DE69230569T2 - Verfahren zur Herstellung von Terephthalsäure - Google Patents
Verfahren zur Herstellung von TerephthalsäureInfo
- Publication number
- DE69230569T2 DE69230569T2 DE69230569T DE69230569T DE69230569T2 DE 69230569 T2 DE69230569 T2 DE 69230569T2 DE 69230569 T DE69230569 T DE 69230569T DE 69230569 T DE69230569 T DE 69230569T DE 69230569 T2 DE69230569 T2 DE 69230569T2
- Authority
- DE
- Germany
- Prior art keywords
- preparation
- terephthalic acid
- terephthalic
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/26—1,4 - Benzenedicarboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB919104776A GB9104776D0 (en) | 1991-03-07 | 1991-03-07 | Process for the production of terephthalic acid |
| IDP97064092A ID19108A (id) | 1991-03-07 | 1992-06-08 | Proses produksi asam tereftalat (pecahan dari p-002451) |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69230569D1 DE69230569D1 (de) | 2000-02-17 |
| DE69230569T2 true DE69230569T2 (de) | 2000-07-27 |
Family
ID=32599058
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69230569T Expired - Lifetime DE69230569T2 (de) | 1991-03-07 | 1992-02-02 | Verfahren zur Herstellung von Terephthalsäure |
| DE69214859T Expired - Lifetime DE69214859T2 (de) | 1991-03-07 | 1992-02-20 | Verfahren zur Herstellung von Terephthalsäure |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69214859T Expired - Lifetime DE69214859T2 (de) | 1991-03-07 | 1992-02-20 | Verfahren zur Herstellung von Terephthalsäure |
Country Status (15)
| Country | Link |
|---|---|
| US (4) | US5563293A (de) |
| EP (3) | EP0722927A1 (de) |
| JP (1) | JPH0565246A (de) |
| KR (1) | KR100225371B1 (de) |
| CN (2) | CN1038409C (de) |
| CA (1) | CA2062063C (de) |
| DE (2) | DE69230569T2 (de) |
| EG (1) | EG19876A (de) |
| ES (2) | ES2142006T3 (de) |
| GB (2) | GB9104776D0 (de) |
| ID (1) | ID19108A (de) |
| MX (1) | MX9200997A (de) |
| RU (1) | RU2106337C1 (de) |
| SG (1) | SG66231A1 (de) |
| ZA (1) | ZA921380B (de) |
Families Citing this family (103)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9310070D0 (en) * | 1992-05-29 | 1993-06-30 | Ici Plc | Process for the production of purified terephthalic acid |
| GB9400570D0 (en) * | 1994-01-13 | 1994-03-09 | Ici Plc | Handling of materials at elevated pressure |
| TW299318B (de) * | 1994-11-15 | 1997-03-01 | Mitsubishi Chem Corp | |
| US5961942A (en) * | 1995-06-05 | 1999-10-05 | E. I. Du Pont De Nemours And Company | Effluent gas treatment |
| DE69609959T2 (de) * | 1995-06-05 | 2001-02-08 | Du Pont | Abgasbehandlung |
| US5929274A (en) | 1995-06-07 | 1999-07-27 | Hfm International, Inc. | Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid |
| US6054610A (en) | 1995-06-07 | 2000-04-25 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid and isophthalic acid from mixed xylenes |
| US5767311A (en) | 1995-06-07 | 1998-06-16 | Glitsch International, Inc. | Method and apparatus for preparing purified terephtalic acid |
| US6013835A (en) | 1995-06-07 | 2000-01-11 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid |
| AU1803697A (en) * | 1996-02-22 | 1997-09-10 | E.I. Du Pont De Nemours And Company | Production of aromatic polycarboxylic acids |
| TW442461B (en) * | 1996-02-22 | 2001-06-23 | Du Pont | Process for the production of an aromatic carboxylic acid |
| GB9705349D0 (en) | 1997-03-14 | 1997-04-30 | Ici Plc | Treatment of effluent streams |
| EP0967025B1 (de) * | 1997-12-12 | 2003-03-26 | Mitsubishi Heavy Industries, Ltd. | Walzvorrichtung und walzverfahren |
| TR200001718T2 (tr) * | 1997-12-15 | 2001-01-22 | Shell Internationale Research Maatschappij B.V. | Aromatik karboksilik asitler üretme yöntemi. |
| TW483886B (en) * | 1998-08-11 | 2002-04-21 | Du Pont | Method for recovering methyl acetate and residual acetic acid in the production of pure terephtalic acid |
| IT1311976B1 (it) * | 1999-03-25 | 2002-03-22 | Franco Codignola | Procedimento per la produzione di acidi aromatici. |
| IT1319169B1 (it) | 2000-07-14 | 2003-09-26 | Eurotecnica Dev & Licensing Sr | Procedimento per la purificazione di acidi carbossilici aromatici. |
| US6765113B2 (en) | 2000-07-19 | 2004-07-20 | E.I. Du Pont De Nemours And Company | Production of aromatic carboxylic acids |
| US6420589B1 (en) | 2000-12-14 | 2002-07-16 | General Electric Company | Process for the production of diaryl carbonates |
| US6384262B1 (en) | 2000-12-14 | 2002-05-07 | General Electric Company | Process for the production of diaryl carbonates |
| US6521777B2 (en) | 2000-12-14 | 2003-02-18 | General Electric Company | Process for the production of diaryl carbonates |
| CA2492148A1 (en) * | 2002-07-09 | 2004-01-15 | Invista Technologies S.A.R.L. | Process for producing aromatic dicarboxylic acids under supercritical conditions |
| US7276625B2 (en) * | 2002-10-15 | 2007-10-02 | Eastman Chemical Company | Process for production of a carboxylic acid/diol mixture suitable for use in polyester production |
| US7132566B2 (en) * | 2003-09-22 | 2006-11-07 | Eastman Chemical Company | Process for the purification of a crude carboxylic acid slurry |
| PL375596A1 (en) * | 2002-12-09 | 2005-12-12 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| US7074954B2 (en) * | 2002-12-09 | 2006-07-11 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| US7161027B2 (en) | 2002-12-09 | 2007-01-09 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| KR100498490B1 (ko) * | 2003-02-28 | 2005-07-01 | 삼성전자주식회사 | 인페이스 신호와 쿼드러쳐 신호 간의 위상차를 가변시킬수 있는 쿼드러쳐 전압제어 발진기 |
| US7193109B2 (en) * | 2003-03-06 | 2007-03-20 | Eastman Chemical Company | Process for production of a carboxylic acid/diol mixture suitable for use in polyester production |
| US20050059709A1 (en) * | 2003-09-15 | 2005-03-17 | Meythaler Jay M. | Treatment of a neuropathy with rapid release aminopyridine |
| US7546747B2 (en) * | 2004-01-15 | 2009-06-16 | Eastman Chemical Company | Process for production of a dried carboxylic acid cake suitable for use in polyester production |
| US7214760B2 (en) * | 2004-01-15 | 2007-05-08 | Eastman Chemical Company | Process for production of a carboxylic acid/diol mixture suitable for use in polyester production |
| US20050283022A1 (en) * | 2004-06-18 | 2005-12-22 | Sheppard Ronald B | Filtrate preparation process for terephthalic acid filtrate treatment |
| US7608732B2 (en) * | 2005-03-08 | 2009-10-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7371894B2 (en) * | 2004-09-02 | 2008-05-13 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7608733B2 (en) * | 2004-09-02 | 2009-10-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7399882B2 (en) * | 2004-09-02 | 2008-07-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7482482B2 (en) * | 2004-09-02 | 2009-01-27 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7910769B2 (en) * | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7572932B2 (en) * | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7361784B2 (en) * | 2004-09-02 | 2008-04-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7582793B2 (en) | 2004-09-02 | 2009-09-01 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7683210B2 (en) | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7741515B2 (en) | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7586000B2 (en) * | 2004-09-02 | 2009-09-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US20060047153A1 (en) * | 2004-09-02 | 2006-03-02 | Wonders Alan G | Optimized liquid-phase oxidation |
| US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7589231B2 (en) * | 2004-09-02 | 2009-09-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7504535B2 (en) * | 2004-09-02 | 2009-03-17 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7507857B2 (en) * | 2004-09-02 | 2009-03-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7568361B2 (en) * | 2004-09-02 | 2009-08-04 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7495125B2 (en) * | 2004-09-02 | 2009-02-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7390921B2 (en) * | 2004-09-02 | 2008-06-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7572936B2 (en) * | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7381836B2 (en) * | 2004-09-02 | 2008-06-03 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| MX2007011184A (es) * | 2005-03-21 | 2007-10-03 | Bp Corp North America Inc | Proceso y aparato para fabricar acidos carboxilicos aromaticos, incluyendo formas puras de los mismos. |
| US7834208B2 (en) | 2005-05-19 | 2010-11-16 | Eastman Chemical Company | Process to produce a post catalyst removal composition |
| US7557243B2 (en) | 2005-05-19 | 2009-07-07 | Eastman Chemical Company | Enriched terephthalic acid composition |
| US7897809B2 (en) | 2005-05-19 | 2011-03-01 | Eastman Chemical Company | Process to produce an enrichment feed |
| US20060264664A1 (en) * | 2005-05-19 | 2006-11-23 | Parker Kenny R | Esterification of an exchange solvent enriched composition |
| US20060264662A1 (en) * | 2005-05-19 | 2006-11-23 | Gibson Philip E | Esterification of an enriched composition |
| US7304178B2 (en) | 2005-05-19 | 2007-12-04 | Eastman Chemical Company | Enriched isophthalic acid composition |
| US7432395B2 (en) | 2005-05-19 | 2008-10-07 | Eastman Chemical Company | Enriched carboxylic acid composition |
| US7884231B2 (en) | 2005-05-19 | 2011-02-08 | Eastman Chemical Company | Process to produce an enriched composition |
| US20060264656A1 (en) * | 2005-05-19 | 2006-11-23 | Fujitsu Limited | Enrichment process using compounds useful in a polyester process |
| US7741516B2 (en) | 2005-05-19 | 2010-06-22 | Eastman Chemical Company | Process to enrich a carboxylic acid composition |
| US7880031B2 (en) | 2005-05-19 | 2011-02-01 | Eastman Chemical Company | Process to produce an enrichment feed |
| US7919652B2 (en) | 2005-05-19 | 2011-04-05 | Eastman Chemical Company | Process to produce an enriched composition through the use of a catalyst removal zone and an enrichment zone |
| KR100708919B1 (ko) * | 2005-05-30 | 2007-04-17 | 삼성석유화학(주) | 테레프탈산의 회수 방법 |
| US7884232B2 (en) | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| WO2007076384A2 (en) * | 2005-12-29 | 2007-07-05 | Bp Corporation North America Inc. | Ethanolysis of pet to form det and oxidation thereof |
| US7358389B2 (en) * | 2006-01-04 | 2008-04-15 | Eastman Chemical Company | Oxidation system employing internal structure for enhanced hydrodynamics |
| US7355068B2 (en) * | 2006-01-04 | 2008-04-08 | Eastman Chemical Company | Oxidation system with internal secondary reactor |
| US20070179312A1 (en) * | 2006-02-02 | 2007-08-02 | O'meadhra Ruairi Seosamh | Process for the purification of a crude carboxylic axid slurry |
| US8697906B2 (en) * | 2006-03-01 | 2014-04-15 | Grupo Petrotemex, S.A. De C.V. | Methods and apparatus for producing a low-moisture carboxylic acid wet cake |
| US7462736B2 (en) * | 2006-03-01 | 2008-12-09 | Eastman Chemical Company | Methods and apparatus for isolating carboxylic acid |
| US8173836B2 (en) * | 2006-03-01 | 2012-05-08 | Grupo Petrotemex, S.A. De C.V. | Method and apparatus for drying carboxylic acid |
| US7847121B2 (en) * | 2006-03-01 | 2010-12-07 | Eastman Chemical Company | Carboxylic acid production process |
| US20070208199A1 (en) * | 2006-03-01 | 2007-09-06 | Kenny Randolph Parker | Methods and apparatus for isolating carboxylic acid |
| US7888529B2 (en) | 2006-03-01 | 2011-02-15 | Eastman Chemical Company | Process to produce a post catalyst removal composition |
| US7863483B2 (en) * | 2006-03-01 | 2011-01-04 | Eastman Chemical Company | Carboxylic acid production process |
| CN100368370C (zh) * | 2006-03-29 | 2008-02-13 | 中国石化仪征化纤股份有限公司 | 对二甲苯氧化母液中悬浮物的回收系统装置 |
| US8115029B2 (en) | 2006-11-02 | 2012-02-14 | University Of Kansas | Cobalt-catalyzed oxidations in volumetrically expanded liquids by compressed gases |
| RU2463096C2 (ru) * | 2007-12-20 | 2012-10-10 | Хитачи Плант Текнолоджиз, Лтд. | Способ фильтрации кристаллической суспензии |
| US8455680B2 (en) | 2008-01-15 | 2013-06-04 | Eastman Chemical Company | Carboxylic acid production process employing solvent from esterification of lignocellulosic material |
| US8614350B2 (en) | 2008-01-15 | 2013-12-24 | Eastman Chemical Company | Carboxylic acid production process employing solvent from esterification of lignocellulosic material |
| CN101417943B (zh) * | 2008-12-08 | 2010-11-10 | 中国纺织工业设计院 | 高效回收利用pta装置精制母液的简易方法和系统 |
| US8636898B2 (en) * | 2010-04-30 | 2014-01-28 | Antonio Perez | Site drainer |
| CN101914013B (zh) * | 2010-07-30 | 2015-03-18 | 浙江大学 | 一种节水的对苯二甲酸生产方法 |
| US8466312B2 (en) * | 2010-08-20 | 2013-06-18 | Grupo Petrotemex, S.A. De C.V. | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
| WO2012130827A1 (en) * | 2011-03-28 | 2012-10-04 | Dsm Ip Assets B.V. | Process for the preparation of condensation products of melamine |
| US20140175025A1 (en) * | 2012-12-21 | 2014-06-26 | Eastman Chemical Company | Generation of low-solids second mother liquor from terephthalic acid production filter |
| CN104338500B (zh) * | 2013-07-31 | 2015-12-02 | 沅江华龙催化科技有限公司 | 一种气液固多相反应分离同步反应器 |
| CN104338499B (zh) * | 2013-07-31 | 2016-01-20 | 沅江华龙催化科技有限公司 | 一种液固多相反应分离同步反应器 |
| MX2016007841A (es) | 2013-12-18 | 2016-10-07 | Bp Corp North America Inc | Proceso mejorado y aparato para fabricar acidos carboxilicos aromaticos. |
| BR112016015320A2 (pt) | 2013-12-30 | 2017-10-10 | Bp Corp North America Inc | misturas de alimentação de ácido carboxílico aromático bruto pressurizado |
| CN103772182B (zh) * | 2014-01-26 | 2015-06-17 | 沅江华龙催化科技有限公司 | 基于气液固多相反应分离同步反应器的利用空气氧化对二甲苯生产对苯二甲酸的方法 |
| JP2015140342A (ja) * | 2014-01-30 | 2015-08-03 | 株式会社日立製作所 | 精製テレフタル酸の製造方法 |
| CN103936581A (zh) * | 2014-04-24 | 2014-07-23 | 天华化工机械及自动化研究设计院有限公司 | 一种提高cta溶剂交换效率的方法 |
| CN105085231A (zh) | 2014-05-20 | 2015-11-25 | 天华化工机械及自动化研究设计院有限公司 | 一种pta工业装置氧化单元中醋酸溶剂的处理方法 |
| CN115867683A (zh) | 2020-08-14 | 2023-03-28 | 科氏技术英国有限公司 | 从氧化剂清洗流中回收金属催化剂 |
| WO2023021347A1 (en) | 2021-08-20 | 2023-02-23 | Koch Technology Solutions UK Limited | Nickel and cobalt separation in a pta process |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE926605C (de) * | 1953-07-22 | 1955-04-21 | Heinz Dipl-Volksw Hoening | Waschband fuer Drehfilter |
| GB970492A (en) * | 1960-10-18 | 1964-09-23 | Standard Oil Co | Production of aromatic carboxylic acids |
| GB926605A (en) * | 1961-03-24 | 1963-05-22 | Atomic Energy Authority Uk | Improvements in or relating to fire-detection apparatus |
| GB1152575A (en) * | 1965-05-17 | 1969-05-21 | Standard Oil Co | Purification of Aromatic Polycarboxylic Acids. |
| NL6606774A (de) * | 1965-05-17 | 1966-11-18 | ||
| NL7210541A (de) * | 1972-08-01 | 1974-02-05 | ||
| US4786753A (en) * | 1987-05-18 | 1988-11-22 | Amoco Corporation | Oxidation process for the manufacture of aromatic acids from alkylaromatic compounds |
| US4782181A (en) * | 1987-06-04 | 1988-11-01 | Amoco Corporation | Process for removal of high molecular weight impurities in the manufacture of purified terephthalic acid |
| JP2545103B2 (ja) * | 1987-12-17 | 1996-10-16 | 三井石油化学工業株式会社 | テレフタル酸スラリ―の分散媒交換方法 |
| JP2595657B2 (ja) * | 1988-05-27 | 1997-04-02 | 三井石油化学工業株式会社 | スラリーから結晶を回収する方法 |
| US4939297A (en) * | 1989-06-05 | 1990-07-03 | Eastman Kodak Company | Extraction process for removal of impurities from terephthalic acid filtrate |
| GB9102393D0 (en) * | 1991-02-05 | 1991-03-20 | Ici Plc | Production of terephthalic acid |
| US5175355A (en) * | 1991-04-12 | 1992-12-29 | Amoco Corporation | Improved process for recovery of purified terephthalic acid |
| WO1992018453A1 (en) * | 1991-04-12 | 1992-10-29 | Amoco Corporation | Process for preparation of terephthalic acid |
| US5200557A (en) * | 1991-04-12 | 1993-04-06 | Amoco Corporation | Process for preparation of crude terephthalic acid suitable for reduction to prepare purified terephthalic acid |
-
1991
- 1991-03-07 GB GB919104776A patent/GB9104776D0/en active Pending
-
1992
- 1992-02-02 DE DE69230569T patent/DE69230569T2/de not_active Expired - Lifetime
- 1992-02-02 ES ES96115916T patent/ES2142006T3/es not_active Expired - Lifetime
- 1992-02-20 EP EP96105413A patent/EP0722927A1/de not_active Withdrawn
- 1992-02-20 ES ES92301413T patent/ES2093189T3/es not_active Expired - Lifetime
- 1992-02-20 EP EP96115916A patent/EP0754673B1/de not_active Expired - Lifetime
- 1992-02-20 EP EP92301413A patent/EP0502628B1/de not_active Expired - Lifetime
- 1992-02-20 GB GB929203674A patent/GB9203674D0/en active Pending
- 1992-02-20 SG SG1996002186A patent/SG66231A1/en unknown
- 1992-02-20 DE DE69214859T patent/DE69214859T2/de not_active Expired - Lifetime
- 1992-02-25 ZA ZA921380A patent/ZA921380B/xx unknown
- 1992-02-28 CA CA002062063A patent/CA2062063C/en not_active Expired - Fee Related
- 1992-03-04 EG EG290192A patent/EG19876A/xx active
- 1992-03-05 JP JP4048527A patent/JPH0565246A/ja active Pending
- 1992-03-06 KR KR1019920003690A patent/KR100225371B1/ko not_active IP Right Cessation
- 1992-03-06 MX MX9200997A patent/MX9200997A/es not_active IP Right Cessation
- 1992-03-06 RU SU5011176A patent/RU2106337C1/ru active
- 1992-03-07 CN CN92101553A patent/CN1038409C/zh not_active Expired - Fee Related
- 1992-06-08 ID IDP97064092A patent/ID19108A/id unknown
-
1995
- 1995-06-06 US US08/470,955 patent/US5563293A/en not_active Expired - Lifetime
- 1995-06-06 US US08/470,965 patent/US5527957A/en not_active Expired - Lifetime
-
1996
- 1996-07-17 US US08/682,424 patent/US5679846A/en not_active Expired - Lifetime
- 1996-08-15 CN CN96109974A patent/CN1067977C/zh not_active Expired - Fee Related
-
1997
- 1997-05-22 US US08/861,595 patent/US5877346A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5877346A (en) | 1999-03-02 |
| KR920018005A (ko) | 1992-10-21 |
| CN1064676A (zh) | 1992-09-23 |
| GB9203674D0 (en) | 1992-04-08 |
| EP0502628A3 (en) | 1993-01-27 |
| KR100225371B1 (ko) | 1999-10-15 |
| EP0502628A2 (de) | 1992-09-09 |
| EP0754673A1 (de) | 1997-01-22 |
| ES2142006T3 (es) | 2000-04-01 |
| EP0502628B1 (de) | 1996-10-30 |
| CN1067977C (zh) | 2001-07-04 |
| US5563293A (en) | 1996-10-08 |
| MX9200997A (es) | 1992-10-01 |
| GB9104776D0 (en) | 1991-04-17 |
| US5527957A (en) | 1996-06-18 |
| RU2106337C1 (ru) | 1998-03-10 |
| CA2062063C (en) | 2002-07-09 |
| SG66231A1 (en) | 1999-10-19 |
| ES2093189T3 (es) | 1996-12-16 |
| CN1038409C (zh) | 1998-05-20 |
| CA2062063A1 (en) | 1992-09-08 |
| EP0754673B1 (de) | 2000-01-12 |
| DE69230569D1 (de) | 2000-02-17 |
| EG19876A (en) | 1996-06-30 |
| JPH0565246A (ja) | 1993-03-19 |
| DE69214859T2 (de) | 1997-02-27 |
| EP0722927A1 (de) | 1996-07-24 |
| US5679846A (en) | 1997-10-21 |
| ZA921380B (en) | 1993-08-25 |
| CN1150945A (zh) | 1997-06-04 |
| ID19108A (id) | 1998-06-18 |
| DE69214859D1 (de) | 1996-12-05 |
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