DE60038900D1 - Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren - Google Patents
Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatorenInfo
- Publication number
- DE60038900D1 DE60038900D1 DE60038900T DE60038900T DE60038900D1 DE 60038900 D1 DE60038900 D1 DE 60038900D1 DE 60038900 T DE60038900 T DE 60038900T DE 60038900 T DE60038900 T DE 60038900T DE 60038900 D1 DE60038900 D1 DE 60038900D1
- Authority
- DE
- Germany
- Prior art keywords
- olefin polymers
- prepared
- contractor
- ionic catalysts
- preparing polyolefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1386—Natural or synthetic rubber or rubber-like compound containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31696—Including polyene monomers [e.g., butadiene, etc.]
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17273799P | 1999-12-20 | 1999-12-20 | |
| PCT/US2000/034706 WO2001046273A1 (en) | 1999-12-20 | 2000-12-20 | Processes for the preparation polyolefin resins using supported ionic catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60038900D1 true DE60038900D1 (de) | 2008-06-26 |
Family
ID=22629002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60038900T Expired - Lifetime DE60038900D1 (de) | 1999-12-20 | 2000-12-20 | Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US6590055B2 (de) |
| EP (1) | EP1250362B1 (de) |
| JP (1) | JP2003518169A (de) |
| KR (1) | KR20020063242A (de) |
| CN (2) | CN1631910A (de) |
| AT (1) | ATE395368T1 (de) |
| BR (1) | BR0016495A (de) |
| CA (1) | CA2393327A1 (de) |
| DE (1) | DE60038900D1 (de) |
| MX (1) | MXPA02006197A (de) |
| WO (1) | WO2001046273A1 (de) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE395368T1 (de) | 1999-12-20 | 2008-05-15 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren |
| US6818013B2 (en) * | 2001-06-14 | 2004-11-16 | Cordis Corporation | Intravascular stent device |
| US7511104B2 (en) | 2001-06-20 | 2009-03-31 | Exxonmobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
| DE10163154A1 (de) * | 2001-12-20 | 2003-07-03 | Basell Polyolefine Gmbh | Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation |
| US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| EP1539841B1 (de) * | 2002-09-20 | 2012-08-01 | ExxonMobil Chemical Patents Inc. | Herstellung von polymeren unter überkritischen bedingungen |
| US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US7439312B2 (en) | 2002-10-24 | 2008-10-21 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7144934B2 (en) * | 2002-10-24 | 2006-12-05 | Dow Global Technologies Inc. | Charge dissipation modifiers for olefinic interpolymer compositions |
| US7339018B2 (en) | 2002-12-05 | 2008-03-04 | Exxonmobil Chemical Patents Inc. | Diene-modified propylene copolymers |
| AU2003287683A1 (en) * | 2002-12-05 | 2004-06-30 | Exxonmobil Chemical Patents Inc. | High temperature bulk polymerization of branched crystalline polypropylene |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| US7741420B2 (en) | 2004-07-14 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
| US7662895B2 (en) * | 2005-11-22 | 2010-02-16 | Exxonmobil Chemical Patents Inc. | Syndiotactic propylene elastomers |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
| US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
| ES2446294T3 (es) * | 2007-06-04 | 2014-03-07 | Exxonmobil Chemical Patents Inc. | Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución |
| EP2201042B1 (de) * | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line-mischen von weichmachern mit einem basispolymer |
| EP2195349B1 (de) | 2007-09-13 | 2012-07-11 | ExxonMobil Research and Engineering Company | In-line-verfahren zur herstellung von weichgemachten polymeren und weichgemachten polymerblends |
| US7910679B2 (en) | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
| US8138269B2 (en) | 2007-12-20 | 2012-03-20 | Exxonmobil Research And Engineering Company | Polypropylene ethylene-propylene copolymer blends and in-line process to produce them |
| CN101945942B (zh) * | 2007-12-20 | 2012-08-08 | 埃克森美孚研究工程公司 | 生产粒料稳定的聚烯烃的在线方法 |
| US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US7939610B2 (en) | 2008-05-22 | 2011-05-10 | Exxonmobil Research And Engineering Company | Polymerization processes for broadened molecular weight distribution |
| US8399586B2 (en) | 2008-09-05 | 2013-03-19 | Exxonmobil Research And Engineering Company | Process for feeding ethylene to polymerization reactors |
| US8765217B2 (en) * | 2008-11-04 | 2014-07-01 | Entrotech, Inc. | Method for continuous production of (meth)acrylate syrup and adhesives therefrom |
| US20100113692A1 (en) * | 2008-11-04 | 2010-05-06 | Mcguire Jr James E | Apparatus for Continuous Production of Partially Polymerized Compositions |
| US8329079B2 (en) * | 2009-04-20 | 2012-12-11 | Entrochem, Inc. | Method and apparatus for continuous production of partially polymerized compositions and polymers therefrom |
| US8562915B2 (en) | 2010-01-14 | 2013-10-22 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
| WO2011087731A1 (en) * | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| WO2021086468A1 (en) * | 2019-10-28 | 2021-05-06 | Exxonmobil Chemical Patents Inc. | Supported non-coordinating anion activators, use thereof, and production thereof |
| US20240018283A1 (en) * | 2020-11-24 | 2024-01-18 | Lg Chem, Ltd. | Organic-inorganic hybrid polyolefin composite and preparation method thereof |
Family Cites Families (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4414369A (en) | 1977-08-17 | 1983-11-08 | Nippon Oil Company, Limited | Continuous process for the preparation of polyolefins having widely distributed molecular weights |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5153282A (en) | 1987-06-08 | 1992-10-06 | Exxon Chemical Patents Inc. | Preparation of polyolefin incorporating functional groups from masked functional group-containing monomers |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| CN1038284A (zh) | 1988-04-29 | 1989-12-27 | 联合碳化公司 | 高纯度α-烯烃聚合物的制备方法 |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE3831355A1 (de) | 1988-09-15 | 1990-03-29 | Hoechst Ag | Hochleistungsdielektrikumsfolie mit verbesserter thermostabilitaet |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP3131218B2 (ja) | 1989-12-06 | 2001-01-31 | トランスウィッチ・コーポレーション | 波形整形トランスバーサルフィルタ |
| ATE186918T1 (de) | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
| BR9106589A (pt) | 1990-06-22 | 1993-06-01 | Exxon Chemical Patents Inc | Catalisadores de monociclopentadienil metaloceno isentos de aluminio para a polimerizacao de olefinas |
| ATE135358T1 (de) | 1990-12-27 | 1996-03-15 | Exxon Chemical Patents Inc | Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen |
| EP0516458B2 (de) | 1991-05-31 | 2007-12-19 | Mitsui Chemicals, Inc. | Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation |
| DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5246783A (en) | 1991-08-15 | 1993-09-21 | Exxon Chemical Patents Inc. | Electrical devices comprising polymeric insulating or semiconducting members |
| TW300901B (de) | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| JP3394997B2 (ja) | 1991-10-15 | 2003-04-07 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特異的に置換されたインデニル配位子を持つメタロセンを用いてオレフィンポリマーを製造する方法 |
| ES2108861T3 (es) | 1991-11-25 | 1998-01-01 | Exxon Chemical Patents Inc | Composiciones cataliticas polionicas de metales de transicion. |
| DE69232297T2 (de) | 1992-01-06 | 2002-08-14 | Dow Chemical Co | Katalysatorzusammensetzung |
| WO1993019103A1 (en) | 1992-03-16 | 1993-09-30 | Exxon Chemical Patents Inc. | IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY |
| EP0578838A1 (de) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung |
| US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
| US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
| DE69332811T2 (de) | 1992-07-01 | 2004-01-29 | Exxonmobil Chem Patents Inc | Auf Übergangsmetallen der Gruppen 5 und 6 basierende Katalysator-Vorläufer |
| CA2141814A1 (en) | 1992-08-05 | 1994-02-17 | David Jonathan Upton | Supported ionic transition metal catalysts for olefin polymerization |
| JP3202349B2 (ja) | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
| EP0591756B1 (de) | 1992-09-22 | 1998-11-25 | Idemitsu Kosan Company Limited | Polymerisationskatalysatore und Verfahren zur Herstellung von Polymeren |
| US5635573A (en) | 1992-12-01 | 1997-06-03 | Exxon Chemical Patents Inc. | Method for preparing alpha-olefin/cycloolefin copolymers |
| US5837787A (en) | 1993-01-19 | 1998-11-17 | Exxon Chemical Patents, Inc. | Process for producing elastic thermoplastic α-olefin/cyclic olefin copolymers |
| DE4304310A1 (de) | 1993-02-12 | 1994-08-18 | Hoechst Ag | Teilkristalline Cycloolefin-Copolymer-Folie |
| FR2701938B1 (fr) | 1993-02-23 | 1995-05-24 | Cuir Jean Pierre | Dispositif de distribution de feuilles semi-rigides, notamment de carton, à partir d'un empilement. |
| DE9302594U1 (de) | 1993-02-23 | 1993-04-15 | Alten, Kurt, 3015 Wennigsen, De | |
| KR100190268B1 (ko) | 1993-04-26 | 1999-06-01 | 에인혼 해롤드 | 유동상에서 단량체를 중합시키는 방법 |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| EP0638593A1 (de) | 1993-08-02 | 1995-02-15 | Shell Internationale Researchmaatschappij B.V. | Katalysatorzusammensetzungen |
| GB9319340D0 (en) | 1993-09-17 | 1993-11-03 | Exxon Chemical Patents Inc | Olefin polymersisation process |
| WO1995016716A1 (en) | 1993-12-14 | 1995-06-22 | Exxon Chemical Patents Inc. | Process for producing elastomers with an indenyl metallocene catalyst system |
| US5491207A (en) | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| US6403307B1 (en) | 1997-03-21 | 2002-06-11 | University Of Iowa Research Foundation | Glaucoma therapeutics and diagnostics |
| ATE208404T1 (de) * | 1994-08-03 | 2001-11-15 | Exxonmobil Chem Patents Inc | Ionische katalysatorzusammensetzung auf träger |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| EP0708117B1 (de) | 1994-10-03 | 1999-08-11 | Sumitomo Chemical Company Limited | Verfahren zur Herstellung eines Copolymerkautschuks |
| US6506866B2 (en) * | 1994-11-17 | 2003-01-14 | Dow Global Technologies Inc. | Ethylene copolymer compositions |
| US5939347A (en) | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
| EP0728773B1 (de) | 1995-02-21 | 1998-11-04 | Mitsubishi Chemical Corporation | Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren |
| US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| US6143682A (en) | 1995-06-07 | 2000-11-07 | Exxon Chemical Patents Inc. | Bimetallocyclic transition metal catalyst systems |
| US5900466A (en) | 1995-09-08 | 1999-05-04 | Shell Oil Company | Polyolefin-substituted dicarboxylic derivatives |
| US5767208A (en) | 1995-10-20 | 1998-06-16 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| DK0863919T3 (da) * | 1995-11-27 | 2000-12-11 | Grace W R & Co | Understøttet katalysator indeholdende en tøjret, kationdannende aktivator |
| WO1997022639A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
| US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
| JPH103277A (ja) | 1996-04-15 | 1998-01-06 | Matsushita Electric Works Ltd | 表示装置 |
| US5763556A (en) | 1996-05-21 | 1998-06-09 | Exxon Chemical Patents Inc. | Copolymers of ethylene and geminally disubstituted olefins |
| EP0906343B1 (de) | 1996-06-17 | 2001-04-18 | Exxon Chemical Patents Inc. | Olefinpolymerisationkatalysatorsysteme von gemischten übergangsmetalen |
| BR9710511A (pt) | 1996-07-23 | 1999-08-17 | Dow Chemical Co | Composi-Æo de catalisador e processo para polimeriza-Æo de mon-meros polimeriz veis por adi-Æo |
| DE69714022T2 (de) | 1996-08-09 | 2002-11-28 | Toray Industries | Polypropylenfolie und kondensator hergestellt durch verwendung derselben als dielektrikum |
| US5763533A (en) | 1996-12-10 | 1998-06-09 | Exxon Chemical Patents Inc. | Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers |
| US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
| US5851945A (en) | 1997-02-07 | 1998-12-22 | Exxon Chemical Patents Inc. | Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state |
| US6100354A (en) | 1997-02-24 | 2000-08-08 | Exxon Chemical Patents Inc. | Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds |
| US6228795B1 (en) * | 1997-06-05 | 2001-05-08 | Exxon Chemical Patents, Inc. | Polymeric supported catalysts |
| US5770022A (en) | 1997-06-05 | 1998-06-23 | Dow Corning Corporation | Method of making silica nanoparticles |
| US6100214A (en) * | 1997-06-05 | 2000-08-08 | Exxon Chemical Patents Inc. | Polymeric supported catalysts for olefin polymerization |
| FR2764895B1 (fr) | 1997-06-19 | 2000-02-11 | Toray Plastics Europ Sa | Films barriere composites metallises |
| GB2343388B (en) | 1997-08-20 | 2001-10-31 | Implico Bv | Catalytic convertor |
| WO1999030822A1 (en) | 1997-12-16 | 1999-06-24 | Exxon Research And Engineering Company | Group 11 transition metal amine catalysts for olefin polymerization |
| CN1133660C (zh) | 1998-03-04 | 2004-01-07 | 埃克森美孚化学专利公司 | 烯烃的高温聚合方法 |
| CA2321712C (en) | 1998-05-01 | 2008-03-18 | Exxon Chemical Patents, Inc. | Tridentate ligand-containing metal catalyst complexes for olefin polymerization |
| US6403773B1 (en) | 1998-09-30 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Cationic group 3 catalyst system |
| ATE395368T1 (de) | 1999-12-20 | 2008-05-15 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren |
-
2000
- 2000-12-20 AT AT00986633T patent/ATE395368T1/de not_active IP Right Cessation
- 2000-12-20 KR KR1020027007884A patent/KR20020063242A/ko not_active Application Discontinuation
- 2000-12-20 BR BR0016495-0A patent/BR0016495A/pt not_active IP Right Cessation
- 2000-12-20 MX MXPA02006197A patent/MXPA02006197A/es not_active Application Discontinuation
- 2000-12-20 US US09/745,232 patent/US6590055B2/en not_active Expired - Fee Related
- 2000-12-20 CN CNA2004100973341A patent/CN1631910A/zh active Pending
- 2000-12-20 EP EP00986633A patent/EP1250362B1/de not_active Expired - Lifetime
- 2000-12-20 WO PCT/US2000/034706 patent/WO2001046273A1/en active Application Filing
- 2000-12-20 US US09/742,762 patent/US6562920B2/en not_active Expired - Fee Related
- 2000-12-20 CA CA002393327A patent/CA2393327A1/en not_active Abandoned
- 2000-12-20 CN CNB008174067A patent/CN1227272C/zh not_active Expired - Fee Related
- 2000-12-20 DE DE60038900T patent/DE60038900D1/de not_active Expired - Lifetime
- 2000-12-20 JP JP2001547180A patent/JP2003518169A/ja not_active Withdrawn
-
2003
- 2003-05-28 US US10/446,320 patent/US7163993B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20020063242A (ko) | 2002-08-01 |
| CN1631910A (zh) | 2005-06-29 |
| EP1250362A1 (de) | 2002-10-23 |
| ATE395368T1 (de) | 2008-05-15 |
| US6590055B2 (en) | 2003-07-08 |
| CA2393327A1 (en) | 2001-06-28 |
| US20020007030A1 (en) | 2002-01-17 |
| CN1411473A (zh) | 2003-04-16 |
| US7163993B2 (en) | 2007-01-16 |
| US20030208023A1 (en) | 2003-11-06 |
| MXPA02006197A (es) | 2002-12-09 |
| BR0016495A (pt) | 2002-09-17 |
| US20020004567A1 (en) | 2002-01-10 |
| US6562920B2 (en) | 2003-05-13 |
| JP2003518169A (ja) | 2003-06-03 |
| WO2001046273A1 (en) | 2001-06-28 |
| EP1250362B1 (de) | 2008-05-14 |
| CN1227272C (zh) | 2005-11-16 |
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