DE4129986A1 - Oil in water emulsion for cleaning skin and hair - contains anionic surfactant, non silicone oil for refatting, polymer to impart specific flow properties and mono:valent cation salt - Google Patents

Abstract

Oil-in-water emulsion, free of nonionic and cationic surfactants, for cleaning hair and skin comprises (by wt.): (a) 5-30% at least one anionic surfactant (I), opt. together with an amphoteric surfactant (II) at les than 50 wt.% total surfactant; the surfactant concn. in the aq. emulsion phase being not over 45 mmole per 100g; (b) 2-10% at least one water-insoluble silicone-free oil (III), opt. together with a water-insoluble anion-cation complex (IV); (c) 0.3-5% at least one nonionic, amphoteric or anionic polymer (V), which imparts a flow limit of at least 3 Pa at 0-50 deg.C and (d) at least one low mol. wt. water-soluble inorganic salt (V) of a monovalent cation at a concn. of 1-35 mmole per 100 g of aq. phase. USE/ADVANTAGE - The compsns. have very good emulsion stability and foaming and cleaning properties, and component (b) ensures refatting of the skin without the difficulties associated with use of silicone oils. The compsn. is well retained; does not impart a fatty or dry feel, and leaves the hair shin

Description

The invention relates to a nourishing and strong foaming of the hair and skin cleanser in the form of a stable Oil-in-water emulsion.

Hair and skin cleansers usually contain aqueous solutions of anionic surfactants, for example of Alkyl ether sulfates, alkyl sulfates, alkyl sulfonates, Al kylestersulfonaten, alkyl ether sulfonates and alkyl sulfone Acid ester salts of polybasic acids. Aqueous anionic surfactant solutions when rubbing the consumer for Hair and skin cleansers desired strong foam development, a strong cleansing effect and a good one Eye, skin and mucous membrane compatibility with good biodegradability, but they also possess a number of disadvantages.

Thus anionic surfactants cause a strong degreasing of skin and hair. The washed with pure anionic surfactant solutions Hair is brittle and lackluster, has a rough grip and a bad combing on. The treatment of Skin with anionic surfactant solutions leaves a lot of tension feel and can cause the skin to dry out.

If the concentration of anionic surfactant is reduced to one less heavily degreasing amount to the previously described NEN disadvantages, so the distribution of Mit tels hampered by the reduced foaming and felt by the user as unpleasant and inadequate.  

The addition of nourishing ingredients, as they are to Example in the literature by S. Jellinek, Cosmetology, Hüthig Verlag (1976), pages 348-350 described who to hair and skin cleansers based on Anionic surfactant solutions leads to a strong reduction foam development and leaves behind the application a greasy feel on the skin.

Water-insoluble oils, for example paraffin oils, fat Alcohols, fatty acids, or triglycerides are used as a care gend acting ingredients, so-called Rückfettungsmit tel, for example by H. Schrader, Hüthig Verlag (1989), page 700, recommended. Anionic surfactants assets only a limited amount of these water-insoluble oils to solubilize clearly. After exceeding the maximum amount of oil causes an undesirable separation between oil and water phase. The water-insoluble oils are usually in an amount of 0.5 to 2 Ge percent and must be replaced by the addition non-ionic surfactants in hair and skin cleansing be solubilized, otherwise no homogeneous Products are obtained. Such nonionic surfactants However, containing hair and skin cleansers have an unsatisfactory foam development on and left behind feel greasy on the skin after application.

By emulsification, an emulsion can be obtained, wel However, they re-open within a few minutes separates. From DE-OS 24 04 607 it is known by the Addition of thickening agents and the Er caused Increasing the viscosity of this process of phase separation in water-insoluble oils containing skin cleansers to delay something. As the phase separation of the emulsion  However, stability can not be stopped the means described in DE-OS 24 04 607 unbefrie apologetically.

In hair cleanser, non-volatile silicone Oils used as nourishing ingredients. It showed, however, that after repeated use the These silicones on the hair are a rechargeable battery Lation of silicone oils takes place. By the strong up Drawing and the water repellent character of the Silicone oils are such hair pretreated to further hair Treatment methods no longer or only diminished accessible. This is reflected, for example, in a vermin derten Wellstabilität after the permanent wave treatment or in a missing color depth after dyeing processes with Silicone oils treated hair. In addition, the Ver Use of silicone oils from an ecological point of view as questionable, since they are not biodegraded can.

In EP-OS 04 07 041 storage-stable, anionic surfactant containing hair cleanser containing a water content have insoluble oils described. This hair cleansing However, agents contain as essential to the invention Component soluble in the aqueous emulsion phase, Free cationic surfactants whose bad eye and eyes Mucosal compatibility is known.

It was therefore the task of a strong in the application foaming hair and skin cleanser on the base of anionic surfactants available in Form of one of non-ionic and cationic surfactants free stable emulsion is present and skin and hair on reason of a content of moisturizing water-insoluble Gently cleanses oils without the previously described parts of the silicone oil-containing detergents.  

It has now been found that a hair and skin cleansing medium in the form of one of non-ionic and cationic Surfactants free oil-in-water emulsion, characterized records that it is a combination of

• A) 5 to 30 weight percent of at least one anioni surfactant or a mixture of at least an anionic surfactant with at least one ampho surfactant, wherein the proportion of the amphoteric surfactant based on component (A) less than 50 Ge weight percent, and the total content of these ten side 45 mmol in 100 g of the aqueous emulsion phase does not exceed
• B) 2 to 10% by weight of at least one water soluble silicone-free oil or a mixture of at least one water-insoluble silicone-free oil and a water-insoluble anion-cation complex,
• C) 0.3 to 5 percent by weight of at least one not ionic, amphoteric or anionic polymer, the the agent at a temperature of 0 to 50 degrees Celsius a yield point of at least 3 Pascal ver lends, and
• D) at least one low-molecular-weight, water-soluble organic salt of a monovalent cation, the concentration of the monovalent cation of this salt being from 1 to 35 mmol in 100 g of the aqueous emulsion phase,

contains, the task given to a great extent does justice.  

The water-insoluble oils containing inventive Hair and skin cleanser is in the form of a sta bilen oil-in-water emulsion, due to its rheological properties a good hold on skin and Hair on, is characterized by an excellent foam can disperse, spreads well and cleanses the skin and hair thoroughly and gently. The invention Means has a very good nourishing effect on the skin and Hair. The remedy causes neither after its application a greasy skin feeling still a feeling of tension Skin, it still dries out the skin. The one with him hair treated according to the invention treated show a ge Cared for appearance, have a pleasant grip as well a beautiful shine and are further hair treatment procedure easily accessible.

Of the anionic surfactants suitable for the hair and skin cleansing compositions according to the invention, mention may be made, for example, of the following; the alkali, alkaline earth, ammonium, alkylammonium or alkanolammonium salts of the C ₈ - to C ₁₈ -alkyl ether sulfates, the C ₁₀ - to C ₂₀ -alkanesulfonates, the C ₁₀ - to C ₁₈ -olefinsulfonates, the C ₈ - to C ₁₈ -alkyl sulfates, in particular the C ₁₂ - to C ₁₄ -alkyl sulfates, the straight-chain alkylbenzenesulfonates, with 1 to 8 ethylene oxide ethoxylated C ₁₀ - to C ₁₈ -Ethercarbonsäuren, C _{8 to} C ₁₈ alkylglyceryl ether sulfonates, the C ₈ to C ₁₈ fatty acid amide ether sulfates or the C _{8 to} C ₁₈ alkyl sulfosuccinates and their derivatives ethoxylated with up to 8 ethylene oxide units.

The anionic surfactant of component (A) of the invention proper hair and skin cleansing agent is preferred Salt of an alkyl ether sulfate of the general formula (I)

RO (C _n H _2n O) _x SO₃M Y (I)

wherein R is an alkyl radical having 8 to 18, but preferably 12 to 14, carbon atoms, M is an alkali, Alkaline earth, ammonium, alkylammonium or alkanolammo nium cation, n is an integer from 2 to 4, be but preferably 2, and x is an integer of 1 to 10 represents.

In the component (A) of the hair and skin cleansing agent according to the invention, in addition to the anionic surfactants, it is possible to use all ampho teren surfactants customary for such compositions. Particularly preferred amphoteric surfactants are the following: C ₁₀ - to C ₁₈ N-alkyl betaines, C ₁₀ - to C ₁₈ N-Alkylpolybetaine, C ₁₀ - to C ₁₈ N- alkylaminobetaines, C ₁₀ - to C ₁₈ N Alkylsulfobetaine, C ₁₀ to C ₁₈ acylamphoglycinates, C ₁₀ to C ₁₈ acylpolyampho glycinate and C ₁₀ to C ₁₈ acylamphocarboxyglycinates.

The agent according to the invention preferably contains 7 to 20 Weight percent of component (A).

The hair and skin cleaning agent according to the invention free of water-soluble cationic surfactants.

As a water-insoluble, silicone-free oil of the component (B) may be natural in the composition of the invention or synthetic oils or a mixture of natural and synthetic oils.

Of the water-insoluble, silicone-free oils suitable for use in the hair and skin cleanser according to the invention, mention may be made, for example, of the following: paraffin oils; isoparaffin; Vaseline; straight-chain fatty acid esters, such as myristyl myristinate, lauric acid hexyl ester, isopropyl myristate or oleyl oleate; branched fatty acid esters such as cetyl or stearyl isononanoate, isooctyl fatty acid esters such as isooctyl stearate; squalane; Triglycerides of C ₈ to C ₂₄ fatty acids, preferably of saturated C ₈ to C ₂₄ fatty acids; C ₈ - to C ₂₄ -fatty alcohols and natural oils such as jojoba oil, sesame oil, man delöl, terpene oils such as pine needle oil, palm kernel oil, tree seed oil, coconut oil and shea butter.

The hair and skin cleansing agent according to the invention ent preferably holds 2.5 to 5 weight percent of the compo term (B).

Component (B) of the hair and skin of the invention Furthermore, cleaning agent may also consist of a mixture of at least one water-insoluble anion-cation complex, which is due to the reaction of equimolar amounts of anionic surfactants and sparingly water-soluble cationi surfactants is formed, and at least one water-insoluble, silicone-free oil.

In particular, the anion-cation complex is prepared from sparingly water-soluble C ₈ - to C ₁₈ -trialkylmethylammonium chlorides or bromides as cationic complexing agents. As cationic complexing agents, however, non-water-soluble cationic polymers can also be used.

Suitable anion-cation complexes are in the oil phase too at least 0.01% by weight soluble, such as example trioctylmethylammonium cetyl sulfate or with three Ethylene oxide units ethoxylated tricetylmethyl ammonium lauryl ether sulfate.  

Component (B) of the agent according to the invention consists preferably from paraffin oil or jojoba oil.

As component (C) are non-ionic, amphoteric or anionic polymers which are the emulsionförmi Means according to the invention a plastic or pseudo give plastic behavior. The rheological flow Behavior of the agent according to the invention is characterized by a Yield point of at least 3 pascals in a linear Shear gradient characterized (Haake rotational viscometer RV 12, measuring system PKV - 0.5, 30 degrees Celsius).

The height of the flow limit (in Pascal) of the composition according to the invention is dependent on the polymer contained and should preferably not exceed a value of 150 Pascal. The viscosity of the compositions according to the invention measurable after exceeding the yield point is between 2 and 20,000 mPa · s, but preferably 1 to 5 Pa · s, with a maximum shear rate of 100 s ^-1 , measured at a temperature of 30 degrees Celsius.

Of those for use in the invention Hair and skin cleansers suitable natural, synthetic or semisynthetic non-ionic, am photeren or anionic polymers of component (C) For example, the following may be mentioned: hetero- and Homopolysaccharides, for example xanthan gums and β-1,3-D-glucans; Natural products of the galactomannan type, such as for example locust bean gum and the endosperm powder from the seeds of prosopis juliflora; acrylic acid and methacrylic acid polymers; Acrylic and methacrylic acid copolymers, for example polyethylene-acrylic acid copolymers; Chitosan, preferably with a deacetylie degree of 30 to 60 percent; Chitin and Chitosande such as N-carboxymethyl, hydroxypropyl or glycidyl chitosans, or mixtures thereof.  

For use in the composition according to the invention come especially those by the fungus Schizophyllum commune ATCC 38 548, Sclerotium glucanicum or Sclero tium rolfsii produced β-1,3-D-glucans which by U. Rau et al. in Biopress Engineering 5 (1990), Sci 89 to 93.

For use in the hair and hair of the invention Skin cleansing suitable polysaccharides are included For example, under the name Exelflo® of the German Shell Chemie distributed polysaccharide and the under the name Carelflo A® of the German Shell Chemie distributed succinoglycan polysaccharide and the under the name Alphaflo® from the company Internati onal Bio-Synthetics distributed Succinoglycanpoly saccharide.

Also for use as component (C) in the hair and skin cleanser of the invention are suitable are the xanthan gums made by the company International Bio-synthetics under the name Maxaflo®, from the German Shell Chemie GmbH under the name Careflo M® and Kelco under the names Keltrol®, Kelzan® and Kelgum®. Suitable acrylic acid polymers are from the company Röhm and Haas under the name Acrysol ICS-1® and from the Company B.F. Goodrich under the names Carbopol 1342® and Permulen TR-1®. As component (C) suitable polyethylene-acrylic acid copolymers for example, under the name Aclyn 276A® and Aclyn 285A® sold by Allied Signal Inc. The aforesaid endosperul powder from the seeds of prosopis juliflora is sold under the name Diagum 1.1 sold by the company Diamalt AG.  

Among those for the component (C) of the invention Hair and skin cleansing agent suitable polymers the xanthan gums are particularly preferred.

As component (D) contains the agent according to the invention preferably sodium chloride, potassium chloride, ammonium chloride, Sodium sulfate, sodium phosphate or their mixture.

The component (D) is to be used in an amount such that the concentration of the monovalent cation of the component te (D) in the hair and Hautreini invention preferably 10 to 25 mmol in 100 g of the aqueous emulsion phase.

Of course, in the hair and body cleansing agents, for such agents usual cosmetic additives are contained.

As suitable cosmetic additives example wise preservatives, such as salicylic acid or mandelic acid; Anti-dandruff agents, such as play zinc pyridinethione, selenium sulfide or 1- (4-chlorophe Noxy) 1 (1-imidazoyl) -3,3-dimethyl-2-butanone; cosmetic Dyes such as fluorescein sodium salt; and pearlescing agents, such as a mixture fatty acid monoalkylolamide and ethylene glycol distearate; Thickeners, such as fatty acid polyglycol esters, Fatty acid diethanolamide or hydroxyethylcellulose, fer ner complexing agent; Buffer substances; Hydrotropica, at For example, cumene sulfonate or xylene sulfonate; detoxifier, such as collagen hydrolysates; Lichtschutzmit tel; bactericidal and fungicidal substances, such as formalin; Dyeing dyes, such as FD & C Blue No. 2 (C. I. 73 015); Antioxidants, such as ascorbic acid; Humectants and foam stabilizers called.  

The suitable cosmetic additives can be used in such agents conventional amounts in the invention Hair and skin cleansers are used at For example, preservatives in an amount of 0.01 to 0.7 weight percent pearlescing agent in an amount from 1.0 to 10 weight percent, humectant and Foam stabilizers in an amount of 0.01 to 0.8 Weight.

The agent according to the invention has a pH of 4 to 7.

The hair and skin cleansing agent according to the invention especially as a wash and shower bath emulsion, as a bath milk, as a nourishing hair shampoo or as a skin cleansing emulsion.

The hair and skin cleaning agent according to the invention is produced in the first in a vacuum, the mixture of all oil-soluble ingredients at 20 to 80 degrees Celsius in the heated to the same temperature and stirred aq solution of the surfactants and all other water-soluble solvents components in half of the total amount of water is sucked axially under tangential shear. As soon as stirring an air-free emulsion with a Droplet diameter of 0.1 to 3 microns formed has, this emulsion is in a gel by 1 to 2 hours swelling of a 0.1 to 10 percent solution of the polymer (C) in the second half of the total water quantity was prepared, homogeneously stirred.

For the preparation of the at least one anion-cation complex containing inventive agent are first equimolar amounts of the aqueous solution or dispersion  present anionic surfactant with the aqueous as Dis Persion present, poorly water-soluble cationic Surfactant mixed with stirring. After the addition of all further oil-soluble constituents becomes the water phase separated and the oil phase optionally with distillate washed water to any soluble salt residues remove. The mixture prepared in this way oil-soluble ingredients with the anion-cation complex is in the vacuum at 20 to 80 degrees Celsius in the on the same temperature heated and stirred aqueous solution the surfactants and all other water-soluble stock Divide axially in half of the total amount of water sucked tangential shear. Once under Stir an air-free emulsion with a droplet diameter of 0.1 to 3 microns is formed This emulsion is made into a gel by 1 to 2 hours Swelling of a 0.1 to 10 percent solution of the polymer (C) in the second half of the total amount of water was prepared, homogeneously stirred.

The examples below are intended to cover the subject matter of Explain the invention in more detail.

Examples Example 1 shampoo

12.040 g of ethoxylated sodium lauryl diglycol ether sulfate with 1 to 4 ethylene oxide units
0.010 g orthophosphoric acid
0.050 g FD & C Blue No. 2 (CI 73 015)
0.200 g of formalin, 35 percent aqueous solution
0.645 g of sodium chloride
0.430 g sodium sulfate
0.600 g of xanthan gum
1.300 g paraffin oil
1,000 g of isopropyl palmitate
0.500 g of squalane
0.200 g of perfume oil
83.025 g

water
100,000 g

The above milky-cloudy emulsion hair detergent has a flow limit of 6 to 10 Pa at 30 Degrees Celsius on. At a dilution of 1: 10 with Water shows the shampoo in the Ross Miles foam test at 37.8 degrees Celsius a foam height of 177 mm. A Containing 12.04 weight percent lauryl ether sulfate aqueous solution shows at the same dilution one Foam height of 180 mm.

When washing hair with the above hair washing medium creates a strong, fine-pored foam that Rinse well. The hair shows a good wet and dry combing and leave by their beautiful shine a well-kept impression.

Example 2 Baby shampoo 9,000 g a mixture of sodium and magnesium salts of sulfuric monoesters of oxyethylated myristyl, lauryl and oleyl alcohols 0.010 g Formalin, 35% aqueous solution 0.030 g D & Yellow No. 10 (C.I. 47 005) 0.015 g sodium hydroxide 0.900 g sodium chloride 0.600 g sodium sulphate 1,000 g of a microbiologically produced succinoglycan polysaccharide (Alphaflo® from International Bio-Synthetics) 1,600 g jojoba oil 0.900 g sesame oil 0.200 g perfume oil 0.200 g Trioctylmethylammonium-cetyl 0.100 g alpha tocopherol (vitamin E)  85.445 g water 100,000 g

The above baby shampoo is in the form of a yellow brown emulsion with a yield strength of 28 to 35 Pa at 30 degrees Celsius. After dilution of 1:10 shows the above baby shampoo in the Ross Miles Procedure at 37.8 degrees Celsius a foam height of 175 mm. The above baby shampoo cleanses the senses gentle baby skin and acts to dry out the Skin without leaving behind a greasy feeling on the skin sen.

example 3 bath preparation

11,200 g of sodium lauryl ether sulfate ethoxylated with one to four ethylene oxide units,
0.100 g of formalin, 35 percent aqueous solution
0.040 g of Acid Yellow No. 3 (CI 47 005)
0.030 g FD & C Blue No. 1 (CI 42 090)
0.030 g of sodium citrate
5,000 g of acrylic acid copolymer (Permulen TR-1® from BF Goodrich)
0.616 g sodium chloride
0.160 g sodium sulfate
1,500 g jojoba oil
3,000 g pine needle oil
0.500 g with 3 ethylene oxide units ethoxylated tricetylmethylammonium lauryl ether sulfate
77.824 g

water
100,000 g

The above bath preparation has a yield point of 10 to 20 Pa at 30 degrees Celsius. In a dil 1: 10 water was in the Ross-Miles foam test at 37.8 degrees Celsius a foam height of 193 mm be Right. After bathing with the above bathing preparation the skin feels refreshed, soft and well-groomed.

Example 4 Hand washing emulsion 7.50 g secondary C₁₄ to C₁₇ alkyl sulfonate 3.00 g disodium coconut fatty acid isopropylamidoglycol ether sulfosuccinate ethoxylated with 4 ethylene oxide units 3.00 g cocoamidopropyl 0.50 g sodium sulphate 0.58 g sodium chloride 0.20 g citric acid 0.10 g FD & C Red No. 4 (C.I. 14 700) 1.50 g Copolymer of acrylic acid and an alkyl methacrylate crosslinked with an allyl ether of pentaerythritol or sucrose (Carbopol 1342® from B.F. Goodrich) 3.00 g almond oil 2.50 g isopropyl 0.50 g vaseline 0.20 g perfume oil  77.42 g water 100,000 g

The above hand wash lotion showed a yield point from 35 to 50 Pa at 30 degrees Celsius. In a dil 1: 10 water was in the Ross-Miles foam test at 37.8 degrees Celsius a foam height of 110 mm be Right. The foam formed is particularly compact and  pored. Despite excellent cleaning power compared heavy oily dirt with hand wash lotion cleansed hands supple and well-groomed.

All yield strengths were determined using a Haake RV 12 rotational viscometer, PKV-0.5 measuring system at 30 degrees Celsius with a linearly increasing shear rate of 0 to 100 s ^-1 .

Comparative Examples 5-22

Table 1 shows the dependence of the emulsion stabilizer the hair and skin cleansing according to the invention tel of the content of low molecular weight inorganic salt (Component (D)) and of the surfactant content (component (A)) shown.

In Tables 1 and 2, the stability of the emulsion is evaluated according to the following scale,
- = within one day separation of the emulsion phases,
- = separation of the emulsion phases within 3 days,
+ = more than 3 days stable emulsion,
++ = stable emulsion over 3 weeks.

Table 1

Table 1 (continued)

Table 1 (continued)

Table 1 (continued)

Table 1 (continued)

Table 1 (continued)

Comparative Examples 5 to 22 can be seen that the hair and skin cleansers according to the invention according to Examples 5 to 16 at a content of Surfactants of component (A) of less than 45 mmol and a Content of 1 to 35 mmol on the cation of component (D) in 100 g of the aqueous emulsion phase in contrast to the non-inventive examples 17 to 22 in the form a stable emulsion.

Comparative Examples 23-48

In Table 2, the emulsion stability invention containing hair and skin cleanser on various suitable surfactants and unterschiedli Chem salinity of the emulsion stability due to a too high surfactant content not inventive emulsions compared.

The evaluation of emulsion stability in the table he follows after that for the comparative examples 51-22 give rating scale.  

Table 2

Table 2 (continued)

Table 2 (continued)

Table 2 (continued)

Table 2 (continued)

Table 2 (continued)

Table 2 (continued)

Table 2 (continued)

The comparative experiments 23-48 it can be seen that the hair and skin cleanser according to the invention, unab depending on which of the suitable surfactants is, with a content of at most 45 mmol of surfactants of Component (A) give a stable emulsion while the non-inventive compositions 25 to 28, 33 to 35, 39 to 42 and 45 to 48 give unstable emulsions.

All percentages stated in the application represent weight percent.

Claims (13)

1. Hair and skin cleansing compositions in the form of a non-ionic and cationic surfactant-free oil-in-water emulsion, characterized in that it is a combination of

• A) 5 to 30 weight percent of at least one anionic surfactant or a mixture of at least one anionic surfactant with at least one amphoteric surfactant, wherein the proportion of the amphoteric surfactant based on the component (A) is less than 50 weight percent, and the total content of these surfactants Does not exceed 45 mmol in 100 g of the aqueous emulsion phase,
• B) 2 to 10 percent by weight of at least one water-insoluble silicone-free oil or a mixture of at least one water-insoluble silicone-free oil and a water-insoluble anion-cation complex,
• C) 0.3 to 5 weight percent of at least one nonionic, amphoteric or anionic polymer which imparts to the composition a yield strength of at least 3 Pascal at a temperature of 0 to 50 degrees Celsius, and
• D) at least one low molecular weight water-soluble inorganic salt of a monovalent cation, the concentration of the monovalent cation of this salt being 1 to 35 mmol in 100 g of the aqueous emulsion phase,

contains.   2. Composition according to claim 1, characterized in that the anionic surfactant of component (A) is selected from the alkali, alkaline earth, ammonium, alkyl ammonium or alkanolammonium salts of C ₈ - to C ₁₈ - alkyl ether sulfates, C ₁₀ - to C ₂₀ -alkanesulfonates, the C ₁₀ - to C ₁₈ -Olefinsulfonate, the C ₈ - to C ₁₈ -alkyl sulfates, the straight-chain alkylbenzenesulfonates, with 1 to 8 ethylene oxide ethoxylated C ₁₀ - to C ₁₈ -Ethercarbonsäuren, the C ₈ - C ₁₈ fatty acid amide or C ₈ - to C ₁₈ alkyl sulfosuccinates and their ethoxylated with up to 8 ethylene oxide derivatives. 3. Composition according to one of claims 1 or 2, characterized in that the anionic surfactant te the components (A) a salt of a Alkylethersulfats the general formula (I) RO (C _n H _2n O) _x SO₃M (I) wherein R is an alkyl radical having 8 to 18 Kohlenstoffato men, M is an alkali, alkaline earth, ammonium, alkylammonium or alkanolammonium cation, n is an integer from 2 to 4 and x represents an integer from 1 to 10. 4. Composition according to one of claims 1 to 3, characterized in that the amphoteric surfactant of component (A) is selected from: the C ₁₀ - to C ₁₈ -N-Alkylbe tainene, the C ₁₀ - to C ₁₈ -N Alkyl polybetaines, C ₁₀ to C ₁₈ N-alkylaminobetaines, C ₁₀ to C ₁₈ N-alkylsulfobetaines, C ₁₀ to C ₁₈ acylamphoglycinates, C ₁₀ to C ₁₈ acylpolyamphoglycinates and C ₁₀ to C ₁₈ acylamphocarboxyglycinates. 5. Composition according to one of claims 1 to 4, characterized ge indicates that it is 7 to 20 percent by weight of Component (A) contains. 6. Composition according to one of claims 1 to 5, characterized in that the water-insoluble, silicone-free oil of component (B) is selected from paraffin oils, isoparaffin oils, Vaseline, straight-chain fatty acid esters, branched fatty acid esters, squalane, triglycerides of C ₈ - to C ₂₄ -fatty acids, C ₈ - to C ₂₄ -fatty alcohols and natural oils. 7. Composition according to one of claims 1 to 6, characterized ge indicates that it is 2.5 to 5 weight percent of Component (B) contains. 8. Composition according to one of claims 1 to 7, characterized ge indicates that component (B) consists of jojoba oil or paraffin oil. 9. Composition according to one of claims 1 to 8, characterized ge indicates that the polymer of component (C) consists of is chosen from hetero- and homopolysaccarids, Na galactomannan-type, acrylic acid and Methacrylic acid polymers, acrylic acid and methacyrl acid copolymers, chitosan, as well as chitosan and chi tine derivatives or mixtures thereof. 10. Composition according to one of claims 1 to 9, characterized ge indicates that component (C) is a xanthan gum mi is.   11. Composition according to one of claims 1 to 10, characterized characterized in that the monovalent cation of the compo component (D) in an amount of 10 to 25 mmol in 100 g the aqueous emulsion phase is included. 12. Composition according to one of claims 1 to 11, characterized characterized in that it as component (D) sodium chloride, potassium chloride, ammonium chloride, sodium sulfate, sodium phosphate or their mixture.