CN1756671A - 用于施用到一个表面上的制品及其方法 - Google Patents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
本发明包括一种层压制品,例如可被用来将一种功能效果施用到一个表面上的制品。功能效果可以是颜色。所述制品具有多个层片。当需要粘合到表面上时,所述层片暂时地(为了重新定位)或是永久地(为了长期使用)彼此优先脱离或彼此优先相互粘附。
Description
发明领域
本发明涉及用于将一种颜色或功能效果施用到一个表面上的制品,其中制品可为层压片。
发明背景
层压片已为本领域所熟知。层压片被用于将一种颜色效果施用到一个表面上。这样的片可包括壁纸或一种干颜色组分。当出现在油漆中时,颜色组分可包括固定到一种粘合剂中的颜色。片可被粘附到表面上或通过本领域已知的其它方法,例如凝聚、磁吸引、静态/静电电荷、机械部件、抽气/真空、其它差压等连接。
制品可以宽度不定的连续长度提供或以散片提供。制品可为盘绕的或平直的片。此外,可将制品从连续卷裁切成散片,例如贴花纸。
在将制品施用到底物上后,重要的是层压结构保持原样。一种尤其优选的层压结构可包括叠置的薄片,例如一个可分离型衬纸、一种颜色组分或功能效果和一种粘合剂或其它键合剂。
然而,重要的是避免薄片过早脱层。例如,在将制品设置在表面上和永久地定位在其上之前,不将可分离衬料从颜色组分上去除很重要-除非明确需要它这样做。同样,不发生键合剂或颜色组分的内聚失效也很重要。此外,人们可能希望将片重新定位以确保与一个角落一致,达到真正垂直、图案匹配等。因此,制品与底物间的粘合强度不增加得太快使这能够发生很重要。
发明概述
本发明包括一种用于给一个表面提供一种功能效果的制品。制品包括一个包括呈面对面关系的薄片的层压材料。薄片包括一个提供功能效果的片、一种结合到片的第一侧面上的键合剂,和一个可分离地连接到片的第二侧面上的可分离衬料。功能效果可为颜色。片可具有特定厚度和施用压力以粘到表面上。
制品可以绕式、切割式和叠式等提供。制品可手工施用到表面上或用一个分配器施用。分配器具有在分配期间产生的内力。在分配期间,在分配器和制品之间也产生一个力。
各层片之间的相对推力可提供分配器内的力大于每个薄片的内聚力和片与可分离衬料之间的力、以及片与键合剂之间的力。此外,当将制品分配到一个表面上时,将制品粘合到表面上的力大于施用到表面上时制品和分配器之间的力。
附图概述
图1A为卷成一个卷的依照本发明的制品的透视图。
图1B为堆叠排列的依照本发明的制品的透视图。
图2为在相邻的层压材料被分开时图1的卷或图2的堆叠的一部分的垂直剖面图。
图3为在将可分离衬料从制品的剩余部分去除时粘合到一个表面上的图2制品的垂直剖面图。
图4为依照本发明的一个可供选择的实施方案的垂直剖面视图。
具体实施方案的详细描述
本发明涉及用于给一个表面施用功能效果例如颜色的制品和方法。本文所用术语“颜色”用来指一种颜色效果,即,在颜色感知方面的美学差异。在一种具体的实施方案中,颜色效果为基本永久的颜色效果,即,不能被去除或在偶然接触、轻柔洗涤等时不会显著减退的颜色效果。因此,基本永久的颜色效果有别于可容易地去除或减退的暂时颜色效果,例如由粉笔或蜡笔所产生的颜色效果。本文所用术语“颜色组分”是指产生颜色效果的发明制品的组分。
可供选择地,制品可给一个表面提供其它功能效果。例如,制品可提供隔声、隔热、纹理、标记/指示、紫外线辐射、杀菌、质量传送、定时释放的气味控制、发香墙壁、铜面、小型方案、荧光墙壁(例如,颜色记忆、光记忆、不同荧光、光反应脱色)、白板能力、可擦性、清洁性、对于悬挂品的粘附能力(例如钩环)、图画、磁性表面、发光、热、声,自洁、吸尘、凸出反映(可为墙壁内的小区域)、透声、发声、防火、捕集碎片等的安全网、单向窗、烟雾检测、一氧化碳检测、侵入检测报警、声音检测、声音响应等等。要理解的是,尽管依照本发明的制品可为大致平直的并呈片状,下文中也考虑了厚度很厚的制品。
本文所用术语“表面”是指能够在其上安放颜色组分的物体或底物的任何外层或边界。合适的表面可以为大致二维的和平坦的或为大致三维的并包括弯曲处、角形部分等。在一个实施方案中,利用本发明的制品和方法施用颜色组分的表面包括建筑表面,即建筑物、建筑灯具(即电器)、家具等的表面。建筑物表面可以是在建筑物内部的内表面或在建筑物外部的外表面。大致三维的建筑表面可包括例如二维表面如板条(例如,绕窗户或门道的板条)、地板、器具、家具、房间地面、台面等之类的边缘处理。建筑表面可被永久地安装,也可被暂时地安装或者是便携式的。本发明的产品还能被施用到制品的表面上,使其具有与建筑表面相同或不同的纹理和/或外观。例如,这种产品可用来将颜色层施用到电器、家具和其它建筑制品上。根据本公开内容,对于本领域的技术人员来说,适于利用本发明的制品和方法施用颜色的其它表面将是显而易见的。
本文所引用的术语例如“垂直的”、“水平的”、“下面”、“上面”等是作为实施例而并非作为限制所用的以建立一个参照系。要理解的是,可采用各种其它参照系而不背离本发明的宗旨和范围。本领域的技术人员将会知道,本文所描述的作用于制品上的力是加在制品组分上实际力的示意性表示,并被分布在整个制品上和/或在制品中相邻薄层之间的相应的分界面或分界线上。下面的说明与具有一种功能效果(包括颜色)的制品10结合给出。然而,要认识到的是,给出该说明仅用于说明之目的,权利要求并非受此限制。
参见图1A、1B和2,一个用于将颜色施用到一个表面上的制品10包括一个颜色片12、一种键合剂14(例如压敏粘合剂)和一个可分离衬料16。可分离衬料16被可分离地与片12结合,并旨在和适于在片12被施用到所需表面20(图3)上之后短时间内或施用到表面20之后立刻去除。片12可包括一个外涂层22,例如包括一个透明的、半透明的、珍珠般的或不透明的涂层,例如提供光泽的、半光泽的、光滑的、蛋壳似的或浅色的光辉或其它光学效果例如漫射、反射等等,或其它有益的性质。片12和键合剂14的总厚度可小于约0.08毫米(0.0033英寸)。
键合剂14(其可为任何粘合剂,例如本领域技术人员已知的压敏粘合剂)适于在施加小于约3500克/平方厘米((50lbs/in2)的压力时将片12粘合到表面20上。示例性的制品10被描述于名称为“Articles and Methods for ApplyingColor on Surfaces”普通转让的专利申请序列号10/324,237中。
可分离衬料16可为片12提供结构支撑和/或强度(例如当可分离衬料16是呈薄膜形式时),和/或在生产、存储和使用期间有利于处理制品。可分离衬料16可由诸如聚对苯二甲酸乙二醇酯(PET)之类聚合物、无纺材料或纤维素片制成。可分离衬料16在面临片12的表面上可具有一个分离涂层例如硅氧烷涂层。可分离衬料16的厚度可大于片12的厚度。
制品10可以缠卷形式(图1A)提供,或可供选择地以叠的形式(图1B)提供,使得可分离衬料16将紧贴键合剂14设置并与其相接触。在卷的形式中,可缠绕制品10使得可分离衬料16径向朝外,如图2所示,或可反过来缠绕使得键合剂14径向向外。同样,可叠放单个叠状制品10(图1B)使得键合剂14和可分离衬料16呈面对面的关系,交替的制品10可交换位置,或可供选择地,制品10可按随机方位进行排列。
制品10的厚度可小于0.076mm(0.0033英寸),优选小于0.069mm(0.003英寸)。测量厚度仅考虑键合剂14和片12,不考虑可分离衬料16。厚度采用一个5mm直径的压脚在8.74gms的载荷下进行测量。制品10可手工施用或通过使用一个分配器施用。如果利用了一个分配器,则分配器可依照Procter & Gamble的2003年6月10日提交的美国专利申请序列号10/458,520和2003年11月4日提交的美国专利申请序列号10/700,614的说明进行制造。
要成功地展开或换句话讲将键合剂14从可分离衬料16上分开,在可分离衬料16和键合剂14之间所具有的总的联合(例如,展开或分开)力(图2中标为F1)必须小于在片12和可分离衬料16之间所具有的总的联合(例如,剥离)力(图2中标为F2)。否则,在展卷或分叠期间可分离衬料16将被键合剂14固定到片12上,而不是保持固定到片12上在随后施用到表面20期间去除。可分离衬料16从片12上的此类过早去除或脱层对于正确施用到表面20上是不适当的。
如果从卷的形式将制品10展开,则展开力被定义为在可分离衬料16和片12接触可分离衬料16的相邻部分的表面之间作用的粘合力。同样,如果制品10被排列成叠状或层状形式,则分开力被定义为在可分离衬料16和键合剂14之间作用的粘合力。依照ASTM D3811的修正版本,展开或分开力可在一个剥离试验中用一个5.08cm(2.0英寸)宽的剥离条、采用一个型号80-90的Lab MasterRelease and Adhesion Tester和一个40.6cm(16英寸)长的试样在1830cm(720英寸)测试速度下进行测量。在其中制品10被卷成一个卷的本发明的某些实施方案中,如果以约30.5cm(12英寸)每分钟至约2030cm(800英寸)每分钟的速率和以小于约180度特别是90度的角度展开制品10,则展开一个成卷制品10所需的展开力F1小于约150克每5.08cm(两英寸)。该角度相对于位于键合剂14与下面的可分离衬料16的剥离线处的圆形卷层的切平面进行测量,其中可分离衬料16为另一个薄片。在本发明的其它实施方案中,如果以约30.5cm(12英寸)每分钟至约1830cm(720英寸)每分钟范围的速率展开卷,则展开力F1小于约100克每5.08cm(两英寸)。在本发明的又一个其它实施方案中,如果以约460cm(180英寸)每分钟至约1830cm(720英寸)每分钟范围的速率展开卷,则展开力F1在约50克每5.08cm(两英寸)至65克每5.08cm(两英寸)之间变化。在仍然另一个实施方案中,以30.5(12)和760cm(300英寸)的速率测量,展开力小于约50克每5.08cm(两英寸)。
在其中制品10不需要展开的本发明的某些实施方案中,如果以约30.5cm(12英寸)每分钟至约2030cm(800英寸)每分钟的速率分开,则分开可分离衬料16和键合剂14所需的分开力F1小于约150克每5.08cm(两英寸)。在本发明的其它实施方案中,如果以约30.5cm(12英寸)每分钟至约1830cm(720英寸)每分钟范围的速率分开可分离衬料16和键合剂14,则分开力F1小于约100克每5.08cm(两英寸)。在本发明的另一个实施方案中,如果以约460cm(180英寸)每分钟至约1830cm(720英寸)每分钟范围的速率分开可分离衬料16和键合剂14,则分开力F1在约50克每5.08cm(两英寸)至约65克每5.08cm(两英寸)范围内变化。
展开或分开力F1的大小可通过改变键合剂14的组分或化学成分来改变。例如,可将增粘剂和/或交联剂添加到组分中改变粘合剂的粘着性。也可改变键合剂14的涂层重量或厚度来改变展开力或分开力。可供选择地,可改变可分离衬料16的分离涂层的组分或化学成分,以影响展开一个卷或分开相邻的叠片时从键合剂14分开的能力。展开力的值也受到制品10缠绕成的卷的紧密度和压实度的影响。如果键合剂14采用粘合剂,则可冷藏粘合剂以降低其对表面20的粘附性。同样,用来使可分离衬料16与键合剂14相接触的压力可影响分开力的大小。由作用在键合剂14的可分离衬料16之间的静态负荷产生的力可增大展开或分开力的值。
参见图3,在制品被施用到表面20上之后,在本发明的某些实施方案中,键合剂14和表面20之间的粘附力(图3中标为F3)大于约125克每5.08cm(两英寸)。粘附力F3通过将制品10以小于约180度、尤其90度的角度从表面20上剥离而确定。在本发明的其它实施方案中,键合剂14和表面20之间的粘附力F3在30.5cm(12英寸)每分钟的速率下测量大于约180克每5.08cm(两英寸)。尽管一般取键合剂14和外表面20之间的力作为F3,本发明并不受此限制。例如,F3可在制品10的第一部分的键合剂14和制品10的第二部分的片12之间进行测量。这可能会发生,例如,如果制品10的两个部分以搭接关系进行放置,例如在一个接缝处。
粘附力F3的大小可受到键合剂14和表面20之间的结合程度的影响。具体地讲,如果键合剂14和表面20之间的共同交界线或交界面基本上未受污染,则粘附力增大。归根结底,为了施用制品10,可通过例如擦拭表面20在某种意义上有效地去除任何临时附上的并因此可去除的残余物来准备表面20的状态。去除残余物增加了表面20和键合剂14间的接触面积,其增加了粘合剂粘合的强度,因为介于其间的残余物会减少表面20用来建立粘合剂粘合的可用表面积。
制品10能够被完全施用到表面20上。影响“基本施用”建立的因素包括但不限于:用来将制品10施用到表面20上的挤压和修平压力、表面20的表面能、散碎片的存在和污染(例如,打磨残余物)、表面20的表面纹理、施用制品前存在于表面20上的油漆涂层、如果有在施用前表面20上的油漆种类、下层的表面特性和壁纸清除的任何残余物(例如,胶料)。表面20的表面纹理和清除气泡影响键合剂14的各部分和表面20之间的接触程度,其中纹理较大降低粘合剂粘合的强度。如果需要,制品10可进行打孔使空气能够通过其逸出。在键合剂和表面20之间的粘附程度将也受到表面20上任何现有油漆性质的影响。例如,在底漆、瓷漆或乳胶漆之中,或在光泽、半光泽、光滑的、蛋壳似的和浅色末道漆之中,粘结程度就不同。制品10的抗弯刚度也影响制品10实现与表面20接触和粘附的能力。而且,如果制品10被打孔,则空气可通过该孔释放出去,并增加制品10与表面20间的接触/粘附。
可被添加到键合剂14中的颗粒包括但不限于碳黑、碳酸钙、二氧化钛、二氧化硅、缎光白、重晶石、云母、氧化锌、塑性颜色或高岭土颜色,其主要由高岭石(一种含水硅酸铝(Al2Si2O5(OH)4))组成。当在键合剂14的基质中时,颗粒应该是惰性的。颗粒的平均直径或中径可在约25nm至约150μm之间变化。按重量计,键合剂15的组分可包括约5%的颗粒,其中其它组分包括一种有机基质,尽管随着键合剂14变厚,可采用更大百分比的颗粒。
继续参见图3,当制品10被施用到表面20上时,键合剂14将片12粘附固定到表面20上并且可分离衬料16被去除以暴露出片12。剥离力(图2中标为F2)表征可分离衬料16从片12上分离的特性,如上所述。在本发明的某些实施方案中,当以约30.5cm(12英寸)每分钟至约1830cm(720英寸)每分钟的速率和以至少约45°的角度从片12上剥离可分离衬料时,可分离衬料16和片12之间的剥离力F2介于约20克每5.08cm(两英寸)至约200克每5.08cm(两英寸)之间。在本发明的其它实施方案中,当以约30cm(12英寸)每分钟至约760cm(300英寸)每分钟的速率和以小于约180度的角度从片12上剥离可分离衬料16时,剥离力F2在约1 10克每5.08cm(两英寸)至约150克每5.08cm(两英寸)之间变化。在本发明的另一个其它实施方案中,当以约30cm(12英寸)每分钟至约760cm(300英寸)每分钟的速率和以小于约180度的角度从片12上剥离可分离衬料16时,剥离力F2在约40克每5.08cm(两英寸)至约80克每5.08cm(两英寸)之间变化。
在一个尤其优选的实施方案中,对于F1、F2和F3可采用下面的力:
力 | 可接受 | 优选 | 更优选 |
F3 | >125g/5.08cm(2in);在30-1829cm/min(12-720ipm)的速率下测量;测试角度为180° | >125g/5.08cm(2in);在30cm/min(12ipm)的速率下测量;测试角度小于180° | >180g/5.08cm(2in);在30cm/min(12ipm)的速率下测量;测试角度为90° |
F2 | 20-200g/5.08cm(2in);在30-1829cm/min(12-720ipm)的速率下测量;测试角度小于180° | 40-100g/5.08cm(2in);在30-762cm/min(12-300ipm)的速率下测量;测试角度小于180° | 40-60@在30cm/min(12ipm)的速率下测量,测试角度为90°50-75g/5.08cm(2in)@300ipm,测试角度为90° |
F1 | <100g/5.08cm(2in);在30-1829cm/min(12-720ipm)的速率下测量;测试角度小于180° | <90g/5.08cm(2in);在457-1829cm/min(180-720)的速率下测量;测试角度小于180° | <70g/5.08cm(2 in);在457-1829cm/min(180ipm-720ipm)的速率下测量;测试角度为90° |
改变可分离衬料16和片12之间的粘附性(例如通过改变两个组件之间的接触面积)可导致剥离力F2的改变。改变可分离衬料16和片12之间的分界面起到改变粘附性的作用。同样,片12和可分离衬料16之间的静电荷在这些薄片之间产生不良的吸附力。
继续参见图3,键合剂14和表面20之间的粘附力(图3中标为F3)小于剥离力F2,以便在施加压力将片12粘合到表面20上之后去除可分离衬料16时,片12保持与表面20粘合。另外,键合剂14和片12之间的分开力(图3中标为F4)大于粘附力F3,以便在施用到表面20上去除可分离衬料16时,片12和键合剂14保持粘合在一起。
当制品被施用到一个表面20上之时,在初始施用点处键合剂14和表面20之间的粘附力F3大于在施用制品10期间和展开卷状制品10期间施加的施用力。典型地,卷状制品10被施用和粘着在表面20上的一个位置并展长、裁切和抵住表面20按压以建立一个粘合剂结合。在初次粘着之后,在粘着区上的粘附力应该适中,允许继续使用,在粘着区域上没有损失粘附性。
更细致地调查依照本发明的制品10,技术人员将了解到存在着粘性力和内聚力两种力。例如,参见图2-3,在可分离衬料16内部的内聚力C1描述将可分离衬料16的一部分从自身上分离所需的力的大小。同样,内聚力C3描述使片12与自身分离所需的内聚力。同样,内聚力C5描述将键合剂14与自身分开所需的内聚力。因此,技术人员将认识到,当用一个分配器(未示出)施用制品10时,在制品10和那个分配器之间产生分配力D6。同样,在分配器内部产生力D7。力D7与分配系统的内摩擦、分配器引起的制动动作等有关。
在初次粘贴到表面20上之时。需要重新定位能力:F2>F1和F3(在开始正交于表面时)<F2(在开始正交于表面时)<C1、C3、C5
要用可分离衬料16将制品10分配适当,靠近施用点下列关系必须适用。分配器力D7必须小于制品10各个层之间和内聚的力。同样,制品10和表面20之间的附着力F3必须大于制品10和分配器之间的吸附力。数学上,可将其表示为:
D7<C1、F2、C3、F4、C5
以及F3(在施用期间)>D6+D7
并且优选地F4
>F3>F2。要理解的是,如果不用分配器将制品10施用到表面20上,则不用这个公式。
此外,如果在可分离衬料16仍然保持就位时分配
a.F3(在开始时正交于和相切于表面时)≥D6≥F1+D7
b.F2>F1
式中,D6为制品10和分配器之间的力,并且是使用者在分配期间施加到表
面上的力,D7等于分配器的内部摩擦/阻力。
并且如果没标上具体的“正向”或“切向”符号,那么两种力都施加。
如果需要,为了降低其内部力,分配器可为电动的。
此外,技术人员将了解到,可能希望在制品20初次施用之后重新定位制品10。例如,制品10可能不是以垂直的、平滑的或水平的方式施用。人们可能希望去除皱纹等。在重新定位期间,键合剂14和表面20之间的力F3必须小于制品10中固有的其它力。数学上,可将其表示为:
F3(在重新定位期间)<C1、F2、C3、F4、C5。
在最终施用到表面20上时,将制品10连接到表面20上的结合力大于可分离衬料16和片12之间的力很重要。数学上,可将其表示为:
F3>F2I>F2
C、C3、C5>F3(在使用者正交于和相切于表面任何挤压之后)>F2(在开始去除可分离衬料16时在开始正交于和相切于表面所取的)>F2(衬纸16和片12之间的剥离力)。
对于在施用时具有一个可分离衬料16的制品10,其中F2I是从制品10的剩余部分去除可分离衬料16所需的初始力。如果已经预先将可分离衬料16从片12上分离,则前述公式可简化为:
F3(在施用时)>F2。
如果需要,本领域已知分配器在施用时从制品10的剩余部分缠绕可分离衬料16。如果这样,将键合剂14结合到表面20上的力F3必需小于制品10中存在的其它力。数学上,可将其表示为:
F3(在施用时)<C1、F2I、C3、F4、C5。
C1、C3、C5>F3(正交于和相切于表面)≥D6≥(F1+F2+D7)
F2>F1
此外,粘合剂和分配器之间的力必须大于片12和可剥离层16之间的力、加上键合剂14和分配器之间的力、加上分配器本身内的力。数学上,可将其表示为:
F3(在施用时)>F2+D6+D7。
在去除可分离衬料16之后,人们可能仍然希望如上所述重新定位制品10。此时,制品10和表面20之间的粘附力必须小于片12的内聚强度、键合剂14的内聚强度和它们之间的力。数学上,可将其表示为:
F3(在重新定位期间)<C3、F4、C5。
可如下所述增加一个加强层。即使没有一个加强层,下面的拉力关系必须被遵守,其中将制品10结合到表面20上的力小于上面提到的内力组合。数学上,可将其表示为:
F3(正交于表面剥离))<C3+F4+C5(每个均在拉力模式下)。
内聚强度可依照ASTM D882进行测量,然而层的分离可在保持15分钟后依照ASTM D3330进行测量。片12和键合剂14之间、可分离衬料16和片12之间和/或键合剂14和可分离衬料16之间的粘附性可通过表面处理而改变。具体地讲,片12和/或可剥离衬料16可通过电晕处理、通过粗化目标表面增加表面积、通过增大目标表面、分子间混合、通过直接涂敷键合剂、通过在层压期间加热或加压、通过包含一种功能化聚合物来提供共价或分子键、通过压花、刷光或其它机械方法增加一个或多个层的表面积、或通过添加颗粒或通过溶剂腐蚀以及它们的组合进行表面处理。例如,电晕处理涉及暴露于由一对间隔一定距离的电极提供的高压电晕放电下。
参见图4,制品10还可包括设置在片12和键合剂14之间的一个或多个联结层18,其增强它们之间的接合。典型的联结层18包括功能化的聚烯烃乙二醇二乙酸酯、乙烯乙酸乙烯酯、功能化丙烯酸、聚氯乙烯、聚烯烃、聚乙氧基化物和它们的组合物以及本领域所熟知的其它材料。联结层18增强片12和键合剂14之间的结合力。
在发明详述中引用的所有文献的相关部分均引入本文以供参考;任何文献的引用并不可理解为是对其作为本发明的现有技术的认可。尽管已用具体实施方案来说明和描述了本发明,但对于本领域的技术人员显而易见的是,在不背离本发明的精神和保护范围的情况下可作出许多其它的变化和修改。因此有意识地在附加的权利要求书中包括本发明范围内的所有这些变化和修改。
Claims (2)
1.一种用于将颜色传送到表面上的制品,所述制品包括:
具有相对第一和第二侧面的颜色片;
由所述颜色片的所述第一侧面负载的键合剂,所述键合剂能够将所述片粘合到所述表面上,所述颜色片和键合剂中的至少一种的特征在于厚度小于约0.076mm并且所述键合剂适于在室温下和在施加小于约50lbs/in2(3500克/平方厘米)的压力时,将所述制品粘附到表面上;和
可移除附着到所述颜色片的所述第二侧面上的可分离衬料。
2.如权利要求1所述的制品,其中当所述制品被缠绕在卷上以便所述可分离衬料接触所述键合剂时,所述可分离衬料和所述键合剂之间显示具有的总联合力小于所述片和所述可分离衬料之间显示具有的总联合力。
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US10/367,611 | 2003-02-14 | ||
US10/367,611 US20040161564A1 (en) | 2003-02-14 | 2003-02-14 | Dry paint transfer laminate |
US10/457,826 | 2003-06-09 |
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CNA2004800049421A Pending CN1753733A (zh) | 2003-02-14 | 2004-02-11 | 制备干燥油漆转移层压材料的挤出方法 |
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CNA2004800071317A Pending CN1761575A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
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CNA2004800037744A Pending CN1747831A (zh) | 2003-02-14 | 2004-02-13 | 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 |
CNA2004800076359A Pending CN1761578A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
CNA2004800037759A Pending CN1756671A (zh) | 2003-02-14 | 2004-02-13 | 用于施用到一个表面上的制品及其方法 |
CNA2004800076363A Pending CN1761579A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
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CNA2004800049421A Pending CN1753733A (zh) | 2003-02-14 | 2004-02-11 | 制备干燥油漆转移层压材料的挤出方法 |
CNB200480009775XA Expired - Fee Related CN100566991C (zh) | 2003-02-14 | 2004-02-11 | 干涂料转移层压材料 |
CNA2004800071317A Pending CN1761575A (zh) | 2003-02-14 | 2004-02-13 | 用于具有压敏粘合剂的自卷绕多层干粉涂漆装饰性层压材料的有差异的剥离体系 |
CNA2004800071232A Pending CN1761577A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
CNA2004800037744A Pending CN1747831A (zh) | 2003-02-14 | 2004-02-13 | 将颜色涂敷到表面上的耐脱色制品及减轻将颜色涂敷到表面上的制品内脱色的方法 |
CNA2004800076359A Pending CN1761578A (zh) | 2003-02-14 | 2004-02-13 | 具有防变色阻隔层的多层干粉涂漆装饰性层压材料 |
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-
2003
- 2003-02-14 US US10/367,611 patent/US20040161564A1/en not_active Abandoned
- 2003-06-09 US US10/457,791 patent/US7807246B2/en not_active Expired - Fee Related
- 2003-06-09 US US10/457,790 patent/US7905981B2/en not_active Expired - Fee Related
- 2003-06-09 US US10/457,826 patent/US7132142B2/en not_active Expired - Fee Related
- 2003-06-09 US US10/457,806 patent/US20040159969A1/en not_active Abandoned
-
2004
- 2004-02-11 CN CNA2004800049421A patent/CN1753733A/zh active Pending
- 2004-02-11 CN CNB200480009775XA patent/CN100566991C/zh not_active Expired - Fee Related
- 2004-02-13 CN CNA2004800071317A patent/CN1761575A/zh active Pending
- 2004-02-13 CN CNA2004800071232A patent/CN1761577A/zh active Pending
- 2004-02-13 CN CNA2004800037744A patent/CN1747831A/zh active Pending
- 2004-02-13 CN CNA2004800076359A patent/CN1761578A/zh active Pending
- 2004-02-13 CN CNA2004800037759A patent/CN1756671A/zh active Pending
- 2004-02-13 CN CNA2004800076363A patent/CN1761579A/zh active Pending
-
2005
- 2005-10-12 US US11/248,047 patent/US7722938B2/en not_active Expired - Fee Related
-
2006
- 2006-11-07 US US11/557,146 patent/US20070065621A1/en not_active Abandoned
-
2008
- 2008-07-02 JP JP2008173436A patent/JP2009006713A/ja active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116063874A (zh) * | 2016-09-07 | 2023-05-05 | Usg内部有限责任公司 | 透声涂层 |
Also Published As
Publication number | Publication date |
---|---|
US7905981B2 (en) | 2011-03-15 |
CN1761579A (zh) | 2006-04-19 |
US20070065621A1 (en) | 2007-03-22 |
US20040161568A1 (en) | 2004-08-19 |
US20040161567A1 (en) | 2004-08-19 |
CN1747831A (zh) | 2006-03-15 |
US20040159969A1 (en) | 2004-08-19 |
US20040161564A1 (en) | 2004-08-19 |
JP2009006713A (ja) | 2009-01-15 |
CN100566991C (zh) | 2009-12-09 |
CN1761577A (zh) | 2006-04-19 |
US7807246B2 (en) | 2010-10-05 |
US7722938B2 (en) | 2010-05-25 |
CN1761575A (zh) | 2006-04-19 |
CN1761578A (zh) | 2006-04-19 |
CN1753733A (zh) | 2006-03-29 |
US20040161566A1 (en) | 2004-08-19 |
CN1780731A (zh) | 2006-05-31 |
US7132142B2 (en) | 2006-11-07 |
US20060029765A1 (en) | 2006-02-09 |
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