DE102011004500A1 - Method for producing printed composite plate for, e.g. sliding roof of vehicle, involves laminating composite sheet that is printed using inkjet printer before performing lamination process, between outer and inner panes - Google Patents

Method for producing printed composite plate for, e.g. sliding roof of vehicle, involves laminating composite sheet that is printed using inkjet printer before performing lamination process, between outer and inner panes Download PDF

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Publication number
DE102011004500A1
DE102011004500A1 DE102011004500A DE102011004500A DE102011004500A1 DE 102011004500 A1 DE102011004500 A1 DE 102011004500A1 DE 102011004500 A DE102011004500 A DE 102011004500A DE 102011004500 A DE102011004500 A DE 102011004500A DE 102011004500 A1 DE102011004500 A1 DE 102011004500A1
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Prior art keywords
vehicle
printed
composite
pane
inkjet printer
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DE102011004500A
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German (de)
Inventor
Tobias Wiethaler
Philipp Mohr
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Bayerische Motoren Werke AG
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Bayerische Motoren Werke AG
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Priority to DE102011004500A priority Critical patent/DE102011004500A1/en
Publication of DE102011004500A1 publication Critical patent/DE102011004500A1/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10247Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10275Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on interlayer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10247Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10743Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2333/00Polymers of unsaturated acids or derivatives thereof
    • B32B2333/04Polymers of esters
    • B32B2333/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2369/00Polycarbonates

Abstract

The method involves laminating composite sheet which is printed using inkjet printer before performing lamination process, between outer pane and inner pane so as to obtain composite plate. The composite sheet is made of ionomer material. The inner pane is made of plastic material. The composite sheet is provided for covering predetermined portions of the vehicle and shadowing of solar radiation.

Description

Die Erfindung bezieht sich auf ein Verfahren zur Herstellung einer bedruckten Fahrzeug-Verbundscheibe nach dem Oberbegriff des Anspruchs 1 sowie die Verwendung einer solchen Scheibe in einem Fahrzeugdach.The invention relates to a method for producing a printed vehicle composite pane according to the preamble of claim 1 and the use of such a pane in a vehicle roof.

Derzeit werden partiell bedruckte Fahrzeug-Verbundscheiben verwendet, beispielsweise Scheiben mit Schwarzrand, um Stellen im Fahrzeug abzudecken, welche im Fahrzeug nicht sichtbar sein sollen. Beispiele sind die Randbereiche von Schiebe und/oder Hebedächern, aber auch Front-Heck- und Seitenverglasungen des Fahrzeugs. Das Bedrucken der Verbundscheiben erfolgt durch Siebdruck, also ein Durchdruckverfahren mit Schablone.Currently, partially printed vehicle composite panes are used, such as black-rim panes, to cover locations in the vehicle that are not visible in the vehicle. Examples are the edge areas of sliding and / or lifting roofs, but also front-rear and side glazing of the vehicle. The printing of the composite discs is done by screen printing, so a stencil printing method.

Desweiteren werden zur Abschirmung der Sonneneinstrahlung zum Beispiel in Schiebe- und/oder Hebedächern oder in Panoramascheiben, die einen Teil des Fahrzeugdachs bilden, aber auch für den sogenannten Grünkeil von Windschutzscheiben Verbundgläser mit einer homogen und teiltransparent eingefärbten Verbundfolie verwendet.Furthermore, to shield the sunlight, for example in sliding and / or lifting roofs or in panoramic windows, which form part of the vehicle roof, but also for the so-called green wedge of windshield laminated glass with a homogeneous and partially transparent colored composite film used.

Das herkömmliche Glasdruckverfahren für eine Fahrzeugverbundscheibe ist sehr unflexibel. Gleiches gilt für eine eingefärbte Verbundfolie. D. h. es ist beispielsweise nicht möglich, das Muster oder die Farbe des Abdeckrandes der Fahrzeug-Verbundscheibe oder die Teiltransparenz oder die Farbe der Verbundfolie individuell abzustimmen.The conventional glass printing method for a vehicle composite pane is very inflexible. The same applies to a colored composite film. Ie. For example, it is not possible to tailor the pattern or color of the cover of the vehicle composite panel or the partial transparency or the color of the composite foil individually.

Aus WO 02/18154 A1 und US 7,278,730 B2 ist es bekannt, bei Verbundglas, das für dekorative Zwecke z. B. bei einem Fenster oder Glasabdeckungen verwendet wird, durch Bedrucken der Verbundfolie mit einem Tintenstrahldrucker herzustellen.Out WO 02/18154 A1 and US 7,278,730 B2 it is known in laminated glass, the decorative purposes z. B. is used in a window or glass covers to produce by printing the composite film with an inkjet printer.

Aufgabe der Erfindung ist es, die Verbundscheibe eines Fahrzeuges mit einem individuellen und ggf. auch vielfarbigen Design zu versehen.The object of the invention is to provide the composite pane of a vehicle with an individual and possibly also multi-colored design.

Dies wird erfindungsgemäß mit dem im Anspruch 1 gekennzeichneten Verfahren erreicht. In den Unteransprüchen sind vorteilhafte Ausgestaltungen der Erfindung wiedergegeben.This is achieved according to the invention with the method characterized in claim 1. In the subclaims advantageous embodiments of the invention are shown.

Erfindungsgemäß wird zur Erhöhung der Designfreiheit der Fahrzeugverbundscheibe eine im Tintenstrahlverfahren bedruckte Folie in den Schichtaufbau der Verbundscheibe integriert.According to the invention, a film printed in an ink-jet process is integrated into the layer structure of the composite pane in order to increase the design freedom of the vehicle composite pane.

Nach einer ersten Ausführungsform der Erfindung wird die Fahrzeug-Verbundscheibe durch Laminieren der mit dem Tintenstrahldrucker bedruckten Verbundfolie zwischen einer Außen- und einer Innenscheibe erhalten.According to a first embodiment of the invention, the vehicle composite pane is obtained by laminating the composite film printed with the inkjet printer between an outer and an inner pane.

Als Verbundfolie kann, wie bei einem Fahrzeug-Verbundsicherheitsglas üblich, eine Schmelzklebefolie aus Polyvinylbutyral (PVB), Ethylenvinylacetat (EVA) oder thermoplastischem Polyurethan (TPU) verwendet werden.As a composite film, as is common in a vehicle laminated safety glass, a melt adhesive film of polyvinyl butyral (PVB), ethylene vinyl acetate (EVA) or thermoplastic polyurethane (TPU) can be used.

Besonders bevorzugt werden jedoch die Außen- und die Innenscheibe der Fahrzeugverbundscheibe mit einer Schmelzklebefolie aus einem Ionomer laminiert, die mit einem Tintenstrahldrucker bedruckt worden ist. Ionomere sind thermoplastische Copolymerisate aus wenigstens einem unpolaren und wenigstens einem polaren Monomeren, beispielsweise mit einer Sulfonsäuregruppe.Most preferably, however, the outer and inner panes of the vehicle composite pane are laminated with a hot melt adhesive film of an ionomer that has been printed with an inkjet printer. Ionomers are thermoplastic copolymers of at least one nonpolar and at least one polar monomer, for example with a sulfonic acid group.

Ionomerfolien sind im Tintenstrahlverfahren hervorragend bedruckbar. Darüber hinaus weisen sie eine ausgezeichnete Adhäsion an der Innen- und Außenscheibe der Verbundscheibe auf, sodass auch in den bedruckten Bereichen der Ionomerfolie keine Delamination auftritt.Ionomer films are excellent printable by the inkjet process. In addition, they have an excellent adhesion to the inner and outer pane of the composite disc, so that no delamination occurs in the printed areas of the ionomer.

Die hohe Eigensteifigkeit der Ionomerfolie hat zudem den Vorteil, dass die Verbundscheibe dünner und damit leichter ausgebildet werden kann. Die dadurch erreichte Gewichtsreduktion führt vor allem bei Verwendung der Fahrzeugverbundscheibe im Dachbereich zu einer vorteilhaften Verlagerung des Fahrzeugschwerpunktes nach unten. Darüber hinaus wird durch eine Dachverglasung aus einer Verbundfolie mit einer Ionomerfolie die Torsionssteifigkeit erhöht.The high intrinsic stiffness of the ionomer film also has the advantage that the composite disc can be made thinner and thus lighter. The achieved weight reduction leads, especially when using the vehicle composite pane in the roof area to an advantageous shift of the vehicle's center of gravity down. In addition, a roof glazing made of a composite film with an ionomer film increases the torsional rigidity.

Die bedruckte Ionomerfolie ist deshalb neben der Verbundscheibe für das Schiebe- und/oder Hebedach des Fahrzeugs insbesondere auch für Panoramascheiben geeignet, also für Windschutzscheiben, die sich so weit nach hinten erstrecken, dass sie einen mehr oder weniger großen Teil des Fahrzeugdachs bilden.The printed ionomer film is therefore suitable, in addition to the composite pane for the sliding and / or lifting roof of the vehicle, in particular also for panoramic windows, ie for windshields which extend so far back that they form a more or less large part of the vehicle roof.

Die Innenscheibe und die Außenscheibe der Verbundscheibe können entsprechend einem Fahrzeug-Verbundsicherheitsglas jeweils aus einer Glasscheibe bestehen, die chemisch oder thermisch vorgespannt sein kann. Zudem kann die Innenscheibe und/oder Außenscheibe aus einem transparenten Kunststoff, wie Polycarbonat (PC), Polymethylenmethacrylat (PMA) oder Polyethylenterephthalat (PET) bestehen.The inner pane and the outer pane of the composite pane may each consist of a glass pane corresponding to a composite vehicle safety glass, which may be chemically or thermally prestressed. In addition, the inner pane and / or outer pane of a transparent plastic, such as polycarbonate (PC), polymethylene methacrylate (PMA) or polyethylene terephthalate (PET) exist.

Nach einer weiteren Ausführungsform der Erfindung kann die mit dem Tintenstrahldrucker bedruckte Verbundfolie auf die aus Glas oder einem transparenten Kunststoff bestehende Fahrzeugscheibe außen oder innen aufgebracht werden. Die bedruckte Folie kann dazu beispielsweise aus Polyurethan (PU), Polyvinylchlorid (PVC) oder Polyethylenterephthalat (PET) bestehen.According to a further embodiment of the invention, the printed with the inkjet printer composite film can be applied to the glass or a transparent plastic existing vehicle window outside or inside. For example, the printed film can consist of polyurethane (PU), polyvinyl chloride (PVC) or polyethylene terephthalate (PET).

Um die bedruckte Verbundfolie beispielsweise vor Witterungseinflüssen zu schützen, kann sie einlaminiert werden. So kann beispielsweise die bedruckte Verbundfolie zwischen einer Glasscheibe an der Außenseite und einer vorzugsweise kratzfest beschichteten transparenten Kunststofffolie an der Innenseite vorgesehen sein. To protect the printed composite film from, for example, weathering, it can be laminated. Thus, for example, the printed composite film between a glass pane on the outside and a preferably scratch-resistant coated transparent plastic film may be provided on the inside.

Da die Verbundfolie mit dem Tintenstrahldrucker anhand computergenerierter Bilddatei sehr flexibel bedruckt werden kann, ist eine hohe Designfreiheit bezüglich der Optik der Fahrzeugverbundscheibe gewährleistet. Ein weiterer Vorteil besteht darin, dass die Transparenz beliebig eingestellt werden kann, was hinsichtlich des Sonnenschutzes von großem Vorteil ist. Darüber hinaus können Flächen, die zum Beispiel im Fahrzeuginnenraum nicht sichtbar sein sollen, erfindungsgemäß optisch abgedeckt werden.Since the composite film can be printed very flexibly with the inkjet printer on the basis of a computer-generated image file, a high freedom of design with regard to the appearance of the vehicle composite pane is ensured. Another advantage is that the transparency can be set arbitrarily, which is in terms of sun protection of great advantage. In addition, surfaces that should not be visible, for example, in the vehicle interior, according to the invention optically covered.

Das heißt, die Verbundfolie kann beispielsweise im Randbereich mit dem Tintenstrahldrucker mit dem Farbmittel mit einem solchen Deckvermögen bedruckt werden, dass die Stellen im Fahrzeuginnenraum, welche nicht sichtbar sein sollen, zuverlässig optisch abgedeckt sind.That is, the composite film can be printed, for example, in the edge region with the ink jet printer with the colorant with such hiding power that the locations in the vehicle interior, which should not be visible, are reliably optically covered.

Stattdessen kann die Verbundfolie beispielsweise in einem Bereich so bedruckt werden, dass die gewünschte Abschattung der Sonnenstrahlung zum Beispiel durch das Schiebe- und/oder Hebedach oder die Panoramascheibe erfolgt.Instead, the composite film may be printed, for example, in a region such that the desired shading of the solar radiation takes place, for example, by the sliding and / or lifting roof or the panorama window.

ZITATE ENTHALTEN IN DER BESCHREIBUNG QUOTES INCLUDE IN THE DESCRIPTION

Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Zitierte PatentliteraturCited patent literature

  • WO 02/18154 A1 [0005] WO 02/18154 A1 [0005]
  • US 7278730 B2 [0005] US 7278730 B2 [0005]

Claims (8)

Verfahren zur Herstellung einer bedruckten Fahrzeug-Verbundscheibe, dadurch gekennzeichnet, dass die Fahrzeugverbundscheibe mit einer Verbundfolie laminiert wird, die vor dem Laminieren mit einem Tintenstrahldrucker bedruckt worden ist.A method for producing a printed vehicle composite pane, characterized in that the vehicle composite pane is laminated with a composite film which has been printed before lamination with an inkjet printer. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Fahrzeugverbundscheibe durch Laminierung der bedruckten Verbundfolie zwischen einer Außen- und einer Innenscheibe erhalten wird.A method according to claim 1, characterized in that the vehicle composite pane is obtained by lamination of the printed composite film between an outer and an inner pane. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass als Verbundfolie eine Folie aus einem Ionomer verwendet wird.A method according to claim 1 or 2, characterized in that a film of an ionomer is used as the composite film. Verfahren nach Anspruch 2 oder 3, dadurch gekennzeichnet, dass die Innenscheibe aus Kunststoff besteht.A method according to claim 2 or 3, characterized in that the inner pane consists of plastic. Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass die Verbundfolie derart bedruckt wird, dass vorgegebene Stellen dem Fahrzeug optisch abgedeckt werden und/oder eine Abschattung der Sonneneinstrahlung erfolgt.Method according to one of the preceding claims, characterized in that the composite film is printed in such a way that predefined locations are optically covered by the vehicle and / or shading of the solar radiation takes place. Verfahren nach Anspruch 5, dadurch gekennzeichnet, dass die Verbundfolie zur optischen Abdeckung im Randbereich bedruckt wird.A method according to claim 5, characterized in that the composite film is printed for optical coverage in the edge region. Verwendung der nach einem der vorstehenden Ansprüche hergestellten Fahrzeug-Verbundscheibe im Dach des Fahrzeugs.Use of the vehicle composite pane produced according to one of the preceding claims in the roof of the vehicle. Verwendung nach Anspruch 7 im Schiebe- und/oder Hebedach des Fahrzeugs oder als einen Teil des Fahrzeugdachs bildende Panoramascheibe.Use according to claim 7 in the sliding and / or lifting roof of the vehicle or as a part of the vehicle roof forming panoramic window.
DE102011004500A 2011-02-22 2011-02-22 Method for producing printed composite plate for, e.g. sliding roof of vehicle, involves laminating composite sheet that is printed using inkjet printer before performing lamination process, between outer and inner panes Withdrawn DE102011004500A1 (en)

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DE102011004500A DE102011004500A1 (en) 2011-02-22 2011-02-22 Method for producing printed composite plate for, e.g. sliding roof of vehicle, involves laminating composite sheet that is printed using inkjet printer before performing lamination process, between outer and inner panes

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DE102011004500A DE102011004500A1 (en) 2011-02-22 2011-02-22 Method for producing printed composite plate for, e.g. sliding roof of vehicle, involves laminating composite sheet that is printed using inkjet printer before performing lamination process, between outer and inner panes

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US10710340B2 (en) 2015-02-19 2020-07-14 Agp America S.A. Obscuration having superior strength and optical quality for an automotive laminate
US10780674B2 (en) 2015-02-19 2020-09-22 Agp America S.A. Obscuration having superior strength and optical quality for an automotive laminate
WO2021180779A1 (en) 2020-03-13 2021-09-16 Saint-Gobain Glass France Composite pane, method for producing the composite pane and use of the composite pane
WO2021254910A1 (en) * 2020-06-16 2021-12-23 Saint-Gobain Glass France Composite pane
WO2021254911A1 (en) * 2020-06-16 2021-12-23 Saint-Gobain Glass France Wedge-shaped multi-ply intermediate layer with acoustically damping properties
WO2021254976A1 (en) 2020-06-16 2021-12-23 Saint-Gobain Glass France Composite pane

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