DE60006181D1 - Zweiphasige Membran zur Permeation von Wasserstoff - Google Patents
Zweiphasige Membran zur Permeation von WasserstoffInfo
- Publication number
- DE60006181D1 DE60006181D1 DE60006181T DE60006181T DE60006181D1 DE 60006181 D1 DE60006181 D1 DE 60006181D1 DE 60006181 T DE60006181 T DE 60006181T DE 60006181 T DE60006181 T DE 60006181T DE 60006181 D1 DE60006181 D1 DE 60006181D1
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- permeation
- phase
- xmx
- palladium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 3
- 239000001257 hydrogen Substances 0.000 title abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 3
- 239000012528 membrane Substances 0.000 title abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- 239000004020 conductor Substances 0.000 abstract 3
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 229910052693 Europium Inorganic materials 0.000 abstract 1
- 229910052688 Gadolinium Inorganic materials 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- 229910052772 Samarium Inorganic materials 0.000 abstract 1
- 229910052771 Terbium Inorganic materials 0.000 abstract 1
- 229910052769 Ytterbium Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02231—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/0271—Perovskites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
- C01B3/505—Membranes containing palladium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
- C01F17/32—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/26—Electrical properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/34—Three-dimensional structures perovskite-type (ABO3)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Analytical Chemistry (AREA)
- Structural Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Geology (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/302,786 US6235417B1 (en) | 1999-04-30 | 1999-04-30 | Two-phase hydrogen permeation membrane |
US302786 | 2002-11-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60006181D1 true DE60006181D1 (de) | 2003-12-04 |
DE60006181T2 DE60006181T2 (de) | 2004-08-12 |
Family
ID=23169204
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60006181T Expired - Lifetime DE60006181T2 (de) | 1999-04-30 | 2000-04-28 | Zweiphasige Membran zur Permeation von Wasserstoff |
Country Status (6)
Country | Link |
---|---|
US (1) | US6235417B1 (de) |
EP (1) | EP1048614B1 (de) |
AT (1) | ATE253016T1 (de) |
CA (1) | CA2306999C (de) |
DE (1) | DE60006181T2 (de) |
DK (1) | DK1048614T3 (de) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2298850A1 (en) * | 1999-02-17 | 2000-08-17 | Matsushita Electric Industrial Co., Ltd. | Mixed ionic conductor and device using the same |
US6517693B2 (en) * | 2000-02-14 | 2003-02-11 | Matsushita Electric Industrial Co., Ltd. | Ion conductor |
DE10013895A1 (de) * | 2000-03-21 | 2001-10-04 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Verfahren zur katalytischen Umsetzung von Kohlenmonoxid in einem Wasserstoff enthaltenden Gasgemisch |
US6468499B1 (en) * | 2000-06-09 | 2002-10-22 | Argonne National Laboratory | Method of generating hydrogen by catalytic decomposition of water |
US20020179887A1 (en) * | 2001-05-01 | 2002-12-05 | Yongxian Zeng | Supported perovskite-type oxides and methods for preparation thereof |
CN1541184A (zh) * | 2001-06-15 | 2004-10-27 | ά��ϵͳ��˾ | 用于将硫化氢分解成氢和硫并将该分解产物分离的膜式催化反应器 |
US6569226B1 (en) * | 2001-09-28 | 2003-05-27 | The United States Of America As Represented By The United States Department Of Energy | Metal/ceramic composites with high hydrogen permeability |
US7001446B2 (en) * | 2002-03-05 | 2006-02-21 | Eltron Research, Inc. | Dense, layered membranes for hydrogen separation |
US20050241477A1 (en) * | 2002-03-05 | 2005-11-03 | Mundschau Michael V | Hydrogen transport membranes |
EP1487563A4 (de) * | 2002-03-05 | 2005-07-20 | Eltron Research Inc | Wasserstofftransportmembrane |
US7393384B2 (en) * | 2002-04-18 | 2008-07-01 | The Trustees Of Boston University | Hydrogen separation using oxygen ion-electron mixed conduction membranes |
US7045231B2 (en) * | 2002-05-22 | 2006-05-16 | Protonetics International, Inc. | Direct hydrocarbon reforming in protonic ceramic fuel cells by electrolyte steam permeation |
US6726893B2 (en) * | 2002-09-17 | 2004-04-27 | The University Of Chicago | Hydrogen production by high-temperature water splitting using electron-conducting membranes |
US7087211B2 (en) * | 2002-09-17 | 2006-08-08 | The University Of Chicago | Hydrogen production by high temperature water splitting using electron conducting membranes |
US7332237B2 (en) * | 2003-01-27 | 2008-02-19 | Protonetics International, Inc. | Stream reforming of solid carbon in protonic ceramic fuel cells |
US7479241B2 (en) * | 2003-05-16 | 2009-01-20 | Kabushikikaisha Equos Research | Mixed conductor |
JP2007501998A (ja) * | 2003-08-07 | 2007-02-01 | シービーエイチ2 テクノロジーズ,インコーポレイテッド. | 燃料電池発電装置用の自己着火性水素製造システム |
US20050039400A1 (en) * | 2003-08-22 | 2005-02-24 | Francis Lau | Hydrogen production process from carbonaceous materials using membrane gasifier |
US8012380B2 (en) * | 2004-03-05 | 2011-09-06 | Ceramatec, Inc. | Proton conducting ceramic membranes for hydrogen separation |
US7258820B2 (en) * | 2004-03-05 | 2007-08-21 | Ceramatec, Inc. | Ceramic mixed protonic/electronic conducting membranes for hydrogen separation |
JP4193750B2 (ja) * | 2004-04-26 | 2008-12-10 | トヨタ自動車株式会社 | 水素分離膜、燃料電池、およびその水素分離膜、燃料電池の製造方法 |
US20050252853A1 (en) * | 2004-05-13 | 2005-11-17 | Berland Brian S | Novel proton conducting materials and devices incorporating them |
US7255949B2 (en) | 2004-05-25 | 2007-08-14 | Protonetics International, Inc. | Systems and methods to generate hydrogen and electrical power in a reversible compound fuel cell |
US7419648B2 (en) * | 2004-07-16 | 2008-09-02 | Shell Oil Company | Process for the production of hydrogen and carbon dioxide |
KR20070083978A (ko) * | 2004-10-05 | 2007-08-24 | 씨티피 히드로젠 코포레이션 | 전기화학 시스템용 전도성 세라믹 |
US7588626B2 (en) * | 2004-11-23 | 2009-09-15 | Trustees Of Boston University | Composite mixed oxide ionic and electronic conductors for hydrogen separation |
KR100691645B1 (ko) | 2005-07-07 | 2007-03-09 | 요업기술원 | 수소 분리막 및 그의 제조 방법 |
US7771520B1 (en) * | 2006-09-06 | 2010-08-10 | Bossard Peter R | System and method for forming a membrane that is super-permeable to hydrogen |
US7744675B2 (en) * | 2006-11-08 | 2010-06-29 | Shell Oil Company | Gas separation membrane comprising a substrate with a layer of coated inorganic oxide particles and an overlayer of a gas-selective material, and its manufacture and use |
US20080184892A1 (en) * | 2007-02-06 | 2008-08-07 | Ctp Hydrogen Corporation | Architectures for electrochemical systems |
JP2008243627A (ja) * | 2007-03-27 | 2008-10-09 | Toyota Motor Corp | プロトン伝導体、電気化学セル、およびプロトン伝導体の製造方法 |
EP2030669B1 (de) | 2007-08-16 | 2014-04-02 | Sulzer Metco AG | Verfahren zum Herstellen einer wasserstoffpermeablen Membran sowie wasserstoffpermeable Membran |
EP2417058B2 (de) | 2009-04-06 | 2021-08-11 | Basf Se | Verfahren zur elektrochemischen abtrennung von wasserstoff aus einem reaktionsgemisch |
CN102123792B (zh) * | 2009-04-28 | 2014-09-03 | 松下电器产业株式会社 | 光激发半导体和使用它的设备 |
GB201000156D0 (en) * | 2010-01-07 | 2010-02-24 | Gas2 Ltd | Isothermal reactor for partial oxidisation of methane |
RU2495854C1 (ru) * | 2012-04-03 | 2013-10-20 | Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук | Твердый электролит на основе оксида церия и церата бария |
US9790602B2 (en) | 2014-08-11 | 2017-10-17 | International Business Machines Corporation | Techniques for photocatalytic hydrogen generation |
US10899613B2 (en) | 2017-10-20 | 2021-01-26 | University Of South Carolina | Graphene-ceramic composite membrane for hydrogen separation membranes |
JP6691247B1 (ja) * | 2019-01-22 | 2020-04-28 | 東京瓦斯株式会社 | 反応装置及び燃料電池発電システム |
CN111545077A (zh) * | 2020-06-15 | 2020-08-18 | 黄淮学院 | 一种含稀土配合物混合基质膜的制备方法及其应用 |
WO2022191111A1 (ja) * | 2021-03-12 | 2022-09-15 | 国立大学法人北海道大学 | 水素透過材料 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3413777A (en) | 1965-06-22 | 1968-12-03 | Engelhard Min & Chem | Hydrogen diffusion and method for producing same |
US3428476A (en) | 1965-06-22 | 1969-02-18 | Engelhard Min & Chem | Method for producing hydrogen diffusion cells |
JPS612548A (ja) * | 1984-02-10 | 1986-01-08 | 小宮山 宏 | 酸素イオン透過性を有する複合体とこの複合体の製造方法 |
JPS62121616A (ja) * | 1985-11-21 | 1987-06-02 | Ngk Insulators Ltd | 水素ガス分離膜 |
US4851303A (en) | 1986-11-26 | 1989-07-25 | Sri-International | Solid compositions for fuel cells, sensors and catalysts |
DE4117284A1 (de) | 1991-05-27 | 1992-12-03 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung von mikroporoesen keramikmembranen fuer die trennung von gas- und fluessigkeitsgemischen |
JP2882104B2 (ja) | 1991-07-17 | 1999-04-12 | 松下電器産業株式会社 | プロトン伝導体およびその製造方法 |
US5616223A (en) | 1992-05-11 | 1997-04-01 | Gas Research Institute | Mixed ionic-electronic conducting composites for oxygen separation and electrocatalysis |
US5604048A (en) | 1993-02-26 | 1997-02-18 | Kyocera Corporation | Electrically conducting ceramic and fuel cell using the same |
US6033632A (en) * | 1993-12-08 | 2000-03-07 | Eltron Research, Inc. | Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them |
JPH0829375A (ja) * | 1994-07-12 | 1996-02-02 | Tokyo Yogyo Co Ltd | 溶融金属中の水素溶解量測定用センサ |
US5496655A (en) | 1994-10-12 | 1996-03-05 | Lockheed Idaho Technologies Company | Catalytic bipolar interconnection plate for use in a fuel cell |
JP3311218B2 (ja) * | 1995-11-02 | 2002-08-05 | 松下電器産業株式会社 | 炭化水素センサ |
US5670270A (en) | 1995-11-16 | 1997-09-23 | The Dow Chemical Company | Electrode structure for solid state electrochemical devices |
NO304220B1 (no) * | 1996-04-30 | 1998-11-16 | Sintef | FremgangsmÕte til fremstilling av tynne metallmembraner |
ID20211A (id) * | 1997-04-29 | 1998-10-29 | Praxair Technology Inc | Metoda produksi hidrogen dengan menggunakan membran elektrolit padat |
US6056807A (en) * | 1998-01-26 | 2000-05-02 | Air Products And Chemicals, Inc. | Fluid separation devices capable of operating under high carbon dioxide partial pressures which utilize creep-resistant solid-state membranes formed from a mixed conducting multicomponent metallic oxide |
-
1999
- 1999-04-30 US US09/302,786 patent/US6235417B1/en not_active Expired - Lifetime
-
2000
- 2000-04-27 CA CA002306999A patent/CA2306999C/en not_active Expired - Lifetime
- 2000-04-28 EP EP00303635A patent/EP1048614B1/de not_active Expired - Lifetime
- 2000-04-28 AT AT00303635T patent/ATE253016T1/de not_active IP Right Cessation
- 2000-04-28 DE DE60006181T patent/DE60006181T2/de not_active Expired - Lifetime
- 2000-04-28 DK DK00303635T patent/DK1048614T3/da active
Also Published As
Publication number | Publication date |
---|---|
US6235417B1 (en) | 2001-05-22 |
EP1048614B1 (de) | 2003-10-29 |
CA2306999A1 (en) | 2000-10-30 |
DE60006181T2 (de) | 2004-08-12 |
DK1048614T3 (da) | 2004-02-16 |
ATE253016T1 (de) | 2003-11-15 |
CA2306999C (en) | 2008-03-11 |
EP1048614A1 (de) | 2000-11-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE60006181D1 (de) | Zweiphasige Membran zur Permeation von Wasserstoff | |
ATE297874T1 (de) | Wasserstoffdurchlässigkeit durch protonen- und elektronenleitende mischwerkstoffe | |
Rolle et al. | Ca3Co4O9+ δ, a growing potential SOFC cathode material: impact of the layer composition and thickness on the electrochemical properties | |
KR100352097B1 (ko) | 혼합이온 전도체 및 이것을 이용한 장치 | |
WO2004013882A3 (en) | Nano-composite electrodes and method of making the same | |
Hu et al. | Oxygen incorporation at the three-phase boundary of LSCF–SDC composite | |
JP4608506B2 (ja) | 混合イオン伝導体およびこれを用いたデバイス | |
CA2493029A1 (en) | Perovskite-based fuel cell electrode and membrane | |
US20080011604A1 (en) | Process and Device for Water Electrolysis Comprising a Special Oxide Electrode Material | |
CA2466484A1 (en) | Ceramic member with oxygen ion conductivity and use thereof | |
JP2000302550A (ja) | 混合イオン伝導体およびこれを用いたデバイス | |
AU2003277922A1 (en) | Solid oxide fuel cell | |
WO1999041793A3 (en) | Improved lanthanum manganite-based air electrode for solid oxide fuel cells | |
KR101165124B1 (ko) | 이온 전도체 | |
EP1300365A3 (de) | Komplexe Oxide, Oxidionenleiter, leitende Oxidionenschichten und elektrochemische Zellen | |
Kojo et al. | Fabrication and electrochemical performance of anode-supported solid oxide fuel cells based on proton-conducting lanthanum tungstate thin electrolyte | |
ZA200203352B (en) | An electrochemical solid-state device comprising b-site rich lanthanum calcium manganite. | |
KR100365369B1 (ko) | 가스 혼합물 중의 산소분리에 사용되는 세라믹 물질 | |
RU2009128173A (ru) | Композиционный материал для применения в качестве электродного материала в твердооксидных элементах тоэ | |
KR102069861B1 (ko) | 산화물, 이를 포함하는 전해질 및 전기화학장치 | |
JP3141449B2 (ja) | 電極用ペロブスカイト型複合酸化物 | |
JP2001052722A (ja) | 固体酸化物型燃料電池 | |
Santoni et al. | Core-level and valence band photoemission study of perovskite oxide powders synthesized by mechanically and thermally activated solid-state reaction | |
KR101496752B1 (ko) | 이중상 산소분리막 및 그 제조방법 | |
JP2023172824A (ja) | セラミック焼結体 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |