DE3174173D1 - Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization - Google Patents

Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization

Info

Publication number
DE3174173D1
DE3174173D1 DE8181302799T DE3174173T DE3174173D1 DE 3174173 D1 DE3174173 D1 DE 3174173D1 DE 8181302799 T DE8181302799 T DE 8181302799T DE 3174173 T DE3174173 T DE 3174173T DE 3174173 D1 DE3174173 D1 DE 3174173D1
Authority
DE
Germany
Prior art keywords
preparing
aliphatic
fine silica
ethylene polymerization
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8181302799T
Other languages
English (en)
Inventor
Kiu Hee Lee
Gary Stanley Cieloszyk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22592372&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE3174173(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of DE3174173D1 publication Critical patent/DE3174173D1/de
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06Catalyst characterized by its size
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908Containing catalyst of specified particle size
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909Polymerization characterized by particle size of product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Glass Compositions (AREA)
  • Control Of Throttle Valves Provided In The Intake System Or In The Exhaust System (AREA)
  • Air Bags (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Insulating Materials (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
DE8181302799T 1980-06-30 1981-06-22 Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization Expired DE3174173D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/163,959 US4405495A (en) 1980-06-30 1980-06-30 Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization

Publications (1)

Publication Number Publication Date
DE3174173D1 true DE3174173D1 (en) 1986-04-30

Family

ID=22592372

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8181302799T Expired DE3174173D1 (en) 1980-06-30 1981-06-22 Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization

Country Status (27)

Country Link
US (2) US4405495A (de)
EP (1) EP0043220B1 (de)
JP (1) JPS6050367B2 (de)
KR (2) KR840001785B1 (de)
AT (1) ATE18769T1 (de)
AU (1) AU540181B2 (de)
BR (1) BR8104037A (de)
CA (1) CA1171844A (de)
CS (2) CS232723B2 (de)
DD (2) DD160520A5 (de)
DE (1) DE3174173D1 (de)
DK (1) DK288081A (de)
EG (1) EG15793A (de)
ES (2) ES8300118A1 (de)
FI (1) FI70417C (de)
GR (1) GR75713B (de)
IE (1) IE52782B1 (de)
IL (1) IL63155A (de)
IN (2) IN154420B (de)
MA (1) MA19185A1 (de)
MX (1) MX158563A (de)
NO (1) NO160714C (de)
NZ (1) NZ197460A (de)
PH (1) PH19877A (de)
SU (1) SU1295996A3 (de)
TR (1) TR21555A (de)
ZA (1) ZA814068B (de)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58189208A (ja) * 1982-04-30 1983-11-04 Japan Synthetic Rubber Co Ltd 重合体の製造方法
DE3366573D1 (en) * 1982-06-24 1986-11-06 Bp Chimie Sa Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
JPH0629287B2 (ja) * 1984-03-14 1994-04-20 三菱油化株式会社 オレフィン重合用触媒成分
IT1178466B (it) 1984-03-20 1987-09-09 Montedison Spa Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti
JPS61110981U (de) * 1984-12-21 1986-07-14
US4760121A (en) * 1986-01-03 1988-07-26 Mobil Oil Corporation Preparation of alpha-olefin polymers of relatively narrow molecular weight distrbution
DE3634915A1 (de) * 1986-10-14 1988-04-28 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des ethylens mittels eines ziegler-katalysatorsystems
JPS63122710A (ja) * 1986-11-12 1988-05-26 Nippon Petrochem Co Ltd ポリオレフインの製造方法
US5273809A (en) * 1987-04-17 1993-12-28 Mobil Oil Corporation Multilayer stretch wrap film inherently exhibiting a significant cling property
US5617707A (en) * 1987-04-17 1997-04-08 Mobil Oil Corporation Stretch wrap film inherently exhibiting a significant cling property
DE3815486A1 (de) * 1988-05-06 1989-11-16 Basf Ag Katalysator fuer die polymerisation von ethylen, verfahren zu dessen herstellung und verwendung der erhaltenen ethylenpolymerisate zur herstellung von folien mit geringen blockeigenschaften
US5192731A (en) * 1988-05-13 1993-03-09 Mitsui Petrochemical Industries, Ltd. Titanium catalyst components, process for preparing same, catalysts containing same for preparing ethylene polymers and process for preparing said ethylene polymers
WO1989010942A1 (en) * 1988-05-13 1989-11-16 Mitsui Petrochemical Industries, Ltd. Titanium catalyst component, process for its preparation, catalyst for producing ethylenic polymer containing said titanium catalyst component, and process for producing ethylenic polymer
US4876229A (en) * 1988-05-31 1989-10-24 Mobil Oil Corporation Catalyst composition for polymerizing olefins of narrow molecular weight distribution and polymerization therewith
US4983694A (en) * 1988-05-31 1991-01-08 Mobil Oil Corporation Process for polymerizing olefins to form polymers of narrow molecular weight distribution
JP2774171B2 (ja) * 1989-01-21 1998-07-09 三菱化学株式会社 エチレン共重合体の製造法
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
US6025448A (en) * 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
IT1240613B (it) * 1990-03-26 1993-12-17 Enichem Anic Spa Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
FI86989C (fi) * 1990-12-19 1992-11-10 Neste Oy Foerfarande foer framstaellning av en polymerisationskatalysatorkomponent foer olefiner, en polymerisationskatalysatorkomponent som har framstaellts enligt foerfarandet, och dess anvaendning
AR245736A1 (es) * 1991-01-30 1994-02-28 Union Carbide Chem Plastic Un proceso para reducir los extractibles de hexano presentes en copolimeros de etileno.
FI92405C (fi) 1992-12-22 1994-11-10 Borealis Holding As Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin
US5264506A (en) * 1992-12-30 1993-11-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing sticky polymers
CA2177377C (en) * 1993-12-08 2005-01-11 David B. Ramsey Stretch cling film and fabrication method
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5428118A (en) 1994-07-15 1995-06-27 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using gas or gas-solids tangential flow
US5661097A (en) * 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
CA2163465A1 (en) * 1994-11-23 1996-05-24 Arkalgud Venkatapathia Ramamurthy In situ polyethylene blend
US5589539A (en) * 1994-11-23 1996-12-31 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing an in situ polyethylene blend
US5521264A (en) * 1995-03-03 1996-05-28 Advanced Extraction Technologies, Inc. Gas phase olefin polymerization process with recovery of monomers from reactor vent gas by absorption
US5681908A (en) * 1995-03-03 1997-10-28 Advanced Extraction Technologies, Inc. Absorption process for rejection of reactor byproducts and recovery of monomers from waste gas streams in olefin polymerization processes
KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
EP0771820A1 (de) * 1995-11-03 1997-05-07 Union Carbide Chemicals & Plastics Technology Corporation Ziegler-Natta geträgerte Katalysatore für Polyolefin-Herstellung
US6187883B1 (en) * 1996-08-23 2001-02-13 Sumitomo Chemical Company, Limited Solid catalyst component for α-olefin polymerization, catalyst for α-olefin polymerization, and process for producing α-olefin polymer
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US6140264A (en) * 1998-05-12 2000-10-31 Nova Chemicals Ltd. Split aluminum addition process for making catalyst
JP2002265507A (ja) 2001-03-09 2002-09-18 Sumitomo Chem Co Ltd オレフィンの気相流動床式重合反応におけるシーティング防止
CN100351275C (zh) 2003-03-21 2007-11-28 陶氏环球技术公司 形态控制的烯烃聚合方法
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
BRPI0411201B1 (pt) * 2003-05-29 2021-01-26 Basell Poliolefine Italia S.R.L. processo para preparar um componente catalítico
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
US7071137B2 (en) * 2004-08-25 2006-07-04 Novolen Technology Holdings, C.V. Method of making a ziegler-natta catalyst
US20060281879A1 (en) * 2005-06-13 2006-12-14 Univation Technologies, Llc Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
US20070049711A1 (en) * 2005-09-01 2007-03-01 Chi-I Kuo Catalyst compositions comprising support materials having an improved particle-size distribution
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
EP2018389B1 (de) 2006-05-05 2016-03-09 Dow Global Technologies LLC Hafniumkomplexe aus carbazolyl-substituierten imidazolliganden
AU2007293486A1 (en) * 2006-09-07 2008-03-13 Univation Technologies, Llc Methods for on-line determination of degree of resin stickiness using a model for depression of melt initiation temperature
RU2446175C2 (ru) * 2006-09-07 2012-03-27 Юнивейшн Текнолоджиз, Ллк Способы определения значения температуры, характеризующие липкость смолы, на основе данных мониторинга реакции полимеризации
KR20130044226A (ko) * 2010-04-05 2013-05-02 다우 글로벌 테크놀로지스 엘엘씨 고 분자량 분획을 함유하는 올레핀-기재 중합체를 응축 및 초-응축 방식으로 중합시키는 방법
JP6621845B2 (ja) 2015-05-08 2019-12-18 エクソンモービル ケミカル パテンツ インコーポレイテッド 重合方法
JP6743463B2 (ja) 2016-04-12 2020-08-19 住友化学株式会社 ポリオレフィンの製造方法
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
EP3545010B1 (de) 2016-11-28 2021-03-31 Univation Technologies, LLC Herstellung eines polyethylenpolymers
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
JP6916377B2 (ja) * 2017-05-18 2021-08-11 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィンの重合用触媒成分
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
WO2019217173A1 (en) 2018-05-02 2019-11-14 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
CN114829413B (zh) 2019-11-20 2023-04-25 巴塞尔聚烯烃意大利有限公司 制备催化剂组分的方法和由其获得的组分
US11124586B1 (en) 2020-11-09 2021-09-21 Chevron Phillips Chemical Company Lp Particle size control of metallocene catalyst systems in loop slurry polymerization reactors
CN116438206B (zh) 2020-12-08 2024-03-12 切弗朗菲利浦化学公司 环流淤浆聚合反应器中负载型铬催化剂的粒度控制
US11801502B2 (en) 2021-09-13 2023-10-31 Chevron Phillips Chemical Company Lp Hydrocyclone modification of catalyst system components for use in olefin polymerization

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3094568A (en) * 1959-12-01 1963-06-18 Gulf Research Development Co Process for alkylating aromatics in the presence of a heavy metal halide, an organic halide and an organo aluminum halide
NL153168B (nl) * 1965-09-03 1977-05-16 Du Pont Werkwijze voor de bereiding van cyclododecatrieen (1, 5, 9) door trimerisatie van butadieen.
FR1550186A (de) * 1967-08-31 1968-12-20
IE35231B1 (en) * 1970-03-26 1975-12-24 Solvay Process for the preparation of a ziegler-natta type catalyst
NL7113778A (de) * 1970-10-13 1972-04-17
US4098979A (en) * 1970-12-29 1978-07-04 Sumitomo Chemical Company, Limited Method for preparing easily processable polyolefin granule
DE2343361A1 (de) * 1972-08-30 1974-03-14 Stamicarbon Polyalkylene
US3953414A (en) * 1972-09-13 1976-04-27 Montecatini Edison S.P.A., Catalysts for the polymerization of olefins to spherically shaped polymers
US3925338A (en) * 1973-03-16 1975-12-09 Monsanto Co Control of polymer particle size in olefin polymerization
NL7502153A (nl) 1974-02-27 1975-08-29 Monsanto Co Werkwijze voor de regeling van de deeltjes- grootte bij de polymerisatie van alkenen.
DE2553179A1 (de) 1975-11-27 1977-06-08 Hoechst Ag Verfahren zur herstellung eines katalysators
GB1562200A (en) * 1975-12-04 1980-03-05 British Petroleum Co Process for the production of a supported ziegler catalystcomponent
NL7702323A (nl) * 1977-03-04 1978-09-06 Stamicarbon Katalysator voor de bereiding van polyalkenen.
GB2010870B (en) 1977-12-21 1982-05-26 Bp Chem Int Ltd Polymerisaton catalyst
US4302565A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4302566A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor

Also Published As

Publication number Publication date
AU540181B2 (en) 1984-11-08
DD210459A5 (de) 1984-06-13
SU1295996A3 (ru) 1987-03-07
US4405495A (en) 1983-09-20
FI70417C (fi) 1986-09-19
CS228511B2 (en) 1984-05-14
FI812029L (fi) 1981-12-31
CS232723B2 (en) 1985-02-14
IE811456L (en) 1981-12-30
NO160714C (no) 1989-05-24
US4521573A (en) 1985-06-04
MA19185A1 (fr) 1981-12-31
IL63155A (en) 1984-10-31
MX158563A (es) 1989-02-15
KR840001786B1 (ko) 1984-10-20
JPS6050367B2 (ja) 1985-11-08
EG15793A (en) 1987-03-30
PH19877A (en) 1986-08-13
IN156046B (de) 1985-05-04
TR21555A (tr) 1984-09-26
AU7218381A (en) 1982-01-07
NO160714B (no) 1989-02-13
ATE18769T1 (de) 1986-04-15
NZ197460A (en) 1984-03-16
KR840001785B1 (ko) 1984-10-20
CA1171844A (en) 1984-07-31
DD160520A5 (de) 1983-08-17
CS325182A2 (en) 1984-02-13
EP0043220B1 (de) 1986-03-26
IE52782B1 (en) 1988-03-02
ES513361A0 (es) 1983-03-01
ES8303457A1 (es) 1983-03-01
IN154420B (de) 1984-10-27
JPS5744611A (en) 1982-03-13
GR75713B (de) 1984-08-02
EP0043220A1 (de) 1982-01-06
KR830006340A (ko) 1983-09-24
ES503478A0 (es) 1982-11-01
BR8104037A (pt) 1982-03-16
FI70417B (fi) 1986-03-27
ES8300118A1 (es) 1982-11-01
DK288081A (da) 1981-12-31
ZA814068B (en) 1982-07-28
NO812155L (no) 1982-01-04
IL63155A0 (en) 1981-09-13

Similar Documents

Publication Publication Date Title
EG15793A (en) Catalyst impregnated on fine silica,process for preparing and use for ethylene polymerization
DE3064687D1 (en) Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
ES479098A1 (es) Procedimiento catalitico para la produccion de un copolimero de etileno.
JPS5682805A (en) Catalyst component for polymerization of olefins
GR63148B (en) Process for the polymerization of ethylene of a-olefins and catalyst therefor
JPS5340093A (en) Preparation of polyolefin
DE3362530D1 (en) Catalysts for the polymerization and copolymerization of ethylene, and polymerization processes using such catalysts
ES8106915A1 (es) Procedimiento para la preparacion de un catalizador de poli-merizacion
DE3068926D1 (en) Alpha-olefin polymerization catalyst, process for producing catalyst component and process for polymerizing alpha-olefins
JPS57115406A (en) Catalyst component for ethylene polymerization
JPS5693705A (en) Peroxydicarbonate composition and its use for ethylene unsaturated compound polymerization
JPS5317683A (en) Polymerization of alpha-olefin
GR63592B (en) Process for the polymerization of ethylene or a-olefins and catalyst therefor
AU575547B2 (en) Catalyst activator for alpha olefin polymerisation
ES2018115A6 (es) Procedimiento de polimerizacion y copolimerizacion de etileno con otras *-olefinas.
SU472536A1 (ru) Катализатор для полимеризации и сополимеризации олефинов
GB1223086A (en) Ternary olefinic copolymers
TH590EX (th) แคทาลิสท์ที่แพร่อิ่มตัวบนซิลิกาละเอียดและกระบวนการสำหรับการเตรียมและการใช้สำหรับโพลีเมอโรเวชันของเอะลีน
SU1062937A1 (ru) Катализатор для полимеризации этилена и сополимеризации его с альфа-олефинами

Legal Events

Date Code Title Description
8363 Opposition against the patent
8365 Fully valid after opposition proceedings
8328 Change in the person/name/address of the agent

Free format text: BARZ, P., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 80803 MUENCHEN