DE69205137T2 - Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs. - Google Patents
Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs.Info
- Publication number
- DE69205137T2 DE69205137T2 DE69205137T DE69205137T DE69205137T2 DE 69205137 T2 DE69205137 T2 DE 69205137T2 DE 69205137 T DE69205137 T DE 69205137T DE 69205137 T DE69205137 T DE 69205137T DE 69205137 T2 DE69205137 T2 DE 69205137T2
- Authority
- DE
- Germany
- Prior art keywords
- type
- nitrogen adsorption
- ion exchanged
- lithium zeolite
- exchanged lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0259—Physical processing only by adsorption on solids
- C01B13/0262—Physical processing only by adsorption on solids characterised by the adsorbent
- C01B13/027—Zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/04—Purification or separation of nitrogen
- C01B21/0405—Purification or separation processes
- C01B21/0433—Physical processing only
- C01B21/045—Physical processing only by adsorption in solids
- C01B21/0455—Physical processing only by adsorption in solids characterised by the adsorbent
- C01B21/0466—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
- B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/11—Noble gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0046—Nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/811,404 US5152813A (en) | 1991-12-20 | 1991-12-20 | Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69205137D1 DE69205137D1 (de) | 1995-11-02 |
DE69205137T2 true DE69205137T2 (de) | 1996-02-29 |
Family
ID=25206453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69205137T Expired - Fee Related DE69205137T2 (de) | 1991-12-20 | 1992-12-15 | Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs. |
Country Status (5)
Country | Link |
---|---|
US (1) | US5152813A (de) |
EP (1) | EP0548755B1 (de) |
JP (1) | JPH0757300B2 (de) |
CA (1) | CA2085180C (de) |
DE (1) | DE69205137T2 (de) |
Families Citing this family (86)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5292360A (en) * | 1987-07-17 | 1994-03-08 | Rhone-Poulenc Chimie | 5A zeolite/kaolinite adsorbent for gas purification |
US5174979A (en) | 1989-10-06 | 1992-12-29 | Uop | Mixed ion-exchanged zeolites and processes for the use thereof in gas separations |
US5266102A (en) * | 1992-09-23 | 1993-11-30 | Air Products And Chemicals, Inc. | O2 VSA process with low O2 capacity adsorbents |
US5258060A (en) * | 1992-09-23 | 1993-11-02 | Air Products And Chemicals, Inc. | Adsorptive separation using diluted adsorptive phase |
US5268023A (en) * | 1992-10-05 | 1993-12-07 | Air Products And Chemicals, Inc. | Nitrogen adsorption with highly Li exchanged X-zeolites with low Si/Al ratio |
US5258058A (en) * | 1992-10-05 | 1993-11-02 | Air Products And Chemicals, Inc. | Nitrogen adsorption with a divalent cation exchanged lithium X-zeolite |
US5354360A (en) * | 1993-01-11 | 1994-10-11 | Air Products And Chemicals, Inc. | Magnesium A-zeolite for nitrogen adsorption |
US5300138A (en) * | 1993-01-21 | 1994-04-05 | Semco Incorporated | Langmuir moderate type 1 desiccant mixture for air treatment |
US5529610A (en) * | 1993-09-07 | 1996-06-25 | Air Products And Chemicals, Inc. | Multiple zeolite adsorbent layers in oxygen separation |
US5370728A (en) * | 1993-09-07 | 1994-12-06 | Praxair Technology, Inc. | Single bed pressure swing adsorption system and process |
US5415683A (en) * | 1993-11-17 | 1995-05-16 | Praxair Technology, Inc. | Vacuum pressure swing adsorption process |
US5441557A (en) * | 1993-12-14 | 1995-08-15 | Praxair Technology, Inc. | Enhanced gas separations and zeolite compositions therefor |
US5451383A (en) * | 1993-12-23 | 1995-09-19 | Praxair Technology, Inc. | Lithium recovery |
US5464467A (en) * | 1994-02-14 | 1995-11-07 | The Boc Group, Inc. | Adsorptive separation of nitrogen from other gases |
US5567407A (en) * | 1994-05-12 | 1996-10-22 | Coe; Charles G. | Li-exchanged low silica EMT-containing metallosilicates |
US5573745A (en) * | 1994-05-12 | 1996-11-12 | Air Products And Chemicals, Inc. | High micropore volume low silica EMT-containing metallosilicates |
FR2722426B1 (fr) * | 1994-07-18 | 1996-08-23 | Air Liquide | Procede de separation d'azote d'un melange gazeux par adsorption |
US5531808A (en) * | 1994-12-23 | 1996-07-02 | The Boc Group, Inc. | Removal of carbon dioxide from gas streams |
JP3309043B2 (ja) * | 1995-03-02 | 2002-07-29 | プラクスエア・テクノロジー・インコーポレイテッド | 単流イオン交換による混成陽イオン吸着剤の製造法 |
US5529607A (en) * | 1995-03-15 | 1996-06-25 | The Boc Group, Inc. | PSA process with dynamic purge control |
FR2731918B1 (fr) * | 1995-03-24 | 1997-05-23 | Air Liquide | Procede de separation d'azote de composes moins polaires |
DE19518407A1 (de) * | 1995-05-19 | 1996-11-21 | Bayer Ag | Verfahren zur adsorptiven Sauerstoffanreicherung von Luft mit Mischungen aus Molekularsieb-Zeolithen |
DE19528188C1 (de) * | 1995-08-01 | 1996-12-05 | Bayer Ag | Verfahren zur Adsorption von Stickstoff aus Gasgemischen mittels Druckwechseladsorption mit Zeolithen |
US5616170A (en) * | 1995-08-11 | 1997-04-01 | The Boc Group, Inc. | Adsorptive separation of nitrogen from other gases |
FR2743507B1 (fr) * | 1996-01-16 | 1998-03-06 | Air Liquide | Procede pour la separation de melanges d'oxygene et d'azote utilisant un adsorbant a porosite amelioree |
US5604169A (en) * | 1996-03-04 | 1997-02-18 | Praxair Technology, Inc. | Process for producing mixed-cation zeolites |
FR2749004B1 (fr) * | 1996-05-24 | 1998-07-10 | Air Liquide | Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolithe x echangee au lithium |
US5932509A (en) * | 1996-06-18 | 1999-08-03 | The Boc Group, Inc. | Preparation of ion-exchanged zeolites |
US5868818A (en) * | 1996-08-08 | 1999-02-09 | Tosoh Corporation | Adsorbent for air separation, production method thereof, and air-separation method using it |
DE19647290A1 (de) * | 1996-11-15 | 1998-05-28 | Bayer Ag | Verfahren zur Herstellung eines mit Lithium-Ionen ausgetauschten, bindemittelfreien Zeolithgranulats und dessen Verwendung zur adsorptiven Lufttrennung |
FR2758739B1 (fr) * | 1997-01-24 | 1999-02-26 | Ceca Sa | Perfectionnement dans les procedes psa de purification de l'hydrogene |
US6152991A (en) | 1997-04-17 | 2000-11-28 | Praxair Technology, Inc. | Multilayer adsorbent beds for PSA gas separation |
JPH119990A (ja) | 1997-06-24 | 1999-01-19 | Daido Hoxan Inc | 窒素吸着剤およびその使用方法 |
FR2765491B1 (fr) * | 1997-07-07 | 1999-08-06 | Air Liquide | Procede de separation d'un flux gazeux par un procede psa |
FR2766476B1 (fr) * | 1997-07-22 | 1999-09-03 | Ceca Sa | Adsorbant zeolitique ameliore pour la separation des gaz de l'air et son procede d'obtention |
FR2766475B1 (fr) * | 1997-07-22 | 1999-09-03 | Ceca Sa | Procede pour l'obtention de corps granulaires en zeolite lsx a faible taux de liant inerte |
US5997841A (en) * | 1997-08-08 | 1999-12-07 | Air Products And Chemicals, Inc. | Zincoaluminosilicates of the FAU structure |
US6103214A (en) * | 1997-08-08 | 2000-08-15 | Air Products And Chemicals, Inc. | Zincoaluminosilicates of the FAU structure |
FR2771656B1 (fr) * | 1997-12-01 | 2000-01-07 | Air Liquide | Procede psa mettant en oeuvre un adsorbant a proprietes de capacite et/ou de selectivite heterogenes |
FR2771943B1 (fr) * | 1997-12-05 | 2000-01-14 | Air Liquide | Procede de purification de fluides inertes par adsorption sur zeolite lsx |
JP2002504417A (ja) | 1998-02-27 | 2002-02-12 | プラクスエア・テクノロジー・インコーポレイテッド | Psaのための改良吸着剤 |
FR2775618B1 (fr) * | 1998-03-03 | 2000-05-05 | Air Liquide | Adsorbant a taux d'echange heterogene et procede psa mettant en oeuvre un tel adsorbant |
US6171370B1 (en) | 1998-03-04 | 2001-01-09 | Tosoh Corporation | Adsorbent for separating gases |
FR2782460B1 (fr) * | 1998-08-21 | 2000-09-22 | Air Liquide | Procede psa utilisant un adsorbant agglomere constitue d'une phase zeolitique et d'un liant |
FR2782461B1 (fr) * | 1998-08-21 | 2000-09-22 | Air Liquide | Procede psa utilisant une zeolithe faujasite contenant des cations metalliques en tant qu'adsorbant |
FR2784599B1 (fr) * | 1998-10-20 | 2000-12-08 | Air Liquide | Procede de purification d'un flux gazeux en ses impuretes n2o |
EP1005904A3 (de) | 1998-10-30 | 2000-06-14 | The Boc Group, Inc. | Adsorptionsmittel und adsorptives Trennungsverfahren |
FR2792220B1 (fr) * | 1999-04-19 | 2001-06-15 | Air Liquide | Procede psa mettant en oeuvre un adsorbant a resistance intrinseque favorable a la cinetique d'adsorption |
US6143057A (en) * | 1999-04-23 | 2000-11-07 | The Boc Group, Inc. | Adsorbents and adsorptive separation process |
FR2796570B1 (fr) * | 1999-07-22 | 2002-06-07 | Air Liquide | Adsorbant a selectivite amelioree pour la separation des gaz |
US6302943B1 (en) | 1999-11-02 | 2001-10-16 | Air Products And Chemicals, Inc. | Optimum adsorbents for H2 recovery by pressure and vacuum swing absorption |
US6478854B1 (en) * | 1999-11-25 | 2002-11-12 | Tosoh Corporation | High purity, low silica X-type zeolite binderless shaped product and gas separation method employing it |
FR2803282B1 (fr) * | 2000-01-04 | 2002-02-15 | Ceca Sa | Zeolites x echangees notamment au litium, leur procede de preparation et leur utilisation comme adsorbants de l'azote dans la separation des gaz de l'air |
US6407025B1 (en) | 2000-02-10 | 2002-06-18 | The Boc Group, Inc. | Method of manufacture of multicationic molecular sieves |
US6583081B2 (en) * | 2000-02-10 | 2003-06-24 | The Boc Group, Inc. | Method of manufacture of molecular sieves |
US6537348B1 (en) * | 2000-04-04 | 2003-03-25 | Tosoh Corporation | Method of adsorptive separation of carbon dioxide |
EP1148025B1 (de) * | 2000-04-20 | 2007-08-01 | Tosoh Corporation | Verfahren zum Reinigen von einem Wasserstoff enthaltenden Gasgemisch |
JP2000202281A (ja) | 2000-04-20 | 2000-07-25 | Air Water Inc | 選択的窒素吸着剤およびそれを用いた空気分離方法 |
FR2811241B1 (fr) * | 2000-07-07 | 2002-12-13 | Ceca Sa | Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolite x au calcium |
FR2811313B1 (fr) | 2000-07-07 | 2002-08-30 | Ceca Sa | Procede de preparation de zeolites x et lsx agglomerees et echangees au lithium |
US6451723B1 (en) | 2000-07-07 | 2002-09-17 | Honeywell International Inc. | Polymer-bound nitrogen adsorbent and method of making and using it |
US6432171B1 (en) | 2000-08-28 | 2002-08-13 | The Boc Group, Inc. | Thermal swing adsorption process |
US6409800B1 (en) | 2000-08-28 | 2002-06-25 | The Boc Group, Inc. | Temperature swing adsorption process |
US6596256B1 (en) | 2000-08-28 | 2003-07-22 | The Boc Group, Inc. | Synthesis of low silicon sodium X zeolite |
US6416569B1 (en) | 2000-08-28 | 2002-07-09 | The Boc Group, Inc. | Temperature swing adsorption process |
US6790260B2 (en) * | 2000-12-20 | 2004-09-14 | Praxair Technology, Inc. | Enhanced rate PSA process |
US7300905B2 (en) | 2001-01-05 | 2007-11-27 | Questair Technologies Inc. | Methods for their manufacture of adsorbent |
WO2003009811A2 (en) * | 2001-07-25 | 2003-02-06 | Haase Richard A | Processes and apparatus for the manufacture of polynuclear aluminum compounds and disinfectants, and polynuclear aluminum compounds and disinfectants from such processes and apparatus |
GB2386889B (en) | 2002-03-25 | 2006-01-11 | Council Scient Ind Res | Process for the preparation of molecular sieve adsorbent for selective adsorption of nitrogen and argon |
CA2482454C (en) | 2002-04-11 | 2011-12-20 | Richard A. Haase | Water combustion technology-methods, processes, systems and apparatus for the combustion of hydrogen and oxygen |
GB2399775B (en) * | 2003-03-28 | 2005-07-27 | Council Scient Ind Res | Process for the preparation of a molecular sieve adsorbent for the size/shape selective separation of air |
AU2004285450B2 (en) * | 2003-10-20 | 2010-01-14 | Gregory K. Frykman | Zeolite molecular sieves for the removal of toxins |
US7319082B2 (en) * | 2003-10-27 | 2008-01-15 | Council Of Scientific And Industrial Research | Process for the preparation of molecular sieve adsorbent for selective adsorption of oxygen from air |
US8148885B2 (en) * | 2004-12-30 | 2012-04-03 | E. I. Du Pont De Nemours And Company | Methods of conditioning getter materials |
US7404846B2 (en) * | 2005-04-26 | 2008-07-29 | Air Products And Chemicals, Inc. | Adsorbents for rapid cycle pressure swing adsorption processes |
US8173995B2 (en) | 2005-12-23 | 2012-05-08 | E. I. Du Pont De Nemours And Company | Electronic device including an organic active layer and process for forming the electronic device |
US8268269B2 (en) | 2006-01-24 | 2012-09-18 | Clearvalue Technologies, Inc. | Manufacture of water chemistries |
US7592284B2 (en) * | 2006-03-13 | 2009-09-22 | Honeywell International Inc. | Preparation of ion exchanged polymer bound nitrogen adsorbent |
US7886986B2 (en) | 2006-11-08 | 2011-02-15 | Semco Inc. | Building, ventilation system, and recovery device control |
WO2010077392A1 (en) * | 2008-12-17 | 2010-07-08 | Uop Llc | Adsorbent media with li exchanged zeolite |
WO2013094193A1 (ja) * | 2011-12-20 | 2013-06-27 | 東ソー株式会社 | ストロンチウム交換クリノプチロライト |
US9149757B2 (en) | 2012-11-14 | 2015-10-06 | Oddomotive, Inc. | Calcium LSX and lithium H-LSX zeolite oxygen enrichment system for an internal combustion engine |
US20150273453A1 (en) * | 2014-03-25 | 2015-10-01 | Uop Llc | Bismuth-modified molecular sieves and methods for preparing and using bismuth-modified molecular sieves |
CN107486146B (zh) * | 2017-09-06 | 2020-10-23 | 洛阳建龙微纳新材料股份有限公司 | 一种混合阳离子LiCa-LSX分子筛制法及应用 |
FR3103393B1 (fr) * | 2019-11-27 | 2022-07-01 | Arkema France | Séparation des gaz de l’air |
US20210260329A1 (en) | 2020-02-23 | 2021-08-26 | Koninklijke Philips N.V. | Portable oxygen concentrator |
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US2882244A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US2988503A (en) * | 1956-07-25 | 1961-06-13 | Union Carbide Corp | Process of adsorption |
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US3140933A (en) * | 1960-12-02 | 1964-07-14 | Union Carbide Corp | Separation of an oxygen-nitrogen mixture |
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US3313091A (en) * | 1963-11-04 | 1967-04-11 | Exxon Research Engineering Co | Vacuum cycle adsorption |
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DE3829584A1 (de) * | 1988-09-01 | 1990-03-08 | Bayer Ag | Trennung von gasgemischen durch vakuum swing adsorption in einem zwei-adsorber-system |
US4925460A (en) * | 1989-07-20 | 1990-05-15 | Air Products And Chemicals, Inc. | Chabazite for gas separation |
US4964889A (en) * | 1989-12-04 | 1990-10-23 | Uop | Selective adsorption on magnesium-containing clinoptilolites |
US5084075A (en) * | 1990-04-10 | 1992-01-28 | Air Products And Chemicals, Inc. | Vacuum swing adsorption process for production of 95+% n2 from ambient air |
US5074892A (en) * | 1990-05-30 | 1991-12-24 | Union Carbide Industrial Gases Technology Corporation | Air separation pressure swing adsorption process |
-
1991
- 1991-12-20 US US07/811,404 patent/US5152813A/en not_active Expired - Fee Related
-
1992
- 1992-12-11 CA CA002085180A patent/CA2085180C/en not_active Expired - Fee Related
- 1992-12-15 EP EP92121322A patent/EP0548755B1/de not_active Expired - Lifetime
- 1992-12-15 DE DE69205137T patent/DE69205137T2/de not_active Expired - Fee Related
- 1992-12-15 JP JP4354078A patent/JPH0757300B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0548755B1 (de) | 1995-09-27 |
US5152813A (en) | 1992-10-06 |
CA2085180A1 (en) | 1993-06-21 |
JPH06198115A (ja) | 1994-07-19 |
DE69205137D1 (de) | 1995-11-02 |
EP0548755A1 (de) | 1993-06-30 |
JPH0757300B2 (ja) | 1995-06-21 |
CA2085180C (en) | 1997-10-21 |
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