CN1747831A - 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 - Google Patents
将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 Download PDFInfo
- Publication number
- CN1747831A CN1747831A CNA2004800037744A CN200480003774A CN1747831A CN 1747831 A CN1747831 A CN 1747831A CN A2004800037744 A CNA2004800037744 A CN A2004800037744A CN 200480003774 A CN200480003774 A CN 200480003774A CN 1747831 A CN1747831 A CN 1747831A
- Authority
- CN
- China
- Prior art keywords
- thin slice
- goods
- barrier layer
- color
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
- B44C1/1737—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff on a substrate unsuitable for direct deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C7/00—Paperhanging
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/08—Dimensions, e.g. volume
- B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
- B32B2309/105—Thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/906—Roll or coil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/11—Methods of delaminating, per se; i.e., separating at bonding face
- Y10T156/1168—Gripping and pulling work apart during delaminating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1405—Capsule or particulate matter containing [e.g., sphere, flake, microballoon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1452—Polymer derived only from ethylenically unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1462—Polymer derived from material having at least one acrylic or alkacrylic group or the nitrile or amide derivative thereof [e.g., acrylamide, acrylate ester, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1467—Coloring agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1476—Release layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1481—Dissimilar adhesives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1486—Ornamental, decorative, pattern, or indicia
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
- Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2848—Three or more layers
Abstract
将颜色涂敷到表面上的分层制品包括可视觉感知的颜色效果的薄片、能够将薄片粘合到表面上的键合剂以及可移除地连接到薄片上的可分离衬料。该制品还包括一种物质、试剂或屏障,其能防止或至少减弱外来试剂从表面向分层制品内某个位置的转移,这将影响薄片所传送的可视觉感知的颜色效果。
Description
发明领域
本发明涉及将颜色涂敷到表面上的制品和方法。更具体地讲,本发明涉及将颜色涂敷到表面上的制品,该制品抵抗由于外来试剂例如外来染料和颜色从涂敷制品的表面转移出而引起的脱色,以及减弱或防止造成脱色的外来试剂转移的方法。
发明背景
通过粘合层(典型地为粘合剂)将可视觉感知的颜色效果的薄片如干颜色组分粘合性地固定到表面上,以用于涂敷颜色。在表面内或表面上的外来物质或试剂(例如涂漆层中的颜色)可溶解进入粘合层,并浸透转移到可视觉感知的颜色效果的薄片上。起源于表面并转移到薄片的某些外来试剂存在于可视觉感知的颜色效果的薄片内会导致制品所提供的颜色效果的脱色。例如,脱色可由存在于普通墙漆中的有机颜色产生,该颜色被粘合层部分溶解并随后通过粘合层转移到可视觉感知的颜色效果的薄片内。例如,薄片可由于单偶氮基颜色从表面迁移出而变黄。通常,可视觉感知的颜色效果的薄片包括一个外涂层,其可抑制外来试剂从制品中的挥发和释放,并因此加速外来试剂在薄片内的累积和伴随的脱色。在制品使用期限内,外来试剂在可视觉感知的颜色效果的薄片内的浓度和因此造成的脱色程度增加。高温和油漆内的低分子量组分如乙二醇、聚结助剂和水可加速外来试剂的转移,这同样会加速脱色。
发明概述
按照本发明的原则,提供了一种用于将可视觉感知的颜色效果传送到包含外来试剂的表面上的制品。该制品通常包括可视觉感知的颜色效果的薄片、薄片所负载的能够将薄片粘合到表面上的键合剂及可移除地覆盖薄片的可分离衬料。在本发明的一个方面,该制品可包括设置在薄片和键合剂之间的阻挡层。阻挡层可有效地减弱外来试剂从表面向薄片的转移。在各种具体实施方案中,阻挡层可包括镀玻璃的聚合物、镀陶瓷的聚合物、包含硅酸钠的组合物、阴离子层和阳离子层中的至少一个或纳米复合物。阻挡层可任选地掺入无纺材料、金属处理材料、纤维素材料和/或聚合物层。
可供选择地或者除了阻挡层之外,制品的薄片、键合剂、连接层和/或阻挡层还可包括能够清除外来试剂以减弱外来试剂从表面向薄片的转移的清除剂材料。在其它可供选择的实施方案中,制品的薄片、键合剂、连接层和/或阻挡层可包括中和剂,其能够调节外来试剂以减弱外来试剂从表面向薄片的转移。在本发明的另一个实施方案中,用于将可视觉感知的颜色效果传送到包含外来试剂的表面的制品,制品的键合剂对外来试剂的溶解度明显不同于外来试剂在表面中的溶解度。在本发明的另一个实施方案中,键合剂控制脱色。
依照本发明,提供了防止和减轻传送可视觉感知的颜色效果的分层制品脱色的方法。该方法包括使分层制品适于涂敷到包含外来试剂的表面上,并改变分层制品以减弱外来试剂从表面向提供可视觉感知的颜色效果的部分分层制品的转移,这可通过将阻挡层、清除剂材料和/或中和剂添加到分层制品的一层或多层,或者调节外来试剂在分层制品的一层或多层中的溶解度使之明显不同于外来试剂在表面中的溶解度来实现。
附图概述
引入并构成本说明书一部分的附图图示说明了本发明的实施方案,并且与上文给出的本发明的一般说明和下文给出的实施方案的详细说明一起用于解释本发明的原理。
图1为依照本发明的一个实施方案将颜色涂敷到表面上的制品的图解视图;
图1A为依照本发明的一个实施方案类似于图1的图解视图;
图2为依照本发明一个可供选择的实施方案用于将颜色涂敷到表面上的制品的图解视图;
图2A为依照本发明的一个实施方案类似于图2的图解视图;
图3为依照本发明另一个可供选择的实施方案将颜色涂敷到表面上的制品的图解视图;
图3A为依照本发明的一个实施方案类似于图3的图解视图;和
图4为图示说明包含单偶氮颜色的溶液吸光度的图形表示,其中包括添加和不添加各种类型活性炭的情况。
发明详述
本发明涉及将颜色涂敷到表面上的制品和方法,其中要保护提供颜色的材料防止脱色,脱色是由外来试剂从涂敷制品的表面迁移、扩散或弥散到提供颜色的部分制品造成的。本发明所用的术语“颜色”用来指一种颜色效果,即,在色彩感知方面的差异。在一个具体的实施方案中,颜色效果为基本永久的颜色效果,即,不能被去除或在偶然接触、轻柔洗涤等时不会显著减退的颜色效果。因此,基本永久的颜色效果有别于可容易去除或减退的暂时颜色效果,例如由粉笔或蜡笔所产生的颜色效果。本文所用术语“颜色组分”是指提供颜色效果的本发明制品的组分。外涂层或外敷层还可被涂敷到颜色层上。应当理解,在使用时,制品还可向表面提供其它功能效果。制品的主要功能不局限于提供颜色或其它审美效果。
本文所用术语“表面”是指能够在其上接受颜色组分的物体或底物的任何外层或边界。合适的表面可以为大致二维的和平坦的或为大致三维的并包括弯曲处、角形部分等。在一个实施方案中,利用本发明的制品和方法涂敷颜色组分的表面包括建筑表面,即建筑物、房屋灯具(即电器)、家具等的表面。建筑物表面可以是在建筑物内部的内表面或在建筑物外部的外表面。大致三维的建筑表面可包括例如二维表面如板条(例如,绕窗户或门道的板条)、地板、器具、家具、地面、柜台等的边缘处理。建筑表面可被永久地安装也可被暂时地安装或者是便携式的。本发明的产品还能被涂敷到制品的表面上,使其具有与建筑表面相同或不同的纹理和/或外观。例如,这种产品可用来将颜色层涂敷到器具、家具和其它的建筑制品上。根据本公开内容,对于本领域的技术人员来说,适于利用本发明的制品和方法涂敷颜色的其它表面将是显而易见的。
参考图1并依照本发明的原则,将颜色涂敷到表面16上的制品10包括可视觉感知的颜色效果的薄片12(例如干颜色组分)、键合剂14(例如粘合剂)、覆盖薄片12的可分离衬料18、以及位于键合剂14之间的阻挡层20。薄片可包括形成于任何合适材料的外涂层15,材料包括但不限于聚合物,如聚氨酯、聚氯乙烯、聚偏二氟乙烯、聚丙烯酸酯、纤维素材料等,以及它们的共混物和共聚物。键合剂为在制品10外界的环境温度下能够将薄片12粘合到表面16上的任何物质。在本发明的某些实施方案中,薄片12可具有的厚度小于或等于约0.084mm(3.3密耳或0.0033英寸)。
可分离衬料18为可移除的并旨在和适于移除,同时涂敷或随后涂敷薄片12到表面16上。典型地,通过将衬料18剥离薄片12将可分离衬料18移除。可分离衬料18向薄片12提供结构支撑和/或强度(例如当可分离衬料为薄膜形式时),和/或有利于在加工、存储和使用期间处理制品,且可任选地用于将末道漆传送到薄片12。示例性的制品10描述于命名为“Articles and Methods forApplying Color on Surfaces”的普通转让申请系列10/324,237,其公开内容据此全文引入本文以供参考。
本文使用参考术语如“垂直”、“水平”、“下”、“上”等是作为实施例以建立一参照系,而不是作为限制。应当理解,在不背离本发明精神和范围的条件下,可使用各种其它参照系。
继续参考图1,阻挡层20可为预防性阻挡层20并通过包括但不限于扩散和迁移的机理消除或至少明显阻挡外来物质或试剂转移到薄片12内,外来物质或试剂起源于将要涂敷颜色的表面16,在图1中示出并指定为参考数字21。外来试剂21被理解为因以有限浓度存在于薄片12中而被认为是外来的试剂,或者通过增加正常存在于薄片12中的试剂现存浓度而被认为是外来的。一种此类外来试剂21为存在于现有层中(例如现有的油漆层)的有机颜色或染料,其在制品10被涂敷之前位于表面16上或覆盖表面16,且键合剂14与其机械连接以将制品10粘合到表面16上。
阻挡层20可作为物理屏障,其通过限定不能透过的或不可渗透的屏障来妨碍、阻止或换句话讲防止向外来试剂21的通过或渗透转移,使得制品12性质的降解得以防止或减弱,例如防止发生脱色。可供选择地,阻挡层20可减慢或延缓外来试剂21的转移速率,使得至少在提供表面16颜色的制品10的使用期限内薄片12的性质(例如颜色)不会被可觉察地影响。可调整阻挡层20的厚度和性质以提供所需的阻挡或延迟。阻挡层20的厚度小于或等于约0.064 mm(2.5密耳或0.0025in),并且在本发明的某些实施方案中,阻挡层20可为0.025mm(0.1密耳或0.001英寸)或更薄。
阻挡层20图示说明在图1中,其作为可确认的层或薄层掺入到制品10的分层结构中。在本发明一个可供选择的实施方案中,阻挡层20a,特征在于性质与阻挡层20完全相同,可作为键合剂14的组分掺入。在另一个可供选择的实施方案中,阻挡层20b,特征在于性质与阻挡层20完全相同,可作为薄片12的组分掺入。阻挡层20a和20b可作为分别位于键合剂14或薄片12厚度内的层或薄层而被隔离开,或者可均匀分布在相应的键合剂14或薄片12之一的整个厚度内。阻挡层20、20a和20b可单独使用或以任何排列或组合掺入到制品10中。每个阻挡层20、20a和20b可组合本文所述的两个或多个候补材料。应当理解,本文所述阻挡层20的性质同样适用于阻挡层20a和20b。
通常,除了别的以外,阻挡层20所需的特性和性质还将取决于外来试剂21的特性及其在阻挡层20内的传送机理。已知几种因素影响试剂例如外来试剂21在材料例如阻挡层20内的传送性质。形成阻挡层20的聚合物的化学本性影响传送,这是由于据信随着保持聚合物链在一起的力的强度增加,外来试剂的转移降低。聚合物主链被公认为是决定链与链间作用力的重要因素。聚合物链不得不移到一旁或者打开,以容许试剂转移或渗透。带有羟基、氰基、卤素、酯和酰胺键的聚合物为阻挡层20示例性的候补材料,尽管本发明不受此限制。通常,玻璃化转变温度超过涂敷制品10的表面16外界的环境温度条件的任何聚合物将具有足够的链与链间作用力强度。
影响外来试剂21在阻挡层20内传送的另一个因素为形成阻挡层20的聚合物对水分的敏感性。
有水存在时,阻挡性取决于氢键的极性材料的阻挡性将变小。水使聚合物膨胀,这会减小链与链间的作用力并容许渗透。特征在于此类极性键的聚合物包括,但不限于,酯和氰基聚合物。
影响外来试剂21在阻挡层20内传送的另一个因素为构成阻挡层20的聚合物的填充度、结晶度和定向。增加阻挡层20的结晶度可由于自由体积减小而改进阻挡性。增加定向也可改进阻挡性,这是由于试剂转移的通道变成更曲折的通道。然而,材料的硬度也会随着结晶度和定向的增加而增加,这会降低制品10的柔韧性。
影响外来试剂21在阻挡层20内传送的另一个因素为接触薄片12或键合剂14的聚合物表面的本性。亲水的或疏水的表面及/或极性的或非极性的表面可防止,或至少减弱或延缓外来试剂21从表面16的转移。
影响外来试剂21在阻挡层20内传送的另一个因素为添加剂和调节剂的存在。添加剂典型地减弱使聚合物柔韧的链与链间的作用力,因此增加渗透。将低阻挡性的聚合物与具有可接受阻挡性的聚合物共混将增加不良阻挡材料的阻挡性。
在本发明的一个具体实施方案中,阻挡层20具有如下组成的组合物:按重量计约3%至按重量计约40%的水玻璃或硅酸钠(Na2Si4O2),按重量计约3%至按重量计约40%的聚合物,按重量计约20%至按重量计约24%的水。使用硅酸钠作为阻挡层描述于美国专利1,365,715和5,460,855,其公开内容据此全文引入本文以供参考。组合物中的聚合物提供此类阻挡层20柔韧性,且水的存在可稀释组合物以有利于涂层涂敷过程。通过在高温下化合或熔融不同比率的沙子和苏打粉(即碳酸钠)来制造硅酸钠。
在本发明的另一个具体实施方案中,阻挡层20包括阴离子层和阳离子层中的至少一个,其能够捕获或捕捉外来试剂21。将这种阴离子和阳离子层掺入制品10的一种合适技术是用含水分散体涂敷薄片12。合适的阳离子和阴离子含水分散体描述于美国专利6,576,327,其公开内容据此全文引入本文以供参考。例如,具体的阳离子和阴离子含水分散体可以商品名ACRONAL、BUTONAL、STYROFAN和PROPIOFAN商购自BASF Aktiengesellschaft(Ludwigshafen,Germany)。阴离子层可有效地捕获荷上正电的外来试剂21,且阳离子层可有效地捕获荷上负电的外来试剂21。通常,阻挡层20可由双层或多层结构构成,该结构由空间上分开的阴离子和阳离子层组成,从而无论外来试剂21的电荷状态如何,所有带电的外来试剂颗粒均能被捕获并确保不迁移到薄片12内。例如,上游的阴离子层将捕获荷上正电的外来试剂颗粒并传送荷上负电的外来颗粒以被更远离表面16的下游阳离子层捕获。可供选择地,可将双层或多层结构的阳离子层置于阴离子层的上游。可供选择地,可提供阴离子层或阳离子层在键合剂14内,或者作为键合剂14的组分混合,且其余的阴离子层或阳离子层可作为单独的层提供。
在本发明的另一个具体实施方案中,阻挡层20为镀玻璃的聚合物。合适的镀玻璃的聚合物包括,但不限于,涂敷氧化铝的聚对苯二甲酸乙二醇酯聚合物及共聚物、涂敷氧化铝的聚丙烯聚合物及共聚物、涂敷氧化铝的尼龙聚合物及共聚物,以及这些材料的组合。此类玻璃涂层典型地为透明的无机材料。例如,此类玻璃涂层可通过基于等离子的沉积方法被涂敷。
在本发明的另一个具体实施方案中,阻挡层20为镀陶瓷的聚合物。一种合适的涂层材料为氧化硅(SiOx),其可为化学计量的或非化学计量的,并使用硅烷为前体源通过化学气相沉积法沉积。合适的镀陶瓷的聚合物包括,但不限于,涂敷氧化硅的定向聚丙烯、涂敷氧化硅的聚对苯二甲酸乙二醇酯、涂敷氧化硅的定向聚乙烯醇、涂敷氧化硅的聚丙烯、涂敷氧化硅的聚乙烯,以及它们的组合。
在本发明的另一个具体实施方案中,阻挡层20为基于纳米粘土的复合材料或塑性纳米复合物,其生成曲折通道使外来试剂21必须成功地穿过才能到达薄片12。基于纳米粘土的复合材料是通过将纳米粘土片状颗粒、单个片状颗粒的类晶团聚体、类晶团聚体的聚集体或它们的混合物分散在聚合物主体基质内形成的。将纳米粘土片状颗粒排列成具有多个邻近束缚层形式的片状结构,其中平面尺寸显著大于该结构的厚度。在本发明的某些实施方案中,主体聚合物树脂内的纳米粘土负荷按重量计可大于约0.5%。在本发明的其它实施方案中,主体聚合物树脂内的纳米粘土负荷可在按重量计约0.5%至约25%的范围内变化。无论如何,纳米粘土负荷足以限定通过主体聚合物树脂的曲折通道。单个片状颗粒的厚度小于约2nm,直径在约10nm至约5000nm的范围内。
纳米粘土片状颗粒可由任何合适的有机或无机材料组成,具体地讲,可由页硅酸盐组成。适用于本发明的天然页硅酸盐包括但不限于绿粘土,例如蒙脱石、滑石粉、锂蒙脱石、云母、蛭石、膨润土、囊脱石、贝得石、volkonskoite、magadite和kenyaite。适用于本发明的合成页硅酸盐包括,但不限于,合成云母、合成滑石粉及合成锂蒙脱石。合成或天然页硅酸盐可通过氟化作用或者通过添加有机阳离子而改性。适用于本发明的页硅酸盐商购自多个来源,包括Nanocor,Inc.(Arlington Heights,Illinois)。适于基质的主体聚合物树脂包括,但不限于,聚酰胺聚合物及共聚物、聚对苯二甲酸乙二醇酯聚合物及共聚物、聚丙烯聚合物及共聚物,以及它们的组合。纳米粘土片状颗粒可衍生自天然的、合成的及改性的页硅酸盐,其可被处理以容许掺入有机阳离子。
适用于本发明的另一种基于纳米粘土的聚合物材料为商购自Honeywell的AEGIS纳米复合物阻挡树脂,其基于尼龙6。
适用于纳米复合物的其它无机片状颗粒包括铝或锌的片状物,其具有的厚度为约3μm至约10μm,直径为约4μm至约17μm。这些无机片状颗粒可以按重量计约0.1%至按重量计约3.5%的含量提供于上述任何聚合物主体基质内。示例性的铝片状物可作为铝颜色分散体以商品名METALURE商购自Eckhart America L.P.(Louisville,Kentucky)。
在本发明的另一个具体实施方案中,阻挡层20或薄片12是由具有结晶度的聚合物形成,该结晶度可限定曲折的通道。当形成阻挡层20的聚合物涂敷到表面16上时,其玻璃化转变温度应大于制品10的温度,使得组成聚合物具有低的自由体积用于外来试剂21的迁移。
在本发明的另一个具体实施方案中,键合剂14或薄片12对外来试剂21的溶解度明显不同于外来试剂21在表面16中的溶解度。因此,外来试剂21不易从表面l6转移到键合剂14上。如果能阻止外来试剂进入键合剂14,则接着从键合剂14向薄片12的随后转移也不能发生。在这种情况下,键合剂14则充当阻挡层20起作用。可通过改变粘合剂的化学性质来改变外来试剂21在键合剂14内的溶解度,从而调节键合剂14的组成分子间的键合强度。
为改进薄片12与和阻挡层20之间和/或键合剂14与阻挡层20之间的粘合,合适的表面可为经过以下处理的表面:通过电晕处理、目标表面的粗加工以增加表面积、目标表面的膨胀、分子间混合或相互扩散、直接涂敷键合剂、层压期间施加热量或压力、包括官能化聚合物以提供共价键或分子间键合、通过压花、粉刷或其它机械方法增加一个或多个层的表面积、或者通过添加颗粒或通过溶剂刻蚀法,以及它们的组合。例如,电晕处理涉及将薄片12暴露于高电压的电晕放电,同时使薄片12通过一对间隔开的电极之间。
本发明设想本文所述任何各种类型的阻挡层20可单独使用或以相容的组合使用。例如,阻挡层20可由两层结构组成,其包括基于纳米粘土复合材料的一薄层和包含硅酸钠的一薄层。
在本发明的另一个具体实施方案中,阻挡层20还可包括聚合物的薄片或薄膜,其与阻挡层20共同作用以减弱外来试剂21从表面16向薄片12的转移。还可提供聚合物薄膜作为制品10分层结构内的一薄层,该薄层明显不同于阻挡层20,或者可供选择地,聚合物薄膜可作为薄层置于薄片12内或键合剂14内。在多个实施方案中,聚合物薄片或薄膜选自聚偏二氯乙烯聚合物及共聚物、聚乙烯醇聚合物及共聚物、乙烯-乙烯醇聚合物及共聚物、聚三氟氯乙烯聚合物及共聚物、丙烯腈甲基丙烯酸酯聚合物及共聚物、聚丙烯腈聚合物及共聚物、芳族聚酰胺聚合物及共聚物、无定形聚酰胺聚合物及共聚物、聚对苯二甲酸乙二醇酯聚合物及共聚物、聚氯乙烯聚合物及共聚物、聚偏二氟乙烯聚合物、液晶聚合物及共聚物、聚苯乙烯、聚乙烯、丙烯酸类、苯乙烯-丙烯酸共聚物、醇酸树脂、聚氨酯、聚丙烯聚合物及共聚物、定向聚丙烯聚合物及共聚物、纤维素聚合物、共聚物及涂层、脂肪族聚酯、多羟基烷醇、聚已内酯、聚乳酸,以及它们的组合。聚合物薄膜抵抗外来试剂21的渗透从而有助于阻挡层20阻塞或限制外来试剂21向薄片12的转移。本发明设想薄片12或键合剂14可包括所列聚合物之一作为其组分,从而在制品10的分层结构内不需要明显的聚合物层。
适于用作阻挡层20内聚合物薄膜的示例性聚亚乙烯(PVDC)聚合物以商品名SARAN商购自Dow Chemical Company(Midland,Michigan)。聚乙烯醇(PVA)的示例性商业来源包括Clariant GmbH(Frankfurt,DE)和E.I.Du Pont DeNemours & Co.(Wilmington,Delaware)。示例性的乙烯一乙烯醇共聚物以商品名EVAL商购自Kuraray Co.,Ltd.(Kurashiki City,Japan)和以商品名SOARNOL商购自Nippon Gohsei(Osaka,Japan)。一种合适的聚三氟氯乙烯(PCTFE)以商品名ACLAR商购自Honeywell International Inc.(MorrisTownship,New Jersey)。合适的丙烯腈甲基丙烯酸酯共聚物以商品名BAREX商购自BP,p.l.c.(London,England)。示例性的芳族聚酰胺以商品名MDX6商购自Mitsubishi Gas Chemical America Inc.(New York,NY),还可商购自以下来源,例如Honeywell International Inc.(Morris Township,New Jersey)和BASF Aktiengesellschaft(Ludwigshafen,Germany)。适用于本发明的无定形聚酰胺以商品名SELAR PA商购自E.I.Du Pont De Nemours & Co.(Wilmington,Delaware)。示例性的液晶聚合物以商品名VECTRAN商购自Ticona(Summit,New Jersey)。
通过合成期间或不可逆化学反应将邻近链相互连接可任选地交联聚合物薄膜的聚合物、共聚物或共混聚合物(共聚物)。交联可通过共价键合到交联的链上的添加的原子或分子来实现。交联还可通过弱化学交互作用、部分微晶化、甚至物理缠绕来实现。交联可起作用以改进阻挡层20抵抗外来试剂21从粘合制品23的表面16向薄片12的转移。聚合物薄膜可形成于热塑性树脂,当其受热时软化但冷却到室温时又回到其初始状态,或者形成于热固性树脂,当其加热时为不可逆的。与热塑性树脂相反,热固性聚合物树脂已知为可交联的。
在本发明的另一个具体实施方案中,阻挡层20还可掺入无纺织网,该网由具有单根合成纤维、长丝、细丝或纤维长度聚合物纤维(由一种或多种热塑性聚合物组成)的缠绕结构的纤维网组成。还可提供无纺织网作为制品10分层结构内的一薄层,该薄层明显不同于阻挡层20,或者可供选择地,无纺织网可作为薄片12或键合剂14的薄层或分布部件。无纺织网可形成于多种方法,例如熔喷法、纺粘法和粘合粗梳网法。通常,纺粘无纺织网形成于平均直径典型地在约10微米和20微米之间的缠绕长丝的加固结构或薄片,熔喷无纺织网形成于平均直径通常小于10微米的纤维的加固结构或薄片。无纺织网可由多层层压材料组成,特征在于纺粘层和熔喷层的组合。用于形成无纺织网的常见热塑性聚合物包括,但不限于聚烯烃(如聚乙烯、聚丙烯、聚丁烯)、聚酰胺(如尼龙6、尼龙6/6、尼龙10和尼龙12)、聚酯(如聚对苯二甲酸乙二醇酯和聚对苯二酸丁二醇酯)、聚碳酸酯、聚苯乙烯、热塑性弹性体、含氟聚合物、乙烯基聚合物,以及它们的共混物和共聚物。
在本发明的另一个具体实施方案中,阻挡层20还可包括形成于纤维素纤维的缠绕集合或薄毡的纤维素无纺材料,纤维素纤维如木浆纤维、棉(纤维素)纤维、人造丝(再生纤维素)纤维、乙酸(乙酸纤维素)纤维和三乙酸(三乙酸纤维素)纤维。还可提供纤维素无纺材料作为制品10分层结构内的一薄层,该薄层明显不同于阻挡层20,或者可供选择地,纤维素无纺材料可作为薄片12或键合剂14的薄层或分布部件。无纺材料的特征还在于通过例如水缠结法形成的纤维素纤维与热塑性或合成纤维或长丝的复合共混物。无纺材料还可由热塑性纤维与长丝的一个或多个纤维网及层压在一起的一个或多个纤维素纤维网构成。
在本发明的另一个具体实施方案中,阻挡层20还可掺入形成于金属处理涂层或箔的金属化薄膜,并任选地掺入金属处理涂层或箔层压到其上的单层聚合物薄膜。还可提供金属化薄膜作为制品10分层结构内的一薄层,该薄层明显不同于阻挡层20,或者可供选择地,金属化薄膜可作为薄层置于薄片12或键合剂14内。合适的金属化薄膜包括,但不限于,金属处理聚对苯二甲酸乙二醇酯聚合物及共聚物、金属处理聚丙烯聚合物及共聚物、金属处理聚酰胺聚合物及共聚物、金属箔,以及这些材料以例如堆积在层压材料内的层的形式的组合。金属化薄膜可通过例如蒸汽相镀金属法或化学气相沉积法使金属(例如铝)或其它金属(例如金、银和铜)沉积在聚合物薄膜的至少一个平表面上而形成。金属化薄膜可作为一薄层引入形成制品10的制作工艺中。
在本发明的另一个具体实施方案中,阻挡层20还可掺入柔韧的纤维素材料。还可提供柔韧的纤维素材料作为制品10分层结构内的一薄层,该薄层明显不同于阻挡层20,或者可供选择地,柔韧的纤维素材料可作为薄片12或键合剂14的一部分。纤维素材料为以纤维素或纤维素衍生物作为其组分的任何材料。合适的纤维素材料包括,但不限于,纸张、涂敷丁酸盐清漆的纸张、棉花、典型木浆、非木质纤维素纤维、乙酸纤维素、三乙酸纤维素、人造丝、热机械木浆、化学木浆、去粘合的化学木浆、马利筋、细菌纤维素,以及它们的组合。纤维还可为交联的、磺酸化的、丝光处理的、热处理的、与热塑性稳定剂纤维混合的、或用湿强度剂处理的。可使用各种纤维的混合物(包括共成型),以及共沉淀热塑性纤维和木纤维的其它混合物。乙酸纤维素是由木浆制成的,该木浆使用乙酸酐处理而形成乙酸纤维素薄片。乙酸纤维素可制造成各种各样的厚度,范围为0.025mm至0.13mm(0.001英寸至0.005英寸),并通常为透明的。乙酸-丁酸纤维素为光学透明漆,其可被涂敷于纸张或加固木浆。
纤维素材料可用任何常规的颜色层或涂层涂敷,该颜色层或涂层包含碳酸钙、二氧化钛、二氧化硅、缎光白、重晶石、云母、氧化锌、塑性颜色或主要由高岭石(水合硅酸铝(Al2Si2O5(OH)4))组成的高岭粘土颜色。颜色涂层作为颜色材料在粘合剂内的含水悬浮液或分散体涂敷到薄片12上,包括但不限于淀粉、蛋白质、苯乙烯丁二烯分散体或点阵、聚乙酸乙烯酯及点阵、丙烯酸点阵。颜色涂层的存在可向纤维素材料贡献附加的阻挡效果、增强纤维素材料的阻挡效果、或者赋予纤维素材料有效的阻挡效果以阻止或延缓外来试剂21向层12的转移。通常,此类颜色涂层的厚度在约20μm至约80μm的范围内。颜色涂层可用包含例如可溶解的金属盐的表面处理改性以增加其阻挡性。
本发明设想除了阻挡层20之外,制品10还可掺入清除剂材料32(图2)和/或中和剂46(图3),如本文所述它们可与阻挡层20共同作用以减弱或防止外来试剂21从表面16向薄片12的转移。清除剂材料32和/或中和剂46可作为明显的层被提供,或者可被包括在分层制品10的一个或多个薄层中,薄层包括薄片12、键合剂14和阻挡层20。置于制品10内的清除剂材料32可选自沸石、中孔沸石、高表面积的碳黑、DGB碳黑、聚阳离子分子、聚乙烯吡咯烷酮聚合物及共聚物、环糊精化合物、活性炭、阳离子碳、阳离子惰性材料、阴离子材料、氧化镁、活性氧化铝、混合金属氧化物、金属氧化物的纳米颗粒、椰子基碳、木基碳、碳纳米管、碳纳米纤维、离子交换树脂、染料转移抑制剂,以及这些材料的组合、共混物或混合物。
参考图1A,制品10还可包括置于薄片12和阻挡层20之间的一个或多个连接层22(如图1A所述),和/或置于键合剂14和阻挡层20之间的一个或多个连接层(未示出但类似于连接层22)。本发明设想一个或多个连接层22可作为或包含阻挡层20。形成每个连接层22的至少一部分的典型材料包括官能化的聚烯烃乙烯丙烯酸酯、乙烯-乙酸乙烯酯、官能化的丙烯酸、聚氯乙烯、聚烯烃、聚乙氧基化物,以及它们的组合、共混物和共聚物。如本文所述,每个连接层22还可包含清除剂材料32(图2)和/或中和剂46(图3),它们与阻挡层20共同作用以减弱或防止外来试剂21从表面16向薄片12的转移。
参考图2,其中与图1相同的参考数字是指相同的特征,并依照本发明的另一个实施方案,将颜色涂敷到表面16上的制品23包括可视觉感知的颜色效果的薄片24、键合剂26和可分离衬料30。薄片24类似于薄片12并可包括外涂层25作为一薄层,键合剂26类似于键合剂14,可分离衬料30与可分离衬料18完全相同。
依照本发明的原则,制品23还包括清除剂材料,其用参考数字32表示,能够吸收或捕获从涂敷制品23的表面16转移出的外来试剂21,使得制品23在表面16上的使用期限内外来试剂21不影响薄片24的性质(例如染色性)。清除剂材料32通过捕获、吸收、吸附或捕捉来清除外来试剂21,在某种意义上有效地阻塞或防止外来试剂21转移(如扩散、迁移或弥散)到薄片24内,这可防止制品23性质的降解。例如,清除剂材料32的作用可消除薄片24内脱色的发生。可供选择地,清除剂材料32可通过捕获或吸收只是减慢或延缓外来试剂21的转移,使得至少在制品23位于表面16上的使用期限内薄片24的性质(例如颜色)不会被可觉察地影响。清除剂材料32以有效浓度和/或位置存在,以减轻、减弱或消除起源于表面16的外来试剂21对薄片24的影响。清除剂材料32可以多种技术涂敷,包括,但不限于,印刷、挤出、共挤出、涂敷、喷雾,以及这些技术的组合。
在本发明的各种具体实施方案中,清除剂材料32选自聚阳离子分子、聚乙烯吡咯烷酮聚合物及共聚物、环糊精化合物、活性炭、阳离子碳、阳离子惰性材料、阴离子材料、氧化镁、活性氧化铝、混合金属氧化物、金属氧化物的纳米颗粒、椰子基碳、木基碳、碳纳米管、碳纳米纤维、离子交换树脂、染料转移抑制剂,以及这些材料的组合、共混物或混合物。清除剂材料32可任选地掺入至少一种另外的清除剂组分,该组分选自沸石、中孔沸石、高表面积的碳黑和/或DGB碳黑。
清除剂材料32图示说明在图2中,其作为可确认的层或薄层限制在或掺入到制品23的分层结构中。在本发明的一个可供选择的实施方案中,清除剂材料32a,特征在于性质与清除剂材料32完全相同,可作为键合剂26的组分掺入。在另一个可供选择的实施方案中,清除剂材料32b,特征也在于性质与清除剂材料32a完全相同,可作为薄片24的组分掺入。清除剂材料32a和32b可作为分别位于键合剂26或薄片24厚度内的层或薄层而被隔离开,或者可均匀分布在相应的键合剂26或薄片24之一的整个厚度内。清除剂材料32、32a和32b可单独使用或以任何排列或组合掺入到制品23中。每个清除剂材料32、32a和32b可组合本文所述的两个或多个候补材料。本文所述清除剂材料32的性质理解为清除剂材料32a和32b的代表。
在本发明的一个实施方案中,并如上所提及,与清除剂材料32一致的可为染料转移抑制剂。染料转移抑制剂可以有效含量存在于薄片24或键合剂26内以在制品23的有效使用期限内防止染料转移到薄片或延缓染料转移到薄片24。通常,染料转移抑制剂存在的含量范围为按所述组合物的重量计约0.01%至按所述组合物的重量计约10%。合适的染料转移抑制剂包括,但不限于,染料聚乙烯吡咯烷酮聚合物、聚胺N-氧化物聚合物、N-乙烯基吡咯烷酮和N-乙烯基咪唑的共聚物、酞菁锰、过氧化物酶,以及它们的组合。示例性的染料转移抑制剂描述于普通转让的美国专利5,633,225,其公开内容据此全文引入本文以供参考。
在本发明的另一个实施方案中,并如上所提及,清除剂材料32可为活性炭,其由于具有高的多孔性水平而能够吸收从涂敷制品23的表面16转移出的外来试剂21。活性炭可以下列形式提供:颗粒形式、纤维形式、纳米管形式、包含粘合剂、溶剂、墨水和活性炭颗粒的墨水形式,以及这些多种形式的混合物。在颗粒、纤维和纳米管形式中,平均粒径可在约3μm至约70μm的范围内,并优选地在约12.5μm或更小的范围内。可通过任何常规的印刷技术将墨水形式作为明显的层涂敷,或者可供选择地可分散在键合剂26内,并通过下列技术涂敷,例如印刷、挤出、共挤出、涂敷、喷雾,以及这些技术的组合。
活性炭的合适颗粒形式商购自多种来源,包括Calgon Carbon Corp.(Pittsburgh,Pennsylvania)、Specialty Chemicals Division ofMeadWestvaco Corp.(Covington,Virginia)和Carbochem Inc.(Ardmore,Pennsylvania)。可用于实施本发明的活性炭的具体颗粒形式包括Calgon CarbonADP椰子基活性炭、RGC木基活性炭(WAC)、RGC WAC+PVAm、Nuchar SN-30(WAC)和得自MeadWestvaco的Nuchar SA-1500(WAC)、以及Carbochem CA-10(WAC)。
在本发明的另一个实施方案中,并如上所提及,清除剂材料32可包括涂敷到薄片27上的涂层,该涂层包含可被取代或衍生的环糊精化合物。通常,环糊精为环状低聚糖,其由至少五个、优选至少六个吡喃葡萄糖单元通过a-1,4键连接而组成。一种此类基于环糊精的阻挡层20为挤出薄膜涂层,其由溶解或分散在热塑性稀释剂中的按重量计约0.1%至按重量计约60%的环糊精化合物组成,热塑性稀释剂组成该组合物的余量。厚度范围为约0.0075mm(0.3密耳)至约0.038mm(1.5密耳)的挤出薄膜涂层作为一薄层包括在制品23的结构内,位置在薄片24和键合剂26之间。还可使用诸如淀粉、改性淀粉、纤维素、改性纤维素和成膜聚合物的惰性载体或成膜剂(例如粘合剂)用环糊精化合物含水的或其它源自溶剂的溶液或分散体将薄片24溶液涂敷而使环糊精化合物被涂敷。当将水或溶剂移除后,剩余的薄膜应包含约0.1克环糊精每平方米至约0.6克环糊精每平方米。掺入此类环糊精化合物的清除剂材料32描述于国际申请号PCT/US99/08017。
在本发明的另一个实施方案中,并如上所提及,清除剂材料32可包含离子交换树脂。离子交换树脂为包含永久连接到聚合物主链上的带电荷的碎片或固定离子的聚合树脂。
参考图2A,其中与图1A和2相同的参考数字是指相同的特征,制品23还可包括一个或多个连接层22和/或置于薄片24和键合剂26之间的阻挡层20。一个或多个连接层22、清除剂材料32和阻挡层20如果确认为离散薄层,则它们可在制品23的厚度内以任何合适的顺序排列。连接层可包含清除剂材料32或部分清除剂材料32,其与分层制品23另一薄层内的另一部分清除剂材料32共同作用,以减弱或防止外来试剂21从表面16向薄片12的转移。阻挡层20可为本文所述的任何候补阻挡层20。可供选择地,如本文所述,制品23的阻挡层20可由聚合物、纤维素材料、无纺材料或金属化薄膜形成。
参考图3,并依照本发明的另一个实施方案,将颜色涂敷到表面16上的制品36包括可视觉感知的颜色效果的薄片38、薄片38的一个表面42上的键合剂40(例如粘合剂)以及可分离衬料44。薄片38类似于薄片12及24并可包括外涂层45作为一明显的薄层,键合剂40类似于键合剂14及26,可分离衬料44与可分离衬料18及30完全相同。
制品36还包括中和剂,用参考数字46表示,其能够破坏从表面16转移出的外来试剂21的化学键。中和剂46以有效阻塞或防止扩散进入薄片38的方式破坏外来试剂21的化学键,从而防止制品36性质的降解(例如,颜色的脱色),例如防止或减轻脱色的发生。可供选择地,中和剂46可减弱或延缓外来试剂21的转移,从而至少在制品36的有效使用期限内薄片38的性质不会被被可觉察地影响。中和剂46以有效浓度和/或位置存在以减弱或消除外来试剂21从表面16向薄片36的转移。
中和剂46图示说明在图3中,其作为可确认的层或薄层限制或掺入到制品36的分层结构中。在本发明一个可供选择的实施方案中,中和剂46a,特征在于性质与中和剂46完全相同,可作为键合剂40的组分掺入。在另一个可供选择的实施方案中,中和剂46b,特征也在于性质与中和剂46a完全相同,可作为薄片38的组分掺入。中和剂46a和46b可作为分别位于键合剂40或薄片38厚度内的层或薄层而被隔离开,或者可均匀分布在相应的键合剂40或薄片38之一的整个厚度内。中和剂46、46a和46b可单独使用或以任何排列或组合掺入到制品36中。每个中和剂46、46a和46b可组合本文所述的两个或多个候补材料。本文所述中和剂46的性质理解为中和剂46a和46b的代表。
在本发明的一个具体实施方案中,中和剂46为漂白化合物,其能够中和与起源于涂敷制品36的表面16的外来试剂21有关的颜色。漂白化合物可为已知用于洗涤、硬质表面清洁、自动盆碟洗涤或假牙清洁目的的任何氧化剂。适用于本发明的漂白化合物包括,但不限于卤素漂白剂,例如次盐漂白剂(如次氯酸盐漂白剂)、氧漂白剂、过氧化物漂白剂、硼氢化钠、过酸,以及它们的混合物。漂白化合物可起作用以破坏外来试剂21的化学键,从而外来试剂不再呈现或显示具有能够使薄片38脱色的可觉察的颜色。
在另一个具体的实施方案中,如果存在中和剂46的话,其为掺入到薄片38或外涂层45的荧光增白剂。如本领域普通技术人员所知,荧光增白剂为通常用于使白色纺织品看起来更亮的无色荧光染料。荧光增白剂可通过当暴露于波长范围为约300nm至约430nm的紫外光时可发出波长范围为约400nm至约500nm的可见光而有效地起作用,例如当制品36涂敷到表面16上时包含在照亮制品36的人造光或自然光内的紫外光。荧光增白剂通过竞争薄片38内的活化点而干扰染料或颜色如外来试剂21。荧光增白剂可起作用以在视觉上掩盖外来试剂21所呈现的颜色。荧光增白剂由于构造基元构成的发色团而分子上结构化,构造基元选自次亚乙烯基、亚氨基、2-吡唑-1,3-二基、1,4-亚苯基、2,5-呋喃二基、2,5-噻吩二基、苯基、呋喃-2-基、吡唑-4-基、吡唑-1-基、1,2,3-三唑-2-基、1,2,4-三唑-1-基、1,3,5-三嗪-2-基、1,2,4-噁二唑-5-基、1,4-亚萘基、苯并呋喃-2-基、苯并噁唑-2-基、苯并咪唑-2-基、4,7-香豆素二基、石脑油[1,2-d]三唑-2-基、萘二甲酰亚氨基、芘-1-基,以及连在一起的它们的组合。合适的荧光增白剂列于Ullmann’s Encyclopedia of Industrial Chemistry,第18A卷,第153至176页,其公开内容据此全文引入本文以供参考。
在本发明的另一个具体实施方案中,中和剂46为添加到薄片38或键合剂40的pH调节剂,其可使从涂敷制品36的表面16转移出的外来试剂21脱色。pH调节剂破坏外来试剂21的化学键,从而外来试剂21不能显示具有或换句话讲不能呈现可视觉感知的颜色,或至少外来试剂21呈现固有的可视觉感知颜色的能力显著下降。pH调节剂可为任何酸性或碱性物质,如果该物质加到薄片38其能与组成薄片38的材料化学相容,和/或如果该物质加到键合剂40其能与表现键合剂40特征的材料化学相容。
参考图3A,其中与图1A和3相同的参考数字是指相同的特征,制品36还可包括一个或多个连接层22和/或置于薄片38与键合剂40之间的阻挡层20。阻挡层20和/或连接层22还可任选地包含清除剂材料32(图2),如本文所述,清除剂材料与中和剂46联合作用。任选的清除剂材料32还可作为制品36的分层结构内的一明显薄层被提供,或者可供选择地,作为薄片38或键合剂40的一部分被提供。可供选择地,清除剂材料32可作为制品23的分层结构内的一明显薄层被包括,和/或作为制品23的薄片24和/或键合剂26内的组分或薄层被包括。制品36的阻挡层20可为本文所述的任何阻挡层20,或者可供选择地,可形成于选自聚合物、纤维素材料、无纺材料或金属化薄膜的材料。制品36内的清除剂材料32可选自沸石、中孔沸石、高表面积的碳黑、DGB碳黑、聚阳离子分子、聚乙烯吡咯烷酮聚合物及共聚物、环糊精化合物、活性炭、阳离子碳、阳离子惰性材料、阴离子材料、氧化镁、活性氧化铝、混合金属氧化物、金属氧化物的纳米颗粒、椰子基碳、木基碳、碳纳米管、碳纳米纤维、离子交换树脂、染料转移抑制剂,以及这些材料的组合、共混物或混合物。
本发明设想制品36可包括任何可能的排列或组合的阻挡层20(图1)、清除剂材料32(图2)和中和剂46(图3)。因此,阻挡层20、清除剂材料32和/或中和剂46可产生单独的贡献,该贡献共同作用以减弱或防止外来试剂21从表面16向薄片38的转移。在本发明的某些实施方案中,隔离开的单独贡献可能不足以达到所需的防止或减弱外来试剂21的转移,但单独贡献的共同作用则会产生所需效果。本发明还设想可提供联合的多于一种类型的阻挡层20、多于一种类型的清除剂材料32和/或多于一种类型的中和剂46,以提供有目标地所需的防止或减弱外来试剂21的转移。
阻挡层20(图1)、清除剂材料32(图2)或中和剂46(图3)可均匀地或一致地分布于相应制品10、23或36的平面上。可供选择地,阻挡层20、清除剂材料32或中和剂46可以不均匀的图案分布,使得阻挡层20、清除剂材料32或中和剂46的含量或密度在制品的水平面上具有空间依赖性。例如,阻挡层20、清除剂材料32或中和剂46可在某些制品区域不存在,可沿着制品的水平面具有浓度或厚度梯度,可在制品水平面的不同位置以不同的浓度或厚度存在(即,在制品的周边边缘附近具有较高的浓度或厚度),等等。图案内的浓度或厚度可系统地或随机地调整,且制品水平面内的所有区域可具有非零浓度或厚度的阻挡层20、清除剂材料32或中和剂46。
按照以下步骤测量颜色改变/稳定性。提供一个每侧均为7.62cm的正方形样本。将样本粘合性地安放到刚性垫板上,仔细排除空气泡和皱纹。从样本移除其任何上面的载体层或可分离衬料,暴露颜色层。
刚性垫板如下制备。提供由石膏板制成的板。该板涂有市售底漆,按原样以Behr Premium Plus PVA Drywall Primer & Sealer No.73白胶乳购自BehrCorporation。干燥时用具有49.3克/升颜色的油漆涂该板。合适的油漆以Behr,Premium Plus Interior Semi-Gloss Enamel Pastel Base no.3500商购自Behr。用具有约6.35mm间隙的合成小羊皮辊实现涂油漆。将该板置于水平表面上,并涂底漆/涂油漆直到表面具有均匀平坦的底漆/油漆涂层。在50%RH和20摄氏度下使涂层间存在24小时。依照ASTM Test Methods E1164测量充足颜色和E308将颜色量度转化为L.a.b.标度进行样本的基线L*A*B色度计测量。己发现具有脉冲氙弧灯的Minolta CM508d色度计适合使用以下设置:2°/C、SCE、8mm样本区域。进行基线测量后,将样本置于60摄氏度的测试烘箱中。样本每小时移除一次并如上所述再次测试L*A*B*。每小时进行一次测试,直到记录的B*(称为ΔB*)改变在连续的测量之间小于10%。
依照ASTM标准D2805测量,如本发明所述的制品10可具有的不透明度为至少99,优选至少99.3,更优选至少99.5。此外,用底脚直径为5mm的压榨机在8.74克的限定负荷下测量,此类制品可具有的厚度小于0.084mm,优选小于0.076mm,更优选小于0.064mm,更优选小于0.05mm,更优选小于0.04mm。如此制造的制品10将具有的不透明度与厚度的比率为每毫米至少40,优选至少50,更优选至少55。
实施例1
制备10克汉撒黄(单偶氮)颜色和2-丙醇(IPA)的溶液。使用分光光度计找到10ppm溶液的吸收曲线内的峰。在约404nm波长处观察到一主要吸收峰。在404nm处记录所有随后的吸光度读数。测定2ppm、4ppm、6ppm、8ppm和10ppm的溶液在404nm处的吸光度以得到校准曲线。将各种类型的活性炭(直径大约45微米至63微米)添加到10ppm的溶液中,在搅拌盘上不断搅拌该溶液。不加活性炭的溶液用作对照物。30分钟、60分钟和120分钟后,等分试样作为样本被移除。将样本离心去除碳,使用分光光度计测量样本的吸光度。结果示于图4中。
最上面的曲线代表对照物的吸收,下面的四条曲线代表加入各种类型的活性炭后的吸收。从图4可明显看出,由于溶液中活性炭的存在,表现汉撒黄颜色特征的404nm峰的吸光度显著减少。具体地讲,由于活性炭的作用,吸光度被减少五倍并差不多超过一个数量级。按吸光度减少最少至吸光度减少最多的顺序,溶液中具体的活性炭分别为MeadWestvaco SA-1500木基活性炭、木基活性炭、椰子基活性炭、和MeadWestvaco RGC木基活性炭。
活性炭由于具有高的多孔性水平而可有效地吸收汉撒黄(单偶氮)颜色。尽管未在图4中示出,已观察到增加添加到溶液中的活性炭的含量可增加汉撒黄颜色从溶液中去除的含量。因而断定如果外来试剂置于颜色薄片和涂敷制品的表面之间,其将作为清除剂材料起作用而有效地中断外来试剂的迁移。结果,由于在外来试剂进入颜色薄片之前活性炭将捕获迁移的外来试剂,所以颜色薄片将不会脱色。制备另外三十六个样本并依照上述步骤进行测试。结果示于下表1。
表1
材料 | 材料代码 | 涂层浓度或厚度 | 测试 条件 | 视觉改变的天数目标=无改变 | ΔB@384小时目标:ΔB<0.4@384小时 | ΔB *(12/1/03报 导)目标:ΔB<0.4@384小时 | 评论 |
碳/吸收剂 | |||||||
碳墨 | Nuchar PMA Lot #5(60%碳) | 未知的 | 60℃ | 1至13 | 颜色在拇指印和其它点改变 | ||
碳墨 | Nuchar PMA Lot #5(60%碳) | 4.6mg/cm2(30.0mg/in2)干碳(#1) | 60℃ | 无改变@135 | 碳涂层看起来不连续/破裂 | ||
碳墨 | Nuchar PMA Lot #5(60%碳) | 2.58mg/cm2(16.7mg/in2)干碳(#2) | 60℃ | 无改变@135 | 碳涂层看起来不连续/破裂 | ||
碳墨 | Nuchar PMA Lot #5(60%碳) | 2.46mg/cm2(15.9mg/in2)干碳(#3) | 60℃ | 无改变@135 | 碳涂层看起来不连续/破裂 | ||
碳墨 | Nuchar PMA Lot #5(60%碳) | 2.38mg/cm2(15.4mg/in2)干碳(#4) | 60℃ | 3至4 | 颜色在薄的破裂区域内改变 | ||
碳粉末 | 5μm RGC | 未知的 | 60℃ | 2至6 | |||
碳粉末 | 5μm RGC | 未知的 | 60℃ | 3至7 | |||
滑石 | Aldrich<10μm | 未知的 | 60℃ | 1 | |||
PVNO | 2∶1 Flexbond AF75:Chromabond | 20μm的共混物 | 60℃ | 10.7@339小时 | 洗涤与丙烯酸粘合剂共混的DTI聚合物 |
涂层 | |||||||
聚苯乙烯 | XU30900.51 | 74μm(2.8密耳)润湿 | 60℃ | 1至13 | 颜色时时改变。有裂痕的结构只是在载体被拿开的地方而不是在留下其余载体的地方。 | ||
PVDC(薄膜) | Polidene 33-065(ScottBader) | 10μm/15μm AF75 | 60℃ | 6.5@363小时 | PVDC共聚物,Tg=19℃,胶乳 | ||
PVDC(共混物) | 3∶1 Flexbond AF75:Polidene | 20μm的共混物 | 60℃ | 10.0@339小时 | 共混胶乳以产生通过粘合剂的曲折通道 | ||
PVDC(薄膜) | F278(Dow) | 10μm/15μm AF75 | 60℃ | 3.8@365小时 | PVDC共聚物,Tg>室温,溶剂浇铸 | ||
PVDC(薄膜) | F310(Dow) | 10μm/15μm AF75 | 60℃ | 0.57@365小时 | PVDC:AN共聚物,Tg>室温,溶剂浇铸 | ||
薄膜 | |||||||
PurplePrint PakDecorate&12.7μm(0.5密耳)XC003S3506 | Purple Decorate:9/6/01制造#5A 1%;S3506 4-5/03制造 | 12.7μm(0.5密耳)S3506粘合剂添加到12.7μm(0.5密耳)MetPET(加上未知厚度的粘合剂、白灰罩面、颜色和清漆) | 60℃ | 无改变@240 | |||
OPP | CPPD薄膜架 | 20.32μm(0.8密耳) | 60℃ | 2至5 | |||
HDPE | CPPD薄膜架 | 12.7μm(0.5密耳) | 60℃ | 1 | |||
Mylar | CPPD薄膜架 | 12.7μm(0.5密耳) | 60℃ | 无改变@130 | |||
Mylar | Dupont Teijin薄膜(854型) | 48 gauge厚 | 60℃ | 0.39@340小时,0.28@436小时 | ΔB*=0.76@3516小时 | ||
Mylar | Dupont Teijin薄膜(854型) | 48 gauge厚 | 49℃ | 无改变 | 0.22@360小时,0.19@408小时 | ΔB*=0.38@3264小时 | |
Mylar | Dupont Teijin薄膜(854型) | 48 gauge厚 | 38℃ | 无改变 | 0.11@360小时,0.19@408小时 | ΔB*=0.32@3264小时 |
纸张 | |||||||
感热纸 | 来自SJ-301 | 50.8μm(2密耳) | 60℃ | 24小时后呈褐色 | 886小时后结束;ΔB*=4.57 | ||
Bronco纸 | 来自Desk Cube | 101.6μm(4密耳) | 60℃ | 0.26@334小时,0.43@502小时 | ΔB*=0.7@1582小时 | ||
棕色绉纸 | 来自Bruce | 127μm(5密耳) | 60℃ | 0.26@334小时,0.42@502小时 | ΔB*=0.7@1582小时 | ||
复印纸 | 来自打印机 | 101.6μm(4密耳) | 60℃ | 0.31@334小时,0.53@502小时 | ΔB*=0.8@1582小时 | ||
滤纸 | Whatman Qualitative No.1 | 177.8μm(7密耳) | 60℃ | 0.56@334小时,0.6@502小时 | ΔB*=1.1@1582小时 | ||
可供选择的粘合剂 | |||||||
丙烯酸胶乳 | Flexbond AF 75 | 15μm | 60℃ | 11@384小时 | |||
丙烯酸胶乳 | Flexbond AF 75 | 15μm | 60℃ | 10.9@384小时 | |||
丙烯酸胶乳 | Flexbond AF 75 | 50μm | 60℃ | 9.3@54小时 | |||
丙烯酸胶乳 | Flexbond AF 75 | 100μm | 60℃ | 9.8@54小时 | |||
丙烯酸胶乳 | Flexbond AF 75 | 200μm | 60℃ | 9.5@54小时 | |||
PIB | MA 24A | 45μm | 60℃ | 10.2@389小时 | |||
丙烯酸 | HY3 | 45μm | 60℃ | 10.1@389小时 | |||
丙烯酸 | K294 | 15μm | 60℃ | 10.0@172小时 | |||
丙烯酸 | PS 8120 | 15μm | 60℃ | 9.0@172小时 | |||
丙烯酸 | PS 8211 | 15μm | 60℃ | 7.8@172小时 |
在发明详述中引用的所有文献的相关部分均引入本文以供参考;任何文献的引用并不可理解为是对其作为本发明的现有技术的认可。
尽管已用具体实施方案来说明和描述了本发明,但对于本领域的技术人员显而易见的是,在不背离本发明的精神和保护范围的情况下可作出许多其它的变化和修改。因此有意识地在附加的权利要求书中包括本发明范围内的所有这些变化和修改。
Claims (5)
1.一种用来将可视觉感知的颜色效果传送到包含外来试剂的表面的制品,所述制品包括:
可视觉感知的颜色效果的薄片;
由所述薄片负载的键合剂,所述键合剂能够将所述薄片粘合到所述表面上;
可移除地连接到所述薄片上的可分离衬料;和
可有效地减弱所述外来试剂从所述表面向所述薄片的转移的阻挡层,其中所述阻挡层选自镀玻璃的聚合物、镀陶瓷的聚合物、包含硅酸钠的组合物、阴离子层和阳离子层中的至少一个、纳米复合物,以及它们的组合。
2.如权利要求1所述的制品,其中所述键合剂和所述薄片之一包括所述阻挡层。
3.如权利要求1所述的制品,其中所述阻挡层设置在所述薄片和所述键合剂之间。
4.如权利要求1所述的制品,所述制品还包括:
聚合物层、纤维素层、无纺材料和金属处理薄膜中的至少一个,其与所述阻挡层共同作用以减弱所述外来试剂从所述表面向所述薄片的转移。
5.如权利要求1所述的制品,所述制品还包括:
包括所述阻挡层的连接层,所述连接层设置在所述薄片和所述键合剂之间或设置在所述薄片和所述阻挡层之间。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/367,611 | 2003-02-14 | ||
US10/367,611 US20040161564A1 (en) | 2003-02-14 | 2003-02-14 | Dry paint transfer laminate |
US10/457,826 | 2003-06-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1747831A true CN1747831A (zh) | 2006-03-15 |
Family
ID=32850013
Family Applications (8)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2004800049421A Pending CN1753733A (zh) | 2003-02-14 | 2004-02-11 | 制备干燥油漆转移层压材料的挤出方法 |
CNB200480009775XA Expired - Fee Related CN100566991C (zh) | 2003-02-14 | 2004-02-11 | 干涂料转移层压材料 |
CNA2004800071317A Pending CN1761575A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
CNA2004800071232A Pending CN1761577A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
CNA2004800037744A Pending CN1747831A (zh) | 2003-02-14 | 2004-02-13 | 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 |
CNA2004800076359A Pending CN1761578A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
CNA2004800037759A Pending CN1756671A (zh) | 2003-02-14 | 2004-02-13 | 用于施用到一个表面上的制品及其方法 |
CNA2004800076363A Pending CN1761579A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
Family Applications Before (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2004800049421A Pending CN1753733A (zh) | 2003-02-14 | 2004-02-11 | 制备干燥油漆转移层压材料的挤出方法 |
CNB200480009775XA Expired - Fee Related CN100566991C (zh) | 2003-02-14 | 2004-02-11 | 干涂料转移层压材料 |
CNA2004800071317A Pending CN1761575A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
CNA2004800071232A Pending CN1761577A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2004800076359A Pending CN1761578A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
CNA2004800037759A Pending CN1756671A (zh) | 2003-02-14 | 2004-02-13 | 用于施用到一个表面上的制品及其方法 |
CNA2004800076363A Pending CN1761579A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
Country Status (3)
Country | Link |
---|---|
US (7) | US20040161564A1 (zh) |
JP (1) | JP2009006713A (zh) |
CN (8) | CN1753733A (zh) |
Families Citing this family (94)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7709070B2 (en) | 2001-12-20 | 2010-05-04 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US7316832B2 (en) * | 2001-12-20 | 2008-01-08 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US20060165979A1 (en) * | 2002-12-13 | 2006-07-27 | Kinsey Von A | Articles and methods for applying color on surfaces |
JP4290700B2 (ja) * | 2003-02-14 | 2009-07-08 | ザ プロクター アンド ギャンブル カンパニー | 表面上に色彩を適用する耐変色性物品、及び表面上に色彩を適用する物品において変色を低減する方法 |
US20040161564A1 (en) * | 2003-02-14 | 2004-08-19 | Truog Keith L. | Dry paint transfer laminate |
US20050196607A1 (en) * | 2003-06-09 | 2005-09-08 | Shih Frank Y. | Multi-layer dry paint decorative laminate having discoloration prevention barrier |
US20040247837A1 (en) * | 2003-06-09 | 2004-12-09 | Howard Enlow | Multilayer film |
US7332046B2 (en) * | 2003-09-26 | 2008-02-19 | Eastman Chemical Company | Methods of blocking stains on a substrate to be painted, and composites suitable for use in such methods |
ITVR20040014A1 (it) * | 2004-02-04 | 2004-05-04 | Bruno Zanella | Procedimento per l'ottenimento di una pellicola e/o film plastico, realizzata in continuo, utilizzabile nella rifinitura con stampa per pellami sintetici, o qualsiasi altro supporto. |
KR101125678B1 (ko) * | 2004-02-06 | 2012-03-28 | 롬 앤드 하스 일렉트로닉 머트어리얼즈, 엘.엘.씨. | 개선된 이미지화 조성물 및 방법 |
KR100803013B1 (ko) * | 2004-02-13 | 2008-02-14 | 더 프록터 앤드 갬블 캄파니 | 표면에 인가되는 용품 및 그 방법 |
US20050266194A1 (en) * | 2004-05-29 | 2005-12-01 | Peters Daniel F | Peelable laminate and process of making the same |
US20070264457A1 (en) * | 2004-08-26 | 2007-11-15 | Kimoto Co., Ltd. | Material for Decoration |
US20060068213A1 (en) * | 2004-09-29 | 2006-03-30 | O'brien Kevin | Decorative laminate assembly with improved tie sheet and bridging agent |
PL1830790T3 (pl) * | 2004-12-29 | 2018-08-31 | Avon Products, Inc. | Naklejki na paznokcie mające warstwą górną z usieciowanym polimerem |
US20060177649A1 (en) * | 2005-02-07 | 2006-08-10 | Clark Mark D | Methods of blocking stains on a substrate to be painted, and composites suitable for use in such methods |
US7758949B1 (en) | 2005-02-08 | 2010-07-20 | Sloan Donald D | Thermal reactive ink transfer system |
US20060191654A1 (en) * | 2005-02-25 | 2006-08-31 | John Theisen | Paper product and method for manufacturing |
JP2006247893A (ja) * | 2005-03-08 | 2006-09-21 | Nissha Printing Co Ltd | 転写フィルム、加飾フィルムおよび加飾品の製造方法並びに加飾品 |
US20060216453A1 (en) * | 2005-03-23 | 2006-09-28 | General Atomics | Durable pigmented film |
JP2007092030A (ja) * | 2005-08-05 | 2007-04-12 | Rohm & Haas Electronic Materials Llc | 改善された不透明なコーティング |
US8545959B2 (en) | 2005-10-21 | 2013-10-01 | Entrotech Composites, Llc | Composite articles comprising protective sheets and related methods |
US20070148358A1 (en) * | 2005-11-08 | 2007-06-28 | Worthen Industries | Apparatus and method for manufacturing surface protection film with a topcoat |
US7854985B2 (en) * | 2005-11-18 | 2010-12-21 | Soliant Llc | Decorative paint film laminate |
US20070215271A1 (en) * | 2006-03-02 | 2007-09-20 | Mcclintic Shawn A | Covering article and associated method |
JP4845614B2 (ja) * | 2006-07-06 | 2011-12-28 | 日東電工株式会社 | 剥離ライナー、粘着テープ及び粘着テープ巻回体 |
US20090250164A1 (en) * | 2006-10-03 | 2009-10-08 | The Procter & Gamble Company | Methods of Making Articles for Applying Color on Surfaces |
US20080078498A1 (en) * | 2006-10-03 | 2008-04-03 | Zeik Douglas B | Articles and methods for applying color on surfaces |
US20090252937A1 (en) * | 2006-10-03 | 2009-10-08 | The Procter & Gamble Company | Articles for Applying Color on Surfaces |
DE102006047738A1 (de) * | 2006-10-06 | 2008-04-10 | Tesa Ag | Hitzeaktivierbares Klebeband insbesondere für die Verklebung von elektronischen Bauteilen und Leiterbahnen |
US20080087370A1 (en) * | 2006-10-13 | 2008-04-17 | Custom Adhesive Products, Llc | Splicing Tape |
US20080108734A1 (en) * | 2006-11-03 | 2008-05-08 | Smith Dennis C | Ionomer pigmentation |
US20080176090A1 (en) * | 2006-12-19 | 2008-07-24 | Elia Andri E | Composite thermoplastic articles |
US20080176079A1 (en) * | 2006-12-19 | 2008-07-24 | Elia Andri E | Process for coating vehicle exterior parts made from thermoplastic composite articles |
US8263213B2 (en) * | 2006-12-19 | 2012-09-11 | E I Du Pont De Nemours And Company | Painted composite thermoplastic articles |
US7841146B2 (en) * | 2007-01-09 | 2010-11-30 | Henkel Ag & Co. Kgaa | Product and method for concealing joints |
FR2912153B1 (fr) * | 2007-02-02 | 2009-04-17 | Bostik S A Sa | Composition adhesive pour etiquette auto-adhesive decollable |
FR2918069B1 (fr) * | 2007-06-29 | 2009-09-04 | Bostik S A Sa | Hmpsa pour etiquette auto-adhesive decollable |
CN101796120B (zh) * | 2007-07-19 | 2014-11-05 | 艾梅利斯塔尔克美国股份有限公司 | 有机硅涂料、制备有机硅涂布制品的方法以及该涂布制品 |
US20090061221A1 (en) * | 2007-08-07 | 2009-03-05 | Saint-Gobain Technical Fabrics | Composite tack film for asphaltic paving, method of paving, and process for making a composite tack film for asphaltic paving |
US10035932B2 (en) | 2007-09-25 | 2018-07-31 | Aero Advanced Paint Technology, Inc. | Paint replacement films, composites therefrom, and related methods |
JP2009166478A (ja) * | 2007-12-17 | 2009-07-30 | Pilot Ink Co Ltd | 変色性積層体 |
US10981371B2 (en) | 2008-01-19 | 2021-04-20 | Entrotech, Inc. | Protected graphics and related methods |
US20090220768A1 (en) * | 2008-02-29 | 2009-09-03 | Hallmark Cards, Incorporated | Repositionable self-adhesive giftwrap |
US8551279B2 (en) * | 2008-03-25 | 2013-10-08 | 3M Innovative Properties Company | Multilayer articles and methods of making and using the same |
BRPI0910076A2 (pt) * | 2008-03-25 | 2015-12-29 | 3M Innovative Properties Co | compósitos para filme de pintura e métodos para a produção dos mesmos |
US20100096062A1 (en) * | 2008-09-16 | 2010-04-22 | Serigraph, Inc. | Supported Article for Use in Decorating a Substrate |
US9682540B2 (en) * | 2009-02-25 | 2017-06-20 | Avery Dennison Corporation | Method for making multi-layer print media by extrusion coating |
US8367176B1 (en) * | 2009-03-13 | 2013-02-05 | Lolliprops, Inc. | Repositionable, self-adhesive wallpaper |
US20100252187A1 (en) * | 2009-04-02 | 2010-10-07 | Jonathan Javier Calderas | Methods of Making Customized Articles for Applying Color on Surfaces |
DE102009026548A1 (de) * | 2009-05-28 | 2011-03-24 | Henkel Ag & Co. Kgaa | Klebefolie oder Klebeband auf Basis von Epoxiden |
FR2946280B1 (fr) * | 2009-06-03 | 2018-01-05 | Corso Magenta | Article en feuille pour application sur une paroi a decorer, procede de fabrication et procede d'application associes |
JP5609340B2 (ja) * | 2009-08-10 | 2014-10-22 | セイコーエプソン株式会社 | 転写媒体製造方法、転写媒体 |
FR2950299B1 (fr) * | 2009-09-22 | 2011-10-07 | Soc Nat Des Chemins De Fer Francais Sncf | Revetement decoratif avec adhesif integre pour vehicule de transport |
DE102010014381A1 (de) * | 2010-04-01 | 2011-10-06 | Karl Wörwag Lack- Und Farbenfabrik Gmbh & Co. Kg | Substrate mit mehrfarbiger Lackierung und ihre Herstellung |
US8742010B2 (en) * | 2010-04-09 | 2014-06-03 | Bayer Materialscience Llc | Two-component waterborne polyurethane coatings |
US8668967B2 (en) | 2011-03-15 | 2014-03-11 | Zoom Creative Products, Llc | Embellishment transfer delivery system |
US9421736B2 (en) | 2011-06-17 | 2016-08-23 | Sonoco Development, Inc. | Hybrid pressure sensitive adhesive |
CN102283491B (zh) * | 2011-06-28 | 2013-03-13 | 廖静宜 | 一种凝胶指甲贴饰生产工艺 |
DE102011085223A1 (de) * | 2011-10-26 | 2013-05-02 | Tesa Se | Biobasierte Naturkautschukmasse und deren Verwendung |
JP2013237214A (ja) | 2012-05-16 | 2013-11-28 | Three M Innovative Properties Co | 装飾シート |
JP2013244668A (ja) * | 2012-05-25 | 2013-12-09 | Daikyo Seiko Ltd | ゴム成形品 |
CN103707585B (zh) * | 2012-09-28 | 2016-11-16 | 广东华润涂料有限公司 | 多层层叠物及其制备方法 |
US9950559B2 (en) | 2012-09-28 | 2018-04-24 | Valspar Sourcing, Inc. | Multilayered laminate and process for preparing the same |
US20140278277A1 (en) | 2013-03-15 | 2014-09-18 | Premier Protection Holdings, LLC | Protective film for automotive surfaces |
US9573164B2 (en) * | 2013-03-15 | 2017-02-21 | Akzo Nobel Coatings International B.V. | Dry primer film composite and use thereof |
WO2015009271A1 (en) | 2013-07-15 | 2015-01-22 | Hewlett-Packard Development Company, L.P. | Printable medium |
CN103360570A (zh) * | 2013-07-31 | 2013-10-23 | 常德市武陵金德镭射科技有限公司 | 水性聚氨酯及其制备方法与水性转移涂料 |
CN103512832B (zh) * | 2013-10-09 | 2015-08-19 | 广东生益科技股份有限公司 | 检测压板时胶水流动状态的方法 |
CN106459691A (zh) * | 2014-03-21 | 2017-02-22 | 艾利丹尼森公司 | 无面标签以及相关系统和方法 |
US9683143B2 (en) * | 2014-12-24 | 2017-06-20 | United States Gypsum Company | Joint finishing adhesive |
WO2016118293A1 (en) * | 2015-01-23 | 2016-07-28 | Hastings Jeffrey Logan | Paint tape device and methods of treating painted surfaces |
ES2774692T3 (es) | 2015-09-04 | 2020-07-22 | Toppan Printing Co Ltd | Lámina decorativa |
WO2017180558A1 (en) * | 2016-04-11 | 2017-10-19 | Tremco Incorporated | Self-adhered sheet installation devices and methods of use |
IL262529B2 (en) * | 2016-05-30 | 2023-06-01 | Landa Labs 2012 Ltd | A method for creating a multi-layered product |
CN106281078B (zh) * | 2016-08-11 | 2019-06-25 | 苏州柯创电子材料有限公司 | 一种石墨复合型单面胶带及其制备工艺 |
CN106189911B (zh) * | 2016-08-11 | 2019-05-28 | 苏州柯创电子材料有限公司 | 一种高强度胶带及其制备工艺 |
US9738796B1 (en) * | 2016-09-07 | 2017-08-22 | Usg Interiors, Llc | Acoustically transparent coating |
US20190136095A1 (en) | 2016-09-20 | 2019-05-09 | Aero Advanced Paint Technology, Inc. | Paint Film Appliques with Reduced Defects, Articles, and Methods |
JP7006191B2 (ja) * | 2016-11-29 | 2022-01-24 | 凸版印刷株式会社 | 化粧シート及び化粧シートの製造方法 |
WO2018136034A1 (en) | 2017-01-17 | 2018-07-26 | Hewlett-Packard Development Company, L.P. | Printable medium |
DE102017101595B3 (de) * | 2017-01-27 | 2018-05-30 | Leonhard Kurz Stiftung & Co. Kg | Transferfolie, deren Verwendung und Verfahren zur Herstellung einer Transferfolie sowie Verfahren zur Herstellung eines mit einer Transferlage einer Transferfolie dekorierten Spritzgussartikels |
CA3050742C (en) * | 2017-02-07 | 2021-10-26 | Shurtape Technologies, Llc | Digital printed duct tape |
US9855724B1 (en) | 2017-02-10 | 2018-01-02 | Custom Adhesive Products Llc | Splice tape with internal, interlayer separation interface |
WO2018183663A1 (en) | 2017-03-30 | 2018-10-04 | Novelis Inc. | Surface roughening of polymer films |
CN111201137B (zh) | 2017-10-10 | 2022-11-01 | 东丽株式会社 | 膜 |
WO2019108439A2 (en) * | 2017-11-28 | 2019-06-06 | Rubin Eliot I | Multi-layered decorative wrap and method of use of the same |
CN108656825B (zh) * | 2018-05-15 | 2022-02-08 | 山东京宏智能科技股份有限公司 | 一种双面压花pcm彩色涂层钢板及其生产工艺 |
CN109116582B (zh) * | 2018-08-24 | 2020-02-18 | 上海康耐特光学有限公司 | 光致变色树脂眼镜片及其制造方法 |
US20210221157A1 (en) * | 2020-01-21 | 2021-07-22 | Ready, Set, Co., LLC | Multiple layered print structure and apparatus for fabric or cloth |
US20210292593A1 (en) * | 2020-02-27 | 2021-09-23 | Ppg Industries Ohio, Inc. | Coating System |
CN112480796A (zh) * | 2020-12-17 | 2021-03-12 | 广东花王涂料有限公司 | 一种木器清漆及其制备方法 |
WO2022169832A1 (en) * | 2021-02-02 | 2022-08-11 | Brewster Home Fashions Llc | Repositionable peel-and-stick embellished wall coverings |
CN114106619B (zh) * | 2021-12-08 | 2023-03-24 | 固克节能科技股份有限公司 | 一种消光浆及其制备方法和应用 |
Family Cites Families (336)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US26932A (en) * | 1860-01-24 | Richard a | ||
US37479A (en) * | 1863-01-20 | Improvement in axles | ||
US752498A (en) * | 1904-02-16 | Frederick william witte | ||
US92420A (en) * | 1869-07-13 | Improvement in cane-scraper | ||
US126529A (en) * | 1872-05-07 | Improvement in type-wheels for printing-telegraphs | ||
US179372A (en) * | 1876-06-27 | Improvement in valves for brass musical instruments | ||
US1365715A (en) | 1919-06-09 | 1921-01-18 | Cornell Wood Products Co | Sizing composition |
US2746893A (en) * | 1952-12-03 | 1956-05-22 | Meyercord Co | Dry strip transfer |
US3152030A (en) | 1959-06-15 | 1964-10-06 | Mystik Tape Inc | Fused poly-laminate adhesive tape and method of making same |
GB967405A (en) | 1962-06-15 | 1964-08-19 | Ernest Leslie Whick | Improvements relating to an appliance for pasting and applying paper directly from the roll to ceiling or walls |
US3301741A (en) | 1963-09-11 | 1967-01-31 | Minnesota Mining & Mfg | Adhesive sheet and method of making |
US3331729A (en) | 1963-02-14 | 1967-07-18 | Minnesota Mining & Mfg | Adhesive bonding method and product |
US3314838A (en) * | 1964-08-26 | 1967-04-18 | Minnesota Mining & Mfg | Pressure sensitive adhesives containing hollow spheroidal particles |
GB1232971A (zh) | 1967-04-28 | 1971-05-26 | ||
US3900645A (en) | 1967-12-11 | 1975-08-19 | Morgan Adhesives Co | Scored adhesive laminate |
US3896249A (en) | 1968-01-19 | 1975-07-22 | Johnson Matthey Co Ltd | Self-adhesive transfers |
US3671236A (en) * | 1968-03-18 | 1972-06-20 | Minnesota Mining & Mfg | Presensitized color-proofing sheet |
US3640791A (en) | 1969-02-19 | 1972-02-08 | Richard Rosenheim | Process of preparing and applying an improved painting device |
US3616192A (en) | 1970-02-04 | 1971-10-26 | Riegel Paper Corp | Decorative polyvinyl fluoride laminations |
US3654044A (en) * | 1970-11-10 | 1972-04-04 | Toyo Plywood Co Ltd | Decorative overlay paper covered plywood and process of manufacturing the same |
US3743086A (en) | 1971-02-05 | 1973-07-03 | Brady Co W H | Adhesive tape dispenser package |
US4037008A (en) | 1971-05-17 | 1977-07-19 | Photo-Lith International | Transfer printing process and article |
US3741786A (en) | 1971-05-28 | 1973-06-26 | Avery Products Corp | Transfer tape having non-contiguous pressure sensitive adhesive patterns |
US3916046A (en) | 1971-09-13 | 1975-10-28 | Minnesota Mining & Mfg | Decorative adhesive laminate, for heat-pressure application to substrates |
US3666516A (en) * | 1971-10-12 | 1972-05-30 | Richard E Dunning | Hot stamp tape |
US4026648A (en) * | 1971-12-17 | 1977-05-31 | Canon Kabushiki Kaisha | Cleaning device for use in electrophotographic copying apparatus |
US3804700A (en) * | 1972-05-10 | 1974-04-16 | Rohm & Haas | Decorative laminate |
US4094690A (en) | 1972-08-07 | 1978-06-13 | Imperial Chemical Industries Limited | Liquid composition |
JPS4939997A (zh) | 1972-08-26 | 1974-04-15 | ||
US3826701A (en) * | 1972-10-31 | 1974-07-30 | Us Army | Controllable heat sealing process for optimum seal strength |
DE2254430A1 (de) | 1972-11-07 | 1974-05-09 | Rolf Herzog | Vorfabrizierte lackierung, vornehmlich fuer kraftfahrzeuge |
US3900644A (en) | 1973-03-20 | 1975-08-19 | United Merchants & Mfg | Heat resistant laminate |
US3907974A (en) * | 1973-11-08 | 1975-09-23 | Dennison Mfg Co | Curable decorating systems for glass or metal containers |
US3907628A (en) | 1973-12-20 | 1975-09-23 | United Merchants & Mfg | Applicator for self-adhesive sheet material |
US3969181A (en) | 1974-06-03 | 1976-07-13 | Minnesota Mining And Manufacturing Company | Transfer adhesive dispensing device |
US3933702A (en) * | 1974-07-10 | 1976-01-20 | National Starch And Chemical Corporation | Aqueous release coating compositions for pressure sensitive adhesives |
GB1493407A (en) | 1974-12-16 | 1977-11-30 | Ici Ltd | Decorative sheet material |
US4076895A (en) * | 1976-05-05 | 1978-02-28 | Champion International Corporation | Transparent multi-layered film and processes therefor |
CA1106993A (en) * | 1976-05-26 | 1981-08-11 | Martin M. Sackoff | Method for making a pressure sensitive adhesive coated laminate |
US4118541A (en) | 1976-11-03 | 1978-10-03 | Formica Corporation | Release sheet of a coated cellulose paper |
US4068033A (en) * | 1976-11-17 | 1978-01-10 | Commercial Decal, Inc. | Heat-releasable decalcomanias and adhesive composition therefor |
US4369157A (en) * | 1977-04-11 | 1983-01-18 | Dri-Print Foils, Inc. | Method of automatically decorating articles as they are in-mold formed automatically |
US4376159A (en) * | 1977-05-09 | 1983-03-08 | Keuffel & Esser Company | Method of preparing matte finish color-proofing surprints |
US4248762A (en) * | 1977-07-18 | 1981-02-03 | Stauffer Chemical Company | Pressure sensitive products with decorative appearance |
US4248917A (en) * | 1977-07-18 | 1981-02-03 | Stauffer Chemical Company | Pressure sensitive products with decorative appearance |
GB2001912B (en) * | 1977-08-08 | 1982-03-03 | Lake E | Wallpaper applicator |
DE2747978C3 (de) * | 1977-10-26 | 1981-06-04 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zum Herstellen einer endlosen Verbundbahn |
DE2800635C2 (de) * | 1978-01-07 | 1985-03-14 | Fa. Leonhard Kurz, 8510 Fürth | Prägefolie, insbesondere Heißprägefolie |
US4175156A (en) | 1978-05-19 | 1979-11-20 | Usm Corporation | Composite film adhesive |
DE2844397A1 (de) * | 1978-10-12 | 1980-04-30 | Basf Ag | Verbundschichtstoffe aus gefuellten polyolefinen und einer thermoplastischen dekorschicht sowie deren herstellung und verwendung |
US4258096A (en) * | 1978-11-09 | 1981-03-24 | Sheldahl, Inc. | Composite top membrane for flat panel switch arrays |
US4241129A (en) | 1978-12-15 | 1980-12-23 | The Dow Chemical Company | Delamination resistant multilayer metal/polymer composites |
US4235657A (en) | 1979-02-12 | 1980-11-25 | Kimberly Clark Corporation | Melt transfer web |
US4232077A (en) | 1979-02-22 | 1980-11-04 | Fritz Meisel | Hot-stamping film, and process and apparatus for its manufacture |
US4298647A (en) | 1979-07-16 | 1981-11-03 | Clopay Corporation | Cross-tearable decorative sheet material |
DE2948688A1 (de) | 1979-12-04 | 1981-06-11 | Heinz Cossonay-Ville Sovilla-Brulhart | Isoliertapete |
DE3039721A1 (de) | 1980-10-21 | 1982-05-27 | Wacker-Chemie GmbH, 8000 München | Verfahren zur herstellung von ueberzuegen |
NL8005935A (nl) * | 1980-10-29 | 1982-05-17 | Nordipa A G | Overdraagbaar lakvel, alsmede werkwijze voor het vervaardigen daarvan. |
US4396157A (en) * | 1981-03-17 | 1983-08-02 | Elstat Limited | Nozzle for spraying apparatus |
US4377050A (en) * | 1981-06-01 | 1983-03-22 | Renholts Roy J | Laminated tape for imprinting |
US4376151A (en) * | 1981-06-29 | 1983-03-08 | Moore Business Forms, Inc. | Pressure threshold adhesive |
JPS5813682A (ja) | 1981-07-16 | 1983-01-26 | Nippon Carbide Ind Co Ltd | 感圧接着剤層 |
US4517044A (en) * | 1981-11-18 | 1985-05-14 | Advanced Graphic Technology | Dry transfer decal and method of manufacture |
JPS58145490A (ja) | 1982-02-19 | 1983-08-30 | Sumitomo Suriim Kk | マ−キング用材料 |
US4499130A (en) * | 1982-03-01 | 1985-02-12 | Carprotec, Inc. | Temporary strippable protective laminate |
EP0103407B1 (en) | 1982-08-19 | 1986-06-18 | Minnesota Mining And Manufacturing Company | Composite decorative article |
EP0103344B1 (en) | 1982-09-07 | 1988-10-19 | Energy Sciences Inc. | Process of in-line coating and decorative layer lamination with panel board material and the like employing electron-beam irradiation, and decorated panel produced thereby |
US4650587A (en) * | 1982-09-09 | 1987-03-17 | Akzona Incorporated | Ammonia scavenger |
EP0103458A1 (en) | 1982-09-14 | 1984-03-21 | Reed International P.L.C. | Wallcoverings in roll form |
US4515877A (en) | 1982-11-27 | 1985-05-07 | Basf Aktiengesellschaft | Image-recording materials and image-recording carried out using these to produce an optical mask |
US4550683A (en) | 1984-01-23 | 1985-11-05 | Jones Wallace R | Sheet construction and method |
US4564406A (en) * | 1984-02-21 | 1986-01-14 | Solar-Kist Corporation | Method of and means for combination design transfer and application of heat reactivatable adhesive |
US4545090A (en) | 1984-09-24 | 1985-10-08 | Redmond Daniel R | Glass filled plastic hinge |
US4650704A (en) * | 1985-03-06 | 1987-03-17 | Stik-Trim Industries, Inc. | Self-adhesive wall covering or the like and method of making same |
US4555441A (en) | 1985-03-06 | 1985-11-26 | Stik-Trim Industries, Incorporated | Self-adhesive wall covering or the like and method of making same |
US4737225A (en) * | 1985-06-12 | 1988-04-12 | The D. L. Auld Company | Method of making a substrateless decorative article |
US4661182A (en) | 1985-07-31 | 1987-04-28 | Color Communications, Inc. | Method and composition for repairing minor surface damage to coated surfaces |
US4598020A (en) | 1985-08-16 | 1986-07-01 | Inmont Corporation | Automotive paint compositions containing pearlescent pigments and dyes |
JPH0626708B2 (ja) | 1985-09-10 | 1994-04-13 | 関西ペイント株式会社 | 複合塗膜形成法 |
DE3533136A1 (de) | 1985-09-17 | 1987-03-26 | Hoechst Ag | Trennfolie zur herstellung oberflaechlich strukturierter, dekorativer schichtstoffplatten |
DE3543777A1 (de) | 1985-12-11 | 1987-06-19 | Hammel Geb Messemer Christel | Verfahren zur herstellung von urkundensicheren plaketten und insbesondere nach diesem verfahren hergestellte urkundensichere plakette zur dauerhaften aufbringung auf die oberflaeche eines kennzeichenschildes, eines geraetegehaeuses oder werkstueckes, eines schriftstueckes oder dergleichen |
CA1319862C (en) * | 1986-01-14 | 1993-07-06 | Bruce E. Johnson | Composite useful for paint transfer and method of use and preparation thereof |
AT386564B (de) | 1986-02-18 | 1988-09-12 | Isovolta | Dekorative verbundfolie fuer oberflaechenbeschichtungen, deren verwendung in einem mehrschichtverbund, sowie verfahren zum herstellen eines solchen mehrschichtverbundes |
NO871019L (no) | 1986-03-17 | 1987-09-18 | Deltaglass Sa | Laminert sikkerhetsglass. |
US4919994A (en) * | 1986-04-01 | 1990-04-24 | Minnesota Mining And Manufacturing Company | Dry transfer graphics article and methods of preparation and use thereof |
US4759441A (en) | 1986-10-14 | 1988-07-26 | Leurck William J | Combination tool for use in hanging wallpaper |
US5342666A (en) * | 1986-10-28 | 1994-08-30 | Rexham Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US4786537A (en) | 1986-10-30 | 1988-11-22 | Minnesota Mining And Manufacturing Company | Self-weeding dry transfer article |
GB8625997D0 (en) | 1986-10-30 | 1986-12-03 | Cotton Colne Ltd John | Manufacture of laminated elements |
US4711682A (en) | 1986-11-10 | 1987-12-08 | Christian Barbe | Wallpaper applicator devices and method for its use |
US4783354A (en) | 1986-12-15 | 1988-11-08 | Coated Sales, Inc. | Adherable, yet removable sheet material |
US6835267B1 (en) * | 1987-03-27 | 2004-12-28 | Avery Dennison Corporation | Dry paint transfer process and product |
US5707697A (en) * | 1987-03-27 | 1998-01-13 | Avery Dennison Corporation | Dry paint transfer product having high DOI automotive paint coat |
GB2206843B (en) * | 1987-07-02 | 1991-03-13 | Crown Decorative Prod Ltd | Paste-the-wall wallcoverings and method of making |
US5000810A (en) * | 1987-08-10 | 1991-03-19 | Custom Laminations, Inc. | Decorative or printed laminates and methods for making same |
US4806184A (en) * | 1987-08-31 | 1989-02-21 | Shannon Brian P | Wallpaper applicator |
JPH01154740A (ja) | 1987-12-11 | 1989-06-16 | Shin Etsu Chem Co Ltd | 粘着性構造体 |
US5135798A (en) | 1987-12-03 | 1992-08-04 | Pelikan Aktiengesellschaft | Multilayer, flexible transfer strip |
US4871618A (en) | 1987-12-04 | 1989-10-03 | Shell Oil Company | Laminar structures prepared with polyketone structural adhesives |
US4902557A (en) * | 1988-01-25 | 1990-02-20 | E. I. Du Pont De Nemours And Company | Thermoplastic polyolefin composite structure |
US4854610A (en) | 1988-02-10 | 1989-08-08 | Bertek, Inc. | Method of making laminated articles and articles made therefrom |
US5075149A (en) | 1988-10-26 | 1991-12-24 | Owens R Larry | Molded hole repair patch and method of manufacture |
US5045569A (en) | 1988-11-30 | 1991-09-03 | Minnesota Mining And Manufacturing Company | Hollow acrylate polymer microspheres |
US5073457A (en) | 1988-12-01 | 1991-12-17 | Minnesota Mining And Manufacturing Company | Repositionable adhesive |
JPH02160536A (ja) | 1988-12-14 | 1990-06-20 | Dainippon Printing Co Ltd | 光輝性化粧板の製造法 |
US5045386A (en) | 1989-02-01 | 1991-09-03 | Minnesota Mining And Manufacturing Company | Pressure-sensitive film composite having improved adhesion to plasticized vinyl substrates |
DE3905790A1 (de) | 1989-02-24 | 1990-09-06 | Bayer Ag | Mehrschichten-verbundwerkstoff |
US5266372A (en) | 1989-04-24 | 1993-11-30 | Nitto Denko Corporation | Fixing tape |
JP2533174Y2 (ja) | 1989-04-24 | 1997-04-23 | 日東電工株式会社 | オムツ用粘着テ−プ |
AU598719B1 (en) | 1989-05-01 | 1990-06-28 | Gencorp Inc. | Thermoformable decorative rigid lamina for interiors of transportation vehicles |
US5084317A (en) * | 1989-05-08 | 1992-01-28 | Avery Dennison Corporation | Pressure-sensitive adhesive release liner |
GB8911354D0 (en) * | 1989-05-17 | 1989-07-05 | Mono Web Ltd | Improvements relating to coating of substrates |
DE4091501T (zh) | 1989-08-31 | 1991-10-10 | ||
US5203941A (en) * | 1989-10-19 | 1993-04-20 | Avery Dennison Corporation | Process for manufacturing plastic siding panels with outdoor weatherable embossed surfaces |
ATE155076T1 (de) | 1989-10-19 | 1997-07-15 | Avery Dennison Corp | Verfahren zur herstellung von platten aus kunststoff mit aeusseren wetterfesten gepraegten und aeussere wetterfeste kunststoffplatten |
US5192612A (en) | 1989-10-31 | 1993-03-09 | Avery International Corporation | Positionable-repositionable pressure-sensitive adhesive |
US5141790A (en) * | 1989-11-20 | 1992-08-25 | Minnesota Mining And Manufacturing Company | Repositionable pressure-sensitive adhesive tape |
US5034269A (en) | 1990-04-04 | 1991-07-23 | Wheeler Richard W | Process for the manufacture of paint-coated film and product produced therefrom |
US5244524A (en) | 1990-04-09 | 1993-09-14 | Brother Kogyo Kabushiki Kaisha | Printing method for thermally transferring image section of print sheet to image receiving member |
US5229207A (en) | 1990-04-24 | 1993-07-20 | Minnesota Mining And Manufacturing Company | Film composite having repositionable adhesive by which it can become permanently bonded to a plasticized substrate |
JP2916211B2 (ja) | 1990-05-17 | 1999-07-05 | ミネソタ マイニング アンド マニユフアクチユアリング カンパニー | Epdmゴム基材用装飾材料 |
US5114514A (en) * | 1990-05-30 | 1992-05-19 | Eastman Kodak Company | Bonding of thermoplastic sheet material to roughened substrates |
JPH04101846A (ja) | 1990-08-22 | 1992-04-03 | Nippon Dekoratsukusu Kk | 化粧積層板 |
US5215826A (en) | 1990-09-25 | 1993-06-01 | Rexham Industries Corp. | Surfacing film with thermoformable carrier layer |
IT1242070B (it) | 1990-10-11 | 1994-02-08 | Siv Soc Italiana Vetro | Procedimento per la fabbricazione di vetri laminati decorati di sicurezza |
KR100228593B1 (ko) | 1990-10-25 | 1999-11-01 | 스프레이그 로버트 월터 | 역반사성의 착색상을 형성하기 위한 전사제품 및 이를 제조하는 방법 |
US5316843A (en) * | 1990-11-20 | 1994-05-31 | Somar Corporation | Matted film containing a matting agent consisting of an organic filler and an inorganic filler |
US5196246A (en) * | 1991-05-17 | 1993-03-23 | Minnesota Mining And Manufacturing Company | Wall decorating system |
US5198301A (en) * | 1991-05-17 | 1993-03-30 | Minnesota Mining And Manufacturing Company | Flexible and conformable ionomeric resin based films |
GB9119655D0 (en) * | 1991-09-13 | 1991-10-23 | Forbo Cp Ltd | Self-adhesive wallcoverings |
US5467794A (en) | 1991-09-24 | 1995-11-21 | Posit Plus | Collapsible shade structure |
EP0742111A3 (en) | 1991-10-02 | 1997-09-24 | Fuji Kagaku Shikogyo | Device for transferring a painted film |
US5939479A (en) | 1991-11-22 | 1999-08-17 | Avery Dennison Corporation | Removable and guillotinable emulsion pressure-sensitive adhesives |
US5141584A (en) | 1991-11-27 | 1992-08-25 | Polaroid Corporation | Apparatus and method for controlling the delamination of a laminate |
US5169474A (en) | 1991-11-27 | 1992-12-08 | Polaroid Corporation | Apparatus and method for delaminating a composite laminate structure |
US5487927A (en) * | 1992-01-24 | 1996-01-30 | Revlon Consumer Products Corporation | Decorating method and products |
US5250336A (en) | 1992-02-11 | 1993-10-05 | Morgan Adhesives Company | Colored release liner |
EP0638019B1 (en) | 1992-04-29 | 2000-01-05 | MURRAY, Nicholas John | Laminates |
ATE188905T1 (de) | 1992-05-14 | 2000-02-15 | Decora Inc | Selbstklebendes, dekoratives oberflächenbelagmaterial |
US5490893A (en) * | 1992-05-22 | 1996-02-13 | Avery Dennison Corporation | Thermoformable conductive laminate and process |
DE4219446C3 (de) | 1992-06-13 | 2001-01-18 | Wilhelm Taubert | Verfahren zum Auftragen einer dekorativen Schicht auf ein Trägermaterial |
JP3231086B2 (ja) | 1992-06-30 | 2001-11-19 | テルモ株式会社 | 液体分離装置 |
US5354588A (en) | 1992-07-13 | 1994-10-11 | Moore Business Forms, Inc. | Linerless labels with tie coat |
US5633225A (en) | 1992-07-15 | 1997-05-27 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
US5308694A (en) * | 1992-07-31 | 1994-05-03 | Tarkett Ab | Barrier layer for floor and wall coverings |
JPH06129066A (ja) * | 1992-10-19 | 1994-05-10 | Toyo Kasei Kk | 外壁面美装シ−ト |
CA2084716C (en) * | 1992-11-05 | 1999-11-16 | John R. Johnson | Exterior automotive laminate with pressure-sensitive adhesive |
US5468532A (en) | 1992-12-10 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Multilayer graphic article with color layer |
US5487929A (en) * | 1993-02-03 | 1996-01-30 | Borden, Inc. | Repositionable wall covering |
JP3142095B2 (ja) * | 1993-02-23 | 2001-03-07 | 大日本印刷株式会社 | スウェード調化粧シートの製造方法 |
DE4311200A1 (de) | 1993-04-05 | 1994-10-06 | Zweckform Buero Prod Gmbh | Schmucketiketten und Verfahren zu ihrer Herstellung |
US6312777B1 (en) | 1993-04-06 | 2001-11-06 | Decora Incorporated | Methods and composition for making a pressure sensitive adhesive coated laminate |
US5814402A (en) | 1993-04-20 | 1998-09-29 | Decora Incorporated | Pressure sensitive dry transfer graphics article and method of manufacture |
US5362812A (en) * | 1993-04-23 | 1994-11-08 | Minnesota Mining And Manufacturing Company | Reactive polymeric dyes |
GB2282128B (en) * | 1993-04-26 | 1997-07-16 | Pentel Kk | Tape dispenser |
US5409883A (en) | 1993-05-07 | 1995-04-25 | Minnesota Mining And Manufacturing Company | Process for the manufacture of multi-color donor elements for thermal transfer systems |
JPH079601A (ja) * | 1993-06-07 | 1995-01-13 | Minnesota Mining & Mfg Co <3M> | 装飾用フィルム |
US5476901A (en) | 1993-06-24 | 1995-12-19 | The Procter & Gamble Company | Siloxane modified polyolefin copolymers |
DE4322140C1 (de) | 1993-07-02 | 1994-08-25 | Benecke Ag J H | Folie auf der Basis von Polymerisaten des Ethylens und Propylens sowie deren Verwendung |
CA2128347C (en) | 1993-07-28 | 1998-12-08 | Akihiko Takano | Biodegradable adhesive tape and biodegradable adhesive label |
US5451440A (en) | 1993-07-30 | 1995-09-19 | American Tape Co. | Release coating for silicone pressure sensitive adhesives |
DE4330700C2 (de) * | 1993-09-10 | 1996-08-08 | Continental Ag | Vulkanetten zum Aufbringen auf Substrate aus Gummi oder Kautschukmischungen |
CA2172996A1 (en) * | 1993-10-18 | 1995-04-27 | Craig D. Thompson | Tape dispenser |
US5866228A (en) * | 1993-11-22 | 1999-02-02 | Mitsubishi Chemical Corporation | Vacuum heat-insulator |
US5466324A (en) * | 1993-11-29 | 1995-11-14 | Polaroid Corporation | Apparatus and process for separation of laminae |
NZ277412A (en) | 1994-01-07 | 1997-07-27 | Minnesota Mining & Mfg | Graphic article comprising an electrostatic toner receptor layer comprising acrylic and vinyl resins, chlorinated or polyurethane rubber and plasticiser on surface of urethane-based crack resistant film |
WO1995018720A1 (en) | 1994-01-07 | 1995-07-13 | Minnesota Mining And Manufacturing Company | Graphics transfer article |
US5523129A (en) | 1994-02-14 | 1996-06-04 | Mcgeehan-Hatch; Mary Kate | Removable scene-scapes bordered by an interchangeable window frame for decorating the walls of children's rooms |
JP3522822B2 (ja) * | 1994-03-30 | 2004-04-26 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | ハンマートーン模様を有する装飾用シート及び装飾用シートの製造方法 |
US5441784A (en) | 1994-04-04 | 1995-08-15 | Decora, Incorporated | Paper base wallcoverings |
US5665458A (en) | 1994-04-14 | 1997-09-09 | Specialty Adhesive Film Co. | Heat activated applique on pressure sensitive release paper and method of making |
US5442832A (en) | 1994-04-19 | 1995-08-22 | Tonsager; Wayne M. | Adjustable trowel |
US6086995A (en) | 1994-05-13 | 2000-07-11 | Decora North America | Self-wound self-adhesive surface covering material |
US5788796A (en) | 1994-05-20 | 1998-08-04 | Minnesota Mining And Manufacturing | Decal assembly and method of making same |
EP0688008A1 (en) | 1994-06-14 | 1995-12-20 | LINTEC Corporation | Printed label, method and apparatus for manufacturing printed labels, and method and apparatus for attaching printed labels |
US5403432A (en) * | 1994-06-20 | 1995-04-04 | Burch; Teresa G. | Suspendible wallpaper applicator |
US5985772A (en) | 1994-06-23 | 1999-11-16 | Cellresin Technologies, Llc | Packaging system comprising cellulosic web with a permeant barrier or contaminant trap |
EP0695629A3 (de) | 1994-07-12 | 1996-10-23 | Alkor Gmbh | Verbundwerkstoff, Verfahren zu dessen Herstellung und Verwendung desselben |
US5670014A (en) | 1994-10-18 | 1997-09-23 | Tapelicator, Inc. | Tape dispensing applicator and replaceable tape cartridge |
JP3929082B2 (ja) * | 1994-12-05 | 2007-06-13 | リケンテクノス株式会社 | 化粧シートおよびその製造方法 |
US5478432A (en) | 1994-12-16 | 1995-12-26 | Vester; Raita E. | Wallpaper border applicator apparatus |
US5643668A (en) | 1994-12-30 | 1997-07-01 | Minnesota Mining And Manufacturing Company | Tape for rough surfaces |
US5591290A (en) * | 1995-01-23 | 1997-01-07 | Wallace Computer Services, Inc. | Method of making a laminate having variable adhesive properties |
US5544384A (en) | 1995-02-13 | 1996-08-13 | Forselius; Frank E. | Wall corner finishing tool |
US5573865A (en) | 1995-02-14 | 1996-11-12 | Minnesota Mining And Manufacturing Company | Graphics transfer article |
US5571557A (en) | 1995-05-09 | 1996-11-05 | Chartpak, Inc. | Faux glass etch product and process of preparing same |
US5750254A (en) * | 1995-06-05 | 1998-05-12 | Rsw, Inc., Specialty Tapes Division | Tape with plural adhesive zones and an automobile protection arrangement |
US5728469A (en) * | 1995-06-06 | 1998-03-17 | Avery Dennison Corporation | Block copolymer release surface for pressure sensitive adhesives |
US5750234A (en) * | 1996-06-07 | 1998-05-12 | Avery Dennison Corporation | Interior automotive laminate with thermoplastic low gloss coating |
US5968996A (en) * | 1995-06-07 | 1999-10-19 | Moore Business Forms, Inc. | Matte finished release composition, linerless labels incorporating the release compositon and method for making same |
ZA964731B (en) * | 1995-06-07 | 1997-01-07 | Avery Dennison Corp A Legal Bo | Extrusion coating process for making protective and decorative films |
US5676787A (en) | 1995-06-07 | 1997-10-14 | Borden Decorative Products, Inc. | Method for making repositionable wall covering and intermediate for same |
EP0831998A4 (en) | 1995-06-07 | 2000-03-01 | Avery Dennison Corp | EXTRUSION METHOD OF WEATHERPROOF PROTECTIVE COATINGS FOR SIDEWALLS OR SIMILAR ITEMS |
DE29513170U1 (de) | 1995-08-16 | 1997-01-02 | Zweckform Etikettiertechnik | Haftetikett |
JPH09123693A (ja) * | 1995-08-31 | 1997-05-13 | Nissha Printing Co Ltd | 転写材および転写物 |
JP3500240B2 (ja) | 1995-10-27 | 2004-02-23 | リンテック株式会社 | 着色フイルム |
US5795636A (en) * | 1995-11-15 | 1998-08-18 | Minnesota Mining And Manufacturing Company | Positionable and repositionable adhesive article |
US5639539A (en) * | 1995-11-29 | 1997-06-17 | Imperial Wallcoverings | Wall covering |
WO1997030848A1 (fr) | 1996-02-22 | 1997-08-28 | Idemitsu Petrochemical Co., Ltd. | Pellicule ou plaque decorative, materiau decoratif et materiau de construction fait a partir de ce materiau decoratif |
JPH09237045A (ja) | 1996-02-29 | 1997-09-09 | Lintec Corp | ハーフ蒸着ラベル |
US5759270A (en) | 1996-02-29 | 1998-06-02 | Katsuyuki Miyazaki | Correction tape adhesiver for correcting mistyped letters |
US5985079A (en) | 1996-03-28 | 1999-11-16 | Rexam Industries Corp. | Flexible composite surfacing film and method for producing same |
AT404240B (de) | 1996-04-25 | 1998-09-25 | Isovolta | Laminat bestehend aus einer basis- und deckschicht sowie verfahren zur herstellung einer dekoroberfläche an diesem laminat |
US5707482A (en) | 1996-05-16 | 1998-01-13 | Fusselman; Stephen M. | Removable highlighting tape |
US5904968A (en) * | 1996-05-24 | 1999-05-18 | Moore Business Forms, Inc. | Method of labeling blow molded articles with linerless labels |
US5919537A (en) | 1996-06-18 | 1999-07-06 | Android Industries Of Michigan, L.L.C. | Decorative films and laminated formable sheets with dual protective film layers |
JPH1016498A (ja) * | 1996-07-02 | 1998-01-20 | Nissha Printing Co Ltd | 絵付シート |
US5721086A (en) * | 1996-07-25 | 1998-02-24 | Minnesota Mining And Manufacturing Company | Image receptor medium |
JPH1035086A (ja) * | 1996-07-26 | 1998-02-10 | Dainippon Printing Co Ltd | 三次元成形品絵付け用転写フィルム |
DE19635587B4 (de) | 1996-09-02 | 2005-12-08 | SOCIéTé BIC | Handgerät zum Übertragen eines Filmes aus z. B.klebendem, deckendem oder farbigem Material von einem auf einer Vorratsspule aufgewickelten Trägerband auf ein Substrat |
US5981058A (en) * | 1996-09-13 | 1999-11-09 | Mannington Mills, Inc. | Stain blocking barrier layer |
US6461707B1 (en) | 1997-09-26 | 2002-10-08 | Avery Dennison Corporation | Faceless pressure-sensitive adhesive construction |
US6020062A (en) * | 1996-11-08 | 2000-02-01 | D.W. Wallcovering Inc. | Article having slippable adhesive |
US5981009A (en) * | 1997-01-30 | 1999-11-09 | Leonard Kurz Gmbh & Co. | Decorative film with hot melt adhesive layer |
US6413630B1 (en) | 1997-05-15 | 2002-07-02 | 3M Innovative Properties Company | Decorative film |
JP3954157B2 (ja) * | 1997-05-30 | 2007-08-08 | スリーエム カンパニー | 装飾シート及びその製造方法 |
JP3505673B2 (ja) * | 1997-07-23 | 2004-03-08 | 株式会社トンボ鉛筆 | 塗布具 |
EP0894644B1 (fr) * | 1997-07-31 | 2002-02-06 | Dominique Blanc-Brude | Feuille adhésive par application de pression |
DE19735958A1 (de) | 1997-08-19 | 1999-02-25 | Basf Ag | Thermisch härtbare, wässrige Zusammensetzungen |
US5851931A (en) | 1997-09-03 | 1998-12-22 | Foss Manufacturing Co., Inc. | Paintable substrate of nonwoven fabric and extruded resin |
US6083616A (en) | 1997-09-19 | 2000-07-04 | Seal Products, Inc. | Nontack pressure activated adhesive |
KR100258600B1 (ko) | 1997-10-06 | 2000-06-15 | 성재갑 | 멜라민시트적층염화비닐바닥장식재 |
DE19744957C1 (de) | 1997-10-10 | 1999-07-29 | Pritt Produktionsgesellschaft | Mehrschichtiges, flexibles Korrekturband |
WO1999024290A1 (en) | 1997-11-12 | 1999-05-20 | Collins & Aikman Products Co. | Vibration dampening laminate |
US6194064B1 (en) * | 1997-12-03 | 2001-02-27 | Dyna-Tech Adhesive, Inc. | Pressure sensitive adhesive for decorative films with removable and repositionable properties |
US6096396A (en) | 1998-01-21 | 2000-08-01 | Rexam Industries Corp. | Decorative sheet material suitable for use as a flexible weatherable paint film or decal |
US6153283A (en) | 1998-02-11 | 2000-11-28 | Steelwood Extruding Corp. | Structure having at least one improved surface and a method of making the structure |
US6740379B1 (en) | 1998-03-13 | 2004-05-25 | 3M Innovative Properties Company | Adhesive tape for adhering inserts to a page of a magazine |
US6432241B1 (en) | 1998-03-13 | 2002-08-13 | 3M Innovative Properties Company | Splicing tape, splicing method and assembly comprising the splicing tape |
US6235363B1 (en) * | 1998-05-06 | 2001-05-22 | Avery Dennison Corporation | Composite construction containing barrier layer |
US6284183B1 (en) * | 1998-06-08 | 2001-09-04 | Avery Dennison Corporation | Thick sheet laminating process for making exterior automotive body panels |
US6221198B1 (en) * | 1998-06-09 | 2001-04-24 | 3M Innovative Properties Company | Method of stabilizing films or membranes using adhesive as a reservoir |
JP2002518209A (ja) | 1998-06-15 | 2002-06-25 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | マルチコンポーネント一方向性グラフィック物品 |
EP2402159B1 (en) | 1998-07-14 | 2015-12-02 | Dai Nippon Printing Co., Ltd. | Decorative material |
DE19837774A1 (de) | 1998-08-20 | 2000-02-24 | Waldemar Sturn | Verfahren zum Aufbringen von Farbe auf einem Untergrund |
US6391415B1 (en) * | 1998-08-31 | 2002-05-21 | Environmental Inks And Coatings Corporation | Label system |
US6228486B1 (en) * | 1998-10-06 | 2001-05-08 | Avery Dennison Corporation | Thermal transfer laminate |
ES2213248T3 (es) | 1998-10-13 | 2004-08-16 | Bush Industries, Inc. | Procedimiento para aplicar una decoracion de color sobre un sustrato. |
US6383613B1 (en) * | 1998-10-16 | 2002-05-07 | 3M Innovative Properties Company | Decorative film and method for the production of the same |
US6482488B1 (en) | 1998-10-28 | 2002-11-19 | 3M Innovative Properties Company | Repaired scratched and/or abraded transparent substrates having protective removable sheets thereon and a method of making |
US6394165B1 (en) | 1998-11-09 | 2002-05-28 | Steven M. Rader | Self-adhesive element dispenser and applicator device and method thereof |
GB2343864B (en) | 1998-11-20 | 2003-07-16 | Agra Vadeko Inc | Improved security thread and method and apparatus for applying same to a substrate |
US6432528B1 (en) | 1998-12-09 | 2002-08-13 | 3M Innovative Properties Company | Variably printed tape and system for printing and applying tape onto surfaces |
US6399193B1 (en) | 1998-12-18 | 2002-06-04 | The University Of Massachusetts Lowell | Surfacing laminate with bonded with pigmented pressure sensitive adhesive |
US6649682B1 (en) | 1998-12-22 | 2003-11-18 | Conforma Clad, Inc | Process for making wear-resistant coatings |
CA2291316A1 (en) | 1999-01-08 | 2000-07-08 | Nicholas A. Farkas | Silicone-containing low surface tension film |
KR100585250B1 (ko) | 1999-01-25 | 2006-06-01 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 진공식 적층 장치 및 이의 이용 방법 |
US6152030A (en) | 1999-02-19 | 2000-11-28 | Fuqua; Rick Lee | Curing apparatus for a multi-color screen printing system |
MXPA01009418A (es) | 1999-03-19 | 2002-06-04 | 3M Innovative Properties Co | Sistema adhesivo para graficos de imagen que usa un adhesivo no pegajoso. |
US6163951A (en) | 1999-03-31 | 2000-12-26 | Sealright Co., Inc. | Method and apparatus for lifting tabs of a laminate from a substrate |
US6324811B1 (en) | 1999-03-31 | 2001-12-04 | Jane S. Gauss | Covering an interior surface |
US6421052B1 (en) | 1999-04-09 | 2002-07-16 | The Procter & Gamble Company | Method of seaming and expanding amorphous patterns |
US6193918B1 (en) | 1999-04-09 | 2001-02-27 | The Procter & Gamble Company | High speed embossing and adhesive printing process and apparatus |
EP1203968B1 (en) | 1999-04-21 | 2012-06-27 | Nippon Mitsubishi Oil Corporation | Production method for an optical laminate |
ATE214642T1 (de) | 1999-05-17 | 2002-04-15 | Argotec Lacksysteme Gmbh | Verfahren zum auftragen von lack und dekor auf einen gegenstand und verfahren sowie vorrichtung zum laminieren von lack, dekor und kleber auf einen film |
ITLU990012A1 (it) | 1999-05-24 | 2000-11-24 | Rotoplast Srl | Procedimento per inserire corpi solidi tra un film plastico ed altri supporti (plastica, stoffa, pelle, etc.) |
US6723427B1 (en) * | 1999-06-21 | 2004-04-20 | Avery Dennison Corporation | Fade printed decorative sheets and methods and apparatus for making the same |
AU5429900A (en) | 1999-06-25 | 2001-01-31 | Toyo Kohan Co. Ltd. | Printing resin film for laminating high-sharpness decorative laminated sheet excellent in workability and high-sharpness decorative laminated sheet laminated with the resin films |
US6311399B1 (en) | 1999-10-05 | 2001-11-06 | 3M Innovative Properties Company | Multi-pin air release tool and method |
US6541109B1 (en) * | 1999-10-08 | 2003-04-01 | 3M Innovative Properties Company | Release coating formulation providing low adhesion release surfaces for pressure sensitive adhesives |
BR0014748A (pt) | 1999-10-15 | 2002-07-02 | 3M Innovative Properties Co | Pelìculas de múltiplas camadas |
US6444311B1 (en) | 1999-10-19 | 2002-09-03 | Saint-Gobain Performance Plastics Corporation | Impact resistant protective multilayer film |
US6475616B1 (en) | 1999-11-30 | 2002-11-05 | 3M Innovative Properties Company | Paint replacement appliques |
US6482638B1 (en) | 1999-12-09 | 2002-11-19 | 3M Innovative Properties Company | Heat-relaxable substrates and arrays |
US6376058B1 (en) | 1999-12-21 | 2002-04-23 | Avery Dennison Corporation | Polypropylene based compositions and films and labels formed therefrom |
US6461422B1 (en) | 2000-01-27 | 2002-10-08 | Chartpak, Inc. | Pressure sensitive ink jet media for digital printing |
US6554044B2 (en) | 2000-01-28 | 2003-04-29 | Fargo Electronics Inc. | Laminator peel-off bar |
US6379791B1 (en) * | 2000-02-08 | 2002-04-30 | 3M Innovative Properties Company | Compatibilized pressure-sensitive adhesives |
JP4404430B2 (ja) | 2000-02-15 | 2010-01-27 | 新熊取谷石材株式会社 | 建築物装飾材の取付方法および該取付装置 |
JP3388437B2 (ja) * | 2000-02-18 | 2003-03-24 | 大日本印刷株式会社 | 化粧シート |
JP4069583B2 (ja) * | 2000-03-28 | 2008-04-02 | 三菱電機株式会社 | プラズマディスプレイ装置 |
JP3409016B2 (ja) | 2000-04-14 | 2003-05-19 | 株式会社ダイフレックス | 防水シートおよび防水シートの接合構造および防水施工方法 |
WO2001079372A2 (en) | 2000-04-17 | 2001-10-25 | Avery Dennison Corporation | Large-sized, mountable and removable sheet assembly and method therefor |
JP2001302991A (ja) | 2000-04-20 | 2001-10-31 | Lintec Corp | 塗装用粘着テープ |
US6630049B2 (en) | 2000-04-24 | 2003-10-07 | Avery Dennison Corporation | Adhesive articles with improved air egress and methods of making the same |
JP4566328B2 (ja) | 2000-04-28 | 2010-10-20 | ロンシール工業株式会社 | 防水シート及び施工方法 |
US6520234B1 (en) | 2000-05-23 | 2003-02-18 | 3M Innovative Properties Company | Steered vacuum-assisted laminating apparatus and methods of use |
US6706131B2 (en) * | 2000-05-23 | 2004-03-16 | 3M Innovative Properties Company | Film lamination and removal system and methods of use |
US6824638B1 (en) | 2000-07-27 | 2004-11-30 | 3M Innovative Properties Company | Graphic image film registration systems and methods |
JP2002067243A (ja) | 2000-09-04 | 2002-03-05 | Dainippon Printing Co Ltd | 化粧シート |
AU2002211431A1 (en) | 2000-10-06 | 2002-04-15 | Imperial Home Decor Group Management, Inc. | Bleed-resistant dry-transfer wallcoverings |
JP2002113995A (ja) | 2000-10-06 | 2002-04-16 | Toppan Printing Co Ltd | 化粧シート及び化粧材 |
TW490373B (en) | 2000-10-23 | 2002-06-11 | Matsushita Electric Works Ltd | Laminate with a peelable top layer and method of peeling off the top layer from the laminate |
US6756095B2 (en) | 2001-01-10 | 2004-06-29 | Avery Dennison Corporation | Heat-sealable laminate |
US6984429B2 (en) * | 2001-01-12 | 2006-01-10 | 3M Innovative Properties Company | Laminate from which decorative films can be applied to a substrate |
US6613411B2 (en) | 2001-01-25 | 2003-09-02 | 3M Innovative Properties Company | Conformable multi-layer sheet materials |
EP1226958A1 (de) | 2001-01-25 | 2002-07-31 | Celfa AG | Bildempfangsmaterial mit einer Klebstoffschicht, Verfahren zur Herstellung und Verwendung |
US20020142155A1 (en) | 2001-02-08 | 2002-10-03 | Steinberg Richard F. | Decorative substrate for removably adhering to a window and/or wall |
JP2002294181A (ja) | 2001-03-21 | 2002-10-09 | Three M Innovative Properties Co | 装飾シート |
US20020182955A1 (en) | 2001-03-29 | 2002-12-05 | Weglewski James T. | Structural bonding tapes and articles containing the same |
JP2002321328A (ja) | 2001-04-04 | 2002-11-05 | Three M Innovative Properties Co | 装飾シート |
CA2442955A1 (en) | 2001-04-12 | 2002-10-24 | Avery Dennison Corporation | Metallized inkjet substrates and methods of making the same |
US6875800B2 (en) | 2001-06-18 | 2005-04-05 | Ppg Industries Ohio, Inc. | Use of nanoparticulate organic pigments in paints and coatings |
JP2003025793A (ja) * | 2001-07-13 | 2003-01-29 | Minoru Yoshida | 蓄光転写フィルム |
US20030026932A1 (en) | 2001-07-30 | 2003-02-06 | Johnson John R. | Multilayer laminate |
MXPA04001306A (es) | 2001-08-17 | 2004-05-20 | Avery Dennison Corp | Composiciones de recubrimiento superior, sustratos que contienen un recubrimiento superior proveniente de las mismas y metodos de preparacion de las mismas. |
US7022385B1 (en) * | 2001-10-04 | 2006-04-04 | Nucoat, Inc. | Laminated imaged recording media |
US6773653B2 (en) | 2001-10-05 | 2004-08-10 | Avery Dennison Corporation | In-mold labeling method |
US6601741B2 (en) | 2001-11-28 | 2003-08-05 | Illinois Tool Works Inc. | Laminated distribution manifold plate system |
EP1318011B1 (en) | 2001-12-07 | 2004-09-22 | 3M Innovative Properties Company | Multi-layer sheet comprising a protective polyurethane layer |
US7316832B2 (en) | 2001-12-20 | 2008-01-08 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US7709070B2 (en) | 2001-12-20 | 2010-05-04 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
CA2471767A1 (en) | 2002-01-08 | 2003-07-24 | 3M Innovative Properties Company | Method of conforming a film to a surface |
US6752075B2 (en) | 2002-02-14 | 2004-06-22 | Stahls' Inc. | Screen printed fabric |
KR200280679Y1 (ko) | 2002-02-16 | 2002-07-13 | 주식회사 다이아덤코리아 | 장식용 스티커 시트 |
KR100849750B1 (ko) | 2002-02-28 | 2008-07-31 | 솔루티아인코포레이티드 | 엠보싱 반사 라미네이트 |
EP1488923A1 (en) | 2002-03-01 | 2004-12-22 | C. I. Kasei Company, Limited | Decorative sheet and process for producing the same |
US20030211334A1 (en) | 2002-05-07 | 2003-11-13 | Jones Kyle R. | Low gloss automotive interior laminates |
EP1506097A1 (en) | 2002-05-13 | 2005-02-16 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US6872268B2 (en) * | 2002-06-11 | 2005-03-29 | 3M Innovative Properties Company | Method of conforming an adherent film to a substrate by application of vacuum |
ES2200697B1 (es) | 2002-06-28 | 2005-01-01 | Alec Mian | Procedimiento para la fabricacion de paneles artisticos traslucidos y paneles fabricados. |
US7311956B2 (en) * | 2002-11-26 | 2007-12-25 | 3M Innovative Properties Company | Laminate and method used for applying a design to a substrate |
US20060165979A1 (en) | 2002-12-13 | 2006-07-27 | Kinsey Von A | Articles and methods for applying color on surfaces |
US6844041B2 (en) | 2002-12-27 | 2005-01-18 | Exxonmobil Oil Corporation | Clear polymeric label including delaminatable mask layer |
JP2004216573A (ja) | 2003-01-09 | 2004-08-05 | Three M Innovative Properties Co | 化粧シート及びその製造方法 |
JP2006517881A (ja) | 2003-02-14 | 2006-08-03 | エーブリー デニソン コーポレイション | ドライペイント移動ラミネート |
JP4290700B2 (ja) * | 2003-02-14 | 2009-07-08 | ザ プロクター アンド ギャンブル カンパニー | 表面上に色彩を適用する耐変色性物品、及び表面上に色彩を適用する物品において変色を低減する方法 |
US20040161564A1 (en) | 2003-02-14 | 2004-08-19 | Truog Keith L. | Dry paint transfer laminate |
AU2004213765B2 (en) | 2003-02-14 | 2008-01-31 | Avery Dennison Corporation | Extrusion method of making a dry paint transfer laminate |
US20040170855A1 (en) | 2003-02-27 | 2004-09-02 | Shigeo Kawabata | Decorative film-like material and decorative sheet |
EP1462423A1 (en) | 2003-03-21 | 2004-09-29 | Cristales Curvados S.A. | Ornamental multilayer glass |
US20050196607A1 (en) | 2003-06-09 | 2005-09-08 | Shih Frank Y. | Multi-layer dry paint decorative laminate having discoloration prevention barrier |
US20040247837A1 (en) | 2003-06-09 | 2004-12-09 | Howard Enlow | Multilayer film |
US6808586B1 (en) | 2003-06-10 | 2004-10-26 | The Procter & Gamble Company | Applicator for and method of applying a sheet material to a substrate |
US7204288B2 (en) | 2003-06-10 | 2007-04-17 | The Procter & Gamble Company | Multi-burnish applicator for and method of applying a sheet material to a substrate |
AU2003245534A1 (en) | 2003-06-16 | 2005-02-04 | Serigraph Inc. | Architectural graphic system |
JP2005220337A (ja) | 2004-01-09 | 2005-08-18 | Nichiban Co Ltd | 粘着シート、表面光沢装飾シート、及びインクジェット印刷用メディア |
JP2005206724A (ja) | 2004-01-23 | 2005-08-04 | Three M Innovative Properties Co | 装飾フィルム |
WO2005075591A1 (en) | 2004-02-02 | 2005-08-18 | 3M Innovative Properties Company | Method of producing colored graphic marking films |
KR100803013B1 (ko) * | 2004-02-13 | 2008-02-14 | 더 프록터 앤드 갬블 캄파니 | 표면에 인가되는 용품 및 그 방법 |
CN1774336B (zh) * | 2004-02-13 | 2010-10-06 | 宝洁公司 | 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 |
JP2007533491A (ja) | 2004-04-16 | 2007-11-22 | ミリケン・アンド・カンパニー | テキスタイル構造体 |
US20050255271A1 (en) | 2004-05-11 | 2005-11-17 | Joseph Brimo | Apparently seamless wall covering system |
US20060073318A1 (en) * | 2004-10-06 | 2006-04-06 | Applied Extrusion Technologies, Inc. | Opaque decorative film and construction laminates employing same |
US20060088695A1 (en) * | 2004-10-21 | 2006-04-27 | Theodore Coburn | Multilayer separable film or sheet |
US20060093776A1 (en) * | 2004-11-03 | 2006-05-04 | Crum Jesse D | Pressure sensitive laminate assembly having faux patterned embossments for use with business communication documents and method of creating a business document |
-
2003
- 2003-02-14 US US10/367,611 patent/US20040161564A1/en not_active Abandoned
- 2003-06-09 US US10/457,791 patent/US7807246B2/en not_active Expired - Fee Related
- 2003-06-09 US US10/457,790 patent/US7905981B2/en not_active Expired - Fee Related
- 2003-06-09 US US10/457,826 patent/US7132142B2/en not_active Expired - Fee Related
- 2003-06-09 US US10/457,806 patent/US20040159969A1/en not_active Abandoned
-
2004
- 2004-02-11 CN CNA2004800049421A patent/CN1753733A/zh active Pending
- 2004-02-11 CN CNB200480009775XA patent/CN100566991C/zh not_active Expired - Fee Related
- 2004-02-13 CN CNA2004800071317A patent/CN1761575A/zh active Pending
- 2004-02-13 CN CNA2004800071232A patent/CN1761577A/zh active Pending
- 2004-02-13 CN CNA2004800037744A patent/CN1747831A/zh active Pending
- 2004-02-13 CN CNA2004800076359A patent/CN1761578A/zh active Pending
- 2004-02-13 CN CNA2004800037759A patent/CN1756671A/zh active Pending
- 2004-02-13 CN CNA2004800076363A patent/CN1761579A/zh active Pending
-
2005
- 2005-10-12 US US11/248,047 patent/US7722938B2/en not_active Expired - Fee Related
-
2006
- 2006-11-07 US US11/557,146 patent/US20070065621A1/en not_active Abandoned
-
2008
- 2008-07-02 JP JP2008173436A patent/JP2009006713A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
US7905981B2 (en) | 2011-03-15 |
CN1761579A (zh) | 2006-04-19 |
US20070065621A1 (en) | 2007-03-22 |
US20040161568A1 (en) | 2004-08-19 |
US20040161567A1 (en) | 2004-08-19 |
US20040159969A1 (en) | 2004-08-19 |
US20040161564A1 (en) | 2004-08-19 |
JP2009006713A (ja) | 2009-01-15 |
CN1756671A (zh) | 2006-04-05 |
CN100566991C (zh) | 2009-12-09 |
CN1761577A (zh) | 2006-04-19 |
US7807246B2 (en) | 2010-10-05 |
US7722938B2 (en) | 2010-05-25 |
CN1761575A (zh) | 2006-04-19 |
CN1761578A (zh) | 2006-04-19 |
CN1753733A (zh) | 2006-03-29 |
US20040161566A1 (en) | 2004-08-19 |
CN1780731A (zh) | 2006-05-31 |
US7132142B2 (en) | 2006-11-07 |
US20060029765A1 (en) | 2006-02-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1747831A (zh) | 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 | |
CN1774336B (zh) | 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 | |
US7846522B2 (en) | Discoloration-resistant articles for applying color on surfaces and methods of reducing discoloration in articles for applying color on surfaces | |
JP6882573B2 (ja) | 電磁エネルギー吸収性光学製品及び製造方法 | |
KR101975192B1 (ko) | 인쇄 특성이 우수한 장식재용 잉크 수용층 조성물, 장식재 및 장식재 제조방법. | |
US20130189516A1 (en) | Flame-retardant polymer member with environmental resistance and flame-retardant polymer member with hygienic property | |
JP2001505141A (ja) | 金属化多層包装フィルム | |
JP2011236703A (ja) | 壁装材用抗菌防汚フィルム及びそれを積層して成る壁装材 | |
JP2011104966A (ja) | 熱転写受像シート | |
JP2006264087A (ja) | 熱転写受像シート | |
JP2005035167A (ja) | ガスバリア性フィルム | |
CN111303787A (zh) | 一种阻燃抗菌航空装饰膜 | |
JP2015024576A (ja) | 熱転写受像シート | |
JP2000117913A (ja) | 吸放湿性能を有する化粧材 | |
JP4110717B2 (ja) | 化粧シートの製造方法 | |
JP4015880B2 (ja) | インクジェット記録用シート | |
KR100711037B1 (ko) | 표면에 색상을 인가하기 위한 내변색성 용품 및 표면에색상을 인가하기 위한 용품에서 변색을 감소시키는 방법 | |
JP5716989B2 (ja) | 熱転写受像シート | |
TWI284063B (en) | Co-extrusion coating die set and process for co-extrusion coating two coating solutions | |
JP4290228B2 (ja) | 積層体の製法 | |
JP2004066819A (ja) | インクジェット記録要素 | |
WO2016017721A1 (ja) | 電飾用インクジェット記録材料、電飾用画像及びその形成方法、並びに電飾看板 | |
JP2021020357A (ja) | ガスバリア性フィルム | |
JP2004181935A (ja) | インクジェット記録用シート | |
JP2014156026A (ja) | バリア性フィルムおよびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
AD01 | Patent right deemed abandoned |
Effective date of abandoning: 20060315 |
|
C20 | Patent right or utility model deemed to be abandoned or is abandoned |