CN1140539C - 烯烃聚合方法、所用的金属茂催化剂和用于活化金属茂催化剂前体的助催化剂 - Google Patents
烯烃聚合方法、所用的金属茂催化剂和用于活化金属茂催化剂前体的助催化剂 Download PDFInfo
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- CN1140539C CN1140539C CNB99812074XA CN99812074A CN1140539C CN 1140539 C CN1140539 C CN 1140539C CN B99812074X A CNB99812074X A CN B99812074XA CN 99812074 A CN99812074 A CN 99812074A CN 1140539 C CN1140539 C CN 1140539C
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- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C07—ORGANIC CHEMISTRY
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- C07F17/00—Metallocenes
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- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
Abstract
Description
催化剂前体 | 取代的Cp | 桥 | 对称性 | 杂原子 |
Cp2ZrCl2 | 否 | 否 | 是 | 否 |
Ind2ZrMe2 | 是 | 否 | 是 | 否 |
Me2Si(Cp)2ZrCl2 | 否 | 是 | 是 | 否 |
rac-Et(Ind)2ZrCl2 | 是 | 是 | 是 | 否 |
Ph2C(Cp-9-Flu)ZrCl2 | 是 | 是 | 否 | 否 |
Ph2Si(Cp-9-Flu)ZrCl2 | 是 | 是 | 否 | 否 |
Me2Si(C5Me4)(ButN)TiCl2 | 是 | 是 | 否 | 是 |
Claims (38)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/173,396 US6225427B1 (en) | 1998-10-15 | 1998-10-15 | Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst |
US09/173,396 | 1998-10-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1323321A CN1323321A (zh) | 2001-11-21 |
CN1140539C true CN1140539C (zh) | 2004-03-03 |
Family
ID=22631818
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB99812074XA Expired - Fee Related CN1140539C (zh) | 1998-10-15 | 1999-09-15 | 烯烃聚合方法、所用的金属茂催化剂和用于活化金属茂催化剂前体的助催化剂 |
Country Status (11)
Country | Link |
---|---|
US (1) | US6225427B1 (zh) |
EP (1) | EP1131360B1 (zh) |
JP (1) | JP4132672B2 (zh) |
KR (1) | KR100541146B1 (zh) |
CN (1) | CN1140539C (zh) |
AT (1) | ATE283292T1 (zh) |
BR (1) | BR9914539A (zh) |
CA (1) | CA2346284A1 (zh) |
DE (1) | DE69922241T2 (zh) |
TW (1) | TWI243183B (zh) |
WO (1) | WO2000022005A1 (zh) |
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EP2261269B1 (en) | 2003-07-09 | 2016-11-09 | Arlanxeo Netherlands B.V. | Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene |
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US8080699B2 (en) * | 2009-08-28 | 2011-12-20 | Chemtura Corporation | Two-stage process and system for forming high viscosity polyalphaolefins |
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KR101585206B1 (ko) * | 2013-07-22 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
CN104610479B (zh) * | 2013-11-05 | 2017-03-29 | 中国石油化工股份有限公司 | 用于乙烯聚合的负载化茂金属催化剂及其制备方法和应用 |
CN105566534B (zh) * | 2014-10-13 | 2018-03-02 | 中国石油化工股份有限公司 | 一种烯烃聚合物及其制造方法 |
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-
1998
- 1998-10-15 US US09/173,396 patent/US6225427B1/en not_active Expired - Lifetime
-
1999
- 1999-09-15 CN CNB99812074XA patent/CN1140539C/zh not_active Expired - Fee Related
- 1999-09-15 DE DE69922241T patent/DE69922241T2/de not_active Expired - Lifetime
- 1999-09-15 AT AT99970402T patent/ATE283292T1/de not_active IP Right Cessation
- 1999-09-15 EP EP99970402A patent/EP1131360B1/en not_active Expired - Lifetime
- 1999-09-15 BR BR9914539-1A patent/BR9914539A/pt not_active Application Discontinuation
- 1999-09-15 KR KR1020017004554A patent/KR100541146B1/ko not_active IP Right Cessation
- 1999-09-15 WO PCT/US1999/021278 patent/WO2000022005A1/en active IP Right Grant
- 1999-09-15 CA CA002346284A patent/CA2346284A1/en not_active Abandoned
- 1999-09-15 JP JP2000575907A patent/JP4132672B2/ja not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
TWI243183B (en) | 2005-11-11 |
DE69922241T2 (de) | 2005-11-10 |
EP1131360A1 (en) | 2001-09-12 |
ATE283292T1 (de) | 2004-12-15 |
CN1323321A (zh) | 2001-11-21 |
BR9914539A (pt) | 2001-10-23 |
DE69922241D1 (de) | 2004-12-30 |
JP4132672B2 (ja) | 2008-08-13 |
WO2000022005A1 (en) | 2000-04-20 |
CA2346284A1 (en) | 2000-04-20 |
KR100541146B1 (ko) | 2006-01-16 |
US6225427B1 (en) | 2001-05-01 |
JP2002527542A (ja) | 2002-08-27 |
EP1131360B1 (en) | 2004-11-24 |
KR20010075622A (ko) | 2001-08-09 |
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