CN1875424A - 成像的组合物、体系以及方法 - Google Patents
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Abstract
用于记录图像的体系。所述体系包括成像材料100，其中由感受剂材料吸收辐照能110。该感受剂材料可以选自酞菁和萘酞菁。
Description
背景技术
用于产生变色的材料在能量(例如光或热)的刺激下可能应用在成像方面。例如，用于热敏打印纸和瞬时成像胶片的这些材料。通常，迄今为止这样的材料和组合物可能要求多层结构和进一步处理以产生图像(例如瞬时照相胶片)。而在传真和热感应头介质的情况下，需要供给超过1-5J/cm2的高能量以获得好的成像。多层胶片介质中的组合物可能需要控制在形成颜色化学和进一步处理的扩散，在分开的相和层中也是如此。许多热敏和传真纸涂层由通过精细分散两种以上的组分制备的涂料构成。这些组分在施加能量的条件下混合和相互反应，得到彩色材料。为了必要的混合，这些微粒可能需要横贯三个或更多的相或层接触并且合并形成新的相。由于这些多个相和层，在实施这种工序中需要高的能量。例如，可能需要能量密度为3J/cm2以大大超过100μs的相对大功率的二氧化碳激光器以产生标记。在一些情况下，这种高能量的施加可能对成像基质造成破坏。
在许多情况下，为了更有效的产生可见标记，采用较低强度的、较低功率的和/或更短暂的能量施加可能是理想的。因此，需要快速标记涂料，该涂料可能由不足三个相构成并在单层中形成。一种有效的方法可以是提供粘合剂、染料、显色剂和感受剂(antenna)，其中染料在与显色剂反应时改变颜色，其中染料和显色剂之一在环境温度下可以溶解在粘合剂中，其中感受剂和溶于粘合剂的化合物溶解在粘合剂中；并且染料和显色剂化合物其中的另一种基本上均匀地分布在粘合剂中。在这样的体系中，如果感受剂基本上不是热和光稳定性的，换而言之，由于吸收了环境的能量(例如太阳光，人造光和/或环境的热量)，那么进行标记的能力将会消失或者降低。感受剂可以通过吸收能量而丧失性能和释放能量来形成影像。例如，就算是最初被认为是稳定的感受剂(也就是指它们的消光系数大于100000或者在暴露在光或热应激后，吸收损失低于20％)也可能对环境能量非常敏感以及可能在暴露在环境能量之后显示出降低的光标记能力。
此外，如果没有用足够的能量进行显影，所形成的图像可能褪色。例如，很多标记在暴露在40℃/80％的湿度之后三天可能褪色。褪色的原因可能由于感受剂未能向染料提供充足的能量，特别是由于暴露到光和热的作用下。因此，需要建立一个能够解决上面所述一个或多个问题的体系。
发明概述
本文公开了成像材料以及制备成像材料材料的方法。在此，所公开的材料包括选自包含酞菁生色团的化合物和包含萘酞菁生色团的化合物的化合物的感受剂。
附图简述
为了详细的描述本发明实施方案，先参照附图，其中：
附图1示出了根据本发明实施方案制备成像材料的一种方法。
附图2示出了根据本发明实施方案的一种成像介质。
注释和命名
在以下的描述和权利要求中用到某些术语是指特定体系组分。作为本领域技术人员可以理解的是，公司可以用不同名称命名组分。本文件并没有打算区分那些仅仅名称上而非功能上存在差异的组分。在下面的论述和权利要求中，术语“包含”和“包括”以开放的方式使用，并因此应该被理解成“包括但不限于…”。术语“无色染料”是指在未活化状态时为无色或单色的，在活化状态可以产生或者改变颜色的成色物质。这里用到的术语“活化剂”是一种可以与无色染料发生反应并导致“无色染料”改变其化学结构而改变或产生颜色的物质。仅举例来说，活化剂可以是可以引起变化的酚或者其他给质子物质。术语“感受剂”表示吸收辐照的化合物。感受剂很容易吸收所需特定波长的标记辐照并传递能量来形成标记。
发明详述
下面是针对本发明的多个实施方案的论述。这些公开的实施方案不能解释为，或者另外用于限定本公开包括权利要求书的范围。此外，本领域技术人员将理解下面描述具有宽的用途，并且任何具体实施方案的论述仅表示示例性的实施方案，而不是将本公开、包括权利要求书的范围限制到所述实施方案中。
本发明具体实施方案包括能形成在环境条件或接近环境条件下基本稳定的标记的涂层。能够在能量刺激下形成标志的材料包括：成色剂，例如荧烷(fluoran)无色染料和活化剂，例如磺酰基苯酚，其分散在诸如辐照固化的丙烯酸酯低聚物和单体的基体中，并施加到基材上。在一些实施方案中，无色染料或活化剂中可以在环境条件下基本上不溶于基体。涂层中还存在一种基本上稳定的、并具有吸收能量和将能量输送到反应物功能的辐射能吸收剂(例如感受剂)。然后，能量可能通过例如激光或红外线的方式进行提供。在施加能量的情况下，活化剂、成色物质或两者都被加热和混合，导致成色物质被活化，产生标记。
先参看附图2中阐述的实施方案，其中示出了影像介质100、能量110、基材120、成像组合物130、和悬浮粒子140。成像介质100可以包括基材120。基材120可以是任何适合的制造标记的基材，例如，仅以举例方式，纸(例如，标签、票据、收据或者文具)，幻灯片，或者光盘例如CD-R/RW/ROM或DVD-R/RW/ROM的标记表面。
成像组合物130可以包括基体、活化剂、感受剂和成色染料。活化剂和成色染料在混合时可能会改变颜色。活化剂或者成色染料中的一种可以溶解于基体中，另一组分(活化剂或成色染料)基本上不溶于基体，并且像均匀分布的悬浮粒子140一样悬浮在基体中。成像组合物130可以以任意能接受的方法施加到基材上，所述方法例如，仅举例性举出，辊轧、喷雾、丝网印刷。
能量110可以被成像式地引入到影像基质100。能量的形式可以根据可用的设备、环境条件和需要的结果而变化。能量的实例可以使用包括红外线辐照、紫外线辐照、X射线或可见光线。感受剂可以吸收该能量加热成像组合物130。这些热可能导致悬浮粒子140达到足以使原来存在于粒子中的成色物质相互扩散的温度(例如悬浮粒子140和基体的玻璃态转化温度(Tg)或融化温度(Tm))。活化剂和染料可能发生反应而形成颜色。非限制性的，感受剂可以选自以下化合物：
(A)硅2，3萘酞菁双(三己基甲硅烷基氧化物)(式1)(Aldrich38，993-5，来自Aldrich，P.O.Box 2060，Milwaukee，WI 53201)，和可溶于基体的2，3萘酞菁衍生物(式2)
其中R为-O-Si-(CH2(CH2)4CH3)3；
(B)在Rodgers，A.J.等人，PHYS.CHEM.A 3503-3514(2003年5月8日)中记载了可溶于基体的硅酞菁衍生物，和在Aoudia，Mohamed，119 J.AM.CHEM.SOC.6029-6039(1997年7月2日)，记载了可溶于基体的苯并酞菁衍生物(亚结构分别如式3和式4所示)：
R为三己基甲硅烷氧基
其中M为金属原子，和；
(C)如式5所示化合物的化合物(如公开于美国专利US6015896)
其中M为金属或氢；Pc为酞菁核；R1，R2，W1和W2独立地是H或任选取代的烷基、芳基或芳烷基；R3为氨基烷基基团；L为二价的有机连接基团；x，y和t分别独立地为0.5-2.5；并且(x+y+t)为3到4；
(D)如式6所示化合物的化合物(如公开于美国专利US6025486)
其中其中M为金属或氢；Pc为酞菁核；每一个R1独立地是H或任选取代的烷基、芳基或芳烷基；L1独立地为二价的有机连接基团；Z为任选取代的哌嗪基；q为1或2；x和y各自独立地具有0.5-3.5的值；并且(x+y)为2到5；或者
(E)800NP(一种专利染料，可由Avecia，PO Box 42，HexagonHouse，Blackley，Manchester M9 8ZS，England获得)。
活化剂(例如双酚-A)和成色染料90(例如2’-苯胺基-3’-甲基-6’-(二丁基氨基)荧烷，其结构如下式7所示)可以协力作用(act intandem)以形成标记。
活化剂和染料可以为任意两种在一起反应时导致颜色变化的物质。反应后，活化剂可能启动染料中的颜色变化或者使染料显影。活化剂或染料中的一种可能在环境条件下溶解于基料中(例如漆30)。另一种组分在环境条件下应该基本不溶于漆料中。这里提到的“基本不溶解”是指另一种组分在漆料中的溶解度如此低，使得在环境条件下染料和活化剂不会发生反应而导致色彩发生变化或者仅发生非常小的颜色变化。不过，在上述具体实施方案中，在环境条件下活化剂可以是溶解在漆料中的，以及染料以固体形式悬浮在基体中，同样的可以接受的是，在环境条件下成色物质可以是溶解在基体中，而活化剂可以保持为悬浮固体。活化剂可以包括但不限于质子供体和酚化合物例如双酚-A和双酚-S。成色物质可以包括但不限于无色染料例如荧烷无色染料和在″The Chemistry and Applications of Leuco Dyes″，Muthyala，Ramiah，ed.，Plenum Press(1997)(ISBN 0-306-45459-9)中记载的2-苯并呋喃酮成色剂，该文献在此引入作为参考。可以接受的荧烷无色染料的实例包括如式8所示的结构：
其中A和R为芳基或烷基。
漆料30可以为任何用于能够溶解和/或分散活化剂、感受剂和成色剂的基体。可以接受的漆料包括，仅为举例，具有photo package的能紫外固化的基体例如丙烯酸酯衍生物、低聚物和单体。
实施例1
参照附图1的实施方式，该图示出了根据本发明具体实施方案来制备成像溶液的方法，该方法可能包括活化剂熔体10、活化剂/感受剂溶液20、可紫外固化的漆溶液30、漆料/感受剂/活化剂溶液40和可紫外固化的两相糊剂50。
根据附图1中阐述的具体实施方案，将2克草酸二苄酯加热至熔化(约85℃)。将20克的双酚-A活化剂和1克的感受剂硅2，3萘酞菁双(三己基甲硅烷基氧化物)(式1)溶解在熔融的草酸二苄酯中。活化剂/感受剂溶液20被冷却并研磨得到细粉末70。
将5克被研磨的活化剂/感受剂粉末70溶解在15.3克Nor-CoteCDG000 UV漆料30中以形成漆料/感受剂/活化剂溶液40。
将10克的间三联苯50(作为加速剂)在烧杯中熔化。将熔体50加热至110。再在匀速搅拌的情况下向其中小剂量地滴加100克的2’-苯胺基-3’-甲基-6’-(二丁基氨基)荧烷(式9)
(使得平均粒度小于约5μm)。该混合物的温度升温至170-180℃。持续搅拌至2’-苯胺基-3’-甲基-6’-(二丁基氨基)荧烷完全溶解在熔体中(大概10-15分钟)，以形成加速剂/无色染料溶液。在匀速搅拌的情况下向其中加入550mg的硅2，3萘酞菁双(三己基甲硅烷基氧化物)(式1)。
另外继续加热和搅拌约2-3分钟，直到IR染料完全地溶解在熔体中形成无色染料/感受剂/加速剂的混合物(alloy)(共晶体)。无色染料/感受剂/加速剂混合物的温度保持在约190℃以下。
将无色染料/感受剂/加速剂的混合物倒入一个内衬有铝箔的预先冷却的制冷托盘中，在此使其固化。固化后的熔体被磨成粗粉末，然后在水分散体中研磨直至研磨混合物的平均粒度小于约4μm。真空干燥研磨所述混合物形成无色染料共晶粉末。
配制无色染料/感受剂/加速剂的混合物和漆料/感受剂/活化剂溶液40得到能紫外固化的糊剂50，然后将其以大致约5-约7μm的厚度丝网印刷在基材上形成成像介质。用水银灯将该介质上的涂层进行紫外线固化。
用45毫瓦的激光照射所得的经涂覆基材直接进行标记。以约30-约100μsec能量施加时间段产生了约为20μm×45μm的标记。当所需要的图像标记在成像介质上时，无需使用印刷中介物，直接进行成像。
实施例2
实施实施例1的方法，区别在于20克苯酚，4，4’-磺酰基双[2-(2-(丙烯基)-(9C1)(式10)
被用作活化剂和1.2克感受剂硅2，3萘酞菁双(三己基甲硅烷基氧化物)(式1)，溶解在熔融的草酸二苄酯中，形成活化剂/感受剂溶液20。活化剂/感受剂溶液20被冷却并研磨得到细粉末70。此外，用15克的2-苯胺基-3-甲基-6-(N-乙基-N-异戊基氨基)荧烷(式11)代替100克的2’-苯胺基-3’-甲基-6’-(二丁基氨基)荧烷来作为无色染料(平均粒度小于5μm)用来形成加速剂/无色染料溶液。
同实施例1一样，无色染料/感受剂/加速剂的混合物和漆料/感受剂/活化剂溶液40经配制得到可紫外固化的糊剂90，并以约7μm的厚度丝网印刷到基材上形成成像介质。用水银灯将该介质上的涂层进行紫外固化。用45毫瓦的激光在所得的经涂覆基材上进行直接标记。用约60-100μsec的能量施加获得了光学密度大于0.5的大小约为20μm×45μm的标志。
采用吲哚花氰绿(Aldrich 22886-9)(式12)作为感受剂e进行相似的工序；
IR 780(Aldrich 42，531-1)(式13)；和800NP
将涂层暴露在21000lux的荧光灯下24小时，根据标记速度和光密度进行筛选。在用光处理后，包含吲哚花氰绿或IR 780的涂层没有显示任何标记。包含硅2，3萘酞菁双(三己基甲硅烷基氧化物)(式1)感受剂或800NP的涂层在曝光后，显示出低于20％的光密度下降。
上述论述是指对本发明原理和各种实施方案的示例性说明。一旦完全理解了上述公开，许多变形和改进对于本领域技术人员将是显而易见的。以下的权利要求意图被解释为涵盖所有这些变形和改进。
Claims (9)
1、一种直接光成像化合物130，包括：
基体，和感受剂，
其中该感受剂包括选自包括酞菁生色团的化合物和包括萘酞菁生色团的化合物的化合物，并且其中所述感受剂溶解在基体中。
2、权利要求1的化合物，还包括：
成色剂和活化剂，其中活化剂和成色剂中的一种在环境条件下可溶于基体或基体前体中；其中活化剂和成色剂中能溶解的组分溶解在基体中，并且，其中活化剂和成色剂的另一组分基本均匀分布140在基体中。
3、上述权利要求中任一项的化合物，其中所述感受剂选自(A)硅2，3萘酞菁双(三己基甲硅烷基氧化物)；(B)2，3萘酞菁的衍生物；(C)硅酞菁的衍生物；(D)苯并酞菁的衍生物；(E)
其中M为金属或氢；Pc为酞菁核；R1，R2，W1和W2独立地是H或任选取代的烷基、芳基或芳烷基；R3为氨基烷基；L为二价的有机连接基团；x，y和t分别独立地为0.5-2.5；并且(x+y+t)为3到4；(F)
其中其中M为金属或氢；Pc为酞菁核；每一个R1独立地是H或任选取代的烷基、芳基或芳烷基；每一个L1独立地为二价的有机连接基团；Z为任选取代的哌嗪基；q为1或2；x和y分别独立地具有0.5-3.5的值；并且(x+y)为2到5；和(G)800NP。
4、上述权利要求任一项的化合物，其中感受剂被调节为易于吸收预定频率的激光辐射110。
5、上述权利要求任一项的化合物，其中感受剂被调节为易于吸收预定频率的红外辐射110。
6、一种制备直接光成像材料130的方法，该方法包括：
提供粘合剂、染料、显色剂和感受剂，
其中所述感受剂溶解于粘合剂中并选自包括酞菁生色团的化合物和包括萘酞菁生色团的化合物；
其中染料在与显色剂反应时改变颜色；和
在环境条件下，染料和显色剂的一种可以溶解在粘合剂中；
将感受剂和能溶于粘合剂的化合物溶解在粘合剂中，和
将染料和显色剂的另一组分140化合物基本上均匀分布在粘合剂中。
7、权利要求6的方法，其中感受剂被调节为能吸收预定频率的红外辐射110。
8、权利要求6或7的方法，其中感受剂被调节为能吸收预定频率的激光辐射110。
9、权利要求6-8的方法，其中感受剂选自(A)硅2，3萘酞菁双(三己基甲硅烷基氧化物)；(B)2，3萘酞菁衍生物；(C)硅酞菁衍生物；(D)苯并酞菁衍生物；(E)
其中M为金属或氢；Pc为酞菁核；R1，R2，W1和W2独立地是H或任选取代的烷基、芳基或芳烷基；R3为氨基烷基；L为二价的有机连接基团；x，y和t分别独立地为0.5-2.5；并且(x+y+t)为3到4；(F)
其中其中M为金属或氢；Pc为酞菁核；每一个R1独立地是H或任选取代的烷基、芳基或芳烷基；每一个L1独立地为二价的有机连接基团；Z为任选取代的哌嗪基；q为1或2；x和y分别独立地具有0.5-3.5的值；并且(x+y)为2到5；和(G)800NP。
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| PCT/US2004/028354 WO2005027130A1 (en) | 2003-09-05 | 2004-08-31 | Compositions, systems, and methods for imaging |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102224458B (zh) * | 2008-10-15 | 2013-04-24 | 国际纸业公司 | 组合物、制备方法以及施加和曝光光成像纸张的方法 |
| US8586279B2 (en) | 2008-10-15 | 2013-11-19 | International Paper Company | Imaging particulates, paper and process, and imaging of paper using dual wavelength light |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7083904B2 (en) * | 2003-09-05 | 2006-08-01 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7198834B2 (en) * | 2005-03-22 | 2007-04-03 | Hewlett-Packard Development Company, L.P. | Imaging media including interference layer for generating human-readable marking on optical media |
| US20070065623A1 (en) * | 2005-09-21 | 2007-03-22 | Vladek Kasperchik | Laser-imageable coating based on exothermic decomposition |
| US20070065749A1 (en) | 2005-09-21 | 2007-03-22 | Vladek Kasperchik | Radiation-markable coatings for printing and imaging |
| US20070086308A1 (en) * | 2005-10-13 | 2007-04-19 | Gore Makarand P | Systems and methods for imaging |
| US7390610B2 (en) * | 2005-10-18 | 2008-06-24 | Hewlett-Packard Development Company, L.P. | Color forming composition |
| US20070105039A1 (en) * | 2005-10-18 | 2007-05-10 | Vladek Kasperchik | Dual band color forming composition |
| US20070092827A1 (en) * | 2005-10-20 | 2007-04-26 | Gore Makarand P | Inks for use on light-activated imaging media |
| US7935471B2 (en) * | 2005-10-20 | 2011-05-03 | Hewlett-Packard Development Company, L.P. | NIR/IR curable coatings for light directed imaging |
| US20070248918A1 (en) * | 2006-04-25 | 2007-10-25 | Vladek Kasperchik | Compositions, systems and methods for imaging |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3399A (en) * | 1844-01-06 | jnoq xbooth a andx w wm | ||
| US3658543A (en) * | 1970-12-18 | 1972-04-25 | Du Pont | Dual response photosensitive composition containing acyl ester of triethanolamine |
| JPS5389434A (en) * | 1977-01-17 | 1978-08-07 | Mita Industrial Co Ltd | Stacked photosensitive body for electrophotography |
| US4142151A (en) * | 1977-07-25 | 1979-02-27 | General Electric Company | Failed diode indicator |
| US4170190A (en) * | 1978-04-04 | 1979-10-09 | Warner John H | Method for detecting and a detector for indicating excessive temperature at electrical wiring devices |
| FR2527822B1 (zh) * | 1982-05-31 | 1987-04-17 | Nippon Telegraph & Telephone | |
| JPS6163491A (ja) | 1984-09-06 | 1986-04-01 | Canon Inc | 光記録素子 |
| US4682857A (en) * | 1985-04-02 | 1987-07-28 | Peng Tan | Liquid crystal hot spot detection with infinitesimal temperature control |
| JPS61239444A (ja) | 1985-04-15 | 1986-10-24 | Nippon Telegr & Teleph Corp <Ntt> | レ−ザ光感熱記録媒体 |
| US4838664A (en) * | 1986-07-10 | 1989-06-13 | Brent Graham | Diagnostic overlay |
| US4835475A (en) * | 1986-11-17 | 1989-05-30 | Niichi Hanakura | Battery tester including a thermochromic material |
| US4835476A (en) * | 1986-11-28 | 1989-05-30 | Three Tec Davis Inc. | Voltage measuring sheet |
| US4891250A (en) * | 1988-02-17 | 1990-01-02 | Weibe Edward W | Electronic component operating temperature indicator |
| KR0171182B1 (ko) * | 1988-07-18 | 1999-04-15 | 와따나베 히로시 | 정보기록메체 및 그 제조방법 |
| JP2718785B2 (ja) * | 1988-10-25 | 1998-02-25 | 日立化成工業株式会社 | ナフタロシアニン誘導体及びその製造法並びにそれを用いた光学記録媒体及びその光学記録媒体の製造法 |
| US5039600A (en) * | 1989-01-11 | 1991-08-13 | Hitachi Chemical Company, Ltd. | Naphthalocyanine derivatives, production thereof, optical recording medium using the same, and production thereof |
| JP2564642B2 (ja) * | 1989-02-20 | 1996-12-18 | 日本製紙株式会社 | 光記録体 |
| US5409797A (en) * | 1991-03-04 | 1995-04-25 | Fuji Photo Film Co., Ltd. | Heat-sensitive recording material for laser recording |
| EP0676298B1 (en) * | 1991-06-24 | 1997-03-05 | Nippon Paper Industries Co., Ltd. | Transparent recording medium and process for its production |
| US5464673A (en) * | 1991-08-08 | 1995-11-07 | Hitachi Chemical Co., Ltd. | Information recording medium having recording layer with organic polymer and dye contained therein |
| US5294374A (en) * | 1992-03-20 | 1994-03-15 | Leviton Manufacturing Co., Inc. | Electrical overstress materials and method of manufacture |
| JPH05278329A (ja) * | 1992-03-31 | 1993-10-26 | Fuji Photo Film Co Ltd | レーザー記録用感熱記録材料 |
| US5322762A (en) * | 1992-04-13 | 1994-06-21 | Mitsubishi Rayon Co., Ltd. | Photopolymerizable composition |
| JP3125240B2 (ja) | 1992-10-12 | 2001-01-15 | コニカ株式会社 | 電子写真感光体 |
| CA2110233C (en) * | 1992-12-02 | 1999-01-12 | Mitsui Toatsu Chemicals, Incorporated | Optical information recording medium and composition for optical information recording film |
| US5673028A (en) * | 1993-01-07 | 1997-09-30 | Levy; Henry A. | Electronic component failure indicator |
| JPH082106A (ja) | 1994-06-24 | 1996-01-09 | Nippon Kayaku Co Ltd | マーキング用組成物及びレーザーマーキング方法 |
| JPH06257362A (ja) | 1993-03-08 | 1994-09-13 | Koken Kogyo Kk | 削孔装置 |
| US5691757A (en) * | 1993-12-22 | 1997-11-25 | Nippon Kayaku Kabushiki Kaisha | Laser marking method and aqueous laser marking composition |
| US5543382A (en) * | 1993-12-27 | 1996-08-06 | New Oji Paper Co., Ltd. | Heat-sensitive recording paper |
| US6057067A (en) * | 1994-07-11 | 2000-05-02 | 3M Innovative Properties Company | Method for preparing integral black matrix/color filter elements |
| US5460646A (en) * | 1994-11-10 | 1995-10-24 | Sia Technology Corporation | Infrared printing ink and method of making same |
| DE19501114C2 (de) * | 1995-01-17 | 2001-01-18 | Gerd Hugo | Anstrichstoff mit reflektierenden Eigenschaften in zwei Wellenlängenbereichen und absorbierenden Eigenschaften in einem dritten Wellenlängenbereich |
| US5679661A (en) * | 1995-07-25 | 1997-10-21 | The Procter & Gamble Company | Low hue photodisinfectants |
| GB9520490D0 (en) * | 1995-10-07 | 1995-12-13 | Zeneca Ltd | Compounds |
| GB9520491D0 (en) * | 1995-10-07 | 1995-12-13 | Zeneca Ltd | Compounds |
| JP3139381B2 (ja) * | 1996-01-18 | 2001-02-26 | 富士電機株式会社 | 電子写真用感光体およびその製造方法 |
| US6022648A (en) * | 1996-03-08 | 2000-02-08 | Massachusetts Institute Of Technology | Bistable, thermochromic recording method for rendering color and gray scale |
| US6436600B1 (en) * | 1998-01-06 | 2002-08-20 | Asahi Kogaku Kogyo Kabushiki Kaisha | Image-forming substrate and image-forming system using same |
| US6078183A (en) * | 1998-03-03 | 2000-06-20 | Sandia Corporation | Thermally-induced voltage alteration for integrated circuit analysis |
| US6251571B1 (en) * | 1998-03-10 | 2001-06-26 | E. I. Du Pont De Nemours And Company | Non-photosensitive, thermally imageable element having improved room light stability |
| CA2269566C (en) * | 1998-04-21 | 2003-01-21 | Nec Corporation | Photoreceptor for electrophotography and method of manufacturing the same |
| US6137669A (en) * | 1998-10-28 | 2000-10-24 | Chiang; Justin N. | Sensor |
| GB9906011D0 (en) * | 1999-03-16 | 1999-05-12 | Whiley Foils Ltd | Fluorescent materials |
| JP2000296682A (ja) * | 1999-04-15 | 2000-10-24 | Fuji Photo Film Co Ltd | 平版印刷版の製造方法 |
| US6323340B1 (en) * | 1999-07-30 | 2001-11-27 | Nippon Shobukai Co., Ltd. | Phthalocyanine compound, method for production thereof, and near infrared absorption dye using the compound |
| AU2001238462A1 (en) * | 2000-02-16 | 2001-08-27 | Arcturus Engineering, Inc. | Transfer film for laser microcapture |
| US6486473B2 (en) * | 2000-03-02 | 2002-11-26 | Mine Safety Applicances Company | Thermal imaging camera |
| US6549025B1 (en) * | 2000-07-06 | 2003-04-15 | Advanced Micro Devices, Inc. | System and method for thermal testing of circuit boards using thermal films |
| JP2002059655A (ja) * | 2000-08-23 | 2002-02-26 | Saito Kaseihin Kenkyusho:Kk | 感熱記録材料 |
| US6864040B2 (en) | 2001-04-11 | 2005-03-08 | Kodak Polychrome Graphics Llc | Thermal initiator system using leuco dyes and polyhalogene compounds |
| US6613716B2 (en) * | 2001-02-13 | 2003-09-02 | Miami Wabash Paper Llc | Thermal print paper and process |
| JP2003004939A (ja) * | 2001-06-25 | 2003-01-08 | Asahi Glass Co Ltd | 光学フィルム |
| JP2003149838A (ja) | 2001-11-16 | 2003-05-21 | Konica Corp | 電子写真感光体、それを用いた画像形成装置及びプロセスカートリッジ |
| JP2003178488A (ja) | 2001-12-11 | 2003-06-27 | Fuji Photo Film Co Ltd | 光記録媒体 |
| US6815679B2 (en) * | 2002-02-13 | 2004-11-09 | Mitsubishi Paper Mills Limited | Reversible thermal recording material and method of recording image on reversible thermal recording material |
| US20040146612A1 (en) * | 2003-01-07 | 2004-07-29 | Owades Joseph L. | Method for treating foods and beverages to hide odor of trans-2-nonenal and foods and beverages so treated |
| US6974661B2 (en) * | 2003-01-24 | 2005-12-13 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7083904B2 (en) * | 2003-09-05 | 2006-08-01 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7169542B2 (en) * | 2003-10-28 | 2007-01-30 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
-
2003
- 2003-09-05 US US10/656,021 patent/US7083904B2/en not_active Expired - Fee Related
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2004
- 2004-03-16 TW TW093106998A patent/TWI310000B/zh not_active IP Right Cessation
- 2004-08-31 GB GB0603606A patent/GB2421804B/en not_active Expired - Fee Related
- 2004-08-31 WO PCT/US2004/028354 patent/WO2005027130A1/en active Application Filing
- 2004-08-31 CN CN200480032729.1A patent/CN1875424B/zh not_active Expired - Fee Related
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2006
- 2006-06-02 US US11/421,880 patent/US7314705B2/en not_active Expired - Lifetime
- 2006-12-28 HK HK06114221A patent/HK1093786A1/xx not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102224458B (zh) * | 2008-10-15 | 2013-04-24 | 国际纸业公司 | 组合物、制备方法以及施加和曝光光成像纸张的方法 |
| US8586279B2 (en) | 2008-10-15 | 2013-11-19 | International Paper Company | Imaging particulates, paper and process, and imaging of paper using dual wavelength light |
| US8586280B2 (en) | 2008-10-15 | 2013-11-19 | International Paper Company | Composition, process of preparation and method of application and exposure for light imaging paper |
| US8980523B2 (en) | 2008-10-15 | 2015-03-17 | International Paper Company | Imaging particulates, paper and process, and imaging of paper using dual wavelength light |
Also Published As
| Publication number | Publication date |
|---|---|
| US7083904B2 (en) | 2006-08-01 |
| TW200510924A (en) | 2005-03-16 |
| CN1875424B (zh) | 2010-09-01 |
| GB2421804A (en) | 2006-07-05 |
| GB2421804B (en) | 2007-06-06 |
| GB0603606D0 (en) | 2006-04-05 |
| US7314705B2 (en) | 2008-01-01 |
| US20050053860A1 (en) | 2005-03-10 |
| WO2005027130A1 (en) | 2005-03-24 |
| TWI310000B (en) | 2009-05-21 |
| HK1093786A1 (en) | 2007-03-09 |
| US20060216655A1 (en) | 2006-09-28 |
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