DE102009055442A1 - Graphite-containing plate comprises a solidified mixture of largely uniformly distributed graphite particles and plastic particles, where the graphite particles and plastic particles are distributed homogeneously into the mixture - Google Patents

Graphite-containing plate comprises a solidified mixture of largely uniformly distributed graphite particles and plastic particles, where the graphite particles and plastic particles are distributed homogeneously into the mixture Download PDF

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Publication number
DE102009055442A1
DE102009055442A1 DE102009055442A DE102009055442A DE102009055442A1 DE 102009055442 A1 DE102009055442 A1 DE 102009055442A1 DE 102009055442 A DE102009055442 A DE 102009055442A DE 102009055442 A DE102009055442 A DE 102009055442A DE 102009055442 A1 DE102009055442 A1 DE 102009055442A1
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Germany
Prior art keywords
mixture
graphite
plate
particles
plastic particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE102009055442A
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German (de)
Inventor
Christian Dr. 95119 Kipfelsberger
Werner 86674 Guckert
Siegfried 86368 Rauch
Robert 86672 Michels
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SGL Carbon SE
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SGL Carbon SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SGL Carbon SE filed Critical SGL Carbon SE
Priority to DE202009018618U priority Critical patent/DE202009018618U1/en
Priority to DE102009055442A priority patent/DE102009055442A1/en
Priority to SG2012048468A priority patent/SG182296A1/en
Priority to CN2010800646432A priority patent/CN102781876A/en
Priority to US13/520,273 priority patent/US20130040194A1/en
Priority to SG2012048435A priority patent/SG181988A1/en
Priority to CA2786150A priority patent/CA2786150A1/en
Priority to JP2012546459A priority patent/JP2013516505A/en
Priority to KR20127020054A priority patent/KR20120112676A/en
Priority to PCT/EP2010/070974 priority patent/WO2011080334A2/en
Priority to EP10803462A priority patent/EP2519480A2/en
Priority to PCT/EP2010/070977 priority patent/WO2011080337A1/en
Priority to US13/520,219 priority patent/US20130032278A1/en
Priority to PCT/EP2010/070978 priority patent/WO2011080338A1/en
Priority to SG2012048393A priority patent/SG182294A1/en
Priority to ES10798152.4T priority patent/ES2641013T3/en
Priority to JP2012546456A priority patent/JP2013516374A/en
Priority to EP10803101A priority patent/EP2519782A1/en
Priority to CN2010800640671A priority patent/CN102792101A/en
Priority to EP10803102.2A priority patent/EP2519783B1/en
Priority to CN2010800646447A priority patent/CN102781877A/en
Priority to KR20127020055A priority patent/KR20120110151A/en
Priority to JP2012546455A priority patent/JP2013527964A/en
Priority to EP10803103A priority patent/EP2519576A1/en
Priority to PCT/EP2010/070979 priority patent/WO2011080339A1/en
Priority to PCT/EP2010/070976 priority patent/WO2011080336A2/en
Priority to CA2786143A priority patent/CA2786143A1/en
Priority to CN2010800648207A priority patent/CN102869711A/en
Priority to CA2786134A priority patent/CA2786134A1/en
Priority to PL10803102T priority patent/PL2519783T3/en
Priority to CA 2786180 priority patent/CA2786180A1/en
Priority to EP10798152.4A priority patent/EP2519479B1/en
Priority to US13/520,222 priority patent/US20130032750A1/en
Priority to CA2786157A priority patent/CA2786157C/en
Priority to US13/520,223 priority patent/US20130192793A1/en
Publication of DE102009055442A1 publication Critical patent/DE102009055442A1/en
Priority to US13/540,039 priority patent/US20130168040A1/en
Ceased legal-status Critical Current

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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
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    • H05B3/12Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/145Carbon only, e.g. carbon black, graphite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/58Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
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    • F28F1/12Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
    • F28F1/14Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending longitudinally
    • F28F1/22Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending longitudinally the means having portions engaging further tubular elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/02Constructions of heat-exchange apparatus characterised by the selection of particular materials of carbon, e.g. graphite
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/06Constructions of heat-exchange apparatus characterised by the selection of particular materials of plastics material
    • F28F21/061Constructions of heat-exchange apparatus characterised by the selection of particular materials of plastics material for domestic or space-heating systems
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N23/00Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
    • G01N23/02Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by transmitting the radiation through the material
    • G01N23/06Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by transmitting the radiation through the material and measuring the absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2103/00Use of resin-bonded materials as moulding material
    • B29K2103/04Inorganic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2507/00Use of elements other than metals as filler
    • B29K2507/04Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/604Pressing at temperatures other than sintering temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D11/00Central heating systems using heat accumulated in storage masses
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D2220/00Components of central heating installations excluding heat sources
    • F24D2220/10Heat storage materials, e.g. phase change materials or static water enclosed in a space
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00Hot-water central heating systems
    • F24D3/12Tube and panel arrangements for ceiling, wall, or underfloor heating
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2223/00Investigating materials by wave or particle radiation
    • G01N2223/30Accessories, mechanical or electrical features
    • G01N2223/33Accessories, mechanical or electrical features scanning, i.e. relative motion for measurement of successive object-parts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]

Abstract

The graphite-containing plate (5) comprises a solidified mixture of largely uniformly distributed graphite particles (6) and plastic particles (7), where the graphite particles and plastic particles are distributed homogeneously into the mixture. A component (9) is embedded in the plate. The graphite particle contains expanded graphite. The mixture contains 15-60 wt% of graphite particles and 20-50 wt.% of plastic particles. The plastic particles contain thermoplastics and/or thermosetting plastics. The plastic is malleable. The plate is formed in a predetermined contour.

Description

Die Erfindung betrifft eine graphithaltige Platte nach dem Oberbegriff des Anspruchs 1 sowie ein Verfahren zur Herstellung einer graphithaltigen Platte.The invention relates to a graphite-containing plate according to the preamble of claim 1 and to a method for producing a graphite-containing plate.

Aus der DE 103 41 255 B4 ist eine Leichtbau-Wärmeleitplatte sowie ein Verfahren zu deren Herstellung bekannt. Diese Wärmeleitplatte wird aus an sich bekanntem expandierten Graphit (Graphitexpandat) durch Verdichtung hergestellt. Die Herstellung von expandiertem Graphit ist aus dem Stand der Technik hinlänglich bekannt, u. a. aus der US 3,404,061 A . So werden zur Herstellung von expandiertem Graphit Graphiteinlagerungsverbindungen bzw. Graphitsalze wie z. B. Graphithydrogensulfat oder Graphitnitrat schockartig erhitzt. Dabei vergrößert sich das Volumen der Graphitpartikel um einen Faktor von ca. 200–400 und gleichzeitig sinkt die Schüttdichte auf Werte von 2–20 g/l. Das so erhaltene Graphitexpandat besteht aus wurm- bzw. ziehharmonikaförmigen Aggregaten. Bei der Leichtbau-Wärmeleitplatte der DE 103 41 255 B4 wird derartiges Graphitexpandat unter gerichteter Einwirkung eines Drucks kompaktiert, so dass sich die Schichtebenen des Graphits bevorzugt senkrecht zur Einwirkungsrichtung des Drucks anordnen und sich die einzelnen Aggregate untereinander verhaken. Hierdurch lassen sich ohne Zusatz von Bindemitteln selbsttragende, flächige Gebilde wie Bahnen oder Platten herstellen. Solchermaßen kompaktierte Wärmeleitplatten ohne Bindemittel sind zwar grundsätzlich formstabil, weisen jedoch eine geringe Festigkeit auf, brechen also bei relativ geringen Belastungen leicht auseinander. So weisen beispielsweise rechteckige Wärmeleitplatten mit einem Flächengewicht von 1000 g/m2, einer Dicke von 13 mm und der Größe 11 × 13 cm lediglich eine Biegefestigkeit von 0,1 MPa auf. Es können deshalb lediglich formstabile Platten mit relativ geringen Abmessungen, z. B. 50 × 50 cm hergestellt werden, da größere Platten nicht mehr handhabbar sind. Insbesondere führt bereits das Eigengewicht größerer Platten dazu, dass die Platte beim Anhaben an nur einer Seitenkante bricht. Diese Platten sind deshalb für die Verwendung im Baubereich ohne zusätzliche Versteifungen nicht geeignet.From the DE 103 41 255 B4 is a lightweight heat conduction and a process for their preparation is known. This heat conduction plate is made of known per se expanded graphite (Graphitexpandat) by compaction. The production of expanded graphite is well known from the prior art, including from US 3,404,061 A , Thus, for the production of expanded graphite Graphiteinlagerungsverbindungen or graphite salts such. B. graphite hydrogen sulfate or graphite nitrate shock-heated. The volume of the graphite particles increases by a factor of about 200-400 and at the same time the bulk density drops to values of 2-20 g / l. The graphite expandate thus obtained consists of worm-shaped or accordion-shaped aggregates. In the lightweight thermal plate of DE 103 41 255 B4 If such Graphitexpandat is compacted under the direction of a pressure, so that the layer planes of the graphite preferably arranged perpendicular to the direction of action of the pressure and the individual units interlock with each other. As a result, self-supporting, flat structures such as webs or plates can be produced without the addition of binders. Such compacted heat conducting plates without binders are basically dimensionally stable, but have a low strength, so they break apart easily at relatively low loads. For example, rectangular heat conducting plates having a weight per unit area of 1000 g / m 2 , a thickness of 13 mm and a size of 11 × 13 cm only have a bending strength of 0.1 MPa. It can therefore only dimensionally stable plates with relatively small dimensions, for. B. 50 × 50 cm are made because larger plates are no longer manageable. In particular, even the weight of larger plates to the fact that the plate breaks when it touches on only one side edge. These panels are therefore not suitable for use in the construction sector without additional stiffeners.

Um diesen Nachteil zu überwinden, schlägt die DE 103 41 255 B4 vor, die Wärmeleitplatten nach dem Verpressen komplett oder teilweise mit Kunststoffen, beispielsweise Harzen oder Thermoplasten zu imprägnieren, um die Dichtigkeit und die Beständigkeit gegen mechanische und andere Umwelteinwirkungen zu erhöhen. Diese nachträgliche Flüssigimprägnierung der verpressten Graphitexpandatplatten weist jedoch den Nachteil auf, dass die Infiltration des expandierten, verdichteten Graphits mit den flüssigen Bindemitteln ungleichmäßig erfolgt. So wurde bereits bei Folien aus verdichtetem expandiertem Graphit festgestellt, dass sie lediglich in oberflächennahen Bereich gleichmäßig infiltriert werden. In weiter innen liegende Bereiche der Folien dringt das Bindemittel nur noch unzureichend oder gar nicht ein. Gleiches gilt in noch stärkerem Maß für die gegenüber Folien deutlich dickeren Platten aus verdichtetem expandiertem Graphit. Diese ungleichmäßige Verteilung des Bindemittels führt zu einer ungleichmäßige Steifigkeit und Stabilität der Platten, so dass die Platten an von außen nicht erkennbaren Stellen leichter brechen als an anderen.To overcome this disadvantage, the beats DE 103 41 255 B4 prior to impregnation, the heat-conducting plates completely or partially impregnate with plastics, such as resins or thermoplastics in order to increase the tightness and resistance to mechanical and other environmental effects. However, this subsequent liquid impregnation of the compressed Graphitexpandatplatten has the disadvantage that the infiltration of the expanded, compacted graphite is carried out unevenly with the liquid binders. For example, it has already been found in films of compressed expanded graphite that they are uniformly infiltrated only in the area close to the surface. In more interior areas of the films penetrates the binder only insufficient or not at all. The same applies to an even greater extent for the sheets of thicker expanded graphite, which are significantly thicker than foils. This uneven distribution of the binder results in uneven stiffness and stability of the panels, such that the panels break more easily at locations not recognizable from outside than at others.

In 1 ist ein schematischer Querschnitt durch eine derartige Leichtbau-Wärmeleitplatte 1 gezeigt. Dort ist verpresster, expandierter Graphit 2 von den Seitenflächen der Platte 1 aus nachträglich mit einem flüssigen Bindemittel 3 infiltriert worden. Das Bindemittel 3 ist jedoch nur ungleichmäßig in die Platte eingedrungen, so dass insbesondere ein durch die ovale, gestrichelte Umrandung gekennzeichneter Bereich 4 bindemittelfrei 3 und somit deutlich weniger steif und stabil als angrenzende Bereiche der Platte 1 ist. Dieser Bereich 4 ist somit bruchgefährdeter als die angrenzenden Bereiche der Platte 1.In 1 is a schematic cross section through such a lightweight heat conduction plate 1 shown. There is compressed, expanded graphite 2 from the side surfaces of the plate 1 subsequently with a liquid binder 3 been infiltrated. The binder 3 However, it has only unevenly penetrated into the plate, so that in particular a marked by the oval, dashed border area 4 binder-free 3 and thus significantly less stiff and stable than adjacent areas of the plate 1 is. This area 4 is thus more vulnerable to breakage than the adjacent areas of the plate 1 ,

Es ist deshalb Aufgabe der Erfindung, eine graphithaltigen Platte und ein Verfahren zur Herstellung einer graphithaltigen Platte bereitzustellen, welche die oben genannten Nachteile überwinden und eine gleichmäßig steife und formstabile Platte bereitstellen.It is therefore an object of the invention to provide a graphite-containing plate and a method for producing a graphite-containing plate, which overcome the above-mentioned disadvantages and provide a uniformly rigid and dimensionally stable plate.

Diese Aufgabe wird durch eine graphithaltigen Platte mit den Merkmalen des Anspruchs 1 sowie ein Verfahren zur Herstellung einer graphithaltigen Platte mit den Merkmalen des Anspruchs 10 gelöst. Vorteilhafte Weiterbildungen und bevorzugte Ausgestaltungen der Platte und des Verfahrens sind in den Unteransprüchen angegeben.This object is achieved by a graphite-containing plate having the features of claim 1 and a method for producing a graphite-containing plate having the features of claim 10. Advantageous developments and preferred embodiments of the plate and the method are specified in the subclaims.

Eine erfindungsgemäße graphithaltige Platte ist dadurch gekennzeichnet, dass sie ein verfestigtes Gemisch aus weitgehend gleichmäßig verteilten Graphitpartikeln und Kunststoffpartikeln enthält, wobei diese Platte erfindungsgemäß dadurch hergestellt werden kann, dass Graphitpartikel und Kunststoffpartikel zunächst zu einem Gemisch mit weitgehend gleichmäßiger Verteilung der Graphitpartikel und Kunststoffpartikel vermischt werden und das Gemisch anschließend verfestigt wird.A graphite-containing plate according to the invention is characterized in that it contains a solidified mixture of largely uniformly distributed graphite particles and plastic particles, which plate can be produced according to the invention by first mixing graphite particles and plastic particles into a mixture with a substantially uniform distribution of the graphite particles and plastic particles, and the mixture is then solidified.

In einer bevorzugten Ausführung können die Graphitpartikel und Kunststoffpartikel homogen in dem Gemisch verteilt sein, was u. a. durch ausreichend lange Vermischung der Partikel erreicht werden kann.In a preferred embodiment, the graphite particles and plastic particles may be homogeneously distributed in the mixture, which u. a. can be achieved by sufficiently long mixing of the particles.

In einer fertigungstechnisch vorteilhaften Ausführung kann die Platte ausschließlich aus dem Gemisch aus Graphitpartikeln und Kunststoffpartikeln bestehen, ohne weitere Zusatzstoffe beifügen zu müssen. sind zum Erhalt einer formstabilen Platte nicht notwendig.In a production-technically advantageous embodiment, the plate can only from the mixture of graphite particles and Plastic particles exist without having to add any additional additives. are not necessary to obtain a dimensionally stable plate.

Vorteilhaft kann das Gemisch 5 bis 90 Gewichts-%, bevorzugt 15 bis 60 Gewichts-% und besonders bevorzugt 20 bis 50 Gewichts-% an Kunststoffpartikeln enthalten, um eine ausreichend stabile Platte zu erhalten.Advantageously, the mixture may contain from 5 to 90% by weight, preferably from 15 to 60% by weight, and more preferably from 20 to 50% by weight, of plastic particles in order to obtain a sufficiently stable plate.

Die Graphitpartikel können vorteilhaft expandierten Graphit, und besonders vorteilhaft ausschließlich expandierten Graphit enthalten. Die Kunststoffpartikel können vorteilhaft Thermoplaste und/oder Duroplaste enthalten.The graphite particles may advantageously contain expanded graphite, and more preferably exclusively expanded graphite. The plastic particles may advantageously contain thermoplastics and / or thermosets.

In einer bevorzugten Ausführung kann als Kunststoff PVC verwendet werden, da es auch bei Temperaturen über 80°C eingesetzt werden kann. Besonders vorteilhaft ist dies bei der vorteilhaften Verwendung der erfindungsgemäßen Platte als thermisch wirksames Bauelement zur Heizung von Räumen, da Temperaturen von Heizmedien üblicherweise bis zu 60°C betragen.In a preferred embodiment can be used as plastic PVC, since it can also be used at temperatures above 80 ° C. This is particularly advantageous in the advantageous use of the plate according to the invention as a thermally active device for heating rooms, since temperatures of heating media are usually up to 60 ° C.

Als weitere geeignete Thermoplaste können für die Kunststoffpartikel vorteilhaft Polypropylen (PP), Polyamide (PA), Acrylnitril-Butadien-Styrol (ABS), Polyetherketon (PEEK), Polyvinylidenfluorid (PVDF), Fluoropolymere, Benzoxazine und/oder Polysulfon (PP) verwendet werden.As further suitable thermoplastics, polypropylene (PP), polyamides (PA), acrylonitrile-butadiene-styrene (ABS), polyetherketone (PEEK), polyvinylidene fluoride (PVDF), fluoropolymers, benzoxazines and / or polysulfone (PP) can advantageously be used for the plastic particles ,

Ein geeignetes Duroplast ist vorzugsweise Epoxidharz, welches weit verbreitet, gut verarbeitbar, relativ kostengünstig und temperaturbeständig ist. Für höhere Ansprüche können vorteilhaft Phenolharze verwendet werden, ebenso auch Melaminharz, Harnstoffharze und Polyester-Harze, insbesondere ungesättigte Polyester-Harze (UP-Harze).A suitable thermoset is preferably epoxy resin, which is widely used, easy to process, relatively inexpensive and temperature resistant. Phenol resins can advantageously be used for higher demands, as well as melamine resin, urea resins and polyester resins, in particular unsaturated polyester resins (UP resins).

Bevorzugt kann die Verfestigung des Gemischs durch Verdichtung, insbesondere mittels Verpressen, erfolgen. Auch kann die Verfestigung einen Schmelz- und einen Abkühlschritt umfassen, um beispielsweise Thermoplaste teilweise oder vollständig aufzuschmelzen. Hierdurch lässt sich eine gute Verbindung zwischen Graphitpartikeln und Kunststoffpartikeln erzielen. Insbesondere bei der Verwendung von Duroplasten kann die Verfestigung einen Aushärteschritt umfassen. Auch kann die Verfestigung durch eine alternative oder zusätzliche Sinterung des Gemischs erfolgen.Preferably, the solidification of the mixture by compression, in particular by means of compression, take place. Also, the solidification may include a melting and a cooling step to partially or completely melt, for example, thermoplastics. This makes it possible to achieve a good bond between graphite particles and plastic particles. In particular, when using thermosets, the solidification may include a curing step. Also, the solidification can be done by an alternative or additional sintering of the mixture.

In einer vorteilhaften Ausgestaltung ist die Platte plastisch verformbar, so dass sie am Einbauort einfach an vorgegebene Konturen von Wänden oder Decken von Räumen, beispielsweise Kanten, Krümmungen, Ecken, Friesen etc. angeformt werden kann. Anschließend kann die Platte dann am Einbauort endverfestigt werden, beispielsweise durch Erhitzen der noch plastisch verformbaren Platte im eingebauten Zustand.In an advantageous embodiment, the plate is plastically deformable, so that it can be easily molded at the installation site to predetermined contours of walls or ceilings of rooms, such as edges, bends, corners, friezes, etc. Subsequently, the plate can then be finally solidified at the installation site, for example by heating the still plastically deformable plate in the installed state.

Für die vorteilhafte Verwendung der erfindungsgemäßen Platte als Wand- oder Deckenverkleidung und/oder als thermisch wirksames Bauelement zur Kühlung oder Heizung von Räumen kann das Gemisch zunächst so vorfestigt werden, dass es plastisch verformbar bleibt. Anschließend kann mindestens ein Bauteil, vorteilhaft Rohre oder Rohrleitungen zur Aufnahme eines fluiden Kühl- oder Heizmediums, in das plastisch verformbar Gemisch eingedrückt werden.For the advantageous use of the panel according to the invention as a wall or ceiling paneling and / or as a thermally active component for cooling or heating of rooms, the mixture can first be pre-consolidated so that it remains plastically deformable. Subsequently, at least one component, advantageously tubes or pipes for receiving a fluid cooling or heating medium, are pressed into the plastically deformable mixture.

Zusätzlich oder alternativ kann vorteilhaft, das plastisch verformbar Gemisch respektive die somit plastische verformbare Platte an eine vorgegebene Kontur angeformt werden, beispielsweise um an nicht ebene Wand- oder Deckenverläufen angeformt werden zu können. Anschließend kann nachfolgend das plastisch verformbare Gemisch respektive Platte endverfestigt werden. Alternativ kann vorteilhaft vorgesehen werden, dass vor dem Verfestigen des Gemischs mindestens ein oben genanntes Bauteil in das Gemisch eingebracht und nachfolgend das Gemisch endverfestigt wird. Als Bauteile können aber vorteilhaft auch Befestigungselement, -anker etc. eingebettet werden.Additionally or alternatively, advantageously, the plastically deformable mixture or the thus plastic deformable plate can be formed to a predetermined contour, for example, to be formed on not flat wall or ceiling slopes. Subsequently, subsequently the plastically deformable mixture or plate can be finally consolidated. Alternatively it can be advantageously provided that before solidification of the mixture at least one component mentioned above is introduced into the mixture and subsequently the mixture is finally solidified. As components but can also be advantageously embedded fastener, anchors, etc.

Erfindungsgemäße Platten können im Baubereich bspw. als Decken- oder Wandelement zur Befestigung an einer Decke bzw. Wand verwendet werden. So eignen sich die erfindungsgemäßen Platten z. B. zur Verwendung in Raumtemperierungssystemen und in Akustikelementen zur Verbesserung der Schallabsorption.Inventive plates can be used in the construction sector, for example, as a ceiling or wall element for attachment to a ceiling or wall. Thus, the plates of the invention are suitable for. B. for use in Raumtemperierungssystemen and in acoustic elements to improve the sound absorption.

Weitere Besonderheiten und Vorzüge der Erfindung ergeben sich aus der folgenden Beschreibung von bevorzugten Ausführungsbeispielen anhand der Zeichnungen. Es zeigen:Other features and advantages of the invention will become apparent from the following description of preferred embodiments with reference to the drawings. Show it:

1 eine aus dem Stand der Technik bekannte graphithaltige Platte; 1 a graphite-containing plate known in the art;

2 einen Querschnitt durch eine erfindungsgemäße graphithaltige Platte nach einem ersten Ausführungsbeispiel; 2 a cross section through a graphite-containing plate according to the invention according to a first embodiment;

3 einen Querschnitt durch eine erfindungsgemäße graphithaltige Platte nach einem zweiten Ausführungsbeispiel; 3 a cross section through a graphite-containing plate according to the invention according to a second embodiment;

4 einen Querschnitt durch eine erfindungsgemäße graphithaltige Platte nach einem dritten Ausführungsbeispiel. 4 a cross section through a graphite-containing plate according to the invention according to a third embodiment.

Eine in 2 dargestellte erfindungsgemäße graphithaltige Platte 5 besteht aus Graphitpartikeln 6 aus expandiertem Graphit, welche in bekannter Weise wurm- oder ziehharmonikaförmig sind. Anstelle von expandiertem Graphit kann auch Naturgraphit oder synthetischer Graphit, bevorzugt in Pulverform, verwendet werden. Expandierter Graphit weist jedoch den Vorteil auf, dass es sich einerseits gut zu einer dichten, in geringem Umfang formstabilen Platte verpressen lässt und andererseits gut mit festen Kunststoffpartikeln 7 vermischbar ist.An in 2 illustrated graphite-containing plate according to the invention 5 consists of graphite particles 6 of expanded graphite, which in known worm or accordion-shaped. Instead of expanded graphite, natural graphite or synthetic graphite, preferably in powder form, can also be used. However, expanded graphite has the advantage that it can be pressed well on the one hand to a dense, to a small extent dimensionally stable plate and on the other hand well with solid plastic particles 7 is miscible.

Die Graphitpartikel 6 werden zunächst mit den festen Kunststoffpartikeln 7, hier PVC, weitgehend gleichmäßig vermischt. Dies kann in bekannter Weise durch an sich bekannte Mischvorrichtungen für pulverförmige Materialien erfolgen. Die Graphitpartikel 6 werden dabei weitgehend gleichmäßig, also vorteilhafterweise mindestens zu 85%, mit den Kunststoffpartikeln 7 vermischt, um eine möglichst gleichmäßig stabile Platte 5 zu erhalten. Bevorzugt werden die Partikel 6, 7 homogen miteinander vermischt.The graphite particles 6 be first with the solid plastic particles 7 , here PVC, largely uniformly mixed. This can be done in a known manner by per se known mixing devices for powdery materials. The graphite particles 6 be largely uniform, so advantageously at least 85%, with the plastic particles 7 mixed to a stable as evenly stable plate 5 to obtain. The particles are preferred 6 . 7 homogeneously mixed together.

Nach dem Vermischen werden wird das Gemisch in bekannter Weise durch Druckeinwirkung zur Platte 5 verpresst. Um die Bindung zwischen den Kunststoffpartikeln 7 untereinander und mit den Graphitpartikeln 6 zu erhöhen, wird das Gemisch zusätzlich erhitzt, so dass die Kunststoffpartikel 7 anschmelzen oder sogar ganz aufschmelzen, dann untereinander verschmelzen und sich mit den Graphitpartikeln verbinden. In einem Kühlvorgang, der durch aktive Kühlung oder passive Abkühlen des Gemischs erfolgen kann, erstarren die aufgeschmolzenen Kunststoffpartikel 7 unter Beibehaltung ihrer geschmolzenen Form, so dass eine gleichmäßig formstabile Platte 5 erhalten wird.After mixing, the mixture is in a known manner by pressure to the plate 5 pressed. To the bond between the plastic particles 7 with each other and with the graphite particles 6 To increase, the mixture is additionally heated so that the plastic particles 7 melt or even completely melt, then merge together and connect with the graphite particles. In a cooling process, which can be done by active cooling or passive cooling of the mixture, solidify the molten plastic particles 7 while maintaining its molten shape, leaving a uniformly dimensionally stable plate 5 is obtained.

Die beiden oben genannten Schritte – Verpressen und Erhitzen – können auch hintereinander durchgeführt werden. Alternativ oder auch zusätzlich kann die Verfestigung bzw. Verdichtung auch durch Aushärten und/oder Sintern erfolgen. Auch lassen sich diese unterschiedlichen Arten der Verfestigung miteinander kombinieren.The two steps mentioned above - pressing and heating - can also be carried out in succession. Alternatively or additionally, the solidification or compression can also be effected by curing and / or sintering. Also, these different types of consolidation can be combined.

Durch die erfindungsgemäße Vermischung der Graphitpartikel 6 und der Kunststoffpartikel 7 zu einem Gemisch mit weitgehend gleichmäßiger Verteilung der Partikel vor der Verfestigung kann eine gegenüber den bekannten graphithaltigen Platten 1 vorteilhafte gleichmäßige über ihre Fläche formstabile, steife, robuste und leicht handhabbare Platte 5 hergestellt werden.By the inventive mixing of the graphite particles 6 and the plastic particles 7 to a mixture with a substantially uniform distribution of the particles before solidification can be compared to the known graphite-containing plates 1 advantageous uniform over its surface dimensionally stable, rigid, robust and easy to handle plate 5 getting produced.

Bevorzugt Verwendungsbeispiele der erfindungsgemäßen Platte und des erfindungsgemäßen Herstellungsverfahrens zeigen 3 und 4. Gleiche Teile werden mit den gleichen Bezugszeichen versehen wie in 2.Preferably show examples of use of the plate according to the invention and the manufacturing method according to the invention 3 and 4 , The same parts are provided with the same reference numerals as in 2 ,

3 zeigt die erfindungsgemäße vorteilhafte Verwendung einer erfindungsgemäßen Platte 5 als thermisch wirksames Bauelement in Form einer Decken-/Wandverkleidungsplatte zur Heizung und/oder Kühlung eines Raumes. Hierbei wurden nach dem Vermischen der Graphitpartikel 6 und der Kunststoffpartikel 7, aber vor dem Verfestigen dieses Gemischs, zwei Leitungsrohre 8 mittig in das Gemisch eingebracht. Nachfolgend wurde dann das Gemisch wie oben beschrieben endverfestigt. Hierdurch lassen sich auf einfache Weise vorkonfektionierte und für die Verwendung als Heiz- und/oder Kühlelement vorbereitete Wandverkleidungsplatten herstellen, so dass eine Fertigung derartiger Platten sowie ihre Verwendung im Baubereich in industriellem Maßstab durchgeführt werden kann. Aufgrund der großen Formstabilität und Steifigkeit derartiger Platten wird die Handhabung und Montage der Platten im Baustellenbereich erleichtert, insbesondere können auch formstabile Platten mit größeren Abmessungen hergestellt und verwendet werden, ohne eine Beschädigung der Platten bei Transport und Handhabung befürchten zu müssen. 3 shows the advantageous use according to the invention of a plate according to the invention 5 as a thermally active component in the form of a ceiling / wall cladding panel for heating and / or cooling a room. In this case, after mixing, the graphite particles 6 and the plastic particles 7 but before solidifying this mixture, two pipes 8th introduced centrally into the mixture. Subsequently, the mixture was finally solidified as described above. As a result, can be prepared in a simple way prefabricated and prepared for use as heating and / or cooling element wall cladding panels, so that a production of such plates and their use in the construction sector can be carried out on an industrial scale. Due to the great dimensional stability and rigidity of such plates, the handling and assembly of the plates in the construction site area is facilitated, in particular dimensionally stable plates can be made and used with larger dimensions without having to fear damage to the plates during transport and handling.

Eine solche Platte mit eingebetteten Leitungsrohren 8 kann bspw. in einer Einrichtung zur Temperierung eines Raumes verwendet werden, wobei die Einrichtung wenigstens ein Bauelement, wie z. B. eine Betondecke oder -wand, welches einen thermischen Speicher bildet und eine in den Raum weisende Oberfläche aufweist und wobei die Leitungsrohre 8 mit dem thermischen Speicher gekoppelt und mit einem Heiz- oder Kühlmedium beaufschlagbar sind.Such a plate with embedded pipes 8th can be used, for example, in a device for controlling the temperature of a room, wherein the device is at least one component, such as. B. a concrete ceiling or wall, which forms a thermal storage and having a surface facing in the space and wherein the conduits 8th coupled with the thermal storage and can be acted upon by a heating or cooling medium.

Eine solche Einrichtung zur Temperierung eines Raumes ermöglicht es, die Masse der Decken oder Wände als thermischer Speicher zu nutzen, ohne dass Rohrleitungen zur Durchleitung eines Heiz- oder Kühlmediums zur thermischen Aktivierung des Speichers in die Decken oder Wände eingebracht werden müssen. Dadurch wird ein energieeffizientes Temperiersystem mit kurzen Ansprechzeiten bereit gestellt, welches darüber hinaus auch bei der Sanierung von Altbauten nachträglich eingebaut werden kann.Such a device for controlling the temperature of a room makes it possible to use the mass of the ceilings or walls as a thermal storage without pipes must be introduced for the passage of a heating or cooling medium for thermal activation of the memory in the ceilings or walls. This provides an energy-efficient temperature control system with short response times, which can also be retrofitted to refurbish old buildings.

4 zeigt die erfindungsgemäße vorteilhafte Verwendung einer erfindungsgemäßen Platte 5 als thermisch wirksames Bauelement in Form einer Decken-/Wandverkleidungsplatte zur Heizung und/oder Kühlung eines Raumes. Hierbei wurden im Gegensatz zu der Ausführung in 3 nach dem Vermischen der Graphitpartikel 6 und der Kunststoffpartikel 7, das Gemisch zunächst so vorverfestigt, dass es noch plastisch verformbar ist, und erst dann zwei Leitungsrohre 9 in die plastisch verformbar Platte 5 eingedrückt und nachfolgend die Platte 5 bzw. das Gemisch endverfestigt, wie oben beschrieben. Bei der Ausführung nach 4 ergeben sich die Vorteile wie bei der Ausführung nach 3. 4 shows the advantageous use according to the invention of a plate according to the invention 5 as a thermally active component in the form of a ceiling / wall cladding panel for heating and / or cooling a room. This was in contrast to the execution in 3 after mixing the graphite particles 6 and the plastic particles 7 , the mixture first pre-consolidated so that it is still plastically deformable, and only then two pipes 9 in the plastically deformable plate 5 pressed in and subsequently the plate 5 or the mixture finally solidified, as described above. In the Execution after 4 the advantages arise as in the execution 3 ,

In einer Weiterbildung der Platte 5 aus 4 kann diese vorteilhaft zunächst bei der Fertigung plastisch verformbar vorverfestigt, anschließend zum Einsatzort, beispielsweise einer Baustelle, transportiert und erst dort die Leitungsrohre 9 an geeigneten Stellen in die Platte 5 eingedrückt werden. Anschließend wird die Endverfestigung vor Ort durchgeführt, beispielsweise durch Erhitzen der noch plastisch verformbaren Platte 5 in bereits eingebautem Zustand. Hierdurch kann die Verlegung der Leitungsrohre 9 einfach an die speziellen Gegebenheiten vor Ort angepasst werden.In a further development of the plate 5 out 4 This can advantageously first pre-consolidated plastically deformable during manufacture, then transported to the site, such as a construction site, and only there the pipes 9 in suitable places in the plate 5 be pressed. Subsequently, the final consolidation is carried out on site, for example by heating the still plastically deformable plate 5 in already installed condition. As a result, the laying of the pipes 9 easily adapted to the specific conditions on site.

ZITATE ENTHALTEN IN DER BESCHREIBUNG QUOTES INCLUDE IN THE DESCRIPTION

Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Zitierte PatentliteraturCited patent literature

  • DE 10341255 B4 [0002, 0002, 0003] DE 10341255 B4 [0002, 0002, 0003]
  • US 3404061 A [0002] US 3404061 A [0002]

Claims (25)

Graphithaltige Platte (5), dadurch gekennzeichnet, dass sie ein verfestigtes Gemisch aus weitgehend gleichmäßig verteilten Graphitpartikeln (6) und Kunststoffpartikeln (7) enthält.Graphite-containing plate ( 5 ), characterized in that it comprises a solidified mixture of largely evenly distributed graphite particles ( 6 ) and plastic particles ( 7 ) contains. Platte (5) nach Anspruch 1, dadurch gekennzeichnet, dass die Graphitpartikel (6) und Kunststoffpartikel (7) homogen in dem Gemisch verteilt sind.Plate ( 5 ) according to claim 1, characterized in that the graphite particles ( 6 ) and plastic particles ( 7 ) are homogeneously distributed in the mixture. Platte (5) nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass mindestens ein Bauteil (8; 9) in die Platte (5) eingebettet ist.Plate ( 5 ) according to claim 1 or 2, characterized in that at least one component ( 8th ; 9 ) into the plate ( 5 ) is embedded. Platte (5) nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass sie ausschließlich aus dem Gemisch aus Graphitpartikeln (6) und Kunststoffpartikeln (7) besteht.Plate ( 5 ) according to claim 1 or 2, characterized in that it consists exclusively of the mixture of graphite particles ( 6 ) and plastic particles ( 7 ) consists. Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass die Graphitpartikel (6) expandierten Graphit enthalten.Plate ( 5 ) according to one of the preceding claims, characterized in that the graphite particles ( 6 ) contain expanded graphite. Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass das Gemisch 5 bis 90 Gewichts-%, bevorzugt 15 bis 60 Gewichts-% und besonders bevorzugt 20 bis 50 Gewichts-% Kunststoffpartikel (7) enthält.Plate ( 5 ) according to any one of the preceding claims, characterized in that the mixture 5 to 90% by weight, preferably 15 to 60% by weight and particularly preferably 20 to 50% by weight of plastic particles ( 7 ) contains. Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass die Kunststoffpartikel (7) Thermoplaste und/oder Duroplaste enthalten.Plate ( 5 ) according to one of the preceding claims, characterized in that the plastic particles ( 7 ) Thermoplastics and / or thermosetting plastics. Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass die Kunststoffpartikel (7) Polyvinylchlorid (PVC), Polypropylen (PP), Polyamide (PA), Acrylnitril-Butadien-Styrol (ABS), Polyetherketon (PEEK), Polyvinylidenfluorid (PVDF), Fluoropolymere, Benzoxazine und/oder Polysulfon (PP) enthalten.Plate ( 5 ) according to one of the preceding claims, characterized in that the plastic particles ( 7 ) Polyvinyl chloride (PVC), polypropylene (PP), polyamides (PA), acrylonitrile-butadiene-styrene (ABS), polyether ketone (PEEK), polyvinylidene fluoride (PVDF), fluoropolymers, benzoxazines and / or polysulfone (PP). Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass die Kunststoffpartikel (7) Epoxidharz, Phenolharz, Melaminharz, Harnstoffharze, und/oder Polyester-Harze, insbesondere ungesättigte Polyester-Harze (UP-Harze), enthalten.Plate ( 5 ) according to one of the preceding claims, characterized in that the plastic particles ( 7 ) Epoxy resin, phenolic resin, melamine resin, urea resins, and / or polyester resins, in particular unsaturated polyester resins (UP resins). Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass sie plastisch verformbar ist.Plate ( 5 ) according to one of the preceding claims, characterized in that it is plastically deformable. Platte (5) nach einem der voranstehenden Ansprüche, dadurch gekennzeichnet, dass sie in einer vorgegebenen Kontur geformt ist.Plate ( 5 ) according to one of the preceding claims, characterized in that it is shaped in a predetermined contour. Verfahren zur Herstellung einer graphithaltigen Platte (5), wobei Graphitpartikel (6) und Kunststoffpartikel (7) zu einem Gemisch mit weitgehend gleichmäßiger Verteilung der Graphitpartikel (6) und Kunststoffpartikel (7) vermischt werden und das Gemisch anschließend verfestigt wird.Process for producing a graphite-containing plate ( 5 ), whereby graphite particles ( 6 ) and plastic particles ( 7 ) to a mixture with a substantially uniform distribution of the graphite particles ( 6 ) and plastic particles ( 7 ) and the mixture is then solidified. Verfahren nach Anspruch 12, dadurch gekennzeichnet, dass das Gemisch eine homogene Verteilung. der Graphitpartikel (6) und Kunststoffpartikel (7) aufweist.A method according to claim 12, characterized in that the mixture is a homogeneous distribution. the graphite particle ( 6 ) and plastic particles ( 7 ) having. Verfahren nach Anspruch 12 oder 13 dadurch gekennzeichnet, dass das Verfestigen des Gemischs einen Verdichtungsschritt umfasst.A method according to claim 12 or 13, characterized in that the solidification of the mixture comprises a densification step. Verfahren nach Anspruch 14, dadurch gekennzeichnet, dass das Verdichten durch Verpressen des Gemischs erfolgt.A method according to claim 14, characterized in that the compression takes place by pressing the mixture. Verfahren nach einem der Ansprüche 12 bis 15, dadurch gekennzeichnet, dass das Verfestigen einen Schmelz- und einen Abkühlschritt umfasst.A method according to any one of claims 12 to 15, characterized in that the solidification comprises a melting and a cooling step. Verfahren nach Anspruch 16, dadurch gekennzeichnet, dass die Kunststoffpartikel (7) im Schmelzschritt vollständig aufgeschmolzen werden.A method according to claim 16, characterized in that the plastic particles ( 7 ) are completely melted in the melting step. Verfahren nach einem der Ansprüche 12 bis 17, dadurch gekennzeichnet, dass das Verfestigen einen Aushärteschritt umfasst.Method according to one of claims 12 to 17, characterized in that the solidification comprises a curing step. Verfahren nach einem der Ansprüche 12 bis 18, dadurch gekennzeichnet, dass das Verfestigen einen Sinterschritt umfasst.Method according to one of claims 12 to 18, characterized in that the solidification comprises a sintering step. Verfahren nach einem der Ansprüche 12 bis 19, dadurch gekennzeichnet, dass das Gemisch zunächst so vorverfestigt wird, dass es plastisch verformbar bleibt.Method according to one of claims 12 to 19, characterized in that the mixture is first pre-consolidated so that it remains plastically deformable. Verfahren nach Anspruch 20, dadurch gekennzeichnet, dass mindestens ein Bauteil (9) in das plastisch verformbar Gemisch eingedrückt wird.Method according to claim 20, characterized in that at least one component ( 9 ) is pressed into the plastically deformable mixture. Verfahren nach Anspruch 20 oder 21, dadurch gekennzeichnet, dass das plastisch verformbare Gemisch an eine vorgegebene Kontur angeformt wird.A method according to claim 20 or 21, characterized in that the plastically deformable mixture is formed to a predetermined contour. Verfahren nach Anspruch 21 oder 22, dadurch gekennzeichnet, dass das plastisch verformbare Gemisch nachfolgend endverfestigt wird.A method according to claim 21 or 22, characterized in that the plastically deformable mixture is subsequently finally solidified. Verfahren nach einem der Ansprüche 12 bis 19, dadurch gekennzeichnet, dass vor dem Verfestigen des Gemischs mindestens ein Bauteil (8) in das Gemisch eingebracht und nachfolgend das Gemisch endverfestigt wird.Method according to one of claims 12 to 19, characterized in that prior to solidification of the mixture at least one component ( 8th ) are introduced into the mixture and subsequently the mixture is finally solidified. Verfahren nach einem der Ansprüche 10 bis 21, dadurch gekennzeichnet, dass die Platte (5) nach einem der Ansprüche 1 bis 9 ausgebildet ist. Method according to one of claims 10 to 21, characterized in that the plate ( 5 ) is designed according to one of claims 1 to 9.
DE102009055442A 2009-12-31 2009-12-31 Graphite-containing plate comprises a solidified mixture of largely uniformly distributed graphite particles and plastic particles, where the graphite particles and plastic particles are distributed homogeneously into the mixture Ceased DE102009055442A1 (en)

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DE202009018618U DE202009018618U1 (en) 2009-12-31 2009-12-31 Graphite-containing plate
DE102009055442A DE102009055442A1 (en) 2009-12-31 2009-12-31 Graphite-containing plate comprises a solidified mixture of largely uniformly distributed graphite particles and plastic particles, where the graphite particles and plastic particles are distributed homogeneously into the mixture
EP10803101A EP2519782A1 (en) 2009-12-31 2010-12-31 Ceiling or wall element with a heating or cooling register
CN2010800646447A CN102781877A (en) 2009-12-31 2010-12-31 Layered composite material for use in a redox flow battery
CN2010800640671A CN102792101A (en) 2009-12-31 2010-12-31 Ceiling or wall element with a heating or cooling register
CN2010800646432A CN102781876A (en) 2009-12-31 2010-12-31 Graphite-containing moulded body and method for the production thereof
CA2786150A CA2786150A1 (en) 2009-12-31 2010-12-31 Ceiling or wall element with a heating or cooling register
JP2012546459A JP2013516505A (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing graphite-containing plate
KR20127020054A KR20120112676A (en) 2009-12-31 2010-12-31 Graphite-containing moulded body and method for the production thereof
PCT/EP2010/070974 WO2011080334A2 (en) 2009-12-31 2010-12-31 Layered composite material for use in a redox flow battery
EP10803462A EP2519480A2 (en) 2009-12-31 2010-12-31 Graphite-containing moulded body and method for the production thereof
PCT/EP2010/070977 WO2011080337A1 (en) 2009-12-31 2010-12-31 Ceiling or wall element with a heating or cooling register
US13/520,219 US20130032278A1 (en) 2009-12-31 2010-12-31 Graphite-containing molded body and method for the production thereof
PCT/EP2010/070978 WO2011080338A1 (en) 2009-12-31 2010-12-31 Device for tempering a chamber
SG2012048393A SG182294A1 (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing a graphite-containing plate
ES10798152.4T ES2641013T3 (en) 2009-12-31 2010-12-31 Stratified composite material for use in a redox flow battery
JP2012546456A JP2013516374A (en) 2009-12-31 2010-12-31 Graphite-containing molded body and method for producing the same
SG2012048468A SG182296A1 (en) 2009-12-31 2010-12-31 Device for temperature control of a room
US13/520,273 US20130040194A1 (en) 2009-12-31 2010-12-31 Layered composite material for use in a redox flow battery
SG2012048435A SG181988A1 (en) 2009-12-31 2010-12-31 Ceiling or wall element with a heating or cooling register
EP10803102.2A EP2519783B1 (en) 2009-12-31 2010-12-31 Device for tempering a chamber
KR20127020055A KR20120110151A (en) 2009-12-31 2010-12-31 Layered composite material for use in a redox flow battery
JP2012546455A JP2013527964A (en) 2009-12-31 2010-12-31 Composite laminate materials for use in redox flow batteries
EP10803103A EP2519576A1 (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing a graphite-containing plate
PCT/EP2010/070979 WO2011080339A1 (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing a graphite-containing plate
PCT/EP2010/070976 WO2011080336A2 (en) 2009-12-31 2010-12-31 Graphite-containing moulded body and method for the production thereof
CA2786143A CA2786143A1 (en) 2009-12-31 2010-12-31 Graphite-containing moulded body and method for the production thereof
CN2010800648207A CN102869711A (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing a graphite-containing plate
CA2786134A CA2786134A1 (en) 2009-12-31 2010-12-31 Layered composite material for use in a redox flow battery
PL10803102T PL2519783T3 (en) 2009-12-31 2010-12-31 Device for tempering a chamber
CA 2786180 CA2786180A1 (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing a graphite-containing plate
EP10798152.4A EP2519479B1 (en) 2009-12-31 2010-12-31 Layered composite material for use in a redox flow battery
US13/520,222 US20130032750A1 (en) 2009-12-31 2010-12-31 Graphite-containing plate and method for producing a graphite-containing plate
CA2786157A CA2786157C (en) 2009-12-31 2010-12-31 Device for temperature control of a room
US13/520,223 US20130192793A1 (en) 2009-12-31 2010-12-31 Device for temperature control of a room
US13/540,039 US20130168040A1 (en) 2009-12-31 2012-07-02 Ceiling or wall element with a heating or cooling register

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202012003810U1 (en) 2012-03-15 2013-02-08 Sgl Carbon Se Thermally conductive composite element based on expanded graphite
WO2013135515A1 (en) 2012-03-15 2013-09-19 Sgl Carbon Se Thermally conductive composite element based on expanded graphite
DE102012204124A1 (en) 2012-03-15 2013-09-19 Sgl Carbon Se Thermally conductive composite element based on expanded graphite
CN104245304A (en) * 2012-03-15 2014-12-24 西格里碳素欧洲公司 Thermally conductive composite element based on expanded graphite
AU2013231509B2 (en) * 2012-03-15 2015-03-26 Sgl Carbon Se Thermally conductive composite element based on expanded graphite
CN104245304B (en) * 2012-03-15 2016-11-30 西格里碳素欧洲公司 Heat conduction composite component based on expanded graphite
US9612064B2 (en) 2012-03-15 2017-04-04 Sgl Carbon Se Thermally conductive composite element based on expanded graphite and production method

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