DE3886905T2 - Ziegler-Natta-Katalysator und Verfahren zur Herstellung derselben. - Google Patents

Ziegler-Natta-Katalysator und Verfahren zur Herstellung derselben.

Info

Publication number
DE3886905T2
DE3886905T2 DE88310876T DE3886905T DE3886905T2 DE 3886905 T2 DE3886905 T2 DE 3886905T2 DE 88310876 T DE88310876 T DE 88310876T DE 3886905 T DE3886905 T DE 3886905T DE 3886905 T2 DE3886905 T2 DE 3886905T2
Authority
DE
Germany
Prior art keywords
halide
ziegler
solid catalyst
mean diameter
making
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE88310876T
Other languages
English (en)
Other versions
DE3886905D1 (de
Inventor
Erick Bp Chimie S A Cent Daire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of DE3886905D1 publication Critical patent/DE3886905D1/de
Publication of DE3886905T2 publication Critical patent/DE3886905T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE88310876T 1987-11-30 1988-11-17 Ziegler-Natta-Katalysator und Verfahren zur Herstellung derselben. Expired - Fee Related DE3886905T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8716754A FR2623812B1 (fr) 1987-11-30 1987-11-30 Catalyseur de polymerisation d'olefines de type ziegler natta et procede de preparation a partir de dialcoxyde de magnesium

Publications (2)

Publication Number Publication Date
DE3886905D1 DE3886905D1 (de) 1994-02-17
DE3886905T2 true DE3886905T2 (de) 1994-05-05

Family

ID=9357408

Family Applications (1)

Application Number Title Priority Date Filing Date
DE88310876T Expired - Fee Related DE3886905T2 (de) 1987-11-30 1988-11-17 Ziegler-Natta-Katalysator und Verfahren zur Herstellung derselben.

Country Status (12)

Country Link
US (1) US5006499A (de)
EP (1) EP0319173B1 (de)
JP (1) JPH01201305A (de)
KR (1) KR890008178A (de)
CN (1) CN1016422B (de)
AT (1) ATE99703T1 (de)
AU (1) AU606483B2 (de)
CA (1) CA1325003C (de)
DE (1) DE3886905T2 (de)
ES (1) ES2061691T3 (de)
FR (1) FR2623812B1 (de)
MY (1) MY104929A (de)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4874737A (en) * 1988-09-06 1989-10-17 Shell Oil Company Silicate-modified magnesium alkoxide polymerization catalysts
US5104997A (en) * 1988-09-30 1992-04-14 Fmc Corporation Mass treatment of cellulosic materials
EP0398167A3 (de) * 1989-05-17 1991-10-16 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Ethylen(co-)polymeren
SG52620A1 (en) * 1990-09-06 1998-09-28 Hoechst Ag Process for the preparation of ethylene (CO) polymers
EP0908470B1 (de) * 1990-10-18 2002-11-20 Union Carbide Chemicals & Plastics Technology Corporation Olefinpolymerisationskatalysatorvorläufer
US5818647A (en) * 1993-12-21 1998-10-06 Olympus Optical Co., Ltd. Lens barrel
US6486274B1 (en) 1997-01-28 2002-11-26 Fina Technology, Inc. Hydrogen response Ziegler-Natta catalyst for narrowing MWD of polyolefin, method of making, method of using, and polyolefins made therewith
KR100524293B1 (ko) 1999-05-27 2005-10-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100546499B1 (ko) * 1999-05-27 2006-01-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
DE10003872A1 (de) 1999-11-26 2001-08-16 Basell Polyolefine Gmbh Verfahren zum Herstellen eines Poly-l-olefins in Gegenwart eines Ziegler Katalysators
KR100361224B1 (ko) * 1999-12-01 2002-11-29 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매의 제조방법
KR100387734B1 (ko) * 2000-06-17 2003-06-18 삼성종합화학주식회사 올레핀 중합용 촉매 및 중합방법
KR100389475B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100389477B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389476B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389962B1 (ko) * 2000-11-10 2003-07-02 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100421551B1 (ko) * 2000-12-16 2004-03-09 삼성아토피나주식회사 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법
ATE297441T1 (de) * 2000-12-22 2005-06-15 Samsung General Chemicals Co Polypropylenharzzusammensetzung mit verbesserter oberflächenhärte und kratzfestigkeit
US20040072936A1 (en) * 2000-12-22 2004-04-15 Sok-Won Kim Polyolefin resin composition
US7067576B2 (en) * 2000-12-22 2006-06-27 Samsung Atofina, Co., Ltd. Flame retardant polypropylene resin composition
US6872683B2 (en) * 2000-12-22 2005-03-29 Samsung Atofina Co., Ltd. Method for preparing chelated catalyst for olefin polymerization
KR100496776B1 (ko) * 2001-06-21 2005-06-22 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100530794B1 (ko) * 2001-06-21 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
EP1308465A1 (de) * 2001-11-06 2003-05-07 Fina Technology, Inc. Ziegler-Natta Katalysator mit verbesserter Wasserstoffempfindlichkeit zur Einschränkung der MWD eines Polyolefins, Verfahren zur seiner Herstellung, Olefinpolymerisationsverfahren unter Verwendung desselben und daraus hergestellte Polyolefine
KR100851032B1 (ko) * 2001-12-17 2008-08-12 피나 테크놀러지, 인코포레이티드 폴리올레핀의 분자량 분포를 좁히기 위한 향상된 수소반응지글러-나타 촉매, 이것의 제조방법, 사용방법 및이것으로 제조된 폴리올레핀
JP4443403B2 (ja) 2002-05-29 2010-03-31 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング チーグラー触媒の存在下でのポリ−１−オレフィンの製造方法
US6677266B1 (en) 2002-07-09 2004-01-13 Eastman Chemical Company Process for preparing a vanadium/titanium catalyst and use in olefin polymerization
EP1539836B1 (de) 2002-08-09 2006-06-21 Basell Polyolefine GmbH Modifizierter ziegler-katalysator, herstellungsverfahren dafür und verfahren zur herstellung von poly-1-olefinen in seiner gegenwart
DE102004037229A1 (de) 2004-07-29 2006-02-16 Basell Polyolefine Gmbh Verfahren zum Herstellen eines Poly-1-olefins in Gegenwart eines Ziegler Katalysators
US20060135720A1 (en) * 2004-12-17 2006-06-22 Fina Technology, Inc. Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith
US8003741B2 (en) * 2008-02-07 2011-08-23 Fina Technology, Inc. Ziegler-Natta catalyst
SA3686B1 (ar) 2009-10-16 2014-10-22 China Petroleum& Chemical Corp مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه
WO2011047967A1 (en) * 2009-10-22 2011-04-28 Basell Polyolefine Gmbh Catalyst components for the polymerization of olefins and catalysts therefrom obtained
US8592535B2 (en) * 2010-01-11 2013-11-26 Fina Technology, Inc. Ziegler-natta catalyst systems and polymers formed therefrom
CN105845195B (zh) * 2016-03-28 2017-08-11 中国科学院上海硅酸盐研究所 一种过渡金属氧化物/石墨烯复合薄膜及其制备方法
JP2023546624A (ja) 2020-10-26 2023-11-06 中国石油化工股▲ふん▼有限公司 オレフィン重合触媒を製造するための固体成分、その製造方法およびその利用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE758994A (fr) * 1969-11-17 1971-05-17 Hoechst Ag Procede de polymerisation d'alpha-olefines
DE2021831C3 (de) * 1970-05-05 1974-08-01 Farbwerke Hoechst Ag, Vormals Meister Lucius & Bruening, 6000 Frankfurt Verfahren zur Herstellung von Polymerisationskatalysatoren
JPS5618607A (en) * 1979-07-24 1981-02-21 Mitsubishi Petrochem Co Ltd Polymerization of ethylene
US4376062A (en) * 1979-11-28 1983-03-08 Union Carbide Corporation Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization
US4472521A (en) * 1982-12-20 1984-09-18 Stauffer Chemical Company Supported catalyst for polymerization of olefins
JPH062772B2 (ja) * 1984-02-28 1994-01-12 東燃株式会社 オレフイン重合用触媒成分の製造方法
DE3767762D1 (de) * 1986-05-21 1991-03-07 Mitsubishi Chem Ind Verfahren zur herstellung eines olefinpolymers.
US4698323A (en) * 1986-09-29 1987-10-06 Stauffer Chemical Company Transition metal catalyst component containing magnesium alkoxy alkoxides

Also Published As

Publication number Publication date
CN1016422B (zh) 1992-04-29
FR2623812B1 (fr) 1992-02-21
EP0319173A1 (de) 1989-06-07
FR2623812A1 (fr) 1989-06-02
EP0319173B1 (de) 1994-01-05
CN1033385A (zh) 1989-06-14
ATE99703T1 (de) 1994-01-15
MY104929A (en) 1994-07-30
AU2580088A (en) 1989-06-01
JPH01201305A (ja) 1989-08-14
KR890008178A (ko) 1989-07-10
ES2061691T3 (es) 1994-12-16
AU606483B2 (en) 1991-02-07
CA1325003C (en) 1993-12-07
US5006499A (en) 1991-04-09
DE3886905D1 (de) 1994-02-17

Similar Documents

Publication Publication Date Title
DE3886905D1 (de) Ziegler-Natta-Katalysator und Verfahren zur Herstellung derselben.
IT1161200B (it) Processo e apparecchio per la preparazione di particelle di ossidi metallici monodisperse, sferiche, non aggregate e di dimensione inferiore al micron
KR880009998A (ko) 미립자상 알루미노옥산, 그 제법 및 그 용도
DE69034205D1 (de) Verfahren zur Polymerisation von Olefinen
DE68916048T2 (de) Verfahren zur Herstellung von monodispersen Polymerteilchen mit erhöhter Teilchengrösse.
TW375621B (en) Process for obtaining polymers which are super-absorbent for water and aqueous fluids in the form of particle aggregates
NO963570D0 (no) Fremgangsmåte for fremstilling av kobberpyrition
ATE16015T1 (de) Verfahren zur herstellung von katalysatortraegern zur olefinpolymerisation und erhaltene traeger.
PL318099A1 (en) Very fine magnetic particles of metal oxides, methods of obtaining them and their applications
FR2480732B1 (fr) Procede et bruleur pour la production de fines particules d'oxydes de metaux et de metalloides
JPS56141559A (en) Reagent for immunological inspection
NO832264L (no) Polymeriseringskatalysator.
CA2029076A1 (en) Method for treating substrates
KR910003036A (ko) 소판형 기재
EP0071704A3 (en) Multiple-surface systems for fixing substrates having nucleophilic groups
DE69024168D1 (de) Verfahren und Vorrichtung zur Herstellung von Polymerisationskatalysatorträgern
WO1999031141A3 (de) Verfahren zur herstellung von regulären porösen perlcellulosen, die perlcellulosen und ihre verwendung
JPS57187322A (en) Production of particulate product
US3274120A (en) Catalyst composition having increased hydroxyl groups bound thereto and method for producing same
FR2290954A1 (fr) Procede pour agglomerer de fines particules et reduire la distribution des dimensions de particules d'un catalyseur, et composition obtenue
AU581530B2 (en) Process for the preparation of granules and granules obtained by this process
HU9601112D0 (en) Latex dispensions containing a hydroxyle and a carboxyle function group, and use of them for making coatings
TH6471EX (th) ตัวเร่งปฏิกิริยาซิกเลอร์ - นัดตะและกระบวนการเตรียมตัวเร่งปฏิกิริยา
EP0270919A3 (en) Process for the manufacture of granular polymers and copolymers of ethylene by means of a catalyst system based on chromium trioxide
EP0238345A3 (de) Katalysatoren für alpha-Olefin-Polymerisation

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee