DE69115455T2 - ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMEN - Google Patents

ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMEN

Info

Publication number
DE69115455T2
DE69115455T2 DE69115455T DE69115455T DE69115455T2 DE 69115455 T2 DE69115455 T2 DE 69115455T2 DE 69115455 T DE69115455 T DE 69115455T DE 69115455 T DE69115455 T DE 69115455T DE 69115455 T2 DE69115455 T2 DE 69115455T2
Authority
DE
Germany
Prior art keywords
sox
clays
removal
gas flows
base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69115455T
Other languages
English (en)
Other versions
DE69115455D1 (de
Inventor
Thomas Pinnavaia
Christine Polansky
Jayantha Amarasekera
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michigan State University MSU
Original Assignee
Michigan State University MSU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michigan State University MSU filed Critical Michigan State University MSU
Publication of DE69115455D1 publication Critical patent/DE69115455D1/de
Application granted granted Critical
Publication of DE69115455T2 publication Critical patent/DE69115455T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE69115455T 1990-07-16 1991-05-28 ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMEN Expired - Fee Related DE69115455T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/553,254 US5219536A (en) 1990-07-16 1990-07-16 Composite clay materials for removal of sox from gas streams
PCT/US1991/003644 WO1992001509A1 (en) 1990-07-16 1991-05-28 COMPOSITE CLAY MATERIALS FOR REMOVAL OF SOx FROM GAS STREAMS

Publications (2)

Publication Number Publication Date
DE69115455D1 DE69115455D1 (de) 1996-01-25
DE69115455T2 true DE69115455T2 (de) 1996-05-02

Family

ID=24208742

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69115455T Expired - Fee Related DE69115455T2 (de) 1990-07-16 1991-05-28 ZUSAMMENGESETZTE TONE ZUM ENTFERNEN VON SOx AUS GASSTRÖMEN

Country Status (14)

Country Link
US (2) US5219536A (de)
EP (1) EP0491931B1 (de)
JP (1) JPH0620540B2 (de)
KR (1) KR950008192B1 (de)
CN (1) CN1125157A (de)
AT (1) ATE131414T1 (de)
CA (1) CA2065026C (de)
DE (1) DE69115455T2 (de)
DK (1) DK0491931T3 (de)
ES (1) ES2083586T3 (de)
GR (1) GR3018686T3 (de)
MX (1) MX9100166A (de)
MY (1) MY106358A (de)
WO (1) WO1992001509A1 (de)

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US5234877A (en) * 1990-07-16 1993-08-10 Board Of Trustees Operating Michigan State University Composite clay materials for removal of SOx from gas streams
US5334564A (en) * 1990-07-16 1994-08-02 Board Of Trustees Operating Michigan State University Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams
US5225384A (en) * 1990-07-16 1993-07-06 Board Of Trustees Operating Michigan State University Composite clay materials for removal of sox from gas streams
US5298473A (en) * 1990-07-16 1994-03-29 Board Of Trustees Operating Michigan State University Hydrated lime clay composites for the removal of SOx from flue gas streams
DE4220950A1 (de) * 1992-06-26 1994-01-05 Metallgesellschaft Ag Verfahren zur Abscheidung von HF, HCl, SO¶2¶, SO¶3¶ und/oder H¶2¶S aus Gasen
US5415850A (en) * 1993-02-24 1995-05-16 The Research Foundation Of State Univeristy Of New York Pillared interlayered clay catalysts for the selective reduction of nitrogen oxides with ammonia
DE4417837A1 (de) 1994-05-20 1995-11-23 Basf Ag Substituierte 3-Phenylpyrazole
CN1314826A (zh) 1998-06-30 2001-09-26 伊斯曼化学公司 用于生产二元醇—酯的碱性粘土催化剂
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
FR2814533B1 (fr) * 2000-09-27 2002-10-31 Alstom Power Nv Procede pour reduire simultanement les emissions de co2 de so2 dans une installation de combustion
US20070104983A1 (en) * 2003-12-03 2007-05-10 Hidenobu Wakita Fuel cell system
CA2571471C (en) 2004-06-28 2014-07-08 Nox Ii International, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
CN103759249A (zh) 2005-03-17 2014-04-30 Noxii国际有限公司 降低煤燃烧中的汞排放量
RU2494793C2 (ru) 2005-03-17 2013-10-10 НОКС II ИНТЕНЭШНЛ, эЛТиДи. Способ сжигания ртутьсодержащего топлива (варианты), способ снижения количества выброса ртути, способ сжигания угля с уменьшенным уровнем выброса вредных элементов в окружающую среду, способ уменьшения содержания ртути в дымовых газах
US7531154B2 (en) * 2005-08-18 2009-05-12 Solvay Chemicals Method of removing sulfur dioxide from a flue gas stream
US7481987B2 (en) * 2005-09-15 2009-01-27 Solvay Chemicals Method of removing sulfur trioxide from a flue gas stream
US8150776B2 (en) * 2006-01-18 2012-04-03 Nox Ii, Ltd. Methods of operating a coal burning facility
US20070184394A1 (en) * 2006-02-07 2007-08-09 Comrie Douglas C Production of cementitious ash products with reduced carbon emissions
MX2010001267A (es) * 2007-08-02 2010-07-30 Benthamite Company Llc Composicion, produccion y uso de particulas sorbentes para la desulfuracion de gas de chimenea.
CN101445250B (zh) * 2008-12-05 2011-06-01 山东师范大学 一种有机物与无机物复合体及其制备方法
ES2336636B1 (es) * 2009-10-14 2010-11-24 Universidad De Cantabria Procedimiento para la obtencion de un sorbente captador de so2.
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
EP4019114A1 (de) 2010-02-04 2022-06-29 ADA-ES, Inc. Verfahren und system zur steuerung von quecksilber-emissionen in durch kohle angetriebenen wärmeverfahren
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
WO2011112854A1 (en) 2010-03-10 2011-09-15 Ada Environmental Solutions, Llc Process for dilute phase injection or dry alkaline materials
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
CN101792617B (zh) * 2010-03-15 2013-01-02 湖南博深实业有限公司 一种用于pp填充的碳酸钙/蒙脱土纳米复合粒子及其制备方法
US8845986B2 (en) 2011-05-13 2014-09-30 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
US10532313B2 (en) 2012-03-30 2020-01-14 Rheinkalk Gmbh Activation of a material containing alkaline-earth metal carbonate and alkaline-earth metal hydroxide for the dry scrubbing of flue gas
DK2644267T4 (da) 2012-03-30 2021-04-12 Rheinkalk Gmbh Aktivering af et materiale, der indeholder jordalkalicarbonat og jordalkalihydroxid, til tør røggasrensning
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
US9957454B2 (en) 2012-08-10 2018-05-01 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
CN105307751A (zh) * 2013-03-13 2016-02-03 诺文达集团公司 用于去除汞的多组分组合物
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system
CA3102921A1 (en) * 2018-09-14 2020-03-19 Minplus B.V. A method of operating an incinerator comprising a device for capturing ash entrained by flue gas
CN114011234B (zh) * 2021-11-10 2024-04-23 山东鲁碧建材有限公司 一种处理低温烟气的干法脱硫方法
CN115779850A (zh) * 2022-11-01 2023-03-14 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 石粉硅基材料、制备方法以及应用
CN115999499A (zh) * 2022-12-27 2023-04-25 国家电投集团远达环保工程有限公司 一种用于脱除烟气中so3的吸附剂及其制备方法

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US1346349A (en) * 1916-09-21 1920-07-13 John C Tate Absorbing and purifying composition
US1657440A (en) * 1920-04-24 1928-01-24 Catalpo Ltd Process of hydrolysis, particularly the splitting of oils and fats
US2352932A (en) * 1942-04-03 1944-07-04 Elliott P Barrett Adsorbent
JPS5584537A (en) * 1978-12-20 1980-06-25 Mitsubishi Heavy Ind Ltd Preparing adsorbent for hydrogen sulfide
SU947043A1 (ru) * 1980-05-27 1982-07-30 Грузинский Ордена Ленина И Ордена Трудового Красного Знамени Политехнический Институт Им.В.И.Ленина Способ получени газопоглотительной массы
US4316813A (en) * 1980-08-04 1982-02-23 Engelhard Minerals & Chemicals Corp. Limestone-based sorbent agglomerates for removal of sulfur compounds in hot gases and method of making
US4387653A (en) * 1980-08-04 1983-06-14 Engelhard Corporation Limestone-based sorbent agglomerates for removal of sulfur compounds in hot gases and method of making
US4419273A (en) * 1981-11-04 1983-12-06 Chevron Research Company Clay-based sulfur sorbent
US4731233A (en) * 1986-01-09 1988-03-15 Thompson Richard E Method and composition for utilizing lime-urea hydrates to simultaneously reduce NOx and SOx in combustion effluents
US4804521A (en) * 1986-11-07 1989-02-14 Board Of Regents, The University Of Texas System Process for removing sulfur from sulfur-containing gases
US4866019A (en) * 1987-01-13 1989-09-12 Akzo N.V. Catalyst composition and absorbent which contain an anionic clay
US4904627A (en) * 1987-03-13 1990-02-27 Uop Alkaline earth metal spinel/kaolin clays and processes for making
US4830840A (en) * 1987-03-13 1989-05-16 Uop Process for removing sulfur oxide and nitrogen oxide
JPH0655257B2 (ja) * 1988-12-05 1994-07-27 三菱重工業株式会社 乾式排ガス処理方法
US4981825A (en) * 1989-09-12 1991-01-01 Board Of Trustees Operating Michigan State University Dried metal oxide and clay particle compositions and method for the preparation thereof

Also Published As

Publication number Publication date
MY106358A (en) 1995-05-30
EP0491931A1 (de) 1992-07-01
CN1125157A (zh) 1996-06-26
JPH0620540B2 (ja) 1994-03-23
WO1992001509A1 (en) 1992-02-06
DE69115455D1 (de) 1996-01-25
DK0491931T3 (da) 1996-03-04
ES2083586T3 (es) 1996-04-16
CA2065026C (en) 1998-04-14
EP0491931A4 (en) 1993-05-26
EP0491931B1 (de) 1995-12-13
CA2065026A1 (en) 1992-01-17
KR920702251A (ko) 1992-09-03
KR950008192B1 (ko) 1995-07-26
MX9100166A (es) 1992-02-28
US5219536A (en) 1993-06-15
US5126300A (en) 1992-06-30
GR3018686T3 (en) 1996-04-30
JPH04504979A (ja) 1992-09-03
ATE131414T1 (de) 1995-12-15

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee