DE69115455T2 - ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMEN - Google Patents
ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMENInfo
- Publication number
- DE69115455T2 DE69115455T2 DE69115455T DE69115455T DE69115455T2 DE 69115455 T2 DE69115455 T2 DE 69115455T2 DE 69115455 T DE69115455 T DE 69115455T DE 69115455 T DE69115455 T DE 69115455T DE 69115455 T2 DE69115455 T2 DE 69115455T2
- Authority
- DE
- Germany
- Prior art keywords
- sox
- clays
- removal
- gas flows
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/553,254 US5219536A (en) | 1990-07-16 | 1990-07-16 | Composite clay materials for removal of sox from gas streams |
PCT/US1991/003644 WO1992001509A1 (en) | 1990-07-16 | 1991-05-28 | COMPOSITE CLAY MATERIALS FOR REMOVAL OF SOx FROM GAS STREAMS |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69115455D1 DE69115455D1 (de) | 1996-01-25 |
DE69115455T2 true DE69115455T2 (de) | 1996-05-02 |
Family
ID=24208742
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69115455T Expired - Fee Related DE69115455T2 (de) | 1990-07-16 | 1991-05-28 | ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMEN |
Country Status (14)
Country | Link |
---|---|
US (2) | US5219536A (de) |
EP (1) | EP0491931B1 (de) |
JP (1) | JPH0620540B2 (de) |
KR (1) | KR950008192B1 (de) |
CN (1) | CN1125157A (de) |
AT (1) | ATE131414T1 (de) |
CA (1) | CA2065026C (de) |
DE (1) | DE69115455T2 (de) |
DK (1) | DK0491931T3 (de) |
ES (1) | ES2083586T3 (de) |
GR (1) | GR3018686T3 (de) |
MX (1) | MX9100166A (de) |
MY (1) | MY106358A (de) |
WO (1) | WO1992001509A1 (de) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5334564A (en) * | 1990-07-16 | 1994-08-02 | Board Of Trustees Operating Michigan State University | Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams |
US5225384A (en) * | 1990-07-16 | 1993-07-06 | Board Of Trustees Operating Michigan State University | Composite clay materials for removal of sox from gas streams |
US5234877A (en) * | 1990-07-16 | 1993-08-10 | Board Of Trustees Operating Michigan State University | Composite clay materials for removal of SOx from gas streams |
US5298473A (en) * | 1990-07-16 | 1994-03-29 | Board Of Trustees Operating Michigan State University | Hydrated lime clay composites for the removal of SOx from flue gas streams |
DE4220950A1 (de) * | 1992-06-26 | 1994-01-05 | Metallgesellschaft Ag | Verfahren zur Abscheidung von HF, HCl, SO¶2¶, SO¶3¶ und/oder H¶2¶S aus Gasen |
US5415850A (en) * | 1993-02-24 | 1995-05-16 | The Research Foundation Of State Univeristy Of New York | Pillared interlayered clay catalysts for the selective reduction of nitrogen oxides with ammonia |
DE4417837A1 (de) * | 1994-05-20 | 1995-11-23 | Basf Ag | Substituierte 3-Phenylpyrazole |
DE69907915T2 (de) | 1998-06-30 | 2004-01-15 | Eastman Chem Co | Die herstellung von glykolmonoester |
US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
FR2814533B1 (fr) * | 2000-09-27 | 2002-10-31 | Alstom Power Nv | Procede pour reduire simultanement les emissions de co2 de so2 dans une installation de combustion |
WO2005055356A1 (ja) * | 2003-12-03 | 2005-06-16 | Matsushita Electric Industrial Co., Ltd. | 燃料電池システム |
WO2006006978A1 (en) | 2004-06-28 | 2006-01-19 | Nox Ii International, Ltd. | Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels |
PL1872054T5 (pl) | 2005-03-17 | 2022-08-16 | Nox Ii International, Ltd. | Zmniejszenie emisji rtęci w spalinach ze spalania węgla |
CA3174527A1 (en) | 2005-03-17 | 2006-09-21 | Nox Ii, Ltd. | Reducing mercury emissions from the burning of coal |
US7531154B2 (en) * | 2005-08-18 | 2009-05-12 | Solvay Chemicals | Method of removing sulfur dioxide from a flue gas stream |
US7481987B2 (en) * | 2005-09-15 | 2009-01-27 | Solvay Chemicals | Method of removing sulfur trioxide from a flue gas stream |
US8150776B2 (en) * | 2006-01-18 | 2012-04-03 | Nox Ii, Ltd. | Methods of operating a coal burning facility |
US20070184394A1 (en) * | 2006-02-07 | 2007-08-09 | Comrie Douglas C | Production of cementitious ash products with reduced carbon emissions |
MX2010001267A (es) * | 2007-08-02 | 2010-07-30 | Benthamite Company Llc | Composicion, produccion y uso de particulas sorbentes para la desulfuracion de gas de chimenea. |
CN101445250B (zh) * | 2008-12-05 | 2011-06-01 | 山东师范大学 | 一种有机物与无机物复合体及其制备方法 |
ES2336636B1 (es) * | 2009-10-14 | 2010-11-24 | Universidad De Cantabria | Procedimiento para la obtencion de un sorbente captador de so2. |
CN107866141A (zh) | 2010-02-04 | 2018-04-03 | Ada-Es股份有限公司 | 控制从烧煤的热工艺释放汞的方法和系统 |
US11298657B2 (en) | 2010-10-25 | 2022-04-12 | ADA-ES, Inc. | Hot-side method and system |
US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
WO2011112854A1 (en) | 2010-03-10 | 2011-09-15 | Ada Environmental Solutions, Llc | Process for dilute phase injection or dry alkaline materials |
CN101792617B (zh) * | 2010-03-15 | 2013-01-02 | 湖南博深实业有限公司 | 一种用于pp填充的碳酸钙/蒙脱土纳米复合粒子及其制备方法 |
US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
US9017452B2 (en) | 2011-11-14 | 2015-04-28 | ADA-ES, Inc. | System and method for dense phase sorbent injection |
US10532313B2 (en) | 2012-03-30 | 2020-01-14 | Rheinkalk Gmbh | Activation of a material containing alkaline-earth metal carbonate and alkaline-earth metal hydroxide for the dry scrubbing of flue gas |
PL2644267T5 (pl) | 2012-03-30 | 2021-05-31 | Rheinkalk Gmbh | Aktywacja materiału zawierającego węglan metalu ziem alkalicznych i wodorotlenek metalu ziem alkalicznych do suchego oczyszczania gazu spalinowego |
US8883099B2 (en) | 2012-04-11 | 2014-11-11 | ADA-ES, Inc. | Control of wet scrubber oxidation inhibitor and byproduct recovery |
US8974756B2 (en) | 2012-07-25 | 2015-03-10 | ADA-ES, Inc. | Process to enhance mixing of dry sorbents and flue gas for air pollution control |
US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
DE112014001316T5 (de) * | 2013-03-13 | 2015-12-31 | Novinda Corporation | Mehrkomponenten-Zusammensetzungen zur Entfernung von Quecksilber |
US10350545B2 (en) | 2014-11-25 | 2019-07-16 | ADA-ES, Inc. | Low pressure drop static mixing system |
PL3850270T3 (pl) * | 2018-09-14 | 2023-02-20 | Minplus B.V. | Metoda eksploatacji spalarni obejmująca urządzenie do wychwytywania popiołu wprowadzanego przez gaz spalinowy |
CN114011234A (zh) * | 2021-11-10 | 2022-02-08 | 山东鲁碧建材有限公司 | 一种处理低温烟气的干法脱硫方法 |
CN115779850A (zh) * | 2022-11-01 | 2023-03-14 | 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 | 石粉硅基材料、制备方法以及应用 |
CN115999499A (zh) * | 2022-12-27 | 2023-04-25 | 国家电投集团远达环保工程有限公司 | 一种用于脱除烟气中so3的吸附剂及其制备方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1346349A (en) * | 1916-09-21 | 1920-07-13 | John C Tate | Absorbing and purifying composition |
US1657440A (en) * | 1920-04-24 | 1928-01-24 | Catalpo Ltd | Process of hydrolysis, particularly the splitting of oils and fats |
US2352932A (en) * | 1942-04-03 | 1944-07-04 | Elliott P Barrett | Adsorbent |
JPS5584537A (en) * | 1978-12-20 | 1980-06-25 | Mitsubishi Heavy Ind Ltd | Preparing adsorbent for hydrogen sulfide |
SU947043A1 (ru) * | 1980-05-27 | 1982-07-30 | Грузинский Ордена Ленина И Ордена Трудового Красного Знамени Политехнический Институт Им.В.И.Ленина | Способ получени газопоглотительной массы |
US4316813A (en) * | 1980-08-04 | 1982-02-23 | Engelhard Minerals & Chemicals Corp. | Limestone-based sorbent agglomerates for removal of sulfur compounds in hot gases and method of making |
US4387653A (en) * | 1980-08-04 | 1983-06-14 | Engelhard Corporation | Limestone-based sorbent agglomerates for removal of sulfur compounds in hot gases and method of making |
US4419273A (en) * | 1981-11-04 | 1983-12-06 | Chevron Research Company | Clay-based sulfur sorbent |
US4731233A (en) * | 1986-01-09 | 1988-03-15 | Thompson Richard E | Method and composition for utilizing lime-urea hydrates to simultaneously reduce NOx and SOx in combustion effluents |
US4804521A (en) * | 1986-11-07 | 1989-02-14 | Board Of Regents, The University Of Texas System | Process for removing sulfur from sulfur-containing gases |
US4866019A (en) * | 1987-01-13 | 1989-09-12 | Akzo N.V. | Catalyst composition and absorbent which contain an anionic clay |
US4904627A (en) * | 1987-03-13 | 1990-02-27 | Uop | Alkaline earth metal spinel/kaolin clays and processes for making |
US4830840A (en) * | 1987-03-13 | 1989-05-16 | Uop | Process for removing sulfur oxide and nitrogen oxide |
JPH0655257B2 (ja) * | 1988-12-05 | 1994-07-27 | 三菱重工業株式会社 | 乾式排ガス処理方法 |
US4981825A (en) * | 1989-09-12 | 1991-01-01 | Board Of Trustees Operating Michigan State University | Dried metal oxide and clay particle compositions and method for the preparation thereof |
-
1990
- 1990-07-16 US US07/553,254 patent/US5219536A/en not_active Expired - Fee Related
-
1991
- 1991-05-17 MY MYPI91000836A patent/MY106358A/en unknown
- 1991-05-28 JP JP3513034A patent/JPH0620540B2/ja not_active Expired - Lifetime
- 1991-05-28 AT AT91913738T patent/ATE131414T1/de not_active IP Right Cessation
- 1991-05-28 EP EP91913738A patent/EP0491931B1/de not_active Expired - Lifetime
- 1991-05-28 KR KR1019920700546A patent/KR950008192B1/ko not_active IP Right Cessation
- 1991-05-28 DE DE69115455T patent/DE69115455T2/de not_active Expired - Fee Related
- 1991-05-28 DK DK91913738.0T patent/DK0491931T3/da active
- 1991-05-28 ES ES91913738T patent/ES2083586T3/es not_active Expired - Lifetime
- 1991-05-28 CA CA002065026A patent/CA2065026C/en not_active Expired - Fee Related
- 1991-05-28 WO PCT/US1991/003644 patent/WO1992001509A1/en active IP Right Grant
- 1991-06-24 US US07/719,987 patent/US5126300A/en not_active Expired - Lifetime
- 1991-07-11 MX MX9100166A patent/MX9100166A/es unknown
-
1995
- 1995-05-30 CN CN95105635A patent/CN1125157A/zh active Pending
-
1996
- 1996-01-17 GR GR960400087T patent/GR3018686T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2083586T3 (es) | 1996-04-16 |
US5219536A (en) | 1993-06-15 |
US5126300A (en) | 1992-06-30 |
WO1992001509A1 (en) | 1992-02-06 |
JPH04504979A (ja) | 1992-09-03 |
KR950008192B1 (ko) | 1995-07-26 |
DE69115455D1 (de) | 1996-01-25 |
JPH0620540B2 (ja) | 1994-03-23 |
CN1125157A (zh) | 1996-06-26 |
CA2065026C (en) | 1998-04-14 |
ATE131414T1 (de) | 1995-12-15 |
GR3018686T3 (en) | 1996-04-30 |
DK0491931T3 (da) | 1996-03-04 |
CA2065026A1 (en) | 1992-01-17 |
MY106358A (en) | 1995-05-30 |
EP0491931A4 (en) | 1993-05-26 |
EP0491931A1 (de) | 1992-07-01 |
MX9100166A (es) | 1992-02-28 |
EP0491931B1 (de) | 1995-12-13 |
KR920702251A (ko) | 1992-09-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |