DE60034308D1 - Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationkatalysator, und ein Verfahren zur Herstellung von Polyolefinen - Google Patents

Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationkatalysator, und ein Verfahren zur Herstellung von Polyolefinen

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Publication number
DE60034308D1
DE60034308D1 DE60034308T DE60034308T DE60034308D1 DE 60034308 D1 DE60034308 D1 DE 60034308D1 DE 60034308 T DE60034308 T DE 60034308T DE 60034308 T DE60034308 T DE 60034308T DE 60034308 D1 DE60034308 D1 DE 60034308D1
Authority
DE
Germany
Prior art keywords
preparation
metallocenes
polyolefins
polymerization catalyst
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60034308T
Other languages
English (en)
Other versions
DE60034308T2 (de
Inventor
Koji Kawai
Masahiro Yamashita
Yasushi Tohi
Nobuo Kawahara
Kenji Michiue
Hiromu Kaneyoshi
Ryoji Mori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Application granted granted Critical
Publication of DE60034308D1 publication Critical patent/DE60034308D1/de
Publication of DE60034308T2 publication Critical patent/DE60034308T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE60034308T 1999-10-08 2000-10-05 Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen Expired - Lifetime DE60034308T2 (de)

Applications Claiming Priority (13)

Application Number Priority Date Filing Date Title
JP28883999 1999-10-08
JP28884099 1999-10-08
JP28883999 1999-10-08
JP28883899 1999-10-08
JP28883899 1999-10-08
JP28884099 1999-10-08
JP2000250390 2000-08-21
JP2000250391 2000-08-21
JP2000250390 2000-08-21
JP2000250387 2000-08-21
JP2000250387 2000-08-21
JP2000250391 2000-08-21
PCT/JP2000/006945 WO2001027124A1 (fr) 1999-10-08 2000-10-05 Compose metallocene, son procede de fabrication, catalyseur de polymerisation d'olefine, procede de production de polyolefine et polyolefine

Publications (2)

Publication Number Publication Date
DE60034308D1 true DE60034308D1 (de) 2007-05-24
DE60034308T2 DE60034308T2 (de) 2007-12-20

Family

ID=27554452

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60034308T Expired - Lifetime DE60034308T2 (de) 1999-10-08 2000-10-05 Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen

Country Status (7)

Country Link
US (2) US6939928B1 (de)
EP (1) EP1138687B1 (de)
JP (2) JP4554133B2 (de)
KR (1) KR100746676B1 (de)
CN (2) CN100434433C (de)
DE (1) DE60034308T2 (de)
WO (1) WO2001027124A1 (de)

Families Citing this family (169)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6635715B1 (en) † 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6469188B1 (en) 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
EP1031582A1 (de) * 1999-02-26 2000-08-30 Fina Research S.A. Verwendung und Herstellung von Polypropylen
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
WO2004029062A1 (ja) 2002-09-27 2004-04-08 Mitsui Chemicals, Inc. オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法
CN101440179B (zh) 2003-03-28 2011-09-21 三井化学株式会社 聚烯烃树脂组合物
JP5036964B2 (ja) * 2003-08-22 2012-09-26 三井化学株式会社 プロピレン系重合体及びその用途
JP2005171169A (ja) * 2003-12-15 2005-06-30 Mitsui Chemicals Inc ポリプロピレン樹脂組成物
JP2005200452A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc α−オレフィン（共）重合体の製造方法
JP2005200453A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc α−オレフィン（共）重合体の製造方法
TW200613320A (en) * 2004-06-10 2006-05-01 Mitsui Chemicals Inc Olefin polymer and use thereof
BRPI0513057A (pt) 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
US7214749B2 (en) * 2004-07-09 2007-05-08 The Texas A&M University Systems Catalyst system for high activity and stereoselectivity in the homopolymerization and copolymerization of olefins
JP4823910B2 (ja) * 2004-08-30 2011-11-24 三井化学株式会社 プロピレン系重合体の製造方法
CN100390256C (zh) 2004-11-26 2008-05-28 三井化学株式会社 合成润滑油和润滑油组合物
JP5438256B2 (ja) 2006-11-17 2014-03-12 三井化学株式会社 ポリプロピレン系樹脂フィルムおよびその用途
KR101064037B1 (ko) * 2005-05-18 2011-09-08 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매, 올레핀 중합체의 제조방법, 프로필렌계 공중합체의 제조방법, 프로필렌 중합체, 프로필렌계 중합체 조성물 및 이들의 용도
CN101838363B (zh) * 2005-05-18 2012-07-25 三井化学株式会社 丙烯系共聚物的制造方法
US7094938B1 (en) * 2005-05-20 2006-08-22 Fina Technology, Inc. Process for the preparation of substituted fluorenes
JPWO2006126610A1 (ja) * 2005-05-25 2008-12-25 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン系重合体の製造方法
EP1900715B1 (de) * 2005-05-25 2015-04-22 Mitsui Chemicals, Inc. Fluorenderivat, übergangsmetallverbindung, katalysator für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren
JP2006328300A (ja) * 2005-05-30 2006-12-07 Mitsui Chemicals Inc ポリプロピレン樹脂、並びに該樹脂の高透明シートへの応用
EP1734059A1 (de) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Kohlenstoffverbrückte Cyclopentadienyl-Fluorenyl-Liganden
US7335711B2 (en) * 2005-08-17 2008-02-26 Fina Technology, Inc. Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins
US20070080483A1 (en) * 2005-10-07 2007-04-12 Mitsui Chemicals, Inc. Process for producing injection molded product
US20070225423A1 (en) * 2005-10-07 2007-09-27 Mitsui Chemicals, Inc. Process for producing blow molded product by blow molding
US20070082998A1 (en) * 2005-10-07 2007-04-12 Mitsui Chemicals, Inc. Process for producing injection molded product
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
US20070100056A1 (en) * 2005-10-31 2007-05-03 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
JP2007161876A (ja) * 2005-12-14 2007-06-28 Mitsui Chemicals Inc オレフィン系重合体およびその製造方法
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
EP1992658A4 (de) * 2006-02-15 2011-04-06 Mitsui Chemicals Inc Spannungsrissbeständigkeitsmodifikator und spannungsrissbeständigkeitsmodifizierte harzzusammensetzung damit
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
EP1995037B1 (de) 2006-03-10 2011-07-06 Mitsui Chemicals, Inc. Verfahren zur herstellung von formteilen durch das aufblasverfahren
US20090166911A1 (en) 2006-03-27 2009-07-02 Mitsui Chemicals, Inc. Process for Producing Molded Article by T-Die Molding
WO2007116709A1 (ja) 2006-03-29 2007-10-18 Mitsui Chemicals, Inc. プロピレン系ランダムブロック共重合体、該共重合体を含む樹脂組成物およびそれからなる成形体
JP2007261201A (ja) 2006-03-29 2007-10-11 Mitsui Chemicals Inc ブロー成形による成形体の製造方法
EP2002955A4 (de) 2006-03-30 2009-09-16 Mitsui Chemicals Inc Verfahren zur herstellung eines geformten objekts durch spritzgiessen
JP4987339B2 (ja) * 2006-04-05 2012-07-25 株式会社プライムポリマー 医療用シリンジ用プロピレン樹脂およびこれを射出成形して得られる医療用シリンジ並びにプレフィルドシリンジ製剤
JP5344909B2 (ja) 2006-04-13 2013-11-20 三井化学株式会社 熱可塑性樹脂組成物、太陽電池封止用シートおよび太陽電池
CN101490168B (zh) 2006-07-31 2012-05-23 三井化学株式会社 太阳能电池密封用热塑性树脂组合物、太阳能电池密封用片材及太阳能电池
US7470759B2 (en) * 2006-07-31 2008-12-30 Fina Technology, Inc. Isotactic-atactic polypropylene and methods of making same
KR101107825B1 (ko) * 2006-08-11 2012-02-08 가부시키가이샤 프라임 폴리머 포장 재료용 프로필렌계 수지 조성물
WO2008026628A1 (fr) 2006-08-31 2008-03-06 Mitsui Chemicals, Inc. Polymère de polyoléfine contenant des groupements vinyle à ses deux extrémités et composition le contenant
JPWO2008059974A1 (ja) 2006-11-17 2010-03-04 三井化学株式会社 シンジオタクティックプロピレン系重合体の製造方法
US7863368B2 (en) 2006-11-17 2011-01-04 Mitsui Chemicals, Inc. Propylene resin composition, process for producing propylene resin composition, propylene polymer composition, shaped article produced of the propylene resin composition, and electric wire
EP2083022A4 (de) * 2006-11-17 2010-12-01 Mitsui Chemicals Inc Verfahren zur herstellung von syndiotaktischem propylenpolymer
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
JP5390194B2 (ja) 2007-01-18 2014-01-15 株式会社プライムポリマー 応力耐久成形体用のプロピレン単独重合体、および該重合体を含む組成物、並びにこれらから得られる応力耐久成形体
US8299188B2 (en) * 2007-05-18 2012-10-30 Fina Technology, Inc. Supported metallocene catalysts
US20080287619A1 (en) * 2007-05-18 2008-11-20 William Gauthier Supported metallocene catalysts
JP2010529253A (ja) 2007-06-04 2010-08-26 エクソンモービル・ケミカル・パテンツ・インク 非常に均一なプロピレンの溶液重合法
US8119553B2 (en) * 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
WO2009041381A1 (ja) * 2007-09-28 2009-04-02 Mitsui Chemicals, Inc. シリンジ用ポリプロピレン樹脂およびこれを原料として得られるシリンジ並びにプレフィルドシリンジ製剤
US7799721B2 (en) 2007-09-28 2010-09-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with high comonomer incorporation
CN105294779A (zh) 2007-11-19 2016-02-03 三井化学株式会社 交联茂金属化合物以及使用其的烯烃聚合用催化剂、以及使用该催化剂得到的乙烯系聚合物
US7468452B1 (en) * 2007-12-12 2008-12-23 Chevron Phillips Chemical Company Lp Process for one-pot synthesis of 1,1-diphenyl-1-(3-substituted-cyclopentadienyl)-1-(2,7-di-t-butyl-fluoren-9-yl)methane type ligands
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN101945942B (zh) * 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
CN103254497B (zh) * 2007-12-20 2015-11-18 埃克森美孚研究工程公司 生产聚丙烯和乙烯-丙烯共聚物的共混物的在线共混方法
WO2009088033A1 (ja) 2008-01-11 2009-07-16 Mitsui Chemicals, Inc. 変性プロピレン樹脂
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
CN102942647B (zh) 2008-01-31 2014-10-01 Lg化学株式会社 胺桥接的茂金属催化剂
EP2241438B1 (de) 2008-02-08 2014-03-26 Mitsui Chemicals, Inc. Film zur verpackung mit wärmesterilisierung
KR101280685B1 (ko) 2008-03-27 2013-07-01 미쓰이 가가쿠 가부시키가이샤 수지 조성물 및 그 용도
CN101981111A (zh) 2008-03-31 2011-02-23 三井化学株式会社 树脂组合物和熔融袋
CN102083914B (zh) 2008-07-10 2015-02-04 三井化学株式会社 4-甲基-1-戊烯类聚合物以及含有4-甲基-1-戊烯类聚合物的树脂组合物及其母料以及它们的成型品
US8765872B2 (en) 2008-07-10 2014-07-01 Mitsui Chemicals, Inc. 4-methyl-1-pentene polymer, resin composition containing 4-methyl-1-pentene polymer, masterbatch thereof, and formed product thereof
US8293856B2 (en) 2008-08-19 2012-10-23 Mitsui Chemicals, Inc. Process for preparing olefin polymer using mixed catalyst
KR101249994B1 (ko) * 2008-09-22 2013-04-03 주식회사 엘지화학 올레핀-실란 공중합체 및 이의 제조방법
WO2010038698A1 (ja) 2008-09-30 2010-04-08 三井化学株式会社 繊維強化樹脂組成物およびその成形体
JP5303264B2 (ja) * 2008-12-25 2013-10-02 三井化学株式会社 １−ブテン系重合体およびその製造方法
JP2010159320A (ja) * 2009-01-06 2010-07-22 Mitsui Chemicals Inc ポリプロピレンシートおよび該シートから得られる成形体
US8916644B2 (en) 2009-01-07 2014-12-23 Toray Battery Separator Film Co., Ltd Polypropylene resin composition for use in formation of microporous membrane
JP5653760B2 (ja) 2009-01-07 2015-01-14 三井化学株式会社 微多孔膜形成用ポリプロピレン樹脂組成物
EP2383300B1 (de) 2009-01-27 2016-10-12 Mitsui Chemicals, Inc. Propylenhomopolymer für kondensatoren
JP5666918B2 (ja) * 2009-01-27 2015-02-12 株式会社カネカ ポリプロピレン系樹脂予備発泡粒子とその製造方法、及びポリプロピレン系樹脂型内発泡成形体
SG174602A1 (en) 2009-03-30 2011-11-28 Mitsui Chemicals Inc Copolymer of olefin and conjugated diene, and process for producing same
WO2010123033A1 (ja) 2009-04-21 2010-10-28 三井化学株式会社 オレフィン重合体の製造方法
KR101154507B1 (ko) 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
JP5807325B2 (ja) 2009-09-30 2015-11-10 住友化学株式会社 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１−ヘキセンの製造方法、エチレン系重合体の製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法
WO2011055803A1 (ja) 2009-11-06 2011-05-12 三井化学株式会社 ４－メチル－１－ペンテン・α－オレフィン共重合体、該共重合体を含む組成物および４－メチル－１－ペンテン共重合体組成物
US8716418B2 (en) 2009-12-21 2014-05-06 Mitsui Chemicals, Inc. Process for producing syndiotactic α-olefin polymer
JP5798113B2 (ja) 2010-04-28 2015-10-21 三井化学株式会社 ４−メチル−１−ペンテン系重合体からなる樹脂微粉末、およびそれを含む組成物、ならびにその製造方法
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
EP2433922A1 (de) 2010-08-25 2012-03-28 Syngenta Participations AG Herstellungsverfahren für Dichlorfulven
EP2631252B1 (de) 2010-10-21 2015-09-09 Mitsui Chemicals, Inc. Verfahren zur herstellung von polymerteilchen auf ethylenbasis und von streckgeformten artikeln aus polymerteilchen auf ethylenbasis
US20120116034A1 (en) 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
CN103210034B (zh) 2010-12-09 2015-09-30 三井化学株式会社 改性聚丙烯组合物及使用了该组合物的层叠体
EP2711380A4 (de) 2011-05-18 2014-11-05 Mitsui Chemicals Inc Propylencopolymer und propylencopolymerzusammensetzung, form und schaumstoff dafür sowie verfahren zur herstellung dieser form und dieses schaumstoffs
EP2740766B1 (de) 2011-08-01 2017-03-01 Mitsui Chemicals, Inc. Thermoplastische harzzusammensetzung für reflektierendes material, reflektierende platte und lichtemittierendes diodenelement
JP5758008B2 (ja) 2011-10-13 2015-08-05 三井化学株式会社 エチレン系共重合体、当該共重合体を含む組成物、及びエチレン系共重合体あるいは組成物からなる成形品並びにフィルム又はシート
WO2013060810A1 (en) * 2011-10-28 2013-05-02 Total Research & Technology Feluy Polypropylene having improved elongational properties
EP2799488B1 (de) 2011-12-27 2016-07-20 Mitsui Chemicals, Inc. 4-methyl-1-penten-(co)polymerzusammensetzung sowie folie und hohlformkörper aus der 4-methyl-1-penten-(co)polymerzusammensetzung
CN104203993B (zh) 2012-03-21 2016-06-15 三井化学株式会社 烯烃聚合物的制造方法
KR101609503B1 (ko) 2012-03-28 2016-04-05 미쓰이 가가쿠 가부시키가이샤 프로필렌·α-올레핀 공중합체 및 그의 용도
EP2842972B1 (de) 2012-04-26 2017-08-30 Mitsui Chemicals, Inc. Verfahren zur herstellung eines olefinpolymers
EP2889133B1 (de) 2012-08-22 2018-03-28 Mitsui Chemicals, Inc. Vliesstofflaminat
US9458261B2 (en) 2012-09-25 2016-10-04 Mitsui Chemicals, Inc. Transition metal compound, olefin polymerization catalyst, and olefin polymer production process
CN104662050B (zh) 2012-09-25 2017-03-22 三井化学株式会社 烯烃聚合物的制造方法及烯烃聚合物
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
EP2921525B1 (de) 2012-11-19 2017-07-19 Mitsui Chemicals, Inc. Polyesterharzzusammensetzung, herstellungsverfahren dafür und kameramodul mit dieser polyesterharzzusammensetzung
JP5805332B2 (ja) 2012-11-30 2015-11-04 三井化学株式会社 光学材料用組成物およびその用途
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
KR101746744B1 (ko) 2013-02-08 2017-06-13 미쓰이 가가쿠 가부시키가이샤 고체상 폴리알루미녹세인 조성물, 올레핀 중합용 촉매, 올레핀 중합체의 제조 방법, 및 고체상 폴리알루미녹세인 조성물의 제조 방법
SG11201507471PA (en) 2013-03-12 2015-10-29 Mitsui Chemicals Inc Production method of olefin polymer and olefin polymerization catalyst
EP2985312B1 (de) 2013-04-12 2017-05-31 Mitsui Chemicals, Inc. Aggregat und zusammensetzung
US10072171B2 (en) 2013-06-07 2018-09-11 Mitsui Chemicals, Inc. Olefin-based paint containing propylene/α-olefin copolymer
JP2016530360A (ja) 2013-07-17 2016-09-29 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒を使用する方法およびそれに由来する生成物
WO2015009473A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9644047B2 (en) 2013-07-17 2017-05-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN105377904B (zh) 2013-07-17 2018-07-10 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
TWI635100B (zh) 2013-11-05 2018-09-11 三井化學股份有限公司 改質丙烯．α－烯烴共聚合體與其製造方法、含有其之塗佈材、成形用樹脂組成物及熱熔性組成物
CN109824809B (zh) 2014-02-13 2022-06-28 三井化学株式会社 乙烯-α-烯烃-非共轭多烯共聚物及其用途
CN106062019B (zh) 2014-02-14 2019-02-26 三井化学株式会社 乙烯-α-烯烃-非共轭多烯共聚物、其制造方法以及用途
CN106133005B (zh) 2014-03-28 2018-08-24 三井化学株式会社 烯烃系树脂及其制造方法
US9944728B2 (en) 2014-09-11 2018-04-17 Mitsui Chemicals, Inc. Production method of olefin (co)polymer containing constituent unit derived from 1-butene
KR101720920B1 (ko) 2014-12-09 2017-03-28 미쯔이가가꾸가부시끼가이샤 프로필렌계 수지 조성물
KR101902139B1 (ko) 2015-03-20 2018-09-28 미쓰이 가가쿠 가부시키가이샤 열가소성 엘라스토머 조성물 및 그의 제조 방법
KR101840993B1 (ko) 2015-03-20 2018-03-21 미쓰이 가가쿠 가부시키가이샤 열가소성 엘라스토머 조성물, 그의 용도, 그의 제조 방법, 에틸렌·α-올레핀·비공액 폴리엔 공중합체 및 그의 용도
KR101913992B1 (ko) 2015-03-31 2018-10-31 미쓰이 가가쿠 가부시키가이샤 수지 조성물 및 그의 용도
US20180320102A1 (en) 2015-11-09 2018-11-08 Mitsui Chemicals, Inc. Viscosity modifier for lubricating oils, additive composition for lubricating oils, and lubricating oil compositions
EP3424705B1 (de) 2016-03-04 2023-03-22 Mitsui Chemicals, Inc. Laminat und anwendung dafür
US11155063B2 (en) 2016-03-25 2021-10-26 Mitsui Chemicals, Inc. Stretchable structure, multilayered stretchable sheet, spun yarn, and fiber structure
WO2018016460A1 (ja) 2016-07-21 2018-01-25 三井化学株式会社 ポリプロピレン系樹脂組成物ならびに単層および多層フィルム
KR102072697B1 (ko) 2016-12-09 2020-02-03 주식회사 엘지화학 가공성 및 기계적 물성이 우수한 에틸렌/1-헥센 공중합체
US11530280B2 (en) 2016-12-15 2022-12-20 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
WO2018108918A1 (en) 2016-12-15 2018-06-21 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
JP6710780B2 (ja) 2016-12-27 2020-06-17 三井化学株式会社 潤滑油組成物、潤滑油用粘度調整剤、および潤滑油用添加剤組成物
CN110234689A (zh) 2017-02-02 2019-09-13 三井化学株式会社 发泡体、聚烯烃系发泡片及复合体
JP6792650B2 (ja) 2017-02-20 2020-11-25 三井化学株式会社 積層体
BR112019017366B1 (pt) 2017-02-20 2023-03-07 Mitsui Chemicals, Inc Laminado, mangueira e método para produzir o referido laminado
US11034782B2 (en) 2017-03-27 2021-06-15 Mitsui Chemicals, Inc. 4-methyl-1-pentene polymer, resin composition and molded article
US11028192B2 (en) * 2017-03-27 2021-06-08 Exxonmobil Chemical Patents Inc. Solution process to make ethylene copolymers
US10442921B2 (en) * 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10442920B2 (en) * 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
EP3698800A4 (de) 2017-10-20 2021-06-02 Mitsui Chemicals, Inc. Kohlendioxid-retardpackung für hautapplikationen und verfahren zur verzögerten freisetzung von kohlendioxid auf der haut
KR102317015B1 (ko) * 2017-11-08 2021-10-26 주식회사 엘지화학 부직포용 호모 폴리프로필렌 수지 및 그의 제조 방법
JP6980092B2 (ja) 2018-03-13 2021-12-15 三井化学株式会社 通気性シート、積層体および複合体
CN111868116B (zh) 2018-03-20 2022-12-09 三井化学株式会社 乙烯-α-烯烃-非共轭多烯共聚物、其制造方法及用途
CN112969726A (zh) 2018-12-04 2021-06-15 三井化学株式会社 含有4-甲基-1-戊烯共聚物的树脂组合物及电容器用膜
KR102382131B1 (ko) * 2018-12-11 2022-04-01 한화솔루션 주식회사 폴리올레핀 및 이의 제조 방법
WO2020184421A1 (ja) 2019-03-12 2020-09-17 三井化学株式会社 オレフィン系樹脂、その架橋物およびそれらの製造方法
WO2020189676A1 (ja) 2019-03-19 2020-09-24 三井化学株式会社 プロピレン系樹脂組成物、成形体およびプロピレン重合体
JP7340597B2 (ja) 2019-03-28 2023-09-07 三井・ダウポリケミカル株式会社 シーラント用樹脂組成物、積層体、包装材及び包装容器
KR102580620B1 (ko) 2019-03-29 2023-09-19 미쓰이 가가쿠 가부시키가이샤 수지 조성물
CN111484573A (zh) * 2019-06-04 2020-08-04 安徽敦茂新材料科技有限公司 一种烯烃聚合催化剂的合成方法
BR112022002330A2 (pt) 2019-08-08 2022-04-19 Mitsui Chemicals Inc Composição de polímero de propileno e artigo modelado
JP7223862B2 (ja) 2019-08-29 2023-02-16 三井化学株式会社 潤滑油組成物
WO2021070811A1 (ja) 2019-10-07 2021-04-15 三井化学株式会社 エチレン・α－オレフィン共重合体組成物およびその用途
CN114651044B (zh) 2019-11-15 2024-02-20 三井化学株式会社 树脂组合物和成型体
KR102579816B1 (ko) * 2019-11-18 2023-09-19 한화솔루션 주식회사 올레핀계 중합체 및 그 제조방법
KR20220123062A (ko) 2020-01-30 2022-09-05 미쓰이 가가쿠 가부시키가이샤 폴리아마이드 조성물
CN115298279B (zh) 2020-03-19 2024-01-09 三井化学株式会社 自粘着片
EP4129670A4 (de) 2020-03-27 2024-03-13 Mitsui Chemicals Inc Mehrschichtkörper, walzkörper damit und verpackung
WO2021201112A1 (ja) 2020-03-31 2021-10-07 三井化学株式会社 組成物および成形体
WO2022050208A1 (ja) 2020-09-01 2022-03-10 三井化学株式会社 樹脂組成物および成形体
WO2022158511A1 (ja) 2021-01-25 2022-07-28 三井化学株式会社 樹脂組成物および成形体
WO2022186044A1 (ja) 2021-03-02 2022-09-09 三井化学株式会社 ４－メチル－１－ペンテン重合体
WO2022186208A1 (ja) 2021-03-02 2022-09-09 三井化学株式会社 多層フィルム、容器、細胞培養用パック及び多層フィルムの製造方法
CN115677879A (zh) * 2021-07-31 2023-02-03 华为技术有限公司 环烯烃共聚物制备用催化剂、环烯烃共聚物的制备方法、环烯烃共聚物及其应用
CN115819656A (zh) * 2021-09-16 2023-03-21 华为技术有限公司 环烯烃共聚物及其制备方法和应用
WO2023054440A1 (ja) 2021-09-30 2023-04-06 三井化学株式会社 潤滑油組成物

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2182929T3 (es) * 1991-03-09 2003-03-16 Basell Polyolefine Gmbh Metaloceno y catalizador.
JPH0559077A (ja) 1991-08-28 1993-03-09 Mitsui Toatsu Chem Inc 新規遷移金属化合物
US6245870B1 (en) * 1992-03-20 2001-06-12 Fina Technology, Inc. Process for producing syndiotactic/isotactic block polyolefins
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
TW274100B (de) * 1993-02-12 1996-04-11 Hoechst Ag
DE69426043T3 (de) * 1993-06-07 2015-06-18 Mitsui Chemicals, Inc. Polypropylen
US5498581A (en) 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
JP3628772B2 (ja) * 1994-12-06 2005-03-16 三井化学株式会社 ポリプロピレン組成物
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
WO1997011775A2 (de) * 1995-09-28 1997-04-03 Targor Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
JP2000507499A (ja) 1996-03-29 2000-06-20 ザ・ダウ・ケミカル・カンパニー メタロセン用共触媒
WO1997040075A1 (fr) * 1996-04-22 1997-10-30 Japan Polyolefins Co., Ltd. Procede de production de polyolefine et catalyseur approprie
JP2000514494A (ja) 1996-07-16 2000-10-31 エクソン・ケミカル・パテンツ・インク アルキル置換されたメタロセンでのオレフィン重合法
JP3320619B2 (ja) 1996-10-02 2002-09-03 三井化学株式会社 新規メタロセン化合物とそれを用いたオレフィンまたはジエンの重合方法
DE69734508T2 (de) * 1996-11-29 2006-08-10 Chisso Corp. Fasern und daraus hergestellte faserige formmassen
US5753785A (en) * 1996-12-16 1998-05-19 Fina Technology, Inc. Production of E-B copolymers with a single metallocene catalyst and a single monomer
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
JPH10265527A (ja) * 1997-03-25 1998-10-06 Idemitsu Kosan Co Ltd プロピレン重合体
DE19719103A1 (de) * 1997-05-06 1998-11-12 Targor Gmbh Stereorigide Metallocenverbindung
EP0881236A1 (de) * 1997-05-26 1998-12-02 Fina Research S.A. Mettallocen-Katalysatorkomponente zur Herstellung von isotaktischen Polyolefinen
US6184317B1 (en) * 1997-07-14 2001-02-06 The Board Of Trustees Of The Leland Stanford Jr. University Catalysts and processes for the synthesis of alternating ethylene/α-olefin copolymers, and isotactic copolymers thereof
TW482770B (en) * 1997-08-15 2002-04-11 Chisso Corp Propylene/ethylene random copolymer, molding material, and molded article
JP3675619B2 (ja) * 1997-09-26 2005-07-27 出光興産株式会社 高立体規則性ポリプロピレン
JP3845187B2 (ja) * 1997-12-11 2006-11-15 三菱化学株式会社 プロピレン系重合体
EP0965603A1 (de) * 1998-06-19 1999-12-22 Fina Research S.A. Polyolefinherstellung
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
JP4864176B2 (ja) * 1999-02-19 2012-02-01 トータル・ペトロケミカルズ・リサーチ・フエリユイ ポリオレフィン製造
US6515086B1 (en) * 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
GB0522766D0 (en) 2005-11-08 2005-12-14 Dupont Teijin Films Us Ltd Polymeric film packaging

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