DE60226868D1 - Verfahren zum entfernen von halogenen von nicht-zeolitischen molekularsiebkatalysatoren - Google Patents
Verfahren zum entfernen von halogenen von nicht-zeolitischen molekularsiebkatalysatorenInfo
- Publication number
- DE60226868D1 DE60226868D1 DE60226868T DE60226868T DE60226868D1 DE 60226868 D1 DE60226868 D1 DE 60226868D1 DE 60226868 T DE60226868 T DE 60226868T DE 60226868 T DE60226868 T DE 60226868T DE 60226868 D1 DE60226868 D1 DE 60226868D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- conversion
- oxygenates
- zeolitic molecular
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 5
- 229910052736 halogen Inorganic materials 0.000 title abstract 3
- 150000002367 halogens Chemical class 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates (SAPO compounds)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/891,674 US6440894B1 (en) | 2001-06-25 | 2001-06-25 | Methods of removing halogen from non-zeolitic molecular sieve catalysts |
| PCT/US2002/013489 WO2003000411A1 (en) | 2001-06-25 | 2002-05-01 | Hydrocarbon conversion processes using non-zeolitic molecular sieve catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60226868D1 true DE60226868D1 (de) | 2008-07-10 |
Family
ID=25398632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60226868T Expired - Fee Related DE60226868D1 (de) | 2001-06-25 | 2002-05-01 | Verfahren zum entfernen von halogenen von nicht-zeolitischen molekularsiebkatalysatoren |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US6440894B1 (de) |
| EP (1) | EP1401572B1 (de) |
| JP (1) | JP4362363B2 (de) |
| KR (1) | KR100854899B1 (de) |
| CN (3) | CN100512961C (de) |
| AT (1) | ATE396786T1 (de) |
| AU (1) | AU2002314760B2 (de) |
| CA (1) | CA2450005C (de) |
| DE (1) | DE60226868D1 (de) |
| NO (1) | NO20035733L (de) |
| WO (1) | WO2003000411A1 (de) |
| ZA (2) | ZA200309696B (de) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
| US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| WO2003004444A1 (en) * | 2001-07-02 | 2003-01-16 | Exxonmobil Chemical Patents Inc. | Inhibiting catalyst coke formation in the manufacture of an olefin |
| US7271123B2 (en) * | 2002-03-20 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion process |
| US6872680B2 (en) * | 2002-03-20 | 2005-03-29 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
| US6897179B2 (en) * | 2003-06-13 | 2005-05-24 | Exxonmobil Chemical Patents Inc. | Method of protecting SAPO molecular sieve from loss of catalytic activity |
| US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| WO2005021468A1 (en) | 2003-07-15 | 2005-03-10 | Grt, Inc. | Hydrocarbon synthesis |
| WO2005025744A1 (en) * | 2003-09-05 | 2005-03-24 | Exxonmobil Chemical Patents Inc. | Processes for formulating catalyst compositions having desirable particle size characteristics |
| US7125821B2 (en) * | 2003-09-05 | 2006-10-24 | Exxonmobil Chemical Patents Inc. | Low metal content catalyst compositions and processes for making and using same |
| US7241713B2 (en) | 2003-10-02 | 2007-07-10 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
| US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
| US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| CN100569370C (zh) * | 2005-01-31 | 2009-12-16 | 埃克森美孚化学专利公司 | 分子筛催化剂组合物，其制备和在转化方法中的应用 |
| US7498475B2 (en) | 2005-02-25 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Molecular sieve mixtures for olefin formation |
| CN101395088B (zh) | 2006-02-03 | 2012-04-04 | Grt公司 | 轻气体与卤素的分离方法 |
| UA95276C2 (ru) | 2006-02-03 | 2011-07-25 | ДжиАрТи, ИНК. | Непрерывный процесс преобразования углеводного сырья в один или более высших углеводородов (варианты) |
| JP5777339B2 (ja) * | 2007-04-26 | 2015-09-09 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ | 遷移金属／ゼオライトｓｃｒ触媒 |
| MX2009012581A (es) | 2007-05-24 | 2010-03-15 | Grt Inc | Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible. |
| US8815764B2 (en) * | 2007-08-31 | 2014-08-26 | Uop Llc | Water treated catalyst to produce light olefins |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| AU2009270801B2 (en) | 2008-07-18 | 2014-04-24 | Reaction 35, Llc | Continuous process for converting natural gas to liquid hydrocarbons |
| CN102481555B (zh) | 2009-06-12 | 2015-10-07 | 阿尔比马尔欧洲有限公司 | Sapo分子筛催化剂及其制备和用途 |
| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
| EP2531276A4 (de) | 2010-02-04 | 2014-07-02 | Ada Es Inc | Verfahren und system zur steuerung von quecksilber-emissionen in durch kohle angetriebenen wärmeverfahren |
| US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| WO2011112854A1 (en) | 2010-03-10 | 2011-09-15 | Ada Environmental Solutions, Llc | Process for dilute phase injection or dry alkaline materials |
| US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
| EP2580177A1 (de) | 2010-06-14 | 2013-04-17 | Dow Global Technologies LLC | Umwandlung von methylamin in olefin oder olefingemische |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| US9017452B2 (en) | 2011-11-14 | 2015-04-28 | ADA-ES, Inc. | System and method for dense phase sorbent injection |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| JP5883328B2 (ja) * | 2012-03-28 | 2016-03-15 | 花王株式会社 | オレフィンの製造方法 |
| US8883099B2 (en) | 2012-04-11 | 2014-11-11 | ADA-ES, Inc. | Control of wet scrubber oxidation inhibitor and byproduct recovery |
| US8974756B2 (en) | 2012-07-25 | 2015-03-10 | ADA-ES, Inc. | Process to enhance mixing of dry sorbents and flue gas for air pollution control |
| US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
| CN104718025B (zh) | 2012-10-15 | 2017-05-10 | 三菱瓦斯化学株式会社 | 甲胺类制造用催化剂的制造方法和甲胺类的制造方法 |
| US10350545B2 (en) | 2014-11-25 | 2019-07-16 | ADA-ES, Inc. | Low pressure drop static mixing system |
| CN109701631B (zh) * | 2017-10-26 | 2021-10-01 | 中国石油化工股份有限公司 | 由合成气直接制低碳烃的催化剂及其用途方法 |
| CN108751217A (zh) * | 2018-09-05 | 2018-11-06 | 中国科学院上海高等研究院 | 一种常压制备纳米sapo-34分子筛的方法 |
| CN112283712B (zh) * | 2020-10-21 | 2021-07-27 | 深圳市捷晶能源科技有限公司 | 一种含氯含溴固体废物热解系统 |
| CN113277530B (zh) * | 2021-06-08 | 2022-10-21 | 深圳技术大学 | 一种铌掺杂AlPO-31分子筛晶体及其制备方法 |
| CN113717748B (zh) * | 2021-11-02 | 2022-02-08 | 山东百联化工有限公司 | 一种石脑油裂解装置 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3130065A1 (de) * | 1981-07-30 | 1983-02-17 | Bayer Ag, 5090 Leverkusen | Verfahren zur regeneration von katalysatoren |
| US4914067A (en) * | 1983-05-02 | 1990-04-03 | Uop | Catalytic cracking catalysts and cracking process using mixed catalyst system |
| US4859314A (en) * | 1983-05-02 | 1989-08-22 | Uop | Catalytic cracking catalysts and cracking process using non-zeolitic molecular sieves |
| US5776849A (en) | 1983-11-10 | 1998-07-07 | Exxon Research & Engineering Company | Regeneration of severely deactivated reforming catalysts |
| US4818739A (en) * | 1984-12-18 | 1989-04-04 | Uop | Hydrocracking catalysts and processes employing non-zeolitic molecular sieves |
| US4681864A (en) | 1985-07-15 | 1987-07-21 | W. R. Grace & Co. | Cracking catalyst |
| US4973792A (en) | 1987-07-07 | 1990-11-27 | Uop | Chemical conversion process |
| CA1315300C (en) * | 1987-07-07 | 1993-03-30 | William Howard Henstock | Chemical conversion process |
| US4861938A (en) * | 1987-07-07 | 1989-08-29 | Uop | Chemical conversion process |
| US4973972A (en) * | 1989-09-07 | 1990-11-27 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Adminstration | Stripline feed for a microstrip array of patch elements with teardrop shaped probes |
| US5248647A (en) | 1991-02-28 | 1993-09-28 | Uop | Sapo catalysts and use thereof in methanol conversion processes |
| US5095163A (en) | 1991-02-28 | 1992-03-10 | Uop | Methanol conversion process using SAPO catalysts |
| US5346875A (en) | 1993-07-21 | 1994-09-13 | Exxon Research And Engineering Company | Method of manufacturing fluid catalytic cracking catalyst |
| EP0768117B1 (de) | 1995-04-27 | 2002-06-26 | Nippon Sanso Corporation | Kohlenartiges adsorbens, verfahren zu dessen herstellung und methode und vorrichtung zur gastrennung |
| US5939349A (en) * | 1996-01-26 | 1999-08-17 | Chevron U.S.A. Inc. | Method of preparing non-zeolitic molecular sieve catalyst |
| CN1223601A (zh) * | 1996-05-29 | 1999-07-21 | 埃克森化学专利公司 | 烃转化催化剂及其应用 |
| JP3501265B2 (ja) | 1997-10-30 | 2004-03-02 | 富士通株式会社 | 半導体装置の製造方法 |
| US6153552A (en) | 1997-10-29 | 2000-11-28 | Exxon Chemical Patents Inc. | Methods for making catalysts |
| WO1999021651A1 (en) * | 1997-10-29 | 1999-05-06 | Exxon Chemical Patents Inc. | Method for making catalysts containing silicoaluminophosphate molecular sieve and catalyst thus prepared |
| US5980731A (en) | 1997-11-07 | 1999-11-09 | Exxon Chemical Patents Inc. | Naphtha reforming catalyst and process |
-
2001
- 2001-06-25 US US09/891,674 patent/US6440894B1/en not_active Expired - Lifetime
-
2002
- 2002-05-01 CN CNB028126971A patent/CN100512961C/zh not_active Expired - Lifetime
- 2002-05-01 EP EP02741684A patent/EP1401572B1/de not_active Expired - Lifetime
- 2002-05-01 CA CA2450005A patent/CA2450005C/en not_active Expired - Fee Related
- 2002-05-01 CN CN2009101511272A patent/CN101607210B/zh not_active Expired - Lifetime
- 2002-05-01 AU AU2002314760A patent/AU2002314760B2/en not_active Ceased
- 2002-05-01 KR KR1020037016908A patent/KR100854899B1/ko not_active IP Right Cessation
- 2002-05-01 WO PCT/US2002/013489 patent/WO2003000411A1/en active Application Filing
- 2002-05-01 DE DE60226868T patent/DE60226868D1/de not_active Expired - Fee Related
- 2002-05-01 AT AT02741684T patent/ATE396786T1/de not_active IP Right Cessation
- 2002-05-01 JP JP2003507045A patent/JP4362363B2/ja not_active Expired - Lifetime
- 2002-06-10 US US10/166,422 patent/US7151199B2/en not_active Expired - Lifetime
- 2002-06-24 CN CNB2006100940648A patent/CN100446859C/zh not_active Expired - Lifetime
-
2003
- 2003-12-12 ZA ZA200309696A patent/ZA200309696B/en unknown
- 2003-12-12 ZA ZA200309697A patent/ZA200309697B/xx unknown
- 2003-12-19 NO NO20035733A patent/NO20035733L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1895780A (zh) | 2007-01-17 |
| CN101607210A (zh) | 2009-12-23 |
| AU2002314760B2 (en) | 2007-12-06 |
| JP4362363B2 (ja) | 2009-11-11 |
| WO2003000411A1 (en) | 2003-01-03 |
| US6440894B1 (en) | 2002-08-27 |
| EP1401572B1 (de) | 2008-05-28 |
| ZA200309696B (en) | 2004-06-09 |
| CN1520337A (zh) | 2004-08-11 |
| US7151199B2 (en) | 2006-12-19 |
| ZA200309697B (en) | 2004-05-12 |
| CN101607210B (zh) | 2013-04-10 |
| CA2450005A1 (en) | 2003-01-03 |
| NO20035733L (no) | 2004-02-23 |
| ATE396786T1 (de) | 2008-06-15 |
| KR20040012975A (ko) | 2004-02-11 |
| CA2450005C (en) | 2010-11-09 |
| CN100512961C (zh) | 2009-07-15 |
| NO20035733D0 (no) | 2003-12-19 |
| JP2004535435A (ja) | 2004-11-25 |
| KR100854899B1 (ko) | 2008-08-28 |
| CN100446859C (zh) | 2008-12-31 |
| EP1401572A1 (de) | 2004-03-31 |
| US20030032848A1 (en) | 2003-02-13 |
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