DE3485074D1 - Verfahren und katalysator fuer die herstellung von polyaethylen mit einer breiten molekulargewichtsverteilung. - Google Patents

Verfahren und katalysator fuer die herstellung von polyaethylen mit einer breiten molekulargewichtsverteilung.

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Publication number
DE3485074D1
DE3485074D1 DE8484303804T DE3485074T DE3485074D1 DE 3485074 D1 DE3485074 D1 DE 3485074D1 DE 8484303804 T DE8484303804 T DE 8484303804T DE 3485074 T DE3485074 T DE 3485074T DE 3485074 D1 DE3485074 D1 DE 3485074D1
Authority
DE
Germany
Prior art keywords
catalyst
polyethylene
production
molecular weight
weight distribution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8484303804T
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English (en)
Inventor
John Alexander Ewen
Welborn, Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of DE3485074D1 publication Critical patent/DE3485074D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
DE8484303804T 1983-06-06 1984-06-05 Verfahren und katalysator fuer die herstellung von polyaethylen mit einer breiten molekulargewichtsverteilung. Expired - Lifetime DE3485074D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/501,740 US4530914A (en) 1983-06-06 1983-06-06 Process and catalyst for producing polyethylene having a broad molecular weight distribution

Publications (1)

Publication Number Publication Date
DE3485074D1 true DE3485074D1 (de) 1991-10-24

Family

ID=23994836

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8484303804T Expired - Lifetime DE3485074D1 (de) 1983-06-06 1984-06-05 Verfahren und katalysator fuer die herstellung von polyaethylen mit einer breiten molekulargewichtsverteilung.

Country Status (10)

Country Link
US (1) US4530914A (de)
EP (1) EP0128045B1 (de)
JP (1) JPH0791328B2 (de)
AU (1) AU567562B2 (de)
CA (1) CA1231701A (de)
DE (1) DE3485074D1 (de)
ES (1) ES8506328A1 (de)
MX (1) MX168236B (de)
NO (1) NO164906C (de)
ZA (1) ZA844156B (de)

Families Citing this family (368)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX167872B (es) * 1983-06-06 1993-04-20 Exxon Research Engineering Co Proceso y catalizador para producir poliolefinas dmezclas del reactor
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US5580939A (en) * 1983-06-06 1996-12-03 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
FR2570381B1 (fr) * 1984-09-17 1987-05-15 Bp Chimie Sa Procede de polymerisation d'ethylene ou de copolymerisation d'ethylene et d'alpha-olefine en lit fluidise en presence de catalyseur a base d'oxyde de chrome
JPH0788403B2 (ja) * 1984-11-01 1995-09-27 昭和電工株式会社 ポリオレフインの製造方法
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
EP0200351B2 (de) * 1985-03-26 1996-10-16 Mitsui Petrochemical Industries, Ltd. Flüssiges statisches Ethylencopolymer, Verfahren zur Herstellung und Anwendung desselben
JPH0639496B2 (ja) * 1985-06-03 1994-05-25 旭化成工業株式会社 オレフインの重合方法
US4897455A (en) * 1985-06-21 1990-01-30 Exxon Chemical Patents Inc. Polymerization process
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5124418A (en) * 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US4791180A (en) * 1985-12-12 1988-12-13 Exxon Chemical Patents Inc. New polymerization catalyst
IL80888A (en) * 1985-12-12 1991-12-12 Exxon Chemical Patents Inc Olefin polymerization catalysts,their preparation and use thereof
US6013743A (en) * 1985-12-24 2000-01-11 Mitsui Chemicals Inc. Process for polymerization of alpha-olefins
US5641843A (en) * 1985-12-24 1997-06-24 Mitsui Petrochemical Industries, Ltd. Process for polymerization of alpha-olefins
US5700750A (en) * 1985-12-26 1997-12-23 Mitsui Petrochemical Industries, Ltd. Process for polymerization of alpha-olefins
JPH0780930B2 (ja) * 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
US4658078A (en) * 1986-08-15 1987-04-14 Shell Oil Company Vinylidene olefin process
US5654248A (en) * 1986-08-26 1997-08-05 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing alpha-olefins and process for polymerization
KR920001353B1 (ko) * 1986-08-26 1992-02-11 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 α-올레핀의 중합용 촉매 및 중합법
US5077255A (en) * 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
ATE177759T1 (de) 1986-09-24 1999-04-15 Mitsui Chemicals Inc Verfahren zur olefinpolymerisation
US5700749A (en) * 1986-09-24 1997-12-23 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins
JPH0780933B2 (ja) * 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
JPH03503674A (ja) * 1986-11-20 1991-08-15 エヌディーイー・テクノロジー・インコーポレーテッド 地下貯蔵タンク等の容積漏れ検出システム
DE3640924A1 (de) * 1986-11-29 1988-06-01 Hoechst Ag 1-olefin-stereoblockpolymer und verfahren zu seiner herstellung
JP2618384B2 (ja) * 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
US4921825A (en) * 1986-12-30 1990-05-01 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and processes for its production
JPH0742301B2 (ja) * 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
US5003019A (en) * 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
US4874880A (en) * 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US5064797A (en) * 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
ATE133690T1 (de) 1987-04-03 1996-02-15 Fina Technology Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke.
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4975403A (en) * 1987-09-11 1990-12-04 Fina Technology, Inc. Catalyst systems for producing polyolefins having a broad molecular weight distribution
DE3750776T2 (de) * 1987-09-11 1995-04-27 Fina Technology Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung.
JPH0713075B2 (ja) * 1988-06-20 1995-02-15 チッソ株式会社 橋架け構造のビス置換シクロペンタジエニル配位子を有するジルコニウム化合物
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
JPH0720973B2 (ja) * 1988-06-20 1995-03-08 チッソ株式会社 橋架け構造のビス置換シクロペンタジエニル配位子を有するハフニウム化合物
US4912075A (en) * 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
DE3808267A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5008228A (en) * 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
KR100197327B1 (ko) * 1988-07-15 1999-06-15 치어즈 엠. 노우드 신디오택틱 폴리프로필렌
US5043515A (en) * 1989-08-08 1991-08-27 Shell Oil Company Ethylene oligomerization catalyst and process
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
EP0685498B1 (de) 1988-12-26 1999-05-26 Mitsui Chemicals, Inc. Olefincopolymere und Verfahren zur Herstellung davon
US5830087A (en) * 1995-06-26 1998-11-03 Lisco, Inc. Multi-layer golf ball
DE3907964A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
DE3916553A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
US5004820A (en) * 1989-08-07 1991-04-02 Massachusetts Institute Of Technology Preparation of chiral metallocene dihalides
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US6686488B2 (en) 1989-08-31 2004-02-03 The Dow Chemical Company Constrained geometry addition polymerization catalysts
US6025448A (en) * 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
US6075077A (en) * 1989-08-31 2000-06-13 The Dow Chemical Company Asphalt, bitumen, and adhesive compositions
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US7041841B1 (en) 1989-09-13 2006-05-09 Exxonmobil Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5547675A (en) * 1989-09-13 1996-08-20 Exxon Chemical Patents Inc. Modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins
US5036034A (en) * 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
US5151204A (en) * 1990-02-01 1992-09-29 Exxon Chemical Patents Inc. Oleaginous compositions containing novel ethylene alpha-olefin polymer viscosity index improver additive
MY107639A (en) * 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
DE4015254A1 (de) * 1990-05-12 1991-11-14 Hoechst Ag Verfahren zur herstellung eines polyolefins
US5070055A (en) * 1990-06-29 1991-12-03 Union Carbide Chemicals And Plastics Technology Corporation Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5262498A (en) * 1991-01-12 1993-11-16 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
US5169818A (en) * 1991-01-12 1992-12-08 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
CA2060019A1 (en) * 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
EP0503422B1 (de) 1991-03-09 1998-06-03 TARGOR GmbH Verfahren zur Herstellung chemisch einheitlicher Cycloolefincopolymere
JP3117231B2 (ja) * 1991-03-11 2000-12-11 三井化学株式会社 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法
US5418200A (en) * 1991-03-29 1995-05-23 Chevron Chemical Company Cyclopentadienyl group 6B metal α-olefin polymerization catalysts and process for polymerizing α-olefins
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5399636A (en) * 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
EP0702030B1 (de) 1991-05-27 2001-03-21 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
EP0516019B1 (de) * 1991-05-27 1995-12-27 Hoechst Aktiengesellschaft Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung
US5693583A (en) * 1991-06-10 1997-12-02 Mobil Oil Corporation High activity polyethylene catalysts which produce bimodal or trimodal product molecular weight distributions
CA2071706C (en) * 1991-06-20 1996-09-17 Junichi Imuta Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst
US5594078A (en) * 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
US5250612A (en) * 1991-10-07 1993-10-05 The Dow Chemical Company Polyethylene films exhibiting low blocking force
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5847053A (en) * 1991-10-15 1998-12-08 The Dow Chemical Company Ethylene polymer film made from ethylene polymer blends
US5525695A (en) 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5582923A (en) * 1991-10-15 1996-12-10 The Dow Chemical Company Extrusion compositions having high drawdown and substantially reduced neck-in
US5783638A (en) * 1991-10-15 1998-07-21 The Dow Chemical Company Elastic substantially linear ethylene polymers
US5395471A (en) * 1991-10-15 1995-03-07 The Dow Chemical Company High drawdown extrusion process with greater resistance to draw resonance
US5677383A (en) * 1991-10-15 1997-10-14 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
US5674342A (en) * 1991-10-15 1997-10-07 The Dow Chemical Company High drawdown extrusion composition and process
JP3378598B2 (ja) * 1991-10-28 2003-02-17 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒組成物
US5286694A (en) * 1991-12-11 1994-02-15 Phillips Petroleum Company Lanthanide halide catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US5260244A (en) * 1991-12-19 1993-11-09 Phillips Petroleum Company Transition metal/rare earth catalyst, olefin polymeration process, and polymer produced
US5182244A (en) * 1991-12-19 1993-01-26 Phillips Petroleum Company Transition metal/rare earth catalyst and olefin polymerization process
KR100253826B1 (ko) 1991-12-30 2000-04-15 그레이스 스티븐 에스. 에틸렌 공중합체의 중합방법
US6184326B1 (en) 1992-03-20 2001-02-06 Fina Technology, Inc. Syndiotactic polypropylene
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US5308817A (en) * 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
US5688887A (en) * 1992-05-26 1997-11-18 Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
US6043401A (en) * 1992-05-26 2000-03-28 Bp Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
DE69332811T2 (de) * 1992-07-01 2004-01-29 Exxonmobil Chem Patents Inc Auf Übergangsmetallen der Gruppen 5 und 6 basierende Katalysator-Vorläufer
US5332707A (en) * 1992-07-31 1994-07-26 Amoco Corporation Olefin polymerization and copolymerization catalyst
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5464905A (en) * 1992-11-19 1995-11-07 Mitsui Petrochemical Industries, Ltd. Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
CA2103379C (en) * 1992-11-19 2000-05-23 Toshiyuki Tsutsui Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition
US6001941A (en) 1992-11-19 1999-12-14 Mitsui Chemicals, Inc. Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin
GB9224876D0 (en) 1992-11-27 1993-01-13 Exxon Chemical Patents Inc Improved processing polyolefin blends
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5602067A (en) * 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
PT681592E (pt) * 1993-01-29 2001-01-31 Dow Chemical Co Interpolimerizacoes de etileno
US5350807A (en) * 1993-06-25 1994-09-27 Phillips Petroleum Company Ethylene polymers
US5539069A (en) * 1993-08-10 1996-07-23 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalysts and methods of olefin polymerization
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) * 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
US5455741A (en) * 1993-10-26 1995-10-03 Pulse Engineering, Inc. Wire-lead through hole interconnect device
ZA948934B (en) * 1993-11-15 1996-05-10 Mobil Oil Corp Catalyst composition for use in the polymerization and copolymerization of ethylene
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
US5399622A (en) * 1993-11-17 1995-03-21 Phillips Petroleum Company System of chromium catalyst and yttrium catalyst, olefin polymerization process, and polymer
DE69419893T2 (de) * 1993-12-27 1999-12-02 Mitsui Chemicals Inc Katalysator und Verfahren zur Olefinpolymerisation
US5624877A (en) * 1994-02-25 1997-04-29 Phillips Petroleum Company Process for producing polyolefins
US5543376A (en) * 1994-02-25 1996-08-06 Phillips Petroleum Company Process for producing polyolefins
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
US5541272A (en) 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
ATE207085T1 (de) * 1994-06-24 2001-11-15 Exxonmobil Chem Patents Inc Polymerisationskatalysatorsystem, ihre herstellung und verwendung
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
EP0776909B1 (de) * 1994-08-18 2003-11-19 Asahi Kasei Kabushiki Kaisha Ethylenpolymer hoher dichte und verfahren zu dessen herstellung
JPH10505622A (ja) 1994-09-08 1998-06-02 モービル・オイル・コーポレーション 単一の反応器内での広い/2モードのmwdの樹脂の触媒制御
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5741195A (en) * 1994-09-30 1998-04-21 Lisco, Inc. High visibility inflated game ball
US5792534A (en) * 1994-10-21 1998-08-11 The Dow Chemical Company Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US5549867A (en) * 1994-11-03 1996-08-27 Fiberweb North America, Inc. Distribution enhanced polyolefin meltspinning process and product
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US5543484A (en) * 1994-11-18 1996-08-06 The Penn State Research Foundation α-olefin/para-alkylstyrene copolymers
US5625015A (en) 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
ES2116188B1 (es) 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
US5670589A (en) * 1995-02-08 1997-09-23 Phillips Petroleum Company Organoaluminoxy product, catalyst systems, preparation, and use
EP0729967B1 (de) * 1995-02-17 1998-08-12 Witco GmbH Verfahren zur Herstellung von Übergangsmetallkomplexen mit 1,3-disubstituierten Cyclopentadienyl-Liganden
US5593931A (en) * 1995-03-03 1997-01-14 Chevron Chemical Company Cyclopentadienyl group 6b metal alpha-olefin polymerization catalysts and process for polymerizing alpha-olefins
BE1009186A3 (fr) * 1995-03-13 1996-12-03 Solvay Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.
US5830958A (en) * 1995-05-12 1998-11-03 Phillips Petroleum Company Polynuclear metallocene preparation and use
US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
DE69621809T2 (de) 1995-08-10 2003-01-09 Exxonmobil Chem Patents Inc Mit metallocen stabilisiertes alumoxan
US5652202A (en) * 1995-08-15 1997-07-29 Exxon Chemical Patents Inc. Lubricating oil compositions
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
US5558802A (en) * 1995-09-14 1996-09-24 Exxon Chemical Patents Inc Multigrade crankcase lubricants with low temperature pumpability and low volatility
US5916982A (en) * 1995-09-29 1999-06-29 Nippon Oil Co., Ltd. Process for the production of polyolefins
US5795941A (en) * 1995-10-03 1998-08-18 The Dow Chemical Company Crosslinkable bimodal polyolefin compositions
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
WO1997021745A1 (fr) * 1995-12-08 1997-06-19 Kaneka Corporation Resine de polyolefine greffee et composition de resine thermoplastique la contenant
TR199601005A2 (tr) 1995-12-15 1997-07-21 Union Carbide Chem Plastic Uzun zincirli, dallanmis poliolefinlerin üretimi icin yöntem.
US6395669B1 (en) * 1996-01-18 2002-05-28 Equistar Chemicals, Lp Catalyst component and system
NO300220B1 (no) 1996-01-26 1997-04-28 Borealis As Fremgangsmåte og katalysatorsystem for polymerisering av etylen, eventuelt sammen med <alfa>-olefiner, og fremstilt polymermateriale
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
US5644007A (en) * 1996-04-26 1997-07-01 Minnesota Mining And Manufacturing Company Continuous process for the production of poly(1-alkenes)
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
EP0906343B1 (de) * 1996-06-17 2001-04-18 Exxon Chemical Patents Inc. Olefinpolymerisationkatalysatorsysteme von gemischten übergangsmetalen
GB9613814D0 (en) * 1996-07-02 1996-09-04 Bp Chem Int Ltd Supported polymerisation catalysts
AU3505497A (en) * 1996-07-15 1998-02-09 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
US6248837B1 (en) 1996-07-15 2001-06-19 The Penn State Research Foundation Process for preparing polyolefin diblock copolymers involving borane chain transfer reaction in transition metal-mediated olefin polymerization
US5849823A (en) * 1996-09-04 1998-12-15 The Dow Chemical Company Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications
HUP9904527A2 (hu) * 1996-11-15 2000-05-28 Montell Technology Company B.V. Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorok
US6177377B1 (en) * 1996-12-18 2001-01-23 Amherst Polymer Technology, Inc. Polymer blends and process for preparation
US6005463A (en) * 1997-01-30 1999-12-21 Pulse Engineering Through-hole interconnect device with isolated wire-leads and component barriers
KR100564500B1 (ko) * 1997-02-07 2006-03-29 엑손모빌 케미칼 패턴츠 인코포레이티드 폴리에틸렌 마크로머를 혼입한 프로필렌 중합체
JP2001511214A (ja) 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク ビニル含有マクロマーの調製
US6552126B2 (en) 1997-03-03 2003-04-22 Spalding Sports Worldwide, Inc. Golf ball cover containing a blend of ionomer and plastomer, and method of making same
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6153551A (en) * 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6482765B1 (en) 1997-08-21 2002-11-19 Sumitomo Chemical Company, Limited Modified particles, carrier prepared therefrom, olefin polymerization catalyst component prepared therefrom, olefin polymerization catalyst prepared therefrom, and process for preparing olefin polymer
US6114483A (en) * 1997-08-27 2000-09-05 E. I. Du Pont De Nemours And Company Polymerization of olefins
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
DE69907785T2 (de) 1998-03-09 2004-02-12 Basell Poliolefine Italia S.P.A. Mehrstufiges Verfahren zur Olefinpolymerisation
JP4440355B2 (ja) 1998-03-25 2010-03-24 住友化学株式会社 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法
CN1130392C (zh) 1998-05-13 2003-12-10 埃克森美孚化学专利公司 丙烯均聚物及其制备方法
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6207606B1 (en) * 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US6376416B1 (en) * 1998-07-21 2002-04-23 Japan Polychem Corporation Olefin polymerization catalyst and process for producing olefin polymer
CA2245375C (en) 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
EP1115761B1 (de) 1998-08-26 2013-09-18 ExxonMobil Chemical Patents Inc. Verzweigte polypropylenzusammensetzungen
CA2247703C (en) 1998-09-22 2007-04-17 Nova Chemicals Ltd. Dual reactor ethylene polymerization process
US6258903B1 (en) * 1998-12-18 2001-07-10 Univation Technologies Mixed catalyst system
US6291608B1 (en) * 1998-12-23 2001-09-18 Phillips Petroleum Company Polymerization catalyst system and polymerization process
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
TW444043B (en) 1999-05-11 2001-07-01 Ind Tech Res Inst Resin compositions for electric circuit boards
DE19929809A1 (de) 1999-06-30 2001-01-04 Ticona Gmbh Kontinuierliches Verfahren zur Herstellung eines amorphen Polyolefins mit breiter Molmassenverteilung und einheitlicher Glastemperatur
CA2278042C (en) 1999-07-19 2008-12-16 Nova Chemicals Corporation Mixed phosphinimine catalyst
US6096849A (en) * 1999-07-21 2000-08-01 The Penn State Research Foundation Linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same
US6265493B1 (en) 1999-07-21 2001-07-24 The Penn State Research Foundation Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
US6403520B1 (en) 1999-09-17 2002-06-11 Saudi Basic Industries Corporation Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6294626B1 (en) 1999-11-15 2001-09-25 Equistar Chemicals, Lp Olefin polymerization catalysts containing modified boraaryl ligands
US6809168B2 (en) * 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
US6977287B2 (en) * 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
ATE293643T1 (de) * 1999-12-10 2005-05-15 Exxonmobil Chem Patents Inc Propen dien copolymerisate
US6399531B1 (en) 1999-12-28 2002-06-04 Union Carbide Chemicals & Plastics Technology Corporation Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins
US6444605B1 (en) 1999-12-28 2002-09-03 Union Carbide Chemicals & Plastics Technology Corporation Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins
ATE239057T1 (de) 2000-02-15 2003-05-15 Asahi Chemical Ind Polyamidzusammensetzung
US6455638B2 (en) 2000-05-11 2002-09-24 Dupont Dow Elastomers L.L.C. Ethylene/α-olefin polymer blends comprising components with differing ethylene contents
US6812304B2 (en) 2000-06-14 2004-11-02 Equistar Chemicals, Lp Process for producing improved premixed supported boraaryl catalysts
US6444765B1 (en) 2000-06-14 2002-09-03 Equistar Chemicals, Lp Olefin polymerization process for producing broad MWD polymers
US6518445B1 (en) 2000-12-15 2003-02-11 Albemarle Corporation Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof
US6388051B1 (en) 2000-12-20 2002-05-14 Union Carbide Chemicals & Plastics Technology Corporation Process for selecting a polyethylene having improved processability
US6479600B2 (en) 2001-01-08 2002-11-12 The Penn State Research Foundation Polyolefin containing a terminal phenyl or substituted phenyl group and process for preparing same
MY137183A (en) 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
GB0111443D0 (en) * 2001-05-10 2001-07-04 Borealis Tech Oy Olefin polymerisation process
CA2347410C (en) 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
SG96700A1 (en) * 2001-09-27 2003-06-16 Sumitomo Chemical Co Catalyst component for addition polymerization, process for producing catalyst for addition polymerization and process for producing addition polymer
CN1275985C (zh) * 2001-11-30 2006-09-20 埃克森美孚化学专利公司 用非单中心/单中心催化剂结合物制备的乙烯/α-烯烃共聚物及其制备方法和用途
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
DE60314852T2 (de) * 2002-03-19 2007-11-08 Ineos Europe Ltd., Lyndhurst Zyklon zur zentrifugaltrennung eines gemisches aus gas und feststoffteilchen
EP1495038B1 (de) * 2002-04-12 2008-07-23 Dow Global Technologies Inc. Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation
JP2005528501A (ja) * 2002-06-04 2005-09-22 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション ポリマー組成物およびそれらからパイプ類を製造する方法
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
DE10393129T5 (de) * 2002-08-16 2005-09-01 Johnson & Johnson Vision Care, Inc., Jacksonville Formen für die Herstellung von Kontaktlinsen
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
EP1539841B1 (de) * 2002-09-20 2012-08-01 ExxonMobil Chemical Patents Inc. Herstellung von polymeren unter überkritischen bedingungen
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US7541412B2 (en) * 2002-12-20 2009-06-02 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7183364B2 (en) * 2002-12-20 2007-02-27 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7199072B2 (en) * 2002-12-31 2007-04-03 Univation Technologies, Llc Process of producing a supported mixed catalyst system and polyolefins therefrom
US7195806B2 (en) * 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
EP1611169B1 (de) 2003-03-21 2010-06-02 Dow Global Technologies Inc. Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
DE102004008313B4 (de) * 2004-02-20 2014-01-16 Wankel Super Tec Gmbh Kreiskolbenbrennkraftmaschine mit einer verbesserten Innendichtung
EP1574525B1 (de) * 2004-03-12 2007-05-02 Saudi Basic Industries Corporation Katalysatorzusammensetzung für die Polymerisation von Olefinen und Polymerisationsverfahren unter dessen Verwendung
EP1732957B1 (de) * 2004-04-07 2012-05-23 Union Carbide Chemicals & Plastics Technology LLC Verfahren zur steuerung der olefinpolymerisation
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
KR100677869B1 (ko) * 2004-07-01 2007-02-02 대림산업 주식회사 다중핵 금속 화합물, 이를 포함하는 촉매 시스템 및 이를이용한 올레핀의 중합 방법
WO2006025949A2 (en) * 2004-07-08 2006-03-09 Exxonmobil Chemical Patents Inc. Polymer production at supercritical conditions
US20060052540A1 (en) 2004-09-09 2006-03-09 Maria Ellul Thermoplastic vulcanizates
EP1650232A1 (de) * 2004-10-25 2006-04-26 Total Petrochemicals Research Feluy Herstellung von LDPE-Polymeren mittels Bisindenyl-Liganden, die verschiedene Ringsysteme enthalten
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7321015B2 (en) * 2004-12-07 2008-01-22 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
US7064096B1 (en) * 2004-12-07 2006-06-20 Nova Chemicals (International) Sa Dual catalyst on a single support
US7323523B2 (en) 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
AU2005316788B2 (en) 2004-12-17 2012-04-05 Dow Global Technologies Llc Rheology modified polyethylene compositions
JP5154754B2 (ja) * 2005-01-31 2013-02-27 三井化学株式会社 エチレン系重合体およびこれから得られる成形体
US20060205898A1 (en) * 2005-03-08 2006-09-14 Goyal Shivendra K Dual reactor polyethylene resins with balanced physical properties
WO2006102106A1 (en) * 2005-03-17 2006-09-28 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
WO2006102119A2 (en) * 2005-03-17 2006-09-28 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
US20060235147A1 (en) * 2005-04-14 2006-10-19 Nova Chemicals (International) S.A. Dual reactor polyethylene resins for food packaging - films, bags and pouches
JP5158304B2 (ja) * 2005-04-21 2013-03-06 東ソー株式会社 ポリエチレンの製造方法
US20060247373A1 (en) * 2005-04-28 2006-11-02 Nova Chemicals (International) S.A. Dual reactor polyethylene resins for electronic packaging-films, tapes, bags and pouches
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
WO2007025556A1 (en) * 2005-08-30 2007-03-08 Pirelli & C. S.P.A. Process for manufacturing a thermoplastic elastomeric material
US7714082B2 (en) * 2005-10-04 2010-05-11 Univation Technologies, Llc Gas-phase polymerization process to achieve a high particle density
US7531602B2 (en) * 2005-10-05 2009-05-12 Nova Chemicals (International) S.A. Polymer blends
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
KR100886681B1 (ko) 2006-03-31 2009-03-04 주식회사 엘지화학 선형 저밀도 폴리에틸렌의 제조방법
EP1847555A1 (de) * 2006-04-18 2007-10-24 Borealis Technology Oy Mehrfach verzweigtes Polypropylen
JP5575470B2 (ja) 2006-05-02 2014-08-20 ダウ グローバル テクノロジーズ エルエルシー 高密度ポリエチレン組成物、それを作製する方法、それから作製されるワイヤおよびケーブル用ジャケット、ならびにそのようなワイヤおよびケーブル用ジャケットを作製する方法
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US7662894B2 (en) * 2006-12-19 2010-02-16 Saudi Bosic Industries Corporation Polymer supported metallocene catalyst composition for polymerizing olefins
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) * 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
US7754834B2 (en) * 2007-04-12 2010-07-13 Univation Technologies, Llc Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density
CN101490163A (zh) * 2007-05-02 2009-07-22 陶氏环球技术公司 高密度聚乙烯组合物、其制备方法、由其制得的注塑制品以及该制品的制备方法
US8487033B2 (en) * 2007-05-16 2013-07-16 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom
US8470939B2 (en) * 2007-06-01 2013-06-25 Equistar Chemicals, Lp Preparation of polyethylene
ES2446294T3 (es) * 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
US8962762B2 (en) * 2007-06-13 2015-02-24 Exxonmobil Chemical Patents Inc. Thermoplastic polymer compositions, methods for making the same, and articles made therefrom
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
EP2195349B1 (de) * 2007-09-13 2012-07-11 ExxonMobil Research and Engineering Company In-line-verfahren zur herstellung von weichgemachten polymeren und weichgemachten polymerblends
EP2201042B1 (de) * 2007-09-13 2012-06-27 ExxonMobil Research and Engineering Company In-line-mischen von weichmachern mit einem basispolymer
WO2011087520A1 (en) 2009-12-22 2011-07-21 Univation Technologies, Llc Catalyst systems having a tailored hydrogen response
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
JP5308797B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP5308794B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 噴流層装置を用いたポリオレフィン製造方法
JP5249730B2 (ja) 2007-12-11 2013-07-31 住友化学株式会社 オレフィン重合反応装置及びポリオレフィン製造方法
JP5308795B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 ポリオレフィン製造方法、並びに、噴流層装置を備えたポリオレフィン製造システム
JP5427396B2 (ja) 2007-12-11 2014-02-26 住友化学株式会社 粉体移送装置、及び、ポリオレフィンの製造方法
WO2009078487A1 (ja) 2007-12-19 2009-06-25 Japan Polyethylene Corporation 発泡性積層体用樹脂、発泡性積層体、及びそれを用いた発泡加工紙並びに断熱容器
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
CN101945942B (zh) * 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
EP2083046A1 (de) 2008-01-25 2009-07-29 ExxonMobil Chemical Patents Inc. Thermoplastische Elastomerzusammensetzungen
EP2172490A1 (de) 2008-10-03 2010-04-07 Ineos Europe Limited Polimerisationsverfahren
DE112009002670B4 (de) 2008-10-30 2020-02-20 Dow-Mitsui Polychemicals Co.,Ltd. Mehrschichtige Folie und deren Verwendung als Dichtungsmaterial für ein Solarzellenelement sowie Solarzellenmodul
RU2515900C2 (ru) 2008-12-18 2014-05-20 Юнивейшн Текнолоджиз, Ллк Способ обработки зародышевого слоя реакции полимеризации
WO2010088265A1 (en) 2009-01-30 2010-08-05 Dow Global Technologies Inc. High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices
US8791208B2 (en) 2009-02-17 2014-07-29 Du Pont-Mitsui Polychemicals Co., Ltd. Sheet for solar cell encapsulant and solar cell module
CN102341159B (zh) 2009-03-30 2014-07-23 东丽电池隔膜株式会社 微孔膜、该膜的制备方法及该膜作为电池隔膜的应用
CN102422437B (zh) 2009-05-13 2016-05-04 三井-杜邦聚合化学株式会社 太阳能电池密封材料用片材及太阳能电池组件
CA2757045C (en) 2009-05-14 2017-03-07 Univation Technologies, Llc Mixed metal catalyst systems having a tailored hydrogen response
JP5545800B2 (ja) 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
MX2012000250A (es) * 2009-06-29 2012-01-25 Chevron Philips Chemical Company Lp Sistemas catalizadores duales de metaloceno para disminuir el indice de fusion e incrementar las velocidades de produccion de polimero.
US8207280B2 (en) 2009-06-29 2012-06-26 Chevron Phillips Chemical Company Lp Use of hydrogen scavenging catalysts to control polymer molecular weight and hydrogen levels in a polymerization reactor
WO2011075536A2 (en) 2009-12-18 2011-06-23 Chevron Oronite Company Llc Carbonyl-ene functionalized polyolefins
EP2357035A1 (de) 2010-01-13 2011-08-17 Ineos Europe Limited Polymerpulveraufbewahrungs- und/oder -transport- und/oder -entgasungsgefäßen
EP2383298A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
EP2383301A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
US20130137331A1 (en) 2010-06-15 2013-05-30 Galen C. Richeson Nonwoven Fabrics Made From Polymer Blends And Methods For Making Same
WO2012072417A1 (en) 2010-11-29 2012-06-07 Ineos Commercial Services Uk Limited Polymerisation control process
CN103402636B (zh) 2011-01-14 2016-12-14 格雷斯公司 制造改性金属茂催化剂的方法、制成的催化剂及其用途
SG184672A1 (en) 2011-03-25 2012-10-30 Sumitomo Chemical Co Olefin polymerization reactor, polyolefin production system, and polyolefin production process
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
EP2573091A1 (de) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen
CN103874714B (zh) 2011-10-17 2016-06-22 英尼奥斯欧洲股份公司 聚合物脱气工艺控制
KR101339550B1 (ko) * 2011-11-24 2013-12-10 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법
KR101331556B1 (ko) 2012-03-30 2013-11-20 대림산업 주식회사 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
US8940842B2 (en) * 2012-09-24 2015-01-27 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations
US8865846B2 (en) 2012-09-25 2014-10-21 Chevron Phillips Chemical Company Lp Metallocene and half sandwich dual catalyst systems for producing broad molecular weight distribution polymers
KR101437509B1 (ko) 2012-12-03 2014-09-03 대림산업 주식회사 성형성 및 기계적 물성이 우수한 멀티모달 폴리올레핀 수지 제조를 위한 촉매 조성물 및 이를 이용한 중합 방법
CN104918947A (zh) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 将铝氧烷的生产整合到催化剂生产中的方法
KR102135226B1 (ko) 2013-01-14 2020-07-20 유니베이션 테크놀로지즈, 엘엘씨 증가된 생산성을 갖는 촉매 시스템의 제조 방법
WO2016094848A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Organosilica materials for use as adsorbents for oxygenate removal
US10294312B2 (en) 2014-12-12 2019-05-21 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016171807A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
EP3274381B1 (de) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Katalysatorzusammensetzung mit fluoridiertem träger und verfahren zur verwendung davon
KR102006096B1 (ko) 2015-05-08 2019-07-31 엑손모빌 케미칼 패턴츠 인코포레이티드 중합 방법
JP6499927B2 (ja) 2015-06-10 2019-04-10 Jxtgエネルギー株式会社 網状構造体
KR101850985B1 (ko) 2015-06-15 2018-04-20 주식회사 엘지화학 메탈로센 담지 촉매의 제조 방법
KR101810740B1 (ko) 2015-09-25 2017-12-20 롯데케미칼 주식회사 폴리올레핀의 제조방법 및 이로부터 제조된 폴리올레핀
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
JP6845005B2 (ja) 2016-12-27 2021-03-17 Eneos株式会社 粘着テープ
WO2018191000A1 (en) 2017-04-10 2018-10-18 Exxonmobil Chemicl Patents Inc. Methods for making polyolefin polymer compositions
WO2018208414A1 (en) 2017-05-10 2018-11-15 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for using the same
KR20190063794A (ko) 2017-11-30 2019-06-10 롯데케미칼 주식회사 응력 저항성이 향상된 폴리올레핀 조성물
US11591417B2 (en) 2017-12-13 2023-02-28 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization processes
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
EP3788082A1 (de) 2018-05-02 2021-03-10 ExxonMobil Chemical Patents Inc. Verfahren zur aufskalierung von einer pilotanlage zu einer grösseren produktionsanlage
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
EP3826833A1 (de) 2018-07-26 2021-06-02 ExxonMobil Chemical Patents Inc. Mehrlagige schaumstofffolien und verfahren zur herstellung davon
US20200087495A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
US20220025135A1 (en) 2018-11-13 2022-01-27 Exxonmobil Chemical Patents Inc. Polyethylene Films
WO2020102380A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
KR102474477B1 (ko) 2018-11-29 2022-12-05 롯데케미칼 주식회사 응력 저항성이 향상된 폴리올레핀 조성물
KR102116476B1 (ko) 2019-01-18 2020-05-28 대림산업 주식회사 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
MX2021006769A (es) 2019-02-20 2021-07-15 Fina Technology Composiciones de polimero con baja distorsion.
CN117417635A (zh) 2019-05-13 2024-01-19 旭化成株式会社 低孔隙的粒料以及成型体的制造方法
KR102203007B1 (ko) 2019-06-05 2021-01-14 대림산업 주식회사 다단계 연속 중합 방법을 이용한 멀티모달 폴리올레핀 제조방법
EP4050066A4 (de) 2019-10-24 2022-12-21 Asahi Kasei Kabushiki Kaisha Polyamid-zellulose-harzzusammensetzung
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
WO2022168928A1 (ja) 2021-02-03 2022-08-11 旭化成株式会社 樹脂組成物の製造方法
JP7374372B2 (ja) 2021-02-22 2023-11-06 旭化成株式会社 セルロースナノファイバーを含む組成物
WO2022232123A1 (en) 2021-04-26 2022-11-03 Fina Technology, Inc. Thin single-site catalyzed polymer sheets
EP4330294A1 (de) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Verfahren zum übergang zwischen verschiedenen polymerisationskatalysatoren in einem polymerisationsreaktor
EP4353782A1 (de) 2021-06-10 2024-04-17 Asahi Kasei Kabushiki Kaisha Harzzusammensetzung und verfahren zur herstellung davon

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3306919A (en) * 1958-01-15 1967-02-28 Union Carbide Corp Cyclopentadienyl titanium compounds
US3013002A (en) * 1960-04-05 1961-12-12 Hercules Powder Co Ltd Polymerization of ethylene with dicyclopentadienyl chromium-metal alkylcatalysts
US3135809A (en) * 1960-07-21 1964-06-02 Southern Res Inst Isomerization process
NL296404A (de) * 1962-08-08
GB1233599A (de) * 1966-04-04 1971-05-26
BE737574A (de) * 1968-09-05 1970-02-02
DE2043515A1 (de) * 1970-09-02 1972-04-20 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE2608933A1 (de) * 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
DE2608863A1 (de) * 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
JPS54134792A (en) * 1978-04-11 1979-10-19 Mitsui Petrochem Ind Ltd Polymerization or copolymerization of ethylene
JPS55151010A (en) * 1979-05-16 1980-11-25 Mitsui Petrochem Ind Ltd Polymerization or copolymerization olefin
IT1193358B (it) * 1980-01-18 1988-06-15 Montedison Spa Componenti di catalizzatori per la polimerizzazione delle alfa-olefine e catalizzatori da essi ottenuti
DE3007725A1 (de) * 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
US4310648A (en) * 1980-10-20 1982-01-12 The Dow Chemical Company Polymerization of olefins in the presence of a catalyst containing titanium and zirconium
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
MX167872B (es) * 1983-06-06 1993-04-20 Exxon Research Engineering Co Proceso y catalizador para producir poliolefinas dmezclas del reactor
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control

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ZA844156B (en) 1986-01-29
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NO842257L (no) 1984-12-07
EP0128045B1 (de) 1991-09-18
NO164906C (no) 1990-11-28
EP0128045A1 (de) 1984-12-12
NO164906B (no) 1990-08-20
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JPH0791328B2 (ja) 1995-10-04
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