DE69224353D1 - Verfahren zur herstellung von styrol-polymeren und katalysator dafür - Google Patents

Verfahren zur herstellung von styrol-polymeren und katalysator dafür

Info

Publication number
DE69224353D1
DE69224353D1 DE69224353T DE69224353T DE69224353D1 DE 69224353 D1 DE69224353 D1 DE 69224353D1 DE 69224353 T DE69224353 T DE 69224353T DE 69224353 T DE69224353 T DE 69224353T DE 69224353 D1 DE69224353 D1 DE 69224353D1
Authority
DE
Germany
Prior art keywords
catalyst
styrenic polymer
highly syndiotactic
styrene polymers
producing styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69224353T
Other languages
English (en)
Other versions
DE69224353T2 (de
Inventor
Shoji Naganuma
Masami Watanabe
Norio Tomotsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Publication of DE69224353D1 publication Critical patent/DE69224353D1/de
Application granted granted Critical
Publication of DE69224353T2 publication Critical patent/DE69224353T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
DE69224353T 1991-06-12 1992-06-09 Verfahren zur herstellung von styrol-polymeren und katalysator dafür Expired - Fee Related DE69224353T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP3139955A JPH04366109A (ja) 1991-06-12 1991-06-12 スチレン系重合体の製造方法及びその触媒
PCT/JP1992/000736 WO1992022589A1 (en) 1991-06-12 1992-06-09 Process for producing styrenic polymer and catalyst therefor

Publications (2)

Publication Number Publication Date
DE69224353D1 true DE69224353D1 (de) 1998-03-12
DE69224353T2 DE69224353T2 (de) 1998-06-10

Family

ID=15257566

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69224353T Expired - Fee Related DE69224353T2 (de) 1991-06-12 1992-06-09 Verfahren zur herstellung von styrol-polymeren und katalysator dafür

Country Status (6)

Country Link
US (1) US5391661A (de)
EP (1) EP0543022B1 (de)
JP (1) JPH04366109A (de)
AT (1) ATE163018T1 (de)
DE (1) DE69224353T2 (de)
WO (1) WO1992022589A1 (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05331228A (ja) * 1971-11-18 1993-12-14 Idemitsu Kosan Co Ltd ポリオレフィンの製造方法
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
EP0698619B1 (de) * 1993-03-31 2001-11-07 Idemitsu Kosan Company Limited Katalysator zur herstellung von vinylpolymer und verfahren zur herstellung von vinylaromatischem polymer
JPH0733812A (ja) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
JP3216748B2 (ja) * 1993-07-23 2001-10-09 出光興産株式会社 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
US5428120A (en) * 1993-10-08 1995-06-27 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
DE19509785A1 (de) * 1995-03-17 1996-09-19 Basf Ag Verfahren zur Herstellung von Polymerisaten von vinylaromatischen Verbindungen unter Druck in Gegenwart von leicht flüchtigen Kohlenwasserstoffen
AU717137B2 (en) * 1995-11-24 2000-03-16 Ciba Specialty Chemicals Holding Inc. Borate coinitiators for photopolymerization
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5854166A (en) * 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US5895771A (en) * 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
US6670299B1 (en) * 1999-07-03 2003-12-30 Northwestern University Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts
MXPA02005642A (es) * 1999-12-09 2002-09-02 Exxon Chemical Patents Inc Catalizadores de polimerizacion de olefinas derivados de compuestos cationicos del grupo 15 y procesos que los usan.
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6538081B2 (en) * 2000-12-18 2003-03-25 Univation Tech Llc Polymerization process
US7759489B2 (en) * 2006-01-27 2010-07-20 Idemitsu Kosan Co., Ltd. Transition metal complex compound and organic electroluminescence device using the compound
KR20200086295A (ko) * 2017-12-01 2020-07-16 이데미쓰 고산 가부시키가이샤 스타이렌계 수지의 제조 방법 및 스타이렌계 수지 성형체

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3418303A (en) * 1964-09-16 1968-12-24 Du Pont Coordination catalyst system and polymerization process
US3459825A (en) * 1967-10-26 1969-08-05 Sun Oil Co Catalyst and process for dimerization of olefins
JP2531583B2 (ja) * 1987-01-28 1996-09-04 出光興産株式会社 スチレン系共重合体およびその製造方法
JPS62187708A (ja) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd スチレン系重合体の製造法
JPH085929B2 (ja) * 1987-01-22 1996-01-24 出光興産株式会社 スチレン系重合体の製造法
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
JPH075524B2 (ja) * 1989-03-29 1995-01-25 日本ペイント株式会社 新規ベンジルアンモニウム塩
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
US5066740A (en) * 1989-12-26 1991-11-19 The B. F. Goodrich Company Pyridinium metathesis catalysts for cycloolefin polymerization
US5171919A (en) * 1990-10-17 1992-12-15 Idemitsu Kosan Co., Ltd. Process for producing propylene based oligomers

Also Published As

Publication number Publication date
EP0543022B1 (de) 1998-02-04
WO1992022589A1 (en) 1992-12-23
EP0543022A4 (en) 1994-11-23
ATE163018T1 (de) 1998-02-15
US5391661A (en) 1995-02-21
EP0543022A1 (de) 1993-05-26
JPH04366109A (ja) 1992-12-18
DE69224353T2 (de) 1998-06-10

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee