DE2147416C2 - Wasserunempfindliche hydraulische Flüssigkeiten - Google Patents

Wasserunempfindliche hydraulische Flüssigkeiten

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Publication number
DE2147416C2
DE2147416C2 DE2147416A DE2147416A DE2147416C2 DE 2147416 C2 DE2147416 C2 DE 2147416C2 DE 2147416 A DE2147416 A DE 2147416A DE 2147416 A DE2147416 A DE 2147416A DE 2147416 C2 DE2147416 C2 DE 2147416C2
Authority
DE
Germany
Prior art keywords
water
hydraulic fluids
weight
boric acid
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2147416A
Other languages
English (en)
Other versions
DE2147416A1 (de
Inventor
David A. Orange Conn. Csejka
Arthur W. Hamden Conn. Sawyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olin Corp
Original Assignee
Olin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US630536A external-priority patent/US3632656A/en
Priority claimed from US80121A external-priority patent/US3635825A/en
Application filed by Olin Corp filed Critical Olin Corp
Publication of DE2147416A1 publication Critical patent/DE2147416A1/de
Priority claimed from JP50045711A external-priority patent/JPS51120332A/ja
Application granted granted Critical
Publication of DE2147416C2 publication Critical patent/DE2147416C2/de
Expired legal-status Critical Current

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    • C10M111/04Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
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Description

R[O-R"1,OR'
worin
R eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen,
R' Wasserstoff oder eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen,
R" eine Alkylengruppe mit 2 bis 4 Kohlenstoffatomen und
y eine ganze Zahl von 2 bis 4
bedeuten, und gegebenenfalls
c) einem Polyoxyalkylenglykol mit einem Molekulargewicht von nicht weniger als etwa 150 bis 400 nach Patent 17 68 933
dadurch gekennzeichnet, daß der Gehalt an der Borsäureester-Verbindung 20 bis 44 Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, beträgt.
2. Hydraulische Flüssigkeit nach Anspruch 1, dadurch gekennzeichnet, daß der Gehalt an der Borsäureester-Verbindung mindestens 30 Gewichtsprozent beträgt.
3. Hydraulische Flüssigkeit nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, daß sie einen Triester der Borsäure der nachstehenden allgemeinen Formel
worin
R eine Alkylgruppe mit 1 bis 4 C-Atomen,
R' Wasserstoff oder eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen,
R" cine Alkylengruppe mit 2 bis 4 Kohlenstoffatomen und
y eine ganze Zahl von 2 bis 4
bedeuten. Vorzugsweise hat R" die Bedeutung von —(CH2)a, wobei χ eine ganze Zahl von 2 bis 4 ist
Überraschenderweise wurde nunmehr gefunden, daß sich der Anwendungsbereich von wasserunempfindlichen hydraulischen Flüssigkeiten dieses Typs wesentlich verbreitern läßt, wenn man den Bereich für der. Gehalt an der Borsäureester-Verbindung erweitert Insbesondere hydraulische Flüssigkeiten mit einem Gehalt an der borhaltigen Verbindung im Bereich von etwa 20 bis 44 Gewichtsprozent weisen einen niedrigeren Siedepunkt auf als die hydraulischen Flüssigkeiten des Hauptpatents, was für bestimmte Anwendungszwecke vorteilhaft ist Trotzdem wird aber der Siedepunkt durch die Aufnahme von Wasser während des praktischen Gebrauchs, beispielsweise als Bremsflüssigkeit in Kraftwagen, nicht in unerwünschter Weise so weit herabgesetzt, daß die vorgeschriebenen Sicherheitsgrenzen überschritten würden.
Demgemäß betrifft die vorliegende Erfindung hydraulische Flüssigkeiten, bestehend aus wenigstens einer als Schmiermittel wirkenden Borsäureester-Verbindung, einem Verdünnungsmittel der allgemeinen Formel I
[R1(O- R,), -O]3- B
enthält, in welcher
Ri einen Alkylrest mit 1 bis 4 Kohlenstoffatomen
bedeutet,
R1, ein Alkylenrest mit 2 bis 4 Kohlenstoffatomen
ist und
y eine ganze Zahl von 2 bis 4 darstellt.
4. Hydraulische Flüssigkeit nach den Ansprüchen 1 bis 3, dadurch gekennzeichnet, daß der Gehalt an dem Verdünnungsmittel der allgemeinen Formel (I) bis zu 80 Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, beträgt.
Das Patent 17 68 933 betrifft wasserunempfindliche hydraulische Flüssigkeiten, bestehend aus etw 44 bis Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, an wenigstens einer als Schmiermittel wirkenden Borsäureester-Verbindung, 0 bis etwa Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, wenigstens eines Polyoxyalkylenglykols mit einem Molekulargewicht von nicht weniger als 150 bis zu etwa 400, und etwa 3 bis etwa 50 Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, an wenigstens einem Verdünnungsmittel der allgemeinen Formel
R[O-R1I1OR'
R[O-R"],OR'
worin
R eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen,
R' Wasserstoff oder eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen.
R" eine Alkylengruppe mit 2 bis 4 Kohlenstoffatomen und
y eine ganze Zahl von 2 bis 4
bedeuten, und gegebenenfalls einem Polyoxyalkylenglykol mit einem Molekulargewicht von nicht weniger als etwa 150 bis 400 nach Patent 17 68 933, welche dadurch gekennzeichnet sind, daß der Gehalt an der Borsäureester-Verbindung etwa 20 bis 44 Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, beträgi.
Aus der CH-PS 3 16 412 sind'zwar Bremsflüssigkeiten für Kraftfahrzeuge bekannt, welche als Basisflüssigkeit mindestens einen Glykoläther bzw. ein Glykol enthalten und deren Schmierfähigkeit durch einen Gehalt von 3 bis 10% einer Borsäureverbindung, wie eines Borsäureesters, verbessert werden soll. Diese Literaturstelle vermittelt aber keine Lehre, wie hydraulische Flüssigkeiten beschaffen sein müssen, die eine erhöhte Wasserfestigkeit aufweisen und den sehr strengen US-Bestimmungen in bezug auf den Mindest-Siedepunkt bei einem Wassergehalt von 3,5 Gewichtsprozent entsprechen.
Auch die aus der DE-AS 12 95 124 bekannten Hydraulikflüssigkeiten auf Glykol- bzw. Glykolätherbasis mit einem Gehalt an Komplexverbindungen, die durch Umsetzen von Tetraboraten bzw. Metaboraten mit überschüssigem Glykol erhalten werden können, genügen diesen strengen Anforderungen nicht. Vergleichs-
M versuche zeigten, daß derartige Hydraulikflüssigkeiten einen zu niedrigen Siedepunkt im wasserhaltigen Zustand und außerdem eine relativ hohe Viskosität im Vergleich zu erfindungsgemäßen Hydraulikflüssigkeiten
aufweisen.
Vorzugsweise beträgt der Gehalt an der Borsäureester-Verbindung bei den erfindungsgemäßen hydraulischen Flüssigkeiten mindstens 30 Gewichtsprozent
Die erfindungsgemäßen Hydraulikflüssigkeiten zeichnen sich unter anderem dadurch aus, daß sie den vom US-Department of Transportation in Betracht gezogenen Standardbedingungen für Bremsflüssigkeiten entsprechen, d. h., daß sie bei einem Wasserzusatz bis zu etwa 3,5 Volumenprozent einen Siedepunkt oberhalb 1600C im praktisch wasserfreien Zustand einen Siedepunkt oberhalb 232,2° C aufweisen.
Weiterhin zeigen die erfindungsgemäßen Hydraulikflüssigkeiten nur eine geringe Korrosivität, und sie sind gut mit Kautschuk verträglich, auch ohne einen Zusatz an kostspieligen Alkoholen, wie 2-Äthylhexanol, Heptanolen, Glykolbutyläthern und Glykoldiäthern.
Die Borsäureester-Verbindungen leiten sich vorzugsweise vun einem Glykolmonoäther ab, insbesondere handelt es sich dabei um Triester der Borsäure der nachstehenden allgemeinen Formel
[R1(O-R1)^-O]3-B
Die erfindungsgemäßen Hydraulikflüssigkeiten können außerdem übliche Zusatzstoffe in Mengen bis zu 10 Gewichtsprozent enthalten, beispielsweise Antikorrosions- und Anti-oxydationsrr.ittel, Rostinhibitoren, Antischaummittel, Stabilisatoren und Mittel zur Verbesserung des Viskositätsindex.
Die Beispiele erläuteren die Erfindung.
(II)
in welcher
Ri einen Alkylrest mit 1 bis 4 Kohlenstoffatomen bedeutet,
R3 einen Alkylenrest mit 2 bis 4 Kohlenstoffatomen darstellt und
y eine ganze Zahl von 2 bis 4 ist.
Beispiele hierfür sind die folgenden Verbindungen:
[CH3(OCH2CH2)SO]3-B,
[C2Hä(OHC2CH2)2O]3-B,
[C2H5(OCH2CH2J3O]3-B,
[C2H5(OCH2CH2J4O]3- B,
[C3H7(OCH2CH2J3O]3-B,
[C4H9(OCH2CH2J2O]3-B und
[C4H9(OCH2CH2J3O]3-B.
Derartige Borsäueester lassen sich in an sich bekannter Weise aus Borsäure und den entsprechenden Glykoläthern in Anwesenheit eines mit Wasser azeotrop abdestillierenden Lösungsmittels herstellen.
Im Rahmen der Erfindung können aber auch andere Typen von Borsäureester-Verbindungen eingesetzt werden, wie sie auch in dem Hauptpatent 17 68 933 beschrieben sind.
Das Verdünnungsmittel der vorstehend angegebenen Formel I wird zweckmäßig in Mengen bis zu 80 Gewichtsprozent, bezogen auf das Gesamtgewicht der Flüssigkeit, eingesetzt. Wegen ihrer besonders g günstigen Wirkung auf die Viskositätseigenschaften und das Wasseraufnahmevermögen werden die nachstehenden Glykoläther bevorzugt:
Diäthylenglykolmonomethyläther,
Diäthylenglykolmonoäthyläther,
Diäthylenglykolmonobutyläther,
Triäthylenglykolmonomethyläther,
Triäthylenglykolmonoäthyläther,
Triäthylenglykolmonobutyläther,
Tetraäthylenglykolmonomethyläther,
Tetraäthylenglykolmonoäthyläther und
Tetraä thy lenglykolmonobu ty lather.
Gegebenenfalls können die erfindungsgemäßen Hydraulikflüssigkeiten zusätzlich auch Polyoxyalkylenglykole enthalten, deren Molekulargewicht vorzugsweise etwa 1OO bis 300 beträgt.
Beispiel 1 Gewichts
prozent
40,0
[CH3(OCH2CH2J3O]3-B 9,4
Tetraäthylenglykolmonoäthyläther 50,01
Triäthylenglykolmonomethyläther 0,5
Monoäthanolamin 0,03
Benzotriazol 0,06
Düsopropanolaminnitrit 100,00
Eigenschaften:
Siedepunkt unter Rückfluß 243,3° C
(wasserfrei)
Siedepunkt unter Rückfluß
(wasserhaltig)
(3,5 ml Wasser 171.rc
+100 ml Hydraulikflüssigkeit) 584 cS
Viskosität bei -4O0C
Beispiel 2 Gewichts
prozent
30,0
[CH3(OCH2CH2J3O]3-B 7,0
Tetraäthylenglykolmonoäthyläther 62,56
Triäthylenglykolmonomethyläther 0,38
Monoäthanoiamin 0,02
Benzotriazol 0,04
Düsopropanolaminnitrit 100,00
Eigenschaften:
Siedepunkt unter Rückfluß 241,70C
(wasserfrei)
Siedepunkt unter Rückfluß
(wasserhaltig)
(3,5 ml Wasser 166,7° C
+100 ml Hydraulikflüssigkeit) 456 cS
Viskosität bei -40°C
Beispiel 3 Gewichts
prozent
20,00
[CH3(OCH2CH2)3O]3-B 4,70
Tetraäthylenglykolmonoäthyläther 75,01
Triäthylenglykolmonomethyläther 0,25
Monoäthanolamin 0,01
Benzotriazol 0,03
Düsopropanolaminnitrit 100,00
Eigenschaften:
Siedepunkt unter Rückfluß 240° C
(wasserfrei)
Siedepunkt unter Rückfluß
(wasserhaltig)
(3,5 ml Wasser 161,7°C
+ 100 ml Hydraulikflüssikgeit) 373 cS
Viskosität bei —400C
21 47 416 15 168,9° C
5
Beispiel 4
Gewichts
prozent
1H3(OCH2CH2J3O]3-B 40,00 5
■iäthylenglykolmonomethyläther 50,59
iäthanolamin 1,78
>lyäthylenglykol (M. G. 300) 7,62
atriumnitrit 0,01
100,00 ,o
genschaften:
Siedepunkt unter Rückfluß
(wasserfrei) 239,4° C
Siedepunkt unter Rückfluß
(wasserhaltig)
(3,5 ml Wasser
+100 ml Hydraulikflüssigkeit
20
25
30
45
50
55
60

Claims (1)

  1. Patentansprüche:
    1. Hydraulische Flüssigkeit, bestehend aus
    wenigstens einer als Schmiermittel wirkenden Borsäureester-Verbindung,
    einem Verdünnungsmittel der allgemeinen Formel
DE2147416A 1967-04-13 1971-09-22 Wasserunempfindliche hydraulische Flüssigkeiten Expired DE2147416C2 (de)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
US630536A US3632656A (en) 1967-04-13 1967-04-13 Crystallization of mannitol
US65333867A 1967-07-14 1967-07-14
US65333967A 1967-07-14 1967-07-14
US65333567A 1967-07-14 1967-07-14
US65333767A 1967-07-14 1967-07-14
US71799768A 1968-04-01 1968-04-01
US71799668A 1968-04-01 1968-04-01
US80121A US3635825A (en) 1967-07-14 1970-10-12 Water-insensitive hydraulic fluids containing bis-borate esters or bridged-borate esters
US8730670A 1970-11-05 1970-11-05
FR7040995A FR2113788B1 (de) 1967-04-13 1970-11-16
US13340771A 1971-04-12 1971-04-12
US13345271A 1971-04-12 1971-04-12
US13445671A 1971-04-15 1971-04-15
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DE2147416A1 DE2147416A1 (de) 1973-07-26
DE2147416C2 true DE2147416C2 (de) 1984-09-20

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DE19681768133 Pending DE1768133A1 (de) 1967-04-13 1968-04-04 Kristallines Mannitol und Verfahren zu dessen Herstellung
DE1768933A Expired DE1768933C3 (de) 1967-04-13 1968-07-15 Wasserunempfindliche hydraulische Flüssigkeiten
DE2141441A Granted DE2141441B2 (de) 1967-04-13 1971-08-18 Wasserunempfindliche hydraulische Flüssigkeiten
DE2147416A Expired DE2147416C2 (de) 1967-04-13 1971-09-22 Wasserunempfindliche hydraulische Flüssigkeiten
DE19762610934 Pending DE2610934A1 (de) 1967-04-13 1976-03-16 Vergaser fuer ottomotoren

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DE19681768133 Pending DE1768133A1 (de) 1967-04-13 1968-04-04 Kristallines Mannitol und Verfahren zu dessen Herstellung
DE1768933A Expired DE1768933C3 (de) 1967-04-13 1968-07-15 Wasserunempfindliche hydraulische Flüssigkeiten
DE2141441A Granted DE2141441B2 (de) 1967-04-13 1971-08-18 Wasserunempfindliche hydraulische Flüssigkeiten

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DE19762610934 Pending DE2610934A1 (de) 1967-04-13 1976-03-16 Vergaser fuer ottomotoren

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US (6) US3637794A (de)
CA (2) CA987656A (de)
DE (5) DE1768133A1 (de)
FR (3) FR2113788B1 (de)
GB (8) GB1214171A (de)

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Also Published As

Publication number Publication date
DE1768133B2 (de) 1974-04-04
GB1384251A (en) 1975-02-19
US3729497A (en) 1973-04-24
DE2141441B2 (de) 1981-07-23
FR2307970A1 (fr) 1976-11-12
DE1768933C3 (de) 1982-09-16
US3711412A (en) 1973-01-16
GB1384685A (en) 1975-02-19
DE1768133A1 (de) 1971-09-02
FR2132617A2 (de) 1972-11-24
GB1531096A (en) 1978-11-01
DE1768933B2 (de) 1977-11-10
CA980756A (en) 1975-12-30
FR2113788B1 (de) 1974-08-23
DE2141441C3 (de) 1987-12-03
GB1232369A (de) 1971-05-19
US3625899A (en) 1971-12-07
DE2610934A1 (de) 1976-10-21
FR2132617B2 (de) 1975-07-11
GB1232370A (de) 1971-05-19
GB1354355A (en) 1974-06-05
DE2141441A1 (de) 1973-08-16
US3711411A (en) 1973-01-16
US3711410A (en) 1973-01-16
FR2307970B1 (de) 1978-05-05
GB1214171A (en) 1970-12-02
DE2147416A1 (de) 1973-07-26
GB1382418A (en) 1975-01-29
FR2113788A1 (de) 1972-06-30
DE1768933A1 (de) 1972-04-20
CA987656A (en) 1976-04-20
US3637794A (en) 1972-01-25

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