DE69225182D1 - Verfahren zur Herstellung von Polymeren und Copolymeren mit kontinuierlich sich ändernder Zusammensetzung und dadurch erzeugte Produkte - Google Patents
Verfahren zur Herstellung von Polymeren und Copolymeren mit kontinuierlich sich ändernder Zusammensetzung und dadurch erzeugte ProdukteInfo
- Publication number
- DE69225182D1 DE69225182D1 DE69225182T DE69225182T DE69225182D1 DE 69225182 D1 DE69225182 D1 DE 69225182D1 DE 69225182 T DE69225182 T DE 69225182T DE 69225182 T DE69225182 T DE 69225182T DE 69225182 D1 DE69225182 D1 DE 69225182D1
- Authority
- DE
- Germany
- Prior art keywords
- copolymers
- polymers
- preparation
- products produced
- continuously changing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/754,493 US5241008A (en) | 1991-09-03 | 1991-09-03 | Process for producing continuously tapered polymers and copolymers and products produced thereby |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69225182D1 true DE69225182D1 (de) | 1998-05-28 |
DE69225182T2 DE69225182T2 (de) | 1998-08-13 |
Family
ID=25035053
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69225182T Expired - Fee Related DE69225182T2 (de) | 1991-09-03 | 1992-09-03 | Verfahren zur Herstellung von Polymeren und Copolymeren mit kontinuierlich sich ändernder Zusammensetzung und dadurch erzeugte Produkte |
Country Status (10)
Country | Link |
---|---|
US (1) | US5241008A (de) |
EP (1) | EP0530795B1 (de) |
JP (1) | JP2628822B2 (de) |
KR (1) | KR100237192B1 (de) |
BR (1) | BR9203448A (de) |
CA (1) | CA2077371C (de) |
DE (1) | DE69225182T2 (de) |
ES (1) | ES2114899T3 (de) |
MX (1) | MX9205060A (de) |
ZA (1) | ZA926696B (de) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5614579A (en) * | 1992-12-22 | 1997-03-25 | Bridgestone Corporation | Process for the preparation of tapered copolymers via in situ dispersion |
US5795944A (en) * | 1996-03-18 | 1998-08-18 | Shell Oil Company | Programmed addition of heavy ethers for microstructure control of diene polymers |
EP1236747B1 (de) * | 1999-08-09 | 2005-11-02 | Zeon Corporation | Copolymerkautschuk aus vinylaromat/konjugiertem dien mit sich ändernder zusammensetzung, verfahren zu seiner herstellung und kautschukzusammensetzung |
US6956084B2 (en) | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
KR100458169B1 (ko) * | 2002-07-26 | 2004-11-20 | 금호석유화학 주식회사 | 비대칭 다중블록 sbs 중합체 및 이의 제조 방법 |
JP4683928B2 (ja) | 2002-12-18 | 2011-05-18 | 株式会社ブリヂストン | クレイの剥離方法、該方法から得られた組成物、及び該組成物を含む変性ゴム |
US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
US7205370B2 (en) | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
US7718737B2 (en) | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
US20050282956A1 (en) | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
US7998554B2 (en) | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
US7579398B2 (en) | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
US7659342B2 (en) | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
US9061900B2 (en) | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
US7538159B2 (en) | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
US8697775B2 (en) | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
US7601772B2 (en) | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
US7935184B2 (en) | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
EP3495322A1 (de) | 2006-07-28 | 2019-06-12 | Bridgestone Corporation | Polymere kern-schalen-nanopartikel mit einem interphasenbereich |
US7597959B2 (en) | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
US7649049B2 (en) | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
MX2010011953A (es) * | 2008-04-30 | 2011-04-26 | Styron Europe Gmbh | Polimeros de estireno-butadieno con gradiente de estireno y metodos para hacer los mismos. |
CN101628959A (zh) * | 2008-07-15 | 2010-01-20 | 中国石油化工集团公司 | 一种可发泡苯乙烯属单体-二烯烃共聚物、其制备方法和用途 |
US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
EP2370349B1 (de) | 2008-12-31 | 2014-10-29 | Bridgestone Corporation | Herstellungsverfahren für core-first-nanopartikel, nanopartikel und zusammensetzung |
KR101726457B1 (ko) | 2009-03-19 | 2017-04-12 | 트린세오 유럽 게엠베하 | 신규한 스티렌을 혼입한 스티렌 부타디엔 고무 |
US9062144B2 (en) | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
US9115222B2 (en) | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3598886A (en) * | 1965-09-15 | 1971-08-10 | Borg Warner | Hydrogenated block copolymers |
US4022959A (en) * | 1969-11-22 | 1977-05-10 | Chemische Werke Huels Aktiengesellschaft | Organolithium-Lewis base polymerization of 1,3-butadiene and novel polybutadienes thus produced |
US3700748A (en) * | 1970-05-22 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
US3823203A (en) * | 1971-03-29 | 1974-07-09 | Shell Oil Co | Vulcanizable selectively hydogenated block copolymer compositions |
US4057601A (en) * | 1975-11-20 | 1977-11-08 | Phillips Petroleum Company | Block copolymers of alkadienes and monovinyl arenes |
EP0014947B1 (de) * | 1979-02-15 | 1985-09-18 | The Dow Chemical Company | Blockcopolymerisate von Dien mit endständigen statistischen Copolymerisatblöcken von Styrol oder Alkylstyrol und Alpha-Methylstyrol und ihre Herstellung |
GB2071117B (en) * | 1980-03-07 | 1984-05-10 | Dunlop Ltd | Elastomers and tyres containing them |
BE887829A (fr) * | 1980-03-07 | 1981-09-07 | Dunlop L | Elastomeres et pneus les contenant |
US4430472A (en) * | 1982-12-17 | 1984-02-07 | Hughes Tool Company | Elastomeric compositions with improved chemical, water and heat resistance |
JPS60179409A (ja) * | 1984-02-27 | 1985-09-13 | Sumitomo Chem Co Ltd | 樹脂改良材及びその製造法 |
US4631314A (en) * | 1985-06-26 | 1986-12-23 | The Dow Chemical Company | Block copolymers utilizing a mixture of cis and trans-isomers of 1,3-pentadiene |
JPS6241213A (ja) * | 1985-08-16 | 1987-02-23 | シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ | 変性ブロツクコポリマ−、該コポリマ−を含有する耐衝撃性組成物、及び該コポリマ−の製造法 |
US4672097A (en) * | 1986-03-25 | 1987-06-09 | The Firestone Tire & Rubber Company | Process and system for preparing random copolymers having low vinyl contents |
US4843120A (en) * | 1986-09-29 | 1989-06-27 | The Goodyear Tire & Rubber Company | Rubber composition |
GB2200123B (en) * | 1986-12-02 | 1990-06-13 | Shell Int Research | Elastomers and tyres containing them |
JPH0788439B2 (ja) * | 1987-12-23 | 1995-09-27 | 日本ゼオン株式会社 | 防振ゴム組成物 |
US5071920A (en) * | 1989-11-24 | 1991-12-10 | The Dow Chemical Company | Tapered block copolymers |
US5047484A (en) * | 1989-11-24 | 1991-09-10 | The Dow Chemical Company | Tapered block copolymers |
US5070148A (en) * | 1990-01-16 | 1991-12-03 | The Goodyear Tire & Rubber Company | Segmented elastomer |
-
1991
- 1991-09-03 US US07/754,493 patent/US5241008A/en not_active Expired - Fee Related
-
1992
- 1992-09-02 CA CA002077371A patent/CA2077371C/en not_active Expired - Fee Related
- 1992-09-03 BR BR929203448A patent/BR9203448A/pt not_active IP Right Cessation
- 1992-09-03 ZA ZA926696A patent/ZA926696B/xx unknown
- 1992-09-03 KR KR1019920016193A patent/KR100237192B1/ko not_active IP Right Cessation
- 1992-09-03 ES ES92115066T patent/ES2114899T3/es not_active Expired - Lifetime
- 1992-09-03 JP JP4260712A patent/JP2628822B2/ja not_active Expired - Fee Related
- 1992-09-03 EP EP92115066A patent/EP0530795B1/de not_active Expired - Lifetime
- 1992-09-03 DE DE69225182T patent/DE69225182T2/de not_active Expired - Fee Related
- 1992-09-03 MX MX9205060A patent/MX9205060A/es not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2077371C (en) | 1998-08-18 |
CA2077371A1 (en) | 1993-03-04 |
JP2628822B2 (ja) | 1997-07-09 |
JPH05271354A (ja) | 1993-10-19 |
KR930006063A (ko) | 1993-04-20 |
EP0530795A1 (de) | 1993-03-10 |
KR100237192B1 (ko) | 2000-01-15 |
ZA926696B (en) | 1993-05-10 |
EP0530795B1 (de) | 1998-04-22 |
MX9205060A (es) | 1993-03-01 |
DE69225182T2 (de) | 1998-08-13 |
ES2114899T3 (es) | 1998-06-16 |
BR9203448A (pt) | 1993-04-06 |
US5241008A (en) | 1993-08-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: FIRESTONE POLYMERS, LLC, AKRON, OHIO, US |
|
8339 | Ceased/non-payment of the annual fee |