DE69205137T2 - Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs. - Google Patents

Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs.

Info

Publication number
DE69205137T2
DE69205137T2 DE69205137T DE69205137T DE69205137T2 DE 69205137 T2 DE69205137 T2 DE 69205137T2 DE 69205137 T DE69205137 T DE 69205137T DE 69205137 T DE69205137 T DE 69205137T DE 69205137 T2 DE69205137 T2 DE 69205137T2
Authority
DE
Germany
Prior art keywords
type
nitrogen adsorption
ion exchanged
lithium zeolite
exchanged lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69205137T
Other languages
English (en)
Other versions
DE69205137D1 (de
Inventor
Charles Gardner Coe
John Francis Kirner
Ronald Pierantozzi
Thomas Robert White
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Application granted granted Critical
Publication of DE69205137D1 publication Critical patent/DE69205137D1/de
Publication of DE69205137T2 publication Critical patent/DE69205137T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • B01J20/186Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0229Purification or separation processes
    • C01B13/0248Physical processing only
    • C01B13/0259Physical processing only by adsorption on solids
    • C01B13/0262Physical processing only by adsorption on solids characterised by the adsorbent
    • C01B13/027Zeolites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/04Purification or separation of nitrogen
    • C01B21/0405Purification or separation processes
    • C01B21/0433Physical processing only
    • C01B21/045Physical processing only by adsorption in solids
    • C01B21/0455Physical processing only by adsorption in solids characterised by the adsorbent
    • C01B21/0466Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • B01D2253/1085Zeolites characterized by a silicon-aluminium ratio
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/12Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/102Nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/11Noble gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0046Nitrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00Gas separation: processes
    • Y10S95/90Solid sorbent
    • Y10S95/902Molecular sieve
DE69205137T 1991-12-20 1992-12-15 Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs. Expired - Fee Related DE69205137T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/811,404 US5152813A (en) 1991-12-20 1991-12-20 Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite

Publications (2)

Publication Number Publication Date
DE69205137D1 DE69205137D1 (de) 1995-11-02
DE69205137T2 true DE69205137T2 (de) 1996-02-29

Family

ID=25206453

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69205137T Expired - Fee Related DE69205137T2 (de) 1991-12-20 1992-12-15 Stickstoffadsorption mit einen Ca- und/oder Sr-ionenausgetauschter Lithiumzeolit des X-Typs.

Country Status (5)

Country Link
US (1) US5152813A (de)
EP (1) EP0548755B1 (de)
JP (1) JPH0757300B2 (de)
CA (1) CA2085180C (de)
DE (1) DE69205137T2 (de)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5292360A (en) * 1987-07-17 1994-03-08 Rhone-Poulenc Chimie 5A zeolite/kaolinite adsorbent for gas purification
US5174979A (en) 1989-10-06 1992-12-29 Uop Mixed ion-exchanged zeolites and processes for the use thereof in gas separations
US5266102A (en) * 1992-09-23 1993-11-30 Air Products And Chemicals, Inc. O2 VSA process with low O2 capacity adsorbents
US5258060A (en) * 1992-09-23 1993-11-02 Air Products And Chemicals, Inc. Adsorptive separation using diluted adsorptive phase
US5268023A (en) * 1992-10-05 1993-12-07 Air Products And Chemicals, Inc. Nitrogen adsorption with highly Li exchanged X-zeolites with low Si/Al ratio
US5258058A (en) * 1992-10-05 1993-11-02 Air Products And Chemicals, Inc. Nitrogen adsorption with a divalent cation exchanged lithium X-zeolite
US5354360A (en) * 1993-01-11 1994-10-11 Air Products And Chemicals, Inc. Magnesium A-zeolite for nitrogen adsorption
US5300138A (en) * 1993-01-21 1994-04-05 Semco Incorporated Langmuir moderate type 1 desiccant mixture for air treatment
US5529610A (en) * 1993-09-07 1996-06-25 Air Products And Chemicals, Inc. Multiple zeolite adsorbent layers in oxygen separation
US5370728A (en) * 1993-09-07 1994-12-06 Praxair Technology, Inc. Single bed pressure swing adsorption system and process
US5415683A (en) * 1993-11-17 1995-05-16 Praxair Technology, Inc. Vacuum pressure swing adsorption process
US5441557A (en) * 1993-12-14 1995-08-15 Praxair Technology, Inc. Enhanced gas separations and zeolite compositions therefor
US5451383A (en) * 1993-12-23 1995-09-19 Praxair Technology, Inc. Lithium recovery
US5464467A (en) * 1994-02-14 1995-11-07 The Boc Group, Inc. Adsorptive separation of nitrogen from other gases
US5567407A (en) * 1994-05-12 1996-10-22 Coe; Charles G. Li-exchanged low silica EMT-containing metallosilicates
US5573745A (en) * 1994-05-12 1996-11-12 Air Products And Chemicals, Inc. High micropore volume low silica EMT-containing metallosilicates
FR2722426B1 (fr) * 1994-07-18 1996-08-23 Air Liquide Procede de separation d'azote d'un melange gazeux par adsorption
US5531808A (en) * 1994-12-23 1996-07-02 The Boc Group, Inc. Removal of carbon dioxide from gas streams
JP3309043B2 (ja) * 1995-03-02 2002-07-29 プラクスエア・テクノロジー・インコーポレイテッド 単流イオン交換による混成陽イオン吸着剤の製造法
US5529607A (en) * 1995-03-15 1996-06-25 The Boc Group, Inc. PSA process with dynamic purge control
FR2731918B1 (fr) * 1995-03-24 1997-05-23 Air Liquide Procede de separation d'azote de composes moins polaires
DE19518407A1 (de) * 1995-05-19 1996-11-21 Bayer Ag Verfahren zur adsorptiven Sauerstoffanreicherung von Luft mit Mischungen aus Molekularsieb-Zeolithen
DE19528188C1 (de) * 1995-08-01 1996-12-05 Bayer Ag Verfahren zur Adsorption von Stickstoff aus Gasgemischen mittels Druckwechseladsorption mit Zeolithen
US5616170A (en) * 1995-08-11 1997-04-01 The Boc Group, Inc. Adsorptive separation of nitrogen from other gases
FR2743507B1 (fr) * 1996-01-16 1998-03-06 Air Liquide Procede pour la separation de melanges d'oxygene et d'azote utilisant un adsorbant a porosite amelioree
US5604169A (en) * 1996-03-04 1997-02-18 Praxair Technology, Inc. Process for producing mixed-cation zeolites
FR2749004B1 (fr) * 1996-05-24 1998-07-10 Air Liquide Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolithe x echangee au lithium
US5932509A (en) * 1996-06-18 1999-08-03 The Boc Group, Inc. Preparation of ion-exchanged zeolites
US5868818A (en) * 1996-08-08 1999-02-09 Tosoh Corporation Adsorbent for air separation, production method thereof, and air-separation method using it
DE19647290A1 (de) * 1996-11-15 1998-05-28 Bayer Ag Verfahren zur Herstellung eines mit Lithium-Ionen ausgetauschten, bindemittelfreien Zeolithgranulats und dessen Verwendung zur adsorptiven Lufttrennung
FR2758739B1 (fr) * 1997-01-24 1999-02-26 Ceca Sa Perfectionnement dans les procedes psa de purification de l'hydrogene
US6152991A (en) 1997-04-17 2000-11-28 Praxair Technology, Inc. Multilayer adsorbent beds for PSA gas separation
JPH119990A (ja) 1997-06-24 1999-01-19 Daido Hoxan Inc 窒素吸着剤およびその使用方法
FR2765491B1 (fr) * 1997-07-07 1999-08-06 Air Liquide Procede de separation d'un flux gazeux par un procede psa
FR2766476B1 (fr) * 1997-07-22 1999-09-03 Ceca Sa Adsorbant zeolitique ameliore pour la separation des gaz de l'air et son procede d'obtention
FR2766475B1 (fr) * 1997-07-22 1999-09-03 Ceca Sa Procede pour l'obtention de corps granulaires en zeolite lsx a faible taux de liant inerte
US5997841A (en) * 1997-08-08 1999-12-07 Air Products And Chemicals, Inc. Zincoaluminosilicates of the FAU structure
US6103214A (en) * 1997-08-08 2000-08-15 Air Products And Chemicals, Inc. Zincoaluminosilicates of the FAU structure
FR2771656B1 (fr) * 1997-12-01 2000-01-07 Air Liquide Procede psa mettant en oeuvre un adsorbant a proprietes de capacite et/ou de selectivite heterogenes
FR2771943B1 (fr) * 1997-12-05 2000-01-14 Air Liquide Procede de purification de fluides inertes par adsorption sur zeolite lsx
JP2002504417A (ja) 1998-02-27 2002-02-12 プラクスエア・テクノロジー・インコーポレイテッド Psaのための改良吸着剤
FR2775618B1 (fr) * 1998-03-03 2000-05-05 Air Liquide Adsorbant a taux d'echange heterogene et procede psa mettant en oeuvre un tel adsorbant
US6171370B1 (en) 1998-03-04 2001-01-09 Tosoh Corporation Adsorbent for separating gases
FR2782460B1 (fr) * 1998-08-21 2000-09-22 Air Liquide Procede psa utilisant un adsorbant agglomere constitue d'une phase zeolitique et d'un liant
FR2782461B1 (fr) * 1998-08-21 2000-09-22 Air Liquide Procede psa utilisant une zeolithe faujasite contenant des cations metalliques en tant qu'adsorbant
FR2784599B1 (fr) * 1998-10-20 2000-12-08 Air Liquide Procede de purification d'un flux gazeux en ses impuretes n2o
EP1005904A3 (de) 1998-10-30 2000-06-14 The Boc Group, Inc. Adsorptionsmittel und adsorptives Trennungsverfahren
FR2792220B1 (fr) * 1999-04-19 2001-06-15 Air Liquide Procede psa mettant en oeuvre un adsorbant a resistance intrinseque favorable a la cinetique d'adsorption
US6143057A (en) * 1999-04-23 2000-11-07 The Boc Group, Inc. Adsorbents and adsorptive separation process
FR2796570B1 (fr) * 1999-07-22 2002-06-07 Air Liquide Adsorbant a selectivite amelioree pour la separation des gaz
US6302943B1 (en) 1999-11-02 2001-10-16 Air Products And Chemicals, Inc. Optimum adsorbents for H2 recovery by pressure and vacuum swing absorption
US6478854B1 (en) * 1999-11-25 2002-11-12 Tosoh Corporation High purity, low silica X-type zeolite binderless shaped product and gas separation method employing it
FR2803282B1 (fr) * 2000-01-04 2002-02-15 Ceca Sa Zeolites x echangees notamment au litium, leur procede de preparation et leur utilisation comme adsorbants de l'azote dans la separation des gaz de l'air
US6407025B1 (en) 2000-02-10 2002-06-18 The Boc Group, Inc. Method of manufacture of multicationic molecular sieves
US6583081B2 (en) * 2000-02-10 2003-06-24 The Boc Group, Inc. Method of manufacture of molecular sieves
US6537348B1 (en) * 2000-04-04 2003-03-25 Tosoh Corporation Method of adsorptive separation of carbon dioxide
EP1148025B1 (de) * 2000-04-20 2007-08-01 Tosoh Corporation Verfahren zum Reinigen von einem Wasserstoff enthaltenden Gasgemisch
JP2000202281A (ja) 2000-04-20 2000-07-25 Air Water Inc 選択的窒素吸着剤およびそれを用いた空気分離方法
FR2811241B1 (fr) * 2000-07-07 2002-12-13 Ceca Sa Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolite x au calcium
FR2811313B1 (fr) 2000-07-07 2002-08-30 Ceca Sa Procede de preparation de zeolites x et lsx agglomerees et echangees au lithium
US6451723B1 (en) 2000-07-07 2002-09-17 Honeywell International Inc. Polymer-bound nitrogen adsorbent and method of making and using it
US6432171B1 (en) 2000-08-28 2002-08-13 The Boc Group, Inc. Thermal swing adsorption process
US6409800B1 (en) 2000-08-28 2002-06-25 The Boc Group, Inc. Temperature swing adsorption process
US6596256B1 (en) 2000-08-28 2003-07-22 The Boc Group, Inc. Synthesis of low silicon sodium X zeolite
US6416569B1 (en) 2000-08-28 2002-07-09 The Boc Group, Inc. Temperature swing adsorption process
US6790260B2 (en) * 2000-12-20 2004-09-14 Praxair Technology, Inc. Enhanced rate PSA process
US7300905B2 (en) 2001-01-05 2007-11-27 Questair Technologies Inc. Methods for their manufacture of adsorbent
WO2003009811A2 (en) * 2001-07-25 2003-02-06 Haase Richard A Processes and apparatus for the manufacture of polynuclear aluminum compounds and disinfectants, and polynuclear aluminum compounds and disinfectants from such processes and apparatus
GB2386889B (en) 2002-03-25 2006-01-11 Council Scient Ind Res Process for the preparation of molecular sieve adsorbent for selective adsorption of nitrogen and argon
CA2482454C (en) 2002-04-11 2011-12-20 Richard A. Haase Water combustion technology-methods, processes, systems and apparatus for the combustion of hydrogen and oxygen
GB2399775B (en) * 2003-03-28 2005-07-27 Council Scient Ind Res Process for the preparation of a molecular sieve adsorbent for the size/shape selective separation of air
AU2004285450B2 (en) * 2003-10-20 2010-01-14 Gregory K. Frykman Zeolite molecular sieves for the removal of toxins
US7319082B2 (en) * 2003-10-27 2008-01-15 Council Of Scientific And Industrial Research Process for the preparation of molecular sieve adsorbent for selective adsorption of oxygen from air
US8148885B2 (en) * 2004-12-30 2012-04-03 E. I. Du Pont De Nemours And Company Methods of conditioning getter materials
US7404846B2 (en) * 2005-04-26 2008-07-29 Air Products And Chemicals, Inc. Adsorbents for rapid cycle pressure swing adsorption processes
US8173995B2 (en) 2005-12-23 2012-05-08 E. I. Du Pont De Nemours And Company Electronic device including an organic active layer and process for forming the electronic device
US8268269B2 (en) 2006-01-24 2012-09-18 Clearvalue Technologies, Inc. Manufacture of water chemistries
US7592284B2 (en) * 2006-03-13 2009-09-22 Honeywell International Inc. Preparation of ion exchanged polymer bound nitrogen adsorbent
US7886986B2 (en) 2006-11-08 2011-02-15 Semco Inc. Building, ventilation system, and recovery device control
WO2010077392A1 (en) * 2008-12-17 2010-07-08 Uop Llc Adsorbent media with li exchanged zeolite
WO2013094193A1 (ja) * 2011-12-20 2013-06-27 東ソー株式会社 ストロンチウム交換クリノプチロライト
US9149757B2 (en) 2012-11-14 2015-10-06 Oddomotive, Inc. Calcium LSX and lithium H-LSX zeolite oxygen enrichment system for an internal combustion engine
US20150273453A1 (en) * 2014-03-25 2015-10-01 Uop Llc Bismuth-modified molecular sieves and methods for preparing and using bismuth-modified molecular sieves
CN107486146B (zh) * 2017-09-06 2020-10-23 洛阳建龙微纳新材料股份有限公司 一种混合阳离子LiCa-LSX分子筛制法及应用
FR3103393B1 (fr) * 2019-11-27 2022-07-01 Arkema France Séparation des gaz de l’air
US20210260329A1 (en) 2020-02-23 2021-08-26 Koninklijke Philips N.V. Portable oxygen concentrator

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882244A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US2988503A (en) * 1956-07-25 1961-06-13 Union Carbide Corp Process of adsorption
NL112453C (de) * 1957-11-21
US2951552A (en) * 1958-06-23 1960-09-06 Gen Electric Gas separator
US3140931A (en) * 1960-12-01 1964-07-14 Union Carbide Corp Separation of an oxygen-nitrogen mixture
US3140932A (en) * 1960-12-02 1964-07-14 Union Carbide Corp Separation of an oxygen-nitrogen mixture
US3140933A (en) * 1960-12-02 1964-07-14 Union Carbide Corp Separation of an oxygen-nitrogen mixture
US3280536A (en) * 1963-07-30 1966-10-25 Exxon Research Engineering Co Method for providing an oxygen-enriched environment
US3313091A (en) * 1963-11-04 1967-04-11 Exxon Research Engineering Co Vacuum cycle adsorption
US3282028A (en) * 1964-01-06 1966-11-01 Exxon Research Engineering Co Synthetic molecular sieves
US3446645A (en) * 1968-05-06 1969-05-27 Union Carbide Corp Desiccant bodies
JPS4970877A (de) * 1972-09-25 1974-07-09
US4013429A (en) * 1975-06-04 1977-03-22 Air Products And Chemicals, Inc. Fractionation of air by adsorption
JPS538400A (en) * 1976-07-09 1978-01-25 Mobil Oil Process for preparing boujacite having low silica content
US4322394A (en) * 1977-10-31 1982-03-30 Battelle Memorial Institute Adsorbent regeneration and gas separation utilizing microwave heating
DE3143993A1 (de) * 1981-11-05 1983-05-11 Bayer Ag, 5090 Leverkusen Molekularsieb-zeolith fuer die gewinnung von wasserstoff mit der druckwechsel-adsorptions-technik
US4544378A (en) * 1982-11-15 1985-10-01 Air Products And Chemicals, Inc. Nitrogen adsorption process
US4481018A (en) * 1982-11-15 1984-11-06 Air Products And Chemicals, Inc. Polyvalent ion exchanged adsorbent for air separation
US4557736A (en) * 1984-10-29 1985-12-10 Air Products And Chemicals, Inc. Binary ion exchanged type X zeolite adsorbent
US4685939A (en) * 1985-03-19 1987-08-11 Air Products And Chemicals, Inc. Production of oxygen enriched air
US4606899A (en) * 1985-03-27 1986-08-19 Air Products And Chemicals, Inc. Synthesis of maximum aluminum X zeolites
US4756723A (en) * 1987-03-04 1988-07-12 Air Products And Chemicals, Inc. Preparation of high purity oxygen
US4859217A (en) * 1987-06-30 1989-08-22 Uop Process for separating nitrogen from mixtures thereof with less polar substances
US4810265A (en) * 1987-12-29 1989-03-07 Union Carbide Corporation Pressure swing adsorption process for gas separation
DE3829584A1 (de) * 1988-09-01 1990-03-08 Bayer Ag Trennung von gasgemischen durch vakuum swing adsorption in einem zwei-adsorber-system
US4925460A (en) * 1989-07-20 1990-05-15 Air Products And Chemicals, Inc. Chabazite for gas separation
US4964889A (en) * 1989-12-04 1990-10-23 Uop Selective adsorption on magnesium-containing clinoptilolites
US5084075A (en) * 1990-04-10 1992-01-28 Air Products And Chemicals, Inc. Vacuum swing adsorption process for production of 95+% n2 from ambient air
US5074892A (en) * 1990-05-30 1991-12-24 Union Carbide Industrial Gases Technology Corporation Air separation pressure swing adsorption process

Also Published As

Publication number Publication date
EP0548755B1 (de) 1995-09-27
US5152813A (en) 1992-10-06
CA2085180A1 (en) 1993-06-21
JPH06198115A (ja) 1994-07-19
DE69205137D1 (de) 1995-11-02
EP0548755A1 (de) 1993-06-30
JPH0757300B2 (ja) 1995-06-21
CA2085180C (en) 1997-10-21

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