CN1358710A - 支链表面活性剂的制备 - Google Patents
支链表面活性剂的制备 Download PDFInfo
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- CN1358710A CN1358710A CN01124413A CN01124413A CN1358710A CN 1358710 A CN1358710 A CN 1358710A CN 01124413 A CN01124413 A CN 01124413A CN 01124413 A CN01124413 A CN 01124413A CN 1358710 A CN1358710 A CN 1358710A
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Abstract
使α-烯烃二聚形成亚乙烯基烯烃,然后将其异构化,并在羰基合成条件下将其与CO/H2反应或直接在羰基合成条件下与CO/H2反应,得到中链或接近中链支化的醇。这些支链醇是制备烷基硫酸盐、烷基乙氧基硫酸盐和烷基羧酸盐表面活性剂和其它表面活性剂的原料。
Description
本申请是申请号为97195560.3、申请日为1997年4月16日、发明名称为“支链表面活性剂的制备”的发明专利申请的分案申请。
发明领域
本发明涉及制备洗涤表面活性剂,特别是那些含有支链疏水单元的洗涤表面活性剂的方法。
发明背景
常规洗涤表面活性剂含有水增溶取代基(亲水基)和亲油取代基(疏水基)的分子。这类表面活性剂一般含有如羧酸盐、硫酸盐、磺酸盐、氧化胺、聚氧乙烯等亲水基,其连接在通常含有约10~约20个碳原子的烷基、烯烃基或烷芳基疏水物上。因此,这类表面活性剂的制造商必须能获得疏水基源,通过化学方法,可将所期望的亲水物连接到其上。最早的疏水基源包括天然脂肪和油,其可通过用碱皂化转化为皂(即羧酸盐亲水物)。椰子油、棕榈油仍可用来制备皂和制备烷基硫酸盐(“AS”)类的表面活性剂。其它疏水物可从石油化学品得到,其包括用来制备烷基苯磺酸盐表面活性剂(“LAS”)的烷基化苯。
文献称某些支链疏水物可被有利地用于制备烷基硫酸盐洗涤表面活性剂;例如,参考1969年11月25日授权给deWitt等人的美国专利3,480,556。但已确定,描述于‘556专利中的β支链表面活性剂在某种溶度参数方面是差的,如其克拉夫特(Krafft)温度所证实的那样。还进一步确定,支链朝向疏水物碳链中心的表面活性剂有很低的克拉夫特温度。参考:R.G.Laughlin的“表面活性剂的水相性质”,学术出版社(“The Aqueous Phasa Behavior of Surfactants”,AcademicPress),纽约,1994年,第347页。因此,现已确定,这类表面活性剂特别优选用于冷水或低温水的洗涤条件(如20℃~5℃)。
制备具有中链或接近中链支化的疏水基的洗涤表面活性剂的一个相关问题是缺少这类疏水物的备用源。依据本发明,描述了一种制备这类支链疏水物和将其转化为中链或接近中链支化的表面活性剂的方法。
发明概述
本发明包括一种制备中链或接近中链支化的烯烃(主要是,在中链或接近中链区支化的甲基)的方法。然后将这类物质用作提供支链洗涤表面活性剂疏水部分的基本原料。
通过以下述反应序列说明本发明的方法。
1)α-烯烃的二聚和其中,R和R’可为相同或不同的直链烷基,和其中R为C3~C7,优选为C5~C7的直链烷基,R’为C3~C7,优选为C5~C7的直链烷基。为了用于制备用于洗涤产品如洗衣用洗涤剂、洗餐具液体等的表面活性剂,R和R1优选相同或链长彼此在一或两个碳原子之内。有些直链烯烃还可由二聚作用制得,并可任选地被用分子筛除去。设计本发明方法的步骤1,以提供优选总计包含约12~约18(平均)个碳原子的支烯烃。2)醇的制备
在步骤2(路线A)中,可将步骤1的烯烃混合物预先无规则化,以促进随后步骤3中醇(i)和醇(ii)的最终形成。可供选择地(步骤2,路线B),可略去该预先无规则化步骤,羰基合成催化剂本身可在三个可能的末端位置上无规则化终产物。路线A 或路线B
制备醇的羰基合成方法被详述于Kirk-Othmer的《化学工艺百科全书》(Encyclopedia of Chemical Technology)第4版,第1卷,第903~8页,执行编辑:Jacqueline I.Kroschwitz,由纽约Wiley-Interscience出版。该步的催化剂为例如钴-一氧化碳-有机膦。
本方法步骤(2)的醇混合物包括用于如下步骤(3)的下述化学式的支链伯醇化合物。和和少量的要知道,当在R或R’位置取代CH2OH时,主要发生在其各自的末端碳,或在更小程度上,发生在其倒数第二个碳上。期望步骤(3)中存在最少量的化学式为(iii)的化合物。3)表面活性剂的制备
有利地,本方法不导致成对支链化,即,无“季”碳取代。使用钴-一氧化碳物-有机膦时,位阻将阻止向亚乙烯基碳的逆向加成,否则将会形成非生物可降解的季碳。而且,几乎不(低于约3%)发生邻位支链化。当然,全部原料中仍有一些未被支链化。一般而言,优选从洗涤性能和生物降解性能的观点看,本方法在异构体i)和ii)情况下提供了具有一个靠近中心甲基的疏水物。
除非特别注明,本发明的所有百分比、比率和比例均以重量计。本发明引用的所有文献的相关部分均引入本发明作为参考。发明详述
1)烯烃的二聚:
本发明包括由两个相同或接近相同链长的α-烯烃的二聚作用,以制成洗涤剂范围的亚乙烯基烯烃来制备表面活性剂前体疏水物的方法。这些C5~C10,优选C7~C9的α-烯烃被二聚得到C10~C20,优选C14~C18的亚乙烯基烯烃,经过羰基合成反应其可生成C11~C21,优选C15~C19的醇。有许多实现所述二聚作用的方法,参考美国专利申请9,200,398、美国专利4,658,078和美国专利4,973,788;O.S.Vostrikova,A.G.Ibragimov,G.A.Tolstikov,L.M.Zelenova和U.M.Dzhemilev著,Izv.Akad.Nauk SSSR,Ser.khim.,1980年第10期,第2330-2页[化学文摘94:65032];日本公开特许公报06228016A2[化学文摘122:186930]。
2)醇的制备
路线A
a部分),用一种方法,如Shell在其SHOP方法中使用的异构化α-烯烃的方法,将亚乙烯基烯烃的碳碳双键预先异构化;参考《Kirk-Othmer化学工艺百科全书》(Kirk-Othmer Encyclopedia ofChemical Technology),第4版,第17卷,第848-50页,执行编辑:Jacqueline I.Kroschwitz,由纽约Wiley-Interscience出版,和《化学经济学手册》(Chemical Economics Handbook)第681页,5053K-L,斯坦福研究所(Stanford Research Institute),Menlo公园,加州94025,1993年10月。
b部分)用羰基合成化学将预异构化的亚乙烯基烯烃(现大部分为内烯烃)转化为伯醇混合物。为此,需要羰基合成催化剂,该催化剂在羰基化作用前将双键异构到α位,就象在一步法中使用羰基钴-膦催化剂一样,参考《Kirk-Othmer化学工艺百科全书》(Kirk-OthmerEncyclopedia of Chemical Technology)第4版,第1卷,第903-8页(1991年)。采用路线A(包括预异构化作用),以保证醇i和ii相对醇iii有相对高的产率。注意,i和ii的醇硫酸盐为所期望的表面活性剂,而iii的醇硫酸盐则是不足的。
路线B
该步骤直接对预先不异构化的亚乙烯基烯烃使用相同的羰基合成催化剂。这取决于催化剂在羰基化作用前,可彻底异构化亚乙烯基烯烃的碳碳双键。目的是相对iii而言,获得与路线A同样多的i和ii。
还可制备其它衍生于脂肪醇的表面活性剂,例如,烷基乙氧基硫酸盐(AES)、烷基多苷(APG)等。注意,除醇硫酸盐或AES以外的表面活性剂可由氧化所述醇或其醛直接生成羧酸盐(即,一种支链皂)制得。该皂本身可为出色的表面活性剂和/或洗涤剂助剂。该羧酸盐还可被用作原料,并可用本领域公开的技术转化为支链酰基牛磺酸盐、酰基羟乙磺酸盐、酰基肌氨酸盐、酰基-N-甲基葡糖胺或其它酰基衍生的表面活性剂。工业适用性
由本方法制得的支链型表面活性剂可被用于所有种类的洗涤组合物。这些组合物包括,但不局限于,粒状、条状和液态洗衣洗涤剂;液态手洗洗餐具组合物;液态、凝胶状和条状的个人洗涤用品;洗发香波;牙膏;硬表面清洗剂等。这些组合物可包含各种常规的洗涤组分。下文列出的这些组分可给配方设计者提供方便,并非借此限制可与本发明支链表面活性剂混合使用的组分类型。
本发明的支链表面活性剂可与洗涤助洗剂结合使用。这类助洗剂包括,例如,1~10微米的沸石A,多羧酸盐助洗剂,如柠檬酸盐,层状硅酸盐助洗剂,如“SKS-6”(Hoechst)和磷酸盐物质,特别是三聚磷酸钠(“STPP”)。大多数洗衣洗涤剂一般包含至少约1%的助洗剂,更一般地,包含约5-%~约80%的助洗剂或助洗剂混合物。
可将酶如蛋白酶、淀粉酶、脂肪酶、纤维素酶、过氧化物酶及其混合物用于含有支链表面活性剂的洗涤剂组合物中。一般的洗涤剂组合物包含约0.001%~约5%的商品酶。
洗涤剂组合物还可包含聚合的去污剂(SRA’s)。这类物质包括,例如,阴离子、阳离子和不带电荷的单体单元,特别是聚酯物质。该类型的优选物质包括低聚对苯二酸酯、磺化的基本上直链的酯低聚物,其包含一对苯二酰基和氧化烯氧基重复单元的骨架,和衍生于邻苯二甲酰基的磺化的末端部分。各种SPR’s被描述于,例如,美国专利4,968,451;4,711,730;4,721,580;4,702,857;4,877,896;5,415,807和其它的参考文献中。这类去污物质一般占成品洗涤剂组合物的约0.01%~约10%。
洗涤剂组合物还可任选包含含有一种漂白剂和一种或多种漂白活化剂的漂白组合物。若存在漂白剂如过碳酸盐或过硼酸盐(具体为过硼酸盐一水合物“PB1”),则其用量一般为成品洗涤剂组合物的约1%~约30%。可以使用漂白活化剂如壬酰氧基苯磺酸盐(NOBS)和四乙酰基乙二胺(TAED)及其混合物,以提高如过硼酸盐和过碳酸盐物质的漂白活性。若存在漂白剂活化剂,则其量一般为包括漂白剂和漂白活化剂的漂白组合物的约0.1%~约60%。还可使用其它的如被称作“光活化”漂白剂(参考美国专利4,033,718)的漂白剂。磺化锌酞菁为特别优选的光活化漂白剂。
洗涤剂组合物还可包含粘土污垢去除剂/抗再沉积剂,如乙氧基化四亚乙基五胺;见美国专利4,597,898。这类物质一般为完全配制的洗衣洗涤剂的约0.01%~约10%。
洗涤剂组合物还可包含约0.1%~约7%的聚合分散剂,其在沸石和/或层状硅酸盐助洗剂存在下是特别有用的。本领域已经知道这类物质(见美国专利3,308,067)。这类物质包括丙烯酸盐/苹果酸(malic)基共聚物,如描述于欧洲专利193,360中的那些,和聚乙二醇(“PEG”)。
本发明的洗涤剂组合物还可包含各种增白剂、染料转移抑制剂(特别是N-乙烯基吡咯烷酮和N-乙烯基咪唑的聚合物)、抑泡剂(特别是聚硅氧烷)、螯合剂,如次氮基三乙酸盐、乙二胺二琥珀酸盐等。这类物质一般为完全配制的洗涤组合物的约0.5%~约10%(重量)。
而且,要知道以本发明的方法制备的支链表面活性剂可被单独用于洗涤组合物中,或与其它洗涤表面活性剂混合使用。一般情况下,为获得在各种使用条件下对各种污垢和污渍宽范围的洗涤效果,完全配制的洗涤组合物将包含各类表面活性剂的混合物。本发明支链表面活性剂的一个优点是其能被容易地与其它已知类型的表面活性剂结合配制的能力。可以一般以约1%-约55%(重量)的含量用于本发明的其它表面活性剂的非限定性实例包括不饱和硫酸盐,如油基硫酸盐、C10~C18烷基烷氧基硫酸盐(“AExS”;特别是EO1~7乙氧基硫酸盐)、C10~C18烷基烷氧基羧酸盐(特别是EO1~5乙氧基羧酸盐)、C10~C18甘油醚、C10~C18烷基多苷及其相应的硫酸化聚葡糖苷,和C12~C18α-磺化的脂肪酸酯。也可使用非离子表面活性剂,如乙氧基化的C10~C18醇和烷基酚(例如,C10~C18EO(1~10))。若期望,还可将其它常规的表面活性剂,如C12~C18甜菜碱和磺基甜菜碱(“sultaines”)、C10~C18氧化胺等加入全部组合物中。还可使用C10~C18N-烷基多羟基脂肪酰胺。一般实例包括C12~C18N-甲基葡糖酰胺。见WO9,206,154。其它衍生于糖的表面活性剂包括N-烷氧基多羟基脂肪酰胺,如C10~C18N-(3-甲氧基丙基)葡糖酰胺。N-丙基到N-己基C12~C18葡糖酰胺可用于低发泡。也可使用C10~C20的常规皂。若期望高发泡,则可用支链C10~C16皂。常用于洗衣洗涤剂组合物的C10~C14烷基苯磺酸盐(LAS)可与本发明的支链表面活性剂混合使用。
下述实施例说明了根据本发明制备的支链表面活性剂在各种洗涤组合物中的应用,但并不试图局限于此。
实施例1
如下制备粒状洗衣洗涤剂。
A B C
吹制粉末
沸石A 30.0 22.0 6.0
硫酸钠 19.0 5.0 7.0
聚丙烯酸盐
LAS 13.0 11.0 21.0
支链AS* 9.0 8.0 8.0
硅酸盐,钠盐 - 1.0 5.0
皂 - - 2.0
碳酸盐,钠盐 8.0 16.0 20.0喷于
C10~C18EO7 1.0 1.0 1.0干添加剂
蛋白酶 1.0 1.0 1.0
脂肪酶 0.4 0.4 0.4
淀粉酶 0.1 0.1 0.1
纤维素酶 0.1 0.1 0.1
NOBS - 6.1 4.5
PB1 1.0 5.0 6.0
硫酸钠 - 6.0 -水及微量组分---------------------余量---------------
*C12~C14甲基支化的烷基硫酸盐,按上文所公开的内容制备。
一种含漂白剂的非水液态洗衣洗涤剂制备如下:
实施例II
组分 重量% 范围(重量%)
液相
支链AS* 25.3 18~35
C12-14,EO5醇乙氧基化物 13.6 10~20
己二醇 27.3 20~30
香料 0.4 0~1.0
固体物
蛋白酶 0.4 0~1.0
柠檬酸三钠,无水 4.3 3~6
过硼酸钠(PB-1) 3.4 2~7
壬酰氧基苯磺酸钠(NOBS) 8.0 2~12
碳酸钠 13.9 5~20
二乙基三胺五乙酸(DTPA) 0.9 0~1.5
增白剂 0.4 0~0.6
抑泡剂 0.1 0~0.3
少量组分 -------余量-------
*C12~C16甲基支化的烷基硫酸盐,钠盐,按上文所公开的内容制备。
一种手洗餐具液体如下:
实施例III
组分 %(重量) 范围(重量%)支链AS* 13.0 5~15C12~C13烷基乙氧基硫酸铵 15.0 10~35椰子基氧化胺 2.6 2~5甜菜碱**/Tetronic704® 0.87~0.10 0~2(混合物)醇乙氧基化物C8E11 5.0 2~10二甲苯磺酸铵 4.0 1~6乙醇 4.0 0~7柠檬酸铵 0.06 0~1.0氯化镁 3.3 0~4.0氯化钙 2.5 0~4.0硫酸铵 0.08 0~4.0过氧化氢 200ppm 0~300ppm香料 0.18 0~0.5Maxatase®蛋白酶 0.50 0~1.0水和少量组分 -------余量-------*C12C14甲基支化的烷基硫酸盐,三乙醇铵盐,按上文所公开的内容制备。**椰子烷基甜菜碱。
Claims (4)
2.一种制备支链烷基乙氧基硫酸盐的方法,其包括先将根据权利要求1所制备的醇乙氧基化,然后硫酸化。
3.一种通过氧化根据权利要求1所制备的醇或其醛中间体而制备支链烷基羧酸盐表面性剂的方法。
4.一种用根据权利要求3所制备的支链羧酸盐作为原料,制备支链酰基牛磺酸盐、支链酰基羟乙磺酸盐、支链酰基肌氨酸盐或支链酰基N-甲基葡糖胺等的方法。
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---|---|---|---|---|
EG21174A (en) * | 1996-04-16 | 2000-12-31 | Procter & Gamble | Surfactant manufacture |
PH11997056158B1 (en) * | 1996-04-16 | 2001-10-15 | Procter & Gamble | Mid-chain branched primary alkyl sulphates as surfactants |
ES2185936T3 (es) * | 1996-04-16 | 2003-05-01 | Procter & Gamble | Composiciones liquidas de limpieza que contienen tensioactivos ramificados en mitad de la cadena seleccionados. |
EG22088A (en) * | 1996-04-16 | 2002-07-31 | Procter & Gamble | Alkoxylated sulfates |
MA24137A1 (fr) * | 1996-04-16 | 1997-12-31 | Procter & Gamble | Fabrication d'agents de surface ramifies . |
US6150322A (en) | 1998-08-12 | 2000-11-21 | Shell Oil Company | Highly branched primary alcohol compositions and biodegradable detergents made therefrom |
US6093856A (en) * | 1996-11-26 | 2000-07-25 | The Procter & Gamble Company | Polyoxyalkylene surfactants |
US5780694A (en) | 1996-11-26 | 1998-07-14 | Shell Oil Company | Dimerized alcohol compositions and biodegradible surfactants made therefrom having cold water detergency |
US5849960A (en) * | 1996-11-26 | 1998-12-15 | Shell Oil Company | Highly branched primary alcohol compositions, and biodegradable detergents made therefrom |
BR9813250B1 (pt) * | 1997-10-10 | 2008-11-18 | processo para a preparaÇço de aglomerados detergentes. | |
US6482789B1 (en) | 1997-10-10 | 2002-11-19 | The Procter & Gamble Company | Detergent composition comprising mid-chain branched surfactants |
ZA989155B (en) | 1997-10-10 | 1999-04-12 | Procter & Gamble | Mixed surfactant system |
ZA989158B (en) * | 1997-10-10 | 1999-04-12 | Procter & Gamble | Detergent composition with a selected surfactant system containing a mid-chain branched surfactant |
ZA989157B (en) * | 1997-10-10 | 1999-04-12 | Procter & Gamble | Detergent composition containing mid-chain branched surfactants and an electrolyte for improved performance |
EP1023042A1 (en) | 1997-10-14 | 2000-08-02 | The Procter & Gamble Company | Personal cleansing compositions comprising mid-chain branched surfactants |
WO1999019434A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Granular detergent compositions comprising mid-chain branched surfactants |
ES2237848T3 (es) | 1997-10-14 | 2005-08-01 | THE PROCTER & GAMBLE COMPANY | Composiciones detergentes para lavar la vajilla, liquidas o en forma de gel, de accion suave que comprenden tensioactivos ramificados a mitad de cadena. |
WO1999019435A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Granular detergent compositions comprising mid-chain branched surfactants |
WO2000012451A1 (en) * | 1998-09-02 | 2000-03-09 | The Procter & Gamble Company | Improved processes for making surfactants via adsorptive separation and products thereof |
CN1177791C (zh) * | 1998-10-22 | 2004-12-01 | 荷兰解决方案研究有限公司 | α,α- 支链羧酸的制备方法 |
DE19910370A1 (de) | 1999-03-09 | 2000-09-14 | Basf Ag | Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung |
DE19912418A1 (de) | 1999-03-19 | 2000-09-21 | Basf Ag | Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung |
WO2001002328A1 (en) * | 1999-07-06 | 2001-01-11 | Sasol Technology (Pty) Ltd. | Use of metathesis products of fischer-tropsch process products |
US6677289B1 (en) | 1999-07-16 | 2004-01-13 | The Procter & Gamble Company | Laundry detergent compositions comprising polyamines and mid-chain branched surfactants |
BR0012517B1 (pt) | 1999-07-16 | 2010-12-28 | composições detergentes de lavanderia compreendendo poliaminas zwitteriÈnicas e tensoativos de cadeia intermediária ramificada. | |
US6696401B1 (en) * | 1999-11-09 | 2004-02-24 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines |
BR0015465A (pt) * | 1999-11-10 | 2002-07-09 | Unilever Nv | Método para a lavagem de um artigo de plásttco sujo em uma máquina de lavar louças, e, uso de tensoativos catiÈnicos em composições para lavagem de louças em máquina |
AU1516201A (en) * | 1999-11-10 | 2001-06-06 | Unilever Plc | Automatic dishwashing compositions containing water soluble cationic surfactants |
EP1283863B1 (en) * | 2000-05-22 | 2007-06-27 | The Procter & Gamble Company | A kit for caring for a fabric article |
CN1192085C (zh) | 2000-06-16 | 2005-03-09 | 巴斯福股份公司 | 基于羰基合成醇的洗涤剂 |
US6624132B1 (en) | 2000-06-29 | 2003-09-23 | Ecolab Inc. | Stable liquid enzyme compositions with enhanced activity |
US7569532B2 (en) | 2000-06-29 | 2009-08-04 | Ecolab Inc. | Stable liquid enzyme compositions |
US20050164902A1 (en) * | 2003-10-24 | 2005-07-28 | Ecolab Inc. | Stable compositions of spores, bacteria, and/or fungi |
US7795199B2 (en) * | 2000-06-29 | 2010-09-14 | Ecolab Inc. | Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme |
EP1241112A3 (en) | 2001-03-15 | 2003-02-26 | The Procter & Gamble Company | Flexible multiple compartment pouch |
DE10116021A1 (de) * | 2001-03-30 | 2002-10-24 | Henkel Kgaa | Wasch-oder Reinigungsmittel mit verbesserter Reinigungsleistung |
US6617136B2 (en) | 2001-04-24 | 2003-09-09 | 3M Innovative Properties Company | Biological sample processing methods and compositions that include surfactants |
US6537960B1 (en) * | 2001-08-27 | 2003-03-25 | Ecolab Inc. | Surfactant blend for use in highly alkaline compositions |
KR100966395B1 (ko) | 2002-03-29 | 2010-06-28 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀의 올리고머화 |
US7557076B2 (en) * | 2002-06-06 | 2009-07-07 | The Procter & Gamble Company | Organic catalyst with enhanced enzyme compatibility |
US7169744B2 (en) | 2002-06-06 | 2007-01-30 | Procter & Gamble Company | Organic catalyst with enhanced solubility |
US20040029757A1 (en) * | 2002-08-08 | 2004-02-12 | Ecolab Inc. | Hand dishwashing detergent composition and methods for manufacturing and using |
AU2003268193A1 (en) * | 2002-08-30 | 2004-03-19 | The Procter And Gamble Company | Detergent compositions comprising hydrophobically modified polyamines |
ATE393813T1 (de) * | 2002-09-12 | 2008-05-15 | Procter & Gamble | Polymersysteme und diese enthaltende reinigungs- oder waschmittelzusammensetzungen |
US20040226620A1 (en) * | 2002-09-26 | 2004-11-18 | Daniel Therriault | Microcapillary networks |
US7053125B2 (en) * | 2002-11-14 | 2006-05-30 | The Board Of Trustees Of The University Of Illinois | Controlled dispersion of colloidal suspension by comb polymers |
DE60327248D1 (de) * | 2002-12-18 | 2009-05-28 | Procter & Gamble | Organischer aktivator |
US20040176655A1 (en) * | 2003-02-05 | 2004-09-09 | Ayoub Paul Marie | Methods of preparing branched alkyl aromatic hydrocarbons |
JP4908197B2 (ja) * | 2003-04-16 | 2012-04-04 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 化粧品用オリゴ−α−オレフィン含有組成物 |
US7141617B2 (en) * | 2003-06-17 | 2006-11-28 | The Board Of Trustees Of The University Of Illinois | Directed assembly of three-dimensional structures with micron-scale features |
US7335802B2 (en) * | 2003-10-15 | 2008-02-26 | Shell Oil Company | Methods of preparing branched aliphatic alcohols |
WO2005037747A2 (en) * | 2003-10-15 | 2005-04-28 | Shell Internationale Research Maatschappij B.V. | Preparation of branched aliphatic alcohols using combined process streams from a hydrogenation unit, a dehydrogenation unit and an isomerization unit |
WO2005037416A2 (en) * | 2003-10-15 | 2005-04-28 | Shell Internationale Research Maatschappij B.V. | Preparation of branched aliphatic alcohols using combined process streams from a hydrogenation unit, a dehydrogenation unit, a dimerization unit and an isomerization unit |
WO2005037748A2 (en) * | 2003-10-15 | 2005-04-28 | Shell Internationale Research Maatshappij B.V. | Preparation of branched aliphatic alcohols using combined process streams from a dimerization unit and an isomerization unit |
US20050113246A1 (en) * | 2003-11-06 | 2005-05-26 | The Procter & Gamble Company | Process of producing an organic catalyst |
EP1694847B1 (en) | 2003-11-19 | 2012-06-13 | Danisco US Inc. | Serine proteases, nucleic acids encoding serine enzymes and vectors and host cells incorporating same |
US7985569B2 (en) | 2003-11-19 | 2011-07-26 | Danisco Us Inc. | Cellulomonas 69B4 serine protease variants |
US7754460B2 (en) * | 2003-12-03 | 2010-07-13 | Danisco Us Inc. | Enzyme for the production of long chain peracid |
MXPA06005652A (es) | 2003-12-03 | 2006-08-17 | Genencor Int | Perhidrolasa. |
US8476052B2 (en) * | 2003-12-03 | 2013-07-02 | Danisco Us Inc. | Enzyme for the production of long chain peracid |
MXPA06007022A (es) * | 2003-12-19 | 2006-08-31 | Procter & Gamble | Etoxilatos de poliamina hidrofobica. |
US20050159327A1 (en) * | 2004-01-16 | 2005-07-21 | The Procter & Gamble Company | Organic catalyst system |
US20050181969A1 (en) * | 2004-02-13 | 2005-08-18 | Mort Paul R.Iii | Active containing delivery particle |
US20070196502A1 (en) * | 2004-02-13 | 2007-08-23 | The Procter & Gamble Company | Flowable particulates |
US7425527B2 (en) * | 2004-06-04 | 2008-09-16 | The Procter & Gamble Company | Organic activator |
US20050276831A1 (en) * | 2004-06-10 | 2005-12-15 | Dihora Jiten O | Benefit agent containing delivery particle |
US20050288200A1 (en) * | 2004-06-24 | 2005-12-29 | Willey Alan D | Photo Bleach Compositions |
US20070290013A1 (en) * | 2004-08-12 | 2007-12-20 | Satoshi Yamane | Package for pouring a product |
US20060032872A1 (en) * | 2004-08-12 | 2006-02-16 | The Procter & Gamble Company | Package for pouring a granular product |
JP4784060B2 (ja) * | 2004-09-28 | 2011-09-28 | 日油株式会社 | 低泡性洗浄剤 |
CA2525205C (en) * | 2004-11-08 | 2013-06-25 | Ecolab Inc. | Foam cleaning and brightening composition, and methods |
US7686892B2 (en) | 2004-11-19 | 2010-03-30 | The Procter & Gamble Company | Whiteness perception compositions |
EP1661977A1 (en) * | 2004-11-29 | 2006-05-31 | The Procter & Gamble Company | Detergent compositions |
US20060207890A1 (en) | 2005-03-15 | 2006-09-21 | Norbert Staud | Electrochemical etching |
US7569490B2 (en) * | 2005-03-15 | 2009-08-04 | Wd Media, Inc. | Electrochemical etching |
AR051659A1 (es) * | 2005-06-17 | 2007-01-31 | Procter & Gamble | Una composicion que comprende un catalizador organico con compatibilidada enzimatica mejorada |
US20070044824A1 (en) | 2005-09-01 | 2007-03-01 | Scott William Capeci | Processing system and method of processing |
EP1948775B1 (en) * | 2005-09-27 | 2017-01-11 | The Procter & Gamble Company | Microcapsule and method of producing same |
AU2006299783B2 (en) | 2005-10-12 | 2012-06-14 | Danisco Us Inc. | Use and production of storage-stable neutral metalloprotease |
ES2377571T3 (es) * | 2005-10-24 | 2012-03-29 | The Procter & Gamble Company | Composiciones y sistemas para el cuidado de tejidos que comprenden microemulsiones de organosilicona y métodos que emplean los mismos |
US7678752B2 (en) * | 2005-10-24 | 2010-03-16 | The Procter & Gamble Company | Fabric care composition comprising organosilicone microemulsion and anionic/nitrogen-containing surfactant system |
US20070123440A1 (en) * | 2005-11-28 | 2007-05-31 | Loughnane Brian J | Stable odorant systems |
WO2007067473A2 (en) | 2005-12-06 | 2007-06-14 | Genencor International, Inc. | Perhydrolase epitopes |
US20090311395A1 (en) * | 2005-12-09 | 2009-12-17 | Cervin Marguerite A | ACYL Transferase Useful for Decontamination |
JP2009523903A (ja) * | 2006-01-23 | 2009-06-25 | ミリケン・アンド・カンパニー | チアゾリウム色素を有する洗濯ケア組成物 |
EP1976967A2 (en) * | 2006-01-23 | 2008-10-08 | The Procter and Gamble Company | Detergent compositions |
US20070191249A1 (en) * | 2006-01-23 | 2007-08-16 | The Procter & Gamble Company | Enzyme and photobleach containing compositions |
EP2248882A1 (en) * | 2006-01-23 | 2010-11-10 | The Procter and Gamble Company | Enzyme and fabric hueing agent containing compositions |
US20070191247A1 (en) * | 2006-01-23 | 2007-08-16 | The Procter & Gamble Company | Detergent compositions |
EP1989283A2 (en) * | 2006-02-28 | 2008-11-12 | The Procter and Gamble Company | Compositions comprising benefit agent containing delivery particles |
CN101421383B (zh) * | 2006-03-02 | 2011-12-14 | 金克克国际有限公司 | 表面活性漂白和动态pH |
KR20080098659A (ko) * | 2006-03-22 | 2008-11-11 | 더 프록터 앤드 갬블 캄파니 | 미립자 물질을 함유하는 발포 농축 조성물을 포함하는 에어로졸 제품 |
CA2642970C (en) | 2006-03-22 | 2013-09-24 | The Procter & Gamble Company | Liquid treatment compositions comprising pearlescent agents |
US20070249513A1 (en) * | 2006-04-20 | 2007-10-25 | Mort Paul R | Solid particulate laundry detergent composition comprising aesthetic particle |
US20080027575A1 (en) * | 2006-04-21 | 2008-01-31 | Jones Stevan D | Modeling systems for health and beauty consumer goods |
EP2024467A2 (en) * | 2006-05-19 | 2009-02-18 | The Procter and Gamble Company | Process for decarboxylation of fatty acids and oils to produce paraffins or olefins |
RU2413756C2 (ru) * | 2006-05-31 | 2011-03-10 | Дзе Проктер Энд Гэмбл Компани | Чистящие композиции с амфифильными привитыми полимерами на основе полиалкиленоксидов и сложных эфиров винилового спирта |
US7629158B2 (en) | 2006-06-16 | 2009-12-08 | The Procter & Gamble Company | Cleaning and/or treatment compositions |
US20070295767A1 (en) * | 2006-06-23 | 2007-12-27 | Antonio Victor Angelo | Package for pouring a product |
US20080025960A1 (en) * | 2006-07-06 | 2008-01-31 | Manoj Kumar | Detergents with stabilized enzyme systems |
EP2046269B1 (en) | 2006-08-01 | 2010-12-15 | The Procter & Gamble Company | Benefit agent containing delivery particle |
EP2557148A1 (en) | 2006-11-22 | 2013-02-13 | Appleton Papers Inc. | Benefit agent containing delivery particle |
US20080177089A1 (en) | 2007-01-19 | 2008-07-24 | Eugene Steven Sadlowski | Novel whitening agents for cellulosic substrates |
BRPI0807098A2 (pt) * | 2007-02-15 | 2014-04-29 | Procter & Gamble | Composições para liberação de agente de benefício |
US7487720B2 (en) | 2007-03-05 | 2009-02-10 | Celanese Acetate Llc | Method of making a bale of cellulose acetate tow |
US20080230572A1 (en) * | 2007-03-20 | 2008-09-25 | The Procter & Gamble Company | Package for pouring a product |
EP1975225B1 (en) | 2007-03-20 | 2011-11-09 | The Procter & Gamble Company | Method of cleaning laundry or hard surfaces |
PL1975226T3 (pl) * | 2007-03-20 | 2013-07-31 | Procter & Gamble | Płynna kompozycja do obróbki |
US7956102B2 (en) * | 2007-04-09 | 2011-06-07 | The Board Of Trustees Of The University Of Illinois | Sol-gel inks |
WO2008140988A1 (en) * | 2007-05-10 | 2008-11-20 | Danisco Us Inc., Genencor Division | Stable enzymatic peracid generating systems |
US20080305977A1 (en) * | 2007-06-05 | 2008-12-11 | The Procter & Gamble Company | Perfume systems |
MY157950A (en) | 2007-06-11 | 2016-08-30 | Procter & Gamble | Benefit agent containing delivery particle |
US8021436B2 (en) | 2007-09-27 | 2011-09-20 | The Procter & Gamble Company | Cleaning and/or treatment compositions comprising a xyloglucan conjugate |
US20090094006A1 (en) | 2007-10-03 | 2009-04-09 | William David Laidig | Modeling systems for consumer goods |
EP2205732A2 (en) | 2007-11-01 | 2010-07-14 | Danisco US Inc. | Production of thermolysin and variants thereof and use in liquid detergents |
EP2071017A1 (en) | 2007-12-04 | 2009-06-17 | The Procter and Gamble Company | Detergent composition |
ATE550420T1 (de) | 2007-12-05 | 2012-04-15 | Procter & Gamble | Verpackung mit einem reinigungsmittel |
WO2009087524A1 (en) * | 2008-01-04 | 2009-07-16 | The Procter & Gamble Company | Enzyme and fabric hueing agent containing compositions |
CN101910391B (zh) * | 2008-01-04 | 2013-04-17 | 宝洁公司 | 包含糖基水解酶和包含有益剂递送颗粒的衣物洗涤剂组合物 |
BRPI0821904A2 (pt) * | 2008-01-04 | 2019-10-01 | Procter & Gamble | composição detergente para lavagem de roupas que compreende glicosil hidralase |
EP2085070A1 (en) * | 2008-01-11 | 2009-08-05 | Procter & Gamble International Operations SA. | Cleaning and/or treatment compositions |
US7879790B2 (en) * | 2008-01-22 | 2011-02-01 | Stepan Company | Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them |
US7998920B2 (en) * | 2008-01-22 | 2011-08-16 | Stepan Company | Sulfonated estolide compositions containing magnesium sulfate and processes employing them |
EP2083065A1 (en) * | 2008-01-22 | 2009-07-29 | The Procter and Gamble Company | Colour-Care Composition |
US7666828B2 (en) | 2008-01-22 | 2010-02-23 | Stepan Company | Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them |
US8048412B2 (en) * | 2008-02-11 | 2011-11-01 | Danisco Us Inc. | Enzyme with microbial lysis activity from Trichoderma reesei |
MX346974B (es) | 2008-02-14 | 2017-04-07 | Danisco Us Inc | Granulos pequeños que contienen enzimas. |
US20090209447A1 (en) | 2008-02-15 | 2009-08-20 | Michelle Meek | Cleaning compositions |
EP2247275B1 (en) * | 2008-02-15 | 2017-11-29 | The Procter and Gamble Company | Delivery particle |
BRPI0909220A2 (pt) * | 2008-03-26 | 2015-08-25 | Procter & Gamble | Partícula de liberação |
CA2719153C (en) * | 2008-04-10 | 2016-06-21 | Basf Se | Novel surfactants for tertiary mineral oil extraction based on branched alcohols |
US7923426B2 (en) * | 2008-06-04 | 2011-04-12 | The Procter & Gamble Company | Detergent composition |
MX2010013276A (es) | 2008-06-06 | 2010-12-21 | Procter & Gamble | Composicion detergente que comprende una variante de una xiloglucanasa de la familia 44. |
BRPI0913623A8 (pt) | 2008-06-06 | 2017-10-03 | Danisco Us Inc | Composições e métodos compreendendo variantes de proteases microbianas |
MX2010013179A (es) * | 2008-06-09 | 2011-01-14 | Danisco Inc | Recuperacion de enzima insoluble a partir de caldo de fermentacion y formulacion de enzima insoluble. |
EP2135931B1 (en) | 2008-06-16 | 2012-12-05 | The Procter & Gamble Company | Use of soil release polymer in fabric treatment compositions |
EP2135933B1 (en) | 2008-06-20 | 2013-04-03 | The Procter and Gamble Company | Laundry composition |
EP2272941B1 (en) | 2008-06-20 | 2013-08-14 | The Procter & Gamble Company | Laundry composition |
EP2154235A1 (en) * | 2008-07-28 | 2010-02-17 | The Procter and Gamble Company | Process for preparing a detergent composition |
EP2313058B1 (en) | 2008-07-30 | 2022-09-28 | The Procter & Gamble Company | Delivery particle |
EP2163606A1 (en) * | 2008-08-27 | 2010-03-17 | The Procter and Gamble Company | A detergent composition comprising gluco-oligosaccharide oxidase |
EP2166077A1 (en) | 2008-09-12 | 2010-03-24 | The Procter and Gamble Company | Particles comprising a hueing dye |
EP2163608A1 (en) * | 2008-09-12 | 2010-03-17 | The Procter & Gamble Company | Laundry particle made by extrusion comprising a hueing dye and fatty acid soap |
EP2166078B1 (en) * | 2008-09-12 | 2018-11-21 | The Procter & Gamble Company | Laundry particle made by extrusion comprising a hueing dye |
US8232431B2 (en) * | 2008-09-22 | 2012-07-31 | The Procter & Gamble Company | Specific branched surfactants and consumer products |
CA2735688A1 (en) | 2008-09-22 | 2010-03-25 | The Procter & Gamble Company | Specific branched aldehydes, alcohols, surfactants, and consumer products based thereon |
EP2169042B1 (en) | 2008-09-30 | 2012-04-18 | The Procter & Gamble Company | Composition comprising microcapsules |
US7922939B2 (en) * | 2008-10-03 | 2011-04-12 | The Board Of Trustees Of The University Of Illinois | Metal nanoparticle inks |
US8187500B2 (en) * | 2008-10-17 | 2012-05-29 | The Board Of Trustees Of The University Of Illinois | Biphasic inks |
MX2011004847A (es) * | 2008-11-07 | 2011-05-30 | Procter & Gamble | Agente benefico que contiene particulas de suministro. |
MX339402B (es) | 2008-11-11 | 2016-05-25 | Danisco Us Inc | Composiciones y metodos que comprenden variantes de serina proteasa. |
JP5508431B2 (ja) | 2008-11-11 | 2014-05-28 | ダニスコ・ユーエス・インク | スブチリシン変異体を含む組成物及び方法 |
US8183024B2 (en) | 2008-11-11 | 2012-05-22 | Danisco Us Inc. | Compositions and methods comprising a subtilisin variant |
JP2012508031A (ja) | 2008-11-11 | 2012-04-05 | ダニスコ・ユーエス・インク | 1以上の組み合わせ変異を含むプロテアーゼ |
BRPI0922770A2 (pt) | 2008-12-01 | 2019-09-24 | Procter & Gamble | sistemas de perfume |
US8754028B2 (en) | 2008-12-16 | 2014-06-17 | The Procter & Gamble Company | Perfume systems |
US7723281B1 (en) | 2009-01-20 | 2010-05-25 | Ecolab Inc. | Stable aqueous antimicrobial enzyme compositions comprising a tertiary amine antimicrobial |
US7964548B2 (en) | 2009-01-20 | 2011-06-21 | Ecolab Usa Inc. | Stable aqueous antimicrobial enzyme compositions |
US8124577B2 (en) * | 2009-01-21 | 2012-02-28 | Stepan Company | Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
US8119588B2 (en) * | 2009-01-21 | 2012-02-21 | Stepan Company | Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
US8058223B2 (en) * | 2009-01-21 | 2011-11-15 | Stepan Company | Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
US7884064B2 (en) * | 2009-01-21 | 2011-02-08 | Stepan Company | Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids |
US20100190673A1 (en) * | 2009-01-29 | 2010-07-29 | Johan Smets | Encapsulates |
US20100190674A1 (en) * | 2009-01-29 | 2010-07-29 | Johan Smets | Encapsulates |
EP2414497A1 (en) | 2009-04-02 | 2012-02-08 | The Procter & Gamble Company | Composition comprising delivery particles |
MX2011012192A (es) * | 2009-05-15 | 2011-12-08 | Procter & Gamble | Sistema de perfume. |
US20100305019A1 (en) * | 2009-06-01 | 2010-12-02 | Lapinig Daniel Victoria | Hand Fabric Laundering System |
MX2011013918A (es) | 2009-06-30 | 2012-02-23 | Procter & Gamble | Composiciones para el cuidado de telas, proceso para su elaboracion y metodo de uso. |
US20110005001A1 (en) | 2009-07-09 | 2011-01-13 | Eric San Jose Robles | Detergent Composition |
EP3336164A1 (en) * | 2009-07-10 | 2018-06-20 | The Procter & Gamble Company | Compositions containing benefit agent delivery particles |
EP2277860B1 (en) | 2009-07-22 | 2015-08-19 | Stepan Company | Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them |
WO2011016958A2 (en) | 2009-07-27 | 2011-02-10 | The Procter & Gamble Company | Detergent composition |
AU2010292056B9 (en) | 2009-09-11 | 2014-07-10 | Stepan Company | Liquid cleaning compositions containing sulfonated estolides and alkyl ester sulfonates |
WO2011044305A1 (en) | 2009-10-07 | 2011-04-14 | The Procter & Gamble Company | Detergent composition |
WO2011056934A1 (en) * | 2009-11-06 | 2011-05-12 | The Procter & Gamble Company | High efficiency capsules comprising benefit agent |
EP3434764A3 (en) | 2009-12-09 | 2019-04-03 | The Procter & Gamble Company | Fabric and home care products |
US8728790B2 (en) | 2009-12-09 | 2014-05-20 | Danisco Us Inc. | Compositions and methods comprising protease variants |
EP2512406B1 (en) | 2009-12-18 | 2018-01-24 | The Procter and Gamble Company | Perfumes and perfume encapsulates |
EP2336283B1 (en) | 2009-12-18 | 2013-01-16 | The Procter & Gamble Company | Cleaning composition containing hemicellulose |
EP2513280A1 (en) | 2009-12-18 | 2012-10-24 | The Procter & Gamble Company | Composition comprising encapsulates, and process for making them |
CN102712880A (zh) | 2009-12-21 | 2012-10-03 | 丹尼斯科美国公司 | 含有嗜热脂肪地芽孢杆菌脂肪酶的洗涤剂组合物及其使用方法 |
MX2012007168A (es) | 2009-12-21 | 2012-07-23 | Danisco Us Inc | Composiciones de detergentes que contienen lipasa thermobifida fusca y metodos de uso de esta. |
EP2516612A1 (en) | 2009-12-21 | 2012-10-31 | Danisco US Inc. | Detergent compositions containing bacillus subtilis lipase and methods of use thereof |
US8933131B2 (en) | 2010-01-12 | 2015-01-13 | The Procter & Gamble Company | Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same |
WO2011090980A1 (en) | 2010-01-20 | 2011-07-28 | Danisco Us Inc. | Mold treatment |
MX349047B (es) | 2010-01-29 | 2017-07-06 | The Procter & Gamble Company * | Copolimeros novedosos lineales de polidimetilsiloxano-polieter con grupos amino y/o amonio cuaternario y uso de estos copolimeros. |
DE102010001350A1 (de) | 2010-01-29 | 2011-08-04 | Evonik Goldschmidt GmbH, 45127 | Neuartige lineare Polydimethylsiloxan-Polyether-Copolymere mit Amino- und/oder quaternären Ammoniumgruppen und deren Verwendung |
US8859259B2 (en) | 2010-02-14 | 2014-10-14 | Ls9, Inc. | Surfactant and cleaning compositions comprising microbially produced branched fatty alcohols |
WO2011109322A1 (en) | 2010-03-04 | 2011-09-09 | The Procter & Gamble Company | Detergent composition |
US20110243875A1 (en) | 2010-04-01 | 2011-10-06 | Rajan Keshav Panandiker | Care polymers |
ES2576987T3 (es) | 2010-04-06 | 2016-07-12 | The Procter & Gamble Company | Encapsulados |
EP2556139B1 (en) | 2010-04-06 | 2017-08-02 | The Procter and Gamble Company | Encapsulates |
EP2558573B1 (en) | 2010-04-15 | 2017-02-22 | Danisco US Inc. | Compositions and methods comprising variant proteases |
BR112012026915A2 (pt) | 2010-04-19 | 2016-07-12 | Procter & Gamble Comapny | composição detergente |
EP2380960A1 (en) | 2010-04-19 | 2011-10-26 | The Procter & Gamble Company | Detergent composition |
US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
US20110269657A1 (en) | 2010-04-28 | 2011-11-03 | Jiten Odhavji Dihora | Delivery particles |
DK2566960T3 (da) | 2010-05-06 | 2017-05-22 | Procter & Gamble | Forbrugerprodukter med proteasevarianter |
US8536108B2 (en) | 2010-05-12 | 2013-09-17 | The Procter & Gamble Company | Care polymers |
BR112012029133A2 (pt) | 2010-05-18 | 2016-09-13 | Milliken & Co | abrilhantadores óticos e composições compreendendo os mesmos |
US8262743B2 (en) | 2010-05-18 | 2012-09-11 | Milliken & Company | Optical brighteners and compositions comprising the same |
BR112012030525A2 (pt) | 2010-05-26 | 2016-08-09 | Procter & Gamble | encapsulados |
US8470760B2 (en) | 2010-05-28 | 2013-06-25 | Milliken 7 Company | Colored speckles for use in granular detergents |
US8476216B2 (en) | 2010-05-28 | 2013-07-02 | Milliken & Company | Colored speckles having delayed release properties |
AR081423A1 (es) | 2010-05-28 | 2012-08-29 | Danisco Us Inc | Composiciones detergentes con contenido de lipasa de streptomyces griseus y metodos para utilizarlas |
CA2799484C (en) | 2010-06-22 | 2016-02-02 | The Procter & Gamble Company | Perfume systems |
PL2585569T3 (pl) | 2010-06-22 | 2017-03-31 | The Procter And Gamble Company | Systemy zapachowe |
MX339494B (es) | 2010-06-30 | 2016-05-26 | Procter & Gamble | Composiciones que contienen aminosilicona añadidas durante el enjuague y metodos de uso de las mismas. |
WO2012009660A2 (en) | 2010-07-15 | 2012-01-19 | The Procter & Gamble Company | Detergent compositions comprising microbially produced fatty alcohols and derivatives thereof |
CN103003407B (zh) | 2010-07-20 | 2017-09-05 | 宝洁公司 | 具有多个涂层的颗粒 |
AR083328A1 (es) | 2010-07-20 | 2013-02-21 | Procter & Gamble | Particula de suministro |
EP2619299B1 (en) | 2010-09-20 | 2018-02-28 | Wacker Chemie AG | Fabric care formulations and methods |
JP2013538282A (ja) | 2010-09-20 | 2013-10-10 | ザ プロクター アンド ギャンブル カンパニー | 非フルオロポリマー表面保護組成物 |
EP2619271B1 (en) | 2010-09-20 | 2018-05-16 | The Procter and Gamble Company | Non-fluoropolymer surface protection composition |
WO2010151906A2 (en) | 2010-10-22 | 2010-12-29 | Milliken & Company | Bis-azo colorants for use as bluing agents |
US20120101018A1 (en) | 2010-10-22 | 2012-04-26 | Gregory Scot Miracle | Bis-azo colorants for use as bluing agents |
WO2012054058A1 (en) | 2010-10-22 | 2012-04-26 | The Procter & Gamble Company | Bis-azo colorants for use as bluing agents |
WO2011026154A2 (en) | 2010-10-29 | 2011-03-03 | The Procter & Gamble Company | Cleaning and/or treatment compositions |
WO2012057781A1 (en) | 2010-10-29 | 2012-05-03 | The Procter & Gamble Company | Cleaning and/or treatment compositions comprising a fungal serine protease |
WO2011017719A2 (en) | 2010-11-12 | 2011-02-10 | Milliken & Company | Thiophene azo dyes and laundry care compositions containing the same |
US8715368B2 (en) | 2010-11-12 | 2014-05-06 | The Procter & Gamble Company | Thiophene azo dyes and laundry care compositions containing the same |
EP2468239B1 (en) | 2010-12-21 | 2013-09-18 | Procter & Gamble International Operations SA | Encapsulates |
BR112013016838A2 (pt) * | 2010-12-29 | 2016-09-27 | Shell Int Research | composição de recuperação de hidrocarbonetos, e, métodos de tratamento de uma formação contendo petróleo bruto, e de preparação de uma composição de recuperação de hidrocarbonetos |
WO2012145062A1 (en) | 2011-02-16 | 2012-10-26 | The Procter & Gamble Company | Liquid cleaning compositions |
EP2675885B1 (en) | 2011-02-16 | 2017-10-25 | The Procter and Gamble Company | Compositions and methods of bleaching |
WO2012116021A1 (en) | 2011-02-25 | 2012-08-30 | Milliken & Company | Capsules and compositions comprising the same |
US8980292B2 (en) | 2011-04-07 | 2015-03-17 | The Procter & Gamble Company | Conditioner compositions with increased deposition of polyacrylate microcapsules |
JP6283607B2 (ja) | 2011-04-07 | 2018-02-21 | ザ プロクター アンド ギャンブル カンパニー | ポリアクリレートマイクロカプセルの堆積が増大されたパーソナルクレンジング組成物 |
CN103458858B (zh) | 2011-04-07 | 2016-04-27 | 宝洁公司 | 具有增强的聚丙烯酸酯微胶囊的沉积的洗发剂组合物 |
WO2012142087A1 (en) | 2011-04-12 | 2012-10-18 | The Procter & Gamble Company | Metal bleach catalysts |
US20140073548A1 (en) | 2011-04-29 | 2014-03-13 | Danisco Us Inc. | Detergent compositions containing bacillus sp. mannanase and methods of use thereof |
EP2712363A1 (en) | 2011-04-29 | 2014-04-02 | Danisco US Inc. | Detergent compositions containing geobacillus tepidamans mannanase and methods of use thereof |
EP2702072A1 (en) | 2011-04-29 | 2014-03-05 | Danisco US Inc. | Detergent compositions containing bacillus agaradhaerens mannanase and methods of use thereof |
AR086281A1 (es) | 2011-05-05 | 2013-12-04 | Danisco Us Inc | Composiciones y metodos que comprenden variantes de serina proteasas |
US9163146B2 (en) | 2011-06-03 | 2015-10-20 | Milliken & Company | Thiophene azo carboxylate dyes and laundry care compositions containing the same |
US20140371435A9 (en) | 2011-06-03 | 2014-12-18 | Eduardo Torres | Laundry Care Compositions Containing Thiophene Azo Dyes |
EP2537918A1 (en) | 2011-06-20 | 2012-12-26 | The Procter & Gamble Company | Consumer products with lipase comprising coated particles |
EP2723841B1 (en) | 2011-06-23 | 2017-01-04 | The Procter and Gamble Company | Perfume systems |
MX2013015187A (es) | 2011-06-27 | 2014-02-17 | Procter & Gamble | Polimero estable que contienen sistemas de dos fases. |
US8921299B2 (en) | 2011-07-25 | 2014-12-30 | The Procter & Gamble Company | Detergents having acceptable color |
MX347260B (es) | 2011-08-10 | 2017-04-20 | Procter & Gamble | Encapsulados. |
US8841247B2 (en) | 2011-08-15 | 2014-09-23 | The Procter & Gamble Company | Detergent compositions containing pyridinol-N-oxide compositions |
BR112014003460B1 (pt) | 2011-08-15 | 2019-05-21 | The Procter & Gamble Company | Artigos conformáveis para cuidados pessoais |
CN103781903A (zh) | 2011-08-31 | 2014-05-07 | 丹尼斯科美国公司 | 包含脂肪分解酶变体的组合物和方法 |
EP2756065B1 (en) | 2011-09-13 | 2018-10-24 | The Procter and Gamble Company | Encapsulates |
US20130303427A1 (en) | 2011-09-13 | 2013-11-14 | Susana Fernandez Prieto | MICROCAPSULE COMPOSITIONS COMPRISING pH TUNEABLE DI-AMIDO GELLANTS |
CN104023705B (zh) | 2011-11-11 | 2017-02-15 | 巴斯夫欧洲公司 | 可自乳化的聚烯烃组合物 |
US20130118531A1 (en) | 2011-11-11 | 2013-05-16 | The Procter & Gamble Company | Emulsions containing polymeric cationic emulsifiers, substance and process |
WO2013096653A1 (en) | 2011-12-22 | 2013-06-27 | Danisco Us Inc. | Compositions and methods comprising a lipolytic enzyme variant |
BR112014017513A8 (pt) | 2012-01-18 | 2017-07-04 | Procter & Gamble | sistemas de perfume |
MX353896B (es) | 2012-02-03 | 2018-02-01 | Procter & Gamble | Composiciones y metodos para el tratamiento de superficies con lipasas. |
IN2014DN06969A (zh) | 2012-03-09 | 2015-04-10 | Procter & Gamble | |
CA2867361C (en) | 2012-03-19 | 2017-07-25 | Milliken & Company | Carboxylate dyes |
EP2831214B1 (en) | 2012-03-26 | 2016-03-23 | The Procter and Gamble Company | Cleaning compositions comprising ph-switchable amine surfactants |
WO2013149858A1 (en) | 2012-04-02 | 2013-10-10 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
CA3081178C (en) | 2012-04-13 | 2023-02-21 | REG Life Sciences, LLC | Microbial production of alkanolamides and amidoamines and uses thereof |
JP2015525248A (ja) | 2012-05-16 | 2015-09-03 | ノボザイムス アクティーゼルスカブ | リパーゼを含む組成物およびその使用方法 |
JP6096287B2 (ja) | 2012-05-21 | 2017-03-15 | ザ プロクター アンド ギャンブル カンパニー | 布地処理組成物 |
SG11201407840XA (en) | 2012-05-29 | 2014-12-30 | Shell Int Research | A laundry detergent composition and method of making thereof |
EP2674475A1 (en) | 2012-06-11 | 2013-12-18 | The Procter & Gamble Company | Detergent composition |
CN104471048B (zh) | 2012-07-12 | 2018-11-16 | 诺维信公司 | 具有脂肪酶活性的多肽及编码它的多核苷酸 |
CN104755162B (zh) | 2012-08-28 | 2018-01-09 | 奇华顿股份有限公司 | 芳香剂的载体体系 |
US9422505B2 (en) | 2012-08-28 | 2016-08-23 | Givaudan S.A. | Carrier system for fragrances |
US9796952B2 (en) | 2012-09-25 | 2017-10-24 | The Procter & Gamble Company | Laundry care compositions with thiazolium dye |
EP2712915A1 (en) | 2012-10-01 | 2014-04-02 | The Procter and Gamble Company | Methods of treating a surface and compositions for use therein |
CN105026541A (zh) | 2012-10-04 | 2015-11-04 | 艺康美国股份有限公司 | 用于洗衣和其他硬表面清洁的预浸泡工艺 |
KR20150067336A (ko) | 2012-10-12 | 2015-06-17 | 다니스코 유에스 인크. | 지방분해 효소 변이체를 포함하는 조성물 및 방법 |
CA2888341A1 (en) | 2012-10-24 | 2014-05-01 | The Procter & Gamble Company | Anti foam compositions comprising aryl bearing polyorganosilicons |
US9133421B2 (en) | 2012-10-24 | 2015-09-15 | The Procter & Gamble Company | Compositions comprising anti-foams |
EP2914720B1 (en) | 2012-11-05 | 2022-08-31 | Danisco US Inc. | Compositions and methods comprising thermolysin protease variants |
US20140161741A1 (en) | 2012-12-06 | 2014-06-12 | The Procter & Gamble Company | Perfume systems |
US9303232B2 (en) | 2012-12-06 | 2016-04-05 | The Procter & Gamble Company | Perfume systems |
WO2014093747A2 (en) | 2012-12-14 | 2014-06-19 | The Procter & Gamble Company | Antiperspirant and deodorant compositions |
EP2935573A1 (en) | 2012-12-19 | 2015-10-28 | Danisco US Inc. | Novel mannanase, compositions and methods of use thereof |
JP6251296B2 (ja) | 2013-03-05 | 2017-12-20 | ザ プロクター アンド ギャンブル カンパニー | 混合糖組成物 |
WO2014150171A1 (en) | 2013-03-15 | 2014-09-25 | The Procter & Gamble Company | Specific unsaturated and branched functional materials for use in consumer products |
MX360759B (es) | 2013-03-21 | 2018-11-15 | Novozymes As | Polipeptidos con actividades lipasa y polinucleotidos que los codifican. |
AU2014241193B2 (en) | 2013-03-28 | 2016-10-20 | The Procter And Gamble Company | Cleaning compositions containing a polyetheramine |
US9340757B2 (en) | 2013-04-18 | 2016-05-17 | The Procter & Gamble Company | Fragrance materials |
CN105209612A (zh) | 2013-05-14 | 2015-12-30 | 诺维信公司 | 洗涤剂组合物 |
US20140338134A1 (en) | 2013-05-20 | 2014-11-20 | The Procter & Gamble Company | Encapsulates |
EP2806018A1 (en) | 2013-05-20 | 2014-11-26 | The Procter & Gamble Company | Encapsulates |
EP3699256A1 (en) | 2013-05-28 | 2020-08-26 | The Procter & Gamble Company | Surface treatment compositions comprising photochromic dyes |
JP6367930B2 (ja) | 2013-05-29 | 2018-08-01 | ダニスコ・ユーエス・インク | 新規メタロプロテアーゼ |
CN105492603B (zh) | 2013-05-29 | 2022-06-03 | 丹尼斯科美国公司 | 新型金属蛋白酶 |
WO2014194032A1 (en) | 2013-05-29 | 2014-12-04 | Danisco Us Inc. | Novel metalloproteases |
EP3260538B1 (en) | 2013-05-29 | 2021-04-14 | Danisco US Inc. | Novel metalloproteases |
CN105339334B (zh) * | 2013-06-28 | 2017-10-24 | 陶氏环球技术有限责任公司 | 用于制备轻度支化的疏水物的方法和对应的表面活性剂和其应用 |
EP3019603A1 (en) | 2013-07-09 | 2016-05-18 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
US20160160197A1 (en) | 2013-07-19 | 2016-06-09 | Danisco Us Inc. | Compositions and Methods Comprising a Lipolytic Enzyme Variant |
JP6235144B2 (ja) | 2013-08-26 | 2017-11-22 | ザ プロクター アンド ギャンブル カンパニー | 融点が低いアルコキシル化ポリアミンを含む組成物 |
BR112016005286A2 (pt) | 2013-09-12 | 2017-09-12 | Danisco Us Inc | composições e métodos compreendendo variantes de protease do clado lg12 |
JP6185182B2 (ja) | 2013-09-18 | 2017-08-23 | ザ プロクター アンド ギャンブル カンパニー | チオフェンアゾカルボキシレート染料を含有する洗濯ケア組成物 |
US20150150768A1 (en) | 2013-12-04 | 2015-06-04 | Los Alamos National Security Llc | Furan Based Composition |
ES2723948T3 (es) | 2013-12-13 | 2019-09-04 | Danisco Us Inc | Serina proteasas procedentes de especies de Bacillus |
CN106029881B (zh) | 2013-12-13 | 2023-01-10 | 丹尼斯科美国公司 | 吉氏芽孢杆菌-进化枝的丝氨酸蛋白酶 |
EP3097172A1 (en) | 2014-01-22 | 2016-11-30 | The Procter & Gamble Company | Method of treating textile fabrics |
WO2015109972A1 (en) | 2014-01-22 | 2015-07-30 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
EP3097175B1 (en) | 2014-01-22 | 2018-10-17 | The Procter and Gamble Company | Fabric treatment composition |
EP3097174A1 (en) | 2014-01-22 | 2016-11-30 | The Procter & Gamble Company | Method of treating textile fabrics |
WO2015112339A1 (en) | 2014-01-22 | 2015-07-30 | The Procter & Gamble Company | Fabric treatment composition |
US10155935B2 (en) | 2014-03-12 | 2018-12-18 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
WO2015138576A1 (en) | 2014-03-12 | 2015-09-17 | The Procter & Gamble Company | Detergent composition |
JP6585698B2 (ja) | 2014-03-21 | 2019-10-02 | ダニスコ・ユーエス・インク | バチルス(Bacillus)種のセリンプロテアーゼ |
EP3122847B1 (en) | 2014-03-26 | 2019-05-15 | The Procter and Gamble Company | Perfume systems |
EP3122850A1 (en) | 2014-03-27 | 2017-02-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
JP6275864B2 (ja) | 2014-03-27 | 2018-02-07 | ザ プロクター アンド ギャンブル カンパニー | ポリエーテルアミンを含有する洗浄組成物 |
EP3131921B1 (en) | 2014-04-15 | 2020-06-10 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
US8899318B1 (en) | 2014-04-24 | 2014-12-02 | Ronald C. Parsons | Applying an aggregate to expandable tubular |
EP3139902A2 (en) | 2014-05-06 | 2017-03-15 | The Procter & Gamble Company | Fragrance compositions |
EP3140384B1 (en) | 2014-05-06 | 2024-02-14 | Milliken & Company | Laundry care compositions |
CN106459937A (zh) | 2014-05-27 | 2017-02-22 | 诺维信公司 | 用于产生脂肪酶的方法 |
EP3760713A3 (en) | 2014-05-27 | 2021-03-31 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
EP3152288A1 (en) | 2014-06-06 | 2017-04-12 | The Procter & Gamble Company | Detergent composition comprising polyalkyleneimine polymers |
EP3152286B1 (en) | 2014-06-09 | 2020-01-22 | Stepan Company | Detergents for cold-water cleaning |
CN116103096A (zh) | 2014-06-30 | 2023-05-12 | 宝洁公司 | 衣物洗涤剂组合物 |
WO2016023145A1 (en) | 2014-08-11 | 2016-02-18 | The Procter & Gamble Company | Laundry detergent |
JP6400837B2 (ja) | 2014-08-27 | 2018-10-03 | ザ プロクター アンド ギャンブル カンパニー | 布地の処理方法 |
EP3186345A1 (en) | 2014-08-27 | 2017-07-05 | The Procter and Gamble Company | Detergent composition comprising a cationic polymer |
CA2956081C (en) | 2014-08-27 | 2021-03-16 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
US9809782B2 (en) | 2014-08-27 | 2017-11-07 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer and anionic/nonionic surfactant mixture |
EP3191569B1 (en) | 2014-09-08 | 2023-01-25 | The Procter & Gamble Company | Detergent compositions containing a branched surfactant |
WO2016040248A2 (en) | 2014-09-08 | 2016-03-17 | The Procter & Gamble Company | Detergent compositions containing a branched surfactant |
CN106715665B (zh) | 2014-09-25 | 2019-10-01 | 宝洁公司 | 包含含磺酸根基团的聚合物的衣物洗涤剂和清洁组合物 |
JP6430632B2 (ja) | 2014-09-25 | 2018-11-28 | ザ プロクター アンド ギャンブル カンパニー | ポリエーテルアミンを含有する布地ケア組成物 |
DK3207129T3 (da) | 2014-10-17 | 2020-02-24 | Danisco Us Inc | Serinproteaser af bacillus-arten |
US20170335306A1 (en) | 2014-10-27 | 2017-11-23 | Danisco Us Inc. | Serine proteases |
EP3212783A1 (en) | 2014-10-27 | 2017-09-06 | Danisco US Inc. | Serine proteases |
EP3212782B1 (en) | 2014-10-27 | 2019-04-17 | Danisco US Inc. | Serine proteases |
CN107148472A (zh) | 2014-10-27 | 2017-09-08 | 丹尼斯科美国公司 | 芽孢杆菌属物种的丝氨酸蛋白酶 |
WO2016069552A1 (en) | 2014-10-27 | 2016-05-06 | Danisco Us Inc. | Serine proteases |
EP3015540B1 (en) * | 2014-10-29 | 2022-02-16 | The Procter & Gamble Company | Hard surface cleaners comprising ethoxylated alkoxylated nonionic surfactants |
US9957467B2 (en) | 2014-10-29 | 2018-05-01 | The Procter & Gamble Company | Hard surface cleaners comprising ethoxylated alkoxylated nonionic surfactants |
WO2016081437A1 (en) | 2014-11-17 | 2016-05-26 | The Procter & Gamble Company | Benefit agent delivery compositions |
MX2017007103A (es) | 2014-12-05 | 2017-08-24 | Novozymes As | Variantes de lipasa y polinucleotidos que las codifican. |
US20160177222A1 (en) | 2014-12-19 | 2016-06-23 | The Procter & Gamble Company | Ionic liquid systems |
EP3242925A2 (en) | 2015-01-08 | 2017-11-15 | Stepan Company | Cold-water laundry detergents |
US20160230124A1 (en) | 2015-02-10 | 2016-08-11 | The Procter & Gamble Company | Liquid laundry cleaning composition |
US9499770B2 (en) | 2015-03-10 | 2016-11-22 | The Procter & Gamble Company | Freshening compositions resisting scent habituation |
EP3611259A1 (en) | 2015-03-12 | 2020-02-19 | Danisco US Inc. | Compositions and methods comprising lg12-clade protease variants |
WO2016160407A1 (en) | 2015-03-31 | 2016-10-06 | Stepan Company | Detergents based on alpha-sulfonated fatty ester surfactants |
WO2016172405A1 (en) | 2015-04-23 | 2016-10-27 | The Procter & Gamble Company | A low viscosity hair care composition |
EP3285735B1 (en) | 2015-04-23 | 2021-06-23 | The Procter & Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
JP6633076B2 (ja) | 2015-04-23 | 2020-01-22 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | エアゾールヘアケア組成物 |
DK3088506T3 (en) | 2015-04-29 | 2018-08-13 | Procter & Gamble | detergent |
CN107624127A (zh) | 2015-04-29 | 2018-01-23 | 宝洁公司 | 处理织物的方法 |
DK3088503T3 (en) | 2015-04-29 | 2018-08-20 | Procter & Gamble | PROCEDURE FOR TREATING A TEXTILE SUBSTANCE |
DK3088502T3 (en) | 2015-04-29 | 2018-08-13 | Procter & Gamble | PROCEDURE FOR TREATING A TEXTILE SUBSTANCE |
CN107548415A (zh) | 2015-04-29 | 2018-01-05 | 宝洁公司 | 洗涤织物的方法 |
JP6866302B2 (ja) | 2015-05-04 | 2021-04-28 | ミリケン・アンド・カンパニーMilliken & Company | ランドリーケア組成物中の青味剤としてのロイコトリフェニルメタン色素 |
WO2016184944A1 (en) | 2015-05-19 | 2016-11-24 | Novozymes A/S | Odor reduction |
WO2016196555A1 (en) | 2015-06-02 | 2016-12-08 | Stepan Company | Cold-water cleaning method |
US20160376522A1 (en) | 2015-06-23 | 2016-12-29 | The Procter & Gamble Company | Ionic liquid systems |
CA2987160C (en) | 2015-07-01 | 2022-12-13 | Novozymes A/S | Methods of reducing odor |
CN107969136B (zh) | 2015-07-06 | 2021-12-21 | 诺维信公司 | 脂肪酶变体以及编码它们的多核苷酸 |
PL3636691T3 (pl) | 2015-10-07 | 2021-09-27 | Elementis Specialties, Inc. | Środek zwilżający i przeciwpieniący |
US9902923B2 (en) | 2015-10-13 | 2018-02-27 | The Procter & Gamble Company | Polyglycerol dye whitening agents for cellulosic substrates |
US9777250B2 (en) | 2015-10-13 | 2017-10-03 | Milliken & Company | Whitening agents for cellulosic substrates |
US10155868B2 (en) | 2015-10-13 | 2018-12-18 | Milliken & Company | Whitening agents for cellulosic substrates |
EP3374486B2 (en) * | 2015-11-13 | 2023-04-05 | The Procter & Gamble Company | Cleaning compositions containing a branched alkyl sulfate surfactant and a short-chain nonionic surfactant |
WO2017100051A2 (en) | 2015-12-07 | 2017-06-15 | Stepan Comapny | Cold-water cleaning compositions and methods |
US9719056B1 (en) | 2016-01-29 | 2017-08-01 | The Procter & Gamble Company | Bis-azo colorants for use as bluing agents |
BR112018067494B1 (pt) | 2016-03-03 | 2022-05-10 | The Procter & Gamble Company | Composição anticaspa em aerossol |
EP3432776B1 (en) | 2016-03-23 | 2023-03-29 | The Procter & Gamble Company | Imaging method for determining stray fibers |
WO2017192692A1 (en) | 2016-05-03 | 2017-11-09 | Danisco Us Inc | Protease variants and uses thereof |
US20190136218A1 (en) | 2016-05-05 | 2019-05-09 | Danisco Us Inc | Protease variants and uses thereof |
WO2017196794A1 (en) | 2016-05-09 | 2017-11-16 | The Procter & Gamble Company | Detergent composition comprising an fatty acid-transforming enzyme |
PL3243896T3 (pl) | 2016-05-09 | 2020-03-31 | The Procter And Gamble Company | Kompozycja detergentowa zawierająca dekarboksylazę kwasu tłuszczowego |
ES2721224T3 (es) | 2016-05-09 | 2019-07-29 | Procter & Gamble | Composición detergente que comprende una enzima transformadora de ácido oleico |
EP3458567A1 (en) | 2016-05-20 | 2019-03-27 | Stepan Company | Polyetheramine compositions for laundry detergents |
CA3027745A1 (en) | 2016-06-17 | 2017-12-21 | Danisco Us Inc. | Protease variants and uses thereof |
EP3266861A1 (en) | 2016-07-08 | 2018-01-10 | The Procter & Gamble Company | Liquid detergent composition |
EP4357453A2 (en) | 2016-07-18 | 2024-04-24 | Novozymes A/S | Lipase variants, polynucleotides encoding same and the use thereof |
EP3284809B1 (en) * | 2016-08-17 | 2019-09-25 | The Procter & Gamble Company | Cleaning composition |
WO2018035192A1 (en) * | 2016-08-17 | 2018-02-22 | The Procter & Gamble Company | Cleaning composition |
CA3033937A1 (en) | 2016-08-30 | 2018-03-08 | Church & Dwight Co., Inc. | Composition and method for allergen deactivation |
US20180072970A1 (en) | 2016-09-13 | 2018-03-15 | The Procter & Gamble Company | Stable violet-blue to blue imidazolium compounds |
JP6952768B2 (ja) | 2016-10-21 | 2021-10-20 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 低粘度であり粘度低減剤を含む、安定なコンパクトシャンプー製品 |
CN109862941A (zh) | 2016-10-21 | 2019-06-07 | 宝洁公司 | 用于提供毛发护理有益效果的浓缩型洗发剂泡沫剂型 |
WO2018075855A1 (en) | 2016-10-21 | 2018-04-26 | The Procter & Gamble Company | Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space |
US11154467B2 (en) | 2016-10-21 | 2021-10-26 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair conditioning benefits |
CN109862944A (zh) | 2016-10-21 | 2019-06-07 | 宝洁公司 | 用于以最佳制剂空间递送消费者所需的剂型体积和表面活性剂量的泡沫剂型 |
CN109715131B (zh) | 2016-10-21 | 2022-04-26 | 宝洁公司 | 低粘度毛发护理组合物 |
EP3528894A1 (en) | 2016-10-21 | 2019-08-28 | The Procter and Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
EP3528774A1 (en) | 2016-10-21 | 2019-08-28 | The Procter and Gamble Company | Concentrated shampoo dosage of foam designating hair volume benefits |
US20180119056A1 (en) | 2016-11-03 | 2018-05-03 | Milliken & Company | Leuco Triphenylmethane Colorants As Bluing Agents in Laundry Care Compositions |
US10577571B2 (en) | 2016-11-08 | 2020-03-03 | Ecolab Usa Inc. | Non-aqueous cleaner for vegetable oil soils |
US10870816B2 (en) | 2016-11-18 | 2020-12-22 | The Procter & Gamble Company | Fabric treatment compositions having low calculated cationic charge density polymers and fabric softening actives and methods for providing a benefit |
MX2019005825A (es) | 2016-11-18 | 2019-07-10 | Procter & Gamble | Composiciones para el tratamiento de telas y metodos para proporcionar un beneficio. |
US20180142188A1 (en) | 2016-11-18 | 2018-05-24 | The Procter & Gamble Company | Fabric treatment compositions having polymers and fabric softening actives and methods for providing a benefit |
US20200040283A1 (en) | 2017-03-31 | 2020-02-06 | Danisco Us Inc | Delayed release enzyme formulations for bleach-containing detergents |
JP6821827B2 (ja) | 2017-04-12 | 2021-01-27 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 布地柔軟剤組成物 |
WO2018202846A1 (en) | 2017-05-05 | 2018-11-08 | Novozymes A/S | Compositions comprising lipase and sulfite |
US11141370B2 (en) | 2017-06-06 | 2021-10-12 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel |
US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
US11224567B2 (en) | 2017-06-06 | 2022-01-18 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel |
US11332725B2 (en) | 2017-09-27 | 2022-05-17 | Novozymes A/S | Lipase variants and microcapsule compositions comprising such lipase variants |
MX2020003316A (es) | 2017-10-10 | 2021-12-06 | Procter & Gamble | Composición de champú compacto que contiene surfactantes libres de sulfato. |
US11607373B2 (en) | 2017-10-10 | 2023-03-21 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
MX2020003318A (es) | 2017-10-10 | 2021-12-06 | Procter & Gamble | Composición de champú compacta con surfactantes aniónicos a base de aminoácidos y polímeros catiónicos. |
JP6952906B2 (ja) | 2017-10-10 | 2021-10-27 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 泡形態のパーソナルケア組成物で毛髪又は皮膚を処理する方法 |
US11725197B2 (en) | 2017-12-04 | 2023-08-15 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
BR112020011278A2 (pt) | 2017-12-08 | 2020-11-17 | Novozymes A/S | variante de alfa-amilase, composição, polinucleotídeo, construto de ácido nucleico, vetor de expressão, célula hospedeira, métodos para produção de uma variante de alfa-amilase e para aumento da estabilidade de uma alfa-amilase genitora, uso da variante, e, processo para produção de um xarope a partir de material contendo amido |
JP7280265B2 (ja) | 2017-12-20 | 2023-05-23 | ザ プロクター アンド ギャンブル カンパニー | シリコーンポリマーを含有する透明なシャンプー組成物 |
EP3749761A1 (en) | 2018-02-08 | 2020-12-16 | Novozymes A/S | Lipases, lipase variants and compositions thereof |
US20210071156A1 (en) | 2018-02-08 | 2021-03-11 | Novozymes A/S | Lipase Variants and Compositions Thereof |
US20210214703A1 (en) | 2018-06-19 | 2021-07-15 | Danisco Us Inc | Subtilisin variants |
CN112367963A (zh) | 2018-06-29 | 2021-02-12 | 宝洁公司 | 低表面活性剂气溶胶去头皮屑组合物 |
EP3833731A1 (en) | 2018-08-30 | 2021-06-16 | Danisco US Inc. | Compositions comprising a lipolytic enzyme variant and methods of use thereof |
JP2020033473A (ja) * | 2018-08-30 | 2020-03-05 | ライオン株式会社 | バイオフィルム抑制剤組成物 |
US11732218B2 (en) | 2018-10-18 | 2023-08-22 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11466122B2 (en) | 2018-10-18 | 2022-10-11 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US20200123319A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US20200123472A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US11518963B2 (en) | 2018-10-18 | 2022-12-06 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US20200123475A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US11299591B2 (en) | 2018-10-18 | 2022-04-12 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
CN113227339A (zh) | 2018-12-27 | 2021-08-06 | 高露洁-棕榄公司 | 家庭护理组合物 |
CN114174504A (zh) | 2019-05-24 | 2022-03-11 | 丹尼斯科美国公司 | 枯草杆菌蛋白酶变体和使用方法 |
EP3994255A1 (en) | 2019-07-02 | 2022-05-11 | Novozymes A/S | Lipase variants and compositions thereof |
US11873465B2 (en) | 2019-08-14 | 2024-01-16 | Ecolab Usa Inc. | Methods of cleaning and soil release of highly oil absorbing substrates employing optimized extended chain nonionic surfactants |
US20230049452A1 (en) | 2020-01-13 | 2023-02-16 | Danisco Us Inc | Compositions comprising a lipolytic enzyme variant and methods of use thereof |
EP4103625B1 (en) | 2020-02-14 | 2024-03-13 | Basf Se | Biodegradable graft polymers |
JP2023513256A (ja) | 2020-02-21 | 2023-03-30 | ビーエーエスエフ ソシエタス・ヨーロピア | 改善された生分解性を有するアルコキシル化ポリアミン |
US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
US20210277335A1 (en) | 2020-03-02 | 2021-09-09 | Milliken & Company | Composition Comprising Hueing Agent |
US20210269747A1 (en) | 2020-03-02 | 2021-09-02 | Milliken & Company | Composition Comprising Hueing Agent |
US11718814B2 (en) | 2020-03-02 | 2023-08-08 | Milliken & Company | Composition comprising hueing agent |
JP2020169325A (ja) * | 2020-06-04 | 2020-10-15 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 分岐状アルキルサルフェート界面活性剤及び短鎖非イオン性界面活性剤を含有する洗浄組成物 |
AU2021306707A1 (en) | 2020-07-06 | 2023-02-09 | Ecolab Usa Inc. | Foaming mixed alcohol/water compositions comprising a structured alkoxylated siloxane |
US20220002636A1 (en) | 2020-07-06 | 2022-01-06 | Ecolab Usa Inc. | Peg-modified castor oil based compositions for microemulsifying and removing multiple oily soils |
US20220000757A1 (en) | 2020-07-06 | 2022-01-06 | Ecolab Usa Inc. | Foaming mixed alcohol/water compositions comprising a combination of alkyl siloxane and a hydrotrope/solubilizer |
BR112023008326A2 (pt) | 2020-10-29 | 2023-12-12 | Novozymes As | Variantes de lipase e composições compreendendo tais variantes de lipase |
CN116670261A (zh) | 2020-11-13 | 2023-08-29 | 诺维信公司 | 包含脂肪酶的洗涤剂组合物 |
MX2023005963A (es) | 2020-12-04 | 2023-06-07 | Procter & Gamble | Composiciones para el cuidado del cabello que comprenden materiales de reduccion del mal olor. |
EP4011933A1 (en) | 2020-12-11 | 2022-06-15 | Basf Se | Improved biodegradable polymer with primary washing performance benefit |
US20240018304A1 (en) | 2020-12-15 | 2024-01-18 | Basf Se | Biodegradable polymers |
MX2023007483A (es) | 2020-12-23 | 2023-07-05 | Basf Se | Nuevas polialquileniminas alcoxiladas o poliaminas alcoxiladas. |
WO2022136409A1 (en) | 2020-12-23 | 2022-06-30 | Basf Se | Amphiphilic alkoxylated polyalkylene imines or alkoxylated polyamines |
WO2022197295A1 (en) | 2021-03-17 | 2022-09-22 | Milliken & Company | Polymeric colorants with reduced staining |
US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
AU2022293959A1 (en) | 2021-06-18 | 2024-01-04 | Basf Se | Biodegradable graft polymers |
EP4134421A1 (en) | 2021-08-12 | 2023-02-15 | The Procter & Gamble Company | Detergent composition comprising detersive surfactant and graft polymer |
WO2023017062A1 (en) | 2021-08-12 | 2023-02-16 | Basf Se | Biodegradable graft polymers |
WO2023017064A1 (en) | 2021-08-12 | 2023-02-16 | Basf Se | Biodegradable graft polymers |
EP4134420A1 (en) | 2021-08-12 | 2023-02-15 | The Procter & Gamble Company | Detergent composition comprising detersive surfactant and biodegradable graft polymers |
WO2023017061A1 (en) | 2021-08-12 | 2023-02-16 | Basf Se | Biodegradable graft polymers for dye transfer inhibition |
WO2023021101A1 (en) | 2021-08-19 | 2023-02-23 | Basf Se | Modified alkoxylated polyalkylene imines |
CN117881723A (zh) | 2021-08-19 | 2024-04-12 | 巴斯夫欧洲公司 | 可通过包括步骤a)至d)的方法获得的改性的烷氧基化聚亚烷基亚胺和改性的烷氧基化多胺 |
WO2023021103A1 (en) | 2021-08-19 | 2023-02-23 | Basf Se | Modified alkoxylated oligoalkylene imines and modified alkoxylated oligoamines |
WO2023021105A1 (en) | 2021-08-19 | 2023-02-23 | Basf Se | Modified alkoxylated polyalkylene imines or modified alkoxylated polyamines |
WO2023081742A1 (en) | 2021-11-04 | 2023-05-11 | Coty Inc. | Ethanol-free fragrance chassis |
WO2023114939A2 (en) | 2021-12-16 | 2023-06-22 | Danisco Us Inc. | Subtilisin variants and methods of use |
WO2023117494A1 (en) | 2021-12-20 | 2023-06-29 | Basf Se | Polypropylene imine polymers (ppi), their preparation, uses, and compositions comprising such ppi |
WO2023116569A1 (en) | 2021-12-21 | 2023-06-29 | Novozymes A/S | Composition comprising a lipase and a booster |
WO2023247664A2 (en) | 2022-06-24 | 2023-12-28 | Novozymes A/S | Lipase variants and compositions comprising such lipase variants |
WO2024020445A1 (en) | 2022-07-20 | 2024-01-25 | Ecolab Usa Inc. | Novel nonionic extended surfactants, compositions and methods of use thereof |
WO2024017797A1 (en) | 2022-07-21 | 2024-01-25 | Basf Se | Biodegradable graft polymers useful for dye transfer inhibition |
WO2024042005A1 (en) | 2022-08-22 | 2024-02-29 | Basf Se | Process for producing sulfatized esteramines |
Family Cites Families (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2934568A (en) * | 1950-02-06 | 1960-04-26 | Atlas Powder Co | Detergent reaction products of branched chain aliphatic alcohols and ethylene oxide |
US2695327A (en) * | 1950-06-21 | 1954-11-23 | Ziegler Karl | Dimerization of unsaturated hydrocarbons |
DE1059401B (de) * | 1951-12-22 | 1959-06-18 | Gen Aniline & Film Corp | Oberflaechenaktive Mittel |
FR1151630A (fr) * | 1955-06-15 | 1958-02-03 | Ici Ltd | Nouveaux alcools saturés et leur procédé de fabrication |
US3480556A (en) * | 1966-09-29 | 1969-11-25 | Atlantic Richfield Co | Primary alcohol sulfate detergent compositions |
US3647906A (en) * | 1970-05-11 | 1972-03-07 | Shell Oil Co | Alpha-olefin production |
US3775349A (en) * | 1970-06-29 | 1973-11-27 | Ethyl Corp | Detergent formulations containing alkyl polyethoxy sulfate mixtures |
BE795729A (fr) | 1972-03-07 | 1973-08-21 | Basf Ag | Procede de fabrication de sels de potassium ou d'ammonium mineraux fluides |
DE2213007A1 (de) | 1972-03-17 | 1973-09-20 | Henkel & Cie Gmbh | Klarspuelmittel fuer die maschinelle geschirreinigung |
JPS492962A (zh) | 1972-05-08 | 1974-01-11 | ||
US3887624A (en) * | 1972-06-07 | 1975-06-03 | Jefferson Chem Co Inc | Vinylidene alcohol compositions |
DE2243307C2 (de) * | 1972-09-02 | 1982-04-15 | Henkel KGaA, 4000 Düsseldorf | Feste Wasch- und Waschhilfsmittel mit einem Gehalt an vergrauungsverhütenden Zusätzen |
PH10800A (en) * | 1972-10-31 | 1977-09-07 | Procter & Gamble | Detergent composition |
US4102823A (en) | 1972-12-08 | 1978-07-25 | The Procter & Gamble Company | Low and non-phosphate detergent compositions |
GB1495145A (en) | 1974-04-11 | 1977-12-14 | Procter & Gamble | Controlled sudsing detergent compositions |
IT1106254B (it) * | 1976-03-08 | 1985-11-11 | Procter & Gamble Europ | Composizione detergente liquida contenente enzimi |
CA1086178A (en) * | 1977-04-04 | 1980-09-23 | Christian R. Barrat | Liquid detergent composition |
DE2817834C2 (de) * | 1978-04-24 | 1983-05-19 | Henkel KGaA, 4000 Düsseldorf | Flüssiges Waschmittel |
US4426542A (en) | 1981-04-22 | 1984-01-17 | Monsanto Company | Synthesis of plasticizer and detergent alcohols |
GB8420945D0 (en) * | 1984-08-17 | 1984-09-19 | Unilever Plc | Detergents compositions |
US5030774A (en) * | 1986-10-03 | 1991-07-09 | Exxon Research And Engineering Co. | Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof |
US5026933A (en) | 1987-10-07 | 1991-06-25 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
US4870038A (en) | 1987-10-07 | 1989-09-26 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
GB8811672D0 (en) | 1988-05-17 | 1988-06-22 | Unilever Plc | Detergent composition |
US5245072A (en) | 1989-06-05 | 1993-09-14 | Mobil Oil Corporation | Process for production of biodegradable esters |
DE3918252A1 (de) * | 1989-06-05 | 1990-12-13 | Henkel Kgaa | Fettalkylsulfate und fettalkyl-polyalkylenglycolethersulfate, verfahren zu ihrer herstellung und ihre verwendung |
GB9001404D0 (en) | 1990-01-22 | 1990-03-21 | Unilever Plc | Detergent composition |
WO2004074223A1 (ja) * | 1992-10-06 | 2004-09-02 | Keiichi Sato | 低級オレフィンのニ量化法およびそれを用いたアルコールの製造方法 |
JP3458419B2 (ja) * | 1992-10-06 | 2003-10-20 | 三菱化学株式会社 | 低級オレフィンの二量化法およびそれを用いたアルコールの製造方法 |
US5284989A (en) * | 1992-11-04 | 1994-02-08 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
EP0670888B1 (en) * | 1992-11-16 | 1998-02-04 | Unilever Plc | Detergent compositions |
JP2813112B2 (ja) | 1993-08-30 | 1998-10-22 | 花王株式会社 | 衣料用液体洗浄剤組成物 |
GB9410678D0 (en) * | 1994-05-27 | 1994-07-13 | Unilever Plc | Surfactant composition and cleaning composition comprising the same |
WO1996018711A1 (en) | 1994-12-16 | 1996-06-20 | The Procter & Gamble Company | Hard surface cleaners comprising highly ethoxylated guerbet alcohols |
US5562866A (en) | 1995-06-20 | 1996-10-08 | Albemarle Corporation | Formulated branched chain alcohol ether sulfate compounds |
WO1997001521A1 (en) * | 1995-06-29 | 1997-01-16 | Sasol Technology (Propietary) Limited | Process for producing oxygenated products |
MA24137A1 (fr) * | 1996-04-16 | 1997-12-31 | Procter & Gamble | Fabrication d'agents de surface ramifies . |
ES2185936T3 (es) | 1996-04-16 | 2003-05-01 | Procter & Gamble | Composiciones liquidas de limpieza que contienen tensioactivos ramificados en mitad de la cadena seleccionados. |
WO1997038972A1 (en) | 1996-04-16 | 1997-10-23 | The Procter & Gamble Company | Process for manufacturing sulphates of longer chain branched alkanols and alkoxylated alkanols |
PH11997056158B1 (en) * | 1996-04-16 | 2001-10-15 | Procter & Gamble | Mid-chain branched primary alkyl sulphates as surfactants |
EG21623A (en) | 1996-04-16 | 2001-12-31 | Procter & Gamble | Mid-chain branced surfactants |
EG22088A (en) | 1996-04-16 | 2002-07-31 | Procter & Gamble | Alkoxylated sulfates |
ATE225840T1 (de) * | 1996-04-16 | 2002-10-15 | Procter & Gamble | Ausgewählte mitten in der kette verzweigte primäre oberflachenaktive alkylsulfat-substanzen enthaltende tenside |
EG21174A (en) | 1996-04-16 | 2000-12-31 | Procter & Gamble | Surfactant manufacture |
CA2272139C (en) * | 1996-11-26 | 2002-12-17 | The Procter & Gamble Company | Polyoxyalkylene surfactants |
RO120404B1 (ro) | 1996-11-26 | 2006-01-30 | Shell Internationale Research Maatschappij B.V. | Compoziţie de alcooli primari, cu grad ridicat de ramificare, procedeu de obţinere a acesteia şi compoziţie detergentă care o conţine |
US6093856A (en) | 1996-11-26 | 2000-07-25 | The Procter & Gamble Company | Polyoxyalkylene surfactants |
US5780694A (en) * | 1996-11-26 | 1998-07-14 | Shell Oil Company | Dimerized alcohol compositions and biodegradible surfactants made therefrom having cold water detergency |
GB9703054D0 (en) | 1997-02-14 | 1997-04-02 | Ici Plc | Agrochemical surfactant compositions |
-
1997
- 1997-04-14 MA MA24550A patent/MA24137A1/fr unknown
- 1997-04-14 MA MA24549A patent/MA24136A1/fr unknown
- 1997-04-16 CA CA002252435A patent/CA2252435C/en not_active Expired - Fee Related
- 1997-04-16 AT AT97924504T patent/ATE220389T1/de not_active IP Right Cessation
- 1997-04-16 DE DE69713887T patent/DE69713887T2/de not_active Expired - Fee Related
- 1997-04-16 CN CN97195560A patent/CN1106366C/zh not_active Expired - Fee Related
- 1997-04-16 ES ES97924504T patent/ES2179342T3/es not_active Expired - Lifetime
- 1997-04-16 AU AU29910/97A patent/AU2991097A/en not_active Abandoned
- 1997-04-16 BR BR9708678A patent/BR9708678A/pt not_active Application Discontinuation
- 1997-04-16 EP EP97924504A patent/EP0900181B1/en not_active Revoked
- 1997-04-16 JP JP9537387A patent/JPH11507957A/ja active Pending
- 1997-04-16 CZ CZ983345A patent/CZ334598A3/cs unknown
- 1997-04-16 WO PCT/US1997/006485 patent/WO1997038957A1/en not_active Application Discontinuation
- 1997-04-16 ZA ZA9703246A patent/ZA973246B/xx unknown
- 1997-04-16 TR TR1998/02077T patent/TR199802077T2/xx unknown
- 1997-04-16 KR KR19980708437A patent/KR100307426B1/ko not_active IP Right Cessation
- 1997-04-16 CN CNB011244135A patent/CN1318397C/zh not_active Expired - Fee Related
-
1998
- 1998-10-13 US US09/170,694 patent/US6320080B2/en not_active Expired - Lifetime
- 1998-10-13 US US09/170,185 patent/US6015781A/en not_active Expired - Lifetime
- 1998-10-15 MX MX9808555A patent/MX219947B/es unknown
-
1999
- 1999-11-04 US US09/433,853 patent/US6133222A/en not_active Expired - Lifetime
-
2000
- 2000-06-27 US US09/604,233 patent/US6326348B1/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100441674C (zh) * | 2003-12-03 | 2008-12-10 | 罗迪亚公司 | 气味性质得到改善的支链硫酸酯类物及其在个人护理组合物中的用途 |
CN110639426A (zh) * | 2019-10-10 | 2020-01-03 | 太原理工大学 | 一种支链烷基磺酸盐表面活性剂及其制备工艺 |
Also Published As
Publication number | Publication date |
---|---|
BR9708678A (pt) | 1999-08-03 |
MX219947B (zh) | 2004-04-16 |
DE69713887T2 (de) | 2003-02-27 |
TR199802077T2 (xx) | 1999-01-18 |
CA2252435C (en) | 2004-03-23 |
CA2252435A1 (en) | 1997-10-23 |
ZA973246B (en) | 1997-11-14 |
US6326348B1 (en) | 2001-12-04 |
WO1997038957A1 (en) | 1997-10-23 |
MX9808555A (zh) | 1999-02-28 |
MA24137A1 (fr) | 1997-12-31 |
CZ334598A3 (cs) | 1999-03-17 |
KR20000005563A (ko) | 2000-01-25 |
AU2991097A (en) | 1997-11-07 |
CN1222133A (zh) | 1999-07-07 |
ATE220389T1 (de) | 2002-07-15 |
EP0900181A1 (en) | 1999-03-10 |
CN1318397C (zh) | 2007-05-30 |
MA24136A1 (fr) | 1997-12-31 |
ES2179342T3 (es) | 2003-01-16 |
EP0900181B1 (en) | 2002-07-10 |
KR100307426B1 (ko) | 2001-11-30 |
DE69713887D1 (de) | 2002-08-14 |
JPH11507957A (ja) | 1999-07-13 |
CN1106366C (zh) | 2003-04-23 |
US20010034461A1 (en) | 2001-10-25 |
US6320080B2 (en) | 2001-11-20 |
US6133222A (en) | 2000-10-17 |
US6015781A (en) | 2000-01-18 |
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