939A1 (en) * 1998-12-07 2003-01-16 Meridian Research And Development Lightweight radiation protective articles and methods for making them
CN101104314A (en) * 2006-11-30 2008-01-16 中国人民解放军总后勤部军需装备研究所 Polytetrafluoroethylene multi-layer composite film and its protective material preparation method
CN101135115A (en) * 2007-08-29 2008-03-05 中国人民解放军总后勤部军需装备研究所 Method for preparing polytetrafluoroethylene waterproof moisture permeating fabric
CN102431253A (en) * 2010-09-29 2012-05-02 江苏金纺针织有限公司 Protective composite fabric

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030010939A1 (en) * 1998-12-07 2003-01-16 Meridian Research And Development Lightweight radiation protective articles and methods for making them
CN101104314A (en) * 2006-11-30 2008-01-16 中国人民解放军总后勤部军需装备研究所 Polytetrafluoroethylene multi-layer composite film and its protective material preparation method
CN101135115A (en) * 2007-08-29 2008-03-05 中国人民解放军总后勤部军需装备研究所 Method for preparing polytetrafluoroethylene waterproof moisture permeating fabric
CN102431253A (en) * 2010-09-29 2012-05-02 江苏金纺针织有限公司 Protective composite fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105413979A (en) * 2015-10-28 2016-03-23 沈阳名华模塑科技有限公司 Method for producing colored bumpers
CN108948611A (en) * 2018-08-15 2018-12-07 宁波登越新材料科技有限公司 A method of eliminating polytetrafluoroethylmicroporous microporous membrane layering
CN113524838A (en) * 2021-07-08 2021-10-22 无锡市劲甲新材料科技有限公司 Reusable breathable moisture-permeable antistatic medical protective fabric

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