DE3562887D1 - Titanium-aluminum-phosphorus-silicon-oxide molecular sieves - Google Patents

Titanium-aluminum-phosphorus-silicon-oxide molecular sieves

Info

Publication number
DE3562887D1
DE3562887D1 DE8585104383T DE3562887T DE3562887D1 DE 3562887 D1 DE3562887 D1 DE 3562887D1 DE 8585104383 T DE8585104383 T DE 8585104383T DE 3562887 T DE3562887 T DE 3562887T DE 3562887 D1 DE3562887 D1 DE 3562887D1
Authority
DE
Germany
Prior art keywords
phosphorus
titanium
silicon
aluminum
molecular sieves
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8585104383T
Other languages
English (en)
Inventor
Brent Mei Tak Lok
Bonita Kristoffersen Marcus
Edith Marie Flanigen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of DE3562887D1 publication Critical patent/DE3562887D1/de
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates (SAPO compounds)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08Silicoaluminophosphates (SAPO compounds), e.g. CoSAPO
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/12Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2226Catalytic processes not covered by C07C5/23 - C07C5/31 with inorganic acids; with salt or anhydrides of acids
    • C07C5/224Acids of phosphorus; Salts thereof; Phosphorus oxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/271Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with inorganic acids; with salts or anhydrides of acids
    • C07C5/2716Acids of phosphorus; Salts thereof; Phosphorus oxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/82Phosphates
    • C07C2529/84Aluminophosphates containing other elements, e.g. metals, boron
DE8585104383T 1984-04-13 1985-04-11 Titanium-aluminum-phosphorus-silicon-oxide molecular sieves Expired DE3562887D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/600,179 US4684617A (en) 1984-04-13 1984-04-13 Titanium-aluminum-phosphorus-silicon-oxide molecular sieves

Publications (1)

Publication Number Publication Date
DE3562887D1 true DE3562887D1 (en) 1988-06-30

Family

ID=24402611

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8585104383T Expired DE3562887D1 (en) 1984-04-13 1985-04-11 Titanium-aluminum-phosphorus-silicon-oxide molecular sieves

Country Status (5)

Country Link
US (1) US4684617A (de)
EP (1) EP0161488B1 (de)
JP (1) JPS60260420A (de)
CA (1) CA1248507A (de)
DE (1) DE3562887D1 (de)

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US5147525A (en) * 1983-12-19 1992-09-15 Mobil Oil Corporation Synthesis of crystalline metalloaluminophosphate composition
US4846956A (en) * 1984-04-13 1989-07-11 Uop Manganese-aluminum-phosphorus-silicon-oxide Molecular sieves
US4880520A (en) * 1984-04-13 1989-11-14 Uop Hydrocarbon conversion process using titanium-aluminum-phosphorus-silicon-oxide molecular sieves as catalyst
US4801309A (en) * 1984-04-13 1989-01-31 Uop Titanium-aluminum-phosphorus-silicon-oxide molecular sieves
US4707345A (en) * 1984-04-26 1987-11-17 Union Carbide Corporation Titanium-aluminum-silicon-oxide molecular sieve compositions and process for preparing the same
US4869805A (en) * 1984-04-26 1989-09-26 Uop Titanium-aluminum-silicon-oxide molecular sieve compositions
CA1281314C (en) * 1984-11-27 1991-03-12 Jule A. Rabo Catalytic cracking catalysts and cracking process using non-zeolitic molecular sieves
CA1275400C (en) * 1984-12-18 1990-10-23 Frank Peter Gortsema Dewaxing catalysts and processes employing non- zeolitic molecular sieves
US4913799A (en) * 1984-12-18 1990-04-03 Uop Hydrocracking catalysts and processes employing non-zeolitic molecular sieves
US4818739A (en) * 1984-12-18 1989-04-04 Uop Hydrocracking catalysts and processes employing non-zeolitic molecular sieves
US4741820A (en) * 1986-03-27 1988-05-03 Union Carbide Corporation Reforming/dehydrocyclization catalysts and processes
US4740650A (en) * 1986-06-16 1988-04-26 Union Carbide Corporation Xylene isomerization
US4751340A (en) * 1986-06-16 1988-06-14 Union Carbide Corporation Selective production of para-aromatics
US4752651A (en) * 1986-06-16 1988-06-21 Union Carbide Corporation Production of light olefins
US4734538A (en) * 1986-12-24 1988-03-29 Union Carbide Corporation Process for the production of dienes
US4803185A (en) * 1987-06-04 1989-02-07 Uop Octane boosting catalyst
US4861739A (en) * 1987-06-04 1989-08-29 Uop Microporous crystalline composite compositions
US4826804A (en) * 1987-06-04 1989-05-02 Uop Catalyst for oligomerization process
US4923594A (en) * 1987-06-04 1990-05-08 Uop Fluid catalytic cracking process
US4814316A (en) * 1987-06-04 1989-03-21 Uop Novel catalyst composition, and processes for making and using same
US4922050A (en) * 1987-12-28 1990-05-01 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over indium-containing crystalline microporous materials
US5147626A (en) * 1988-04-08 1992-09-15 Mobil Oil Corporation Synthesis of crystalline aluminophosphate composition
US5169614A (en) * 1988-04-08 1992-12-08 Mobil Oil Corporation Synthesis of crystalline silicoaluminophosphate composition
US5147627A (en) * 1988-04-08 1992-09-15 Mobil Oil Corporation Synthesis of crystalline silicoaluminophosphate composition
US5141728A (en) * 1988-04-08 1992-08-25 Mobil Oil Corporation Synthesis of crystalline aluminophosphate composition
US5141729A (en) * 1988-04-08 1992-08-25 Mobil Oil Corporation Synthesis of crystalline metalloaluminophosphate composition
US5015453A (en) * 1989-04-28 1991-05-14 W. R. Grace & Co.-Conn. Crystalline group IVA metal-containing molecular sieve compositions
US5091073A (en) * 1990-07-13 1992-02-25 Mobil Oil Corp. Crystalline molecular sieve compositions mcm-37
CN1037334C (zh) * 1992-12-19 1998-02-11 中国科学院大连化学物理研究所 一种以三乙胺为模板剂的合成硅磷铝分子筛及其制备
CN1038125C (zh) * 1993-06-18 1998-04-22 中国科学院大连化学物理研究所 以二乙胺为模板剂合成磷酸硅铝分子筛
US6528450B2 (en) 1996-08-29 2003-03-04 Phillips Petroleum Company Catalyst composition and processes therefor and therewith
TWI234556B (en) * 1997-07-23 2005-06-21 Mitsubishi Gas Chemical Co Catalysts for methanol conversion reactions
US6531639B1 (en) 2000-02-18 2003-03-11 Exxonmobil Chemical Patents, Inc. Catalytic production of olefins at high methanol partial pressures
US7227048B2 (en) 2001-12-31 2007-06-05 Exxonmobil Chemical Patents Inc. Converting oxygenates to olefins over a catalyst comprising acidic molecular sieve of controlled carbon atom to acid site ratio
CN1325448C (zh) 2002-08-14 2007-07-11 埃克森美孚化学专利公司 由含氧物制备烯烃的方法
US7122500B2 (en) 2003-09-22 2006-10-17 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
WO2007086824A2 (en) 2005-01-31 2007-08-02 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US9623364B1 (en) * 2008-12-15 2017-04-18 University Of Puerto Rico Removal of carbon dioxide from gas mixtures using ion-exchanged silicoaluminophosphates
DE102010055679A1 (de) 2010-12-22 2012-06-28 Süd-Chemie AG Titano-Silico-Alumo-Phosphat
DE102010055730A1 (de) 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Herstellung von Titano-(Silico)-Alumo-Phosphat
DE102010055728A1 (de) 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Umsetzung stickstoffhaltiger Verbindungen
DE102010055680A1 (de) 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Umsetzung stickstoffhaltiger Verbindungen
DE102010055678A1 (de) 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Herstellung von ungesättigten Kohlenwasserstoff-Verbindungen
DE102010055729A1 (de) 2010-12-22 2012-06-28 Süd-Chemie AG Trocknungsvorrichtung enthaltend ein Titano-Alumo-Phosphat
DE102010055677B4 (de) 2010-12-22 2018-09-20 Clariant Produkte (Deutschland) Gmbh Wärmetauscher-Modul mit Wärmemanagement mit einem Titano-Silico-Alumo-Phosphat als Adsorptionsmittel und dessen Verwendung
DE102012017887A1 (de) 2012-09-11 2014-03-13 Clariant International Ltd. Wärmemanagement mittels eines Titano-Alumo-Phosphats mit AFI-Struktur
EP3016738B1 (de) 2013-07-04 2019-04-24 Total Research & Technology Feluy Katalysatorzusammensetzungen mit kleinen molekularsiebkristallen auf einem porösen material
WO2015094698A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
US10118166B2 (en) * 2014-06-06 2018-11-06 Uop Llc Zeolitic materials with modified surface composition, crystal structure, crystal size, and/or porosity, methods for making the same, and methods for converting oxygenates to olefins via reactions catalyzed by the same
US9783463B2 (en) 2014-09-30 2017-10-10 Exxonmobil Chemical Patents Inc. Conversion of acetylene and methanol to aromatics
US10059638B2 (en) 2015-03-31 2018-08-28 Exxonmobil Chemical Patents Inc. Oxygenated hydrocarbon conversion zoned method

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FR1531775A (fr) * 1967-06-23 1968-07-05 Union Oil Co A titre de zéolithes, des métallo (groupe ivb)-silicates, et leur procédé de fabrication
GR66589B (de) * 1978-06-22 1981-03-30 Snam Progetti
US4310440A (en) * 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
DE3170192D1 (en) * 1980-12-11 1985-05-30 Ici Plc Zeolites
EP0055529B2 (de) * 1980-12-19 1990-09-19 Imperial Chemical Industries Plc Zeolithe
EP0055046B1 (de) * 1980-12-19 1984-11-07 Imperial Chemical Industries Plc Zeolithe
DE3261217D1 (en) * 1981-02-23 1984-12-20 Ici Plc Zeolites
DE3128988A1 (de) * 1981-07-22 1983-02-24 Liebau, Friedrich, Prof. Dr., 2301 Achterwehr Kristalline einschlussverbindungen von siliziumdioxid, verfahren zur herstellung und verwendung
DE3141283A1 (de) * 1981-10-17 1983-04-28 Hoechst Ag, 6230 Frankfurt "titanhaltige zeolithe und verfahren zu ihrer herstellung sowie ihre verwendung"
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4500651A (en) * 1983-03-31 1985-02-19 Union Carbide Corporation Titanium-containing molecular sieves
EP0132550A1 (de) * 1983-06-27 1985-02-13 Norton Company Zeolith und Verfahren zu seiner Herstellung

Also Published As

Publication number Publication date
EP0161488B1 (de) 1988-05-25
JPS60260420A (ja) 1985-12-23
EP0161488A1 (de) 1985-11-21
US4684617A (en) 1987-08-04
CA1248507A (en) 1989-01-10

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee