DE60028826D1 - Katalysatorzusammensetzung und verfahren für olefinpolymerisation - Google Patents
Katalysatorzusammensetzung und verfahren für olefinpolymerisationInfo
- Publication number
- DE60028826D1 DE60028826D1 DE60028826T DE60028826T DE60028826D1 DE 60028826 D1 DE60028826 D1 DE 60028826D1 DE 60028826 T DE60028826 T DE 60028826T DE 60028826 T DE60028826 T DE 60028826T DE 60028826 D1 DE60028826 D1 DE 60028826D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst composition
- olefin polymerization
- bound
- bridge
- utilize
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/434,696 US6420580B1 (en) | 1999-11-05 | 1999-11-05 | Catalyst compositions and method of polymerization therewith |
US434696 | 1999-11-05 | ||
PCT/US2000/027095 WO2001034664A1 (en) | 1999-11-05 | 2000-10-02 | Catalyst compositions and method of polymerization therewith |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60028826D1 true DE60028826D1 (de) | 2006-07-27 |
DE60028826T2 DE60028826T2 (de) | 2007-01-18 |
Family
ID=23725288
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60028826T Revoked DE60028826T2 (de) | 1999-11-05 | 2000-10-02 | Katalysatorzusammensetzung und verfahren für olefinpolymerisation |
Country Status (8)
Country | Link |
---|---|
US (1) | US6420580B1 (de) |
EP (1) | EP1246851B1 (de) |
AT (1) | ATE329940T1 (de) |
AU (1) | AU7845000A (de) |
CA (1) | CA2395681A1 (de) |
DE (1) | DE60028826T2 (de) |
ES (1) | ES2265988T3 (de) |
WO (1) | WO2001034664A1 (de) |
Families Citing this family (63)
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US7132486B2 (en) * | 2000-10-06 | 2006-11-07 | Univation Technologies, Llc | Linear low density polyethylenes with high melt strength and high melt index ratio |
US6884747B2 (en) * | 2000-10-06 | 2005-04-26 | Univation Technologies, Llc | Linear low density polyethylenes with high melt strength and high melt index ratio |
US6734265B1 (en) * | 2000-10-06 | 2004-05-11 | Univation Technologies, Llc. | Linear low density polyethylenes with high melt strength and high melt index ratio |
KR100469470B1 (ko) * | 2003-01-30 | 2005-02-02 | 엘지전자 주식회사 | 열변형을 이용한 댐퍼 및 이를 구비한 세탁기 |
US6870010B1 (en) | 2003-12-01 | 2005-03-22 | Univation Technologies, Llc | Low haze high strength polyethylene compositions |
US7288596B2 (en) | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
US20050182210A1 (en) | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
US7473750B2 (en) * | 2004-12-07 | 2009-01-06 | Fina Technology, Inc. | Random copolymers and formulations useful for thermoforming and blow molding applications |
US7312279B2 (en) * | 2005-02-07 | 2007-12-25 | Univation Technologies, Llc | Polyethylene blend compositions |
US7645834B2 (en) * | 2005-04-29 | 2010-01-12 | Fina Technologies, Inc. | Catalyst system for production of polyolefins |
US20060247394A1 (en) * | 2005-04-29 | 2006-11-02 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
US7081285B1 (en) | 2005-04-29 | 2006-07-25 | Fina Technology, Inc. | Polyethylene useful for blown films and blow molding |
US7220806B2 (en) * | 2005-04-29 | 2007-05-22 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
US7282546B2 (en) * | 2005-06-22 | 2007-10-16 | Fina Technology, Inc. | Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations |
US7683002B2 (en) | 2006-04-04 | 2010-03-23 | Fina Technology, Inc. | Transition metal catalyst and formation thereof |
US20070299222A1 (en) | 2006-04-04 | 2007-12-27 | Fina Technology, Inc. | Transition metal catalysts and formation thereof |
US20070235896A1 (en) * | 2006-04-06 | 2007-10-11 | Fina Technology, Inc. | High shrink high modulus biaxially oriented films |
US20080051538A1 (en) * | 2006-07-11 | 2008-02-28 | Fina Technology, Inc. | Bimodal pipe resin and products made therefrom |
US7449529B2 (en) * | 2006-07-11 | 2008-11-11 | Fina Technology, Inc. | Bimodal blow molding resin and products made therefrom |
US7893181B2 (en) * | 2006-07-11 | 2011-02-22 | Fina Technology, Inc. | Bimodal film resin and products made therefrom |
US7514510B2 (en) * | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
US7470759B2 (en) * | 2006-07-31 | 2008-12-30 | Fina Technology, Inc. | Isotactic-atactic polypropylene and methods of making same |
US20080061468A1 (en) * | 2006-09-07 | 2008-03-13 | Frank Li | Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators |
US7538167B2 (en) * | 2006-10-23 | 2009-05-26 | Fina Technology, Inc. | Syndiotactic polypropylene and methods of preparing same |
US20080114130A1 (en) * | 2006-11-10 | 2008-05-15 | John Ashbaugh | Resin composition for production of high tenacity slit film, monofilaments and fibers |
CN101558115A (zh) | 2006-12-15 | 2009-10-14 | 弗纳技术股份有限公司 | 聚丙烯吹塑薄膜 |
EP2097459A1 (de) * | 2006-12-29 | 2009-09-09 | Fina Technology, Inc. | Succinat-haltiges polymerisierungskatalysatorsystem mit n-butylmethyldimethoxysilan zur herstellung von für polypropylen-folien geeigneten harzen |
US8859084B2 (en) * | 2008-01-29 | 2014-10-14 | Fina Technology, Inc. | Modifiers for oriented polypropylene |
US8003741B2 (en) | 2008-02-07 | 2011-08-23 | Fina Technology, Inc. | Ziegler-Natta catalyst |
US20090202770A1 (en) * | 2008-02-08 | 2009-08-13 | Fengkui Li | Polypropylene/polyisobutylene blends and films prepared from same |
US7740070B2 (en) * | 2008-06-16 | 2010-06-22 | Halliburton Energy Services, Inc. | Wellbore servicing compositions comprising a density segregation inhibiting composite and methods of making and using same |
US8759446B2 (en) | 2008-06-30 | 2014-06-24 | Fina Technology, Inc. | Compatibilized polypropylene and polylactic acid blends and methods of making and using same |
US8545971B2 (en) | 2008-06-30 | 2013-10-01 | Fina Technology, Inc. | Polymeric compositions comprising polylactic acid and methods of making and using same |
US8268913B2 (en) | 2008-06-30 | 2012-09-18 | Fina Technology, Inc. | Polymeric blends and methods of using same |
US9334342B2 (en) | 2008-10-01 | 2016-05-10 | Fina Technology, Inc. | Polypropylene for reduced plate out in polymer article production processes |
US20100087602A1 (en) * | 2008-10-08 | 2010-04-08 | Fina Technology, Inc. | Long chain branched polypropylene for cast film applications |
US8653198B2 (en) | 2009-03-26 | 2014-02-18 | Fina Technology, Inc. | Method for the preparation of a heterophasic copolymer and uses thereof |
US9090000B2 (en) | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
US20100247887A1 (en) | 2009-03-26 | 2010-09-30 | Fina Technology, Inc. | Polyolefin films for in-mold labels |
US9174384B2 (en) * | 2009-09-01 | 2015-11-03 | Fina Technology, Inc. | Multilayer polypropylene films and methods of making and using same |
US8592535B2 (en) | 2010-01-11 | 2013-11-26 | Fina Technology, Inc. | Ziegler-natta catalyst systems and polymers formed therefrom |
US10351640B2 (en) | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
US8278403B2 (en) | 2010-07-08 | 2012-10-02 | Fina Technology, Inc. | Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers |
US20120046429A1 (en) | 2010-08-23 | 2012-02-23 | Fina Technology, Inc. | Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components |
US10711077B2 (en) | 2011-02-07 | 2020-07-14 | Fina Technology, Inc. | Ziegler-natta catalyst composition with controlled morphology |
US8586192B2 (en) | 2011-02-15 | 2013-11-19 | Fina Technology, Inc. | Compatibilized polymeric compositions comprising polyolefin-polylactic acid copolymers and methods of making the same |
US9382347B2 (en) | 2011-02-16 | 2016-07-05 | Fina Technology Inc | Ziegler-Natta catalysts doped with non-group IV metal chlorides |
US8628718B2 (en) | 2011-02-18 | 2014-01-14 | Fina Technology, Inc. | Modified polylactic acid, polymeric blends and methods of making the same |
US8580893B2 (en) | 2011-12-22 | 2013-11-12 | Fina Technology, Inc. | Methods for improving multimodal polyethylene and films produced therefrom |
US9206293B2 (en) | 2014-01-31 | 2015-12-08 | Fina Technology, Inc. | Polyethyene and articles produced therefrom |
JP6806567B2 (ja) | 2014-06-11 | 2021-01-06 | フイナ・テクノロジー・インコーポレーテツドFina Technology, Incorporated | 耐塩素性ポリエチレン化合物およびそれから製造される製品 |
US9650448B2 (en) | 2014-06-13 | 2017-05-16 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
US9624321B2 (en) | 2014-06-13 | 2017-04-18 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
WO2017001882A1 (en) * | 2015-06-30 | 2017-01-05 | Universite Claude Bernard Lyon 1 | Method for the preparation of ultra-high molecular weight polyethylene |
JP7004656B2 (ja) * | 2015-12-31 | 2022-02-04 | ハンファ ケミカル コーポレーション | 混成メタロセン担持触媒、およびそれを用いたオレフィン重合体の製造方法 |
JP6967073B2 (ja) | 2016-10-28 | 2021-11-17 | フイナ・テクノロジー・インコーポレーテツドFina Technology, Incorporated | Boppに応用するためのポリプロピレン中の結晶度を下げる作用剤の使用 |
SG11202003356WA (en) * | 2017-10-27 | 2020-05-28 | Univation Tech Llc | Polyethylene copolymer resins and films |
US10865258B2 (en) | 2018-01-31 | 2020-12-15 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same |
US10851187B2 (en) | 2018-01-31 | 2020-12-01 | Exxonmobil Chemical Patents Inc. | Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same |
WO2020056119A1 (en) | 2018-09-14 | 2020-03-19 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
WO2020172306A1 (en) | 2019-02-20 | 2020-08-27 | Fina Technology, Inc. | Polymer compositions with low warpage |
WO2022232123A1 (en) | 2021-04-26 | 2022-11-03 | Fina Technology, Inc. | Thin single-site catalyzed polymer sheets |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3904468A1 (de) | 1989-02-15 | 1990-08-16 | Hoechst Ag | Polypropylenwachs und verfahren zu seiner herstellung |
DE3922546A1 (de) | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
DE59107926D1 (de) * | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
ATE194630T1 (de) | 1992-09-04 | 2000-07-15 | Bp Chem Int Ltd | Katalysatorzusammensetzung und verfahren zur herstellung von polyolefinen |
TW369545B (en) | 1993-02-12 | 1999-09-11 | Hoechst Ag | Process for preparing cycloolefin copolymers |
DE4333128A1 (de) | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
EP0739897A1 (de) * | 1995-04-27 | 1996-10-30 | Hoechst Aktiengesellschaft | Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator |
US5654454A (en) | 1995-05-30 | 1997-08-05 | Phillips Petroleum Company | Metallocene preparation and use |
DE69722902T2 (de) * | 1996-12-09 | 2004-05-19 | Mitsubishi Chemical Corp. | Katalysator für Alpha-Olefinpolymerisation |
GB9713741D0 (en) | 1997-06-27 | 1997-09-03 | Bp Chem Int Ltd | Polymerisation catalysts |
DE19809159A1 (de) * | 1998-03-04 | 1999-09-09 | Bayer Ag | Metallorganische Verbindungen |
US6262201B1 (en) * | 1998-06-19 | 2001-07-17 | Phillips Petroleum Company | Aryl substituted metallocene catalysts and their use |
SG72966A1 (en) * | 1998-07-08 | 2000-05-23 | Sumitomo Chemical Co | Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer |
US6252098B1 (en) * | 2000-06-05 | 2001-06-26 | Albemarle Corporation | Enhanced synthesis of racemic metallocenes |
-
1999
- 1999-11-05 US US09/434,696 patent/US6420580B1/en not_active Expired - Fee Related
-
2000
- 2000-10-02 AT AT00968557T patent/ATE329940T1/de not_active IP Right Cessation
- 2000-10-02 WO PCT/US2000/027095 patent/WO2001034664A1/en active IP Right Grant
- 2000-10-02 DE DE60028826T patent/DE60028826T2/de not_active Revoked
- 2000-10-02 ES ES00968557T patent/ES2265988T3/es not_active Expired - Lifetime
- 2000-10-02 EP EP00968557A patent/EP1246851B1/de not_active Revoked
- 2000-10-02 AU AU78450/00A patent/AU7845000A/en not_active Abandoned
- 2000-10-02 CA CA002395681A patent/CA2395681A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US6420580B1 (en) | 2002-07-16 |
EP1246851A1 (de) | 2002-10-09 |
AU7845000A (en) | 2001-06-06 |
ATE329940T1 (de) | 2006-07-15 |
EP1246851B1 (de) | 2006-06-14 |
DE60028826T2 (de) | 2007-01-18 |
WO2001034664A1 (en) | 2001-05-17 |
CA2395681A1 (en) | 2001-05-17 |
ES2265988T3 (es) | 2007-03-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8331 | Complete revocation |