DE3214798A1 - Method and device for the anaerobic processing of waste - Google Patents

Method and device for the anaerobic processing of waste

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Publication number
DE3214798A1
DE3214798A1 DE19823214798 DE3214798A DE3214798A1 DE 3214798 A1 DE3214798 A1 DE 3214798A1 DE 19823214798 DE19823214798 DE 19823214798 DE 3214798 A DE3214798 A DE 3214798A DE 3214798 A1 DE3214798 A1 DE 3214798A1
Authority
DE
Germany
Prior art keywords
acid
methane
formation
phase
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19823214798
Other languages
German (de)
Other versions
DE3214798C2 (en
Inventor
Rolf August 8012 Ottobrunn Brand
Wilfried 8045 Ismaning Schraufstetter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Airbus Defence and Space GmbH
Original Assignee
Messerschmitt Bolkow Blohm AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE3102739A external-priority patent/DE3102739C2/en
Application filed by Messerschmitt Bolkow Blohm AG filed Critical Messerschmitt Bolkow Blohm AG
Priority to DE3214798A priority Critical patent/DE3214798C2/en
Priority to CH1712/83A priority patent/CH655327A5/en
Priority to AT0135683A priority patent/AT381506B/en
Priority to BR8302146A priority patent/BR8302146A/en
Publication of DE3214798A1 publication Critical patent/DE3214798A1/en
Application granted granted Critical
Publication of DE3214798C2 publication Critical patent/DE3214798C2/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/34Internal compartments or partitions
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M27/00Means for mixing, agitating or circulating fluids in the vessel
    • C12M27/18Flow directing inserts
    • C12M27/24Draft tube
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

Method for the anaerobic processing of plant and animal biomass, also of waste, consisting of organic materials with relatively high molecular weight, in which in a reactor chamber the high molecular weight organic materials are converted by bacterial strains into organic materials with low molecular weight and the latter are converted into lower organic acids with the formation of H2, CO2 and H2S in acetic acid, then the resulting substances are converted by methane-producing bacteria into CH4 and CO2, there being a division of acid phase and methane phase in the reactor chamber (or chambers) preferably in inverse relation to the breakdown rates of the process stages of acid production and methane production, whereby the broken- down products sink to the bottom in the partitioned chamber for the acid phase and reach the fermentation chamber for the methane production, with the resulting gases, especially CO2 and H2S, being separated out from the first phase of the method, the acid phase.

Description

Verfahren und Vorrichtung zur anaeroben Aufbereitung von Method and device for anaerobic treatment of

-=== ====== = Abfall Zusatz zu Patent (Patentanmeldung P 31 02 739.3) Das Hauptpatent .. .. ... (Patentanmeldung P 31 02 739.3) betrifft ein Verfahren zur Herstellung von Biogas aus pflanzlicher und tierischer Biomasse, auch von Abfall, gemäß dem Oberbegriff von Anspruch 1. - === ====== = waste addition to patent (patent application P 31 02 739.3) The main patent ... ... (patent application P 31 02 739.3) relates to a process for the production of biogas from plant and animal biomass, including waste, according to the preamble of claim 1.

Es wurde nun gefunden, daß die in der ersten Phase, der Säurephase, des Abbauverfahrens entstehenden Gase, im wesentlichen CO2 und H2S, den weiteren Verfahrensablauf belasten und insbesondere in kostspieligen, energieintensiven Trennungsgängen aus dem als Endprodukt entstehenden methanhaltigen Biogas abgetrennt werden müssen. It has now been found that the in the first phase, the acid phase, the gases produced during the decomposition process, mainly CO2 and H2S, the others Load the process flow and especially in costly, energy-intensive separation passages must be separated from the methane-containing biogas produced as the end product.

Bei der Speicherung des Biogases können die nur als Ballaststoffe dienenden Gase, wie CO2 und H2S, aus Gründen der Raumerfordernisse nicht in dem Biogas verbleiben und.die Energiessbeute wUrde durch diese Gase vermindert werden. Außerdem würde H2S eine starke Korrosionswirkung im Leitungssystem hervorrufen. When storing the biogas, they can only be used as dietary fiber Serving gases, such as CO2 and H2S, for reasons of space requirements not in the Biogas remain and the energy yield would be reduced by these gases. In addition, H2S would have a strong corrosive effect on the pipe system.

Erfindungsgemäß wurde nun gefunden, daß diese durch das Mitschleppen der Ballastgase entstehenden Nachteile vermieden werden können, wenn diese Gase, insbesondere H2S und CO2, bereits in der ersten Abbauphase, der Säurephase, durch eine Abzugsleitung entfernt werden. According to the invention it has now been found that this is caused by the entrainment the disadvantages arising from ballast gases can be avoided if these gases, in particular H2S and CO2, already in the first breakdown phase, the acid phase a drain pipe can be removed.

Die Erfindung betrifft demgemäß auch einen Bioreaktor zur Durchführung des Verfahrens gemäß Anspruch 2, in dem mindestens eine Auslableitung (7) aus d.:fl Säurebildungsabschnitt (4) zum Austrag der entstehenden Gase vorgesehen ist.The invention accordingly also relates to a bioreactor for implementation of the method according to claim 2, in which at least one discharge line (7) from d.:fl Acid formation section (4) is provided for discharging the gases formed.

Besonders vorteilhaft ist es auch, wenn das Säureabteil (i)4 und das Methanabteil (e?6 voll mit Flüssigkeit gefUllt ist.It is also particularly advantageous if the acid compartment (i) 4 and the Methane compartment (e? 6 is completely filled with liquid.

Dies kann dadurch erreicht werden, daß das Flüssigkeitsniveau im Einfüll- bzw. Austragsstutzen höher als das übrige Niveau gehalten wird.This can be achieved by keeping the liquid level in the filling or discharge nozzle is kept higher than the rest of the level.

Im Ubrigen kann im Ablaßteil der Methanbildungszone (n)6 eine' Überlaufleitung 3 zum Austrag der verbrauchten Biomasse vorhanden sein.Incidentally, in the discharge part of the methane formation zone (s) 6, an overflow line 3 must be available for discharging the used biomass.

Die Figur stellt eine beispielhafte Ausführungsform der Erfindung dar. Die Erfindung ist natürlich auf alle Ausführungsformen, insbesondere auf die in dem Hauptpatent gezeigten, anwendbar.The figure shows an exemplary embodiment of the invention The invention is of course to all embodiments, in particular to shown in the main patent.

In der Figur bezeichnet 1 die Einführleitung für die Biomasse, 4 den Fermentationsraum für die Säurebildungsstufe, 7 die Abführleitung für die in 4 entstehenden Gase, 5 den nach unten offenen Bodenraum für den Übergang in den Fermentationsraum für die Methanbildung 6. Das methanenthaltende Biogas wird über die Leitung 2 abgeführt, während die abgebaute Biomasse über den Überlauf 3 ausgetragen wird.In the figure, 1 denotes the introduction line for the biomass, 4 denotes the Fermentation room for the acid formation stage, 7 the discharge line for those in 4 Gases, 5 the floor space open at the bottom for the transition to the fermentation room for methane formation 6. The methane-containing biogas is discharged via line 2, while the degraded biomass is discharged via the overflow 3.

Claims (2)

Patentansprche ==s======~===========~======= 1. Verfahren zur anaeroben Aufbereitung pflanzlicher und tierischer Biomasse, auch von Abfall, bestehend aus organischen Materialien mit relativ hohem Molekulargewicht, bei dem in einem Reaktorraum die hochmolekularen organischen Materialien durch Bakterienstämme in organische Materialien mit niedrigem Molekulargewicht und diese in niedere organische Säuren unter Bildung von H2, CO2 und H2S in Essigsäure übergeführt werden, dann die entstehenden Substanzen durch methanbildende Bakterien in CH4 und CO2 umgewandelt werden, wobei in dem oder den Reaktorraum (-räumen) eine Aufteilung von Säurephase und Methanphase vorzugsweise im umgekehrten Verhältnis zu den Abbauraten der Prozeßstufen Säurebildung und Methanbildung erfolgt, wodurch in dem (den) abgeteilten Raum (Räumen) für die Säurephase die abgebauten Produkte (im wesentlichen Essigsäure und H2) nach unten sinken und durch eine oder mehrere offene Verbindungen in den Fermentationsraum für die Methanbildung gelangen, nach Patent .. .. *.. (Patentanmeldung P 31 02 739.3), dadurch gekennzeichnet, daß aus der ersten Phase, der Säurephase, die entstehenden Gase, insbesondere C02 \und H2S,durch eine Abzugsleitung abgeführt werden und nicht mehr den weiteren Verfahrensablauf als Ballast belasten. Claims == s ====== ~ =========== ~ ======= 1. Method of anaerobic Processing of plant and animal biomass, including waste, consisting of relatively high molecular weight organic materials in which in a reactor space the high molecular weight organic materials through bacterial strains into organic Low molecular weight materials and these into lower organic acids are converted into acetic acid with the formation of H2, CO2 and H2S, then the resulting Substances are converted into CH4 and CO2 by methane-forming bacteria, whereby in the reactor room (s) there is a division of acid phase and methane phase preferably in inverse proportion to the degradation rates of the acid formation process stages and methane formation takes place, whereby in the (the) partitioned room (s) for the Acid phase the degraded products (mainly acetic acid and H2) down sink and through one or more open connections into the fermentation room for methane formation, according to patent .. .. * .. (patent application P 31 02 739.3), characterized in that from the first phase, the acid phase, the resulting Gases, especially C02 \ and H2S, are discharged through a discharge line and not burden the rest of the process more than ballast. 2. Bioreaktor zur Durchführung des Verfahrens nach Anspruch 1, enthaltend eine Einlaßleitung (1) für die zu behandelnde organische Substanz, Bereiche (4) für die Behandlung der Biomasse mit säurebildenden Bakterien unter Einschluß eines unterhalb liegenden Bereichs (5) für die Essigsäurebildung, einem damit in offener Verbindung stehenden Bereich (6) für die Methanbildung, wobei vorzugsweise das Verhältnis des säurebildenden Bereichs zu dem methanbildenden Bereich im umgekehrten Verhältnis zu den Abbauraten der Säurebildung und Methanbildung steht, einem Gasaustritt (2) und einem Austrag (3) für die abgebaute Biomasse, gekennzeichnet durch eine Austrittsleitung (7) für die in d S§urebildungsraum (4) entstehenden Gase.2. Bioreactor for performing the method according to claim 1, containing an inlet line (1) for the organic substance to be treated, areas (4) for the treatment of the biomass with acid-forming bacteria including a below lying area (5) for the formation of acetic acid, one with it in open Related area (6) for methane formation, preferably the ratio of the acid generating area to the methane generating area in the inverse proportion to the degradation rates of acid formation and methane formation, a gas outlet (2) and a discharge (3) for the degraded biomass, characterized by an outlet line (7) for the gases produced in the acid formation room (4).
DE3214798A 1981-01-28 1982-04-21 Method and device for the anaerobic treatment of waste Expired DE3214798C2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE3214798A DE3214798C2 (en) 1981-01-28 1982-04-21 Method and device for the anaerobic treatment of waste
CH1712/83A CH655327A5 (en) 1982-04-21 1983-03-28 Process and apparatus for anaerobic processing of waste
AT0135683A AT381506B (en) 1982-04-21 1983-04-15 BIOREACTOR FOR ANAEROBIC TREATMENT OF VEGETABLE AND ANIMAL BIOMASS
BR8302146A BR8302146A (en) 1982-04-21 1983-04-20 PROCESS FOR THE PREPARATION OF PLANT AND ANIMAL BIOMASS AND BIO-REACTOR FOR ITS REALIZATION

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3102739A DE3102739C2 (en) 1981-01-28 1981-01-28 Method and device for the anaerobic treatment of waste
DE3214798A DE3214798C2 (en) 1981-01-28 1982-04-21 Method and device for the anaerobic treatment of waste

Publications (2)

Publication Number Publication Date
DE3214798A1 true DE3214798A1 (en) 1983-11-10
DE3214798C2 DE3214798C2 (en) 1984-10-04

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Family Applications (1)

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DE3214798A Expired DE3214798C2 (en) 1981-01-28 1982-04-21 Method and device for the anaerobic treatment of waste

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DE (1) DE3214798C2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0121729A2 (en) * 1983-03-08 1984-10-17 Wilfried Schraufstetter High performance run-through biological reactor
EP0335825A1 (en) * 1988-03-23 1989-10-04 MANNESMANN Aktiengesellschaft Process and device for a two-step anaerobic treatment of liquid substrates
EP0497414A1 (en) * 1991-02-01 1992-08-05 Organic Waste Systems N.V.,in het kort: O.W.S. N.V. Method and device for determining in an accelerated manner the anaerobic biodegradability of a product
US5318909A (en) * 1991-02-01 1994-06-07 Organic Waste Systems, Naamloze Vennootschap Device for the determination of aerobic biodegradability

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NICHTS-ERMITTELT *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0121729A2 (en) * 1983-03-08 1984-10-17 Wilfried Schraufstetter High performance run-through biological reactor
EP0121729A3 (en) * 1983-03-08 1985-12-04 Wilfried Schraufstetter High performance run-through biological reactor
EP0335825A1 (en) * 1988-03-23 1989-10-04 MANNESMANN Aktiengesellschaft Process and device for a two-step anaerobic treatment of liquid substrates
DE3810250A1 (en) * 1988-03-23 1989-10-05 Mannesmann Ag METHOD AND DEVICE FOR THE TWO-STAGE ANAEROBIC TREATMENT OF LIQUID SUBSTRATES
EP0497414A1 (en) * 1991-02-01 1992-08-05 Organic Waste Systems N.V.,in het kort: O.W.S. N.V. Method and device for determining in an accelerated manner the anaerobic biodegradability of a product
BE1004426A3 (en) * 1991-02-01 1992-11-17 Organic Waste Systems Nv Method and apparatus for an accelerated on way to determine the anaerobic biodegradability of a product.
US5264349A (en) * 1991-02-01 1993-11-23 Organic Waste Systems, Naamloze Vennootschap Method and device for determining in an accelerated manner the anaerobic biodegradability of a product
US5318909A (en) * 1991-02-01 1994-06-07 Organic Waste Systems, Naamloze Vennootschap Device for the determination of aerobic biodegradability

Also Published As

Publication number Publication date
DE3214798C2 (en) 1984-10-04

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