CN105544217A - Resin non-ironing finishing agent and preparation method thereof - Google Patents
Resin non-ironing finishing agent and preparation method thereof Download PDFInfo
- Publication number
- CN105544217A CN105544217A CN201610111194.1A CN201610111194A CN105544217A CN 105544217 A CN105544217 A CN 105544217A CN 201610111194 A CN201610111194 A CN 201610111194A CN 105544217 A CN105544217 A CN 105544217A
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- wash
- resinae
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a resin non-ironing finishing agent comprising components in parts by weight as follows: 15-25 parts of resorcinol-acetaldehyde pre-condensed resin, 10-18 parts of terpene resin, 8-16 parts of manila elemi gum, 5-10 parts of butyl acrylate, 10-15 parts of acrylic acid, 3-8 parts of sodium bicarbonate, 2-7 parts of styrene, 4-7 parts of diacetone acrylamide, 5-12 parts of glyoxal and 30-40 parts of deionized water. With the adoption of the finishing agent, crease resistance, shrinkage resistance and non-ironing performance of textile clothes can be obviously improved and harmful substances such as formaldehyde are effectively avoided.
Description
Technical field
The invention belongs to finishing agent field, be specifically related to a kind of resinae wash and wear finisher and preparation method thereof.
Background technology
Mainly there is wrinkle resistance difference to improve COTTON FABRIC in wash and wear finisher, crease easily, easily shrink, wash after need the defect that presses.Existing resinae wash and wear finisher is mainly N-methylol amide resinae crease proofing agent, and it has cheap, and the advantage of good finishing effect, is thus widely used in textile industry.But the fabric that it arranges can discharge the formaldehyde to human body and bad environmental in processing, storage and use procedure.Thus develop environmental friendliness, the resinae wash and wear finisher of good finishing effect seems particularly important.
Summary of the invention
For the above technical problem existed in prior art, the invention provides a kind of resinae wash and wear finisher and preparation method thereof, utilize this finishing agent process cotton thing, while not discharging formaldehyde, the wrinkle resistance of clothing, anti-shrinkage can be significantly improved, exempt to press performance.
Technical scheme: a kind of resinae wash and wear finisher, comprise the composition of following parts by weight: resorcinol-acetaldehyde precondensate resin 15-25 part, polyterpene resin 10-18 part, Manila elemi resin 8-16 part, butyl acrylate 5-10 part, acrylic acid 10-15 part, sodium bicarbonate 3-8 part, styrene 2-7 part, diacetone acrylamide 4-7 part, glyoxal 5-12 part, deionized water 30-40 part.
Preferably, described resorcinol-acetaldehyde precondensate resin 17-22 part, polyterpene resin 13-16 part, Manila elemi resin 10-14 part, butyl acrylate 7-9 part, acrylic acid 12-14 part, sodium bicarbonate 4-7 part, styrene 3-6 part, diacetone acrylamide 5-7 part, glyoxal 6-9 part, deionized water 35-40 part.
Preferably, described resorcinol-acetaldehyde precondensate resin 20 parts, polyterpene resin 14 parts, Manila elemi resin 13 parts, butyl acrylate 8 parts, 13 parts, acrylic acid, sodium bicarbonate 6 parts, styrene 5 parts, diacetone acrylamide 6 parts, glyoxal 8 parts, deionized water 38 parts.
A preparation method for resinae wash and wear finisher, comprises the steps:
S1: resorcinol-acetaldehyde precondensate resin 15-25 part, polyterpene resin 10-18 part, Manila elemi resin 8-16 part, styrene 2-7 part and glyoxal 5-12 part are added in reactor, raised temperature is to 70-80 DEG C, and reaction 30-50min, obtains mixed liquor A;
S2: butyl acrylate 5-10 part, acrylic acid 10-15 part and deionized water 30-40 part are stirred, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 4-7 part, raised temperature 60-80 DEG C, reaction 10-15min;
S4: drip sodium bicarbonate 3-8 part in step S3, be heated to 90-100 DEG C while stirring, following reaction 1-3h; Described resinae wash and wear finisher can be obtained after question response cooling.
Preferably, temperature described in step S1 is 75 DEG C, reaction 45min.
Preferably, temperature described in step S3 is 70 DEG C, reaction 12min
Preferably, temperature described in step S4 is 95 DEG C, and reaction 2h, heating rate is 1 °/min.
Beneficial effect: the preparation method of a kind of resinae wash and wear finisher of the present invention, with materials such as resorcinol-acetaldehyde precondensate resin, polyterpene resin, Manila elemi resins for raw material, through stirring, adding the steps such as thermal response and prepare resinae wash and wear finisher, avoid the generation of formaldehyde harmful substance; This preparation technology is simple, process is shorter; Wrinkle resistance, the anti-shrinkage of clothing can be significantly improved after textile clothes utilizes finishing agent of the present invention, exempt to press performance.
Detailed description of the invention
Embodiment 1
S1: resorcinol-acetaldehyde precondensate resin 15 parts, polyterpene resin 10 parts, Manila elemi resin 8 parts, styrene 2 parts and glyoxal 5 parts are added in reactor, raised temperature to 70 DEG C, reaction 30min, obtains mixed liquor A;
S2: by butyl acrylate 5 parts, 10 parts, acrylic acid and deionized water 30 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 4 parts, raised temperature 60 DEG C, reaction 10min;
S4: drip sodium bicarbonate 3 parts in step S3, be heated to 90 DEG C while stirring, heating rate is 1 °/min; Following reaction 1h; Described resinae wash and wear finisher can be obtained after question response cooling.
Comparative example 1
S1: styrene 2 parts and glyoxal 5 parts are added in reactor, raised temperature to 70 DEG C, reaction 30min, obtains mixed liquor A;
S2: by butyl acrylate 5 parts, 10 parts, acrylic acid and deionized water 30 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 4 parts, raised temperature 60 DEG C, reaction 10min;
S4: drip sodium bicarbonate 3 parts in step S3, be heated to 90 DEG C while stirring, heating rate is 1 °/min; Following reaction 1h; Finishing agent can be obtained after question response cooling.
Embodiment 2
S1: resorcinol-acetaldehyde precondensate resin 25 parts, polyterpene resin 18 parts, Manila elemi resin 16 parts, styrene 7 parts and glyoxal 12 parts are added in reactor, raised temperature to 80 DEG C, reaction 50min, obtains mixed liquor A;
S2: by butyl acrylate 10 parts, 15 parts, acrylic acid and deionized water 40 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 7 parts, raised temperature 80 DEG C, reaction 15min;
S4: drip sodium bicarbonate 8 parts in step S3, be heated to 100 DEG C while stirring, heating rate is 1 °/min; Following reaction 3h; Described resinae wash and wear finisher can be obtained after question response cooling.
Comparative example 2
S1: styrene 7 parts and glyoxal 12 parts are added in reactor, raised temperature to 80 DEG C, reaction 50min, obtains mixed liquor A;
S2: by butyl acrylate 10 parts, 15 parts, acrylic acid and deionized water 40 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 7 parts, raised temperature 80 DEG C, reaction 15min;
S4: drip sodium bicarbonate 8 parts in step S3, be heated to 100 DEG C while stirring, heating rate is 1 °/min; Following reaction 3h; Finishing agent can be obtained after question response cooling.
Embodiment 3
S1: resorcinol-acetaldehyde precondensate resin 17 parts, polyterpene resin 13 parts, Manila elemi resin 10 parts, styrene 3 parts and glyoxal 6 parts are added in reactor, raised temperature to 70 DEG C, reaction 30min, obtains mixed liquor A;
S2: by butyl acrylate 7 parts, 12 parts, acrylic acid and deionized water 35 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 5 parts, raised temperature 60 DEG C, reaction 10min;
S4: drip sodium bicarbonate 4 parts in step S3, be heated to 90 DEG C while stirring, heating rate is 1 °/min; Following reaction 1h; Described resinae wash and wear finisher can be obtained after question response cooling.
Embodiment 4
S1: resorcinol-acetaldehyde precondensate resin 22 parts, polyterpene resin 16 parts, Manila elemi resin 14 parts, styrene 6 parts and glyoxal 9 parts are added in reactor, raised temperature to 80 DEG C, reaction 50min, obtains mixed liquor A;
S2: by butyl acrylate 9 parts, 14 parts, acrylic acid and deionized water 40 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 7 parts, raised temperature 80 DEG C, reaction 15min;
S4: drip sodium bicarbonate 7 parts in step S3, be heated to 100 DEG C while stirring, heating rate is 1 °/min; Following reaction 3h; Described resinae wash and wear finisher can be obtained after question response cooling.
Embodiment 5
S1: resorcinol-acetaldehyde precondensate resin 20 parts, polyterpene resin 14 parts, Manila elemi resin 13 parts, styrene 5 parts and glyoxal 8 parts are added in reactor, raised temperature to 75 DEG C, reaction 45min, obtains mixed liquor A;
S2: by butyl acrylate 8 parts, 13 parts, acrylic acid and deionized water 38 parts stirring, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 6 parts, raised temperature 70 DEG C, reaction 12min;
S4: drip sodium bicarbonate 6 parts in step S3, be heated to 95 DEG C while stirring, heating rate is 1 °/min; Following reaction 2h; Described resinae wash and wear finisher can be obtained after question response cooling.
By the finishing agent that each embodiment and comparative example obtain, be applied in textile clothes, test creasy recovery angle and the tearing brute force retention rate of treated textile clothes, result is as follows:
Claims (7)
1. a resinae wash and wear finisher, it is characterized in that, comprise the composition of following parts by weight: resorcinol-acetaldehyde precondensate resin 15-25 part, polyterpene resin 10-18 part, Manila elemi resin 8-16 part, butyl acrylate 5-10 part, acrylic acid 10-15 part, sodium bicarbonate 3-8 part, styrene 2-7 part, diacetone acrylamide 4-7 part, glyoxal 5-12 part, deionized water 30-40 part.
2. a kind of resinae wash and wear finisher according to claim 1, it is characterized in that, described resorcinol-acetaldehyde precondensate resin 17-22 part, polyterpene resin 13-16 part, Manila elemi resin 10-14 part, butyl acrylate 7-9 part, acrylic acid 12-14 part, sodium bicarbonate 4-7 part, styrene 3-6 part, diacetone acrylamide 5-7 part, glyoxal 6-9 part, deionized water 35-40 part.
3. a kind of resinae wash and wear finisher according to claim 2, it is characterized in that, described resorcinol-acetaldehyde precondensate resin 20 parts, polyterpene resin 14 parts, Manila elemi resin 13 parts, butyl acrylate 8 parts, 13 parts, acrylic acid, sodium bicarbonate 6 parts, styrene 5 parts, diacetone acrylamide 6 parts, glyoxal 8 parts, deionized water 38 parts.
4. a preparation method for resinae wash and wear finisher, is characterized in that, comprises the steps:
S1: resorcinol-acetaldehyde precondensate resin 15-25 part, polyterpene resin 10-18 part, Manila elemi resin 8-16 part, styrene 2-7 part and glyoxal 5-12 part are added in reactor, raised temperature is to 70-80 DEG C, and reaction 30-50min, obtains mixed liquor A;
S2: butyl acrylate 5-10 part, acrylic acid 10-15 part and deionized water 30-40 part are stirred, ultrasonic process, to dispersed shape, obtains mixed liquid B;
S3: mixed liquid B described in mixed liquor A described in step S1 and step S2 mixed, drips diacetone acrylamide 4-7 part, raised temperature 60-80 DEG C, reaction 10-15min;
S4: drip sodium bicarbonate 3-8 part in step S3, be heated to 90-100 DEG C while stirring, following reaction 1-3h; Described resinae wash and wear finisher can be obtained after question response cooling.
5. the preparation method of a kind of resinae wash and wear finisher according to claim 4, is characterized in that, temperature described in step S1 is 75 DEG C, reaction 45min.
6. the preparation method of a kind of resinae wash and wear finisher according to claim 4, is characterized in that, temperature described in step S3 is 70 DEG C, reaction 12min.
7. the preparation method of a kind of resinae wash and wear finisher according to claim 4, is characterized in that, temperature described in step S4 is 95 DEG C, and reaction 2h, heating rate is 1 °/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111194.1A CN105544217B (en) | 2016-02-29 | 2016-02-29 | A kind of resinae wash and wear finisher and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111194.1A CN105544217B (en) | 2016-02-29 | 2016-02-29 | A kind of resinae wash and wear finisher and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105544217A true CN105544217A (en) | 2016-05-04 |
| CN105544217B CN105544217B (en) | 2018-01-30 |
Family
ID=55823756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610111194.1A Active CN105544217B (en) | 2016-02-29 | 2016-02-29 | A kind of resinae wash and wear finisher and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105544217B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5352242A (en) * | 1992-06-02 | 1994-10-04 | Hoechst Aktiengesellschaft | Formaldehyde-free easy care finishing of cellulose-containing textile material |
| CN103088639A (en) * | 2012-11-09 | 2013-05-08 | 吴江市钱氏纺织有限公司 | Textile coating finishing agent and preparation method thereof |
| CN105133315A (en) * | 2015-09-21 | 2015-12-09 | 宁波雅戈尔科技有限公司 | Finishing agent composition for cotton-silk fabrics and processing method of cotton-silk easy-care shirt |
| CN105297429A (en) * | 2015-11-13 | 2016-02-03 | 朱家勇 | No-ironing clothes with lasting shape memory and preparation method thereof |
| CN105350286A (en) * | 2015-11-12 | 2016-02-24 | 嵊州盛泰色织科技有限公司 | Processing method of natural wash-and-wear purified cotton fabrics |
-
2016
- 2016-02-29 CN CN201610111194.1A patent/CN105544217B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5352242A (en) * | 1992-06-02 | 1994-10-04 | Hoechst Aktiengesellschaft | Formaldehyde-free easy care finishing of cellulose-containing textile material |
| CN103088639A (en) * | 2012-11-09 | 2013-05-08 | 吴江市钱氏纺织有限公司 | Textile coating finishing agent and preparation method thereof |
| CN105133315A (en) * | 2015-09-21 | 2015-12-09 | 宁波雅戈尔科技有限公司 | Finishing agent composition for cotton-silk fabrics and processing method of cotton-silk easy-care shirt |
| CN105350286A (en) * | 2015-11-12 | 2016-02-24 | 嵊州盛泰色织科技有限公司 | Processing method of natural wash-and-wear purified cotton fabrics |
| CN105297429A (en) * | 2015-11-13 | 2016-02-03 | 朱家勇 | No-ironing clothes with lasting shape memory and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 商成杰: "《功能纺织品》", 31 July 2006, 北京：中国纺织出版社 * |
| 邱文革等: "《大辞海 化工轻工纺织卷》", 31 August 2009, 北京：化学工业出版社 * |
| 黎钢: "《精细化工常用中间体手册》", 31 January 2009, 北京：化学工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105544217B (en) | 2018-01-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102391411A (en) | Low-temperature self-crosslinking polyacrylate pigment printing binding agent and preparation method thereof | |
| CN103333352B (en) | A kind of preparation method of cross-linked graft modified polyvinyl alcohol surface reinforcing agent | |
| CN102154852A (en) | Textile machinery printing pigment binding agent and manufacturing method thereof | |
| CN103757890B (en) | A kind of western-style clothes finishing agent and preparation method thereof | |
| CN103554346A (en) | Method for preparing pigment printing binder from oxidized graphene modified polyacrylate | |
| CN104558368B (en) | A kind of high temperature resistant wallpaper basement membrane and preparation method thereof | |
| CN108046648A (en) | A kind of preparation method of foam concrete foamer | |
| CN104831562A (en) | Hydroxypropyl carboxymethyl waxy corn starch acid dye printing paste and preparation method | |
| CN107653704B (en) | Fiber stock solution color paste and preparation method thereof | |
| CN104372690A (en) | Cationic polymer emulsion for dip dyeing of coating | |
| CN105544217A (en) | Resin non-ironing finishing agent and preparation method thereof | |
| CN106046242A (en) | Water-based environment-friendly flocking glue emulsion and manufacturing method thereof | |
| CN104878629B (en) | A kind of anionic dye color fixing agent having except aldehyde function and preparation method thereof | |
| US20130055485A1 (en) | Process for resin application for the treatment, with or without durable shape-memory, of ready-made cotton and mixed cotton garments | |
| CN105885743A (en) | Modified polyvinyl-alcohol binding agent | |
| CN104562719B (en) | The preparation method of a kind of base fabric fabric being applied to synthetic leather and the preparation method of a kind of synthetic leather | |
| CN104610512A (en) | Preparation method of super-soft IPN (interpenetrating polymer network) pigment printing binder | |
| CN104558379A (en) | Preparation technology of polyacrylic ester adhesive | |
| CN108276517A (en) | A kind of rubber cement resin and preparation method thereof that the adhesive force on cloth cover is preferable and anti-sticking | |
| CN103541230B (en) | Antistatic glove leather production method | |
| CN104072621A (en) | Method for preparing ultrahigh-viscosity sodium carboxymethyl cellulose | |
| CN103665236A (en) | Preparation method of anti-dripping agent | |
| CN104387508A (en) | Method for preparing paste resin with medium viscosity | |
| CN107513869A (en) | The preparation method of environment-friendly type low-temperature resistant coating stamp adhesive | |
| CN103061134B (en) | Adhesive for in-situ polymerization composite gluing technology of needled non-woven fabric and preparation method of adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |