DE69315471T2 - Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung - Google Patents

Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung

Info

Publication number
DE69315471T2
DE69315471T2 DE69315471T DE69315471T DE69315471T2 DE 69315471 T2 DE69315471 T2 DE 69315471T2 DE 69315471 T DE69315471 T DE 69315471T DE 69315471 T DE69315471 T DE 69315471T DE 69315471 T2 DE69315471 T2 DE 69315471T2
Authority
DE
Germany
Prior art keywords
preparation
polymerization catalyst
olefin polymerization
supported
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69315471T
Other languages
English (en)
Other versions
DE69315471D1 (de
Inventor
Hans-Friedrich Dr Herrmann
Bernd Dr Bachmann
Walter Dr Spaleck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of DE69315471D1 publication Critical patent/DE69315471D1/de
Publication of DE69315471T2 publication Critical patent/DE69315471T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
DE69315471T 1992-04-29 1993-04-23 Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung Expired - Fee Related DE69315471T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92107331A EP0578838A1 (de) 1992-04-29 1992-04-29 Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung

Publications (2)

Publication Number Publication Date
DE69315471D1 DE69315471D1 (de) 1998-01-15
DE69315471T2 true DE69315471T2 (de) 1998-05-07

Family

ID=8209586

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69315471T Expired - Fee Related DE69315471T2 (de) 1992-04-29 1993-04-23 Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung

Country Status (13)

Country Link
US (2) US5578537A (de)
EP (1) EP0578838A1 (de)
JP (1) JP3416692B2 (de)
AT (1) ATE160793T1 (de)
AU (1) AU661142B2 (de)
CA (1) CA2095100A1 (de)
DE (1) DE69315471T2 (de)
ES (1) ES2113448T3 (de)
FI (1) FI106381B (de)
NO (1) NO300422B1 (de)
RU (1) RU2124526C1 (de)
TW (1) TW327181B (de)
ZA (1) ZA932982B (de)

Families Citing this family (95)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US6143854A (en) 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
TW298593B (de) * 1993-02-12 1997-02-21 Hoechst Ag
DE4336659A1 (de) * 1993-10-27 1995-05-04 Witco Gmbh Verfahren zur Herstellung von Alkylaluminoxanen auf inerten Trägermaterialien
DE59409642D1 (de) * 1993-11-24 2001-03-01 Targor Gmbh Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren
FI945959A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
EP0668157B1 (de) 1994-02-21 2003-05-21 Basell Polyolefine GmbH Siegelbare polyolefinische Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung
EP0685494B1 (de) * 1994-06-03 1998-10-07 PCD Polymere AG Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
DE4436113A1 (de) * 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
DE4446922A1 (de) * 1994-12-28 1996-07-04 Hoechst Ag Metallocenverbindung und ihre Verwendung als Katalysatorkomponente
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
EP0739897A1 (de) 1995-04-27 1996-10-30 Hoechst Aktiengesellschaft Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
TW338046B (en) * 1995-06-29 1998-08-11 Ciba Sc Holding Ag Process for the preparation of stabilized olefin polymers
US6239058B1 (en) * 1995-07-18 2001-05-29 Fina Technology, Inc. Process for activating a metallocene catalyst supported on silica
DE19546501A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
AU718884B2 (en) 1996-06-17 2000-04-20 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US5789278A (en) * 1996-07-30 1998-08-04 Micron Technology, Inc. Method for fabricating chip modules
JP2001511215A (ja) 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク ポリエチレンマクロマーを組み入れるプロピレンポリマー
BR9806952A (pt) 1997-02-07 2000-03-21 Exxon Chemical Patents Inc Preparação de macrÈmeros contendo vinila.
US6187882B1 (en) * 1997-02-21 2001-02-13 Council Of Scientific & Industrial Research Process for polymerization of olefins
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
AU2760599A (en) * 1998-02-04 1999-08-23 Friedman, Robert F. Method and apparatus for combining transponders on multiple satellites into virtual channels
EP0953582A1 (de) * 1998-04-27 1999-11-03 Fina Research S.A. Herstellung von Polyolefin
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
DE19860174A1 (de) 1998-12-24 2000-06-29 Clariant Gmbh Polymeroxidate und ihre Verwendung
FI990283A (fi) * 1999-02-12 2000-08-13 Borealis As alfa-olefiinin polymerointikatalysattorisysteemi ja sen käyttö alfa -olefiinien polymerointiin
CA2363628A1 (en) * 1999-02-22 2000-08-31 James Allen Ponasik Jr. Catalysts containing n-pyrrolyl substituted nitrogen donors
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
US6288181B1 (en) 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6417298B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417301B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417299B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6187879B1 (en) 1999-08-31 2001-02-13 Eastman Chemical Company Process for producing polyolefins
CN1367797A (zh) 1999-08-31 2002-09-04 伊斯曼化学公司 聚烯烃生产方法
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
DE60038900D1 (de) 1999-12-20 2008-06-26 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren
ES2282158T3 (es) 1999-12-21 2007-10-16 Exxonmobil Chemical Patents Inc. Interpolimeros de alfa-olefina adhesivos.
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
US20040127658A1 (en) * 2000-02-18 2004-07-01 Eastman Chemical Company Productivity catalysts and microstructure control
US6579823B2 (en) * 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US7056996B2 (en) * 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6747077B2 (en) 2000-10-17 2004-06-08 Ciba Specialty Chemicals Corporation Stabilized metallocene polypropylene
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
WO2002040549A2 (en) * 2000-11-17 2002-05-23 Univation Technologies, Llc A method for preparing a catalyst composition and its use in a polymerization process
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
US6803339B2 (en) 2001-09-14 2004-10-12 Bp Corporation North America Inc. Latent metallocene catalyst systems for olefin polymerization
DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
JP4742221B2 (ja) 2003-03-21 2011-08-10 ダウ グローバル テクノロジーズ エルエルシー モルホロジー制御オレフィン重合プロセス
US20070073012A1 (en) 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7985811B2 (en) 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
DE102006020486A1 (de) 2006-04-28 2007-10-31 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zur Polymerisation von Olefinen in deren Gegenwart
DE102007015707A1 (de) 2007-04-02 2008-10-09 Topas Advanced Polymers Gmbh Cycloolefin-Copolymere, Verfahren zu ihrer Herstellung, deren Verwendung und Katalysatoren
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
RU2479593C2 (ru) 2007-12-18 2013-04-20 Юнивейшн Текнолоджиз, Ллк Способ регулирования активности бимодального катализатора в процессе полимеризации
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
WO2010014344A2 (en) 2008-08-01 2010-02-04 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
EP2172490A1 (de) 2008-10-03 2010-04-07 Ineos Europe Limited Polimerisationsverfahren
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
CN102803280A (zh) 2009-06-11 2012-11-28 格雷斯公司 制造铝氧烷的方法和包括由此制备的铝氧烷的催化剂
EP2357035A1 (de) 2010-01-13 2011-08-17 Ineos Europe Limited Polymerpulveraufbewahrungs- und/oder -transport- und/oder -entgasungsgefäßen
WO2011090861A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Lubricating oil compositions and method for making them
KR101310592B1 (ko) 2010-02-04 2013-09-23 주식회사 엘지화학 올레핀 중합용 담지 메탈로센 촉매의 제조방법
EP2383301A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
EP2383298A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
US8895465B2 (en) * 2010-11-22 2014-11-25 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
SG190835A1 (en) 2010-11-29 2013-07-31 Ineos Commercial Services Uk Polymerisation control process
EP2663400A4 (de) 2011-01-14 2014-07-30 Grace W R & Co Verfahren zur herstellung eines modifizierten metallocenkatalysators, in diesem verfahren hergestellter katalysator und verwendung davon
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
US9181367B2 (en) 2011-10-17 2015-11-10 Ineos Europe Ag Polymer degassing process control
WO2013158254A1 (en) 2012-04-19 2013-10-24 Exxonmobil Chemical Patents Inc. Blocky ethylene propylene copolymers and methods for making them
BR112015031326B1 (pt) 2013-06-28 2021-05-25 Dow Global Technologies Llc processo para preparar uma composição de fluido de utilidade
US9963648B2 (en) 2013-06-28 2018-05-08 Dow Global Technologies Llc Process for the preparation of branched polyolefins for lubricant applications
CN105339334B (zh) 2013-06-28 2017-10-24 陶氏环球技术有限责任公司 用于制备轻度支化的疏水物的方法和对应的表面活性剂和其应用
EP3224287B1 (de) 2014-11-25 2019-05-01 Univation Technologies, LLC Verfahren zur steuerung des polyolefinschmelzindex
US10988497B2 (en) 2017-09-28 2021-04-27 Univation Technologies, Llc Synthesis of cyclic organic compounds and metallocenes
WO2022232760A1 (en) 2021-04-30 2022-11-03 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3424697C2 (de) * 1984-07-05 1999-07-08 Targor Gmbh Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4925821A (en) * 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937217A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US5008228A (en) * 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5006500A (en) * 1988-10-27 1991-04-09 Exxon Chemical Patents Inc. Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
DE3916553A1 (de) * 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
FR2656314B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2656315B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst

Also Published As

Publication number Publication date
US5614455A (en) 1997-03-25
ZA932982B (en) 1993-11-11
CA2095100A1 (en) 1993-10-30
FI931883A (fi) 1993-10-30
AU661142B2 (en) 1995-07-13
TW327181B (en) 1998-02-21
JPH0625350A (ja) 1994-02-01
NO931545L (no) 1993-11-01
NO300422B1 (no) 1997-05-26
EP0578838A1 (de) 1994-01-19
RU2124526C1 (ru) 1999-01-10
NO931545D0 (no) 1993-04-28
FI106381B (fi) 2001-01-31
JP3416692B2 (ja) 2003-06-16
ATE160793T1 (de) 1997-12-15
ES2113448T3 (es) 1998-05-01
US5578537A (en) 1996-11-26
DE69315471D1 (de) 1998-01-15
FI931883A0 (fi) 1993-04-27
AU3824993A (en) 1993-11-04

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