CN1308520C - 具有高湿/干抗张强度比的无纺布粘合剂 - Google Patents
具有高湿/干抗张强度比的无纺布粘合剂 Download PDFInfo
- Publication number
- CN1308520C CN1308520C CNB2004100457738A CN200410045773A CN1308520C CN 1308520 C CN1308520 C CN 1308520C CN B2004100457738 A CNB2004100457738 A CN B2004100457738A CN 200410045773 A CN200410045773 A CN 200410045773A CN 1308520 C CN1308520 C CN 1308520C
- Authority
- CN
- China
- Prior art keywords
- nonwoven fabric
- polymer
- fabric product
- vinylacetate
- ethene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011230 binding agent Substances 0.000 title abstract description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 100
- 229920000642 polymer Polymers 0.000 claims abstract description 100
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000000835 fiber Substances 0.000 claims abstract description 47
- 239000005977 Ethylene Substances 0.000 claims abstract description 35
- 239000000178 monomer Substances 0.000 claims abstract description 32
- 230000004927 fusion Effects 0.000 claims abstract description 28
- 238000004132 cross linking Methods 0.000 claims abstract description 22
- 239000004745 nonwoven fabric Substances 0.000 claims description 77
- 229940117958 vinyl acetate Drugs 0.000 claims description 73
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical group OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 37
- 238000006116 polymerization reaction Methods 0.000 claims description 32
- 239000000853 adhesive Substances 0.000 claims description 31
- 230000001070 adhesive effect Effects 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 18
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical group [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims description 12
- 238000010304 firing Methods 0.000 claims description 10
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 230000006641 stabilisation Effects 0.000 claims description 7
- 238000011105 stabilization Methods 0.000 claims description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 6
- 229920003043 Cellulose fiber Polymers 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 3
- 229960005070 ascorbic acid Drugs 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 150000001451 organic peroxides Chemical class 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims 3
- 239000003638 chemical reducing agent Substances 0.000 claims 2
- 230000009477 glass transition Effects 0.000 abstract description 5
- 238000002844 melting Methods 0.000 abstract description 4
- 230000008018 melting Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 37
- 239000007864 aqueous solution Substances 0.000 description 29
- 239000007787 solid Substances 0.000 description 24
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 22
- 239000002994 raw material Substances 0.000 description 21
- 230000001934 delay Effects 0.000 description 19
- 239000004094 surface-active agent Substances 0.000 description 18
- -1 carboxylic acid acid amides Chemical class 0.000 description 17
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 14
- 239000004908 Emulsion polymer Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 239000000443 aerosol Substances 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 239000000376 reactant Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
- 239000003431 cross linking reagent Substances 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000012966 redox initiator Substances 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical compound [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 238000010926 purge Methods 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000001595 flow curve Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 235000010352 sodium erythorbate Nutrition 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920006037 cross link polymer Polymers 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000011218 segmentation Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- RQAVKYPVSDCFJQ-UHFFFAOYSA-N 2-methyl-n-(2-methylpropoxy)prop-2-enamide Chemical compound CC(C)CONC(=O)C(C)=C RQAVKYPVSDCFJQ-UHFFFAOYSA-N 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 239000001836 Dioctyl sodium sulphosuccinate Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- RQKOWUOIMOFPJX-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCC(C)C)[Na] Chemical compound S(=O)(=O)(O)O.C(CCCCCCC(C)C)[Na] RQKOWUOIMOFPJX-UHFFFAOYSA-N 0.000 description 1
- SKKZPQRBPINTHS-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCCC)[Na] Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCCC)[Na] SKKZPQRBPINTHS-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- YMSVHTCHCGGFRV-UHFFFAOYSA-N azanium;3-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [NH4+].[O-]S(=O)(=O)CCCNC(=O)C=C YMSVHTCHCGGFRV-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-L dioxidosulfate(2-) Chemical compound [O-]S[O-] HRKQOINLCJTGBK-UHFFFAOYSA-L 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000004835 fabric adhesive Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 229960002163 hydrogen peroxide Drugs 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- JMSTYCQEPRPFBF-UHFFFAOYSA-N methyl 2-methoxy-2-(prop-2-enoylamino)acetate Chemical compound COC(=O)C(OC)NC(=O)C=C JMSTYCQEPRPFBF-UHFFFAOYSA-N 0.000 description 1
- IJXACZWYAHYTJN-UHFFFAOYSA-N n-(1-oxobutan-2-yl)prop-2-enamide Chemical compound CCC(C=O)NC(=O)C=C IJXACZWYAHYTJN-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium erythorbate Chemical compound [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 229940067741 sodium octyl sulfate Drugs 0.000 description 1
- WFRKJMRGXGWHBM-UHFFFAOYSA-M sodium;octyl sulfate Chemical compound [Na+].CCCCCCCCOS([O-])(=O)=O WFRKJMRGXGWHBM-UHFFFAOYSA-M 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D44/00—Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
- A45D44/02—Furniture or other equipment specially adapted for hairdressers' rooms and not covered elsewhere
- A45D44/04—Special adaptations of portable frames or racks
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B19/00—Slide fasteners
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45C—PURSES; LUGGAGE; HAND CARRIED BAGS
- A45C15/00—Purses, bags, luggage or other receptacles covered by groups A45C1/00 - A45C11/00, combined with other objects or articles
- A45C15/04—Purses, bags, luggage or other receptacles covered by groups A45C1/00 - A45C11/00, combined with other objects or articles with mirrors
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D42/00—Hand, pocket, or shaving mirrors
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D29/00—Manicuring or pedicuring implements
- A45D29/18—Manicure or pedicure sets, e.g. combinations without case, etui, or the like
- A45D29/20—Boxes, cases, etuis or the like specially adapted therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
- Y10T442/277—Coated or impregnated cellulosic fiber fabric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/603—Including strand or fiber material precoated with other than free metal or alloy
- Y10T442/607—Strand or fiber material is synthetic polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/647—Including a foamed layer or component
- Y10T442/652—Nonwoven fabric is coated, impregnated, or autogenously bonded
Abstract
Description
原料 | 装料量,g |
去离子水 | 1100 |
Aerosol MA-801 | 10 |
醋酸乙烯酯 | 120 |
原料 | 装料量,g |
含有4.0%碳酸氢钠的10.0%的过硫酸4铵水溶液 | 127 |
15.0%Rhodacal DS-10的稀释水溶液 | 260 |
醋酸乙烯酯 | 540 |
NMA(48%) | 140 |
乙烯 | 在1400psig(9754kPa)下保持5.5小时 |
聚合物组合物(以固体计算) | 45%乙烯50%醋酸乙烯酯5%NMA |
Tg起点(℃) | -31 |
粘度(60/12rpm)(cps) | 27/29 |
100/325目凝固物(ppm) | 66/51 |
%固体 | 47.5 |
pH | 5.1 |
Tm(℃)/熔解热(J/g) | 74.6/23.4 |
原料 | 装料量,g |
去离子水 | 900 |
Aerosol MA801硫酸亚铁铵(2%水溶液) | 106 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 120 |
原料 | 装料量,g |
4.0%的t-BHP水溶液 | 123 |
8%的甲醛合次硫酸钠水溶液 | 135 |
含有10wt%Rhodacal DS-10和17.7wt%NMA的水溶液 | 380 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 540 |
乙烯 | 在1400psig(9754kPa)下保持5.5小时 |
聚合物组合物(以固体计算) | 31.5%乙烯62%醋酸乙烯酯6.5%NMA |
Tg起点(℃) | -28.61 |
粘度(60/12rpm)(cps) | 57/78 |
100/325目凝固物(ppm) | 83/170 |
%固体 | 44.0 |
pH | 4.8 |
Tm(℃)/熔解热(J/g) | 71.8/8.2 |
原料 | 装料量,g |
去离子水 | 1000 |
Aerosol MA801柠檬酸钠 | 151 |
含有0.89%十二烷基硫醇的醋酸乙烯酯 | 200 |
原料 | 装料量,g |
10.0%的过硫酸铵水溶液,其中合有3.5%碳酸氢钠 | 128 |
30%的MAMD特制品水溶液 | 180 |
含有10wt%Rhodacal DS-10的水溶液 | 144 |
含有0.89%十二烷基硫醇的醋酸乙烯酯 | 180 |
乙烯 | 在1500psig(10,444kPa)下保持5.5小时 |
聚合物组合物(以固体计算) | 55%乙烯39%醋酸乙烯酯6%MAMD |
Tg起点(℃) | -33.9 |
粘度(60/12rpm)(cps) | 25/25 |
100/325目凝固物(ppm) | 100/33 |
%固体 | 42 |
pH | 5.4 |
Tm(℃)/熔解热(J/g) | 68.9/35.9 |
原料 | 装料量,g |
去离子水 | 900 |
Aerosol MA801柠檬酸钠硫酸亚铁铵(2%水溶液) | 1516 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 250 |
原料 | 装料量,g |
4.0%的t-BHP水溶液 | 141 |
8%的甲醛合次硫酸钠水溶液 | 152 |
含有8.89wt%Rhodacal DS-10和33.3wt%MAMD特制品的水溶液 | 360 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 405 |
乙烯 | 在1500psig(10,444kPa)下保持5.5小时 |
聚合物组合物(以固体计算) | 29%乙烯65%醋酸乙烯酯6%MAMD |
Tg起点(℃) | -33.0 |
粘度(60/12rpm)(cps) | 34/38 |
100/325目凝固物(ppm) | 81/107 |
%固体 | 42.4 |
pH | 5.15 |
Tm(℃)/熔解热(J/g) | 68.7/5.6 |
原料 | 装料量,g |
去离子水 | 700 |
Aerosol MA801柠檬酸钠硫酸亚铁铵(2%水溶液) | 11.916 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 150 |
原料 | 装料量,g |
4.0%的t-BHP水溶液 | 209 |
10%的异抗坏血酸钠水溶液 | 221 |
含有8.89wt%Rhodacal DS-10和17.1wt%NMA的水溶液 | 429 |
含有0.56%十二烷基硫醇的醋酸乙烯酯 | 648 |
乙烯 | 在1400psig(9574kPa)下保持5.5小时 |
聚合物组合物(以固体计算) | 22%乙烯71.5%醋酸乙烯酯6.5%NMA |
Tg起点(℃) | -26.6 |
粘度(60/12rpm)(cps) | 1465/3000 |
100/325目凝固物(ppm) | 231/13 |
%固体 | 47.0 |
pH | 4.72 |
Tm(℃)/熔解热(J/g) | 40/2.3 |
原料 | 装料量,g |
DI水 | 900 |
Aerosol MA801硫酸亚铁铵(2%水溶液) | 116 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 150 |
原料 | 装料量,g |
4.0%的t-BHP水溶液 | 130 |
8%的甲醛合次硫酸钠水溶液 | 140 |
含有7.78wt%Rhodacal DS-10和16wt%NMA的水溶液 | 380 |
含有0.6%十二烷基硫醇的醋酸乙烯酯 | 540 |
乙烯 | 在1500psig(10,444kPa)下保持5.5小时 |
聚合物组合物(以固体计算) | 38%乙烯57%醋酸乙烯酯5%NMA |
Tg起点(℃) | -30.3 |
粘度(60/12rpm)(cps) | 140/308 |
100/325目凝固物(ppm) | 180/120 |
%固体 | 46.4 |
pH | 5.1 |
Tm(℃)/熔解热(J/g) | 76.9/15.9 |
原料 | 装料量,g |
去离子水 | 900 |
Aerosol MA801柠檬酸钠硫酸亚铁铵(2%水溶液) | 1016 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 120 |
原料 | 装料量,g |
4.0%的t-BHP水溶液 | 181 |
10%的甲醛合次硫酸钠水溶液 | 191 |
含有10wt%Rhodacal DS-10和36.9wt%MAMD特制品的水溶液 | 380 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 540 |
乙烯 | 在1400psig下保持5.5小时 |
聚合物组合物(以固体计算) | 29%乙烯64.2%醋酸乙烯酯6.8%MAMD |
Tg起点(℃) | -31.5 |
粘度(60/12rpm)(cps) | 20/20 |
100/325目凝固物(ppm) | 401/700 |
%固体 | 41.6 |
pH | 5.25 |
Tm(℃)/熔解热(J/g) | 61.4/4.7 |
原料 | 装料量,g |
去离子水 | 1000 |
Aerosol MA-801柠檬酸钠 | 101 |
醋酸乙烯酯 | 120 |
原料 | 装料量,g |
含有3.5%碳酸氢钠的10.0%过硫酸铵的水溶液 | 138 |
15.0%Rhodacal DS-10的稀释水溶液 | 295 |
醋酸乙烯酯 | 600 |
NMA(48%) | 186 |
乙烯 | 在1400psig(9754kPa)下保持6.5小时 |
聚合物组合物(以固体计算) | 29%乙烯64.2%醋酸乙烯酯6.8%MAMD |
Tg起点(℃) | -27 |
粘度(60/12rpm)(cps) | 1150/2300 |
100/325目凝固物(ppm) | 289/126 |
%固体 | 49.9 |
pH | 4.54 |
Tm(℃)/熔解热(J/g) | 85.3/18.2 |
原料 | 装料量,g |
去离子水 | 900 |
Aerosol MA801硫酸亚铁铵(2%水溶液) | 106 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 150 |
原料 | 装料量,g |
4.0%的t-BHP水溶液 | 178 |
10%的异抗坏血酸钠水溶液 | 187 |
含有7.5wt%Rhodacal DS-10和13.5wt%NMA的水溶液 | 380 |
含有0.57%十二烷基硫醇的醋酸乙烯酯 | 540 |
乙烯 | 在700psig(4928kPa)下保持3小时和在1400psig(9754kPa)下保持2.5小时 |
聚合物组合物(以固体计算) | 26%乙烯69%醋酸乙烯酯5%NMA |
Tg起点(℃) | -15.7 |
粘度(60/12rpm)(cps) | 27/28 |
100/325目凝固物(ppm) | 251/86 |
%固体 | 40.3 |
pH | 5.59 |
Tm(℃)/熔解热(J/g) | 85.9/10.4 |
实施例 | %乙烯 | %NMA | %MAMD | 引发 | 压力psig(kPa) | 加料 | Tg | Tm | Hf | 湿抗张强度 | 湿/干抗张强度比 | 吸收速度(g/g/s) | 无纺布手感 |
1 | 45 | 5 | 0 | T | 1400(9754) | S | -31 | 75 | 23 | 1530 | 0.97 | 0.71 | 柔滑,柔软 |
2 | 31.5 | 6.5 | 0 | R | 1400(9754) | S | -28.6 | 72 | 8 | 2395 | 0.87 | 0.62 | 柔滑,柔软 |
3 | 55 | 0 | 6 | T | 1500(10,444) | U | -33.9 | 69 | 36 | 1410 | 0.99 | 0.57 | 柔滑,柔软 |
4 | 29 | 0 | 6 | R | 1500(10,444) | S | -33 | 69 | 6 | 1933 | 0.81 | 0361 | 柔滑,柔软 |
5 | 22 | 6.5 | 0 | R | 1400(9754) | S | -26.6 | 40 | 2 | 2002 | 0.75 | 0.66 | 柔滑,柔软 |
6 | 38 | 5 | 0 | R | 1500(10,444) | S | -30.3 | 77 | 16 | 2064 | 0.72 | 0.69 | 柔滑,柔软 |
7 | 29 | 0 | 6.8 | R | 1400(9754) | S | -31.5 | 61 | 5 | 1919 | 0.91 | 0.67 | 柔滑,柔软 |
8 | 43 | 6.4 | 0 | T | 1400(9754) | S | -27 | 85 | 18.2 | 1713 | 0.86 | 0.67 | 柔滑,柔软 |
9 | 26 | 5 | 0 | R | 700/1400(4928/9754) | S | -15.7 | 86 | 10 | 1707 | 0.74 | 0.61 | 柔滑,柔软 |
比较实施例10 | 30 | 0 | 4.8 | R | <650(4583) | U | -15 | 无 | 0 | 1447 | 0.65 | 0.67 | 柔软 |
比较实施例11 | 12 | 0 | 5 | R | <450(3204) | U | 10 | 无 | 0 | 1702 | 0.58 | 0.68 | 坚硬 |
比较实施例12 | 20 | 5 | 0 | R | <700(4928) | U | 0 | 无 | 0 | 1840 | 0.65 | 0.69 | 介于中间 |
比较实施例13 | 60 | 4 | 0 | R | 1100(7686) | U | ND | ND | ND | ND | 0.67计算值(calc) | ND | ND |
Claims (20)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US10/447,009 US7297644B2 (en) | 2003-05-28 | 2003-05-28 | Nonwoven binders with high wet/dry tensile strength ratio |
US10/447009 | 2003-05-28 |
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CN1572853A CN1572853A (zh) | 2005-02-02 |
CN1308520C true CN1308520C (zh) | 2007-04-04 |
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US (1) | US7297644B2 (zh) |
EP (1) | EP1482081B1 (zh) |
KR (1) | KR100634181B1 (zh) |
CN (1) | CN1308520C (zh) |
AT (1) | ATE361387T1 (zh) |
DE (1) | DE602004006191T2 (zh) |
ES (1) | ES2281708T3 (zh) |
MY (1) | MY137786A (zh) |
SI (1) | SI1482081T1 (zh) |
TW (1) | TWI283273B (zh) |
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- 2004-05-24 ES ES04012266T patent/ES2281708T3/es active Active
- 2004-05-24 EP EP20040012266 patent/EP1482081B1/en not_active Not-in-force
- 2004-05-24 MY MYPI20041983A patent/MY137786A/en unknown
- 2004-05-24 TW TW93114642A patent/TWI283273B/zh not_active IP Right Cessation
- 2004-05-24 AT AT04012266T patent/ATE361387T1/de not_active IP Right Cessation
- 2004-05-24 SI SI200430385T patent/SI1482081T1/sl unknown
- 2004-05-24 DE DE200460006191 patent/DE602004006191T2/de active Active
- 2004-05-27 KR KR1020040037684A patent/KR100634181B1/ko not_active IP Right Cessation
- 2004-05-28 CN CNB2004100457738A patent/CN1308520C/zh not_active Expired - Fee Related
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KR100634181B1 (ko) | 2006-10-16 |
MY137786A (en) | 2009-03-31 |
US7297644B2 (en) | 2007-11-20 |
ES2281708T3 (es) | 2007-10-01 |
EP1482081B1 (en) | 2007-05-02 |
US20040242106A1 (en) | 2004-12-02 |
TW200426267A (en) | 2004-12-01 |
SI1482081T1 (sl) | 2007-10-31 |
TWI283273B (en) | 2007-07-01 |
DE602004006191T2 (de) | 2008-01-10 |
CN1572853A (zh) | 2005-02-02 |
DE602004006191D1 (de) | 2007-06-14 |
EP1482081A1 (en) | 2004-12-01 |
ATE361387T1 (de) | 2007-05-15 |
KR20040103330A (ko) | 2004-12-08 |
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