DE4403686A1 - Aq. fabric conditioner dispersions - Google Patents
Aq. fabric conditioner dispersionsInfo
- Publication number
- DE4403686A1 DE4403686A1 DE4403686A DE4403686A DE4403686A1 DE 4403686 A1 DE4403686 A1 DE 4403686A1 DE 4403686 A DE4403686 A DE 4403686A DE 4403686 A DE4403686 A DE 4403686A DE 4403686 A1 DE4403686 A1 DE 4403686A1
- Authority
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- Prior art keywords
- atoms
- group
- formula
- alkyl
- dispersions
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006185 dispersion Substances 0.000 title claims abstract description 21
- 239000002979 fabric softener Substances 0.000 title claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 16
- 125000002252 acyl group Chemical group 0.000 claims abstract description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 8
- 150000004820 halides Chemical class 0.000 claims abstract description 5
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 125000002091 cationic group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 239000004753 textile Substances 0.000 claims description 8
- 239000004665 cationic fabric softener Substances 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 101100134927 Gallus gallus COR8 gene Proteins 0.000 abstract 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 8
- 239000000654 additive Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000013065 commercial product Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 125000003892 C18 acyl group Chemical group 0.000 description 2
- -1 aliphatic diols Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002190 fatty acyls Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/08—Sulfation or sulfonation products of fats, oils, waxes, or higher fatty acids or esters thereof with monovalent alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Textile Engineering (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Die Erfindung betrifft die Herstellung von wäßrigen Textilweichma cher-Dispersionen auf Basis kationischer Textilweichmacher vom Typ der quartären Ammoniumverbindungen mit wenigstens zwei langen Al kyl-, Alkenyl- oder Acylgruppen die aufgrund einer speziell ausge wählten Kombination quartärer Ammoniumverbindungen eine erhöhte Viskosität und ein besonders günstiges Lagerverhalten aufweisen.The invention relates to the production of aqueous textile soft material cher dispersions based on cationic textile softeners of the type the quaternary ammonium compounds with at least two long Al kyl, alkenyl or acyl groups which have a specially formed selected combination of quaternary ammonium compounds an increased Have viscosity and a particularly favorable storage behavior.
Die in Wäschweichspülmitteln gebräuchlichen Textilweichmacher vom Typ der quartären Ammoniumverbindungen mit wenigstens zwei langket tigen Alkyl- oder Acylgruppen sind in Wasser wenig löslich und lie gen daher auch im Bereich niedriger Konzentrationen von weniger als z. B. 10 Gew.-% in Wasser als Dispersion vor. Diese Dispersionen ha ben die Eigenschaft, daß sie zwar bei höheren Konzentrationen von mehr als 15 Gew.-% in Wasser sehr hochviskos und wenig fließfähig sind, im Bereich niedrigerer Konzentrationen von z. B. unter 10 Gew.-%, also in dem für Haushalts-Wäscheweichspülmittel üblichen Konzentrationsbereich aber sind diese Dispersionen sehr dünnflüs sig. Die niedrige Viskosität dieser Dispersionen ist von Nachteil für die Lagerstabilität und erschwert auch die Handhabung und Do sierung der Produkte.The fabric softeners commonly used in fabric softeners from Type of quaternary ammonium compounds with at least two long chains term alkyl or acyl groups are sparingly soluble in water and lie therefore also in the range of low concentrations of less than e.g. B. 10 wt .-% in water as a dispersion. These dispersions ha have the property that they are at higher concentrations of more than 15% by weight in water very highly viscous and not very flowable are, in the range of lower concentrations of z. B. under 10 % By weight, that is to say in that customary for household fabric softening detergents Concentration range, however, these dispersions are very thin sig. The low viscosity of these dispersions is disadvantageous for storage stability and also complicates handling and do products.
Es sind zwar schon verschiedene Möglichkeiten zur Verdickung solcher Dispersionen vorgeschlagen worden, z. B. durch Zusatz wasserlöslicher Polymeren. Solche Produkte haben jedoch den Nachteil, daß sie die gewebeweichmachende Wirkung beeinträchtigen, daß die Produkte oft nicht ausreichend biologisch abbaubar sind, und daß die Viskosität sich im Laufe längerer Lagerzeiten oft stark verändert.There are different ways to thicken such Dispersions have been proposed, e.g. B. by adding water-soluble Polymers. However, such products have the disadvantage that they Fabric softening effects often affect the products are not sufficiently biodegradable and that the viscosity often changes significantly over the course of longer storage times.
Insbesondere die gut biologisch abbaubaren kationischen Textilweichmacher vom Typ der quartären Ammoniumverbindungen mit zwei Fettacyl oxyalkylgruppen lassen sich ohne Hilfsmittel nur zu sehr dünnflüssi gen Dispersionen verarbeiten. Es bestand daher die Aufgabe, wäßrige Textilweichmacher-Dispersionen zu entwickeln, die gut biologisch abbaubar sind, eine hohe Weichspülleistung aufweisen und deren wäß rige Dispersion in niedrigen Konzentrationsbereichen eine befriedi gende Viskosität aufweist.In particular the readily biodegradable cationic fabric softeners of the type of quaternary ammonium compounds with two fatty acyls oxyalkyl groups can only be used in very thin liquids without auxiliary agents process dispersions. There was therefore the task of aqueous To develop textile softener dispersions that are good biological are degradable, have a high fabric softener performance and their aq dispersion in low concentration ranges a satisfactory has sufficient viscosity.
Gegenstand der Erfindung ist eine wäßrige Weichspülmittel-Dispersion mit einem Gehalt vonThe invention relates to an aqueous fabric softener dispersion grading
- (A) 1-10 Gew.-% eines dispergierten kationischen Textilweichma chers der Formel I in der R¹CO- eine gesättigte oder ungesättigte Acylgruppe mit 12-22 C-Atomen, R² eine Gruppe R¹CO(OCnH2n)z-, eine Alkyl gruppe mit 1-4 C-Atomen oder eine Hydroxyalkylgruppe mit 2-4 C-Atomen und R³ eine Alkylgruppe mit 1-4 C-Atomen oder eine Hydroxyalkylgruppe mit 2-4 C-Atomen, n jeweils 2 oder 3, x, y und z jeweils eine Zahl von 1-4 und A⊖ ein Halogenid- oder CH₃OSO₃⊖-Anion ist und(A) 1-10% by weight of a dispersed cationic fabric softener of the formula I. in the R¹CO- a saturated or unsaturated acyl group with 12-22 C-atoms, R² a group R¹CO (OC n H 2n ) z -, an alkyl group with 1-4 C-atoms or a hydroxyalkyl group with 2-4 C-atoms and R³ is an alkyl group with 1-4 C atoms or a hydroxyalkyl group with 2-4 C atoms, n each 2 or 3, x, y and z each have a number from 1-4 and A⊖ is a halide or CH₃OSO₃⊖- Anion is and
- (B) 0,1-5 Gew.-% eines dispergierten kationischen Textilweichma chers der Formel II in der R⁴ eine Gruppe -CH₂-COOR⁷ oder -(CnH2nO)p-COR⁸, R⁵ und R⁶ Alkylgruppen mit 1-4 C-Atomen oder Hydroxyalkylgruppen mit 2-4 C-Atomen sind, R⁷ eine Alkyl- oder Alkenylgruppe mit 12-22 C-Atomen und -COR⁸ eine gesättigte oder ungesättigte Acylgruppe mit 12-22 C-Atomen ist, n jeweils 2 oder 3 und p jeweils eine Zahl von 1-4 und A⊖ ein Halogenid- oder CH₃OSO₃⊖-Anion ist.(B) 0.1-5% by weight of a dispersed cationic fabric softener of the formula II in which R⁴ is a group -CH₂-COOR⁷ or - (C n H 2n O) p -COR⁸, R⁵ and R⁶ are alkyl groups with 1-4 C atoms or hydroxyalkyl groups with 2-4 C atoms, R⁷ is an alkyl or alkenyl group with 12-22 carbon atoms and -COR⁸ is a saturated or unsaturated acyl group with 12-22 carbon atoms, n is 2 or 3 and p each is a number from 1-4 and A⊖ is a halide or CH₃OSO₃⊖ anion .
Diese erfindungsgemäßen wäßrigen Textilweichmacher-Dispersionen wei sen auch ohne besondere Zusätze eine gegenüber den entsprechenden Dispersionen der Komponente (A) deutlich erhöhte Viskosität auf. Dies gilt insbesondere für relativ niedrig konzentrierte Dispersi onen, dieThese aqueous textile plasticizer dispersions according to the invention white one without any special additives compared to the corresponding ones Dispersions of component (A) have a significantly increased viscosity. This is particularly true for dispersions with a relatively low concentration ones that
- (A) 2-6 Gew.-% eines Textilweichmachers der Formel I und(A) 2-6% by weight of a fabric softener of formula I and
- (B) 0,01-3 Gew.-% eines Textilweichmachers der Formel II(B) 0.01-3% by weight of a textile softener of the formula II
enthalten.contain.
Die textilweichmachenden quartären Ammoniumverbindungen sind bekann te Stoffe und im Handel erhältlich. Sie haben textilweichmachende Wirkung und sind auch gut biologisch abbaubar. So sind z. B. quartäre Ammoniumverbindungen, die der Formel I entsprechen, aus DE 17 94 068 und DE 19 35 499 bekannt. Ein Handelsprodukt dieses Typs ist Stepan tex VS 90, ein Di-(talgfettacyl-oxyethyl)-2-hydroxyethyl-methyl methosulfat. Ein weiteres Handelsprodukt dieses Typs ist Armosoft DEAQ, ein Di-(C₁₆/C₁₈-acyl-oxyethyl)-dimethyl-ammonium-chlorid.The textile-softening quaternary ammonium compounds are known fabrics and commercially available. They have fabric softeners Effect and are also readily biodegradable. So z. B. quaternary Ammonium compounds corresponding to formula I from DE 17 94 068 and DE 19 35 499 known. A commercial product of this type is Stepan tex VS 90, a di (tallow fatty acyl oxyethyl) -2-hydroxyethyl methyl methosulfate. Another commercial product of this type is Armosoft DEAQ, a di (C₁₆ / C₁₈ acyl oxyethyl) dimethyl ammonium chloride.
Quartäre Ammoniumverbindungen der Formel II sind z. B. aus EP 21 431 A1 bekannt. Handelsprodukte dieses Typs sind z. B. Armosoft DMDQ, eine Verbindung der Formel II, in der R⁴ eine Gruppe -CH₂COOR⁷, R⁵ und R⁶ Methylgruppen, R⁷ eine C₁₆/C₁₈-Alkylgruppe und A⊖ ein Chlo rid-Anion ist. Ein weiteres Handelsprodukt ist Armosoft AEBE, eine Verbindung der Formel II, in der R⁴ eine Gruppe -CH₂-CH₂O-COR⁸, R⁵ und R⁶ Methylgruppen, -COR⁸ eine C₁₆/C₁₈-Acylgruppe und R⁷ eine C₁₆/C₁₈-Alkylgruppe und A⊖ ein Chlorid-Anion ist.Quaternary ammonium compounds of the formula II are e.g. B. from EP 21 431 A1 known. Commercial products of this type are e.g. B. Armosoft DMDQ, a compound of formula II in which R⁴ is a group -CH₂COOR⁷, R⁵ and R⁶ is a methyl group, R⁷ is a C₁₆ / C₁₈ alkyl group and A⊖ is a Chlo is rid anion. Another commercial product is Armosoft AEBE, a Compound of formula II in which R⁴ is a group -CH₂-CH₂O-COR⁸, R⁵ and R⁶ is methyl groups, -COR⁸ is a C₁₆ / C₁₈ acyl group and R⁷ is one C₁₆ / C₁₈ alkyl group and A⊖ is a chloride anion.
Neben den erfindungsgemäß einzusetzenden quartären Ammoniumverbin dungen der Formeln I und II können die wäßrigen Textilweichmacher- Dispersionen noch weitere, in Wäscheweichspülmitteln übliche Zusätze enthalten. Als solche sind z. B. weitere, zur Viskositätsbeeinflus sung geeignete Zusätze zu nennen, wie z. B. aliphatische Diole und Polyole oder Polyethylenglycole, die zur Verbesserung der Viskosi tätsstabilität gegenüber Scherbeanspruchung beitragen.In addition to the quaternary ammonium compound to be used according to the invention formulas I and II, the aqueous fabric softener Dispersions and other additives common in fabric softeners contain. As such, e.g. B. more, to influence viscosity solution to name suitable additives, such as. B. aliphatic diols and Polyols or polyethylene glycols that improve viscos stability against shear stress.
Weiterhin können auch anionische Sulfat- oder Sulfonat-Tenside, z. B. Fettalkoholsulfat, Natriumsalze auf Basis von C₁₂-C₁₈-Fettalkoholen bereits in kleinen Mengen die Viskosität der Dispersionen erhöhen. Auch Elektrolyte können zur Beeinflussung der rheologischen Eigen schaften eingesetzt werden. Darüber hinaus kann man den Wäscheweich spülern auch noch andere Hilfsmittel, z. B. Fettsäuren mit 12-22 C-Atomen, Fettsäurepartialglyceriden, Fettsäureoxethylate, Fett säureester, Fettalkoholpolyglycolether und andere Emulgatoren zu setzen. Auch Hilfsmittel, die eine antimikrobielle oder ölabweisende Ausrüstung der Textilfasern bewirken, können in die Weichspülmit tel-Formulierung eingearbeitet werden. Schließlich gehören Farbstof fe, optische Aufheller und Duftstoffe zu den üblichen Zusätzen in Wäscheweichspülmitteln.Furthermore, anionic sulfate or sulfonate surfactants, e.g. B. Fatty alcohol sulfate, sodium salts based on C₁₂-C₁₈ fatty alcohols increase the viscosity of the dispersions even in small quantities. Electrolytes can also influence the rheological properties be used. You can also use the laundry soft also rinse other aids, e.g. B. fatty acids with 12-22 C atoms, fatty acid partial glycerides, fatty acid oxyethylates, fat acid esters, fatty alcohol polyglycol ethers and other emulsifiers put. Also aids that have an antimicrobial or oil repellent Finishing of the textile fibers can result in the fabric softener tel formulation are incorporated. After all, dye belongs Fe, optical brighteners and fragrances to the usual additives in Fabric softener.
Die folgenden Beispiele sollen den Erfindungsgegenstand näher er läutern: The following examples are intended to illustrate the subject matter of the invention purify:
Es wurden Weichspüler-Zusammensetzungen nach folgender Rahmenrezep tur hergestellt:There were fabric softener compositions according to the following general recipe door manufactured:
5 Gew.-% kationischer Textilweichmacher
4,475 ppm Farbstoff
0,3 Gew.-% Duftstoff
Rest (ad 100%) Wasser.5% by weight cationic fabric softener
4.475 ppm dye
0.3% by weight of fragrance
Rest (ad 100%) water.
Der kationische Textilweichmacher war wie folgt zusammengesetzt:The cationic fabric softener was composed as follows:
Dabei wurden milchig aussehende, flüssige Dispersionen erhalten, die folgende Viskosität aufwiesen:Milky-looking liquid dispersions were obtained, which had the following viscosity:
Nach weiteren 10 Wochen Lagerung zeigten die Proben keinen weiteren Viskositätsanstieg.After a further 10 weeks of storage, the samples showed no further Viscosity increase.
Claims (3)
- (A) 1-10 Gew.-% eines dispergierten kationischen Textilweich machers der Formel I in der R¹CO- eine gesättigte oder ungesättigte Acylgruppe mit 12-22 C-Atomen, R² eine Gruppe R¹CO(OCnH2n)z-, eine Alkylgruppe mit 1-4 C-Atomen oder eine Hydroxyalkylgruppe mit 2-4 C-Atomen und R³ eine Alkylgruppe mit 1-4 C-Ato men oder eine Hydroxyalkylgruppe mit 2-4 C-Atomen, n je weils 2 oder 3, x, y und z jeweils eine Zahl von 1-4 und A⊖ ein Halogenid- oder CH₃OSO₃⊖- Anion ist und
- (B) 0,1-5 Gew.-% eines dispergierten kationischen Textil weichmachers der Formel II in der R⁴ eine Gruppe -CH₂-COOR⁷ oder -(CnH2nO)p-COR⁸, R⁵ und R⁶ Alkylgruppen mit 1-4 C-Atomen oder Hydroxyal kylgruppen mit 2-4 C-Atomen sind, R⁷ eine Alkyl- oder Alkenylgruppe mit 12-22 C-Atomen und -COR⁸ eine gesät tigte oder ungesättigte Acylgruppe mit 12-22 C-Atomen ist, n jeweils 2 oder 3 und p jeweils eine Zahl von 1-4 und A⊖ ein Halogenid- oder CH₃OSO₃⊖-Anion ist.
- (A) 1-10% by weight of a dispersed cationic fabric softener of the formula I. in the R¹CO- a saturated or unsaturated acyl group with 12-22 C-atoms, R² a group R¹CO (OC n H 2n ) z -, an alkyl group with 1-4 C-atoms or a hydroxyalkyl group with 2-4 C-atoms and R³ is an alkyl group with 1-4 C-atoms or a hydroxyalkyl group with 2-4 C atoms, n each Weil 2 or 3, x, y and z each have a number of 1-4 and A⊖ is a halide or CH₃OSO₃⊖ - Anion is and
- (B) 0.1-5% by weight of a dispersed cationic textile softener of the formula II in which R⁴ is a group -CH₂-COOR⁷ or - (C n H 2n O) p -COR⁸, R⁵ and R⁶ are alkyl groups with 1-4 C atoms or hydroxyal alkyl groups with 2-4 C atoms, R⁷ is an alkyl or Alkenyl group with 12-22 carbon atoms and -COR⁸ is a saturated or unsaturated acyl group with 12-22 carbon atoms, n is 2 or 3 and p each is a number from 1-4 and A⊖ is a halide or CH₃OSO₃⊖- Anion is.
- (A) 2-6 Gew.-% eines Textilweichmachers der Formel I und
- (B) 0,1-3 Gew.-% eines Textilweichmachers der Formel II
- (A) 2-6% by weight of a fabric softener of formula I and
- (B) 0.1-3% by weight of a textile softener of the formula II
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4403686A DE4403686A1 (en) | 1994-02-07 | 1994-02-07 | Aq. fabric conditioner dispersions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4403686A DE4403686A1 (en) | 1994-02-07 | 1994-02-07 | Aq. fabric conditioner dispersions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4403686A1 true DE4403686A1 (en) | 1995-08-10 |
Family
ID=6509621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4403686A Withdrawn DE4403686A1 (en) | 1994-02-07 | 1994-02-07 | Aq. fabric conditioner dispersions |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE4403686A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8026206B2 (en) | 2005-05-18 | 2011-09-27 | Stepan Company | Low solids, high viscosity fabric softener compositions and process for making the same |
| EP2987905A1 (en) | 2014-08-20 | 2016-02-24 | Klaus Schmitt Beteiligungsgesellschaft mbH | Means for hydrophilic coating of fabrics composed of hydrophobic thermoplastic materials, and the application of the same |
-
1994
- 1994-02-07 DE DE4403686A patent/DE4403686A1/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8026206B2 (en) | 2005-05-18 | 2011-09-27 | Stepan Company | Low solids, high viscosity fabric softener compositions and process for making the same |
| EP2987905A1 (en) | 2014-08-20 | 2016-02-24 | Klaus Schmitt Beteiligungsgesellschaft mbH | Means for hydrophilic coating of fabrics composed of hydrophobic thermoplastic materials, and the application of the same |
| DE102014111881A1 (en) | 2014-08-20 | 2016-02-25 | Klaus Schmitt Beteiligungsgesellschaft Mbh | Aqueous waterproofing agent for fabrics of hydrophobic thermoplastic materials and products made therefrom |
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| Date | Code | Title | Description |
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| 8139 | Disposal/non-payment of the annual fee |