CN1246066A - Adhesive for application of functional articles to skin and comfortable removal of such articles - Google Patents

Adhesive for application of functional articles to skin and comfortable removal of such articles Download PDF

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Publication number
CN1246066A
CN1246066A CN97181848A CN97181848A CN1246066A CN 1246066 A CN1246066 A CN 1246066A CN 97181848 A CN97181848 A CN 97181848A CN 97181848 A CN97181848 A CN 97181848A CN 1246066 A CN1246066 A CN 1246066A
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CN
China
Prior art keywords
articles
skin
adhesive
radian per
topical adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN97181848A
Other languages
Chinese (zh)
Inventor
彼得·科尔斯
费比奥·辛尼尔利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
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Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP96120738A external-priority patent/EP0850619A1/en
Priority claimed from EP97110730A external-priority patent/EP0853934A1/en
Priority claimed from EP97120337A external-priority patent/EP0850649A1/en
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CN1246066A publication Critical patent/CN1246066A/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/47—Sanitary towels, incontinence pads or napkins
    • A61F13/475—Sanitary towels, incontinence pads or napkins characterised by edge leakage prevention means
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/56—Supporting or fastening means
    • A61F13/66—Garments, holders or supports not integral with absorbent pads
    • A61F13/82—Garments, holders or supports not integral with absorbent pads with means for attaching to the body
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/58—Adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/58—Adhesives
    • A61L15/585—Mixtures of macromolecular compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L24/00—Surgical adhesives or cements; Adhesives for colostomy devices
    • A61L24/04—Surgical adhesives or cements; Adhesives for colostomy devices containing macromolecular materials
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/005—Modified block copolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

Abstract

The present invention relates to topical adhesives for attachment to the skin. In particular the present invention relates to such topical adhesives which can be employed for attachment to the skin of protective articles, clothing, prosthesis, heat wraps, pads, and/or packs, cold wraps, hearing aids, protective face masks, ornamental articles, or eye wear but excluding absorbent articles. The topical adhesive provides secure attachment and is pleasing to the skin upon application, yet causes no discomfort and a low level of adhesive residues on the skin upon removal. This is achieved by selecting the chemical composition and rheological characteristics of the topical adhesives, in particular with reference to the relationship between the elastic modulus G' and the viscous modulus G'' of the topical adhesive.

Description

Be fixed on the skin functional articles and the topical adhesive that can comfortablely remove these class articles for use
Invention field
The present invention relates to be used for fixing the topical adhesive (topical adhesives) on the skin.The present invention be more particularly directed to this class topical adhesive, they can be used for functional articles is applied to skin, in particular for the attachment function sex aids or improve the function of these class articles for use.Functional articles on this meaning is beauty treatment thing or the drug conveying articles for use that a kind of material is provided to skin, described material such as skin treating material, cream, skin lotion, hormone, vitamin, deodorizer or the medicine that provides to skin; Improve looks on the other hand thing or drug conveying articles for use also can provide a kind of material that distributes from skin, as insecticide, suck medicine or spice; And, binding agent of the present invention also can be used for not being fixed on the skin but as functions of components sex aids in the articles for use, and these articles for use need have the long time of staying such as ornamental cosmetics (lip pomade, eye shadow, stage foundation cream) or cleaning supplies (hand cleaner, facial film, be used in particular for the sanitary cleaning agent of pore) on skin.Topical adhesive provides safe and reliable fixing or increased the time of staying and made dermal sensation comfortable when using, and can not cause uncomfortable when removing articles for use.Realize these purposes by chemical composition and the rheologic behavio(u)r of selecting topical adhesive.
Background technology
The general prior art that is used for fixing the topical adhesive field on the skin in the absorbent item field such as Band-aid, plaster (plaster) and binder obtained special exploitation.But with in case of emergency, for example wound has appearred to these articles for use in wearer's skin usually, needs to absorb the body fluid that wound is discharged.In this sense, the performance parameter of absorbent item, as comfortable and use easily and use, painless removal, discreteness all occupy back burner, as aseptic, indexs such as the healing effect of wound and mechanical protection effect are then occupied main status.And the absorbent item great majority that this class covers wound are used for this class skin part, before using absorbent item, can remove the chaeta at these positions or not long chaeta or chaeta herein seldom.
The present invention relates to the useful especially topical adhesive of functional articles, beauty treatment thing or the drug conveying articles for use of these functional articles as a kind of material is provided to skin, described material such as skin treating material, cream, skin lotion, hormone, vitamin, deodorizer or the medicine that provides to skin; Improve looks on the other hand thing or drug conveying articles for use also can provide a kind of material that distributes from skin, as insecticide, suck medicine or spice; Binding agent of the present invention also can be used for not being fixed on the skin but as functions of components sex aids in the articles for use, and these articles for use need have the long time of staying such as ornamental cosmetics (lip pomade, eye shadow, stage foundation cream) or cleaning supplies (hand cleaner, facial film, be used in particular for the sanitary cleaning agent of pore) on skin.These class articles for use are not used for absorb body fluids.For example, binding agent of the present invention can be fixed to the vitamin plaster suitably and maybe will suck the drug release articles for use on the skin and be fixed on the breast suitably.Binding agent is added ornamental cosmetics can increase its anti-deciduous, can not cause the problem that is difficult to remove simultaneously.
The topical adhesive that is used for absorbent item such as sanitary towel and scanties lining has been done disclosure at United States statutory invention registration H1602 or WO 96/33683.The more details of this class binding agent has been done open in PCT application WO 95/16424.Disclosed in this document and had the hygienic article of using topical adhesive along the whole periphery on wearer's side of sanitary towel.The problem that this document exists mainly is how safety is fixed on the skin, mentions simultaneously and uses the back not making the wearer feel the problem of removing of these class articles for use under the undue pain.
The open part of WO 95/16424 comprises the rheology standard of labor topical adhesive.But this document does not almost relate to the painless removal problem of these class articles for use, because the rheology standard of describing comprises depilation (promptly removing hair) compositions, as the STREP MIELE (TM) that is sold by gondola Laboratori Vaj S.p.A.And this document has only been mentioned static rheological charactristics, but does not describe the dynamic rheology feature of topical adhesive.
WO 96/13238 discloses a kind of topical adhesive model that depends on frequency.But disclosed all measured values as on the 9th page, all are to record under-60 ℃～+ 120 ℃ temperature and under the actual frequency of 0.1～100 radian per second (rad/s).For the necessary data under the temperature that is applied (about 20 ℃, general bathroom, i.e. storage temperature), used Williams-Landel-Ferry (hereinafter claiming WLF) formula.
This WLF equation is an empirical formula, and only in specific scope effectively, can not be used to be extrapolated to temperature below the glass transition temperature that is lower than polymer adhesive as it, same WLF equation can not be used for based on the numerical value that obtains below the glass transition temperature.About the details of WLF equation and application thereof can find in following document: " Principles ofPolymer processing " (the Polymer Processing principle) of Z.Tadmor and C.G.Gogos, by John Wiley; " Viscoelastic Properties of Polymers " (viscoelastic properties of polymer) of Sons publication or J.D.Ferry is also by John Wiley﹠amp; Son publishes.Owing among the WO 96/13238 this is put down in writing, so can not assess the suitability of disclosed data.
Based on above-mentioned prior art, an object of the present invention is to provide and functional articles is fixed on the skin safely and reliably and can be from painless topical adhesive of removing on the skin.Another object of the present invention is to guarantee when removing, and does not have remaining binding agent to stay on wearer's the skin or hair.
To be the binding agent used of localized immobilization cause cold or other unacceptable temperature sense using Shi Buhui further object of the present invention, although binding agent and skin temperature have the temperature difference.
Except above-mentioned purpose of the present invention, wish that also topical adhesive provides additional benefit as the protection health.And the preferred topical adhesive that does not influence the natural skin situation is as reaching this purpose by ventilative or permeable steam.
Summary of the invention
The present invention is used for being fixed to functional articles on the skin or improves these class articles for use being worn to function on the skin.Functional articles is beauty treatment thing or the drug conveying articles for use that a kind of material is provided to skin, described material such as skin treating material, cream, skin lotion, hormone, vitamin, deodorizer or the medicine that provides to skin; Improve looks on the other hand thing or drug conveying articles for use also can provide a kind of material that distributes from skin, as insecticide, suck medicine or spice; In addition, binding agent of the present invention also can be used for not being fixed on the skin but as functions of components sex aids in the articles for use, and these articles for use need have the long time of staying such as ornamental cosmetics (lip pomade, eye shadow, stage foundation cream) or cleaning supplies (hand cleaner, facial film, be used in particular for the sanitary cleaning agent of pore) on skin.These class articles for use are absorb body fluids not.Articles for use have a surface and an outer surface towards the wearer usually.Topical adhesive makes these articles for use can be fixed on wearer's the skin safely and supports its function.Term in this sense " functional " refers to that articles for use are finished by topical adhesive of the present invention after being placed on the skin and is supported or improved additional function.
The labor of the precedence of the normal conditions that occur when being applied to of functional articles removed these class articles for use has shown that the characteristic that must satisfy concrete binding agent to realize required performance purpose, particularly supports the function of articles for use.The characteristic of having considered in this case be describe material elastic performance elastic modelling quantity and the viscous modulus of the adhering performance of adhesive material is described.
The adhering performance of binding agent can be interpreted as representing the rapidly fixing and agglutinating ability of safety of binding agent, promptly rapidly and skin in the visible superficial makings of the microscopically ability that matches.Elastic performance may be interpreted as an index of " hardness " performance of expression binding agent.Its value also is important to good initial fixation.The size of required power when the population effect that it is believed that them has determined to remove.The relation of elastic modelling quantity and viscous modulus is considered to represent that where partly removing energy will be dissipated in the binding agent, and which part is removed energy and be can be used for causing removing of reality.
In order to be provided for the topical adhesive of functional articles, the relation of elastic modelling quantity and viscous modulus with and kinetic property be particular importance.
Topical adhesive has elastic modelling quantity under the temperature of 37 ℃ (100), be abbreviated as G ' 37, under the temperature of 37 ℃ (100), have viscous modulus, be abbreviated as G " 37Binding agent also has dynamic elasticity character, is defined as △ G ' 37, it is the G ' under the frequency of 100 radian per seconds 37With the G ' under the frequency of 1 radian per second 37Difference, binding agent also has dynamic adhering performance △ G " 37, it is the G under the frequency of 100 radian per seconds " 37With the G under the frequency of 1 radian per second " 37Difference.
Topical adhesive of the present invention satisfies following conditions.
G ' 37(1 radian per second) in the scope of 1500-20000Pa, preferred 1500-15000Pa, most preferably 3000-10000Pa;
G " 37(1 radian per second) in the scope of 100-15000Pa, preferred 100-10000Pa, most preferably 300-5000Pa;
G ' 37(1 radian per second)/G " 37(1 radian per second) is in the scope of 3-30;
Ratio
Figure A9718184800071
Be not less than 0.5, preferably in the scope of 0.7-3, more preferably in the scope of 1-1.8;
Ratio △ G ' 37/ G ' 37(1 radian per second) is not more than 1.5, preferably is not more than 1, most preferably is not more than 0.8; Perhaps △ G ' 37Be not more than 10000Pa, preferably less than 5000Pa, most preferably less than 2000Pa; Perhaps the two all satisfies;
At least the G ' in the frequency range of 1～100 radian per second 37/ G " 37Ratio should be preferably 33 or bigger, more preferably 5 or bigger, most preferably 10 or bigger, the arbitrary place in this frequency range is no more than about 50, preferred 30 simultaneously;
Rheological property also can be relevant with the value of glass transition temperature Tg.For topical adhesive of the present invention, Tg should be more preferably less than-20 ℃, most preferably less than-25 ℃ preferably less than-15 ℃;
Also it is relevant with specific heat capacity for the rheological property of topical adhesive and acceptance.The specific heat capacity of preferred topical adhesive is more preferably less than 3J/g/K, most preferably less than 2J/g/K less than 4J/g/K;
The rheological property of topical adhesive is also relevant with the specific heat conductance of binding agent with acceptance.Preferred specific heat conductance should be low as far as possible, preferred 1-0.1W/m/K, most preferably 0.6-0.1W/m/K.
If satisfy above-mentioned rheology condition, binding agent also satisfies as enough caking property conditions such as (to prevent that adhesive residue is on skin), and enough caking property is important and is conspicuous for those of ordinary skills the commerce application of this class binding agent.The adhesive composition that satisfies above-mentioned standard can be used as topical adhesive that functional articles uses and the component in the functional articles preparation, and condition is that they also satisfy between the operating period and generally be used safely in common requirement on human or animal's skin after removing articles for use.
The comfort of sanitary appearance when contacting also is important usually, thus preferably clear or white and adhesive composition cold, discomfort when preventing to use.
Above-mentioned rheology standard and other consider that item can satisfy by following adhesive composition, and said composition comprises 45%, preferred 51%～99.5% be the plasticized compound or the compositions of liquid in the time of 20 ℃; 0.5～20%, preferred 5～15% the polymerizable compound or the compositions of solvable or swellable in plasticized compound or compositions; With a kind of tackifying resin, the amount ranges of this resin is 0～50% of a composition weight, preferably 0～600% of polymerizable compound weight.Plasticized compound or component are preferably selected from water, alcohol (preferably glycerine), glycol, Polyethylene Glycol, liquid polybutene, oil or its combination.Polymerizable compound or compositions are preferably selected from block-copolymer-thermoplastic elastomer (TPE), styrene-block-copolymer and hydrogenant styrene-block-copolymer, polyacrylic, polyvinyl alcohol, natural gum or gelatin, poly(ethylene oxide), polyvinylpyrrolidone (PVP), polyvinylether, cellulose derivative or its combination.
The binding agent that the detailed Description Of The Invention localized immobilization is used
Topical adhesive of the present invention is directly used on the skin.In specific application, binding agent can be used as function carrier (distribution chemical compound) and be used for fixing, and in other is used, needs to improve fixing and the anti-function of wiping.Topical adhesive of the present invention is used for functional articles, as beauty treatment thing or drug conveying articles for use such as skin treating material, cream, skin lotion, hormone, vitamin, deodorizer or the medicine that a kind of material is provided to skin; Improve looks on the other hand thing or drug conveying articles for use also can provide a kind of material that distributes from skin, as insecticide, suck medicine or spice; In addition, binding agent of the present invention also can be used for not being fixed to the functional articles on the skin, but as parts in the articles for use, these articles for use need have the long time of staying such as ornamental cosmetics (lip pomade, eye shadow, stage foundation cream) or cleaning supplies (hand cleaner, facial film, be used in particular for the sanitary cleaning agent of pore) on skin.The term that the present invention uses " skin " relates to human or animal's skin appearance face really.
For articles for use of the present invention are fixed on the skin, in some applications, also be necessary usually in the topical adhesive that on the specific region on the skin side, provides of articles for use, in other was used, local viscose binder was a kind of chemical compound of articles for use component.The physics of topical adhesive, rheology and adhesive property
Even resembling, topical adhesive is used on human or animal's the skin the contact adhesive, be understood that, have only according to the distinctive rheologic behavio(u)r of tool of differentiating the topical adhesive compositions, just may topical adhesive be regarded as typical contact adhesive (PSA hereinafter referred to as) very difficultly.
In fact, known to the those of ordinary skill of adhesive field, the feature that PSA is different from the tool characteristic of other material that can temporarily cling article (the water between two glass plates) is its rheological parameters, particularly elastic modulus G ' along with the frequency change of the stress that is applied is very big.More specifically, when the frequency of the stress that is applied from typical bonding frequency change when typically peeling off frequency, promptly during hereinafter described 1 radian per second to 100 radian per second, the size of the G ' of PSA can increase more than the several magnitude.
Therefore, can draw: by under given frequency values, provide rheological parameters particularly the value of the G ' material that will plan to use to be defined as " topical adhesive " be unallowed.This may make the people misread, because under the situation that lacks other characteristic, will comprise the material that does not have real value.Therefore, rheological properties must be basis with the dynamic conditions.
This be not only applicable to elastic modulus G ', and ", therefore also be applicable to tan (δ)=G "/G ' that is applicable to viscous modulus G.Well-knownly being that not only the variation of G ' is bigger for typical PSA under the frequency of being considered, and G, " variation bigger, G " may level off to G ', perhaps even bigger than G ', promptly tan (δ) approximately or even greater than 1, particularly typically peeling off under the frequency.
Be not bound by theory, this can be interpreted as meaning that energy expenditure that major part is used for peeling off is binding agent (therefore can not cause effectively and peel off), although should cause very big cohesive force record value on the fact macroscopic view.
As mentioned above, be under as the rheological properties major part that material had of topical adhesive of the present invention as 37 ℃ reference temperature of human body normal body temperature and the frequency of certain limit under measure.Have now found that, when on as vitamin cream class articles for use, using topical adhesive, under lower frequency, form the binding agent contact, and under the speed of removing articles for use, peel off.This speed represents with the frequency of 100 radian per seconds, and has now found that the low frequency that forms adhesives is on the order of magnitude of 1 radian per second.Therefore, the used frequency range of the present invention is 1～100 radian per second.
The bonding characteristic that it is believed that selection binding agent under body temperature is the most suitable.Because topical adhesive of the present invention directly is applied on the skin, those of ordinary skills have the little specific heat capacity adhesive composition of (as preferably less than 4J/g/K) with selecting, the actual temperature of topical adhesive will reach very soon 37 ℃ or even before using by wearer's preheating.
For good bonding condition is provided, promptly under the frequency of 1 radian per second, the absolute value of elastic modelling quantity should be too not high, otherwise binding agent is too hard and can not closely connect or can't will match on adherent surface with it." have lower absolute value so that it also is important having good caking property, when using the articles for use frequently remove and to adhere to once more or to change, material keeps soft and can mildly be bonded to bonding good on the skin valuable especially to G simultaneously.
" 37 (1 radian per seconds) are important to ratio G ' 37/G, and these two values are equilibrated when guaranteeing on being bonded to skin.Simultaneously, in the frequency range of being considered, need the absolute change of restriction G ' 37.Therefore, should keep △ G ' 37 (being G ' 37 (100 radian per second)-G ' 37 (1 radian per second)) less with the ratio of G ' 37 (1 radian per second), so that pass in time or removing/keep the safety of topical adhesive to fix when peeling off, and can not cause uncomfortable.This also can represent with absolute value by △ G ' 37 is remained on below the particular value.
Importantly, ratio Needing enough big promptly provides safety to bond and painless and remove easily so that the kinetic property of elasticity and viscous modulus guarantees a kind of like this relation.
At last, those of ordinary skills will appreciate that also glass transition temperature Tg, specific heat capacity and the specific heat conductance of adhesive composition are the useful parameters that is limited with the topical adhesive of usefulness more comprehensively.
Topical adhesive of the present invention preferably should satisfy following feature:
G ' 37(1 radian per second) in the scope of 1500-20000Pa, preferred 1500-15000Pa, most preferably 3000-10000Pa;
G " 37(1 radian per second) in the scope of 100-15000Pa, preferred 100-10000Pa, most preferably 300-5000Pa;
G ' 37(1 radian per second)/G " 37(1 radian per second) is in the scope of 3-30;
Ratio
Figure A9718184800102
Be not less than 0.5, preferably in the scope of 0.7-3, most preferably in the scope of 1-1.8;
Ratio △ G ' 37/ G ' 37(1 radian per second) is not more than 1.5, preferably is not more than 1, most preferably is not more than 0.8; Perhaps △ G ' 37Be not more than 10000Pa, preferably less than 5000Pa, most preferably less than 2000Pa; Perhaps above-mentioned both satisfies;
At least the G ' in the frequency range of 1～100 radian per second 37/ G " 37Ratio should be preferably 3.3 or bigger, more preferably 5 or bigger, most preferably 10 or bigger, the arbitrary place in frequency range is no more than about 50, preferred 30 simultaneously;
Rheological property also can be relevant with the value of glass transition temperature Tg.For topical adhesive of the present invention, Tg should be more preferably less than-20 ℃, most preferably less than-25 ℃ preferably less than-15 ℃;
The acceptance of rheological property and topical adhesive is also relevant with specific heat capacity.Preferably the specific heat capacity of topical adhesive is more preferably less than 3J/g/K less than 4J/g/K, most preferably less than 2J/g/K;
The acceptance of rheological property and topical adhesive is also relevant with the specific heat conductance of binding agent.Preferred specific heat conductance should be low as far as possible, is more preferably 1-0.1W/m/K, most preferably is 0.6-0.1W/m/K.The chemistry of topical adhesive and composition characteristic
For the topical adhesive compositions that satisfies above-mentioned rheology and physical characteristic needs is provided, can use following preparation standard in addition.It should be noted that the most compositions that is used as topical adhesive has gelatinous basically structure, preferably gel.This comes from the following fact:
-key component is the plasticizer that at room temperature is liquid.
-macromole or polymers compositions are compared with less amount with plasticizer and are existed.In preferred embodiments, it forms the three-dimensional network that is formed by intermolecular physics or chemical bond.Useful especially secondary or physical bond is to contain those keys that exist in the system of inlay section thermal plastic elastic body.
More specifically, compositions contains usually:
-0.5～20%, the solubilized of preferred 5-15% weight or swell in macromolecular polymer in the plasticizer cited below or the mixture of this class material.As non-limiting instance, the macromolecular or polymer material of this class is natural and/or synthetic, as natural gum or derivant such as natural gum and gelatin, its derivant and alginate; Polyacrylic (polyacrilics); Polyvinyl alcohol; Poly(ethylene oxide); Polyvinylpyrrolidone (PVP) or polyvinylether, its copolymer and derivant; Cellulose derivative; The block copolymer thermoplastic elastomer, preferably cinnamic block copolymer is more preferably styrene/ethylene-butylene/styrene (SEBS), styrene/isoprene/styrene (SIS) and the styrene/ethylene-propylene/styrene (SEPS) of hydrogenation level.
-45～99.5% weight, the plasticised mass of preferred 51～99.5% weight or the mixture of plasticised mass, it at room temperature is a liquid.As non-limiting instance, plasticizer can be water, various alcohol (as glycerol particularly), glycol and its ether, Polyethylene Glycol, liquid polybutene, ester such as phthalic acid ester, adipate ester, stearate, cetylate, sebacate or myristinate, natural or artificial oil such as vegetable oil, mineral oil or its combination.
-0～50% (based on the weight of compositions), the tackifying resin of preferred 0～600% macromolecule polyalcohol weight, it mainly is to adjust Tg, particularly based on the Tg of the system of synthetic polymer.
-0～10%, more preferably 0～5% weight is used to promote material with stable hydrophilic or hydrophobic liquid plasticizer gel or gel formation process.These materials can be used for the oily system, as C 8～C 22Fatty acid, its slaine and its polyoxy for derivant; Lanolin derivative; Silicon dioxide; Bentonite, montorillonite clay and derivant thereof; Polyamide, wax or its mixture.
Also can contain the highest consumption and reach 10% the conventional additives for antiseptic, antioxidant, ultraviolet (UV) resistant agent, pigment, mineral filler, rheology change agent etc. known in the art.
When forming chemical crosslinking in the system, cross-linking agent can preferably exist with the amount up to 5% weight.Chemical crosslinking also can be by having different functional groups the mutual neutralization of polymer form, as the reaction between acid polyacrylic and the poly-polysaccharide.
The compositions of the topical adhesive of gained can be divided into three races according to the character of key component (promptly normally liquid plasticizer):
1) hydrophobic composition, the blend of the oil of normally a kind of oil of plasticizer or plant or mineral sources wherein, polymer normally dissolves in or swells in the synthetic polymer in the oil, preferably elastomer.
2) mixed phase compositions, wherein hydrophobicity and hydrophilic component (may in plasticizer and polymer) form two or more separating mutually.In this case, emulsifier/surfactant preferably exists to form inconsistent alternate stable emulsion with suitable content.For topical adhesive of the present invention, preferably the content of hydrophilic component is 30-70% weight, and the content of hydrophobic components is 70-30% weight.
3) hydrophilic composition, normally water/glycerol/glycol etc. and/or its mixture of plasticizer wherein, and polymer phase be synthetic (as polyacrylic) or natural (as natural gum) source or its mixture.
What should emphasize is according to the character of functional articles, must select from above-mentioned each family's compositions.For most of functional articles, the mixed phase compositions is preferred, and in an application of the invention, hydrophilic and hydrophobic adhesive are not too preferred.For functional articles with conveying function, the chemical compound that will carry need come out from the topical adhesive compositions with different speed, can have from height to delivery profile as spice, and medicine is preferably carried excessive to prevent dosage with constant speed than low-value variation.Cosmetics are normally lipophilic and moist, thereby most preferably are watery and combination oily component.
Using of topical adhesive
Can prepare functional articles with this area any method commonly used, contain topical adhesive of the present invention in the described articles for use.Functional articles on this meaning also limits with binding agent substrate to be remained on the skin or with the binding agent as a compositions part and directly is set on the skin.
Topical adhesive is preferably protected before use.This protection can be provided as the paper of handling by release liner, and condition is that this paper is peeled off from selected topical adhesive easily; Or provide by the closed container that stores functional articles, store functional articles in this container.
If possible, functional articles also by be at least permeable steam, preferably air permeable provides breathability airtight to prevent.If can't help topical adhesive itself provides, then breathability can be limited to the zone of articles for use uncoated binding agent.
Embodiment 1
Use the Kraton G-1651 of 9.9% weight, it is a kind of cinnamic styrene/ethylene-butylene/styrene block copolymer that contains 33% weight available from Shell Co., with the Kaydol of 59.3% weight, it is that a kind of paraffin mineral oil available from Witco Co. is prepared oil-based composition of the present invention.
And compositions contains 301 parts of tackifying resin/100 part Kraton polymer.Tackifying resin is Escorez 5300, is a kind of hydrogenant resin available from Exxon Co..
Use is available from the magnesium stearate of the Carlo Erba S.p.A gellant that helps as oil usefulness, and its consumption is 0.7% weight.
Add Irganox 1010, it is a kind of antioxidant available from Ciba-Geigy, and its consumption is 0.3% weight.
Therefore, compositions finally has following percentage composition:
Kraton G-1651 9.9% weight
Kaydol 59.3% weight
Escorez 5,300 29.8% weight
Magnesium stearate 0.7% weight
Irganox 1,010 0.3% weight
In the time of 37 ℃, compositions table reveals following rheological properties:
A) elastic modelling quantity when 1 radian per second, G ' 37=6876Pa;
B) viscous modulus when 1 radian per second, G " 37=550.5Pa;
C) the ratio G ' 37/G " 37=12.49 of elastic modelling quantity and viscous modulus when 1 radian per second;
D) ratio
＝1.22；
E) ratio △ G ' 37/G ' 37 (1 radian per second) is 0.308, △ G ' 37=2124Pa.
The test above-mentioned composition is when it begins to be coated on the skin responsive, hirsutism and when described skin was removed, above-mentioned composition was judged as comfortable.Said composition can be sneaked in the hydrophobic face-care product, and improves its anti-ability of wiping.Said composition is also shown obvious effects as hand cleaner.Comparative Examples
Use the Kraton G-1651 of 7.1% weight, it is a kind of styrene/ethylene-butylene/styrene block copolymer of purchasing in Shell Co. that contains 33% weight styrene, with the Kaydol of 41.9% weight, it is that a kind of paraffin mineral oil available from Witco Co. is prepared the oil base Comparative composition.
And compositions contains 704 parts of tackifying resin/100 part Kraton polymer.Tackifying resin is Regalrez 3102, and it is a kind of hydrocarbon resin available from Hercules Co..
Use is available from the magnesium stearate of the Carlo Erba S.p.A gellant that helps as oil usefulness, and its consumption is 0.7% weight.
Add Irganox 1010, it is a kind of antioxidant available from Ciba-Geigy, and its consumption is 0.3% weight.
So compositions finally has following percentage composition:
Kraton G-1651 7.1% weight
Kaydol 41.9% weight
Regalrez 3,102 50.0% weight
Magnesium stearate 0.7% weight
Irganox 1,010 0.3% weight
In the time of 37 ℃, compositions table reveals following rheological property:
A) elastic modelling quantity when 1 radian per second, G ' 37=3059Pa;
B) viscous modulus when 1 radian per second, G " 37=1208Pa;
C) the ratio G ' 37/G " 37=2.53 of elastic modelling quantity and viscous modulus when 1 radian per second;
D) ratio
Figure A9718184800141
＝-2.87；
E) ratio △ G ' 37/G ' 37 (1 radian per second) is 3.944, △ G ' 37=12064.7Pa.
Above-mentioned composition is judged as very uncomfortable when the skin of forearm is peeled off.It is unacceptable being administered on the skin of responsive hirsutism.The amount of the residue that exists on the forearm when being used for functional articles is judged as not attractive.

Claims (9)

1. one kind is fixed to topical adhesive on the skin with functional articles, and described functional articles is beauty treatment thing or drug conveying articles for use, ornamental cosmetics or cleaning supplies,
Described binding agent under the temperature of 37 ℃ (100), have an elastic modulus G ' 37With a viscous modulus G " 37,
Select described binding agent to have following character:
G ' 37 (1 radian per second) in the scope of 1500-20000Pa, preferred 1500-15000Pa, most preferably 3000-10000Pa;
G " 37 (1 radian per seconds) in the scope of 100-15000Pa, preferred 100-10000Pa, most preferably 300-5000Pa;
" 37 (1 radian per seconds) are in the scope of 3-30 for G ' 37 (1 radian per second)/G;
Ratio
Be not less than 0.5, preferably in the scope of 0.7-3, more preferably in the scope of 1-1.8;
Perhaps G ' 37 (100 radian per second)-G ' 37 (1 radian per second) is not more than 10000Pa, preferably less than 5000Pa, is more preferably less than 2000Pa; Perhaps ratio (G ' 37 (100 radian per second)-G ' 37 (1 radian per second))/G ' 37 (1 radian per second) is not more than 1.5, preferably is not more than 1, most preferably is not more than 0.8; Perhaps the two combination.
2. according to the topical adhesive of claim 1, it is ratio G ' 37/G in the scope of 1-1001 radian per second, and " 37 in the scope of 2-50, preferably 3.3-30.
3. according to the topical adhesive of claim 1 or 2, contain:
45～99.5%, preferred 51～99.5% weight in 20 ℃ of plasticized compounds that are in a liquid state or compositions;
0.5 the solubilized of～20% weight or swellable are in the polymerizable compound or the compositions of described plasticized compound or component;
Tackifying resin, its consumption is 0～50% weight, is preferably 0～600% of described polymerizable compound or composition weight.
4. according to the topical adhesive of claim 3, wherein:
Described plasticized compound or compositions are selected from water, alcohol, glycol, oil or its combination; And
Described polymerizable compound or compositions are selected from block-copolymer-thermoplastic elastomer (TPE), styrene-block-copolymer and hydrogenant styrene-block-copolymer, polyacrylic, polyvinyl alcohol, natural gum or gelatin, poly(ethylene oxide), polyvinylpyrrolidone, polyvinylether, cellulose derivative or its combination.
5. according to each topical adhesive among the claim 1-4, wherein the described binding agent of 30-70% weight is made of hydrophilic component, and the described binding agent of 30-70% weight is made of hydrophobic components.
6. each part sticks with glue agent among the claim 1-5, and the glass transition temperature of wherein said adhesive is more preferably less than-20 ℃, most preferably less than-25 ℃ less than-15 ℃.
7. each part sticks with glue agent among the claim 1-6, and the specific heat capacity of wherein said adhesive is more preferably less than 3J/g/K less than 4J/g/K, most preferably less than 2J/g/K.
8. each part sticks with glue agent among the claim 1-7, and the specific heat conductance of wherein said adhesive in the scope of 0.1-1W/m/K, most preferably is 0.1-0.6W/m/K preferably less than 1W/m/K.
9. according to each topical adhesive among the claim 1-8 functional articles is fixed to application on the skin, described functional articles is beauty treatment thing or drug conveying articles for use, ornamental cosmetics or cleaning supplies.
CN97181848A 1996-12-23 1997-12-22 Adhesive for application of functional articles to skin and comfortable removal of such articles Pending CN1246066A (en)

Applications Claiming Priority (6)

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EP96120738A EP0850619A1 (en) 1996-12-23 1996-12-23 Disposable absorbent article for topical adhesive attachment to the skin of a wearer
EP96120738.8 1996-12-23
EP97110730.5 1997-07-01
EP97110730A EP0853934A1 (en) 1996-12-23 1997-07-01 Disposable absorbent article for secure topical adhesive attachment to the skin of a wearer and comfortable removal
EP97120337.7 1997-11-20
EP97120337A EP0850649A1 (en) 1996-12-23 1997-11-20 Adhesive for application of functional articles to the skin and comfortable removal of such articles

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