DE602005019629D1 - Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierung - Google Patents
Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierungInfo
- Publication number
- DE602005019629D1 DE602005019629D1 DE602005019629T DE602005019629T DE602005019629D1 DE 602005019629 D1 DE602005019629 D1 DE 602005019629D1 DE 602005019629 T DE602005019629 T DE 602005019629T DE 602005019629 T DE602005019629 T DE 602005019629T DE 602005019629 D1 DE602005019629 D1 DE 602005019629D1
- Authority
- DE
- Germany
- Prior art keywords
- substituted
- metal atom
- olefin polymerization
- compound
- producing substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63666204P | 2004-12-16 | 2004-12-16 | |
PCT/US2005/045140 WO2006065844A2 (en) | 2004-12-16 | 2005-12-14 | Process for producing substituted metallocene compounds for olefin polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
DE602005019629D1 true DE602005019629D1 (de) | 2010-04-08 |
Family
ID=34982508
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE602005019629T Active DE602005019629D1 (de) | 2004-12-16 | 2005-12-14 | Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierung |
Country Status (5)
Country | Link |
---|---|
US (4) | US7709670B2 (de) |
EP (3) | EP1866322B1 (de) |
AT (1) | ATE458742T1 (de) |
DE (1) | DE602005019629D1 (de) |
WO (4) | WO2006065844A2 (de) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
US8058371B2 (en) | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US8178636B2 (en) | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
WO2006065844A2 (en) * | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Process for producing substituted metallocene compounds for olefin polymerization |
EP1858934B1 (de) * | 2005-03-18 | 2013-04-24 | Basell Polyolefine GmbH | Metallocen-verbindungen |
BRPI0613343A2 (pt) * | 2005-06-13 | 2011-01-04 | Basell Polyolefine Gmbh | processo para a copolimerização de propileno |
DE102005055866A1 (de) * | 2005-11-23 | 2007-05-24 | Hte Ag The High Throughput Experimentation Company | Verfahren zur Herstellung von Aryl-Aryl gekoppelter Verbindungen |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US20080287619A1 (en) * | 2007-05-18 | 2008-11-20 | William Gauthier | Supported metallocene catalysts |
EP2215129A2 (de) | 2007-08-27 | 2010-08-11 | Borealis Technology OY | Katalysatoren |
WO2009054831A1 (en) * | 2007-10-25 | 2009-04-30 | Novolen Technology Holdings, C.V. | Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
EP2070953A1 (de) | 2007-12-11 | 2009-06-17 | Total Petrochemicals Research Feluy | Träger zur Aktivierung auf der Basis von Phosphoniumkomplexen |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
EP2223944A1 (de) | 2009-02-26 | 2010-09-01 | Borealis AG | Verfahren zur Herstellung von Semikristallin-Propylenpolymeren |
US8058461B2 (en) | 2010-03-01 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Mono-indenyl transition metal compounds and polymerization therewith |
PL2646425T3 (pl) | 2010-12-01 | 2015-12-31 | Boehringer Ingelheim Int | Kwasy indanyloksydihydrobenzofuranylooctowe użyteczne do leczenia zespołu metabolicznego |
EP2663400A4 (de) | 2011-01-14 | 2014-07-30 | Grace W R & Co | Verfahren zur herstellung eines modifizierten metallocenkatalysators, in diesem verfahren hergestellter katalysator und verwendung davon |
KR101212637B1 (ko) | 2011-06-09 | 2012-12-14 | 에스케이종합화학 주식회사 | 신규한 사이클로펜타[b]플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
US8664461B2 (en) * | 2012-03-19 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Catalysts for producing polyalpha-olefins and processes related thereto |
JP6051738B2 (ja) * | 2012-03-29 | 2016-12-27 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
JP6015306B2 (ja) * | 2012-09-28 | 2016-10-26 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
WO2014070655A1 (en) * | 2012-10-31 | 2014-05-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems and methods of preparation thereof |
EP3539993A1 (de) | 2013-07-17 | 2019-09-18 | ExxonMobil Chemical Patents Inc. | Cyclopropyl-substituierte metallocenkatalysatoren |
CN105555811B (zh) | 2013-09-30 | 2018-01-02 | 株式会社Lg化学 | 聚丙烯的制备方法和由此获得的聚丙烯 |
JP6182443B2 (ja) * | 2013-12-06 | 2017-08-16 | 日本ポリエチレン株式会社 | 架橋ビスインデニル化合物の製造方法 |
US9315526B2 (en) | 2014-03-03 | 2016-04-19 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
GB201406406D0 (en) * | 2014-04-09 | 2014-05-21 | Isis Innovation | Lactide polymerisation |
EP2933275A1 (de) * | 2014-04-17 | 2015-10-21 | Borealis AG | Neues Katalysatorsystem zur Herstellung von Polyethylen-Copolymeren in einem Hochtemperaturlösungspolymerisationsverfahren |
CN106459278B (zh) * | 2014-04-17 | 2020-11-06 | 博里利斯股份公司 | 用于以高温溶液聚合法制备聚乙烯共聚物的经改善的催化剂体系 |
JP6593178B2 (ja) * | 2015-01-30 | 2019-10-23 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
KR101910701B1 (ko) | 2015-07-02 | 2018-10-22 | 주식회사 엘지화학 | 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
JP6787188B2 (ja) | 2016-03-04 | 2020-11-18 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
KR102117650B1 (ko) * | 2016-03-14 | 2020-06-01 | 주식회사 엘지화학 | 올레핀 중합체 및 이의 제조 방법 |
US9803037B1 (en) | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
WO2018132247A2 (en) * | 2017-01-13 | 2018-07-19 | Exxonmobil Chemical Patents Inc. | Bridged bis(indenyl) transitional metal complexes, production, and use thereof |
US10807998B2 (en) | 2017-01-13 | 2020-10-20 | Exxonmobil Chemical Patents Inc. | Bridged bis(indenyl) transitional metal complexes, production, and use thereof |
JP7223540B2 (ja) | 2017-09-27 | 2023-02-16 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
JP7248404B2 (ja) | 2017-09-27 | 2023-03-29 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
KR102317015B1 (ko) | 2017-11-08 | 2021-10-26 | 주식회사 엘지화학 | 부직포용 호모 폴리프로필렌 수지 및 그의 제조 방법 |
WO2019093789A1 (ko) * | 2017-11-08 | 2019-05-16 | 주식회사 엘지화학 | 부직포용 호모 폴리프로필렌 수지 및 그의 제조 방법 |
JP2020050615A (ja) * | 2018-09-27 | 2020-04-02 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
KR102584267B1 (ko) * | 2019-09-30 | 2023-10-05 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리에틸렌 공중합체의 제조 방법 |
US20220162353A1 (en) * | 2019-09-30 | 2022-05-26 | Lg Chem, Ltd. | Hybrid Supported Metallocene Catalyst and Process for Preparing Polyethylene Copolymer Using the Same |
US11186665B2 (en) * | 2019-10-04 | 2021-11-30 | Chevron Phillips Chemical Company Lp | Catalyst composition and method for preparing polyethylene |
CN114008084B (zh) * | 2019-11-01 | 2024-04-12 | 株式会社Lg化学 | 生产茂金属负载型催化剂的方法和茂金属负载型催化剂 |
CN114702531A (zh) * | 2021-01-01 | 2022-07-05 | 中国石油化工股份有限公司 | 茂金属、含有其的催化剂及其合成和应用 |
CN114702532A (zh) * | 2021-01-01 | 2022-07-05 | 中国石油化工股份有限公司 | 一种茂金属、含有其的催化剂及其合成和应用 |
CN112939756B (zh) * | 2021-03-03 | 2022-07-08 | 上海鼎素精细化工有限公司 | 一种制备5-氯茚酮的改进工艺方法 |
US11859041B2 (en) * | 2021-08-16 | 2024-01-02 | Chevron Phillips Chemical Company Lp | Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts |
CN116410238A (zh) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | 含硫手性桥联茂金属化合物及其制备和应用 |
CN115232175A (zh) * | 2022-08-17 | 2022-10-25 | 山东清河化工科技有限公司 | 一种含氟准c2对称硅桥联茂金属配合物及其应用 |
Family Cites Families (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US582195A (en) * | 1897-05-11 | Machine for working wood or metal | ||
US577581A (en) * | 1897-02-23 | Chain-protector and dust-guard for bicycles | ||
US1995A (en) * | 1841-03-03 | Latch of door and other locks | ||
US41815A (en) * | 1864-03-01 | Improvement in the preparation of a phosphate of lime for culinary and other purposes | ||
US628566A (en) * | 1898-12-05 | 1899-07-11 | Martin Vay | Rotary engine. |
US666267A (en) * | 1899-10-27 | 1901-01-22 | Leschen & Sons Rope Company A | Tramway-terminal. |
US693502A (en) * | 1901-07-26 | 1902-02-18 | Benjamin G Devoe | Oil-burner. |
US882078A (en) * | 1907-06-24 | 1908-03-17 | William A Prindle | Potato-masher. |
US3678088A (en) | 1971-02-24 | 1972-07-18 | Us Air Force | Polychlorinated metallocenes and their synthesis |
DE3443087A1 (de) | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US4794096A (en) | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5571880A (en) | 1991-05-09 | 1996-11-05 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process |
US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5434116A (en) | 1992-06-05 | 1995-07-18 | Tosoh Corporation | Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
TW294669B (de) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
ES2153368T3 (es) | 1992-08-03 | 2001-03-01 | Targor Gmbh | Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos especiales. |
JP3293927B2 (ja) | 1993-02-19 | 2002-06-17 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
EP0812854B2 (de) | 1993-06-07 | 2011-04-20 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens |
EP0638593A1 (de) | 1993-08-02 | 1995-02-15 | Shell Internationale Researchmaatschappij B.V. | Katalysatorzusammensetzungen |
JPH07216011A (ja) | 1994-02-03 | 1995-08-15 | Mitsui Petrochem Ind Ltd | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法 |
US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
EP0693502B1 (de) | 1994-07-22 | 1997-11-05 | Mitsubishi Chemical Corporation | Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben |
WO1996004317A1 (fr) | 1994-08-02 | 1996-02-15 | Idemitsu Kosan Co., Ltd. | Compose de metal de transition, catalyseur de polymerisation d'olefine, polymere d'olefine obtenu au moyen du catalyseur et procede de production du polymere |
JPH08127612A (ja) | 1994-10-27 | 1996-05-21 | Idemitsu Kosan Co Ltd | 遷移金属化合物、それを含有するオレフィン重合用触媒、その触媒を用いたオレフィン系重合体、およびそのオレフィン系重合体の製造方法。 |
JPH08301914A (ja) | 1995-04-28 | 1996-11-19 | Mitsui Petrochem Ind Ltd | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分 |
IT1275408B (it) | 1995-05-30 | 1997-08-05 | Spherilene Spa | Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
US5786291A (en) | 1996-02-23 | 1998-07-28 | Exxon Chemical Patents, Inc. | Engineered catalyst systems and methods for their production and use |
US6465700B1 (en) | 1997-02-05 | 2002-10-15 | Boulder Scientific Company | Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst ligands |
US6075171A (en) | 1997-02-05 | 2000-06-13 | Boulder Scientific Company | 2-substituted 7-haloindenes and methods for synthesizing |
US6451938B1 (en) | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
JP4812913B2 (ja) | 1997-03-07 | 2011-11-09 | バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 置換インダノンの製造方法 |
JPH111508A (ja) | 1997-06-13 | 1999-01-06 | Mitsubishi Chem Corp | α−オレフィン重合用触媒成分、触媒およびα−オレフィン重合体の製造法 |
JP3952549B2 (ja) | 1997-08-12 | 2007-08-01 | 三井化学株式会社 | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分 |
JPH1180183A (ja) | 1997-09-10 | 1999-03-26 | Denki Kagaku Kogyo Kk | 重合用金属化合物及びそれを用いた芳香族ビニル化合物−オレフィン共重合体の製造方法 |
KR100274973B1 (ko) | 1997-11-24 | 2000-12-15 | 성재갑 | 올레핀계 단량체의 중합 촉매 |
JP3845187B2 (ja) | 1997-12-11 | 2006-11-15 | 三菱化学株式会社 | プロピレン系重合体 |
US6291699B1 (en) | 1999-08-24 | 2001-09-18 | Boulder Scientific Company | 2-alkyl-4-(2,6-dialkylphenyl) indenes |
US6414095B1 (en) | 2000-06-30 | 2002-07-02 | Exxon Mobil Chemical Patents Inc. | Metallocene compositions |
US6399723B1 (en) | 2000-06-30 | 2002-06-04 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
US6541583B2 (en) | 2001-05-17 | 2003-04-01 | Equistar Chemicals, Lp | Polypropylene preparation |
US7074863B2 (en) | 2001-06-22 | 2006-07-11 | Borealis Technology Oy | Metallocene catalysts containing an idenyl moiety substituted at the 4,-5,-6- or 7-position by a siloxy or germyloxy group |
US6727329B2 (en) | 2001-07-23 | 2004-04-27 | Dow Global Technology Inc. | Salts of lewis acid/acid adducts and catalyst activators therefrom |
JP2005510590A (ja) * | 2001-11-27 | 2005-04-21 | バセル ポリオレフィン ジーエムビーエイチ | ポリマー組成物の処理の方法 |
DE10158656A1 (de) | 2001-11-30 | 2003-06-26 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
WO2003050131A1 (en) | 2001-12-10 | 2003-06-19 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
US20060052620A1 (en) | 2002-04-10 | 2006-03-09 | Schulte Jorg L | Preparation of substituted indenes |
US6737487B2 (en) | 2002-07-30 | 2004-05-18 | Equistar Chemicals, Lp | Polyolefin block copolymers |
EP1549688A2 (de) | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Verfahren zur copolymerisation von ethylen |
US6683150B1 (en) | 2002-12-19 | 2004-01-27 | Equistar Chemicals, Lp | High molecular weight polypropylene process |
US6930156B2 (en) | 2003-10-22 | 2005-08-16 | Equistar Chemicals, Lp | Polymer bound single-site catalysts |
WO2005105864A1 (en) | 2004-04-16 | 2005-11-10 | Exxonmobil Chemical Patents Inc. | Heterocyclic substituted metallocene compounds for olefin polymerization |
US7214747B2 (en) | 2004-04-23 | 2007-05-08 | Exxonmobil Chemical Patents Inc. | Phosphorus substituted metallocene compounds for olefin polymerization |
WO2005108435A1 (en) | 2004-04-23 | 2005-11-17 | Exxonmobil Chemical Patents Inc. | Phosphorus bridged metallocene compounds for olefin polymerization |
WO2006065844A2 (en) | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Process for producing substituted metallocene compounds for olefin polymerization |
US7538168B2 (en) | 2005-12-14 | 2009-05-26 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
US7763562B2 (en) | 2005-12-14 | 2010-07-27 | Exxonmobil Chemical Patents Inc. | Heteroatom bridged metallocene compounds for olefin polymerization |
US7550544B2 (en) | 2005-12-14 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
US7667064B2 (en) | 2005-12-14 | 2010-02-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
US7910783B2 (en) | 2005-12-14 | 2011-03-22 | Exxonmobil Chemical Patents Inc. | Preparation of substituted bridged indenyl and related ligands |
-
2005
- 2005-12-14 WO PCT/US2005/045140 patent/WO2006065844A2/en active Application Filing
- 2005-12-14 US US11/302,997 patent/US7709670B2/en not_active Expired - Fee Related
- 2005-12-14 WO PCT/US2005/045138 patent/WO2006065843A2/en active Application Filing
- 2005-12-14 US US11/300,032 patent/US7557171B2/en not_active Expired - Fee Related
- 2005-12-14 EP EP05853949A patent/EP1866322B1/de not_active Not-in-force
- 2005-12-14 DE DE602005019629T patent/DE602005019629D1/de active Active
- 2005-12-14 WO PCT/US2005/045245 patent/WO2006065906A2/en active Application Filing
- 2005-12-14 EP EP05849844A patent/EP1833858A2/de not_active Withdrawn
- 2005-12-14 AT AT05853949T patent/ATE458742T1/de not_active IP Right Cessation
- 2005-12-14 WO PCT/US2005/045056 patent/WO2006065809A2/en active Application Filing
- 2005-12-14 EP EP05853948A patent/EP1833859A2/de not_active Withdrawn
- 2005-12-14 US US11/300,054 patent/US7446216B2/en active Active
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2009
- 2009-12-17 US US12/641,123 patent/US9163046B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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EP1866322A2 (de) | 2007-12-19 |
US20060160968A1 (en) | 2006-07-20 |
US7709670B2 (en) | 2010-05-04 |
EP1833859A2 (de) | 2007-09-19 |
WO2006065906A3 (en) | 2007-02-22 |
EP1833858A2 (de) | 2007-09-19 |
WO2006065809A3 (en) | 2006-09-28 |
WO2006065809A2 (en) | 2006-06-22 |
WO2006065843A3 (en) | 2006-12-07 |
ATE458742T1 (de) | 2010-03-15 |
US20060160967A1 (en) | 2006-07-20 |
US9163046B2 (en) | 2015-10-20 |
WO2006065844A2 (en) | 2006-06-22 |
WO2006065906A2 (en) | 2006-06-22 |
US20060183874A1 (en) | 2006-08-17 |
US20100113717A1 (en) | 2010-05-06 |
EP1866322B1 (de) | 2010-02-24 |
US7557171B2 (en) | 2009-07-07 |
WO2006065843A2 (en) | 2006-06-22 |
WO2006065844A3 (en) | 2007-05-18 |
US7446216B2 (en) | 2008-11-04 |
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